EP1507877A1

EP1507877A1 - Method for sintering materials containing iron oxide in a sintering machine

Info

Publication number: EP1507877A1
Application number: EP03740059A
Authority: EP
Inventors: Wolf Lanzer; Manfred Ludwig; Karl-Rüdiger HÜSIG; Arnd KÖFLER; Walter Gerlach; Romuald Hartmann; Hans-Joachim Werz
Original assignee: Mannesmannroehren Werke AG
Current assignee: Salzgitter Mannesmann GmbH
Priority date: 2002-05-29
Filing date: 2003-05-27
Publication date: 2005-02-23
Anticipated expiration: 2023-05-27
Also published as: EP1507877B1; JP2005530923A; DE10224448A1; ATE359379T1; KR20050004890A; AU2003273380A1; WO2003102252A1; DE10224448B4; DE50307021D1

Abstract

The invention relates to a method for sintering materials containing iron oxide in a sintering machine. According to said method, a sinter mixture containing a solid fuel is ignited, gases containing oxygen are conducted through the sinter mixture and the hot final sinter product is cooled after discharge. One portion of the waste gas is returned to the sintering machine as recycled gas and the other portion of the waste gas is evacuated as residual gas. The division of the total waste gas quantity into recycled gas and residual gas is achieved by a variation of the process surface (sinter strand).

Description

Process for sintering iron oxide-containing substances on a sintering machine

description

The invention relates to a method for sintering iron oxide-containing substances on a sintering belt having a sintering belt, suction boxes and a sintering machine according to the preamble of claim 1.

The sintering of iron oxide-containing substances, in particular iron ores or iron ore concentrates, is carried out on sintering machines. The sinter mixture, consisting of the iron ore, return material, solid fuel and aggregates, is charged onto the sintering belt and the fuel is ignited on the surface of the material bed under the ignition furnace. Fresh air is then sucked through the sinter bed and the sinter front moves from top to bottom through the sinter bed. The exhaust gas is sucked into the gas collection system from the suction boxes under the upper run of the sintered bed and, after cleaning, discharged into the atmosphere. The sintering process requires heat transfer between the hot combustion gas and the cold solid. The amount of solids and the amount of air are heat equivalent. This heat exchange requires large amounts of air and therefore exhaust gas. The exhaust gas contains evaporated water from the sintering mixture, CO ₂ from the combustion of the fuel and from calcination processes, sulfur oxides from the combustion of sulfur - mainly from the added fuel - CO from incomplete combustion, false air and air that flows between the side walls of the grate wagon Feed enters the exhaust gas unused. The exhaust gas also contains dioxins and furans, in particular the exhaust gas drawn off from the rear part of the sintering belt. The exhaust gas also carries dust with it, which must be removed.

On the one hand, the operators of such sintering machines strive to reduce the amount of exhaust gas and to keep the dioxins and furans still contained in the chimney air as low as possible, also in view of the stricter requirements of the respective licensing authority. In order to reduce the amount of exhaust gas, it has already been proposed to divide the exhaust gas flow and to recirculate a partial amount (JP-A-52116703, "Stahl und Eisen" 99 (1979) No. 7, page 327/33). A special regulation of the divided exhaust gas quantity is proposed in EP 0535727A1. In this known method, only a quantity of exhaust gas is discharged as residual gas, which corresponds to the gas formed during the sintering process plus the oxygen-rich gas added for the strengthening plus the outside air which has penetrated from the outside minus the consumed oxygen. The other partial flow of the exhaust gas is recirculated as recycle gas and, before the sintering mixture is acted on, is strengthened to a maximum of 24% oxygen by adding oxygen-rich gases.

In Stahl und Eisen 115 (1995) No. 11, pages 37-40, a plant built according to the method described in EP 0535727 AI is presented under the title "Environmental protection in iron ore sintering plants by exhaust gas recirculation.

The exhaust gas is preferably partially recorded and returned to the sintering belt once as recycle gas and once again discharged as residual gas. In order to be able to set the oxygen content in the recirculated exhaust gas flow in accordance with the specification, a fresh air supply line opens into the circuit line.

DE 19623981 discloses a method for removing harmful ingredients from exhaust gases from sintering plants. In this known method, powdered sorbents in the form of brown coal coke are added to the exhaust gas stream and the exhaust gas stream laden with sorbents is subsequently passed through an electrostatic filter. The loaded sorbents are returned to the sintering process after they have been filtered out. The method can be improved if the exhaust gas flow is passed through a pre-separator before it passes the electrostatic filter.

The object of the invention is to further optimize the sintering process in such a way that, with a still small amount of exhaust gas and good sintering quality, in particular the dioxins and furans still present in the residual gas and the amount of dust are reliably below the limit values specified by the licensing authority. The object is achieved on the basis of the preamble in conjunction with the characterizing features of patent claim 1. Advantageous further developments are the subject of subterranean claims.

According to the teaching of the invention, the total amount of exhaust gas is divided into

Circulation gas and residual gas by varying the process area, the location of the interface between the extraction for the circulation gas and the extraction for the residual gas being selected so that a maximum amount of exhaust gas is conducted in the circuit without impairing the sintering quality and performance, and the residual gas is a partial quantity with lower and the cycle gas is a subset with higher pollutant concentration. Furthermore, the amount of heat of the withdrawn cycle gas is used to heat the residual gas, with the heating up to a temperature to avoid falling below the dew point, but which is lower than the mixing temperature ensured when the total amount of exhaust gas is discharged.

The proposed division of the process surface of the sintering belt with respect to the exhaust gas into a subsection, the exhaust gas amount of which is conducted as recycle gas and into a section, the exhaust gas of which is discharged as residual gas, has the purpose of dividing the exhaust gas flow into a subset that is less polluted with regard to the pollutant concentration and into a subset to divide with higher concentrations. The less polluted portion can be discharged as residual exhaust gas after separating the dust and the adsorbents introduced - including the dioxins and furans adsorbed on it - and after heating up to avoid the acid dew point via the chimney. The portion that is more heavily contaminated with respect to the dioxins and furans is circulated, taking advantage of the effect that a large part of the dioxins and furans are broken down when they are returned to the hot sintering mixture and are thus rendered harmless.

Furthermore, one takes advantage of the effect that the adsorbents introduced into the exhaust gas stream are particularly effective when the temperature in the exhaust gas stream is low. This is achieved by dividing the amount of exhaust gas into cycle gas and residual gas.

The residual gas is withdrawn from the area of the sintering belt, which lies in the feed area and the area adjacent to it. This area is temperature-related low in comparison to the area of the cycle gas despite the heating to avoid falling below the H ₂ SO ₄ dew point. By the proposed combination

- Distribution of the amount of exhaust gas

- Heating the residual gas before discharging achieves several goals:

- The total amount of exhaust gas to be discharged is kept small.

- The adsorbents injected into the residual gas are particularly effective because of the low temperature of the residual gas, so that the remaining proportion of the pollutants in the residual gas to be discharged corresponds to the official requirements. - An H ₂ SO ₄ dew point is not reached by heating the residual gas.

- For heating the residual gas, the thermal energy of the cycle gas is used energetically.

The proposed variation in the division of the process area is a very simple but effective means of being able to optimize the process. On the one hand it can be achieved that the ratio of oxygen supply to oxygen consumption approaches the ideal state 1 and thus the amount of exhaust gas is minimized. On the other hand, the performance of the system can be influenced if the sinter quality remains the same. By varying the essential parameters controlling the process, an optimum can be achieved with regard to the amount of exhaust gas, performance and quality.

The amount of exhaust gas circulated has the further effect that the required oxygen supply is lower compared to a normal process. In the borderline case, this allows with that brought in by the sucked-in false air

Oxygen to meet the need. This saves the fresh air that would otherwise have to be supplied separately.

If fresh air is required in a specific case in addition to the sucked-in false air, it is considered advantageous if, instead of the previously sucked-in ambient air, the dust is removed from the area in the area of cold screening suction air used. This proposed procedural step in turn achieves two goals at the same time:

- The dust removal required in the area of cold screening is used as an oxygen carrier for the sintering process. - The sinter mixture is used as a filter for the dust-laden suction air, so that no separate filter is required.

Further features, advantages and details of the invention result from the following description of an embodiment shown in a drawing. Show it:

Figure 1 is a schematic flow diagram of a sintering plant according to the invention.

Figure 2 is a diagram of the method according to the prior art.

Figure 3 is a diagram of the method according to the invention.

Figure 4 is a schematic representation of the arrangement of the suction boxes and the flue gas manifolds.

FIG. 1 shows in the form of a schematic flow diagram a sintering plant operating according to the invention. The core of the system is a sintering belt 1, in which case the sintering mix is placed on the right and the finished sinter is discarded on the left. This direction of transport is indicated by an arrow 2. Suction boxes and associated exhaust pipes 3, 4 are arranged to the right and left of the sintering belt 1, the exhaust gas drawn off in the beginning area of the sintering belt 1 being discharged as residual gas and the exhaust gas drawn off in the end area of the sintering belt 1 being circulated. The exhaust gas circulated is fed via a line 5 to a heat exchanger 6 and then via a further line 7, a filter 8 arranged therein, which has the function of separating the dust from the exhaust gas.

After passing through the filter 8, the returned gas is fed via a line 9 to the sintering belt 1 by means of a suction blower 22 and distributed evenly over the sintering belt 1. The arrows shown are intended to clarify the task of the recirculated exhaust gas on the sintering belt 1. The residual gas to be discharged is over a line 10 is supplied to the already mentioned heat exchanger 6, the heat of the cycle gas being used for heating the residual gas. This is to avoid falling below the dew point for sulfuric acid. After passing through the heat exchanger 6, the residual gas is fed via a line 11 to an entrained flow reactor 12. In this entrained flow reactor 12, lignite-coke breeze is blown in as known as adsorbent so that the harmful substances in the residual gas, such as dioxins and furans, can attach to it. After passing through the entrained flow reactor 12, the residual gas is fed via a line 13 to a filter 14 in which the dust and the adsorbents previously blown in are separated out. Thereafter, the residual gas cleaned in this way is fed to a chimney 16 by means of a suction blower 23 via a line 15 and distributed into the environment.

The optional separate fresh air supply 21 shown in FIG. 1 is only required if the oxygen supply introduced by the sucked-in false air is too low.

The finished sinter is discarded at the end of the sintering belt 1 and cooled in rotary coolers 17, 18. The air extracted in the rotary coolers 17, 18 is fed via a line 19 to a filter 20 in order to separate the entrained dust.

In a known manner, the extracted dust from the sintering plant itself, as well as accumulating gout dust and casting hall dust from the blast furnace are agglomerated with water with the addition of quicklime to conical particles (mini pellets). This agglomeration takes place in a mechanical eddy current mixer 24, also called "Eirich mixer". The moist agglomerates are continuously fed to the sinter mixture in the specified area.

The sintering process according to the prior art (FIG. 2) and the process according to the invention (FIG. 3) are compared with one another in FIGS.

In these two diagrams, gas quantities in kg / h / m are plotted over the wind boxes. In the bottom line with the squares painted black, the oxygen consumption for the fuel in the sintered mixture is shown. The line above with the black rhombuses shows the supply of oxygen through the supplied sintered air, which is the sum of sucked-in false air and fresh air supplied. The third line with the triangles above shows the course of the exhaust gas quantity.

By comparing the two diagrams directly, the effect of the cycle gas can be clearly seen. The required oxygen supply decreases, so that the second line only runs slightly above the first line, at least in the area of the first wind boxes.

The cross line drawn thick in FIG. 3 symbolizes the separation according to the invention of the sintered strip 1 into an area of recycle gas and an area of residual gas, the double arrow indicating the possibility of displacement of the separation point. The displacement of the separation point according to the invention enables the process to be largely optimized.

Moving the separation point to the left would mean that increasing the proportion of the recycle gas would shift the oxygen supply even further to lower values; ideally, oxygen supply = oxygen consumption. Lower oxygen supply also means lower amount of exhaust gas, since these two amounts are linked by the combustion process.

If the separation point is shifted to the right and the sinter quality is consistently good, the proportion of the recycle gas is reduced and the amount of exhaust gas is thus increased somewhat.

Depending on the process conditions, the optimum can be set easily by moving the separation point.

FIG. 4 shows a schematic representation of a partial area of the arrangement of the suction boxes 25 and the flue gas collecting lines 5, 10.

The suction boxes 25.1 located in the initial region of the sintering belt have a fixed separation 26 with respect to the discharge line for recycle gas 5. This is followed in this embodiment by a total of four suction boxes 25.2, which have a variable separation 27. Variable separation 27 means that these suction boxes 25.2 optionally on the discharge line circuit gas 5 or on the discharge line residual gas 10 can be switched. The effect that can be achieved with this was explained in detail at the beginning.

The remaining suction boxes 25.3 up to the discharge area 28 are permanently connected to the circulation gas 5 discharge line.

In the event of an emergency, the fixed separation 29 arranged in the discharge line residual gas 10 can be removed in order to be able to discharge all of the resulting exhaust gas.

LIST OF REFERENCE NUMBERS

Claims

claims

1. A method for sintering iron oxide-containing substances on a sintering machine, in which a sintering mixture containing solid fuel is ignited, oxygen-containing gases are passed through the sintering mixture and the hot one

Finished sinter is cooled after discharge, part of the exhaust gas is returned to the sintering machine as recycle gas with a higher concentration of pollutants and the other part of the exhaust gas is discharged as residual gas with a lower concentration of pollutants, the dust contained in the recycle gas and residual gas being heated up prior to discharge and also in Plant and the dust generated during cold screening is extracted and removed, characterized in that the total amount of exhaust gas is divided into cycle gas and residual gas by varying the process area (sintered belt), the location of the interface between the suction for the cycle gas and the suction for the Residual gas is selected so that a maximum amount of exhaust gas is conducted in the circuit without impairing the sintering quality and performance and the thermal energy of the withdrawn circuit gas is used to heat the residual gas, the heating to a temperature to avoid the H ₂ S0 ₄ dew point is not reached, but is lower than the resulting one

Mixing temperature when the total amount of exhaust gas is discharged.

2. The method according to claim 1, characterized in that the oxygen-containing gas passed through the sintering mixture is composed of sucked-in false air and separately supplied fresh air, the separately supplied amount of fresh air striving for a minimum value with sufficient oxygen supply due to false air.

A method according to claim 2, characterized in that the minimum value is zero.

4. The method according to claims 1-3, characterized in that the suction of the area of the cold screening and the suction of the plant space is carried out separately and in the case of separate supply of fresh air, the extracted gas of the cold screening as an oxygen-containing gas on

Sintered mixture and the sintered mixture is used as a filter for the carried dust.

5. The method according to claim 1, characterized in that the recirculated gas is distributed evenly over the entire sintering belt.

6. The method according to claim 1, characterized in that the suction taking place in the discharge area of the finished sinter is coupled with the suction of the plant space.

7. The method according to claim 6, characterized in that the thermal energy contained in the exhaust gas of the finished sinter is used energetically.

8. sintering machine for sintering iron oxide-containing substances consisting of a sintering belt, suction boxes, an ignition furnace, a cooler for the finished sinter,

Blowers, filters and pipelines for carrying out the method according to claim 1, characterized in that in the area of the interfaces between the circuit gas extraction and residual gas, the suction boxes (25.2) are provided with sliders for changing the extraction assignment and in the discharge line (5) for the circuit gas the releasing ones Side of a heat exchanger (6) and in the discharge line (10) for the residual gas, the receiving side of the heat exchanger (6) is arranged, which is followed by a known entrained flow reactor (12). Sintering machine according to claim 8, characterized in that, in the case of separate supply (21) of fresh air, the blower is used for the conduction of oxygen-containing gases onto the sintering mixture as an aggregate for the extraction of the cold screening area.