EP1491504A4 - Lithium manganese composite oxide granular secondary particle, method for production thereof and use thereof - Google Patents

Lithium manganese composite oxide granular secondary particle, method for production thereof and use thereof

Info

Publication number
EP1491504A4
EP1491504A4 EP03706987A EP03706987A EP1491504A4 EP 1491504 A4 EP1491504 A4 EP 1491504A4 EP 03706987 A EP03706987 A EP 03706987A EP 03706987 A EP03706987 A EP 03706987A EP 1491504 A4 EP1491504 A4 EP 1491504A4
Authority
EP
European Patent Office
Prior art keywords
production
composite oxide
lithium manganese
secondary particle
manganese composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP03706987A
Other languages
German (de)
French (fr)
Other versions
EP1491504A1 (en
EP1491504B1 (en
Inventor
Koji Tsukuma
Minoru Kuniyoshi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tosoh Corp
Original Assignee
Tosoh Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tosoh Corp filed Critical Tosoh Corp
Publication of EP1491504A1 publication Critical patent/EP1491504A1/en
Publication of EP1491504A4 publication Critical patent/EP1491504A4/en
Application granted granted Critical
Publication of EP1491504B1 publication Critical patent/EP1491504B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/54—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [Mn2O4]-, e.g. Li(NixMn2-x)O4, Li(MyNixMn2-x-y)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/16—Pore diameter
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
EP03706987.9A 2002-02-21 2003-02-20 Lithium manganese composite oxide granular secondary particle, method for production thereof and use thereof Expired - Lifetime EP1491504B1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP2002044877 2002-02-21
JP2002044877 2002-02-21
JP2002195797 2002-07-04
JP2002195797 2002-07-04
PCT/JP2003/001877 WO2003070642A1 (en) 2002-02-21 2003-02-20 Lithium manganese composite oxide granular secondary particle, method for production thereof and use thereof

Publications (3)

Publication Number Publication Date
EP1491504A1 EP1491504A1 (en) 2004-12-29
EP1491504A4 true EP1491504A4 (en) 2010-05-19
EP1491504B1 EP1491504B1 (en) 2016-06-15

Family

ID=27759666

Family Applications (1)

Application Number Title Priority Date Filing Date
EP03706987.9A Expired - Lifetime EP1491504B1 (en) 2002-02-21 2003-02-20 Lithium manganese composite oxide granular secondary particle, method for production thereof and use thereof

Country Status (5)

Country Link
US (1) US7217406B2 (en)
EP (1) EP1491504B1 (en)
CN (1) CN100344543C (en)
AU (1) AU2003211395A1 (en)
WO (1) WO2003070642A1 (en)

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US20090050841A1 (en) * 2005-07-21 2009-02-26 Sumitomo Chemical Company, Limited Positive electrode active material for non-aqueous electrolyte secondary battery
KR20080031424A (en) * 2005-07-21 2008-04-08 스미또모 가가꾸 가부시키가이샤 Positive electrode active material for nonaqueous electrolyte secondary battery
KR101140089B1 (en) * 2007-04-09 2012-04-30 닛산 지도우샤 가부시키가이샤 Positive electrode active material sintered body for battery
EP2144313A4 (en) * 2007-04-09 2012-12-05 Kao Corp Process for producing active material for positive electrode for battery
DE102008029804A1 (en) 2008-06-24 2010-07-08 Süd-Chemie AG Mixed oxide containing a lithium manganese spinel and process for its preparation
KR101593725B1 (en) * 2008-09-18 2016-02-12 도다 고교 가부시끼가이샤 Method for producing lithium manganate particle powder and nonaqueous electrolyte secondary battery
BRPI0919658B1 (en) * 2008-10-22 2020-10-06 Lg Chem, Ltd ACTIVE CATHODIC MATERIAL, CATHODE MIXTURE, CATHODE FOR SECONDARY BATTERIES AND LITHIUM SECONDARY BATTERY
JP4465407B1 (en) * 2008-10-27 2010-05-19 花王株式会社 Method for producing positive electrode active material particles for battery
CN102203987B (en) * 2008-10-27 2014-04-09 花王株式会社 Sintered lithium complex oxide
JP2010135285A (en) * 2008-10-31 2010-06-17 Sanyo Electric Co Ltd Positive electrode active material for lithium secondary battery and method for manufacturing the same
JP5791877B2 (en) * 2009-09-30 2015-10-07 三洋電機株式会社 Positive electrode active material, method for producing the positive electrode active material, and nonaqueous electrolyte secondary battery using the positive electrode active material
WO2011078112A1 (en) * 2009-12-22 2011-06-30 石原産業株式会社 Lithium titanate, manufacturing method therefor, slurry used in said manufacturing method, electrode active material containing said lithium titanate, and lithium secondary battery using said electrode active material
WO2011162253A1 (en) 2010-06-23 2011-12-29 日本碍子株式会社 Plate-shaped particles for positive-electrode active material of lithium secondary battery, positive electrode of lithium secondary battery, and lithium secondary battery
US8821765B2 (en) 2010-08-31 2014-09-02 Ngk Insulators, Ltd. Cathode active material for lithium secondary battery
JP5820662B2 (en) * 2010-09-06 2015-11-24 株式会社Ｎｔｔファシリティーズ Lithium ion secondary battery
KR101264333B1 (en) 2011-01-12 2013-05-14 삼성에스디아이 주식회사 Cathode active material, cathode and lithium battery containing the same, and preparation method thereof
CN103797624A (en) 2011-09-16 2014-05-14 日本碍子株式会社 Positive electrode active material precursor particles and method for manufacturing same, and method for manufacturing positive electrode active material for lithium secondary cell
CN102790214B (en) * 2012-08-15 2014-07-16 四川大学 Method for preparing lithium iron phosphate
JP6129853B2 (en) 2012-09-04 2017-05-17 日本碍子株式会社 Positive electrode active material for lithium secondary battery
WO2014061399A1 (en) 2012-10-15 2014-04-24 日本碍子株式会社 Positive active material for lithium secondary battery, and positive electrode obtained using same
US9306212B2 (en) 2013-07-19 2016-04-05 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium battery, and positive electrode and rechargeable lithium battery including the same
JP6048711B2 (en) * 2013-07-26 2016-12-21 エルジー・ケム・リミテッド Polycrystalline lithium manganese oxide particles, method for producing the same, positive electrode active material including the same, positive electrode, and lithium secondary battery
US9905850B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same
US9905851B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Cathode active material and method of preparing the same
CN105594028B (en) 2013-10-04 2020-05-19 株式会社半导体能源研究所 Lithium manganese composite oxide, secondary battery, electronic device, and method for producing layer
US9917296B2 (en) * 2014-04-02 2018-03-13 Toyota Jidosha Kabushiki Kaisha Nonaqueous electrolyte secondary battery
KR101593401B1 (en) * 2014-10-14 2016-02-12 주식회사 이엔에프테크놀로지 Porous cathod active material for lithium rechargeable battery and preparation method thereof
JP7135269B2 (en) * 2016-03-24 2022-09-13 住友金属鉱山株式会社 Positive electrode active material for non-aqueous electrolyte secondary battery and its manufacturing method, positive electrode mixture paste for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery
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Also Published As

Publication number Publication date
AU2003211395A1 (en) 2003-09-09
CN1633394A (en) 2005-06-29
EP1491504A1 (en) 2004-12-29
US20050123832A1 (en) 2005-06-09
EP1491504B1 (en) 2016-06-15
US7217406B2 (en) 2007-05-15
WO2003070642A1 (en) 2003-08-28
CN100344543C (en) 2007-10-24

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