EP1560955B1 - Fibres bicomposees comprenant un polymere thermoplastique entourant un noyau amylace - Google Patents

Fibres bicomposees comprenant un polymere thermoplastique entourant un noyau amylace Download PDF

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EP1560955B1
EP1560955B1 EP02789689A EP02789689A EP1560955B1 EP 1560955 B1 EP1560955 B1 EP 1560955B1 EP 02789689 A EP02789689 A EP 02789689A EP 02789689 A EP02789689 A EP 02789689A EP 1560955 B1 EP1560955 B1 EP 1560955B1
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Prior art keywords
starch
component
fibers
fiber
thermoplastic polymer
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German (de)
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EP1560955A1 (fr
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Eric Bryan Bond
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Procter and Gamble Co
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Procter and Gamble Co
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    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4266—Natural fibres not provided for in group D04H1/425
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326—Condensation or reaction polymers
    • D04H1/435—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5416—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sea-island
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/544—Olefin series
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/545—Polyvinyl alcohol
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/542—Adhesive fibres
    • D04H1/55—Polyesters
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541—Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5418—Mixed fibres, e.g. at least two chemically different fibres or fibre blends

Definitions

  • the present invention relates to multicomponent fibers comprising a thermoplastic polymer surrounding and protecting a starch rich core.
  • the fibers can be used to make nonwoven webs and disposable articles.
  • Starch fibers are much more difficult to produce than films, blow-molded articles, and injection-molded articles containing starch. This is because of the short processing time required for starch processing due to rapid crystallization or other structure formation characteristics of starch.. The local strain rate and shear rate is much greater in fiber production than other processes. Additionally, a homogeneous composition is required for fiber spinning. For spinning fine fibers, small defects, slight inconsistencies, or non-homogeneity in the melt are not acceptable for a commercially viable process.
  • the selection of materials, configuration of the fibers, and processing conditions are critical.
  • the end-use properties are not suitable for many commercial applications. This is because the starch fibers typically have low tensile strength, are sticky, and are not well suited for fiber-to-fiber bonding in nonwoven webs or substrates.
  • thermoplastic polymers in combination with starch.
  • the melting temperature of the thermoplastic polymer should be high enough for end-use stability, to prevent melting or undue structural deformation during use, but low enough so that the starch/thermoplastic fibers can are processable without burning the starch.
  • the present invention can provide bicomponent fibers that are cost-effective, easily processable, and highly functional.
  • the fibers are made of a starch rich component which is completely surrounded by a thermoplastic polymer component.
  • the starch and polymer bicomponent fiber is suitable for use in commercially available equipment for making bicomponent fibers.
  • the present invention provides such disposable, nonwoven articles made from starch-containing bicomponent fibers.
  • the present invention is directed to bicomponent fibers.
  • the bicomponent fibers will comprise one component comprising thermoplastic starch which is completely surrounded by and protected by another component comprising a thermoplastic polymer.
  • the thermoplastic polymer component has a melting temperature that is higher than that of the thermoplastic starch component.
  • the configuration of the bicomponent fibers can be sheath-core including, for example, sheath-core with a single core surrounded by the sheath, or a plurality of two or more cores surrounded by a sheath, referred to herein as an islands-in-the-sea configuration.
  • thermoplastic polymer protects the starch component. This is particularly relevant during end-use where the starch component alone may not tolerate the environmental conditions without significant loss in fiber properties.
  • the protection may be mechanical, thermodynamic, electrical, solvent based, or combinations thereof.
  • the protection of the starch component also makes the fibers more functional as the fibers are more temperature stable, more resistant to solvents, and able to be thermally bonded.
  • the present invention is also directed to nonwoven webs and disposable articles comprising the bicomponent fibers.
  • the nonwoven webs may also contain other synthetic or natural fibers blended with the fibers of the present invention.
  • the nonwoven webs may also contain other synthetic or natural fibers blended with the fibers of the present invention.
  • Optional fibers include, but are not limited to, fibers comprising cellulosic pulp, regenerated cellulose, polypropylene, polyethylene terephthalate, and nylon, their various polymers and combinations thereof
  • compositions, products, and processes described herein may comprise, consist essentially of, or consist of any or all of the required and/or optional components, ingredients, compositions, or steps described herein.
  • the specification contains a detailed description of (1) materials of the present invention, (2) configuration of the bicomponent fibers, (3) material properties of the bicomponent fibers, (4) processes, and (5) articles.
  • Component A Thermoplastic Polymers
  • Suitable melting temperatures of the thermoplastic polymers, as well as the thermoplastic polymer component are from about 60°C to about 300°C, preferably from about 80°C to about 250°C and preferably from 100°C-215°C.
  • Thermoplastic polymers having a melting temperature (Tm) above 250°C may be used if plasticizers or diluents or other polymers are used to lower the observed melting temperature, such that the melting temperature of the composition of the thermoplastic polymer-containing component is within the above ranges. It may be desired to use a thermoplastic polymer having a glass transition (Tg) temperature of less than 0°C.
  • Tg glass transition
  • the thermoplastic polymer component has rheological characteristics suitable for melt spinning.
  • the molecular weight of the polymer should be sufficiently high to enable entanglement between polymer molecules and yet low enough to be melt spinnable.
  • suitable thermoplastic polymers can have molecular weights about 1,000,000 g/mol or below, preferably from about 5,000 g/mol to about 800,000 g/mol, more preferable from about 10,000 g/mol to about 700,000 g/mol and most preferably from about 20,000 g/mol to about 500,000 g/mol
  • thermoplastic polymers desirably should be able to solidify fairly rapidly, preferably under extensional flow, as typically encountered in known processes as staple fibers (spin draw process) or spunbond/meltblown continuous filament process, and desirably can form a thermally stable fiber structure.
  • "Thermally stable fiber structure” as used herein is defined as not exhibiting significant melting or dimensional change at 25°C and ambient atmospheric pressure over a period of 24 hours at 50% relative humidity when diameter is measured and the fibers are placed in the environment within five minutes of their formation. Dimensional changes in measured fiber diameter greater than 25% difference, using as a basis the corresponding, original fiber diameter measurement, would be considered significant. If the original fiber is not round, the shortest diameter should be used for the calculation. The shortest diameter should also be used for the 24 hour measurement also.
  • Suitable thermoplastic polymers include polyolefins such as polyethylene or copolymers thereof, including low, high, linear low, or ultra low density polyethylenes, polypropylene or copolymers thereof, including atactic polypropylene; polybutylene or copolymers thereof; polyamides or copolymers thereof, such as Nylon 6, Nylon 11, Nylon 12, Nylon 46, Nylon 66; polyesters or copolymers thereof, such as polyethylene terephthalate; olefin carboxylic acid copolymers such as ethylene/acrylic acid copolymer, ethylene/maleic acid copolymer, ethylene/methacrylic acid copolymer, ethylene/vinyl acetate copolymers or combinations thereof; polyacrylates, polymethacrylates, and their copolymers such as poly(methyl methacrylates).
  • polyolefins such as polyethylene or copolymers thereof, including low, high, linear low, or ultra low density polyethylenes, polypropylene or copo
  • thermoplastic polymers include polypropylene, polyethylene, polyamides, polyvinyl alcohol, ethylene acrylic acid, polyolefin carboxylic acid copolymers, polyesters, and combinations thereof.
  • Biodegradable thermoplastic polymers are also suitable for use herein.
  • Biodegradable materials are susceptible to being assimilated by microorganisms such as molds, fungi, and bacteria when the biodegradable material is buried in the ground or otherwise comes in contact with the microorganisms including contact under environmental conditions conducive to the growth of the microorganisms.
  • Suitable biodegradable polymers also include those biodegradable materials which are environmentally degradable using aerobic or anaerobic digestion procedures, or by virtue of being exposed to environmental elements such as sunlight, rain, moisture, wind, temperature, and the like.
  • the biodegradable thermoplastic polymers can be used individually or as a combination of biodegradable or non-biodegradable polymers.
  • Biodegradable polymers include polyesters containing aliphatic components.
  • the polyesters are ester polycondensates containing aliphatic constituents and poly(hydroxycarboxylic) acid.
  • the ester polycondensates include diacids/diol aliphatic polyesters such as polybutylene succinate, polybutylene succinate co-adipate, aliphatic/aromatic polyesters such as terpolymers made of butylenes diol, adipic acid and terephthalic acid.
  • the poly(hydroxycarboxylic) acids include lactic acid based homopolymers and copolymers, polyhydroxybutyrate (PHB), or other polyhydroxyalkanoate homopolymers and copolymers.
  • Such polyhydroxyalkanoates include copolymers of PHB with higher chain length monomers, such as C6 - C12, and higher, polyhydroxyalkanaotes, such as disclosed in US Patent RE 36,548 and US Patent 5,990,271
  • An example of a suitable commercially available poly lactic acid is NATUREWORKS from Cargill Dow and LACEA from Mitsui Chemical.
  • An example of a suitable commercially available diacid/diol aliphatic polyester is the polybutylene succinate/adipate copolymers sold as BIONOLLE 1000 and BIONOLLE 3000 from the Showa High Polymer Company, Ltd. Located in Tokyo, Japan.
  • An example of a suitable commercially available aliphatic/aromatic copolyester is the poly(tetramethylene adipate-co-terephthalate) sold as EASTAR BIO Copolyester from Eastman Chemical or ECOFLEX from BASF.
  • thermoplastic polymer component can contain a single polymer species or a blend of two or more non-starch thermoplastic polymers. Additionally, other materials, including but not limited to thermoplastic starch, can be present in the thermoplastic polymer component. Typically, non-starch, thermoplastic polymers are present in an amount of from about 51% to 100%, preferably from about 60% to about 95%, more preferably from about 70% to about 90%, by total weight of the thermoplastic polymer component.
  • thermoplastic polymer component surrounds and can protect the starch component from ambient conditions which can include, but are not limited to, mechanical, thermodynamic, electrical, or solvent conditions, or combinations thereof.
  • the thermoplastic polymer component can also makes the fibers more functional as the fibers are more temperature stable, more resistant to solvents, and able to be thermally bonded.
  • Component B Thermoplastic Starch
  • the present invention relates to the use of starch, a low cost naturally occurring biopolymer.
  • the starch used in the present invention is thermoplastic, destructured starch.
  • the term "destructurized starch” is used to mean starch that is no longer in its naturally occurring granular structure.
  • the term “thermoplastic starch” or “TPS” is used to mean starch with a plasticizer for improving its thermoplastic flow properties so that it may be able to be spun into fibers.
  • Natural starch does not melt or flow like conventional thermoplastic polymers. Since natural starch generally has a granular structure, it desirably should be "destructurized”, or “destructured”, before it can be melt processed and spun like a thermoplastic material.
  • the granular structure of starch is characterized by granules comprising a structure of discrete amylopectin and amylose regions in a starch granule.
  • This granular structure is broken down during destructurization, which can be followed by a volume expansion of the starch component in he presence of the solvent or plasticizer.
  • Starch undergoing destructuring in the presence of the solvent or plasticizer also typically has an increase in viscosity versus non-destructured starch with the solvent or plasticizer.
  • the resulting destructurized starch can be in gelatinized form or, upon drying and or annealing, in crystalline form. However once broken down the natural granular structure of starch will not, in general, return.
  • the starch be fully destructured such that no lumps impacting the fiber spinning process are present.
  • the destructuring agent used to destructure the starch may remain with the starch during further processing, or may be transient, in that it is removed such that it does not remain in the fiber spun with the starch.
  • Starch can be destructured in a variety of different ways.
  • the starch can be destructurized with a solvent.
  • starch can be destructurized by subjecting a mixture of the starch and solvent to heat, which can be under pressurized conditions and shear, to gelatinize the starch, leading to destructurization.
  • Solvents can also act as plasticizers and may be desirably retained in the composition to perform as a plasticizer during later processing.
  • plasticizing agents that can act as solvents to destructure starch are described herein. These include the low molecular weight or monomeric plasticizers, such as but not limited to hydroxyl-containing plasticizers, including but not limited to the polyols, e.g. polyols such as mannitol, sorbitol, and glycerin. Water also can act as a solvent and plasticizer for starch.
  • plasticizer For starch to flow and be melt spinnable like a conventional thermoplastic polymer, it should have plasticizer present. If the destructuring agent is removed, it is the nature of the starch to in general remain destructured, however a plasticizer should be added to or otherwise included in the starch component to impart thermoplastic properties to the starch component in order to facilitate fiber spinning. Thus, the plasticizer present during spinning may be the same one used to destructure the starch. Alternately, especially when the destructuring agent is transient as described above (for example water), a separate or additional plasticizer may be added to the starch. Such additional plasticizer can be added prior to, during, or after the starch is destructured, as long as it remains in the starch for the fiber spinning step.
  • Suitable naturally occurring starches can include, but are not limited to, corn starch (including, for example, waxy maize starch), potato starch, sweet potato starch, wheat starch, sago palm starch, tapioca starch, rice starch, soybean starch, arrow root starch, bracken starch, lotus starch, cassava starch, high amylose corn starch, and commercial amylose powder. Blends of starch may also be used. Though all starches are useful herein, the present invention is most commonly practiced with natural starches derived from agricultural sources, which offer the advantages of being abundant in supply, easily replenishable and inexpensive in price.
  • Naturally occurring starches particularly corn starch (including, for example, waxy maize starch), and wheat starch, are starch polymers of choice due to their economy and availability. Modified starch may also be used. Modified starch is defined as non-substituted, or substituted, starch that has had its native molecular weight characteristics changed (i.e. the molecular weight is changed but no other changes are necessarily made to the starch). Molecular weight can be modified, preferably reduced, by any technique numerous of which are well known in the art.
  • thermomechanical method and the oxidation method offer an additional advantage when carried out in situ .
  • the exact chemical nature of the starch and molecular weight reduction method is not critical as long as the average molecular weight is provided at the desired level or range. Such techniques can also reduce molecular weight distribution.
  • Natural, unmodified starch generally has a very high average molecular weight and a broad molecular weight distribution (e.g. natural corn starch has an average molecular weight of up to about 60,000,000 grams/mole (g/mol)). It is desirable to reduce the molecular weight of the starch for use in the present invention. Molecular weight reduction can be obtained by any technique known in the art, including those discussed above. Ranges of molecular weight for destructured starch or starch blends added to the melt can be from about 3,000 g/mol to about 8,000,000 g/mol, preferably from about 10,000 g/mol to about 5,000,000 g/mol, and more preferably from about 20,000 g/mol to about 3,000,000 g/mol.
  • substituted starch can be used.
  • Chemical modifications of starch to provide substituted starch include, but are not limited to, etherification and esterification.
  • etherification and esterification For example, methyl, ethyl, or propyl (or larger aliphatic groups) can be substituted onto the starch using conventional etherification and esterification techniques as well known in the art.
  • Such substitution can be done when the starch is in natural, granular form or after it has been destructured. It will be appreciated that substitution can reduce the rate of biodegradability of the starch, but can also reduce the time, temperature, shear, and/or pressure conditions for destructurization.
  • the degree of substitution of the chemically substituted starch is typically, but not necessarily, from about 0.01 to about 3.0, and can also be from about 0.01 to about 0.06.
  • the thermoplastic starch comprises from about 51% to about 100%, preferably from about 60% to about 95%, more preferably from about 70% to about 90% by weight of the thermoplastic starch component.
  • the ratio of the starch component to the thermoplastic polymer will determine the percent of thermoplastic starch in the bicomponent fiber component.
  • the weight of starch in the composition includes starch and its naturally occurring bound water content.
  • bound water means the water found naturally occurring in starch and before mixing of starch with other components to make the composition of the present invention.
  • free water means the water that is added in making the composition of the present invention. A person of ordinary skill in the art would recognize that once the components are mixed in a composition, water can no longer be distinguished by its origin. Natural starch typically has a bound water content of about 5% to about 16% by weight of starch.
  • One or more plasticizers can be used in the present invention to destructurize the starch and enable the starch to flow, i.e. create a thermoplastic starch.
  • a plasticizer may be used as a destructuring agent for the starch. That plasticizer may remain in the destructured starch component to function as a plasticizer for the thermoplastic starch, or may be removed and substituted with a different plasticizer in the thermoplastic starch component.
  • the plasticizers may also improve the flexibility of the final products, which is believed to be due to the lowering of the glass transition temperature of the composition.
  • thermoplastic polymer component may be present to lower the polymer's melting temperature, modify flexibility of the final product, or improve overall compatibility with the thermoplastic starch blend. Furthermore, thermoplastic polymers with higher melting temperatures may be used if plasticizers or diluents are present which suppress the melting temperature of the polymer.
  • the plasticizers should be substantially compatible with the polymeric components of the present invention with which they are intermixed.
  • substantially compatible means when heated to a temperature above the softening and/or the melting temperature of the composition, the plasticizer is capable of forming a homogeneous mixture with polymer present in the component in which it is intermixed.
  • One way to ensure substantial compatability is to enzymatically or synthetically graft or react groups onto starch or starch onto a polymer.
  • the plasticizers herein can include monomeric compounds and polymers.
  • the polymeric plasticizers will typically have a molecular weight of about 100,000 g/mol or less.
  • Polymeric plasticizers can include block copolymers and random copolymers, including terpolymers thereof.
  • the plasticizer has a low molecular weight plasticizer, for example a molecular weight of about 20,000 g/mol or less, or about 5,000 g/mol or less, or about 1,000 g/mol or less.
  • the plasticizers may be used alone or more than one plasticizer may be used in any particular component of the present invention.
  • plasticizers are hydroxy-based polymers such as polyvinyl alcohol, ethylene vinyl alcohol, copolymers and blends thereof at various substitution levels.
  • the plasticizer can be, for example, an organic compound having at least one hydroxyl group, including polyols having two or more hydroxyls.
  • useful hydroxyl plasticizers include sugars such as glucose, sucrose, fructose, raffinose, maltodextrose, galactose, xylose, maltose, lactose, mannose erythrose, and pentaerythritol; sugar alcohols such as erythritol, xylitol, malitol, mannitol and sorbitol; polyols such as glycerol (glycerin), ethylene glycol, propylene glycol, dipropylene glycol, butylene glycol, hexane triol, and the like, and polymers thereof; and mixtures thereof.
  • Suitable plasticizers especially include glycerine, mannitol, and sorbitol.
  • hydroxyl polymeric plasticizers such as poloxomers (polyoxyethylene /polyoxypropylene block copolymers) and poloxamines (polyoxyethylene/polyoxypropylene block copolymers of ethylene diamine). These copolymers are available as Pluronic® from BASF Corp., Parsippany, NJ. Suitable poloxamers and poloxamines are available as Synperonic® from ICI Chemicals, Wilmington, DE, or as Tetronic® from BASF Corp., Parsippany, NJ.
  • hydrogen bond forming organic compounds including those which do not have hydroxyl group, including urea and urea derivatives; anhydrides of sugar alcohols such as sorbitan; animal proteins such as gelatin; vegetable proteins such as sunflower protein, soybean proteins, cotton seed proteins; and mixtures thereof.
  • plasticizers are phthalate esters, dimethyl and diethylsuccinate and related esters, glycerol triacetate, glycerol mono and diacetates, glycerol mono, di, and tripropionates, butanoates, stearates, lactic acid esters, citric acid esters, adipic acid esters, stearic acid esters, oleic acid esters, and other father acid esters which are biodegradable.
  • Aliphatic acids such as ethylene acrylic acid, ethylene maleic acid, butadiene acrylic acid, butadiene maleic acid, propylene acrylic acid, propylene maleic acid, and other hydrocarbon based acids.
  • the amount of plasticizer is dependent upon the molecular weight and amount of starch and the affinity of the plasticizer for the starch or thermoplastic polymer. Any amount that effectively plasticizes the starch component can be used.
  • the plasticizer should sufficiently plasticize the starch component so that it can be processed effectively to form fibers.
  • the amount of plasticizer increases with increasing molecular weight of starch.
  • the plasticizer can be present in an amount of from about 2% to about 70%, and can also be from about 5% to about 55%, or from about 10% to about 50% of the component into which it is intermixed.
  • Polymeric incorporated into the starch component that function as plasticizers for the starch shall be counted as part of the plasticizer constituent of that component of the present invention.
  • Plasticizer is optional for the thermoplastic polymer components in the present invention, and zero percent or amounts below 2% are not meant to be excluded.
  • thermoplastic starch component and thermoplastic polymer component may be incorporated into the thermoplastic starch component and thermoplastic polymer component.
  • These optional ingredients may be present in quantities of less than about 50%, preferably from about 0.1% to about 30%, and more preferably from about 0.1 % to about 10% by weight of the component.
  • the optional materials may be used to modify the processability and/or to modify physical properties such as elasticity, tensile strength and modulus of the final product.
  • Other benefits include, but are not limited to, stability including oxidative stability, brightness, color, flexibility, resiliency, workability, processing aids, viscosity modifiers, and odor control.
  • a preferred processing aid is magnesium stearate.
  • Another optional material that may be desired, particularly in the starch component is ethylene acrylic acid, commercially available as Primacore by Dow Chemical Company. Examples of optional ingredients are found in US application serial number 09/853,131 .
  • the fibers of the present invention are, at least, bicomponent fibers.
  • Component as used herein, is defined as a separate part of the fiber that has a spatial relationship to another part of the fiber.
  • the term bicomponent as used herein, is defined as a fiber having at least two separate parts in spatial relationship to one another at the exit from the extrusion equipment.
  • the bicomponent fibers hereof may optionally be multicomponent with three or more components, as long as at least one component is a thermoplastic polymer component, as described above, surrounding at least one thermoplastic, destructured starch component, also described above. Accordingly, the term "bicomponent fiber” is not meant to exclude other multicomponent fibers, unless otherwise expressly indicated.
  • the bicomponent or multicomponent fibers hereof can have more than two separate components, such as, without limitation, tricomponent.
  • the different components of multicomponent fibers are arranged in substantially distinct regions across the cross-section of the fiber and extend continuously along the length of the fiber.
  • Multiconstituent components are defined as meaning the chemical species of matter or the material.
  • Multiconstituent fiber is defined to mean a fiber, or component thereof, containing more than one chemical species or material.
  • the bicomponent fibers of the present invention may be in any of several different configurations as long as the thermoplastic polymer component surrounds the starch component.
  • the bicomponent fibers may be in an islands-in-the-sea configuration (a plurality of starch component cores surrounded by a thermoplastic polymer sheath) or a sheath-core configuration (a single starch component core surrounded by a thermoplastic polymer component sheath) wherein the starch component is completely surrounded by, the thermoplastic polymer.
  • the weight ratio of the thermoplastic starch component to thermoplastic polymer component can be from about 5:95 to about 95:5. In alternate embodiments, the ratio is from about 10:90 to about 65:35 and or from about 15:85 to about 50:50.
  • the bicomponent fibers of the present invention can have several benefits over monocomponent starch and polymer blend fibers. Because the thermoplastic polymer completely surrounds the starch component, the starch rich component is protected during end-use. This enables the bicomponent fiber to be produced having good fiber properties such as elongation-at-break or tensile strength.
  • the thermoplastic polymer component can also provide protection from mechanical, thermodynamic, electrical, and chemical environmental factors or conditions, and combinations thereof.
  • the thermoplastic polymer component also can enable the fibers to be bonded to make nonwoven substrates.
  • this bicomponent configuration generally makes the fiber more temperature stable, particularly when Tm of the thermoplastic polymer component is at least about 100°C, and especially when at least about 125°C.
  • Improved temperature stability facilities the processing of these fibers with various post-fiber formation processes commonly used in the art including, but not limited to, thermal bonding of fibers such as but not limited to formation of thermally bonded fibrous substrates of webs, post-processing techniques such as but not limited to mechanical drawing, and other processes that otherwise may not be suitable for use with monocomponent starch-containing fibers.
  • the temperature that the fiber is stable until depends upon the specific polymer used, the ratio of thermoplastic polymer to starch component, and the specific configuration.
  • the melting temperature of the starch component is lower than the melting temperature of the thermoplastic polymer component.
  • the fibers of the present invention can also have the benefit of being more resistant to polar and/or non-polar solvents compared to monocomponent starch-containing fibers. This enables starch fibers to be used in various environments, such as aqueous environments, where typical starch fibers may not be suitable.
  • the diameter of the fiber of the present invention is typically less than about 200 micrometers (microns), and alternate embodiments can be less than about 100 microns, less than about 50 microns, or less than 30 microns. In one embodiment hereof, the fibers have a diameter of from about 5 microns to about 25 microns. Fiber diameter is controlled factors well known in the fiber spinning art including, for example, spinning speed and mass through-put.
  • the fibers produced in the present invention may be environmentally degradable depending upon the amount of starch that is present, the polymer used, and the specific configuration of the fiber. "Environmentally degradable” is defined as being biodegradable, disintigratable, dispersible, flushable, or compostable or a combination thereof. In the present invention, the fibers, nonwoven webs, and articles may be environmentally degradable.
  • the fibers described herein are typically used to make disposable nonwoven articles.
  • the articles are commonly flushable.
  • flushable refers to materials which are capable of dissolving, dispersing, disintegrating, and/or decomposing in a septic disposal system such as a toilet to provide clearance when flushed down the toilet without clogging the toilet or any other sewage drainage pipe.
  • the fibers and resulting articles may also be aqueous responsive.
  • aqueous responsive means that when placed in water or flushed, an observable and measurable change will result. Typical observations include noting that the article swells, pulls apart, dissolves, or observing a general weakened structure.
  • the bicomponent fibers of the present invention can have low brittleness and have high toughness, for example a toughness of about 2MPa or greater. Toughness is defined as the area under the stress-strain curve.
  • Extensibility or elongation is measured by elongation to break. Extensibility or elongation is defined as being capable of elongating under an applied force, but not necessarily recovering. Elongation to break is measured as the distance the fiber can be stretched until failure. It has also been found that the fibers of the present invention can be highly extensible.
  • the elongation to break of single fibers are tested according to ASTM standard D3822 except a strain rate of 200 %/min is used. Testing is performed on an MTS Synergie 400 tensile testing machine with a 10 N load cell and pneumatic grips. Tests are conducted at a rate of 2 inches/minute on samples with a 1-inch gage length. Samples are pulled to break. Peak stress and % elongation at break are recorded and averaged for 10 specimens.
  • Nonwoven products produced from the bicomponent fibers can also exhibit desirable mechanical properties, particularly, strength, flexibility, softness, and absorbency. Measures of strength include dry and/or wet tensile strength. Flexibility is related to stiffness and can attribute to softness. Softness is generally described as a physiologically perceived attribute which is related to both flexibility and texture. Absorbency relates to the products' ability to take up fluids as well as the capacity to retain them.
  • the first step in producing a bi- or multi-component fiber can be a compounding or mixing step.
  • the raw materials are heated, typically under shear.
  • the shearing in the presence of heat can result in a homogeneous melt with proper selection of the composition.
  • the melt is then placed in an extruder where fibers are formed.
  • a collection of fibers is combined together using heat, pressure, chemical binder, mechanical entanglement, and combinations thereof resulting in the formation of a nonwoven web.
  • the nonwoven is then assembled into an article.
  • the objective of the compounding step is to produce a homogeneous melt composition for each component of the fibers.
  • the melt composition is homogeneous, meaning that a uniform distribution of ingredients in the melt is present.
  • the resultant melt composition(s) should be essentially free of water to spin fibers. Essentially free is defined as not creating substantial problems, such as causing bubbles to form which may ultimately break the fiber while spinning.
  • the free water content of the melt composition can be about 1% or less, about 0.5% or less, or about 0.15% of less.
  • the total water content includes the bound and free water.
  • the total water content (including bound water and free water) is about 1% or less.
  • the starch or polymers may need to be dried before processed and/or a vacuum is applied during processing to remove any free water.
  • the thermoplastic starch, or other components hereof can be dried at elevated temperatures, such as about 60°C, before spinning.
  • the drying temperature is determined by the chemical nature of a component's constituents. Therefore, different compositions can use different drying temperatures which can range from 20°C to 150°C and are, in general, below the melting temperature of the polymer. Drying of the components may, for example, be in series or as discrete steps combined with spinning. Such techniques for drying as are well known in the art can be used for the purposes of this invention.
  • any method known in the art or suitable for the purposes hereof can be used to combine the ingredients of the components of the present invention.
  • Such techniques will include heat, mixing, and pressure.
  • the particular order or mixing, temperatures, mixing speeds or time, and equipment can be varied, as will be understood by those skilled in the art, however temperature should be controlled such that the starch does not significantly degrade.
  • the resulting melt should be homogeneous.
  • a suitable method of mixing for a starch and plasticizer blend is as follows:
  • a suitable mixing device is a multiple mixing zone twin screw extruder with multiple injection points.
  • the multiple injection points can be used to add the destructurized starch and the polymer.
  • a twin screw batch mixer or a single screw extrusion system can also be used. As long as sufficient mixing and heating occurs, the particular equipment used is not critical.
  • An alternative method for compounding the materials comprises adding the plasticizer, starch, and polymer to an extrusion system where they are mixed in progressively increasing temperatures.
  • the first three zones may be heated to 90°, 120°, and 130° C, and the last three zones will be heated above the melting point of the polymer. This procedure results in minimal thermal degradation of the starch and for the starch to be fully destructured before intimate mixing with the thermoplastic materials.
  • thermoplastic starch An example of compounding destructured thermoplastic starch would be to use a Werner & Pfleiderer (30 mm diameter 40:1 length to diameter ratio) co-rotating twin-screw extruder set at 250RPM with the first two heat zones set at 50°C and the remaining five heating zones set 150°C. A vacuum is attached between the penultimate and last heat section pulling a vacuum of 10 atm.
  • Starch powder and plasticizer e.g., sorbitol
  • Processing aids can be added along with the starch or plasticizer. For example, magnesium separate can be added, for example, at a level of 0 - 1 %, by weight, of the thermoplastic starch component.
  • the fibers of the present invention can be made by melt spinning. Melt spinning is differentiated from other spinning, such as wet or dry spinning from solution, where in such alternate methods a solvent is present in the melt and is eliminated by volatilizing or diffusing it out of the extrudate.
  • Spinning temperatures for the melts can range from about 105°C to about 300°C, and in some embodiments can be from about 130°C to about 250°C or from about 150°C to about 210°C.
  • the processing temperature is determined by the chemical nature, molecular weights and concentration of each component.
  • Fiber spinning speeds of about 10 meters/minute or greater can be used. In some embodiments hereof, the fiber spinning speed is from about 100 to about 7,000 meters/minute, or from about 300 to about 3,000 meters/minute, or from about 500 to about 2,000 meters/minute.
  • the fiber may be made by fiber spinning processes characterized by a high draw down ratio.
  • the draw down ratio is defined as the ratio of the fiber at its maximum diameter (which is typically occurs immediately after exiting the capillary of the spinneret in a conventional spinning process) to the final diameter of the formed fiber.
  • the fiber draw down ratio via either staple, spunbond, or meltblown process will typically be 1.5 or greater, and can be about 5 or greater, about 10 or greater, or about 12 or greater.
  • Continuous fibers can be produced through, for example, spunbond methods or meltblowing processes.
  • non-continuous (staple fibers) fibers can be produced according to conventional staple fiber processes as are well known in the art.
  • the various methods of fiber manufacturing can also be combined to produce a combination technique, as will be understood by those skilled in the art.
  • Hollow fibers for example, can be produced as described in US Patent 6,368,990 . Such methods as mentioned above for fiber spinning are well known and understood in the art.
  • the fibers spun can be collected subsequent for formation using conventional godet winding systems or through air drag attenuation devices. If the godet system is used, the fibers can be further oriented through post extrusion drawing at temperatures from about 50° to about 200° C. The drawn fibers may then be crimped and/or cut to form non-continuous fibers (staple fibers) used in a carding, airlaid, or fluidlaid process.
  • residual water levels typically be 1%, by weight of the fiber, or less, alternately 0.5% or less, or 0.15% or less.
  • Suitable multicomponent melt spinning equipment is commercially available from, for example, Hills, Inc. located in Melbourne, Florida USA and is described in US Patent 5,162,074 (Hills Inc.).
  • the spinneret capillary dimensions can vary depending upon desired fiber size and design, spinning conditions, and polymer properties. Suitable capillary dimensions include, but are not limited to, length-to-diameter ratio of 4 with a diameter of 0.350mm.
  • spinning of the fibers and compounding of the components can optionally be done in-line, with compounding, drying and spinning being a continuous process.
  • the residence time of each component in the spinline can have special significance when a high melting temperatures thermoplastic polymer is chosen to be spun with destructured starch.
  • Spinning equipment can be designed to minimize the exposure of the destructured starch component to high process temperature by minimizing the time and volume of destructured exposed in the spinneret.
  • the polymer supply lines to the spinneret can be sealed and separated until introduction into the bicomponent pack.
  • the at least two components can be introduced and processed in their separate extruders at different temperatures until introduced into the spinneret.
  • a suitable process for spinning bicomponent, segmented pie fiber with at least one destructured starch segment and at least one polypropylene segment is s follows.
  • the destructured starch component extruder profile may be 80°C, 150°C and 150°C in the first three zones of a three heater zone extruder with a starch composition similar to Example 7.
  • the transfer lines and melt pump heater temperatures may be 150°C for the starch component.
  • the polypropylene component extruder temperature profile may be 180°C, 230°C and 230°C in the first three zones of a three heater zone extruder.
  • the transfer lines and melt pump can be heated to 230°C. In this case the spinneret temperature can range from 180°C to 230°C.
  • residual water levels typically be 1%, by weight of the fiber, or less, alternately 0.5% or less, or 0.15% or less.
  • the fibers hereof may be used for any purposes for which fibers are conventionally used. This includes, without limitation, incorporation into nonwoven substrates.
  • the fibers hereof may be converted to nonwovens by any suitable methods known in the art.
  • Continuous fibers can be formed into a web using industry standard spunbond or meltblown type technologies while staple fibers can be formed into a web using industry standard carding, airlaid, or wetlaid technologies.
  • Typical bonding methods include: calendar (pressure and heat), thru-air heat, mechanical entanglement, hydrodynamic entanglement, needle punching, and chemical bonding and/or resin bonding.
  • the calendar, thru-air heat, and chemical bonding are the preferred bonding methods for the starch and polymer multicomponent fibers. Thermally bondable fibers are required for the pressurized heat and thru-air heat bonding methods.
  • the fibers of the present invention may also be bonded or combined with other synthetic or natural fibers to make nonwoven articles.
  • the synthetic or natural fibers may be blended together in the forming process or used in discrete layers.
  • Suitable synthetic fibers include fibers made from polypropylene, polyethylene, polyester, polyacrylates, and copolymers thereof and mixtures thereof.
  • Natural fibers include cellulosic fibers and derivatives thereof. Suitable cellulosic fibers include those derived from any tree or vegetation, including hardwood fibers, softwood fibers, hemp, and cotton. Also included are fibers made from processed natural cellulosic resources such as rayon.
  • Nonwoven articles are defined as articles that contains greater than 15% of a plurality of fibers that are continuous or non-continuous and physically and/or chemically attached to one another.
  • the nonwoven may be combined with additional nonwovens or films to produce a layered product used either by itself or as a component in a complex combination of other materials, such as a baby diaper or feminine care pad.
  • Preferred articles are disposable, nonwoven articles. The resultant products may find use in one of many different uses.
  • Preferred articles of the present invention include disposable nonwovens for hygiene and medical applications. Hygiene applications include such items as wipes; diapers, particularly the top sheet or back sheet; and feminine pads or products, particularly the top sheet.
  • the starches for use in the examples below are StarDri 1, StarDri 100, Ethylex 2015, or Ethylex 2035, all from Staley Chemical Co. The latter Staley materials are substituted starches.
  • the polypropylenes (PP) are Basell Profax PH-835, Basell PDC 1298, or Exxon/Mobil Achieve 3854.
  • the polyethylenes (PE) are Dow Chemicals Aspun 6811A, Dow Chemical Aspun 6830A, or Dow Chemical Aspun 6842A.
  • the glycerine is from Dow Chemical Company, Kosher Grade BU OPTIM* Glycerine 99.7%.
  • the sorbitol is from Archer-Daniels-Midland Co. (ADM), Crystalline NF/FCC 177440-2S.
  • the polyethylene acrylic acid is PRIMACOR 5980I from Dow Chemical Co.
  • Other polymers having similar chemical compositions that differ in molecular weight, molecular weight distribution, and/or comonomer or defect level can also be used.
  • the process condition in Examples 1-18 use a mass through put of 0.8 ghm although actually tested ranges are from 0.2 to 2 ghm. The practical range of mass through put is from about 0.1 to about 8 ghm.
  • Example 1 Solid Sheath/Core Bicomponent Fiber Thermoplastic polymer Component A is Basell Profax 835.
  • Starch Component B is the TPS component and is compounded using 60 parts StarDri 1, 40 parts sorbitol and 1 part Magnesium Stearate (included in all starch formulations of the examples hereof).
  • the melt processing temperature ranges from 180 to 210°C.
  • the ratio of Component A to Component B is 95:5 to 10:90.
  • An advantage to this fiber is that it is temperature stable to at least 140°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 2 Solid Sheath/Core Bicomponent Fiber Component A is Polyethylene.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 150 to 190°C.
  • the ratio of Component A to Component B is 95:5 to 5:95.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 3 Solid Sheath/Core Bicomponent Fiber Component A is PLA.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 180 to 210°C.
  • the ratio of Component A to Component B is 95:5 to 10:90.
  • An advantage to this fiber is that it is temperature stable to at least 140°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 4 Solid Sheath/Core Bicomponent Fiber Component A is Eastman 14285.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 210 to 250°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 90°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 5 Solid Sheath/Core Bicomponent Fiber Component A is Bionolle 1020.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 160 to 200°C.
  • the ratio of Component A to Component B is 95:5 to 15:85.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 6 Solid Sheath/Core Bicomponent Fiber Component A is EASTAR BIO.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 150 to 180°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 7 Islands-in-the-Sea Bicomponent Fiber Component A is Polypropylene.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 180 to 210°C.
  • the ratio of Component A to Component B is 95:5 to 10:90.
  • An advantage to this fiber is that it is temperature stable to at least 140°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 8 Islands-in-the-Sea Bicomponent Fiber Component A is Polyethylene.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 150 to 190°C.
  • the ratio of Component A to Component B is 95:5 to 5:95.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 9 Islands-in-the-Sea Bicomponent Fiber Component A is PLA.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 180 to 210°C.
  • the ratio of Component A to Component B is 95:5 to 10:90.
  • An advantage to this fiber is that it is temperature stable to at least 140°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 10 Islands-in-the-Sea Bicomponent Fiber Component A is Eastman 14285.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 210 to 250°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 90°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 11 Islands-in-the-Sea Bicomponent Fiber Component A is Bionolle 1020.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 160 to 200°C.
  • the ratio of Component A to Component B is 95:5 to 15:85.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 12 Islands-in-the-Sea Bicomponent Fiber Component A is EASTAR BIO.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 150 to 180°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to polar solvents, such as water and alcohols.
  • Example 13 Solid Sheath/Core Bicomponent Fiber Component A is polyvinyl alcohol purchased from Aldrich Chemical with degree of hydrolysis between 90-99% plasticized with glycerine.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol. The melt processing temperature ranges from 180-250°C. The ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 110°C and has excellent resistance to non-polar solvents, such as CCl 4 , benzene and similar aliphatic/organic compounds.
  • Example 14 Solid Sheath/Core Bicomponent Fiber Component A is poly(vinyl alcohol-co-ethylene) purchased from Aldrich Chemical containing 27-44mol% ethylene.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol. The melt processing temperature ranges from 180 to 230°C. The ratio of Component A to Component B is 95:5 to 15:85.
  • An advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to non-polar solvents, such as CCl 4 benzene and similar aliphatic/organic compounds.
  • Example 15 Solid Sheath/Core Bicomponent Fiber Component A is a polyamide; such as Nylon 6, Nylon 12 and Nylon 6,10.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 180 to 230°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 90°C and has excellent resistance to non-polar solvents, such as CCl 4 , benzene and similar aliphatic/organic compounds.
  • Example 16 Islands-in-the-Sea Bicomponent Fiber Component A is polyvinyl alcohol purchased from Aldrich Chemical with degree of hydrolysis between 90-99% plasticized with glycerine.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol. The melt processing temperature ranges from 180-250°C. The ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 110°C and has excellent resistance to non-polar solvents, such as CCl 4 , benzene and similar aliphatic/organic compounds.
  • Example 17 Islands-in-the-Sea Bicomponent Fiber Component A is poly(vinyl alcohol-co-ethylene) purchased from Aldrich Chemical containing 27-44 mol% ethylene.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol. The melt processing temperature ranges from 180 to 230°C. The ratio of Component A to Component B is 95:5 to 15:85.
  • the advantage to this fiber is that it is temperature stable to at least 80°C and has excellent resistance to non-polar solvents, such as CCl 4 , benzene and similar aliphatic/organic compounds.
  • Example 18 Islands-in-the-Sea Bicomponent Fiber Component A is a polyamide; such as Nylon 6, Nylon 12 and Nylon 6,10.
  • Component B is the TPS component and is compounded using 60 parts StarDri 1 and 40 parts sorbitol.
  • the melt processing temperature ranges from 180 to 230°C.
  • the ratio of Component A to Component B is 95:5 to 20:80.
  • An advantage to this fiber is that it is temperature stable to at least 90°C and has excellent resistance to non-polar solvents, such as CCl 4 , benzene and similar aliphatic/organic compounds.
  • Examples 1-18 contain the same composition for Component B.
  • Alternate compositions for Component B include, but are not limited to, those exemplified below.
  • Material 1 represents starch.
  • Material 2 represents plasticizers.
  • Material 3 represents the non-starch thermoplastic polymer.
  • composition (by parts) Composition Material 1 Material 2 Material 3 Material 1 Material 2 Material 3 B1 Staley StarDri 1 ADM sorbitol Dow Primacore 59801 60 40 B2 Staley StarDri 1 ADM sorbitol Dow Primacore 59801 60 40 15 B3 Staley StarDri 100 ADM sorbitol Dow Primacore 59801 60 40 15 B4 Staley Ethylex 2015 ADM sorbitol Dow Primacore 59801 60 40 15 B5 Staley Ethylex 2035 ADM sorbitol Dow Primacore 59801 60 40 15 B6 Staley StarDri 1 Dow Glycerine Dow Primacore 59801 60 40 B7 Staley StarDrl 1 Dow Glycerine Dow Primacore 59801 60 40 15 B8 Staley StarDri 100 ADM sorbitol Dow Primacore 59801 70 30 20

Claims (10)

  1. Fibre à deux composants comprenant :
    A. un composant polymère thermoplastique comprenant un polymère thermoplastique qui n'est pas de l'amidon ;
    B. un composant à base d'amidon thermoplastique comprenant un plastifiant et de l'amidon déstructuré ;
    dans laquelle le composant polymère thermoplastique entoure complètement le composant à base d'amidon thermoplastique ; dans laquelle le composant polymère thermoplastique contient zéro pour cent d'amidon ou un pourcentage plus faible d'amidon que le composant à base d'amidon thermoplastique ; et dans laquelle le composant polymère thermoplastique a une température de fusion plus élevée que le composant à base d'amidon thermoplastique.
  2. Fibre à deux composants selon la revendication 1, où la fibre a un diamètre de 200 micromètres ou moins.
  3. Fibre à deux composants selon la revendication 1 ou 2, où la fibre a une configuration choisie dans le groupe constitué d'îlots dans la mer et gaine-âme.
  4. Fibre à deux composants selon l'une quelconque des revendications 1 à 3, dans laquelle le polymère thermoplastique du composant A est choisi dans le groupe constitué de polyoléfines, polyesters, polyamides et leurs copolymères et combinaisons.
  5. Fibre à deux composants selon l'une quelconque des revendications 1 à 4, dans laquelle le composant A comprend 51 % ou plus, en poids dudit composant, de polymère thermoplastique qui n'est pas de l'amidon et le composant B comprend 51 % ou plus, en poids dudit composant, dudit amidon déstructuré.
  6. Fibre à deux composants selon l'une quelconque des revendications 1 à 5, dans laquelle le composant A a une température de fusion Tm de 100 °C ou supérieure.
  7. Substrat non tissé comprenant les fibres selon l'une quelconque des revendications 1 à 6.
  8. Substrat non tissé selon la revendication 7, dans lequel au moins une partie desdites fibres sont thermosoudées à d'autres desdites fibres dans ledit substrat.
  9. Substrat non tissé selon la revendication 7 ou la revendication 8, comprenant, en outre, un type de fibres supplémentaire, ledit type de fibres supplémentaire entremêlé avec lesdites fibres selon la revendication 2.
  10. Article jetable comprenant la nappe non tissée selon l'une quelconque des revendications 7 à 9.
EP02789689A 2002-11-14 2002-11-14 Fibres bicomposees comprenant un polymere thermoplastique entourant un noyau amylace Expired - Lifetime EP1560955B1 (fr)

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US7998888B2 (en) * 2008-03-28 2011-08-16 Kimberly-Clark Worldwide, Inc. Thermoplastic starch for use in melt-extruded substrates
US20130089747A1 (en) 2011-05-20 2013-04-11 William Maxwell Allen, Jr. Fibers of Polymer-Wax Compositions

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002090630A1 (fr) * 2001-05-10 2002-11-14 The Procter & Gamble Company Fibres multicomposees contenant de l'amidon et des polymeres biodegradables
WO2002090631A1 (fr) * 2001-05-10 2002-11-14 The Procter & Gamble Company Fibres multicomposees comprenant de l'amidon et des polymeres

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4136694C2 (de) * 1991-11-07 1996-10-10 Inventa Ag Stärkefaser oder Stärke-modifizierte Faser, Verfahren zu ihrer Herstellung sowie ihre Verwendung
JP3792254B2 (ja) * 1995-02-14 2006-07-05 チッソ株式会社 生分解性繊維及び不織布

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002090630A1 (fr) * 2001-05-10 2002-11-14 The Procter & Gamble Company Fibres multicomposees contenant de l'amidon et des polymeres biodegradables
WO2002090631A1 (fr) * 2001-05-10 2002-11-14 The Procter & Gamble Company Fibres multicomposees comprenant de l'amidon et des polymeres

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ATE448336T1 (de) 2009-11-15
DE60234392D1 (de) 2009-12-24
JP4098304B2 (ja) 2008-06-11
WO2004050965A1 (fr) 2004-06-17
JP2006505719A (ja) 2006-02-16
AU2002352739A1 (en) 2004-06-23
EP1560955A1 (fr) 2005-08-10
CA2504151A1 (fr) 2004-06-17

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