EP1623172A1 - Verfahren und system zur herstellung von druckluftgas durch kryogene destillation von luft - Google Patents
Verfahren und system zur herstellung von druckluftgas durch kryogene destillation von luftInfo
- Publication number
- EP1623172A1 EP1623172A1 EP04742833A EP04742833A EP1623172A1 EP 1623172 A1 EP1623172 A1 EP 1623172A1 EP 04742833 A EP04742833 A EP 04742833A EP 04742833 A EP04742833 A EP 04742833A EP 1623172 A1 EP1623172 A1 EP 1623172A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- air
- turbine
- column
- pressure
- booster
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000004821 distillation Methods 0.000 title claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 title description 5
- 239000007788 liquid Substances 0.000 claims abstract description 25
- 238000000926 separation method Methods 0.000 claims abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
- 229910052757 nitrogen Inorganic materials 0.000 claims description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 11
- 239000001301 oxygen Substances 0.000 claims description 11
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- 239000007789 gas Substances 0.000 claims description 8
- 238000009834 vaporization Methods 0.000 claims description 7
- 230000008016 vaporization Effects 0.000 claims description 7
- 238000009434 installation Methods 0.000 claims description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/04054—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04163—Hot end purification of the feed air
- F25J3/04169—Hot end purification of the feed air by adsorption of the impurities
- F25J3/04175—Hot end purification of the feed air by adsorption of the impurities at a pressure of substantially more than the highest pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04303—Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04309—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2240/00—Processes or apparatus involving steps for expanding of process streams
- F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
- F25J2240/42—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval the fluid being air
Definitions
- the present invention relates to a method and an installation for producing gas from pressurized air by cryogenic distillation of air.
- Some processes such as those described in EP-A-0 504 029, produce oxygen under high pressure (> 15 bar) using a single compressor to compress the air at a pressure well above the pressure of the medium pressure column. These processes are adapted to a context in which the investment takes precedence because they suffer from a very important energy consumption when no production of liquid is required.
- Temperatures are considered to be close if they differ at most 10 ° C, preferably at most 5 ° C.
- the exchange line is the main heat exchanger where the gases produced by the column system are heated and where the air for distillation is cooled.
- An object of the invention is to propose an alternative for producing process diagrams making it possible to improve the energy performances by type 1 processes while keeping a lower need for exchange volume than cold compression type 2 schemes as described below.
- a process for separating air by cryogenic distillation in a column system comprising a double column or a triple column, the column operating at the highest pressure operating at a so-called average pressure.
- pressure in which: a) all air is heated to a high pressure at least 5 to 10 bar above the medium pressure.
- a portion of the air comprising between 10% and 50% of the air flow under high pressure, is withdrawn from an exchange line, at a temperature close to the (pseudo) vaporization temperature of the liquid, su ⁇ ressée from at least the high pressure by means of a cold su ⁇ resseur, then is returned in the exchange line, and at least a portion liquefies the cold end, then is sent in at least one column of the system of columns after expansion, c) another fraction of the air at least the high pressure, possibly constituting the rest of the air at high pressure, is expanded in a Claude turbine and then sent into the medium pressure column.
- the cold su ⁇ resseur is coupled to a drive device among: i) a turbine (ii) an electric motor; (iii) a combination of an expansion turbine and an electric motor.
- At least a portion of the high pressure air is overpressed before entering the main exchange line in a hot booster and then cools in the exchange line. all the air to be distilled is overpressed at a pressure higher than the high pressure in the hot booster.
- a part of the air coming from the hot booster is sent to the Claude turbine at the outlet pressure of the hot booster.
- a part of the air coming from the hot booster cools in the exchange line, is expanded, liquefied and sent to at least one column of the column system.
- a nitrogen-enriched gas flow from a column of the column system is partially heated in the exchange line, is expanded in the expansion turbine constituting the (or part of) the entrainment device and is heated in the exchange line.
- An air flow is expanded in the expansion turbine constituting the (or part of) the drive device and the expanded air is sent to a column of the column system, in particular to the low pressure column.
- the liquid from the columns which vaporizes is enriched in oxygen with respect to air.
- the suction temperature of the cold booster is close to, preferably substantially equal to that of vaporization of the liquid withdrawn from the columns and introduced pressurized into the exchange line.
- the suction temperature of the Claude turbine is lower than the suction temperature of the cold booster.
- the suction temperature of the turbine constituting the or part of the drive device is greater than the suction temperature of the cold booster.
- an air separation installation by cryogenic distillation comprising: a) a heat exchange line b) a double or triple air separation column whose column operating at the highest pressure operates at a medium pressure c) a Claude turbine d) a hot booster coupled to the turbine Claude e) a cold booster f) a cold su ⁇ resseur drive device consisting of a turbine, an electric motor or a combination of the two, g) means for sending all the compressed air for distillation to the hot booster, means for sending the pressurized air to the heat exchange line; h) means for withdrawing a first part of the air at an intermediate level of the exchange line, preferably constituting
- the turbine constituting the drive device or forming part thereof may be an air expansion turbine, in particular an insufflation turbine, or a nitrogen expansion turbine.
- Figures 1 to 4 each represent an air separation apparatus according to the invention.
- air is compressed to a pressure of about 15 bar in a compressor (not shown) and then purified to remove impurities (not shown).
- the purified air is supercharged at a pressure of about 18 bar in a booster 5.
- the supercharged air cools by heat exchange with a refrigerant such as water and is sent to the hot end of the exchange line 9. All air cools down to an intermediate temperature of the exchange line and then air is divided in two.
- a first portion of the air 11 comprising between 10% and 50% of the air flow under high pressure is sent to a su ⁇ resseur 23 aspiring at a cryogenic temperature.
- the supercharged air is then sent to the exchange line, without being cooled at the outlet of the su ⁇ resseur, at a pressure of about 31 bar, continues cooling and liquefies in particular by heat exchange with a flow of liquid oxygen pumped 25 which pseudo vaporizes.
- the remainder of the air 13 comprising between 50 and 90% of the high-pressure air cools to a temperature lower than the suction temperature of the booster 23 and is expanded in a Claude turbine 17 and sent to the middle column pressure, thus constituting the only flow of gaseous air sent to the double column.
- a nitrogen-enriched gas flow 31 from the medium pressure column 100 heats up in the exchange line, leaves at a temperature higher than the inlet temperature of the Claude 17 turbine and is sent to an expansion turbine 119.
- Nitrogen expanded substantially at low pressure and substantially at the temperature of the cold end of the exchange line is reintroduced into the exchange line where it heats up or joins a nitrogen-enriched gas 33 withdrawn from the lower column. pressure and the nitrogen flow formed 29 is heated through completely the exchange line.
- the nitrogen turbine 119 is coupled to the cold booster 23 while the Claude turbine 17 is coupled to the hot booster 5.
- the expansion turbine 119 is not an essential element of the invention and the drive of the cold booster 23 can be replaced by an electric motor. Similarly, the expansion turbine 119 may be replaced by an air expansion turbine.
- the column system of FIG. 1 and all the figures is a conventional air separation apparatus consisting of a medium pressure column 100 thermally connected to a low pressure column 200 by means of a bottom reboiler of the low pressure column. heated by a medium pressure nitrogen flow. Other types of reboiling can obviously be considered.
- the medium pressure column 100 operates at a pressure of 5.5 bar but can operate at a higher pressure.
- the gaseous air 35 from the turbine 17 is sent to the bottom of the medium pressure column 100.
- the liquefied air 37 is expanded in the valve 39, divided in two, a part being sent to the medium pressure column 100 and the rest to the low pressure column 200.
- Rich liquid 51, lower lean liquid 53 and upper lean liquid 55 are sent from the medium pressure column 100 to the low pressure column 200 after expansion steps in the valves and subcooling.
- Oxygen enriched fluids 57 and nitrogen enriched 59 are optionally withdrawn as final products of the double column.
- Oxygen-enriched liquid is pressurized by the pump 500 and sent as a pressurized liquid to the exchange line 9.
- other liquids, pressurized or otherwise such as other liquid oxygen different pressure, liquid nitrogen and liquid argon, can vaporize in the exchange line 9.
- Residual nitrogen 27 is withdrawn at the top of the low pressure column and is heated in the exchange line 9, after being used to subcool the reflux liquids 51, 53, 55.
- the column may optionally produce argon by treating a flow rate withdrawn in low pressure column 200.
- a portion 41 of the high pressure air unpressurized in su ⁇ ressor 23 can be liquefied in the exchange line by heat exchange with the vaporizing oxygen, is expanded in a valve 43 to the medium pressure and mixes with the liquefied air 37. 11 will be understood that if the air is at supercritical pressure output of su ⁇ resseur 5, the liquefaction will take place after relaxation in the valves 39, 43.
- FIG. 2 differs from FIG. 1 in that there is no medium gas pressure nitrogen withdrawal at the head of the medium pressure column 100.
- the medium pressure nitrogen turbine 119 is replaced by an insufflation turbine 119A. Part 61 of the air coming from the Claude turbine 17 is sent to the blowing turbine and the air expanded in the turbine 119A is sent to the low pressure column 200.
- the hot su ⁇ resseur 5 is always coupled to the turbine Claude but the cold booster 23 is coupled to the insufflation turbine.
- the liquid air relief valves are also different in Figure 2 because the liquid flow rates are only relaxed after division to form the flow rates for the medium pressure and low pressure columns.
- This kind of process is more suitable for producing low purity oxygen.
- Figure 3 is similar to Figures 1 and 2 but does not include any turbine apart from the Claude turbine.
- the cold booster 23 is coupled to a motor 61 and the hot booster 5 is coupled to the turbine Claude.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL04742833T PL1623172T3 (pl) | 2003-05-05 | 2004-04-06 | Sposób i instalacja do wytwarzania gazu ze sprężonego powietrza z wykorzystaniem destylacji kriogenicznej powietrza |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0350142A FR2854683B1 (fr) | 2003-05-05 | 2003-05-05 | Procede et installation de production de gaz de l'air sous pression par distillation cryogenique d'air |
PCT/FR2004/050146 WO2004099691A1 (fr) | 2003-05-05 | 2004-04-06 | Procede et installation de production de gaz de l'air sous pression par distillation cryogenique d'air |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1623172A1 true EP1623172A1 (de) | 2006-02-08 |
EP1623172B1 EP1623172B1 (de) | 2015-12-09 |
Family
ID=33306451
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04742833.9A Expired - Lifetime EP1623172B1 (de) | 2003-05-05 | 2004-04-06 | Verfahren und vorrichtung zur erzeugung eines durch tieftemperaturzerlegung von luft gewonnenen druckgases |
Country Status (8)
Country | Link |
---|---|
US (1) | US9945606B2 (de) |
EP (1) | EP1623172B1 (de) |
JP (1) | JP4728219B2 (de) |
CN (1) | CN1784579B (de) |
FR (1) | FR2854683B1 (de) |
HU (1) | HUE026528T2 (de) |
PL (1) | PL1623172T3 (de) |
WO (1) | WO2004099691A1 (de) |
Families Citing this family (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2865024B3 (fr) * | 2004-01-12 | 2006-05-05 | Air Liquide | Procede et installation de separation d'air par distillation cryogenique |
US7487648B2 (en) * | 2006-03-10 | 2009-02-10 | Praxair Technology, Inc. | Cryogenic air separation method with temperature controlled condensed feed air |
FR2913759B1 (fr) * | 2007-03-13 | 2013-08-16 | Air Liquide | Procede et appareil de production de gaz de l'air sous forme gazeuse et liquide a haute flexibilite par distillation cryogenique. |
FR2913760B1 (fr) * | 2007-03-13 | 2013-08-16 | Air Liquide | Procede et appareil de production de gaz de l'air sous forme gazeuse et liquide a haute flexibilite par distillation cryogenique |
DE102007031765A1 (de) * | 2007-07-07 | 2009-01-08 | Linde Ag | Verfahren zur Tieftemperaturzerlegung von Luft |
BRPI0721930A2 (pt) * | 2007-08-10 | 2014-03-18 | Air Liquide | Processo e aparelho para a separação de ar por destilação criogênica |
EP2176610B1 (de) * | 2007-08-10 | 2019-04-24 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zur trennung von luft durch kryogene destillation |
FR2953915B1 (fr) * | 2009-12-11 | 2011-12-02 | Air Liquide | Procede et appareil de separation d'air par distillation cryogenique |
EP2369281A1 (de) * | 2010-03-09 | 2011-09-28 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Tieftemperaturzerlegung von Luft |
DE102010055448A1 (de) * | 2010-12-21 | 2012-06-21 | Linde Ag | Verfahren und Vorrichtung zur Tieftemperaturzerlegung von Luft |
FR2973485B1 (fr) * | 2011-03-29 | 2017-11-24 | L'air Liquide Sa Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de separation d'air par distillation cryogenique |
CN102353754B (zh) * | 2011-09-02 | 2014-04-09 | 杭州杭氧股份有限公司 | 一种以制冷机为冷源的低温精馏性能测试系统 |
FR2983287B1 (fr) * | 2011-11-25 | 2018-03-02 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et installation de separation d'air par distillation cryogenique |
FR2985305B1 (fr) * | 2012-01-03 | 2017-12-22 | L'air Liquide Sa Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et appareil de production de gaz de l'air sous pression utilisant un surpresseur cryogenique |
DE102012017488A1 (de) | 2012-09-04 | 2014-03-06 | Linde Aktiengesellschaft | Verfahren zur Erstellung einer Luftzerlegungsanlage, Luftzerlegungsanlage und zugehöriges Betriebsverfahren |
WO2014154339A2 (de) | 2013-03-26 | 2014-10-02 | Linde Aktiengesellschaft | Verfahren zur luftzerlegung und luftzerlegungsanlage |
EP2784420A1 (de) * | 2013-03-26 | 2014-10-01 | Linde Aktiengesellschaft | Verfahren zur Luftzerlegung und Luftzerlegungsanlage |
FR3010778B1 (fr) * | 2013-09-17 | 2019-05-24 | Air Liquide | Procede et appareil de production d'oxygene gazeux par distillation cryogenique de l'air |
EP2963370B1 (de) * | 2014-07-05 | 2018-06-13 | Linde Aktiengesellschaft | Verfahren und vorrichtung zur tieftemperaturzerlegung von luft |
WO2018219501A1 (de) | 2017-05-31 | 2018-12-06 | Linde Aktiengesellschaft | Verfahren zur gewinnung eines oder mehrerer luftprodukte und luftzerlegungsanlage |
FR3072451B1 (fr) * | 2017-10-13 | 2022-01-21 | Air Liquide | Procede et appareil de separation d'air par distillation cryogenique |
WO2020083520A1 (de) | 2018-10-26 | 2020-04-30 | Linde Aktiengesellschaft | Verfahren zur gewinnung eines oder mehrerer luftprodukte und luftzerlegungsanlage |
CN109630269B (zh) * | 2019-01-15 | 2021-12-31 | 中国石油大学(华东) | 天然气-蒸汽联合循环洁净发电工艺 |
WO2023051946A1 (de) | 2021-09-29 | 2023-04-06 | Linde Gmbh | Verfahren zur tieftemperaturzerlegung von luft und luftzerlegungsanlage |
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US5475980A (en) * | 1993-12-30 | 1995-12-19 | L'air Liquide, Societe Anonyme Pour L'etude L'exploitation Des Procedes Georges Claude | Process and installation for production of high pressure gaseous fluid |
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DE19951521A1 (de) * | 1999-10-26 | 2001-05-03 | Linde Ag | Verfahren und Vorrichtung zur Gewinnung eines Druckprodukts durch Tieftemperaturzerlegung von Luft |
US6253576B1 (en) * | 1999-11-09 | 2001-07-03 | Air Products And Chemicals, Inc. | Process for the production of intermediate pressure oxygen |
US6962062B2 (en) * | 2003-12-10 | 2005-11-08 | L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Proédés Georges Claude | Process and apparatus for the separation of air by cryogenic distillation |
-
2003
- 2003-05-05 FR FR0350142A patent/FR2854683B1/fr not_active Expired - Fee Related
-
2004
- 2004-04-06 EP EP04742833.9A patent/EP1623172B1/de not_active Expired - Lifetime
- 2004-04-06 PL PL04742833T patent/PL1623172T3/pl unknown
- 2004-04-06 WO PCT/FR2004/050146 patent/WO2004099691A1/fr active Application Filing
- 2004-04-06 JP JP2006505869A patent/JP4728219B2/ja not_active Expired - Fee Related
- 2004-04-06 CN CN2004800120826A patent/CN1784579B/zh not_active Expired - Lifetime
- 2004-04-06 US US10/555,745 patent/US9945606B2/en active Active
- 2004-04-06 HU HUE04742833A patent/HUE026528T2/en unknown
Non-Patent Citations (1)
Title |
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See references of WO2004099691A1 * |
Also Published As
Publication number | Publication date |
---|---|
US20060277944A1 (en) | 2006-12-14 |
PL1623172T3 (pl) | 2016-06-30 |
CN1784579A (zh) | 2006-06-07 |
FR2854683B1 (fr) | 2006-09-29 |
HUE026528T2 (en) | 2016-06-28 |
CN1784579B (zh) | 2010-10-06 |
JP2006525487A (ja) | 2006-11-09 |
FR2854683A1 (fr) | 2004-11-12 |
WO2004099691A1 (fr) | 2004-11-18 |
EP1623172B1 (de) | 2015-12-09 |
US9945606B2 (en) | 2018-04-17 |
JP4728219B2 (ja) | 2011-07-20 |
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