EP1485593A1 - Systeme de combustion pilote par voie catalytique et procedes de fonctionnement - Google Patents

Systeme de combustion pilote par voie catalytique et procedes de fonctionnement

Info

Publication number
EP1485593A1
EP1485593A1 EP03716124A EP03716124A EP1485593A1 EP 1485593 A1 EP1485593 A1 EP 1485593A1 EP 03716124 A EP03716124 A EP 03716124A EP 03716124 A EP03716124 A EP 03716124A EP 1485593 A1 EP1485593 A1 EP 1485593A1
Authority
EP
European Patent Office
Prior art keywords
pilot
fuel
catalyst
air
combustor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP03716124A
Other languages
German (de)
English (en)
Inventor
Kare Lundberg
David Ginter
Sarento George Nickolas
Ralph Dalla Betta
David Yee
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Catalytica Energy Systems Inc
Original Assignee
Catalytica Energy Systems Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Catalytica Energy Systems Inc filed Critical Catalytica Energy Systems Inc
Publication of EP1485593A1 publication Critical patent/EP1485593A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23C—METHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C13/00—Apparatus in which combustion takes place in the presence of catalytic material
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23L—SUPPLYING AIR OR NON-COMBUSTIBLE LIQUIDS OR GASES TO COMBUSTION APPARATUS IN GENERAL ; VALVES OR DAMPERS SPECIALLY ADAPTED FOR CONTROLLING AIR SUPPLY OR DRAUGHT IN COMBUSTION APPARATUS; INDUCING DRAUGHT IN COMBUSTION APPARATUS; TOPS FOR CHIMNEYS OR VENTILATING SHAFTS; TERMINALS FOR FLUES
    • F23L15/00—Heating of air supplied for combustion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/02—Continuous combustion chambers using liquid or gaseous fuel characterised by the air-flow or gas-flow configuration
    • F23R3/04—Air inlet arrangements
    • F23R3/10—Air inlet arrangements for primary air
    • F23R3/12—Air inlet arrangements for primary air inducing a vortex
    • F23R3/14—Air inlet arrangements for primary air inducing a vortex by using swirl vanes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
    • F23R3/286—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply having fuel-air premixing devices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/28—Continuous combustion chambers using liquid or gaseous fuel characterised by the fuel supply
    • F23R3/34—Feeding into different combustion zones
    • F23R3/343—Pilot flames, i.e. fuel nozzles or injectors using only a very small proportion of the total fuel to insure continuous combustion
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23R—GENERATING COMBUSTION PRODUCTS OF HIGH PRESSURE OR HIGH VELOCITY, e.g. GAS-TURBINE COMBUSTION CHAMBERS
    • F23R3/00—Continuous combustion chambers using liquid or gaseous fuel
    • F23R3/40—Continuous combustion chambers using liquid or gaseous fuel characterised by the use of catalytic means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00—Aeronautics or air transport
    • Y02T50/60—Efficient propulsion technologies, e.g. for aircraft

Definitions

  • the present invention relates generally to methods and systems for reducing NO x emissions in gas turbine engines, boilers, burners, and furnaces. More particularly, the present invention relates to methods and systems for reducing NO x in gas turbine engines, boilers, burners, and furnaces using combustion piloted by a catalytic burner.
  • a typical gas turbine engine operates by ingesting air and compressing it using a rotating compressor.
  • the pressurized air is passed through a chamber, or "combustor,” wherein fuel is mixed with the air and burned.
  • the high temperature exhaust of the combusted mixture expands across a rotating turbine, resulting in a torque created by the turbine.
  • the turbine may then be coupled to an external load to harness the mechanical energy.
  • Gas turbine engines are commonly used for electrical generators, and to power turbo-prop aircraft, pumps, compressors, and other devices that may benefit from rotational shaft power.
  • Boilers, burners, and furnaces also use combustion to generate heat for heating processes and generating high temperature steam and/or air. Air passes through a chamber, or "combustor,” wherein fuel is mixed with the air and burned. The high temperature combustion of the fuel-air mixture is applied to heat exchangers or similar devices to transfer the heat from the combustion of the fuel and air to a desired medium.
  • Exhaust gases produced by combusting hydrocarbon and other fuels in typical combustion applications may contain undesirable emissions.
  • exhaust gases typically contain known pollutants such as nitric oxide (NO) and nitrogen dioxide (NO 2 ), which are frequently referred together as NO x .
  • Other emissions for example, may include unburned hydrocarbons (UHC), carbon monoxide (CO), and particulates, such as carbon soot.
  • Nitrogen oxides are of particular concern because of their role in forming ground level smog and acid rain as well as depleting the stratospheric ozone.
  • NO x may be formed by several mechanisms in conventional combustion processes. First, “thermal NO x ,” may form during the high temperature reaction of atmospheric oxygen with atmospheric nitrogen within the combustor, and particularly at adiabatic flame temperatures above about 2800° F. Second, “prompt NO x ,” may form during the reaction of atmospheric nitrogen with hydrocarbon fuel fragments (CHi), particularly under fuel- rich conditions. Finally, “fuel-bound NO x ,” may form during the reaction of nitrogen released from a nitrogen-containing fuel with atmospheric oxygen, particularly under fuel- lean conditions. In typical combustors, atmospheric oxygen and nitrogen are readily available in the air that is mixed with the fuel and burned.
  • LPM lean premixed
  • the excess air used to achieve fuel-lean conditions reduces thermal NO x formation by acting as a diluent to decrease peak flame temperatures.
  • the excess air also decreases the concentration of hydrocarbons available to react with atmospheric nitrogen, thereby reducing the formation of prompt NO x .
  • the amount of excess air needed to reduce thermal and prompt NO x formation may, however, cause the combustor to operate near its lean combustion limit, resulting in combustion instability and undesirable pressure dynamics. For example, at low equivalence ratios, the flame may be blown out. The lowest equivalence ratio at which combustion can be sustained is known as the lean combustion limit.
  • LPM flame stability can be improved by supplementing the main flame with hot vitiated air from a diffusion pilot flame to ensure that the main flame remains lit and stable at very lean conditions.
  • the added stability from the diffusion pilot flame comes at the cost of NO x emissions formed within the diffusion pilot flame.
  • a combustor including a catalytic pilot includes an inlet region for receiving compressor discharge air, and a pilot assembly and main swirler-injector assembly therein.
  • the pilot assembly may include a pilot inlet region for receiving at least a portion of the air, a catalyst located downstream of the pilot inlet region, a pilot fuel injector for delivering pilot fuel upstream of the catalyst, and a pilot outlet region located downstream of the catalyst.
  • the main swirler-injector assembly may include a main swirler-injector assembly inlet region for receiving at least a portion of the air, and a main swirler-injector assembly fuel injector located downstream of the main swirler-injector assembly inlet region.
  • the combustor may further include a combustion zone located downstream of the main swirler-injector assembly fuel injector and downstream of the pilot assembly.
  • a method for operating a combustor piloted by catalytic combustion pilot may include delivering pilot fuel and air through the catalytic pilot, wherein the catalytic pilot includes a catalyst disposed upstream of a main swirler-injector assembly combustion zone.
  • the method further includes adjusting at least one of the pilot fuel and the air delivered to the catalytic pilot to vary the catalyst exit conditions. For example, the temperature, fuel composition, and the like exiting the catalytic pilot may be varied to reduce NO x emissions of the system.
  • Figure 1 illustrates an exemplary gas turbine system piloted by a catalytic combustor
  • Figure 2 illustrates an exemplary catalytic pilot configuration
  • Figure 3 illustrates an exemplary catalytic pilot configuration with two catalyst structures
  • Figure 4 illustrates an exemplary catalytic pilot configuration with a venturi throat mixer
  • Figure 5 illustrates an exemplary catalytic pilot configuration with two catalyst structures
  • Figure 6A illustrates an exemplary catalytic pilot configuration with two inlet regions
  • Figure 6B illustrates a partial cross-sectional view of the exemplary catalytic pilot configuration view of Figure 6A taken along line A-A;
  • Figure 7 illustrates an exemplary catalytic pilot configuration with a post pilot fuel injector/burner
  • Figure 8 illustrates an exemplary catalytic pilot configuration with a post pilot mixing element
  • Figure 9 illustrates an exemplary catalytic pilot configuration with two air inlet regions
  • Figure 10 illustrates an exemplary catalytic pilot configuration with off-axis catalysts
  • Figure 11 illustrates an exemplary catalytic pilot configuration with an annular catalyst
  • Figure 12 illustrates an exemplary graph of speed, load, fuel flow, and compressor discharge temperature versus time for an exemplary control strategy for a combustor having a catalytic pilot
  • Figure 13 illustrates a diagram comparing an exemplary combustion system piloted by a catalytic combustor with and without an inlet duct burner
  • Figure 14 illustrates a diagram comparing an exemplary combustion system with and without a pre-heater
  • Figure 15 illustrates a graph comparing NO x emissions in exemplary systems with a catalytic pilot and a diffusion flame pilot;
  • Figure 16 illustrates a graph of NO x emissions versus pilot equivalence ratio of various pilot configurations
  • Figure 17 illustrate a graph of pilot exit gas temperature versus pilot equivalence ratio
  • Figure 18 illustrates a graph of the dynamic pressure (RMS) versus the overall equivalence ratio of various pilot configurations.
  • Figure 19 illustrates an exemplary graph of catalytic pilot exit gas temperature versus pilot fuel-air ratio for different catalysts.
  • Various aspects of the present invention include the design, application, and control of a combustion system including catalytic combustion in place of a conventional diffusion pilot flame to improve LPM flame stability and decrease NO x emissions.
  • An exemplary catalytic pilot may reduce or prevent the formation of thermal NO x typically generated by diffusion flame pilots because the catalyst generally operates below temperatures where thermal NO x forms. Further, a catalytic pilot may reduce or prevent the formation of prompt NO x because the catalyst may operate under fuel-lean conditions. Further, an exemplary catalytic pilot system may provide desired pilot exit conditions, e.g., exit temperature, fuel/air mixtures, and the like, to improve LPM flame stability without adding undesirable NO x emissions generated by typical diffusion flame pilots.
  • combustion may be defined as the exothermic reaction of fuel and an oxidant. Combustion takes place in many forms, two of which are flame combustion and spontaneous combustion. Stable flame combustion of a mixture of fuel and air generally occurs only when the mixture of fuel and air are within the flammable limits based on, for example, equivalence ratios, pressure, temperature, and the like. Flame combustion may further be divided into two main classes - diffusion flame and premixed flame combustion. In a diffusion flame, the rate of mixing between the fuel and oxidant to generate a flammable mixture is slow so that the overall rate of combustion is limited by the mixing rate.
  • a diffusion flame fuel is fed in a stream into the combustion zone and combustion takes place in the boundary layer between a fuel-rich core and the oxygen-rich surrounding. Oxidation rate is limited by the rate of diffusion of fuel from the core to this boundary layer. Flame temperatures are very high as combustion takes place at near- stoichiometric conditions.
  • the fuel and oxidant are rapidly mixed together prior to combustion, for example, with a swirler, turbulent mixing tube, or the like such that the overall rate of combustion is based on the subsequent chemical reaction rates and other macroscopic system parameters such as pressure, temperature, equivalence ratio, heat conduction, and the like.
  • a specific sub-class of a premixed flame is a lean premixed (LPM) flame whereby the flammable mixture is fuel lean to result in low flame temperatures and minimal thermal NO x formation.
  • LPM lean premixed
  • an ignition source such as a hot surface or an electric spark, is generally used to initiate the flame to combust the flammable mixture.
  • Spontaneous combustion sometimes referred to as homogeneous combustion, spontaneous ignition, or auto-ignition, is a form of combustion wherein the mixture of fuel and oxidant undergoes a chemical reaction which leads to the rapid evolution of heat in the absence of any concentrated source of ignition such as a flame or spark.
  • Spontaneous combustion that is initiated by a catalytic reaction is generally referred to as catalytic combustion.
  • the description herein of exemplary catalytic pilot assemblies involves two categories of catalytic combustion. In one category, the catalyst is designed such that all the fuel that passes through the catalyst initiates the chemical reaction and is fully combusted.
  • the gas exiting the catalyst substrate is therefore predominately vitiated air, i.e., containing combustion products of CO 2 and H 2 O.
  • the catalyst is designed such that only a portion of the fuel (approximately 10 to 75%) that passes through the catalytic substrate is combusted.
  • the gas exiting the catalyst substrate is a mixture of vitiated air and heated fuel.
  • the catalytic pilot is desirably controlled to produce exit conditions desired to sufficiently stabilize the LPM flame and reduce NO x emissions.
  • the catalytic pilot may combust or convert approximately 10 to 100% of the fuel delivered to the catalytic pilot.
  • the conversion of fuel will generally be a function of the catalyst design and operating conditions for a particular combustion system.
  • the level of conversion should be sufficient to generate the pilot exit conditions desired to stabilize the LPM flame.
  • the exit gas is composed solely of hot vitiated air. Therefore, it is desirable that the catalyst exit gas temperature is sufficiently high to stabilize the LPM flame, but not excessively high where thermal NO x may form.
  • the catalyst exit gas is composed of hot uncombusted fuel and vitiated air.
  • characteristics of the catalyst exit gas mixture that may be varied include the exit temperature, ignition delay time, and adiabatic combustion temperature.
  • the catalyst exit characteristics are desirably within a range that ensures LPM flame stability and minimal NO x formation during operation.
  • the following description includes numerous pilot configurations for systems where the catalyst converts 100% of the pilot fuel and/or less than 100% of the pilot fuel.
  • the various pilot configurations may be advantageously employed to vary the pilot exit conditions and to stabilize the main flame in a variety of combustion systems.
  • Figure 1 illustrates an exemplary gas turbine system piloted by catalytic combustion.
  • Compressor 11 ingests ambient air 12 through a compressor bellmouth and compresses the air to a higher pressure.
  • the compressed air is driven, at least in part, through the combustor 13 and through the drive turbine 14.
  • a portion of compressed air is delivered to the burner(s) of combustor 13 through an air line or the like.
  • Fuel is delivered to the swirler-injector assembly(s) of combustor 13 via a fuel line or the like.
  • Combustor 13 includes a catalytic pilot (see Figure 2) for stabilizing the LPM flame of a main swirler- injector assembly disposed within combustor 13.
  • the combustor 13 combusts the air and fuel to produce a hot high velocity gas stream that flows through turbine 14.
  • the hot high velocity gas stream provides power to drive turbine 14 and the load 15.
  • Load 15 may be, for example, a generator or the like.
  • the hot gases are then discharged from the turbine 14 via an exhaust line or the like.
  • combustor 13 may be included in other combustion systems.
  • combustor 13 piloted by a catalytic pilot may be included in a boiler, burner, furnace, and the like as will be recognized by those skilled in the art.
  • the catalytic pilot 110 of this example includes an air inlet 117 for receiving a portion of the compressor discharge air.
  • the catalytic pilot 110 further includes at least one catalyst fuel injector 111 for introducing fuel to the catalytic pilot 110.
  • a fuel-air mixing region 112 is located generally downstream of the fuel injector 111 and air inlet 117.
  • a catalyst 113 is located downstream of the fuel-air mixing region 112 and a pilot outlet region 114 is located downstream of the catalyst 113.
  • Fuel injector 111 injects pilot fuel into the air stream entering pilot inlet 117.
  • the fuel and air may mix in fuel-air mixing region 112.
  • the mixture of fuel and air pass through catalyst 113 where at least a portion of the fuel and air combust and exits the pilot 110 through catalyst exit region 114 at a higher temperature.
  • the hot fuel-vitiated air mixture exiting the catalyst 113 may spontaneously combust within the catalyst exit region 114 to produce predominately hot vitiated air exiting pilot 110.
  • exit region 114 may be sufficiently small such that spontaneous combustion of the fuel and air does not fully occur such that fuel and hot vitiated air exit the catalytic pilot 110.
  • the main swirler-injector assembly 120 receives a portion of the compressor discharge air at location 118.
  • the main swirler-injector assembly 120 generally includes at least one main fuel injector 115 and a fuel-air-mixing region or element 116, such as a typical swirler or the like.
  • the main fuel may be mixed with air by mixing element 116 upstream of the re-circulation zone 119 (often referred to as the combustion zone).
  • the catalytic pilot fuel 111 is at least partially combusted by catalyst 113 to generate hot gas exiting the catalyst 113 into the re-circulation zone 119.
  • the hot vitiated gas mixes with the LPM fuel-air mixture in the combustion or re-circulation region 119 where the balance of combustion takes place to achieve a desired flame temperature.
  • the exit gas from the catalytic pilot 110 may be controlled, for example, by varying the pilot fuel 111 and/or intake air at 117, to stabilize the LPM flame in the re- circulation zone 119 with reduced formation of NO x emissions.
  • a portion of the compressed air from the compressor may be delivered to the pilot assembly 110 through a pilot air-line (not shown).
  • the amount of compressed air, which is branched off, may be adjusted by controlling a valve or the like.
  • pilot fuel 111 may be delivered to the catalytic pilot 110 of the combustor through a pilot fuel line.
  • a valve or the like may be provided to control the amount of pilot fuel 111 delivered to the catalytic pilot 110.
  • Desired amounts of air may be delivered to the mixing region 112 and mixed with the pilot fuel 111 to vary the exit conditions of the catalytic pilot 110.
  • the desired fuel-air mixture may be delivered to the catalyst 113 to undergo a catalytic reaction and delivered from the catalyst 113 to the combustion chamber, i.e., re-circulation zone 119 to support the main swirler-injector assembly flame.
  • the exemplary catalytic pilot generally includes four main components: (i) a fuel injector
  • 111 for introducing fuel to the catalytic pilot; (ii) a fuel-air mixing region 112 to mix the fuel and air; (iii) a catalyst 113 to at least partially combust the fuel-air mixture; and (iv) a catalyst exit region 114 wherein the hot fuel-air mixture exits the catalytic pilot.
  • the fuel injector 111 injects pilot fuel into the flow path of air upstream of catalyst 113.
  • the fuel injector 111 may include various fuel lines and fuel valves for modulating pilot fuel delivery.
  • the fuel valve may be controlled based on a schedule of fuel flow or the like.
  • the fuel may be injected into the catalytic pilot by any suitable method. For example, fuel may be injected radially inward from a fuel manifold around the outer diameter of the catalytic pilot or radially outward from a manifold located in the flow path centerline of the catalytic pilot.
  • the fuel may also be injected axially against or with the air flow direction from a radial fuel peg or injected perpendicular to the air flow direction from a radial fuel peg.
  • the catalytic pilot desirably includes a fuel-air mixing region 112 located within the catalytic pilot and located upstream of catalyst 113.
  • the fuel-air mixing region 112 located within the catalytic pilot and located upstream of catalyst 113.
  • the 112 may include a sufficiently long mixing "tube” or region for the fuel and air to effectively diffuse together.
  • the degree of mixing depends, at least in part, on the particular application as well as various design considerations for the particular catalyst and/or combustor.
  • the fuel and air may also be mixed by a static mixer, such as a swirler (axial or radial) or any other device that generates turbulence and/or shear within the flow path.
  • a static mixer such as a swirler (axial or radial) or any other device that generates turbulence and/or shear within the flow path.
  • Other suitable methods known in the art for mixing the fuel and air may be used such as passing the fuel and air through the throat of a venturi mixer or the like.
  • the catalyst 113 may include various chemicals imparted on a suitable structure such that as the fuel and air mixture pass through catalyst 113 a portion or all of the fuel and air react.
  • the structure and materials of catalyst 113 may generally include any suitable catalyst material and structure for catalytic combustion. Further, any number of catalyst stages, as well as catalyst structures disposed in parallel, are contemplated within an exemplary catalytic pilot design. Depending on the particular application, specific catalyst designs may be varied to achieve a desired catalyst light-off temperature (LOT), defined as the temperature at which the fuel begins to react on the catalyst, a preferred conversion of the hydrocarbon fuel through the catalyst, and a preferred temperature exiting the catalyst in a system to stabilize the LPM flame over a desired operating range of the gas turbine engine.
  • LOT catalyst light-off temperature
  • the catalyst may have sufficient activity to support catalytic combustion, i.e., achieve LOT, at part load conditions where the compressor discharge temperature that feeds the catalyst inlet is very low, e.g., less than approximately 350°C and between approximately 150 and 350°C.
  • the catalyst may include a monolithic structure with all or portions of channels therein coated with dispersed precious metal to provide sufficient catalytic activity for light-off between about 150 and 350°C. Further, employing features that reduce the heat transfer rate without inhibiting the catalyst's surface activity rate may lower the catalyst light-off temperature (LOT).
  • external heat sources may be employed such as electrically heating the monolithic structure or preheating the air entering the catalyst to effectively cause the catalyst to combust fuel at lower compressor discharge temperatures. Electrically heating the catalyst monolith structure is described, for example, in U.S. Patent No. 6,109,018 to Rostrup-Nielsen, et al., which is incorporated herein by reference in its entirety.
  • a multi-staged pilot catalyst system it is preferred to limit these characteristics, i.e., to reduce the LOT, to the inlet or first stage catalyst.
  • the second stage catalysts may have higher LOT because they will receive generally higher temperature fuel-air mixtures exiting the first stage catalyst.
  • the individual catalyst monoliths making- up the balance of the catalyst system may have, for example, the characteristics described by the previously cited U.S. Patents.
  • the catalyst exit region 114 includes the region located adjacent and downstream of the exit face of catalyst 113.
  • the exit region 114 may be adjusted to achieve a desired exit temperature, fuel-air composition, and/or mixing effect in the combustor.
  • the exit region 114 may have a minimal or zero volume such that the catalyst exit temperature and gas composition (fuel and vitiated air or only vitiated air) does not change prior to entering the LPM re-circulation zone 119.
  • the catalyst exit region 114 may have a sufficient volume such that the catalyst exit gas composition may spontaneously combust therein and supply high temperature vitiated air to the LPM re-circulation zone 119.
  • the vitiated gas temperature may vary from approximately 1100 to 1600°C to support the LMP flame, but the preferred range is approximately 1300 to 1400°C.
  • the catalyst exit region 114 may include a device such as a swirler to enhance the mixing of the catalyst exit gas in the LPM re-circulation zone 119. Further, the catalyst exit region 114 may include a device such as a fuel injector to add fuel to the hot vitiated air exiting the catalyst. The device may introduce fuel radially inward from the outer diameter or radially outward from the centerline. Such a device could also act as a diffusion flame to stabilize the LPM combustion flame during the engine start-up sequence before the compressor discharge temperature (CDT) air is hot enough to sustain catalyst combustion in the catalytic pilot, i.e., before catalyst light-off.
  • CDT compressor discharge temperature
  • the catalytic pilot includes two or more catalyst stages as illustrated in Figure 3.
  • the combustor 33 of Figure 3 is similar to that of Figure 2 except that catalytic pilot 310 includes a first stage catalyst 313a and a second stage catalyst 313b located in series along the flow path.
  • the first stage catalyst 313a may be designed to react with a rich low temperature fuel-air mixture and subsequent catalyst stages designed to react with leaner higher temperature fuel-air mixtures.
  • the catalyst fuel injector 311 injects fuel, which mixes with the incoming pilot air 317 in the pilot-mixing region 312.
  • the pilot fuel is partially combusted by the first stage catalyst 313a to generate a hot fuel and at least partially vitiated air mixture.
  • the higher temperature and leaner fuel-air mixture exiting first stage catalyst 313a enters second stage catalyst 313b.
  • the second stage catalyst 313b may be advantageously designed to react with the higher temperature leaner fuel-air mixtures than the first stage catalyst 313a.
  • the hot fuel- vitiated air mixture exiting the second stage catalyst 313b may spontaneously combust within the catalyst exit region 314, or exit region 314 may be sufficiently small such that spontaneous combustion does not fully occur.
  • the high temperature gases exiting the catalytic pilot mix with the main swirler-injector assembly gases in the re-circulation zone 319 to stabilize the LPM flame as previously described.
  • Figure 4 illustrates a cross-sectional view of an exemplary catalytic pilot configuration including a venturi throat mixer at the air inlet of the catalytic pilot.
  • fuel is injected radially inward towards the central axis A-A from the outer walls 401 as illustrated by the arrows.
  • the fuel is injected at the throat 402 of a venturi mixer such that compressor discharge air flowing through the throat 402 is mixed with the injected fuel within or near the venturi throat 402.
  • the venturi throat 402 provides a suitable structure for mixing the fuel and air upstream of the catalyst 403.
  • the pilot fuel may be introduced through one or more fuel lines 406 that may include controllable fuel valves (not shown) to modulate or adjust the fuel delivered to the pilot based on a pre- computed fuel schedule or the like.
  • the fuel-air mixture passes through catalyst 403 to generate a hot mixture of fuel and vitiated air that may homogeneously combust within the catalyst exit region 404 thereby further increasing the exit temperature of the catalytic pilot.
  • Main swirler-injector assembly fuel may be delivered through main fuel line 409 and emerge in the combustion or re-circulation zone 405 located downstream of exit region 404.
  • the high temperature vitiated air emerging from exit region 404 mixes with main fuel from main swirler-injector assembly 408 in the re-circulation zone 405 to support combustion of the LPM flame.
  • the particular catalytic pilot design and configuration shown in Figure 4 generally provides a low cost method of integrating a catalytic pilot with an LPM swirler-injector assembly because a simple fuel injection mixing device is coupled with a single stage catalyst. Further, this example provides a simple, low-pressure drop fuel injection/mixing design through the venturi throat mixer.
  • FIG. 5 illustrates a cross-sectional view of another exemplary catalytic pilot configuration.
  • the catalytic pilot includes a first annular catalyst stage 502 and second catalyst stage 504.
  • the catalytic pilot is configured to reduce the velocity of the fuel-air mixture in the first catalyst stage 502 to reduce the light-off temperature of the first catalyst stage 502.
  • the fuel-air mixture exiting the first catalyst stage 502 is heated by at least a partial reaction of fuel and air such that subsequent catalyst stages, i.e., catalyst stage 504, may be designed to react with leaner higher temperature fuel-air mixtures than the first stage catalyst 502.
  • Compressor discharge air and pilot fuel are mixed in an annular region disposed around the catalytic pilot.
  • Compressor discharge air "WA" flows in through mixing region 501, which may include a swirler or the like as well as fuel pegs or the like for introducing pilot fuel from fuel line 506 to aid in facilitating the mixing of the pilot fuel and air.
  • the fuel and air mixture pass over annular catalyst 502 located downstream of mixing region 501. The catalyst reacts with the fuel-air mixture, and the gases emerging from the first catalyst stage converge into a cylindrical region 503 at a higher temperature.
  • the cross-section area of region 503 (viewed along axis A- A) may be significantly smaller than the cross-sectional area of mixing region 501 (viewed along the flow path), such that the velocity through mixing region 501 would be significantly less that the velocity through region 503.
  • the leaner fuel-air mixture exiting first stage catalyst 502 therefore passes across second catalyst stage 504 located downstream of region 503 at a higher temperature and velocity.
  • the second catalyst stage 504 may be advantageously designed to perform with at least one of a higher inlet temperature, higher velocity, and leaner fuel-air mixture than the first stage catalyst 502.
  • the hot fuel- vitiated air mixture exiting the second stage catalyst 504 may homogeneously combust within the catalyst exit region 505 depending on the length or volume of the exit region 505.
  • the high temperature vitiated air exiting the pilot mixes with the main swirler-injector assembly 508 gases in the re-circulation zone 506 to stabilize the LPM flame as previously described.
  • Figure 6A illustrates a cross-sectional view of another exemplary catalytic pilot design
  • Figure 6B illustrates a view along line A-A of Figure 6 A with part of the structure removed for clarity
  • the catalytic pilot includes two catalyst stages, wherein the first catalyst stage includes two separate air intake regions, mixing regions, and catalyst structures.
  • the combustor includes a catalytic pilot assembly 622 and a main swirler-injector assembly 624 interconnected with the combustor inlet region for receiving compressor discharge air.
  • the pilot assembly 622 includes a first pilot inlet region 66 for intaking air, a first pilot fuel-air mixing region 62 located downstream of the first pilot inlet region 66, at least one first pilot fuel injector (not shown), a first catalyst 64, and a catalyst exit region 614.
  • the pilot assembly 622 also includes a second pilot inlet region 67, a second pilot fuel-air mixing region 61 located downstream of the second pilot inlet region 67, at least one second pilot fuel injector (not shown), a second catalyst 63, and a catalyst exit region 614.
  • Both the first and second catalysts 63 and 64 form a first stage of the catalytic pilot 622 upstream of the third catalyst 626 forming a second stage of the catalytic pilot 622.
  • An inter-catalyst region 628 is located between the first and second pilot stages.
  • the pilot assembly also includes a pilot outlet region 630 located downstream of the third catalyst 626.
  • the main swirler-injector assembly 624 includes a main swirler-injector assembly inlet region 632 for receiving air, a main swirler-injector assembly outlet region 634, a main swirler-injector assembly swirler 636 located downstream of the main swirler- injector assembly inlet region 632, at least one main swirler-injector assembly fuel injector located downstream of the swirler 636, a mixing region 637 located downstream of the fuel injector and upstream of the main swirler-injector assembly outlet region 634, and a main combustion or re-circulation zone 640 located downstream of the pilot assembly 622 exit region 630.
  • the combustor has a central axis L and the third catalyst 626 is located along the central axis.
  • the main swirler-injector assembly inlet region 632 and the main swirler-injector assembly swirler 636 are arranged in an annular configuration about the pilot assembly.
  • pilot fuel from fuel line 651 is injected into the air flow by respective fuel injectors and mixed with the air in fuel-air mixing regions 61 and 62.
  • Various active or passive mixing elements may be included in the fuel-air mixing regions.
  • the fuel injectors are interconnected with fuel lines 651 via a fuel manifold or the like that may include valves or the like for modulating pilot fuel delivery.
  • the pilot fuel is mixed with the pilot air in two distinct locations, both the fuel-air mixing regions 61 and 62, to generate a rich uniform fuel-air mixture to pass across two first stage catalysts 63 and 64.
  • the higher temperature and leaner fuel-air mixture exiting the first stage catalysts 63 and 64 converge at an inter-catalyst region 628 where the gas velocity accelerates as the frontal cross-sectional area (i.e., viewed along the plane A-A) of the inter-catalyst region 628 reduces from the total frontal cross-sectional areas of the first and second pilot fuel-air mixing regions 61 and 62.
  • the frontal cross-sectional area of the inter-catalyst region 628 is exactly half the total frontal area of the first and second pilot fuel-air mixing regions 61 and 62 combined; however, other ratios are contemplated for various applications and designs.
  • the leaner fuel-air mixture in the inter-catalyst region 628 passes across a third catalyst or second catalyst stage 626 that may be designed to perform with at least one of higher inlet temperature, higher velocity, and leaner fuel-air mixture than the first stage catalysts 63 and 64.
  • Compressed air also enters the main swirler-injector assembly 624 at main swirler-injector assembly inlet region 632.
  • Fuel is injected by a main swirler-injector assembly fuel injector, which delivers fuel into the main swirler-injector assembly from a main swirler-injector assembly fuel manifold via a main fuel line 650 that may include a valve (not shown) or the like for modulating main swirler-injector assembly fuel delivery.
  • the hot fuel and vitiated air mixture exiting the second stage catalyst 626 combusts entirely in the pilot outlet region 630 delivering hot vitiated air into the combustion zone 640 where it mixes with the main swirler-injector assembly air and fuel mixture that is delivered from the main swirler-injector assembly into the combustion zone.
  • the pilot outlet region 630 is sufficiently small in length and/or volume so that spontaneous combustion of the fuel and vitiated air mixture does not occur within the pilot outlet region 630. Rather, combustion of the fuel and vitiated air mixture exiting second stage catalyst 626 occurs in the combustion zone 640 where the mixture mixes with the compressed air and fuel of the main swirler-injector assembly.
  • the high temperature gases exiting the catalytic pilot mix with the LPM swirler-injector assembly gases in the re-circulation zone or combustion zone 640 to stabilize the LPM flame.
  • Figure 7 illustrates a cross-sectional view of another exemplary variation of a catalytic pilot incorporated within an LPM combustor.
  • compressor discharge air from a compressor enters the combustor and passes into the pilot assembly 722 and the main swirler-injector assembly 724.
  • the compressed air enters the pilot assembly 722 through the pilot inlet region 702.
  • Fuel is injected into the flow path by at least one first pilot fuel injector 701 where it mixes with air in the fuel-air mixing region 703. Active or passive mixing elements may be included in the fuel-air mixing region 703.
  • the pilot fuel is mixed with the pilot air and generates a fuel-air mixture that passes across the pilot catalyst 704.
  • the hot fuel-air mixture exiting the catalyst 704 mixes with fuel from at least one second pilot fuel injector 705 located downstream of the catalyst 704.
  • the fuel injectors 701 and 705 may be interconnected with a fuel-manifold via fuel lines that may include valves for modulating pilot fuel delivery.
  • Compressed air also enters the main swirler-injector assembly 724 at the main swirler-injector assembly inlet region 718.
  • Fuel is injected by the main swirler- injector assembly fuel injector 720, which may deliver fuel into the main swirler-injector assembly from a main swirler-injector assembly fuel manifold via a main fuel line that includes a valve or the like for modulating main swirler-injector assembly fuel delivery.
  • the hot fuel and vitiated air mixture exiting the pilot assembly mixes with the main swirler-injector assembly air and fuel mixture that is delivered from the main swirler- injector assembly 724 into the combustion or re-circulation zone 707.
  • catalyst 704 may be located along a central axis of the combustor with main swirler-injector assembly inlet region 718 and the main swirler-injector assembly fuel-air mixing region 721 arranged in an annular configuration about the pilot assembly 722.
  • first pilot fuel injector 701 injects fuel, which mixes with the incoming pilot air in the pilot fuel-air mixing region 703.
  • the pilot fuel is at least partially combusted on the catalyst 704 to generate a hot fuel-vitiated air mixture (or completely vitiated air mixture).
  • the hot pilot fuel-vitiated air mixture is mixed with additional fuel through second pilot fuel injector 705 in the catalyst exit region 706 to vary the amount of fuel exiting the catalytic pilot.
  • Second pilot fuel injector 705 may also serve as a diffusion flame to assist in the gas turbine start-up, i.e., an acceleration or loading sequence, until the compressor discharge temperature (CDT) is sufficiently high to sustain catalytic combustion.
  • the hot fuel-vitiated air mixture mixes with the main swirler-injector assembly fuel and main swirler-injector assembly air that is preferably lean pre-mixed in the re-circulation region 707 where the balance of combustion takes place.
  • Figure 8 illustrates a cross-sectional view of another exemplary catalytic pilot configuration.
  • catalyst fuel injector 801 injects fuel, which mixes with the incoming pilot air 802 in the pilot-mixing region 803.
  • the pilot fuel is combusted on the catalyst 804 to generate a hot fuel-vitiated air mixture.
  • the pilot configuration is similar to that of Figure 2 or 3, except that the hot pilot fuel-vitiated air mixture passes through a swirler-type element 805 in the catalyst exit region to enhance the mixing of the pilot exit gas mixture with the LPM fuel-air within the re-circulation region 806 where the balance of combustion takes place.
  • the swirler-type element 805 may be any suitable active or passive swirler, guide vane, baffle, or the like to enhance the mixing of the pilot exit gas mixture as it enters the re-circulation region 806.
  • Swirler-type element 805 may enhance the mixing of the pilot assembly exit gases and main swirler-injector assembly gases to increase flame stability, reduce combustion dynamics within the re-circulation region 806, and minimize the volume needed in the re-circulation region 806 to achieve complete combustion.
  • Figure 9 illustrates a cross-sectional view of another exemplary catalytic pilot configuration.
  • This example is similar to Figure 3 except that additional air is added at 92b, interconnected to the inter-stage region 98 located between catalyst 913a and catalyst 913b.
  • Catalyst fuel injector 911 injects fuel, which mixes with the incoming first stage pilot air in the pilot-mixing region 92a.
  • pilot air may enter in two regions 92a and 92b. In one example, less air enters regions 92a than in a configuration without air inlet at region 92b (such as Figure 3). Reducing the amount of air entering region 92a results in a lower velocity and potentially richer fuel-to-air ratio entering the first stage catalyst 913a.
  • the pilot fuel and air is combusted on the first stage catalyst 913a to generate a hot fuel-vitiated air mixture.
  • the hot pilot fuel-vitiated air mixture is diluted and mixed with additional air entering at 92b upstream of the second stage catalyst 913b and before further combustion of the pilot fuel.
  • the hot fuel-vitiated air mixture exiting the second stage catalyst may spontaneously combust within the catalyst exit region 914, or exit region 914 may be sufficiently small such that spontaneous combustion does not occur.
  • the high temperature gases exiting the catalytic pilot mix with the LPM swirler-injector assembly gases in the re-circulation zone 919 to stabilize the LPM flame as previously described.
  • the exemplary catalytic pilot configurations shown in Figures 2-9 are illustrated with the catalytic pilot generally disposed on the center axis of the LPM swirler- injector assembly.
  • the catalytic pilot may be placed off-axis from the LPM swirler-injector assembly with the hot gas exiting the catalytic pilot into the combustion or re-circulation zone of the LPM swirler-injector assembly.
  • the catalytic pilot may also include one or more annular catalysts incorporated into the main swirler-injector assembly with the hot gas exiting the catalytic pilot into the re-circulation zone of the main swirler- injector assembly.
  • FIG. 10 illustrates a cross-sectional view of an exemplary off-axis catalytic pilot configuration.
  • one or more catalytic pilots 1000 are disposed around a central main swirler-injector assembly 1010.
  • the catalytic pilot 1000 includes a catalyst fuel injector 1002, fuel-air mixing region 1001, catalyst 1003, and catalyst exit region 1004.
  • the main swirler-injector assembly 1010 includes fuel injector 1005 and a fuel-air-mixing element 1006 such as a typical swirler or the like.
  • Catalytic pilots 1000 and main swirler-injector assembly 1010 receive compressor discharge air at locations 1007 and 1008 respectively.
  • the air is mixed with the pilot fuel 1002 and main fuel 1005 in mixing regions 1001 and 1008 respectively.
  • the catalytic pilot fuel 1002 is at least partially combusted by catalyst 1003 to generate hot vitiated gases exiting the catalytic pilot 1000.
  • the hot vitiated gases mix with the LPM fuel-air mixture in the re-circulation region 1009 where the balance of combustion takes place.
  • the volume of catalyst exit region 1004 may be varied (including a minimal volume) depending on the particular application to achieve the desired exit conditions of catalytic pilot 1000.
  • each catalytic pilot 1000 may include a first and second catalyst stage located serially in the flow path through one or more catalytic pilots 1000, second pilot fuel injectors, exit swirlers, and the like.
  • FIG 11 illustrates a cross-sectional view of an annular catalytic pilot configuration.
  • an annular catalytic pilot 1102 is illustrated disposed around a central burner 1101, which may be either a diffusion flame or LPM burner, and has an annular LPM swirler-injector assembly 1103 positioned around the catalytic pilot 1102.
  • the catalytic pilot generally includes the catalyst fuel injector 1104, fuel-air mixing region 1105, catalyst 1106, and catalyst exit region 1107.
  • the hot vitiated gases exiting the catalytic pilot 1102 mix with the fuel-air mixture exiting the LPM swirler-injector assembly 1103 to complete the combustion process and stabilize the flame in the re-circulation zone 1108.
  • the central burner 1101 may be a diffusion flame burner to stabilize combustion downstream of the LPM swirler-injector assembly 1103 during an acceleration or engine loading sequence. Additionally, a first and second stage catalyst may be included in the annular catalytic pilot configuration, and exit region 1107 may be varied in volume (including minimal volume) to achieve desired exit conditions of the catalytic pilot 1102.
  • Control and Operating Strategies include methods for achieving catalyst light-off, preferred catalyst conversion rates, preferred catalyst exit temperatures, and maintaining preferred catalyst performance over desired operating ranges and life of the catalyst within the catalytic pilot.
  • a gas turbine engine system desirably operates in a manner such that the catalyst will sustain catalytic combustion when fuel to the catalyst is initiated.
  • One exemplary method includes monitoring the compressor discharge temperature (CDT) and/or catalyst inlet temperature during an acceleration and engine loading sequence until it is above the catalyst LOT. When the CDT is equal to or above the catalyst LOT, fuel may then be delivered to the catalyst. This method is desirable when the LPM burner is capable of performing the acceleration and loading sequence without the added stability of a pilot flame. In applications where the LPM burner performance is improved with assistance from a pilot flame for stability during an acceleration and loading sequence, various methods described below may be used.
  • in one exemplary method for operating a combustor with a catalytic pilot includes using a diffusion pilot to stabilize the LPM flame during the acceleration and loading sequence.
  • a diffusion pilot to stabilize the LPM flame during the acceleration and loading sequence.
  • the compressor discharge air temperature is high enough to support catalytic combustion in the catalytic pilot and thereby stabilize the LPM flame
  • a transition is made from the diffusion burner to the catalytic pilot.
  • This exemplary method is illustrated in Figure 12 where various parameters of a gas turbine engine system are plotted with respect to time. While the turbine accelerates to full speed and loads to full load, the diffusion pilot is fueled to assist and stabilize the LPM burner.
  • the CDT increases to a level above the catalyst light-off temperature.
  • the diffusion pilot fuel may be decreased while the catalytic pilot fuel is increased.
  • the transition from fueling the diffusion pilot to fueling the catalytic pilot may occur over a range of load and time near or after the CDT temperature rises above the catalyst LOT.
  • the diffusion pilot fuel flow may be reduced to zero and the LPM burner remains stabilized by the catalytic pilot operation.
  • the transition period may vary in time and in relation to the speed and/or load of the turbine.
  • the diffusion pilot fuel could begin to decrease before the CDT is above the catalyst LOT.
  • the CDT may be measured at the compressor discharge air inlet of the combustor, the inlet for the catalytic pilot, or anywhere in between. CDT may also be estimated from turbine operating conditions.
  • a duct burner or the like may be used to increase the inlet air temperature such that the CDT (or catalytic pilot intake temperature) is sufficiently high to light-off the catalyst and stabilize the LPM burner throughout the acceleration and loading sequence.
  • This approach is illustrated in Figure 13 with the temperature profile is graphed through several components of the gas turbine system.
  • the air is drawn through a duct 1301 into the compressor 1302.
  • the compressor compresses the air to a higher pressure and temperature 1303.
  • the resulting compressor discharge temperature typically remains below the catalyst light-off temperature 1304.
  • the compressed air is further heated in the combustor 1305 to generate hot vitiated air.
  • the hot vitiated air passes through the turbine section 1306, extracting energy and cooling the vitiated air.
  • the cooled vitiated air exits the system through the exhaust stack 1307.
  • a gas turbine system with a duct burner as shown in 13b, the air is drawn through a duct 1308 containing a duct heater or burner 1309.
  • the duct burner 1309 heats the intake air to a higher temperature 1310.
  • Duct burner 1309 may be any suitable burner or heater capable of increasing the temperature of the intake air.
  • the preheated air is compressed through the compressor 1311 to a higher pressure and temperature 1312.
  • the resulting compressor discharge air temperature is now greater than the light-off temperature of the catalyst so the catalytic pilot can now be used to stabilize the LPM burner.
  • the balance of the gas turbine system operates similar to 13 a.
  • an electrical heater may be used upstream of the catalytic pilot to pre-heat air entering the catalyst to a temperature where the catalyst may light-off and stabilize the combustion downstream of the LPM swirler-injector assembly.
  • This approach is schematically illustrated in Figure 14. A temperature profile is graphed through several components of a gas turbine system both for a system with and without an electrical pre-heater.
  • an exemplary catalytic pilot assembly without a pre-heater is illustrated.
  • the air temperature 1401 entering the catalytic pilot is below the catalyst light-off temperature 1402 and the catalyst cannot support catalytic combustion of the air and the pilot fuel.
  • an electrical heating element 1404 is disposed upstream of an exemplary catalytic pilot, or at least upstream of the catalyst, to heat the inlet pilot air to a temperature 1405 above the catalyst light-off temperature 1402.
  • the catalytic pilot is now active and the pilot exit temperature 1406 is high enough to stabilize combustion downstream of the LPM swirler-injector assembly.
  • a pre-burner such as an annular pre-burner located around the main LPM swirler-injector assembly or the like may be used to provide a sufficient increase in temperature to the incoming combustor air to support both catalyst light-off within the catalytic pilot and help stabilize combustion downstream of the main LPM swirler-injector assembly.
  • the pre-burner could operate during start-up and acceleration sequences as well as at full-load.
  • Various configurations of a pre-burner in a catalytic pilot combustion system will be apparent to those skilled in the art.
  • the pilot fuel may be doped with hydrogen during a start-up or acceleration sequence so as to initiate catalyst light-off at very low temperatures, e.g., near ambient temperature.
  • a fuel processor as part of the fuel skid (not shown) or the like may generate the hydrogen.
  • the hydrogen may be a provided by a local source such as a high-pressure cylinder or as a process gas from an adjacent chemical plant.
  • various methods are provided for operating the catalytic pilot system in a manner to maintain preferred catalyst exit conditions, such as catalyst conversion (i.e., the ratio of fuel combusted by catalyst) and exit temperature, that stabilize the LPM flame over the life of the catalyst.
  • catalyst conversion i.e., the ratio of fuel combusted by catalyst
  • exit temperature i.e., the ratio of fuel combusted by catalyst
  • the catalytic pilot adiabatic combustion temperature is controlled.
  • the pilot fuel flow may be based on a schedule of catalyst adiabatic combustion temperature (Tad demand) versus load or some other system characteristic consistent with load, such as compressor discharge temperature, exhaust gas temperature, turbine inlet temperature, total fuel flow to the engine, or the like.
  • the control system may determine the pilot airflow based upon engine measurements of compressor discharge pressure, compressor discharge temperature, inlet bell mouth pressure, ambient temperature, inlet guide vane position, or the like.
  • the control system may then use the pilot airflow, pilot inlet temperature, and fuel temperature to calculate the pilot fuel flow to attain the Tad demand. This approach is desirable in systems where the loss in catalyst activity resulting from catalyst aging, poisoning, or the like is negligible.
  • combustion dynamics may include, for example, the dynamic pressure measured by the root-mean-squared (RMS) value of pressure variations within the main combustor chamber. Higher RMS values are generally indicative of combustion instability.
  • RMS root-mean-squared
  • the pilot fuel flow may be adjusted based on one or more measured combustion dynamics within the combustor. As catalyst activity decreases, the catalyst exit temperature may fall below the preferred temperature range that stabilizes the LPM flame, which may increase the measured combustion dynamics.
  • control system may increase the pilot fuel flow to increase the catalyst exit temperature, which may stabilize the LPM flame and reduce combustion dynamics to a desirable level.
  • a desirable level of combustion dynamics generally depends on the specific gas turbine and combustor design.
  • the catalytic pilot fuel flow may be increased to increase the catalyst exit temperature and reduce the combustion dynamics below the desired level of 1 psi RMS.
  • the upper limit is generally determined, at least in part, on the particular system and the particular application.
  • Another exemplary method for operating the catalytic pilot system includes closed loop feedback control on the catalyst exit temperature.
  • the pilot fuel flow is based on a schedule of catalyst exit temperature versus load or an engine fundamental characteristic consistent with load, such as compressor discharge temperature, exhaust gas temperature, turbine inlet temperature, total fuel flow to the engine, or the like. This method may accommodate for changes in catalyst activity resulting from catalyst aging, poisoning, or the like. Closed loop feedback control on the catalyst exit temperature may also be used in conjunction with other control strategies to accommodate for varying catalyst activity, for example, to supplement an operating strategy that does not compensate for catalyst aging.
  • Another exemplary method for operating the catalytic pilot system includes a fixed percentage fuel split schedule between the catalytic pilot and the main burner for a given load on the engine as shown below in Table 1.
  • the split of fuel between the catalytic pilot and LPM may be based on schedules of fuel split versus load or another engine fundamental consistent with load, such as compressor discharge temperature, exhaust gas temperature, turbine inlet temperature, total fuel flow to the engine, or the like.
  • This method generally does not accommodate for the loss in catalyst activity resulting from catalyst aging or poisoning. Therefore, it is desirable, but not necessary, that some level of closed loop feedback control, such as catalyst exit temperature or combustion dynamics in the main chamber also be included to supplement the fixed fuel schedule.
  • Table 1 Example of fixed percentage fuel split schedule to control a catalytic pilot system.
  • Table 1 is illustrative only and various other fixed fuel schedules will be apparent to those skilled in the art.
  • Another exemplary method for operating the catalytic pilot system includes a fixed mass flow fuel schedule is shown below in Table 2.
  • the fuel flow to the catalytic pilot can be based on a schedule of fixed fuel flow versus load or some engine fundamental consistent with load, such at compressor discharge temperature, exhaust gas temperature, turbine inlet temperature, total fuel flow to the engine, or the like.
  • This method generally does not accommodate for the loss in catalyst activity resulting from catalyst aging or poisoning. Therefore, it is desirable, but not necessary, that some level of closed loop feedback control, such as catalyst exit temperature or combustion dynamics in the main chamber also be included to supplement the fixed mass flow fuel schedule.
  • Table 2 Example of fixed mass fuel flow schedule to control a catalytic pilot system.
  • the catalytic pilot is configured to operate at high equivalence ratios and increased catalyst exit gas temperatures.
  • the resulting NO x may be typical of the profile shown in Figure 15.
  • the NO x generally increases with the added fuel (heat/temperature) from the diffusion pilot. In general, additional stability is attained from the diffusion pilot, but at the cost of additional NO x emissions generated by the higher temperature combustion of the diffusion flame pilot.
  • the resulting NO x may decrease as additional fuel is delivered to the catalytic pilot as illustrated in Figure 15.
  • the additional fuel adds heat and increases the temperature of the gas exiting from the catalytic pilot to stabilize the main LPM flame without additional NO x emissions.
  • the graph of resulting NO x for a diffusion flame pilot and a catalytic pilot for given pilot fuel fraction percentages is illustrative only and that the curves may vary in shape and value depending on the particular system such as pilot and combustor designs as well as fuel, pressure, and the like.
  • the catalytic pilot emission curve may remain nearly constant or slightly increase with the added fuel (heat/temperature) from the catalytic pilot as illustrated in Figure 16, but generally will be less than a similar system with a diffusion flame pilot.
  • the stability of the LPM flame may be measured in terms of lean- blow-out (LBO) and dynamic pressure.
  • LBO lean- blow-out
  • a plot of catalyst exit temperature ranging from approximately 1200 to 1800 °F versus pilot equivalence ratio ( ⁇ ) is shown in Figure 17 and illustrates for that for an exemplary catalyst design the directly proportional relationship between exit temperature and ⁇ .
  • Table 3 below summarizes the improved LBO performance with increasing ⁇ (equivalent to catalyst exit gas temperature).
  • Table 3 Lean blow-out (LBO) performance for different pilot configurations.
  • Dynamic pressure may be measured by the root mean square (RMS) of the combustor pressure fluctuations. Higher RMS values generally indicate combustion instability.
  • Figure 18 illustrates an exemplary plot of the RMS pressure versus the overall equivalence ratio for three different pilot configurations at several different pilot ⁇ . In particular, a diffusion pilot, premixed pilot, and a catalytic pilot configuration are compared. The exemplary plot shows that the most stable system (lowest RMS) was measured with a catalytic pilot operating at its highest ⁇ (equivalent to outlet gas temperature). Therefore, improved combustor stability may be improved by both the catalytic pilot operating at a high equivalence ratio and increased catalyst exit gas temperature.
  • RMS root mean square
  • the over-all fuel-air ratio or air fuel ratio (AFR)
  • AFR air fuel ratio
  • the pilot fuel flow is increased by lOpph
  • the main fuel flow should be decreased by lOpph so that the over-all fuel-air ratio and combustor exit temperature remains unchanged.
  • the inlet fuel-air ratio will differ (as illustrated in Figure 19) to produce the same exit temperature.
  • the composition of the pilot exit gas of catalyst A will differ from that of catalyst B.
  • catalyst A has approximately a 25% conversion rate versus catalyst B with approximately a 50% conversion rate.
  • the fuel concentration or mass fuel flow to catalyst A will be twice that of catalyst B.
  • the exit composition of catalyst A will contain, for example, 75pph fuel versus 25pph exiting catalyst B according to the following exemplary conditions:
  • Tout 900 °C with 75pph unburned fuel
  • Tin 450 °C with 50pph fuel x50% conversion of fuel
  • Tout 900 °C with 25pph unburned fuel
  • the unburned fuel exiting the pilot will combust without forming NO x (or possibly forming very little NO x ) because of the uniform and lean fuel-air mixture.
  • the main fuel flow of combustor A will be 50pph less than the main fuel flow of combustor B. Therefore, the available fuel to generate NO x in the main LPM flame will be less in combustor A relative to combustor B and therefore combustor A may have a lower NO x emissions than combustor B even though the pilot exit gas temperature for both combustors may be the same.
  • the total mass flow exiting pilot catalyst A will be greater than pilot catalyst B.
  • the additional high temperature mass flow exiting the catalytic pilot to the LPM flame may provide additional flame stability.
  • the amount of stability gained may depend on the design and operation of the main LPM combustor.
  • For an exemplary combustor exit temperature corresponding generally to the AFR as described above, there is generally a maximum pilot-to-main fiiel ratio where the main burner may become too lean to sustain combustion, resulting in lean-blow-out (LBO).
  • LBO lean-blow-out
  • the highest pilot-to-main fuel ratio attainable is in the range of approximately 0.14 to 0.16. It may be possible, however, to attain pilot-to-main fuel ratios greater than 0.16 for higher combustor exit temperatures or AFR.

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Abstract

L'invention concerne un foyer d'un système de combustion. Le foyer comprend une région d'entrée recevant de l'air provenant d'un compresseur, un assemblage pilote (110) et un assemblage principal injecteur de vaporisation (116). L'assemblage pilote peut comporter une région d'entrée pilote (112) recevant au moins une partie de l'air, un catalyseur (113) disposé en aval de la région pilote, un injecteur de combustible pilote (111) amenant le combustible pilote en amont du catalyseur, et une région de sortie pilote disposée en aval du catalyseur. L'assemblage principal d'injecteur de vaporisation peut comprendre une région d'entrée et un injecteur de combustible disposée en aval de cette région d'entrée.
EP03716124A 2002-02-22 2003-02-21 Systeme de combustion pilote par voie catalytique et procedes de fonctionnement Withdrawn EP1485593A1 (fr)

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