EP1632908A1 - Wertdokument mit Lumineszenzeigenschaften - Google Patents

Wertdokument mit Lumineszenzeigenschaften Download PDF

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Publication number
EP1632908A1
EP1632908A1 EP04020881A EP04020881A EP1632908A1 EP 1632908 A1 EP1632908 A1 EP 1632908A1 EP 04020881 A EP04020881 A EP 04020881A EP 04020881 A EP04020881 A EP 04020881A EP 1632908 A1 EP1632908 A1 EP 1632908A1
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EP
European Patent Office
Prior art keywords
response signal
feature
spectral
different
luminescent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP04020881A
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English (en)
French (fr)
Inventor
Thomas Dr. Giering
Gerhard Dr. Schwenk
Wolfgang Dr. Rauscher
Olivier Martin
Yannick Mechine
Lysis Cubieres
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Giesecke and Devrient GmbH
Banque de France
Original Assignee
Giesecke and Devrient GmbH
Banque de France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Giesecke and Devrient GmbH, Banque de France filed Critical Giesecke and Devrient GmbH
Priority to EP04020881A priority Critical patent/EP1632908A1/de
Priority to CN2005800369566A priority patent/CN101076835B/zh
Priority to RU2007111994/09A priority patent/RU2388054C9/ru
Priority to EP05784193.4A priority patent/EP1805727B1/de
Priority to US11/660,809 priority patent/US20080116272A1/en
Priority to KR1020077007220A priority patent/KR101280751B1/ko
Priority to ES05784193.4T priority patent/ES2627416T3/es
Priority to PCT/EP2005/009435 priority patent/WO2006024530A1/en
Priority to AU2005279291A priority patent/AU2005279291B2/en
Publication of EP1632908A1 publication Critical patent/EP1632908A1/de
Withdrawn legal-status Critical Current

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    • G—PHYSICS
    • G07—CHECKING-DEVICES
    • G07D—HANDLING OF COINS OR VALUABLE PAPERS, e.g. TESTING, SORTING BY DENOMINATIONS, COUNTING, DISPENSING, CHANGING OR DEPOSITING
    • G07D7/00—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency
    • G07D7/06—Testing specially adapted to determine the identity or genuineness of valuable papers or for segregating those which are unacceptable, e.g. banknotes that are alien to a currency using wave or particle radiation
    • G07D7/12—Visible light, infrared or ultraviolet radiation
    • G07D7/1205—Testing spectral properties

Definitions

  • This invention relates to a luminescent security feature whereby the security feature emits luminescence radiation upon excitation.
  • the invention likewise relates to a substrate having said luminescent security feature.
  • the invention relates further to an apparatus and a method for checking a luminescent security feature of a substrate to permit e.g. the authenticity of the substrate to be determined.
  • luminescent substances for marking bank notes has been known for some time.
  • these independent markings were also evaluated independently of each other.
  • the precondition for this was that the different substances emitted in different spectral ranges.
  • substances were used that emitted in the visible upon excitation with ultraviolet light or infrared light, such as up conversion luminescent materials or europium-doped yttrium vanadate or manganese-doped silicate.
  • the luminescent materials were printed on the supporting material or incorporated therein, for example worked into paper or also into security elements, such as security threads or mottling fibers.
  • Another known idea is to use the presence and absence of clearly separate luminescent spectral bands upon superimposition of different spectra for a coding in order to increase the number of distinguishable codings.
  • the different codings thus permit e.g. the denominations or also currencies to be distinguished.
  • the spectral coding with clearly separate luminescent spectral bands has the disadvantage that the forger can again easily analyze the latter and when analyzing several bank notes can also easily determine the coding, e.g. for the individual denominations.
  • EP 1182 048 discloses for example a method for authenticating a security document wherein the emission of a luminescence feature is already coded and said emission is compared with a reference spectrum.
  • WO 97/39428 proposes that a bank note should contain a high security feature consisting of a mixture of two different substances incorporated in or applied to the paper, and a low security feature consisting of another substance. It is described that the high security feature is checked in a high security area, such as a bank, while only the low security feature is checked in a low security area, such as in publicly accessible vending machines.
  • the problem of the present invention is therefore to increase the falsification security of bank notes or other security documents.
  • Substrates according to the invention are typically security documents such as bank notes or checks, value documents made of paper and/ or polymer such as passports, security cards such as ID or credit cards, labels for securing luxury goods, etc.
  • the definition for substrates also covers possible intermediate products on the way to the security document.
  • These are e.g. supporting materials with a security feature that are applied to or incorporated in an end substrate to be secured.
  • the supporting material can be a film element, such as a security thread, having the security feature.
  • the supporting material itself is connected to the object, such as a bank note, in the known way.
  • the formulation "substrate having a security feature” means that the security feature is connected to the substrate in all sorts of ways. This is done in the following manner.
  • the security feature can be applied to the substrate, e.g. directly by printing, spraying, spreading, etc., or indirectly by gluing or laminating a further material equipped with the feature to the substrate.
  • the security feature can be incorporated into the substrate itself, i.e. it can be incorporated into the volume of the paper or polymer substrate.
  • the security feature can be mixed with the paper pulp during papermaking, or it can be added to the plastic during extrusion of films.
  • radiation is not restricted to visible (VIS) radiation but includes other kinds of radiation such as radiation in the infrared (IR) or near infrared (NIR) spectrum or in the UV spectrum. Combinations of said kinds of radiation are also intended by the term “radiation” here. This applies to both excitation and emission radiation.
  • the excitation is effected with radiation in the invisible spectral range, particularly preferably with IR, NIR or UV radiation or combinations thereof.
  • response signal refers to radiation that is emitted by the luminescent security feature when it is irradiated with excitation radiation.
  • the response signal typically lies in the invisible spectrum and can be present for example in the IR, NIR and/or UV spectrum or combinations thereof.
  • the response signal is represented in the form of an emission spectrum, i.e. luminescence intensity versus emission wavelength.
  • the response signal is represented in the form of an excitation spectrum, i.e. luminescence intensity versus excitation wavelength.
  • Fig. 1 shows a substrate 10, which is a bank note 10 here by way of example.
  • the substrate 10 can likewise be any other type, including substrates for intermediate products in the form of a supporting material, such as a film or a thread, which is connected to the end substrate to be secured.
  • the substrate 10 comprises a luminescent security feature 100.
  • the feature 100 can be connected to the substrate 10 in any way, as mentioned above.
  • the feature 100 comprises luminescent feature substances which emit luminescence radiation in response to excitation radiation.
  • This response contains information, based on the spectral distribution of the response and/or the excitation (e.g. distribution of the intensity of the response in the wavelength range).
  • the luminescent security feature 100 preferably comprises at least two luminescent materials whose emission and/or excitation spectra differ and whose response signals are spectrally adjacent.
  • the excitation and the emission of the luminescent substances can be effected in the UV, in the VIS and/or in the IR. In the following IR will also include NIR.
  • substances can be used that are excited in the UV and emit in the visible spectral range, such as europium-doped yttrium vanadate Eu:YVO 4 , manganese-doped silicate, etc. It is further possible to use luminescent substances that are excited in the visible and emit in the visible. It is further possible to use substances that are excited in the visible and emit in the infrared. It is further possible to use substances that are excited in the infrared and emit in the visible, such as up conversion luminescent materials. Luminescent substances that are excited in the UV and also emit in the UV are preferred. Substances that are excited in the infrared and emit in the infrared are further preferred.
  • the following can be used according to the invention as substances that are excited in the visible (VIS) and emit in the infrared (IR)
  • Said substances are excited at approx. 550 nm and emit at approx. 1100 nm.
  • Substances that are excited in the infrared (IR) and emit in the visible (VIS) are so-called up conversion substances. According to the invention one can use
  • the substances to be used according to the invention are luminescent substances having a luminophore in a matrix.
  • the luminophores may be either ions or molecules.
  • the luminophores are particularly preferably rare earth elements, e.g. La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or else ions of Bi, Pb, Ni, Sn, Sb, W, Tl, Ag, Cu, Zn, Ti, Mn, Cr or V, as well as organic luminophores or any combinations thereof.
  • rare earth elements e.g. La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, or else ions of Bi, Pb, Ni, Sn, Sb, W, Tl, Ag, Cu, Zn, Ti, Mn, Cr or V, as well as organic luminophores or any combinations thereof.
  • luminophores examples are the fluorophores listed in Table 2. The stated values for the excitation wavelength and the emission peak are approximate, since these values strongly depend on the matrix in which the fluorophores are embedded (solvent shift). Table 2 Fluorophore Excitation wavelength Emission peak Rhodamine 6G 520 nm 560 nm Rhodamine 700 645 nm 644 nm Carbazine 720 650 670 IR 125 800 850 IR 144 760 850 HDITCI 780 830
  • organic luminophores examples include terphenyls, quarterphenyls, quinquephenyls, sexiphenyls, oxazoles, phenylfuran, oxadiazoles, stilbene, carbostyryl, coumarine, styryl-benzene, sulfaflavine, carbocyanin-iodide, fluoresceine, fluororole, fhodamine, sulforhodamine, oxazine, carbazine, pyridine, hexacyanine, styryls, phthalocyanine, naphthalocyanine, hexadibenzocyanine, dicarbocyanine.
  • the organic luminophores should be stabilized by suitable methods if the stability is not sufficient for the application.
  • the matrices are in particular inorganic host lattices, such as YAG, ZnS, YAM, YAP, AlPO 5 zeolite, Zn 2 SiO 4 , YVO 4 , CaSiO 3 , KMgF 3 , Y 2 O 2 S, La 2 O 2 S, Ba 2 P 2 O 7 , Gd 2 O 2 S, NaYW 2 O 6 , SrMoO 4 , MgF 2 , MgO, CaF 2 , Y 3 Ga 5 O 12 , KY(WO 4 ) 2 , SrAl 12 O 19, ZBLAN, LiYF 4 , YPO 4 , GdBO 3 , BaSi 2 O 5 , SrBeO 7 , etc.
  • inorganic host lattices such as YAG, ZnS, YAM, YAP, AlPO 5 zeolite, Zn 2 SiO 4 , YVO 4 , CaSiO 3 ,
  • Organic matrices such as PMMA, PE, PVB, PS, PP, etc., are also particularly suitable.
  • inorganic luminescent substances which have rare earth elements in inorganic matrices are used.
  • the following substances can be used:
  • the fluorophore is dissolved in the organic matrix, polymerized completely and freeze-ground.
  • the thus produced pigments can then be processed further, by optionally adding TiO 2 and mixing with binder to provide a printing ink.
  • an undoped matrix can be produced in powder form in a first step, and processed under pressure in the autoclave together with the fluorophore in a second step.
  • rare earth elements as a luminophore are preferably combined with inorganic matrices, and organic luminophores combined with organic matrices.
  • chelates as a luminescent substance, whereby e.g. a rare earth element is integrated in an organic cage here.
  • rare earth based systems are preferably used. These are systems that are based on the luminescence of rare earth ions inserted into a host lattice, a so-called "matrix".
  • the at least two luminescent substances with overlapping emission spectra preferably have the same matrix but a different luminophore here, or alternatively a different matrix with the same luminophore.
  • the host lattices can differ in crystallographic configuration and/or in chemical composition.
  • the matrices can firstly have the same chemical composition (e.g. produced from the same chemical elements, generally with different contents of said elements), but with different crystallographic configurations.
  • Such matrices form a family of matrices which are very similar chemically but differ in their crystallographic structures.
  • Examples of such a family include YAG (Y aluminum garnet Y 3 Al 5 O 12 ) matrices and YAM (monoclinic yttrium aluminate Y 4 Al 2 O 9 ) matrices.
  • the matrices can have the same crystallographic configuration but a different chemical composition.
  • Such matrices can be produced for a given crystallographic structure, comprising atoms or groups of atoms selected from e.g. O, N, C, Y, Al, Fe, Cr, P, W, Si, Zn, Gd, Ga, S, La, Ca.
  • narrowband luminescent substances are used according to the invention.
  • said narrowband luminescent substances are combined with luminescent substances that emit broadband radiation and luminesce in the same wavelength range as the narrowband luminescent substance.
  • the broadband luminescent substances that can be used are either inorganic or organic substances. It is of course also possible according to the invention to use substances that exhibit only broadband luminescence.
  • corresponding luminescent substances are selected so that the emission spectra of at least two substances overlap spectrally.
  • Fig. 4 shows schematically a spectrum (luminescence intensity versus wavelength) wherein several substances with single spectral bands P in combination form the luminescence feature 100, the envelope of the total luminescence feature being shown by the dashed line.
  • overlap of spectra refers to at least two spectral bands of different substances which overlap essentially, i.e. the spectral bands cannot be analysed independently from each other. Thus, a complete separation of the individual spectral bands is not possible.
  • the resolution of the measurement is typically about 10 to 15 nm.
  • broadband refers to a response signal represented by a broadband envelope which is not structured so that spectral details of overlapping spectra are not resolved (see e.g. dotted line in Fig.4).
  • Narrowband refers to a response signal represented by a spectral finger print, i.e. spectral details of overlapping spectra can be analysed (see e.g. dashed line in Fig. 4).
  • Narrow spectral bands preferably have a FHWM of about 50 nm or smaller, e.g. regarding organic systems or UV-VIS systems. More preferably, the narrow spectral bands have a FHWM of about 15 nm or smaller, e.g. regarding rare earth systems.
  • an overlap of the excitation spectra can be used instead of the overlap of the emission spectra.
  • the complexity of the security feature can be increased further if not only two substances of the security feature overlap spectrally, but if the number of substances is increased further. This makes it possible to provide luminescent security features that cover a wide wavelength range. Within this wavelength range many different combinations of codings can then be created due to the differing spectra.
  • an overlap of at least two spectra is present in at least one spectral range.
  • This area will also be designated the overlap area in the following.
  • the spectral bands of said further spectrum thus lie in another spectral range which can directly adjoin the first overlap area or else be spaced therefrom.
  • the further spectrum can itself again consist of a combination of overlapping spectra of different substances so that a second overlap area is present, or else be the spectrum of a single substance.
  • spectral ranges that are not directly adjacent but are wavelength ranges apart.
  • one spectral range lies in the visible while the other spectral range lies in the infrared.
  • different radiations are used for exciting the two spectral ranges, such as excitation with UV radiation/ emission in the visible and excitation in the visible/ emission in the infrared.
  • powdered Mn:Zn 2 SiO 4 is mixed with powdered Pr:Y 2 O 2 S and added to the paper pulp during papermaking. Upon irradiation of the finished paper with UV radiation, Mn:Zn 2 SiO 4 luminesces at 520 nm and Pr:Y 2 O 2 S at 515 nm.
  • powdered Tb:La 2 O 2 S, powdered Tb:Y 2 O 2 S and powdered Ag,Ni:ZnS are mixed.
  • the powder mixture is processed to a printing ink and printed on security paper.
  • the three compounds luminesce at the values stated in the table, whereby the three luminescent spectral bands overlap.
  • powdered Er:LaPO 4 , powdered Er:Gd PO 4 and powdered Er:CePO 4 are mixed.
  • the luminescent substances have the same luminophore but have different matrices.
  • the powder mixture is processed to a printing ink and printed on security paper. Upon irradiation of the print with IR radiation the three compounds luminesce in the IR, whereby the three luminescent spectral bands overlap.
  • powdered Er:YAl 12 O 19 and powdered Er:GdAl 12 O 19 are mixed.
  • the luminescent substances have the same luminophore but have different matrices.
  • the powder mixture is processed to a printing ink and printed on security paper. Upon irradiation of the print with IR radiation the two compounds luminesce in the IR, whereby the luminescent spectral bands overlap.
  • the luminescent substances so that the different substances are excited by radiation in different spectral ranges and/or emit in different spectral ranges, for example substances that are excited in the UV and emit in the VIS can be combined with substances that are excited in the visible and emit in the visible. If the spectral ranges of these substance combinations are adjacent, very compact sensors can be produced because the spectral separation can be performed with a single element, e.g. a spectrometer or filter systems, that cover or covers both wavelength ranges of the combinations.
  • overlapping combinations of single substances are located at least in one of said wavelength ranges. It is at first possible that such overlapping combinations in one spectral range are combined with pure spectra (i.e. spectra of pure substances) in another spectral range. This permits the number of distinguishable single substances to be greatly increased, whereby the security is additionally increased over systems today available.
  • Powdered Ce:YPO 4 (emission peak at approx. 380 nm), powdered Ti:Ba 2 P 2 O 7 (emission peak at approx. 500 nm) and powdered Mn,Pb:CaSiO 3 (emission peak at approx. 610 nm) are mixed.
  • the powder mixture is processed to a printing ink and printed on security paper.
  • the three compounds luminesce at the stated values in the UV and VIS, whereby the luminescent spectral bands of Ti:Ba 2 P 2 O 7 and Mn,Pb:CaSiO 3 overlap in the VIS, while Ce:YPO 4 luminesces as an single substance in another spectral range (UV).
  • UV spectral range
  • a development according to the invention is likewise to combine two or more wavelength ranges in which overlapping single substances are located, in the borderline case over the total available spectral range of luminescent substances. It is then selectable for each single spectral range whether single substances or combinations of overlapping spectra are used as long as at least one spectral range shows overlapping spectra.
  • the three luminescent substances Mn:MgGa204 (21), Eu:Sr 2 P 2 O 7 (22) and YNBO 4 :TB (23) are combined.
  • the luminescent substances can be added in powder form to the paper pulp during papermaking or else be mixed with a binder for producing a printing ink.
  • Fig. 6 shows the excitation spectra (dashed lines) as well as the emission spectra (whole line) of the three luminescent substances.
  • the emission peak of Eu:Sr 2 P 2 O 7 is at approx. 450 nm, the emission peak of Mn:MgGa 2 O 4 at approx. 500 nm and the emission peak of YNBO 4 :Tb at approx. 545 nm.
  • the excitation spectra are produced by irradiating the luminescent substances with light sources of different wavelengths and ascertaining which radiation triggers luminescence.
  • light sources of different wavelengths and ascertaining which radiation triggers luminescence.
  • two UV lamps are used which emit at 254 and 365 nm, and three LEDs emitting at 380, 400 or 420 nm.
  • the different light sources shine on the sample alternately so that the particular response signal can be determined.
  • both the excitation and the emission spectra overlap, so that both spectra can be used for the inventive evaluation.
  • a central bank can for example resolve both the excitation and the emission spectra, while e.g. a commercial bank can resolve the excitation spectrum but not the emission spectrum and can thus measure only an envelope 30 (dot-dash line) in the range around 500 nm.
  • a commercial bank can resolve the excitation spectrum but not the emission spectrum and can thus measure only an envelope 30 (dot-dash line) in the range around 500 nm.
  • envelope 30 dot-dash line
  • Ce:YPO 4 has an emission peak of 380 nm, Ce:Y 2 SiO 5 an emission peak of 415 nm, Ti:Ba 2 P 2 O 7 an emission peak of 500 nm and Mn,Pb:CaSiO 3 an emission peak of 610 nm.
  • Two spectral ranges can thus be delimited from each other, the first spectral range reaching from approx. 300 to 450 nm and the second spectral range from approx. 450 to 650 nm.
  • the denomination 10 is characterized by two overlapping spectra in the first spectral range, whereby no signal is present in the second spectral range.
  • the denomination 20 is characterized by two overlapping spectra in the first spectral range, whereby a single spectral band of Ti:Ba 2 P 2 O 7 is present additionally in the second spectral range.
  • Denomination 30 is characterized by two overlapping spectra in the first spectral range, whereby a single spectral band of Mn,Pb:CaSiO 3 is present additionally in the second spectral range.
  • Denomination 40 is characterized in that two overlapping spectra are present both in the first and in the second spectral range.
  • Denomination 50 is characterized by a single spectral band of Ce:YPO4 while two overlapping spectra are present in the second spectral range.
  • a central bank could be given all information about the specific presence of overlapping and non-overlapping spectra. The central bank would thus be able to ascertain for which denominations single spectral bands and/ or overlapping spectra are present. From this information a possibly present coding can then be selected additionally.
  • Commercial banks can be given only partial information. For example, a commercial bank can resolve the overlapping spectra in the first spectral range of the denominations 10 and 40, but only measure the envelope in the second spectral range for the denomination 40. Manufacturers of vending machines, for example, have access to even less information.
  • the possibilities of combination can be further increased e.g. by using further luminescence substances in the single spectral ranges, by utilizing further spectral ranges and by using dummy matrices, so that accordingly exclusive codings are available for a large number of applications.
  • the complex representation of the expected response signal can comprise more than one spectral band.
  • the spectral bands of said complex representation can form a code which is compared with a code formed by the spectral bands of the stored complex representation.
  • This code can be based on the particular wavelengths of the single spectral bands.
  • the code can be based on the particular intensities of the spectral bands.
  • a code can also be developed that is based both on the wavelengths and on the intensities.
  • rare earth systems based on only one rare earth ion in different matrices will also be used for the inventive systems.
  • rare earth systems based on only one rare earth ion in different matrices.
  • luminescence spectrums such differences are far too small to allow a clean separation of the mutually independent single substances.
  • an inventive combination then consists of a rare earth ion which is inserted into two different matrices which are embedded into the security element.
  • this type of coding can be performed either with the emission spectra or with the excitation spectra (or with both).
  • Exact analysis even shows that rare earth ions are particularly well suited for this kind of coding since they have very narrowband spectra, and so many different inventive combinations in different wavelength ranges can be combined into a total system, which greatly increases the complexity of the feature system and thus the security vis-à-vis forgers.
  • the security of the inventive system can be increased even further if not only the emission spectra overlap but also the excitation spectra.
  • two inventively overlapping systems are adjusted so that upon excitation with an excitation wavelength ⁇ 1 a given emission spectrum is adjusted.
  • This is intended to mean that the emission spectrum corresponds to a given emission spectrum within the given tolerances.
  • the security of the inventive system can be furthermore increased even more by combining different inventive combinations that are "adjusted" to each other with different excitation wavelengths.
  • the indices ⁇ , ⁇ and ⁇ state the contents of the substances. Different batches of the single substances A1, A2 and A3 can be combined whose excitation spectra differ.
  • the overlapping spectrum of the single substances A1 and A2 corresponds to a given regularity for all batches of A1 and A2 (only) when excitation is effected at a wavelength ⁇ 1
  • the overlapping emission spectra of the single substances A2 and A3 corresponds to a given regularity for all batches of A2 and A3 (only) when excitation is effected at a wavelength ⁇ 2 unequal ⁇ 1.
  • a light source e.g. the light source 20 explained more precisely hereinafter with respect to Fig. 2, must emit at least at the two excitation wavelengths ⁇ 1 and ⁇ 2.
  • An extension to more than three single substances is possible without qualification.
  • This principle is likewise applicable when the coding is not performed with the emission spectra but with the excitation spectra.
  • the response R must be detected with at least two wavelengths via which the single substances can be adjusted to each other.
  • the luminescence feature can furthermore comprise at least one inactive dummy matrix.
  • an inactive dummy matrix has the advantage of further confusing the forger wanting to perform a chemical analysis of the luminescence feature.
  • An inactive dummy matrix consists e.g. exclusively of matrix material, i.e. the matrix contains no luminophore. Consequently the inactive dummy matrix does not show any luminescence effect when it is exposed to the excitation radiation.
  • the dummy matrix contains the same luminophore as the luminescent substance, but the luminescence of the luminophore in the dummy matrix is prevented completely by small additions of so-called luminescence quenchers.
  • Such an inactive dummy matrix has a strong effect on the results of the analysis of the feature by the forger, but does not have any influence on the spectral emission characteristics of the feature.
  • the one or more inactive dummy matrices in the luminescence feature can, in an alternative embodiment, be different from the matrix or matrices that contain a luminophore and are optically active.
  • the chemical composition of the security feature can also be determined by means of element analysis for checking authenticity.
  • the crystallographic configuration can furthermore be used as an authenticity feature.
  • the detailed analysis of the inactive dummy matrices can be suitable for authenticity verification of the substrate.
  • the security feature comprises at least two inactive dummy matrices, whereby said inactive dummy matrices form a code which can be determined by detailed analysis, as mentioned above.
  • Table 4 Different luminescent substances which were combined with one or two dummy matrices are used for marking three different denominations of a currency XY.
  • Denomination 10 contains as a luminescent substance Yb,Er:Y 2 O 2 S and two further substances, namely YVO 4 and ZBLAN, which function as dummy matrices. The latter do not luminesce themselves.
  • Denomination 20 contains as a luminescent substance Yb,Er:YVO 4 as well as the dummy matrices ZBLAN and Yb,Er,Dy:Y 2 O 2 S. In comparison with substance 1 of the denomination 10, substance 1 of the denomination 20 additionally contains DY which works as a quencher, so that substance 1 of the denomination 20 does not show any luminescence.
  • Denomination 30 contains two luminescent substances and one dummy matrix.
  • the luminescent substances should be selected so as to have overlapping spectra.
  • the luminescent substances listed in Table 4 can therefore be supplemented or replaced in suitable fashion.
  • the application e.g. consists in incorporating the feature substances as powder mixture into a substrate (paper, polymer substrate, incl. polymer coating, incl. paper coating, cardboard, patches, threads, stickers, screen printing elements).
  • a substrate paper, polymer substrate, incl. polymer coating, incl. paper coating, cardboard, patches, threads, stickers, screen printing elements.
  • the problem here is to incorporate the mixture of pigments into the substrate in such a way, that the information of the encoding is preserved.
  • the powders are provided as raw powders and mixed in dry process by means of a mixer.
  • a mixer it could be useful to add additives, that improve the miscibility.
  • a security element or another corresponding element e.g. doctor blade foil
  • a quantitative comparison is produced and compared to standards.
  • the powder is dispersed in a large vessel and successively added in an appropriate fashion to the paper pulp.
  • a detector which possibly measures more specific than the hereinafter described detectors for checking bank notes being in circulation, is moved across the paper web or the substrate in general and proves that it is the right code.
  • the detector is only able to indicate the correspondence of the measured encoding with the predetermined encoding or its quality, but it does not intervene in a controlling or regulating fashion.
  • a metering station can be implemented, which assumes the following functions: For each individual substance of the powder a concentrate is produced, which is filled in different tanks in the metering station. Again a detector can be employed, which via a control system ensures, that the individual substances are apportioned correctly.
  • the system is adjusted in such a way, that at the usual excitation wavelength of 365 nm it leads to a defined emission spectrum. But, furthermore, it is conceivable and subject matter of the invention, that an unusual excitation wavelength, e.g. 254nm is used, which also leads to luminescence emission of the individual substances.
  • This can be achieved e.g. by controlling the manufacturing conditions, for example the annealing time or by choosing the appropriate particle sizes.
  • the intensity values at an excitation wavelength of 254nm can be kept constant whereas they vary at 365 nm.
  • the first two systems from example 1 are adjusted to each other at 254nm, while the 3rd system (Ag-codoped) is adjusted to one of the first two at a wavelength of 365nm. It is also possible, that all three systems are adjusted to each other at the same wavelength.
  • Fig. 2 in a very schematic way shows by way of example an apparatus for checking such a feature 100.
  • Such apparatus can be employed e.g. in bank note counting apparatus or bank note sorting apparatus, bank note depositing machines or bank note dispensers or in vending machines or also in handheld checking devices.
  • the substrate 10 with the feature 100 i.e. e.g. a bank note 10
  • excitation radiation E which is emitted by a light source 20 or by several light sources 20.
  • the feature 100 When exposed to radiation the feature 100 emits a response signal R in the form of luminescence radiation.
  • This response signal R i.e. the radiation coming from the bank note 10 is measured by a detector 30, which comprises one or several sensors so as to permit measuring in different spectral regions, the detector 30 preferably having a spectrometer.
  • the detector 30 is connected to a processor unit 31, which is able to evaluate the information given by the luminescence response signal R.
  • the processor unit 31 is connected to a storage unit 32, in which the expected response signals of real bank notes or quantities derived therefrom are stored as reference signals.
  • the response signal R is compared to predetermined response signals or derived quantities that serve as reference signals and are stored in the storage unit 32.
  • the reading device 1 here can comprise, depending on the use, only the detector 30, or optionally also the further components 20, 31, 32 in one housing.
  • One essential idea of the present invention is, that in areas with different security categories the checking of an identical luminescent security feature is carried out in different ways, using different sensor parameters for different security categories.
  • the same luminescent substance can be used for all security categories, the substance, however, has to be checked in different ways by the users in the areas of the different security categories.
  • a producer of sensors may provide for customers for the use in areas with low security category, such as e.g. for producing vending machines, which usually are put up without high security requirements and freely accessible for everybody, only such sensors which can measure the luminescence radiation of bank notes with a lower spectral resolution than sensors, which the producer of sensors may provide for customers, such as e.g. commercial banks with higher security category.
  • the high-quality sensors used by the central banks (highest security category) for checking bank notes being in circulation are exclusively provided for these and without their approval such sensors cannot be provided for any other institution.
  • the excitation radiation E which is used for the simplified mode and the complex mode respectively, does not necessarily have the same wavelength.
  • the excitation radiation is an IR- or an UV-radiation. Radiation of different wavelengths, depending on the mode, can also be employed.
  • the light sources 20 excite at different wavelengths.
  • the light source can also be used for exciting the luminescence in different feature substances, contained in the substrate 10 as a combination, at the wavelength most appropriate in the individual case.
  • a low security category such as e.g. in vending machines
  • the luminescence feature 100 comprises e.g. at least two luminescent materials, which produce respective luminescence spectral bands as a response when excited by an excitation radiation E.
  • the actually measured spectral bands have a certain non-vanishing width even when using the highest-quality sensors, the individual spectral bands not yet being blurred to one continuous spectrum and thus the details of the spectrum being preserved.
  • the broad-band envelope (dotted line) as shown in Fig. 4.
  • This envelope represents a simplified, broad-band response signal, while the individual frequency-resolved representation of the individual spectral bands can be seen as complex representation of the same response signal.
  • the resolution of the simplified, broad-band response signal is of such a low degree, that the individual spectral bands of the response signal are not resolved, and merely the response signal averaged across a given wavelength range is measured.
  • the response signal of the feature can be measured according to the present invention:
  • the simplified mode requires only a simple detector and can be carried out e.g. with a low-cost broad-band sensor, whereas the complex mode can be carried out only with a higher resolving detector, which is also able to identify individual spectral bands of the response signal.
  • One of the further modes e.g. is the following case, in which the central bank can ascertain the response signal as a completely highly-resolved spectrum across the whole measurable wavelength range.
  • the commercial banks e.g. would only be able to resolve a first spectral partial area, while in a second spectral partial area they could measure the presence or absence of a signal, but they would not be able to resolve it.
  • the producers of vending machines or tills would e.g. only be able to receive information about the second spectral partial area.
  • the last-mentioned group may also only be able to measure the presence or absence of a signal but not to resolve it.
  • the security feature 100 is e.g. a combination of Eu:SrB 4 O 7 with spectral band at 370 nm and Pb:BaSi 2 O 5 with spectral band at 350 nm, there can be provided, that only the reading devices employed in the central banks use a spectrometer with a resolution of a few nanometres, so as to be able to determine, that the two substances are present in the security feature.
  • the reading devices of the commercial banks and producers of vending machine are equipped with a spectrometer, then this is provided with a distinctively lower resolution, e.g. 30 - 50 nm, so that a differentiation of the spectra of the security feature, i.e. the spectra of Eu:SrB 4 O 7 and Pb:BaSi 2 O 5 cannot be effected.
  • the information about the combination of overlapping spectra by this means remains restricted to the area of the central bank.
  • the determination of the spectral course with different resolutions can be achieved on the one hand by providing reading devices 1 for the different areas of use, which have a different resolution e.g. due to differently designed diffraction gratings.
  • the different sensor parameters therefore, are caused by the different design of the reading devices 1.
  • the reading devices 1 provided in the different areas of use in principle are of the same design and e.g. also have identical diffraction gratings, the different measuring accuracy only being present in a different evaluation of the measured signals.
  • This can e.g. mean that software-controlled in the processor unit 31 of the detector 30 of a lower security category for carrying out the simple checking mode only the measured values according to the curve 16 of Fig. 5 are evaluated, while the software of the processor unit 31 of the detector 30 of a higher security category for carrying out the complex checking mode evaluates the spectrum according to the graph 15 of the Fig. 5.
  • the simplified mode thus can be carried out also by the higher-resolving detector, by converting, in this case, the response into a broad-band signal (e.g. by a resolution-reducing folding) before the signal is compared to the simplified representation stored as reference signal. Therefore, in the sensor has to be deposited not the high-resolution reference signal, but only the broad-band signal which is less critical with regard to security.
  • a sensor producer can offer, for example, reading devices 1 with detector 30 and processor unit 31, which can carry out both the complex checking intended for the high security area as well as the simple checking intended for the area requiring lower security.
  • the releasing is effected by means of software, for each different area of use certain software functions of the processor unit 31 can be released or locked, so that for example only in the area of a high security category the measuring of luminescence can be carried out with a high resolution (e.g. curve 15 in Fig. 5) and in the area of a low security category only a measuring with a low resolution (e.g. curve 16 in Fig. 5) can be carried out.
  • the reference signal is deposited preferably in an encoded form in the sensor.
  • a security feature 100 made of Eu:SrB 4 O 7 and Pb:BaSi 2 O 5 e.g. in all pertinent reading devices spectrometers with a resolution of 2 nm will be used, but only in the reading devices employed in the central banks an evaluation software is installed, which then actually evaluates the measured values obtained with this resolution. All other sensors will have an evaluation software in the processor unit, which transforms the data measured with the high resolution of 2 nm into a lower resolution and not until then evaluates.
  • the evaluation software usually is stored encoded in the reading device, the forger is not able to obtain exact details on the composition of the security feature 100 by using reading devices designed for the low security.
  • the security category of a user of the reading device 1 can be checked. This user can authorize himself e.g. by chip cards, a biometric identification or a PIN-entry.
  • the reading unit of the reader preferably comprises several narrow-band detectors, each narrow-band detector being adapted to the detection of a part of the response signal in a narrow-band region of the spectrum.
  • the respective narrow-band wavelength ranges of which the spectrum is composed can cover a wavelength spectrum in a continuous or discontinuous fashion, i.e. only in a regional fashion.
  • a narrow-band wavelength range is of a 10 nm width.
  • the response signal is represented, particularly preferred, as an amount of narrow-band response signals, each narrow-band response signal being measured by an individual narrow-band detector.
  • At least one spectral band of the response signal R is individually measured and the narrow-band response signals R are compared to a complex representation of the expected response signal, which is formed by expected narrow-band response signals and at least comprises one spectral band, i.e. to a reference signal, which has a higher resolution than the respective reference signal of the simple mode.
  • the substrate is illuminated with at least one excitation radiation E, the luminescence response of the security feature to this excitation radiation is measured and the response signal is compared to the expected representation, i.e. to the expected reference signal of the response signal (the representation here is simplified or complex, depending on the mode).
  • the authenticity of the information contained in the response signal R can be identified and thus the authenticity of the checked bank note 10 verified.
  • the security feature 100 is e.g. a combination of Er:CaF2 with a spectral band at 845 nm and Er:YAG with a spectral band at 862 nm
  • two narrow-band detectors with filters are used for carrying out the complex checking mode, which each measure in a spectral region of a width of approx. 15 nm.
  • the first narrow-band detector here measures in a range of 840 to 855 nm and the second narrow-band detector in a range of 855 to 870 nm.
  • the measured response signal can be compared to an expected response signal, so as to check the authenticity of the bank note 10.
  • the response signal can represent a further information, which is also connected to the substrate 10, as e.g. the denomination or the serial number of a checked bank note 10. Only if the measured response signal corresponds to the expected response signal and, additionally, the further information e.g. denomination-specific information represented by the response signal, corresponds to the denomination known because of other checks, the authenticity of the substrate 10 is confirmed.
  • the further information e.g. denomination-specific information represented by the response signal
  • the security feature 100 optionally in combination with other substances, has Mn:Zn 2 SiO 4 with a spectral band at 520 nm and Ce:YPO 4 with a spectral band at 380 nm, there can be provided, that the quantity ratio between Mn:Zn 2 SiO 4 and Ce:YPO 4 and therefore the pertinent response signals is denomination-specifically differently chosen.
  • the reading device of the central banks When the reading device of the central banks has concluded e.g. from a checking of the printed image and/ or the dimensions of the bank note 10, its denomination, there can be checked, whether the ratio of the signal intensities at 380 nm to 520 nm in fact corresponds to the quantity specific for the denomination determined before. If not, it is a forgery.
  • the denomination from determining the ratio of the signal intensities at 380 nm to 520 nm and, optionally, only then other evaluations, e.g. a determination of denomination by means of other checks are carried out.
  • the detector employed in this area reads the encoded spectrum or the encoded spectra (excitation spectrum and/ or emission spectrum) and checks, whether it is a certain spectral signature, i.e. one of several codes possible with bank notes, whereas, however, it is not possible to ascertain which of the several possible encodings in fact is present.
  • the encoding can be determined (only) partially, i.e. checked whether the read encoding is assignable to a partial amount (i.e. family) of predetermined encodings of real bank notes, whereas it is not determined, which exact encoding it is.
  • a high-security reading device which is employed in a central bank and works with a resolution of e.g.10 nm and therefore can differentiate between the individual spectral bands of the three substances, can exactly differentiate the ratio of the signal intensities of the three individual spectral-bands wavelengths of 596 nm, 632 nm and 610 nm. Because of this with such a reading device the individual encodings, which are e.g. denomination-specific, can be differentiated.
  • the exact code is determined by measuring the response signal R in an exactly enough fashion, so as to be able to assign it to a predetermined encoding of real bank notes or to determine, that it is not an encoding of real bank notes.
  • the measuring of the response signal R can be effected - irrespective of whether carried out in simplified or complex mode - in different wavelength ranges.
  • Fig. 3 for example shows the two wavelength ranges D1 and D2.
  • Fig. 3 shows a schematic representation of a further example of a response signal R, i.e. the signal intensity dependent on the wavelength of the emission spectrum of the feature 100 when respectively excited.
  • This spectrum has luminescence spectral bands P at certain wavelengths.
  • the spectral bands as schematically shown in Fig. 3, are idealized spectral bands, without any width along the horizontal wavelength axis.
  • a real response would, according to the example of Fig. 4, show spectral bands, which of course have a certain width and spectrally overlap each other.
  • the border between the wavelength ranges D1 and D2 preferably is defined by the band edge of a silicon detector.
  • This band edge lies at approx. 1100 nm.
  • Silicon detectors are easily accessible and well proven, while for higher wavelengths above the band edge of silicon detectors, substantially more complicated and expensive detection technologies have to be employed. Furthermore, these are difficult to access, which is of benefit to the protection from forgery.
  • the simplified representation of the response signal R preferably extends beyond the band edge of a silicon detector.
  • the sensor unit of the detector should be adapted (both when using them in simplified or in complex mode), so as to be able to completely read the wavelength spectrum of the response signal R.
  • the simplified representation of the response signal R consists of at least two simplified representations of an expected response signal, each simplified representation of the expected spectrum being defined for a respective, preferably spaced-apart from each other wavelength range.
  • the threshold value can correspond to the band edge of a usually available silicon detector.
  • each individual spectral band additionally has to be measured as such in a frequency-resolved fashion.
  • Fig. 5 schematically shows the luminescence spectrum R of the same feature 100, measurable with two different detectors 30 with different spectral resolution, i.e. the dependence of the measured radiation intensity I on the wavelength ⁇ of the luminescence radiation.
  • the continuous curve 15 shows the luminescence spectrum R measured with higher resolution and the dotted curve 16 the luminescence spectrum R measured with lower resolution.
  • the feature to be checked shall be a mixture of two luminescent substances A and B.
  • the substance A by way of example shall have a main maximum at ⁇ A1 and a secondary maximum at ⁇ A2 .
  • the substance B in the shown spectral region shall have merely a single maximum at a wavelength ⁇ B1 , which in spectral terms shall only be slightly distanced from the maximum ⁇ A1 of the component A. In the area of the wavelengths ⁇ A1 and ⁇ B1 the two substances A and B thus have a strongly overlapping spectrum.
  • a spectral separation i.e. a determination of the single components A, B in a luminescence feature consisting of several different substances, will be effected.
  • the reading devices with higher resolution are provided, and if for users in areas with a lower security category only the reading devices with lower resolution are provided, then merely in those areas of use with a high security category the differentiation between the single substances A and B with strongly overlapping spectrum can be made, while such a differentiation is not possible with the lower resolution according to the measuring curve 16.
  • the different reading devices 1 for carrying out the simple or complex mode shall not only measure with different spectral resolution depending on the security category, but additionally or alternatively also in other spectral regions, with the special example in Fig. 5 there can be provided, that only a reading device 1 with high security category can measure in a wavelength range d ⁇ H, which can capture the main maximum ⁇ A1 , ⁇ B1 as well as the secondary maximum ⁇ A2 which is spectrally spaced-apart thereto.
  • the security feature 100 has e.g. among other things Mn:Zn 2 SiO 4 with spectral band at 520 nm and Ce:YPO 4 with spectral band at 380 nm, there can be provided, that only the reading devices 1 of a high security category of the central banks measure in both wavelength ranges of 380 nm and 520 nm, while in the vending machines e.g. only reading devices of a low security category are used, which measure in a range of 450 to 550 nm.
  • a multistage checking is carried out. This can be effected e.g. by evaluating the measuring in the simplified mode with lower resolution in a first stage and, in a subsequent stage, evaluating the measuring in the complex mode with higher resolution.
  • a first stage for example, only the envelope 16 of the overlapping spectrum can be determined with low resolution (according to a measuring in the simplified mode), so as to carry out first evaluations.
  • first evaluations e.g. a luminescence feature 100 consisting of several substances A, B with overlapping spectral bands
  • in a first stage only the general existence of luminescent substances will be determined, such as e.g. the general existence of a certain group of substances and/ or encodings, which in this stage of checking are still undetermined.
  • the overlap of the response signal is actually proven. I.e. it is determined, whether it is in fact one of the predetermined spectra, which each consists of several single spectra of the individual substances of the luminescence feature, which overlap each other. This can be effected, for example, by at least one spectral band or several spectral bands of the response signal R (e.g. according to a complex representation the single spectral bands of the curve 15 in Fig. 5) being captured in a resolved fashion and checked.
  • the reading device employed in central banks has a spectrometer, that works with a resolution of e.g. 15 nm, and thus can differentiate between the individual spectral bands of the three substances.
  • a broadband detector with a filter, which e.g. integratedly measures within the range of 550 to 640 nm. From the mere quick evaluation of the signal of the broadband detector then can be concluded a forgery, if its signal lies below a predetermined reference value. Then the subsequent stage is no longer necessary, in which in an elaborate way the signal intensities of the spectrometers at the three wavelengths of the individual spectral bands 596 nm, 632 nm and 610 nm and their ratio to each other are determined. Due to this the evaluation can be accelerated.
  • the measurements in the simple or the complex mode can be carried out in several different spectral regions.
  • the excitation for all luminescence wavelength ranges is effected with different excitation wavelengths, but there can also be provided, that the excitation for all luminescence wavelength ranges is effected with the same excitation wavelength.
  • the excitation spectra are encoded, i.e. that the light source 20 does not emit constant signals, but a timely modulated excitation radiation E. With that also the response signals R are modulated in a way, that is characteristically for the individual feature substances or feature substance combinations.
  • a high-resolution measuring in one wavelength range can be combined with a lower resolving measuring in another wavelength range. This can be employed, for example, as to individually determine only certain particularly significant feature substances within a combination of substances forming the luminescence feature 100.
  • the present invention is characterized among other things by the fact, that for different security category areas different detectors are provided.
  • the checking can be effected only in a simple mode, e.g. only the envelope of the response signal R is checked, while in the high-security area with a complex mode there can be ascertained e.g. also individual spectral bands P of the response signal R which are not recognizable when measuring the envelope.
  • optical properties of the feature substance can be checked, such as e.g. the envelope of the luminescence signal, whereas in high-security areas, i.e. e.g. in central banks, also other optical properties and/or other properties, such as e.g. magnetic properties, of the security feature 100 are checked.
  • the reading device 1 with a higher security category can carry out this measurement of magnetism, or with a higher accuracy than the reading device of a lower security category.
  • the measuring can be effected in different ways, not only by measuring with different accuracies, such as with different spectral resolution, or in different spectral regions. Depending on the security category, also a measuring can be effected in different areas of the bank note surface.
EP04020881A 2004-09-02 2004-09-02 Wertdokument mit Lumineszenzeigenschaften Withdrawn EP1632908A1 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EP04020881A EP1632908A1 (de) 2004-09-02 2004-09-02 Wertdokument mit Lumineszenzeigenschaften
CN2005800369566A CN101076835B (zh) 2004-09-02 2005-09-01 具有发光特性的有价文件
RU2007111994/09A RU2388054C9 (ru) 2004-09-02 2005-09-01 Ценный документ с люминесцентными свойствами
EP05784193.4A EP1805727B1 (de) 2004-09-02 2005-09-01 Lumineszierendes sicherheitsmerkmal und verfahren zur herstellung des lumineszierenden sicherheitsmerkmals
US11/660,809 US20080116272A1 (en) 2004-09-02 2005-09-01 Value Document with Luminescent Properties
KR1020077007220A KR101280751B1 (ko) 2004-09-02 2005-09-01 발광 특성을 갖는 가치 증서
ES05784193.4T ES2627416T3 (es) 2004-09-02 2005-09-01 Característica de seguridad luminiscente y procedimiento para fabricar la característica de seguridad luminiscente
PCT/EP2005/009435 WO2006024530A1 (en) 2004-09-02 2005-09-01 Value document with luminescent properties
AU2005279291A AU2005279291B2 (en) 2004-09-02 2005-09-01 Value document with luminescent properties

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EP04020881A EP1632908A1 (de) 2004-09-02 2004-09-02 Wertdokument mit Lumineszenzeigenschaften

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EP2350525A1 (de) * 2008-10-23 2011-08-03 Intematix Corporation Auf phosphor basierendes authentifizierungssystem
CN102998321A (zh) * 2012-05-11 2013-03-27 深圳市树德堂文化发展有限公司 防伪标的物及其制备方法、检测方法
EP2475740B1 (de) 2009-09-11 2015-04-15 G.I.P.C. Holdings Ltd. Gemenge, lumineszierende zusammensetzung, herstellungsverfahren und verwendung
EP2569393B1 (de) 2010-05-10 2017-02-22 Swiss Authentication Research and Development AG Kombination von lumineszenzstoffen
DE102016011180A1 (de) 2016-09-14 2018-03-15 Giesecke+Devrient Currency Technology Gmbh Wertdokument mit Sicherheitsmarkierung und Verfahren zur Identifikation der Sicherheitsmarkierung

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Publication number Priority date Publication date Assignee Title
EP2350525A1 (de) * 2008-10-23 2011-08-03 Intematix Corporation Auf phosphor basierendes authentifizierungssystem
EP2350525A4 (de) * 2008-10-23 2012-08-29 Intematix Corp Auf phosphor basierendes authentifizierungssystem
EP2475740B1 (de) 2009-09-11 2015-04-15 G.I.P.C. Holdings Ltd. Gemenge, lumineszierende zusammensetzung, herstellungsverfahren und verwendung
EP2569393B1 (de) 2010-05-10 2017-02-22 Swiss Authentication Research and Development AG Kombination von lumineszenzstoffen
CN102998321A (zh) * 2012-05-11 2013-03-27 深圳市树德堂文化发展有限公司 防伪标的物及其制备方法、检测方法
DE102016011180A1 (de) 2016-09-14 2018-03-15 Giesecke+Devrient Currency Technology Gmbh Wertdokument mit Sicherheitsmarkierung und Verfahren zur Identifikation der Sicherheitsmarkierung
WO2018050283A1 (de) 2016-09-14 2018-03-22 Giesecke+Devrient Currency Technology Gmbh Wertdokument mit sicherheitsmarkierung und verfahren zur identifikation der sicherheitsmarkierung
US10766294B2 (en) 2016-09-14 2020-09-08 Giesecke+Devrient Currency Technology Gmbh Value document having security marking and method for identifying the security marking

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