EP1499769A1 - Thermo-adhesive mesh - Google Patents

Thermo-adhesive mesh

Info

Publication number
EP1499769A1
EP1499769A1 EP03740560A EP03740560A EP1499769A1 EP 1499769 A1 EP1499769 A1 EP 1499769A1 EP 03740560 A EP03740560 A EP 03740560A EP 03740560 A EP03740560 A EP 03740560A EP 1499769 A1 EP1499769 A1 EP 1499769A1
Authority
EP
European Patent Office
Prior art keywords
grid
adhesive
glue
textile
threads
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03740560A
Other languages
German (de)
French (fr)
Inventor
Thierry Gautreau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chavanoz Industrie SARL
Original Assignee
Chavanoz Industrie SARL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chavanoz Industrie SARL filed Critical Chavanoz Industrie SARL
Publication of EP1499769A1 publication Critical patent/EP1499769A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/06Fibrous reinforcements only
    • B29C70/10Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
    • B29C70/16Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
    • B29C70/20Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres
    • B29C70/202Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length oriented in a single direction, e.g. roofing or other parallel fibres arranged in parallel planes or structures of fibres crossing at substantial angles, e.g. cross-moulding compound [XMC]
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • D04H3/04Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles
    • D04H3/045Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments in rectilinear paths, e.g. crossing at right angles for net manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05CAPPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C1/00Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating
    • B05C1/04Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length
    • B05C1/08Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line
    • B05C1/0826Apparatus in which liquid or other fluent material is applied to the surface of the work by contact with a member carrying the liquid or other fluent material, e.g. a porous member loaded with a liquid to be applied as a coating for applying liquid or other fluent material to work of indefinite length using a roller or other rotating member which contacts the work along a generating line the work being a web or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2233/00Use of polymers of unsaturated acids or derivatives thereof, as reinforcement
    • B29K2233/04Polymers of esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2309/00Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement
    • B29K2309/08Glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/184Nonwoven scrim
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/10Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
    • Y10T442/184Nonwoven scrim
    • Y10T442/198Coated or impregnated
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2738Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2861Coated or impregnated synthetic organic fiber fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/20Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
    • Y10T442/2926Coated or impregnated inorganic fiber fabric
    • Y10T442/2992Coated or impregnated glass fiber fabric

Definitions

  • the present invention relates to the general technical field of textile grids formed of a network of warp and weft yarns, such grids acting in particular as reinforcements or supports in different industrial applications.
  • the present invention relates to a textile grid formed by a network of crossed or superimposed nonwoven threads comprising at least one ply of warp threads and at least one ply of weft threads, the warp and weft threads being linked together by a binder, said textile grid being coated on at least one of its faces with a thermally reactivable adhesive for laminating the grid on an external element, for example in order to reinforce it.
  • the present invention also relates to any finished or unfinished industrial product incorporating a textile grid according to the invention.
  • the present invention also relates to a method of manufacturing a textile grid in which a network of crossed or superimposed nonwoven threads is produced, comprising at least one ply of warp threads and at least one ply of weft threads to form a grid. primitive, and in which at least one of the faces of said primitive grid is coated with thermally reactivatable adhesive.
  • the present invention finally relates to a device for implementing at least part of the above-mentioned method.
  • the known grids can, for example, use at least two layers of warp yarns which are superimposed or even offset, each pair of plies having interposed between them at least one ply of weft son.
  • the warp threads and the weft threads are linked together at their crossings by a binder creating a series of bonding points, with a view to obtaining a textile grid having a finished structure and mechanically stable.
  • the grids produced according to this technique generally give satisfaction and serve as reinforcements or supports in very varied technical fields such as, for example, without limitation, in the building industry as supports for parquet and ceramics, or coatings wall and carpet, in the paper industry, or even as reinforcing elements in synthetic or other foams.
  • the grids intended to serve as reinforcements are assembled by bonding to the surface of the element to be reinforced. Such an assembly is also called laminating. This lamination can be done using an external supply of glue.
  • the binder impregnating the grid is capable of ensuring this bonding function.
  • the binders used to date are generally polymeric adhesives in aqueous phase or solvent crosslinked or not.
  • the reactivation of such adhesives requires temperatures of the order of 150 ° C to 300 ° C.
  • Such temperature levels therefore induce significant laminating times, since as a function of the time necessary for the heating device to reach the reactivation temperature, it being understood that the higher this temperature, the longer this temperature rise time will be.
  • Such temperature levels also prohibit laminating on certain materials that would not support them.
  • foams are in fact generally altered or destroyed at such temperature levels.
  • the higher the reactivation temperature the greater the energy input required for this reactivation, requiring heavy equipment and therefore costly. This leads to an increase in the cost price of the reinforced products obtained, which constitutes an industrial disadvantage.
  • the objects assigned to the present invention therefore aim to remedy the various drawbacks of the heat-activated textile grids of the prior art mentioned above, and to propose a new textile grid having improved properties and which is easy to use and at a reduced cost, said grid being formed by a network of crossed non-woven threads, and being coated with a thermally reactivable glue to laminate the grid to an external element.
  • Another object of the invention is to propose a new textile grid coated with a thermally reactivable adhesive which is suitable for laminating on most materials.
  • Another object of the invention is to propose a new textile grid coated with a thermally reactivable adhesive capable of improving the general mechanical and chemical resistance of the grid.
  • Another object of the invention is to propose a new textile grid allowing a clean bonding without solvent.
  • the objects assigned to the invention are achieved using a textile grid formed by a network of nonwoven cross-threads, comprising at least one layer of warp threads and at least one layer of weft threads, the threads of warp and weft being linked together by a binder, said textile grid being coated on at least one of its faces with a thermally reactivable glue to laminate the grid to an external element, characterized in that the viscosity of said glue, measured at a temperature of 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.
  • a method of manufacturing a grid according to the invention characterized in that it comprises at least:
  • a coating step where at least one of the faces of said primitive grid is coated with thermally reactivable adhesive, the viscosity of which is measured at a temperature of 230 ° C. according to the standard
  • ASTM-D3236-88 is less than or equal to 40 Pa.s.
  • a device for implementing the method according to the invention characterized in that it comprises: - a tank intended to contain thermally reactivable glue, the viscosity of which, measured at 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s, said tank being heated so as to keep the glue in melting, and having at least one opening, - a cylinder rotating around its axis of symmetry, said cylinder being arranged and positionable relative to the tank so as to continuously feed, due to its rotation, glue in fusion through of said opening, and continuously depositing this molten glue on the face of a textile grid to be coated with glue, - a conveyor means for bringing said textile grid substantially into contact with the cylinder.
  • FIG. 1 illustrates, in a side view in section, a detail of the structure of a textile grid according to the invention.
  • FIG. 2 illustrates, in a top view, a detail of a grid according to the invention.
  • FIG. 3 illustrates, in a schematic view in longitudinal section, the principle of embodiment and operation of a device for implementing the method according to the invention.
  • FIG. 4 illustrates a detail of the device shown schematically in Figure 3 on an enlarged scale.
  • the textile grid 5A is formed by a network of nonwoven crossed threads, comprising at least one ply of warp threads 1, 1 ', and at least one ply of weft threads 2.
  • the wires thus delimit empty zones, so that the grid has an openwork structure.
  • the textile grid according to the invention comprises at least two plies of warp threads 1, 1 ′ between which is interposed at least one ply of weft threads 2.
  • the construction of the network of warp threads 1, 1 'and weft threads 2 is obtained by shifting the warp threads 1, 1' and weft 2 without superposition (see Figure 2), or on the contrary by ensuring a superposition of the wires.
  • the network of warp 1 and weft 2 threads can be obtained by crossing the warp and weft threads at 90 ° (square construction), or according to a different angular inclination, for example bidirectional or tri- directional.
  • the texture of the textile grid according to the invention may vary from 0.4 thread per centimeter to 10 threads per centimeter, for warp and weft threads.
  • any type of textile thread commonly used to date in the production of textile grids may be used, and for example glass threads (having a linear mass can for example vary from 11 to 544 tex) or polyester (having a linear mass which can vary for example between 78 Dtex and 1100 Dtex).
  • the warp 1, 1 ′ and weft 2 threads are linked together by a binder creating a series of bonding points at the intersections of the network of threads.
  • any binder commonly used to date in the technical field considered may in particular be used, and in particular any polymer adhesive of the thermoplastic polymer binder type.
  • the network of threads forming the textile grid in accordance with the invention can thus be made using synthetic latex (SBR), PVAC, PVC plastisols, polyvinyl alcohol (PVA), conventional iron-on impregnations, polyurethane binders or acrylic binders for example.
  • SBR synthetic latex
  • PVAC PVAC
  • PVC plastisols PVAC
  • PVAC polyvinyl alcohol
  • PVVA polyvinyl alcohol
  • conventional iron-on impregnations polyurethane binders or acrylic binders for example.
  • the textile grid 5A is coated on at least one of its faces A with a thermally reactivable adhesive 3 to laminate the grid to an external element.
  • a thermally reactivatable adhesive is a material which, when it is going to be subjected to a characteristic temperature known as thermal reactivation, will have an adhesive character allowing it to become integral with an external element. This solidarity is lasting, a times the material returned to a temperature below said thermal reactivation temperature.
  • the reactivatable adhesive material can have a non-adhesive nature at room temperature and be in the solid state, while when it is heated to at least its thermal reactivation temperature, it takes the form of a liquid, which can be very viscous, with good adhesive power.
  • the thermal reactivation is done using a heating means which can be of any known type, and for example using high frequency or infrared radiation, conduction or convection phenomena.
  • the viscosity of the adhesive 3, measured at a temperature of 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.
  • the viscosity of said adhesive measured at a temperature of 200 ° C according to standard ASTM-D3236-88, is less than or equal to 30 Pa.s.
  • the viscosity of said adhesive measured at its application temperature (the value of which is systematically available from the manufacturer) according to standard ASTM-D3236-88, is less than or equal to 30 Pa.s.
  • Such a viscosity characteristic is representative of an adhesive which can be reactivated at temperatures which may be relatively low, and which may drop, for example, up to 70 ° C.
  • the textile grid 5A according to the invention can be laminated without damage to materials which do not withstand high temperatures, and in particular synthetic foams.
  • the adhesive 3 is of the “hot-melt” type.
  • a “hot-melt” type adhesive is a 100% hot-melt adhesive, also called 100% active adhesive, which comprises a thermoplastic material capable of passing from a non-adhesive solid state to an adhesive viscous state, and this in a reversible manner.
  • the solid state is obtained when the material is subjected to a temperature below a characteristic temperature called the thermal reactivation temperature, which can vary for example between 70 ° C. and 180 ° C. depending on the formulation of the adhesive.
  • the thermal reactivation temperature a characteristic temperature
  • the thermal reactivation temperature can vary for example between 70 ° C. and 180 ° C. depending on the formulation of the adhesive.
  • Hot-melt adhesives are well known as such. They consist of a mixture of polymers including:
  • polymers or copolymers of high molecular weight for example polyethylene vinyl acetate, polyamide, polyester, epoxy, polyethylene, - waxes of the paraffin type of low molecular weight
  • additives for example anti-UV or antioxidants.
  • the grid according to the invention can be laminated to most materials, so as to form a complex.
  • the grid according to the invention is thus also capable of being compatible with secondary or final transformations of the complex, such as for example thermoforming of the complex.
  • the textile grid according to the invention can use any type of known “hot-melt” glue.
  • the textile grid 5A according to the invention may be covered with thermally reactivable adhesive 3 on at least one of its faces according to a surface mass (or sizing weight) of for example between 2 and 300 g / m 2 .
  • the ratio of the mass of glue 3 coating the network of wires to the mass of said network of wires may be between 50 and 400%, and preferably between 100 and 300%.
  • an adhesive 3 of the “hot-melt” type thus makes it possible to produce large and uniform adhesive deposits, since the adhesive 3 consists entirely of adhesive material, and not of an adhesive-solvent mixture.
  • the binder of the textile grid according to the invention is formed by said thermally reactivable adhesive 3, said adhesive thus ensuring a double function:
  • the grid has a finite and mechanically stable structure (i.e. which stands by itself, independently of any interaction with an external element),
  • the grids according to the invention have a mechanical resistance to rupture of between approximately 19 and 1970 Newtons over 5 cm.
  • the coating of hot-melt type adhesive improves the tensile and tear strength of the grid. It also allows an improvement in the flexural modulus and the stiffness of the grid.
  • the textile grid 5A in accordance with the invention can also be advantageously used as reinforcement for automobile wheelchair foam, since the reactivation temperature of the adhesive is compatible with the temperature that such foam can endure. This makes it possible to produce mechanically resistant armchairs while giving them a high-end connotation.
  • the textile grid according to the invention can be used to replace the polyvinyl chloride reinforcements, usually used for example for car seats. Such use has the important advantage that, in the event of combustion (accidental or end of product life) of the seat, the grid does not release toxic products, while polyvinyl chloride releases chlorine.
  • the textile grid according to the invention will also be particularly well suited for assembling floor coverings of the tiling, parquet type, or for reinforcing wiping cloths. It can also be used for the production of crack cover adhesives.
  • the grid according to the invention thus makes it possible to be adapted to the conditions of use of the final product. It also allows recycling of reinforced products at the end of their life, since due to the reversible nature of the glue used (character which aqueous glues do not have), the grid can be separated at will from the element it reinforces.
  • the process for manufacturing a textile grid according to the invention and as described above implements a series of production steps, at least of which:
  • a step of crossing (not shown) the warp 1, 1 ′ and weft 2 threads to form a primitive grid 5;
  • a production step is well known to those skilled in the art, and can for example be carried out by any suitable method
  • a coating step (see FIGS. 3 and 4), where at least one of the faces A of said primitive grid 5 is coated with thermally reactivable adhesive 3 whose viscosity, measured at a temperature of 230 ° C. according to the ASTM standard- D3236-88, is less than or equal to 40 Pa.s, or more preferably is less than or equal to 30 Pa.s, when it is measured at 200 ° C according to the same standard.
  • the coating step is carried out immediately after the crossing step.
  • the grid 5 does not stand by itself, and the coating step makes it possible both to give the grid 5 a clean mechanical strength and to provide it with a thermally reactivable glue, for subsequent lamination.
  • the thermally reactivable glue 3 therefore acts both as a binder and as a lamination glue.
  • the warp 1, 1 ′ and weft 2 threads are simultaneously covered with glue 3.
  • said adhesive 3 is of the “hot-melt” type.
  • the face A of the primitive grid 5 is coated with glue 3 which can be reactivated thermally, by tangential passage against at least part of the lateral surface 7A of a rotary cylinder 7 coated with said glue 3 in fusion.
  • a cylinder 7 allows an application "with the roller", which allows a deposit of substantially uniform and regular adhesive on the primitive grid 5, without bead.
  • a cylinder 7 makes it possible to avoid the drawbacks of conventional technologies for coating “hot-melt” type products, such as machines with “lip nozzles”.
  • Such machines if they can be successfully used for coating closed supports, such as paper or fabric panels over large widths, are however ineffective for coating open substrates over suitable widths, with a low inherent mechanical strength, such as a primitive grid, without causing beads of glue which make the product very difficult to use.
  • a primary bonding step occurs between the step of crossing the wires and the coating step.
  • the primitive grid 5 is impregnated with a binder, so as to bond the weft 2 and warp 1 yarns together.
  • a method according to this variant implements, after the primary bonding step, a grid having its own mechanical strength imparted by the primary impregnation of binder; the coating step, in this case, is only intended to provide the grid with a layer of thermally reactivable adhesive.
  • the primary bonding step can be carried out by any method of the prior art, which are well known to those skilled in the art.
  • binder conventionally used for such an application can be used during this step, and in particular the binders formed by a polymer adhesive, or those mentioned above.
  • the invention also relates to a device for implementing the method according to the invention.
  • This device includes:
  • a tank 6 intended to contain glue 3 which can be reactivated thermally, the viscosity of which, measured at 230 ° C. according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s, and so preferential is less than or equal to 30 Pa.s at 200 ° C., said tank 6 being heated by any suitable means, so as to keep the glue 3 in fusion, and having at least one opening,
  • a cylinder 7 rotating around its axis of symmetry X, said cylinder 7 being arranged and positionable relative to the tank 6, so as to continuously feed, due to its rotation, glue 3 molten through said opening , and continuously depositing this glue 3 in fusion on the face A of a textile grid 5 to be coated with glue, - a conveying means (not shown) for bringing said grid 5 substantially into contact with the cylinder 7.
  • the cylinder 7 is also heated to a temperature for example between 70 and 300 ° C, and preferably between 100 ° C and 220 ° C.
  • This heating can be achieved by any known means.
  • the rotating cylinder 7 is arranged so that any zone of at least part of its lateral surface 7A is alternately in contact:
  • the cylinder 7 is positioned between the opening and the face A of the grid to be coated with glue 3.
  • the cylinder 7 is driven by a rotational movement (materialized by the arrow 9) around its axis of symmetry X, which gives its lateral surface 7A a certain linear speed.
  • the conveying means which can be of any known type (for example a conveyor belt), gives the grid 5 to be coated with adhesive a longitudinal translational movement which takes place at a certain speed of movement.
  • the longitudinal translational movement 8 takes place at a displacement speed which is substantially equal to the linear speed of the lateral surface 7A of the cylinder.
  • the quantity of glue deposited on the warp threads is substantially equal to the quantity deposited on the weft threads.
  • the difference in linear speed between the lateral surface 7A of the cylinder 7 and the primitive grid 5 to be coated makes it possible to obtain a thickness E1 of adhesive on the warp threads 1, 1 ′ which is different from the thickness E2 of adhesive on the weft yarn 2.
  • the tank 6 is in turn made up of a body 6C provided with a doctor blade 6A for calibrating the coating of the cylinder, that is to say for controlling the thickness E of adhesive depositing on the lateral surface 7A of the rotary cylinder. 7.
  • a second doctor blade 6B opposite the first makes it possible to close the tank 6 in cooperation with the first doctor blade 6A, during machine stops. It is of course conceivable to design a device using two cylinders to coat a primitive grid 5 of glue 3 on its two faces, simultaneously or not, without departing from the scope of the invention.
  • the textile grids are thin enough that a coating on one side is sufficient to obtain a grid coated on both sides with glue.
  • the device according to the invention thus makes it possible to coat, for example, grids whose width can vary between 0.2 and 5 m, at a speed of, for example, between 0.4 and 150 m per minute.
  • the control of the linear speed differentials between the cylinder and the grid that is to say the control of the difference between the linear speed of the cylinder and the speed of movement of the grid, makes it possible to control the distribution of the adhesive deposit between the warp and weft threads, avoiding any unwanted bead.
  • the invention finds its industrial application in the field of textile grids intervening in particular as reinforcements or supports.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing Of Multi-Layer Textile Fabrics (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Adhesive Tapes (AREA)
  • Nonwoven Fabrics (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention relates to a textile mesh (5A), embodied as a system of crossed, non-woven threads, comprising at least one layer of warp thread (1, 1') and at least one layer of weft thread (2), the warp (1,1') and weft (2) threads being connected to each other by means of a bonding agent (3). Said textile mesh (5A) is coated on at least one face (A) thereof by a thermally-reactivating glue (3), to glue the mesh (5A) to an external element, characterised in that the viscosity of said glue (3), measured at a temperature of 230 °C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.. The invention further relates to textile meshes.

Description

GRILLE THERMO-ADHESIVE THERMO-ADHESIVE GRID
DOMAINE TECHNIQUETECHNICAL AREA
La présente invention se rapporte au domaine technique général des grilles textiles formées d'un réseau de fils de chaîne et trame, de telles grilles intervenant notamment en tant que renforts ou supports dans différentes applications industrielles.The present invention relates to the general technical field of textile grids formed of a network of warp and weft yarns, such grids acting in particular as reinforcements or supports in different industrial applications.
La présente invention concerne une grille textile formée par un réseau de fils croisés ou superposés non tissés comprenant au moins une nappe de fils de chaîne et au moins une nappe de fils de trame, les fils de chaîne et de trame étant liés entre eux par un liant, ladite grille textile étant enduite sur au moins une de ses faces par une colle réactivable thermiquement pour contrecoller la grille sur un élément externe, en vue par exemple de le renforcer.The present invention relates to a textile grid formed by a network of crossed or superimposed nonwoven threads comprising at least one ply of warp threads and at least one ply of weft threads, the warp and weft threads being linked together by a binder, said textile grid being coated on at least one of its faces with a thermally reactivable adhesive for laminating the grid on an external element, for example in order to reinforce it.
La présente invention concerne également tout produit industriel fini ou non fini incorporant une grille textile conforme à l'invention.The present invention also relates to any finished or unfinished industrial product incorporating a textile grid according to the invention.
La présente invention concerne également un procédé de fabrication d'une grille textile dans lequel on réalise un réseau de fils croisés ou superposés non tissés, comprenant au moins une nappe de fils de chaîne et au moins une nappe de fils de trame pour former une grille primitive, et dans lequel on enduit au moins une des faces de ladite grille primitive de colle réactivable thermiquement.The present invention also relates to a method of manufacturing a textile grid in which a network of crossed or superimposed nonwoven threads is produced, comprising at least one ply of warp threads and at least one ply of weft threads to form a grid. primitive, and in which at least one of the faces of said primitive grid is coated with thermally reactivatable adhesive.
La présente invention concerne enfin un dispositif pour mettre en oeuvre au moins une partie du procédé susmentionné. TECHNIQUE ANTERIEUREThe present invention finally relates to a device for implementing at least part of the above-mentioned method. PRIOR ART
Il est déjà connu de réaliser industriellement des grilles formées d'un réseau de fils croisés non tissés, les fils étant collés entre eux au niveau de leurs points de croisement par imprégnation avec un liant, du genre colle thermoplastique ou autre. Les grilles connues peuvent par exemple mettre en oeuvre au moins deux nappes de fils de chaîne superposées ou encore décalées, chaque paire de nappes ayant interposée entre elles au moins une nappe de fils de trame.It is already known to produce grids industrially formed from a network of crossed nonwoven threads, the threads being bonded together at their crossing points by impregnation with a binder, of the thermoplastic adhesive type or the like. The known grids can, for example, use at least two layers of warp yarns which are superimposed or even offset, each pair of plies having interposed between them at least one ply of weft son.
Selon ces réalisations connues, les fils de chaîne et les fils de trame sont liés entre eux à leurs croisements par un liant créant une série de points de collage, en vue d'obtenir une grille textile présentant une structure finie et stable sur le plan mécanique.According to these known embodiments, the warp threads and the weft threads are linked together at their crossings by a binder creating a series of bonding points, with a view to obtaining a textile grid having a finished structure and mechanically stable. .
Les grilles réalisées selon cette technique donnent généralement satisfaction et servent de renforts ou de supports dans des domaines techniques très variés tels que, par exemple, de manière non limitative, dans l'industrie du bâtiment en tant que supports pour parquets et céramiques, ou revêtements muraux et moquettes, dans l'industrie papetière, ou encore en tant qu'éléments de renforcement dans les mousses synthétiques ou autres.The grids produced according to this technique generally give satisfaction and serve as reinforcements or supports in very varied technical fields such as, for example, without limitation, in the building industry as supports for parquet and ceramics, or coatings wall and carpet, in the paper industry, or even as reinforcing elements in synthetic or other foams.
De façon générale, les grilles destinées à servir de renforts sont assemblées par collage sur la surface de l'élément à renforcer. Un tel assemblage est également appelé contrecollage. Ce contrecollage peut s'effectuer en utilisant un apport extérieur de colle.Generally, the grids intended to serve as reinforcements are assembled by bonding to the surface of the element to be reinforced. Such an assembly is also called laminating. This lamination can be done using an external supply of glue.
Dans le cas notamment des grilles décrites ci-avant, un tel apport de colle n'est pas nécessaire : le liant imprégnant la grille est apte à assurer cette fonction de collage. Il suffit dans ce cas de positionner la grille contre la surface de l'élément à renforcer, de réactiver thermiquement le liant à l'aide d'un appareil de chauffage, c'est à dire le porter à une température à laquelle il présente un caractère adhésif, ce qui va permettre la solidarisation de l'élément à renforcer et de la grille ; cette solidarisation reste effective une fois que le liant est revenu à une température inférieure à la température susdite.In the case in particular of the grids described above, such an addition of adhesive is not necessary: the binder impregnating the grid is capable of ensuring this bonding function. In this case, it suffices to position the grid against the surface of the element to be reinforced, to thermally reactivate the binder using a heating device, i.e. to bring it to a temperature at which it has an adhesive character, which will allow the joining of the 'element to reinforce and grid; this joining remains effective once the binder has returned to a temperature below the above temperature.
Néanmoins, il apparaît que les grilles textiles imprégnées d'un liant réactivable pour contrecollage connues à ce jour souffrent d'un certain nombre d'inconvénients, et notamment d'inconvénients liés à la température relativement importante nécessaire pour réactiver le liant de façon à lui conférer son caractère adhésif.Nevertheless, it appears that the textile grids impregnated with a reactivable binder for laminating known to date suffer from a certain number of drawbacks, and in particular drawbacks linked to the relatively high temperature necessary to reactivate the binder in such a way confer its adhesive character.
En effet, les liants utilisés jusqu'à ce jour sont généralement des colles polymères en phase aqueuse ou solvant réticulées ou non. La réactivation de telles colles nécessite des températures de l'ordre de 150°C à 300°C. De tels niveaux de température induisent donc des durées de contrecollage importantes, puisque fonction du temps nécessaire à l'appareil de chauffage pour atteindre la température de réactivation, étant entendu que plus cette température est haute, plus ce temps de montée en température sera important. De tels niveaux de température interdisent également le contrecollage sur certains matériaux qui ne les supporteraient pas. Il est ainsi notamment impossible de procéder à des contrecollage de telles grilles textiles sur des mousses synthétiques telles que celles entrant dans la fabrication de sièges automobiles, par exemple en polyéthylène ou en polyuréthane. De telles mousses sont en effet généralement altérées ou détruites à de tels niveaux de température. En dernier lieu, plus la température de réactivation est élevée, plus l'apport d'énergie que nécessite cette réactivation est important, nécessitant des appareillages lourds et donc coûteux. Ceci conduit à augmenter le prix de revient des produits renforcés obtenus, ce qui constitue un inconvénient sur le plan industriel.Indeed, the binders used to date are generally polymeric adhesives in aqueous phase or solvent crosslinked or not. The reactivation of such adhesives requires temperatures of the order of 150 ° C to 300 ° C. Such temperature levels therefore induce significant laminating times, since as a function of the time necessary for the heating device to reach the reactivation temperature, it being understood that the higher this temperature, the longer this temperature rise time will be. Such temperature levels also prohibit laminating on certain materials that would not support them. In particular, it is therefore impossible to laminate such textile grids to synthetic foams such as those used in the manufacture of automobile seats, for example made of polyethylene or polyurethane. Such foams are in fact generally altered or destroyed at such temperature levels. Finally, the higher the reactivation temperature, the greater the energy input required for this reactivation, requiring heavy equipment and therefore costly. This leads to an increase in the cost price of the reinforced products obtained, which constitutes an industrial disadvantage.
EXPOSE DE L'INVENTIONSTATEMENT OF THE INVENTION
Les objets assignés à la présente invention visent en conséquence à porter remède aux différents inconvénients des grilles textiles thermoréactivables de l'art antérieur mentionnés précédemment, et à proposer une nouvelle grille textile ayant des propriétés améliorées et qui soit d'une mise en oeuvre facile et d'un coût réduit, ladite grille étant formée par un réseau de fils croisés non tissés, et étant enduite par une colle réactivable thermiquement pour contrecoller la grille sur un élément externe.The objects assigned to the present invention therefore aim to remedy the various drawbacks of the heat-activated textile grids of the prior art mentioned above, and to propose a new textile grid having improved properties and which is easy to use and at a reduced cost, said grid being formed by a network of crossed non-woven threads, and being coated with a thermally reactivable glue to laminate the grid to an external element.
Un autre objet de l'invention vise à proposer une nouvelle grille textile enduite par une colle réactivable thermiquement qui soit apte au contrecollage sur la plupart des matériaux.Another object of the invention is to propose a new textile grid coated with a thermally reactivable adhesive which is suitable for laminating on most materials.
Un autre objet de l'invention vise à proposer une nouvelle grille textile enduite par une colle réactivable thermiquement susceptible d'améliorer la tenue mécanique et chimique générale de la grille.Another object of the invention is to propose a new textile grid coated with a thermally reactivable adhesive capable of improving the general mechanical and chemical resistance of the grid.
Un autre objet de l'invention vise à proposer une nouvelle grille textile autorisant un collage propre et sans solvant.Another object of the invention is to propose a new textile grid allowing a clean bonding without solvent.
Un autre objet de l'invention vise à proposer un nouveau procédé de fabrication d'une grille textile enduite de colle réactivable qui soit particulièrement simple et rapide à mettre en oeuvre. Un autre objet de l'invention vise à proposer un nouveau dispositif de mise en oeuvre du procédé conforme à l'invention qui permette de réaliser des grilles avec des forts taux de colle de façon simple et rapide.Another object of the invention is to propose a new method of manufacturing a textile grid coated with reactivable glue which is particularly simple and quick to implement. Another object of the invention is to propose a new device for implementing the method according to the invention which makes it possible to produce grids with high levels of glue in a simple and rapid manner.
Les objets assignés à l'invention sont atteints à l'aide d'une grille textile formée par un réseau de fils croisés non tissés, comprenant au moins une nappe de fils de chaîne et au moins une nappe de fils de trame, les fils de chaîne et de trame étant liés entre eux par un liant, ladite grille textile étant enduite sur au moins une de ses faces par une colle réactivable thermiquement pour contrecoller la grille sur un élément externe, caractérisée en ce que la viscosité de ladite colle, mesurée à une température de 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s.The objects assigned to the invention are achieved using a textile grid formed by a network of nonwoven cross-threads, comprising at least one layer of warp threads and at least one layer of weft threads, the threads of warp and weft being linked together by a binder, said textile grid being coated on at least one of its faces with a thermally reactivable glue to laminate the grid to an external element, characterized in that the viscosity of said glue, measured at a temperature of 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.
Les objets assignés à l'invention sont également atteints à l'aide d'un procédé de fabrication d'une grille conforme à l'invention caractérisé en ce qu'il comprend au moins :The objects assigned to the invention are also achieved using a method of manufacturing a grid according to the invention, characterized in that it comprises at least:
- une étape de croisement des fils de chaîne et de trame pour former une grille primitive,a step of crossing the warp and weft threads to form a primitive grid,
- une étape d'enduction où au moins une des faces de ladite grille primitive est enduite de colle réactivable thermiquement, dont la viscosité, mesurée à une température de 230°C selon la normea coating step where at least one of the faces of said primitive grid is coated with thermally reactivable adhesive, the viscosity of which is measured at a temperature of 230 ° C. according to the standard
ASTM-D3236-88, est inférieure ou égale à 40 Pa.s.ASTM-D3236-88, is less than or equal to 40 Pa.s.
Enfin, les objets assignés à l'invention sont également atteints par un dispositif de mise en oeuvre du procédé conforme à l'invention, caractérisé en ce qu'il comprend : - un bac destiné à contenir de la colle réactivable thermiquement dont la viscosité, mesurée à 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s, ledit bac étant chauffé de façon à maintenir la colle en fusion, et présentant au moins une ouverture, - un cylindre en rotation autour de son axe de symétrie, ledit cylindre étant agencé et positionnable relativement au bac de façon à s'alimenter continuellement, du fait de sa rotation, en colle en fusion au travers de ladite ouverture, et à déposer continuellement cette colle en fusion sur la face d'une grille textile à enduire de colle, - un moyen de convoyage pour amener ladite grille textile sensiblement en contact avec le cylindre.Finally, the objects assigned to the invention are also achieved by a device for implementing the method according to the invention, characterized in that it comprises: - a tank intended to contain thermally reactivable glue, the viscosity of which, measured at 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s, said tank being heated so as to keep the glue in melting, and having at least one opening, - a cylinder rotating around its axis of symmetry, said cylinder being arranged and positionable relative to the tank so as to continuously feed, due to its rotation, glue in fusion through of said opening, and continuously depositing this molten glue on the face of a textile grid to be coated with glue, - a conveyor means for bringing said textile grid substantially into contact with the cylinder.
DESCRIPTIF SOMMAIRE DES DESSINSSUMMARY OF DRAWINGS
D'autres objets et avantages particuliers de l'invention apparaîtront plus en détails à la lecture de la description qui suit, et à l'aide des dessins annexés ci-après, à titre purement illustratif et non limitatif, dans lesquels :Other particular objects and advantages of the invention will appear in more detail on reading the description which follows, and with the aid of the appended drawings below, purely by way of non-limiting illustration, in which:
- La figure 1 illustre, selon une vue de côté en coupe, un détail de réalisation de la structure d'une grille textile conforme à l'invention.- Figure 1 illustrates, in a side view in section, a detail of the structure of a textile grid according to the invention.
- La figure 2 illustre, selon une vue de dessus, un détail d'une grille conforme à l'invention.- Figure 2 illustrates, in a top view, a detail of a grid according to the invention.
- La figure 3 illustre, selon une vue schématique en coupe longitudinale, le principe de réalisation et de fonctionnement d'un dispositif de mise en oeuvre du procédé conforme à l'invention. - La figure 4 illustre un détail du dispositif représenté schématiquement à la figure 3 à une échelle agrandie.- Figure 3 illustrates, in a schematic view in longitudinal section, the principle of embodiment and operation of a device for implementing the method according to the invention. - Figure 4 illustrates a detail of the device shown schematically in Figure 3 on an enlarged scale.
MEILLEURE MANIERE DE REALISER L'INVENTIONBEST WAY TO IMPLEMENT THE INVENTION
Selon l'invention, la grille textile 5A conforme à l'invention est formée par un réseau de fils croisés non tissés, comprenant au moins une nappe de fils de chaîne 1 , 1 ', et au moins une nappe de fils de trame 2.According to the invention, the textile grid 5A according to the invention is formed by a network of nonwoven crossed threads, comprising at least one ply of warp threads 1, 1 ', and at least one ply of weft threads 2.
Les fils délimitent ainsi des zones vides, de telle sorte que la grille présente une structure ajourée.The wires thus delimit empty zones, so that the grid has an openwork structure.
De façon avantageuse, la grille textile conforme à l'invention comprend au moins deux nappes de fils de chaîne 1 , 1 ' entre lesquelles est interposée au moins une nappe de fils de trame 2.Advantageously, the textile grid according to the invention comprises at least two plies of warp threads 1, 1 ′ between which is interposed at least one ply of weft threads 2.
Tel que cela est bien connu de l'homme de l'art, la construction du réseau de fils de chaîne 1 , 1 ' et de fils de trame 2 est obtenue en décalant les fils de chaîne 1 , 1 ' et de trame 2 sans superposition (voir figure 2), ou au contraire en assurant une superposition des fils.As is well known to those skilled in the art, the construction of the network of warp threads 1, 1 'and weft threads 2 is obtained by shifting the warp threads 1, 1' and weft 2 without superposition (see Figure 2), or on the contrary by ensuring a superposition of the wires.
De la même manière, le réseau de fils de chaîne 1 et de trame 2 peut être obtenu avec un croisement des fils de chaîne et de trame à 90° (construction carrée), ou selon une inclinaison angulaire différente et par exemple bidirectionnelle ou tri-directionnelle.Likewise, the network of warp 1 and weft 2 threads can be obtained by crossing the warp and weft threads at 90 ° (square construction), or according to a different angular inclination, for example bidirectional or tri- directional.
A titre non limitatif, la contexture de la grille textile selon l'invention pourra varier de 0,4 fil par centimètre à 10 fils par centimètre, pour les fils de chaîne et de trame. A titre non limitatif, et comme cela est bien connu de l'homme du métier, tout type de fil textile couramment utilisé à ce jour dans la réalisation de grilles textiles pourra être utilisé, et par exemple des fils en verre (présentant une masse linéique pouvant par exemple varier de 11 à 544 tex) ou en polyester (présentant une masse linéique pouvant varier par exemple entre 78 Dtex et 1100 Dtex).Without limitation, the texture of the textile grid according to the invention may vary from 0.4 thread per centimeter to 10 threads per centimeter, for warp and weft threads. By way of non-limiting example, and as is well known to those skilled in the art, any type of textile thread commonly used to date in the production of textile grids may be used, and for example glass threads (having a linear mass can for example vary from 11 to 544 tex) or polyester (having a linear mass which can vary for example between 78 Dtex and 1100 Dtex).
Selon l'invention, les fils de chaîne 1 , 1 ' et de trame 2 sont liés entre eux par un liant créant une série de points de collage au niveau des intersections du réseau de fils.According to the invention, the warp 1, 1 ′ and weft 2 threads are linked together by a binder creating a series of bonding points at the intersections of the network of threads.
Au sens de l'invention, tout liant couramment utilisé à ce jour dans le domaine technique considéré pourra notamment être utilisé, et en particulier toute colle polymère du type liant polymère thermoplastique.Within the meaning of the invention, any binder commonly used to date in the technical field considered may in particular be used, and in particular any polymer adhesive of the thermoplastic polymer binder type.
A titre non limitatif, la liaison du réseau de fils formant la grille textile conforme à l'invention pourra ainsi être réalisée par des latex synthétiques (SBR), du PVAC, des plastisols de PVC, de l'alcool polyvinylique (PVA), des imprégnations thermocollantes classiques, des liants polyuréthanes ou des liants acryliques par exemple.By way of non-limiting example, the network of threads forming the textile grid in accordance with the invention can thus be made using synthetic latex (SBR), PVAC, PVC plastisols, polyvinyl alcohol (PVA), conventional iron-on impregnations, polyurethane binders or acrylic binders for example.
Selon l'invention, la grille textile 5A est enduite sur au moins une de ses faces A par une colle réactivable thermiquement 3 pour contrecoller la grille sur un élément externe.According to the invention, the textile grid 5A is coated on at least one of its faces A with a thermally reactivable adhesive 3 to laminate the grid to an external element.
Au sens de l'invention, une colle réactivable thermiquement est un matériau qui, lorsqu'il va être soumis à une température caractéristique dite de réactivation thermique, va présenter un caractère adhésif lui permettant de se solidariser avec un élément externe. Cette solidarisation est durable, une fois le matériau revenu à une température inférieure à ladite température de réactivation thermique.Within the meaning of the invention, a thermally reactivatable adhesive is a material which, when it is going to be subjected to a characteristic temperature known as thermal reactivation, will have an adhesive character allowing it to become integral with an external element. This solidarity is lasting, a times the material returned to a temperature below said thermal reactivation temperature.
Ainsi, le matériau formant colle réactivable peut présenter à température ambiante un caractère non adhésif et être à l'état solide, tandis que lorsqu'il est chauffé au moins à sa température de réactivation thermique, il prend la forme d'un liquide, qui peut être très visqueux, présentant un bon pouvoir adhésif.Thus, the reactivatable adhesive material can have a non-adhesive nature at room temperature and be in the solid state, while when it is heated to at least its thermal reactivation temperature, it takes the form of a liquid, which can be very viscous, with good adhesive power.
La réactivation thermique se fait à l'aide d'un moyen de chauffage qui peut être de tout type connu, et par exemple mettre en oeuvre des rayonnements haute fréquence ou infra-rouges, des phénomènes de conduction ou encore de convexion.The thermal reactivation is done using a heating means which can be of any known type, and for example using high frequency or infrared radiation, conduction or convection phenomena.
Selon une caractéristique essentielle de l'invention, la viscosité de la colle 3, mesurée à une température de 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s.According to an essential characteristic of the invention, the viscosity of the adhesive 3, measured at a temperature of 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.
De façon préférentielle, la viscosité de ladite colle, mesurée à une température de 200°C selon la norme ASTM-D3236-88, est inférieure ou égale à 30 Pa.s.Preferably, the viscosity of said adhesive, measured at a temperature of 200 ° C according to standard ASTM-D3236-88, is less than or equal to 30 Pa.s.
De façon encore plus préférentielle, la viscosité de ladite colle, mesurée à sa température d'application (dont la valeur est systématiquement disponible auprès du fabriquant) selon la norme ASTM-D3236-88, est inférieure ou égale à 30 Pa.s.Even more preferably, the viscosity of said adhesive, measured at its application temperature (the value of which is systematically available from the manufacturer) according to standard ASTM-D3236-88, is less than or equal to 30 Pa.s.
Une telle caractéristique de viscosité est représentative d'une colle qui est réactivable à des températures pouvant être relativement basses, et pouvant descendre par exemple jusqu'à 70°C. Ainsi, la grille textile 5A selon l'invention peut être contrecollée sans dommages sur des matériaux ne résistant pas à des températures élevées, et notamment des mousses synthétiques.Such a viscosity characteristic is representative of an adhesive which can be reactivated at temperatures which may be relatively low, and which may drop, for example, up to 70 ° C. Thus, the textile grid 5A according to the invention can be laminated without damage to materials which do not withstand high temperatures, and in particular synthetic foams.
Avantageusement, la colle 3 est de type « hot-melt ». Une colle de type « hot-melt » est une colle thermofusible 100%, dite encore 100% active, qui comprend un matériau thermoplastique susceptible de passer d'un état solide non adhésif à un état visqueux adhésif, et ce de façon réversible. L'état solide est obtenu lorsque le matériau est soumis à une température inférieure à une température caractéristique appelée température de réactivation thermique, laquelle peut varier par exemple entre 70°C et 180°C selon la formulation de la colle. Lorsque le matériau est soumis à une température supérieure ou égale à cette température de réactivation thermique, il se trouve dans l'état visqueux et adhésif mentionné précédemment.Advantageously, the adhesive 3 is of the “hot-melt” type. A “hot-melt” type adhesive is a 100% hot-melt adhesive, also called 100% active adhesive, which comprises a thermoplastic material capable of passing from a non-adhesive solid state to an adhesive viscous state, and this in a reversible manner. The solid state is obtained when the material is subjected to a temperature below a characteristic temperature called the thermal reactivation temperature, which can vary for example between 70 ° C. and 180 ° C. depending on the formulation of the adhesive. When the material is subjected to a temperature greater than or equal to this thermal reactivation temperature, it is in the viscous and adhesive state mentioned above.
Les colles « hot-melt » sont bien connues en tant que telles. Elles sont constituées d'un mélange de polymères incluant :Hot-melt adhesives are well known as such. They consist of a mixture of polymers including:
- un ou plusieurs polymères ou copolymères de haut poids moléculaire, par exemple du polyéthylènevinylacétate, du polyamide, du polyester, de l'époxy, du polyéthylène, - des cires du type paraffine de bas poids moléculaire- one or more polymers or copolymers of high molecular weight, for example polyethylene vinyl acetate, polyamide, polyester, epoxy, polyethylene, - waxes of the paraffin type of low molecular weight
(800-1 000 g.mol-1),(800-1000 g.mol- 1 ),
- des résines tackifiantes de type colophane de bas poids moléculaire,- low molecular weight rosin-type tackifying resins,
- des additifs, par exemple anti-UV ou anti-oxydants.- additives, for example anti-UV or antioxidants.
Elles permettent un collage propre et sans solvant, et sont utilisables avec de nombreux matériaux, qu'ils soient cellulaires ou pleins, tels que les polymères, dont les polyoléfines, les matériaux naturels, les métaux, les composites, les céramiques.They allow a clean and solvent-free bonding, and can be used with many materials, whether cellular or solid, such as polymers, including polyolefins, natural materials, metals, composites, ceramics.
Ainsi, la grille selon l'invention pourra être contrecollée sur la plupart des matériaux, de façon à former un complexe.Thus, the grid according to the invention can be laminated to most materials, so as to form a complex.
La grille selon l'invention est ainsi également susceptible d'être compatible avec des transformations secondaires ou finales du complexe, telles que par exemple un thermoformage du complexe.The grid according to the invention is thus also capable of being compatible with secondary or final transformations of the complex, such as for example thermoforming of the complex.
La grille textile selon l'invention pourra mettre en oeuvre tout type de colle « hot-melt » connu.The textile grid according to the invention can use any type of known “hot-melt” glue.
La grille textile 5A selon l'invention pourra être recouverte de colle réactivable thermiquement 3 sur au moins une de ses faces selon une masse surfacique (ou poids d'encollage) comprise par exemple entre 2 et 300 g/m2.The textile grid 5A according to the invention may be covered with thermally reactivable adhesive 3 on at least one of its faces according to a surface mass (or sizing weight) of for example between 2 and 300 g / m 2 .
De façon avantageuse, le rapport de la masse de colle 3 enduisant le réseau de fils sur la masse dudit réseau de fils pourra être compris entre 50 et 400 %, et de façon préférentielle entre 100 et 300 %.Advantageously, the ratio of the mass of glue 3 coating the network of wires to the mass of said network of wires may be between 50 and 400%, and preferably between 100 and 300%.
L'utilisation d'une colle 3 de type « hot-melt » permet ainsi de réaliser des dépôts de colle importants et uniformes, puisque la colle 3 est constituée entièrement de matière adhésive, et non d'un mélange adhésif-solvant.The use of an adhesive 3 of the “hot-melt” type thus makes it possible to produce large and uniform adhesive deposits, since the adhesive 3 consists entirely of adhesive material, and not of an adhesive-solvent mixture.
Cela permet de réaliser une couche de protection sensiblement étanche sur les fils de chaîne 1 , 1 ' et de trame 2. De façon préférentielle, le liant de la grille textile selon l'invention est formé par ladite colle réactivable thermiquement 3, ladite colle assurant ainsi une double fonction :This makes it possible to produce a substantially waterproof protective layer on the warp 1, 1 ′ and weft 2 yarns. Preferably, the binder of the textile grid according to the invention is formed by said thermally reactivable adhesive 3, said adhesive thus ensuring a double function:
- de tenue des fils, de façon à ce que la grille présente une structure finie et stable sur le plan mécanique (i.e. qui se tienne par elle-même, indépendamment de toute interaction avec un élément externe),- holding of the wires, so that the grid has a finite and mechanically stable structure (i.e. which stands by itself, independently of any interaction with an external element),
- et de collage lorsque la grille est mise en oeuvre en tant que renfort, et à cet effet est contrecollée sur l'élément à renforcer.- And bonding when the grid is used as reinforcement, and for this purpose is laminated to the element to be reinforced.
Il est ainsi inutile, dans ce cas de figure, de réaliser une imprégnation primaire de liant pour lier les fils de chaîne 1 , 1 ' et de trame 2 entre eux.It is thus unnecessary, in this case, to carry out a primary impregnation of binder to link the warp 1, 1 ′ and weft 2 yarns together.
De façon générale, les grilles selon l'invention présentent une résistance mécanique à la rupture comprise entre sensiblement 19 et 1970 Newtons sur 5 cm. L'enduction de colle du type « hot-melt » permet une amélioration de la résistance à la traction et à la déchirure de la grille. Elle permet également une amélioration du module de flexion et de la raideur de la grille.In general, the grids according to the invention have a mechanical resistance to rupture of between approximately 19 and 1970 Newtons over 5 cm. The coating of hot-melt type adhesive improves the tensile and tear strength of the grid. It also allows an improvement in the flexural modulus and the stiffness of the grid.
La grille textile 5A conforme à l'invention peut également être utilisée avantageusement comme renfort de mousses de fauteuil automobile, puisque la température de réactivation de la colle est compatible avec la température que peuvent endurer de telles mousses. Cela permet de produire des fauteuils résistants mécaniquement tout en leur conférant une connotation haut de gamme.The textile grid 5A in accordance with the invention can also be advantageously used as reinforcement for automobile wheelchair foam, since the reactivation temperature of the adhesive is compatible with the temperature that such foam can endure. This makes it possible to produce mechanically resistant armchairs while giving them a high-end connotation.
La grille textile selon l'invention peut être utilisée pour remplacer les renforts en polychlorure de vinyle, habituellement utilisés par exemple pour les sièges automobiles. Une telle utilisation présente l'avantage important que, en cas de combustion (accidentelle ou en fin de vie du produit) du siège, la grille ne dégage pas de produits toxiques, alors que le polychlorure de vinyle dégage du chlore.The textile grid according to the invention can be used to replace the polyvinyl chloride reinforcements, usually used for example for car seats. Such use has the important advantage that, in the event of combustion (accidental or end of product life) of the seat, the grid does not release toxic products, while polyvinyl chloride releases chlorine.
La grille textile conforme à l'invention sera également particulièrement bien adaptée pour assembler des revêtements de sols du type carrelage, parquet, ou pour renforcer des chiffons d'essuyage. Elle pourra être également utilisée pour la réalisation d'adhésifs cache-fissure.The textile grid according to the invention will also be particularly well suited for assembling floor coverings of the tiling, parquet type, or for reinforcing wiping cloths. It can also be used for the production of crack cover adhesives.
La grille selon l'invention permet ainsi d'être adaptée aux conditions d'usage du produit final. Elle permet également un recyclage des produits renforcés en fin de vie, puisque du fait du caractère réversible de la colle utilisée (caractère que n'ont pas les colles aqueuses), la grille est séparable à volonté de l'élément qu'elle renforce.The grid according to the invention thus makes it possible to be adapted to the conditions of use of the final product. It also allows recycling of reinforced products at the end of their life, since due to the reversible nature of the glue used (character which aqueous glues do not have), the grid can be separated at will from the element it reinforces.
Selon l'invention, le procédé de fabrication d'une grille textile conforme à l'invention et telle que décrite précédemment met en oeuvre une série d'étapes de réalisation, dont au moins :According to the invention, the process for manufacturing a textile grid according to the invention and as described above implements a series of production steps, at least of which:
- une étape de croisement (non représentée) des fils de chaîne 1 , 1 ' et de trame 2 pour former une grille primitive 5 ; une telle étape de réalisation est bien connue de l'homme du métier, et peut par exemple être réalisée par toute méthode appropriée,a step of crossing (not shown) the warp 1, 1 ′ and weft 2 threads to form a primitive grid 5; such a production step is well known to those skilled in the art, and can for example be carried out by any suitable method,
- une étape d'enduction (voir figures 3 et 4), où au moins une des faces A de ladite grille primitive 5 est enduite de colle 3 réactivable thermiquement dont la viscosité, mesurée à une température de 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s, ou de façon plus préférentielle est inférieure ou égale à 30 Pa.s, lorsqu'elle est mesurée à 200°C selon la même norme. De façon préférentielle, l'étape d'enduction est réalisée immédiatement après l'étape de croisement.a coating step (see FIGS. 3 and 4), where at least one of the faces A of said primitive grid 5 is coated with thermally reactivable adhesive 3 whose viscosity, measured at a temperature of 230 ° C. according to the ASTM standard- D3236-88, is less than or equal to 40 Pa.s, or more preferably is less than or equal to 30 Pa.s, when it is measured at 200 ° C according to the same standard. Preferably, the coating step is carried out immediately after the crossing step.
Ainsi, à l'issue de l'étape de croisement des fils, la grille 5 ne se tient pas d'elle-même, et l'étape d'enduction permet à la fois de conférer à la grille 5 une tenue mécanique propre et de la doter d'une colle réactivable thermiquement, en vue d'un contre-collage ultérieur.Thus, at the end of the wire crossing step, the grid 5 does not stand by itself, and the coating step makes it possible both to give the grid 5 a clean mechanical strength and to provide it with a thermally reactivable glue, for subsequent lamination.
Dans ce cas, la colle 3 réactivable thermiquement fait donc à la fois office de liant et de colle de contre-collage.In this case, the thermally reactivable glue 3 therefore acts both as a binder and as a lamination glue.
De façon préférentielle, lors de l'étape d'enduction, les fils de chaîne 1 , 1 ' et de trame 2 sont recouverts simultanément de colle 3.Preferably, during the coating step, the warp 1, 1 ′ and weft 2 threads are simultaneously covered with glue 3.
Avantageusement, ladite colle 3 est de type « hot-melt ».Advantageously, said adhesive 3 is of the “hot-melt” type.
Avantageusement, lors de l'étape d'enduction, la face A de la grille primitive 5 est enduite de colle 3 réactivable thermiquement, par passage tangentiel contre au moins une partie de la surface latérale 7A d'un cylindre rotatif 7 enduite de ladite colle 3 en fusion.Advantageously, during the coating step, the face A of the primitive grid 5 is coated with glue 3 which can be reactivated thermally, by tangential passage against at least part of the lateral surface 7A of a rotary cylinder 7 coated with said glue 3 in fusion.
L'utilisation d'un cylindre 7 permet une application « au rouleau », qui autorise une dépose de colle sensiblement homogène et régulière sur la grille primitive 5, sans bourrelet.The use of a cylinder 7 allows an application "with the roller", which allows a deposit of substantially uniform and regular adhesive on the primitive grid 5, without bead.
La mise en oeuvre d'un cylindre 7 permet d'éviter les inconvénients des technologies classiques d'enduction de produits de type « hot-melts », tels que les machines à « buses à lèvres ». De telles machines, si elles peuvent être utilisées avec succès pour enduire des supports fermés, tels que des panneaux de papier ou de tissu sur de grandes largeurs, sont cependant inefficaces pour enduire sur des largeurs convenables des supports ouverts, avec une faible tenue mécanique propre, telle qu'une grille primitive, sans occasionner des bourrelets de colle qui rendent le produit très difficilement exploitable.The use of a cylinder 7 makes it possible to avoid the drawbacks of conventional technologies for coating “hot-melt” type products, such as machines with “lip nozzles”. Such machines, if they can be successfully used for coating closed supports, such as paper or fabric panels over large widths, are however ineffective for coating open substrates over suitable widths, with a low inherent mechanical strength, such as a primitive grid, without causing beads of glue which make the product very difficult to use.
Selon une variante du procédé selon l'invention, une étape de liaison primaire intervient entre l'étape de croisement des fils et l'étape d'enduction. Lors de cette étape de liaison primaire, la grille primitive 5 est imprégnée par un liant, de façon à lier les fils de trame 2 et de chaîne 1 entre eux. Ainsi, un procédé selon cette variante met en oeuvre, après l'étape de liaison primaire, une grille possédant une tenue mécanique propre conférée par l'imprégnation primaire de liant ; l'étape d'enduction, dans ce cas, a uniquement pour objet de doter la grille d'une couche de colle réactivable thermiquement.According to a variant of the method according to the invention, a primary bonding step occurs between the step of crossing the wires and the coating step. During this primary connection step, the primitive grid 5 is impregnated with a binder, so as to bond the weft 2 and warp 1 yarns together. Thus, a method according to this variant implements, after the primary bonding step, a grid having its own mechanical strength imparted by the primary impregnation of binder; the coating step, in this case, is only intended to provide the grid with a layer of thermally reactivable adhesive.
L'étape de liaison primaire peut être réalisée par tout procédé de l'art antérieur, qui sont bien connus de l'homme du métier.The primary bonding step can be carried out by any method of the prior art, which are well known to those skilled in the art.
Tout liant classiquement utilisé pour une telle application peut être mis en oeuvre lors de cette étape, et notamment les liants formés par une colle polymère, ou ceux mentionnés précédemment.Any binder conventionally used for such an application can be used during this step, and in particular the binders formed by a polymer adhesive, or those mentioned above.
L'invention concerne également un dispositif de mise en oeuvre du procédé conforme à l'invention.The invention also relates to a device for implementing the method according to the invention.
Ce dispositif comprend :This device includes:
- un bac 6 destiné à contenir de la colle 3 réactivable thermiquement dont la viscosité, mesurée à 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s, et de façon préférentielle est inférieure ou égale à 30 Pa.s à 200°C, ledit bac 6 étant chauffé par tout moyen approprié, de façon à maintenir la colle 3 en fusion, et présentant au moins une ouverture,- a tank 6 intended to contain glue 3 which can be reactivated thermally, the viscosity of which, measured at 230 ° C. according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s, and so preferential is less than or equal to 30 Pa.s at 200 ° C., said tank 6 being heated by any suitable means, so as to keep the glue 3 in fusion, and having at least one opening,
- un cylindre 7 en rotation autour de son axe de symétrie X, ledit cylindre 7 étant agencé et positionnable relativement au bac 6, de façon à s'alimenter continuellement, du fait de sa rotation, en colle 3 en fusion au travers de ladite ouverture, et à déposer continuellement cette colle 3 en fusion sur la face A d'une grille textile 5 à enduire de colle, - un moyen de convoyage (non représenté) pour amener ladite grille 5 sensiblement en contact avec le cylindre 7.- A cylinder 7 rotating around its axis of symmetry X, said cylinder 7 being arranged and positionable relative to the tank 6, so as to continuously feed, due to its rotation, glue 3 molten through said opening , and continuously depositing this glue 3 in fusion on the face A of a textile grid 5 to be coated with glue, - a conveying means (not shown) for bringing said grid 5 substantially into contact with the cylinder 7.
Avantageusement, le cylindre 7 est également chauffé à une température par exemple comprise entre 70 et 300°C, et de façon préférentielle entre 100°C et 220°C.Advantageously, the cylinder 7 is also heated to a temperature for example between 70 and 300 ° C, and preferably between 100 ° C and 220 ° C.
Ce chauffage peut être réalisé par tout moyen connu.This heating can be achieved by any known means.
Avantageusement, le cylindre 7 en rotation est agencé de façon à ce que toute zone d'au moins une partie de sa surface latérale 7A soit alternativement en contact :Advantageously, the rotating cylinder 7 is arranged so that any zone of at least part of its lateral surface 7A is alternately in contact:
- d'une part avec la colle 3 en fusion, au travers de ladite ouverture, de façon à ce que la partie de la surface latérale 7A s'enduise de colle,on the one hand with the glue 3 in fusion, through said opening, so that the part of the lateral surface 7A is coated with glue,
- et d'autre part avec la face A de la grille textile 5 à enduire de colle, amenée selon un mouvement de translation longitudinal (dont la direction est matérialisée par la flèche 8) sensiblement tangentiellement à la surface latérale, de façon à déposer au moins une partie de la colle enduisant ladite partie de la surface latérale 7A sur ladite face A.- And on the other hand with the face A of the textile grid 5 to be coated with glue, brought in a longitudinal translational movement (the direction of which is materialized by the arrow 8) substantially tangentially to the lateral surface, so as to deposit at less a part of the glue coating said part of the lateral surface 7A on said face A.
De façon préférentielle, tel que cela est représenté aux figures 3 et 4, le cylindre 7 est positionné entre l'ouverture et la face A de la grille à enduire de colle 3.Preferably, as shown in FIGS. 3 and 4, the cylinder 7 is positioned between the opening and the face A of the grid to be coated with glue 3.
Le cylindre 7 est animé d'un mouvement de rotation (matérialisé par la flèche 9) autour de son axe de symétrie X, qui confère à sa surface latérale 7A une certaine vitesse linéaire. Le moyen de convoyage, qui peut être de tout type connu (par exemple un tapis roulant), confère à la grille 5 à enduire de colle un mouvement de translation longitudinal qui s'effectue selon une certaine vitesse de déplacement.The cylinder 7 is driven by a rotational movement (materialized by the arrow 9) around its axis of symmetry X, which gives its lateral surface 7A a certain linear speed. The conveying means, which can be of any known type (for example a conveyor belt), gives the grid 5 to be coated with adhesive a longitudinal translational movement which takes place at a certain speed of movement.
De façon préférentielle, le mouvement de translation longitudinal 8 s'effectue selon une vitesse de déplacement qui est sensiblement égale à la vitesse linéaire de la surface latérale 7A du cylindre. De cette façon, la quantité de colle déposée sur les fils de chaîne est sensiblement égale à la quantité déposée sur les fils de trame. La différence de vitesse linéaire entre la surface latérale 7A du cylindre 7 et la grille primitive 5 à enduire permet d'obtenir une épaisseur E1 de colle sur les fils de chaîne 1 , 1 ' qui est différente de l'épaisseur E2 de colle sur les fils de trame 2.Preferably, the longitudinal translational movement 8 takes place at a displacement speed which is substantially equal to the linear speed of the lateral surface 7A of the cylinder. In this way, the quantity of glue deposited on the warp threads is substantially equal to the quantity deposited on the weft threads. The difference in linear speed between the lateral surface 7A of the cylinder 7 and the primitive grid 5 to be coated makes it possible to obtain a thickness E1 of adhesive on the warp threads 1, 1 ′ which is different from the thickness E2 of adhesive on the weft yarn 2.
Le bac 6 est quant à lui constitué d'un corps 6C doté d'une racle 6A pour calibrer l'enduction du cylindre, c'est à dire pour piloter l'épaisseur E de colle se déposant sur la surface latérale 7A du cylindre rotatif 7. Une deuxième racle 6B opposée à la première permet de fermer le bac 6 en coopération avec la première racle 6A, lors des arrêts machines. Il est bien sûr envisageable de concevoir un dispositif mettant en oeuvre deux cylindres pour enduire une grille primitive 5 de colle 3 sur ses deux faces, simultanément ou non, sans sortir du cadre de l'invention.The tank 6 is in turn made up of a body 6C provided with a doctor blade 6A for calibrating the coating of the cylinder, that is to say for controlling the thickness E of adhesive depositing on the lateral surface 7A of the rotary cylinder. 7. A second doctor blade 6B opposite the first makes it possible to close the tank 6 in cooperation with the first doctor blade 6A, during machine stops. It is of course conceivable to design a device using two cylinders to coat a primitive grid 5 of glue 3 on its two faces, simultaneously or not, without departing from the scope of the invention.
Il est intéressant de noter que, dans la plupart des cas, les grilles textiles sont suffisamment fines pour qu'une enduction sur une seule face suffise pour obtenir une grille enduite sur ses deux faces de colle.It is interesting to note that, in most cases, the textile grids are thin enough that a coating on one side is sufficient to obtain a grid coated on both sides with glue.
Le dispositif selon l'invention permet ainsi d'enduire par exemple des grilles dont la largeur peut varier entre 0,2 et 5 m, à une vitesse comprise par exemple entre 0,4 et 150 m par minute. Le pilotage des différentiels de vitesse linéaire entre le cylindre et la grille, c'est à dire le pilotage de la différence entre la vitesse linéaire du cylindre et la vitesse de déplacement de la grille, permet de contrôler la répartition du dépôt de colle entre les fils de chaîne et les fils de trame, en évitant tout bourrelet non souhaité.The device according to the invention thus makes it possible to coat, for example, grids whose width can vary between 0.2 and 5 m, at a speed of, for example, between 0.4 and 150 m per minute. The control of the linear speed differentials between the cylinder and the grid, that is to say the control of the difference between the linear speed of the cylinder and the speed of movement of the grid, makes it possible to control the distribution of the adhesive deposit between the warp and weft threads, avoiding any unwanted bead.
POSSIBILITE D'APPLICATION INDUSTRIELLEPOSSIBILITY OF INDUSTRIAL APPLICATION
L'invention trouve son application industrielle dans le domaine des grilles textiles intervenant notamment en tant que renforts ou supports. The invention finds its industrial application in the field of textile grids intervening in particular as reinforcements or supports.

Claims

REVENDICATIONS
- Grille textile (5A) formée par un réseau de fils croisés non tissés, comprenant au moins une nappe de fils de chaîne (1 , 1 ') et au moins une nappe de fils de trame (2), les fils de chaîne (1 ,1 ') et de trame (2) étant liés entre eux par un liant (3), ladite grille textile (5A) étant enduite sur au moins une de ses faces (A) par une colle réactivable thermiquement (3) pour contrecoller la grille (5A) sur un élément externe, caractérisée en ce que la viscosité de ladite colle (3), mesurée à une température de 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s.- Textile grid (5A) formed by a network of nonwoven crossed threads, comprising at least one ply of warp threads (1, 1 ') and at least one ply of weft threads (2), the warp threads (1 , 1 ') and weft (2) being linked together by a binder (3), said textile grid (5A) being coated on at least one of its faces (A) with a thermally reactivable adhesive (3) to laminate the grid (5A) on an external element, characterized in that the viscosity of said adhesive (3), measured at a temperature of 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s.
- Grille textile (5A) selon la revendication 1 caractérisée en ce qu'elle comprend au moins deux nappes de fils de chaîne (1 , 1 ') entre lesquelles est interposée ladite au moins une nappe de fils de trame (2).- Textile grid (5A) according to claim 1 characterized in that it comprises at least two plies of warp threads (1, 1 ') between which said at least one ply of weft threads (2) is interposed.
- Grille textile (5A) selon la revendication 1 ou 2 caractérisée en ce que la viscosité de ladite colle (3), mesurée à une température de 200°C selon la norme ASTM-D3236-88, est inférieure ou égale à 30 Pa.s.- Textile grid (5A) according to claim 1 or 2 characterized in that the viscosity of said adhesive (3), measured at a temperature of 200 ° C according to standard ASTM-D3236-88, is less than or equal to 30 Pa. s.
- Grille textile (5A) selon l'une des revendications 1 à 3 caractérisée en ce que la colle (3) est du type « hot-melt ».- Textile grid (5A) according to one of claims 1 to 3 characterized in that the adhesive (3) is of the "hot-melt" type.
- Grille textile (5A) selon l'une des revendications 1 à 4 caractérisée en ce que les fils de trame (2) et/ou de chaîne (1 , 1 ') sont en verre.- Textile grid (5A) according to one of claims 1 to 4 characterized in that the weft son (2) and / or warp (1, 1 ') are made of glass.
- Grille textile (5A) selon l'une des revendications 1 à 4 caractérisée en ce que les fils de trame (2) et/ou de chaîne (1 , 1 ') sont en polyester. - Grille textile (5A) selon l'une des revendications 1 à 6 caractérisée en ce que la colle (3) recouvre au moins une des faces (A) de la grille, selon une masse surfacique comprise entre 2 et 300 g/m2.- Textile grid (5A) according to one of claims 1 to 4 characterized in that the weft son (2) and / or warp (1, 1 ') are made of polyester. - Textile grid (5A) according to one of claims 1 to 6 characterized in that the adhesive (3) covers at least one of the faces (A) of the grid, according to a surface mass of between 2 and 300 g / m 2 .
- Grille textile (5A) selon l'une des revendications 1 à 7 caractérisée en ce que le liant est une colle polymère.- Textile grid (5A) according to one of claims 1 to 7 characterized in that the binder is a polymer adhesive.
- Grille textile selon l'une des revendications 1 à 7 caractérisée en ce que le liant est formé par la colle réactivable thermiquement (3).- Textile grid according to one of claims 1 to 7 characterized in that the binder is formed by the thermally reactivable adhesive (3).
-Procédé de fabrication d'une grille conforme à l'une des revendications 1 à 9 caractérisé en ce qu'il comprend au moins :-Process of manufacturing a grid according to one of claims 1 to 9 characterized in that it comprises at least:
- une étape de croisement des fils de chaîne (1 , V) et de trame (2) pour former une grille primitive (5),a step of crossing the warp (1, V) and weft (2) threads to form a primitive grid (5),
- une étape d'enduction où au moins une des faces (A) de ladite grille primitive (5) est enduite de colle réactivable thermiquement (3) dont la viscosité, mesurée à une température de 230°C selon la norme ASTM- D3236-88, est inférieure ou égale à 40 Pa.s.a coating step where at least one of the faces (A) of said primitive grid (5) is coated with thermally reactivable adhesive (3) whose viscosity, measured at a temperature of 230 ° C. according to standard ASTM- D3236- 88, is less than or equal to 40 Pa.s.
-Procédé selon la revendication 10 caractérisé en ce que la viscosité de ladite colle (3), mesurée à 200°C, est inférieure ou égale à 30 Pa.s.-A method according to claim 10 characterized in that the viscosity of said adhesive (3), measured at 200 ° C, is less than or equal to 30 Pa.s.
-Procédé de fabrication selon la revendication 10 ou 11 caractérisé en ce que la colle (3) est de type « hot-melt ».-Manufacturing method according to claim 10 or 11 characterized in that the adhesive (3) is of the "hot-melt" type.
-Procédé selon l'une des revendications 10 à 12 caractérisé en ce que lors de l'étape d'enduction, la face de la grille primitive (5) est enduite de colle réactivable thermiquement (3), par passage tangentiel contre au moins une partie de la surface latérale (7A) d'un cylindre rotatif (7) enduite de ladite colle (3) en fusion.-A method according to one of claims 10 to 12 characterized in that during the coating step, the face of the primitive grid (5) is coated with thermally reactivatable adhesive (3), by tangential passage against the at least a part of the lateral surface (7A) of a rotary cylinder (7) coated with said glue (3) in fusion.
-Procédé selon l'une des revendications 10 à 13 caractérisé en ce qu'il comprend une étape de liaison primaire intervenant entre l'étape de croisement des fils et l'étape d'enduction, où la grille primitive (5) est imprégnée par un liant, de façon à lier les fils de trame (2) et de chaîne (1 , l') entre eux.-A method according to one of claims 10 to 13 characterized in that it comprises a primary connection step intervening between the step of crossing the wires and the coating step, where the primitive grid (5) is impregnated with a binder, so as to bind the weft (2) and warp (1, l) threads together.
-Procédé selon la revendication 14 caractérisé en ce que le liant est une colle polymère.-A method according to claim 14 characterized in that the binder is a polymer adhesive.
-Dispositif de mise en œuvre d'un procédé conforme à l'une des revendications 10 à 13 caractérisé en ce qu'il comprend :-A device for implementing a method according to one of claims 10 to 13 characterized in that it comprises:
- un bac (6) destiné à contenir de la colle réactivable thermiquement (3) dont la viscosité, mesurée à 230°C selon la norme ASTM-D3236-88, est inférieure ou égale à 40 Pa.s, ledit bac (6) étant chauffé de façon à maintenir la colle (3) en fusion, et présentant au moins une ouverture,- a tank (6) intended to contain thermally reactivable adhesive (3) whose viscosity, measured at 230 ° C according to standard ASTM-D3236-88, is less than or equal to 40 Pa.s, said tank (6) being heated so as to keep the adhesive (3) in fusion, and having at least one opening,
- un cylindre (7) en rotation autour de son axe de symétrie (X), ledit cylindre (7) étant agencé et positionnable relativement au bac (6) de façon à s'alimenter continuellement, du fait de sa rotation, en colle (3) en fusion au travers de ladite ouverture, et à déposer continuellement cette colle (3) en fusion sur la face (A) d'une grille textile (5) à enduire de colle,- a cylinder (7) rotating around its axis of symmetry (X), said cylinder (7) being arranged and positionable relative to the tank (6) so as to continuously feed, due to its rotation, glue ( 3) in fusion through said opening, and in continuously depositing this adhesive (3) in fusion on the face (A) of a textile grid (5) to be coated with adhesive,
- un moyen de convoyage pour amener ladite grille textile (5) sensiblement en contact avec le cylindre (7). -Dispositif selon la revendication 16 caractérisé en ce que le cylindre (7) en rotation est agencé de façon à ce que toute zone d'au moins une partie de sa surface latérale (7 A) soit alternativement en contact :- Conveying means for bringing said textile grid (5) substantially into contact with the cylinder (7). -A device according to claim 16 characterized in that the rotating cylinder (7) is arranged so that any zone of at least part of its lateral surface (7 A) is alternately in contact:
- d'une part avec la colle (3) en fusion, au travers de ladite ouverture, de façon à ce que la partie de la surface latérale (7A) s'enduise de colle (3) ,on the one hand with the glue (3) in fusion, through said opening, so that the part of the lateral surface (7A) is coated with glue (3),
- et d'autre part avec la face (A) de la grille textile (5) à enduire de colle, amenée selon un mouvement de translation longitudinal (8) sensiblement tangentiellement à la surface latérale (7A), de façon à déposer au moins une partie de la colle (3) enduisant ladite partie de la surface latérale (7 A) sur ladite face (A).- And secondly with the face (A) of the textile grid (5) to be coated with glue, brought in a longitudinal translational movement (8) substantially tangentially to the lateral surface (7A), so as to deposit at least a part of the glue (3) coating said part of the lateral surface (7 A) on said face (A).
-Dispositif selon la revendication 17 caractérisé en ce que le cylindre (7) est positionné entre l'ouverture et la face (A) de la grille (5) à enduire de colle.-A device according to claim 17 characterized in that the cylinder (7) is positioned between the opening and the face (A) of the grid (5) to be coated with glue.
-Dispositif selon la revendication 17 ou 18 caractérisé en ce que le mouvement de translation longitudinal (8) s'effectue selon une vitesse qui est sensiblement égale à la vitesse linéaire de la surface latérale (7 A) du cylindre. -A device according to claim 17 or 18 characterized in that the longitudinal translational movement (8) is carried out at a speed which is substantially equal to the linear speed of the lateral surface (7 A) of the cylinder.
EP03740560A 2002-04-03 2003-04-03 Thermo-adhesive mesh Withdrawn EP1499769A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0204185A FR2838141B1 (en) 2002-04-03 2002-04-03 THERMO-ADHESIVE GRID
FR0204185 2002-04-03
PCT/FR2003/001047 WO2003083198A1 (en) 2002-04-03 2003-04-03 Thermo-adhesive mesh

Publications (1)

Publication Number Publication Date
EP1499769A1 true EP1499769A1 (en) 2005-01-26

Family

ID=28052099

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03740560A Withdrawn EP1499769A1 (en) 2002-04-03 2003-04-03 Thermo-adhesive mesh

Country Status (7)

Country Link
US (1) US20060035547A1 (en)
EP (1) EP1499769A1 (en)
JP (1) JP2005527711A (en)
AU (1) AU2003258849A1 (en)
CA (1) CA2481249A1 (en)
FR (1) FR2838141B1 (en)
WO (1) WO2003083198A1 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0605723D0 (en) * 2006-03-23 2006-05-03 3M Innovative Properties Co Powder filling processes
FI20060569A0 (en) * 2006-06-08 2006-06-08 Walki Wisa Oy Film product and process for its preparation
JP2010148335A (en) * 2008-12-22 2010-07-01 Sumitomo Wiring Syst Ltd Net-like protection material for wire harness and method of manufacturing the same
EP2612755B1 (en) * 2010-08-31 2019-03-20 Sekisui Polymatech Co., Ltd. Thermally conductive sheet
TWI663311B (en) * 2014-04-29 2019-06-21 Low & Bonar B. V. Carrier material for vinyl floor covering and composite product comprising the same
CN104911787B (en) * 2015-06-15 2016-08-24 张光明 A kind of production Apparatus and method for intersecting woven type cloth imitating paper grid gauze

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2291858A1 (en) * 1974-11-21 1976-06-18 Deport Jacques Flexible unarmoured material adhesive coating process - uses reinforcing grille coated with glue together with protective strip
US4460633A (en) * 1981-12-16 1984-07-17 Kurashiki Boseki Kabushiki Kaisha Non-woven reinforcement for composite
FR2526818A1 (en) * 1982-05-12 1983-11-18 Chomarat Et Cie Ets Fils NON-WOVEN TEXTILE GRILLE
EP0252220B1 (en) * 1986-07-09 1992-07-08 Toru Itoi Method of manufacturing fabric samples
JPS6388078A (en) * 1986-10-02 1988-04-19 Canon Inc Roll coater for hot melt adhesive
JP2608414B2 (en) * 1987-08-06 1997-05-07 富士写真フイルム株式会社 Magneto-optical recording medium
DE3835929A1 (en) * 1988-10-21 1990-04-26 Kirson Gmbh Process for mutually joining lattice threads
JPH04316664A (en) * 1991-04-08 1992-11-09 Uenoyama Kiko Kk Device for monitoring bad finishing phenomenon of web
JPH04317764A (en) * 1991-04-15 1992-11-09 Nec Corp Hot melt coater
US5277957A (en) * 1991-09-09 1994-01-11 Orcon Corporation Film reinforced with yarn coated with hot melt adhesive
EP0552573B1 (en) * 1992-01-22 2000-05-17 Isover Saint-Gobain Fire-resistant mineral fibre panel
FR2780740B1 (en) * 1998-07-06 2000-09-29 Daniel Doligez ANTI-HUMIDITY COMPLEX OF FIBER GRID AND PLASTIC FILM, FOR ASPHALTS APPLIED INDEPENDENCE ON SIDEWALK TYPE SUPPORTS, ROOFS
ITPS990004A1 (en) * 1999-02-16 2000-08-16 PROCEDURE FOR THE CONSTRUCTION OF TAMBOURED PANELS AND MACHINE FOR THE REALIZATION OF SUCH PANELS
DE29904191U1 (en) * 1999-03-09 1999-05-27 Pott Richard Warp thread fiber layer
FR2800101B1 (en) * 1999-10-25 2002-04-05 Chomarat & Cie NON WOVEN GRID USABLE AS REINFORCEMENT REINFORCEMENT
FR2802554B1 (en) * 1999-12-17 2002-03-01 Chavanoz Ind REDUCED THICKNESS TEXTILE GRID
US6838163B2 (en) * 2001-04-12 2005-01-04 Milliken & Company Composite facer for wallboards

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO03083198A1 *

Also Published As

Publication number Publication date
US20060035547A1 (en) 2006-02-16
FR2838141B1 (en) 2004-09-10
FR2838141A1 (en) 2003-10-10
WO2003083198A1 (en) 2003-10-09
CA2481249A1 (en) 2003-10-09
JP2005527711A (en) 2005-09-15
AU2003258849A1 (en) 2003-10-13

Similar Documents

Publication Publication Date Title
CA2687830C (en) Method for making composite parts having at least one curved area and resulting parts
EP2595795B1 (en) Novel intermediate reinforcing material consisting of an array of spaced-apart yarns/webs, process using the material and composite part obtained by the process
EP1998953B1 (en) Pprocess for producing a stampable reinforced composite semi-finished product
EP1685952B1 (en) Textile composite for mechanical reinforcement of a bitumen based sealant
EP2035626B1 (en) Composite reinforcement or geotextile product and its manufacturing process
EP0792591A1 (en) Thermobonded lining material and method for its manufacture
EP2657385B1 (en) Textile reinforcement framework and method for manufacturing same
EP1499769A1 (en) Thermo-adhesive mesh
EP1466045A2 (en) Fibrous structure which is used to produce composite materials
FR2746264A1 (en) METHOD FOR MANUFACTURING THERMAL-STICKING LINING AND THERMAL-STICKING LINING THUS OBTAINED
FR3065392A1 (en) METHOD FOR MANUFACTURING A STRUCTURAL PART FOR A MOTOR VEHICLE HAVING IMPROVED FINISHES
WO1998044187A1 (en) Composite sheeting, floor covering comprising said sheeting, and corresponding manufacturing processes
EP1111114B2 (en) Textile mesh with a reduced thickness
CA2423808A1 (en) New reinforcement product
EP1226299B1 (en) Non-woven mesh used as a reinforcing frame
FR2848227A1 (en) Textile material for use as reinforcing layer has high ratio of weft yarns to warp yarns and laid at a non-perpendicular angle to one another
EP1692334A1 (en) Fibre-based reinforcing product and production method thereof
FR2834303A1 (en) FIBROUS COMPLEX WITH DECORATED SIDE FOR PRODUCING COMPOSITE PARTS AND COMPOSITE PARTS USING THE SAME
LU84387A1 (en) APPARATUS FOR THE MANUFACTURE OF FABRICS HAVING BONDED BY A HOT ADHESIVE
FR2780740A1 (en) ANTI-HUMIDITY COMPLEX OF FIBER GRID AND PLASTIC FILM, FOR ASPHALTS APPLIED INDEPENDENCE ON SIDEWALK TYPE SUPPORTS, ROOFS
FR2918920A1 (en) Composite material e.g. article, manufacturing method for e.g. aerospace, involves applying twist to reinforcement thread to compensate length differences of extreme paths of thread on either side of width

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20041102

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL LT LV MK

18W Application withdrawn

Effective date: 20080410

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

R18W Application withdrawn (corrected)

Effective date: 20080410