EP1448755A1 - Ground glass surface or object treating agent, use thereof, and method of making same - Google Patents

Ground glass surface or object treating agent, use thereof, and method of making same

Info

Publication number
EP1448755A1
EP1448755A1 EP02776402A EP02776402A EP1448755A1 EP 1448755 A1 EP1448755 A1 EP 1448755A1 EP 02776402 A EP02776402 A EP 02776402A EP 02776402 A EP02776402 A EP 02776402A EP 1448755 A1 EP1448755 A1 EP 1448755A1
Authority
EP
European Patent Office
Prior art keywords
glass
agent
ground
treating agent
surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02776402A
Other languages
German (de)
French (fr)
Other versions
EP1448755A4 (en
Inventor
Steven C. Haines
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Earthstone International LLC
Original Assignee
Earthstone International LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Earthstone International LLC filed Critical Earthstone International LLC
Publication of EP1448755A1 publication Critical patent/EP1448755A1/en
Publication of EP1448755A4 publication Critical patent/EP1448755A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned

Definitions

  • the present invention relates to a surface or object treating agent that includes ground glass, as well as the use for this agent and a method of making such an agent.
  • the surface or object treating method of the present invention is characterized primarily by the steps of providing an agent that comprises at least ground foamed glass, and contacting a surface or object that is to be treated with the agent and then providing relative movement between the agent and the surface or object to treat the surface or object.
  • an agent that comprises at least ground foamed glass
  • the round ground glass particles act as a more gentle abrasive while the sharp particles of ground foamed glass are a more aggressive abrasive.
  • a large number of combinations of glass types and grit sizes can produce many very specific abrasion levels for many different applications.
  • the agent is a dry agent that is a mixture of 1.0 to 99.9% by weight ground foamed glass, 0.0 to 98.9% by weight ground glass, and 0.1 to 10% by weight of a disinfectant powder and/or a surfactant powder.
  • the disinfectant powder is an antibacterial substance, and can, for example, be citrus based, such as the grapefruit seed extract CITRICIDAL.
  • the surfactant is, for example, a coconut oil based soap, such as MACKANATE CM-100F.
  • the agent mixture can also include a fragrance, which can be a powder or can be in liquid form.
  • a fragrance which can be a powder or can be in liquid form.
  • D-LIMONENE One example of a suitable scent liquid is D-LIMONENE.
  • the surface or object treating agent can be in liquid or gel form.
  • the agent can be a mixture of 1.0 to 88.0% by weight ground foamed glass, 0.0 to 81.0% by weight ground glass, 10.0 to 90.0 % by weight water, along with 2.0 to 10.0% by weight binder, plus optionally 0.5 to 5.0 % by weight thickener and/or 0.5 to 10% by weight surfactant.
  • An example of a suitable binder could be GERMABEN II, and an example of a suitable thickener could be CARBOPOL 940 POLYMER, which is a water-soluble resin from the B.F. Goodrich Chemical Company and has good gel forming properties.
  • a suitable surfactant for the inventive surface or object treating agent in the form of a gel could be sodium hydroxide.
  • the gel agent mixture could additionally include 0.1 to 5.0% by weight fragrance and/or color.
  • One example of a suitable fragrance would be lemon fragrance B.S., and examples of suitable colors could be FD&C Yellow No.5 and D&C Green No. 3.
  • the ground foamed glass could be manufactured from virgin glass, recycled glass or a mixture thereof.
  • the ground glass could be a virgin glass, recycled glass, or a mixture thereof.
  • the ground foamed glass could be a waste product of a foamed glass manufacturing process of other products.
  • the glass and foamed glass in the inventive surface or object treating agent is ground.
  • the glass is ground or otherwise converted to small or very small particles in any suitable manner, for example by means of a ball mill.
  • the term "ground” is used to refer to the conversion of glass into particles regardless of the process used to produce the particles.
  • the glass is ground so that it has a particle size of no greater than 12 mesh.
  • the presently preferred size range for the glass particles is 12 to 400 mesh, although the ground glass or foamed glass could also contain finer powder.
  • the ground glass particles either prior to being mixed with any additional substituents or subsequent to being mixed with other substituents, can be passed through an appropriate sieve or screen.
  • the present invention not only provides a unique method for treating a surface or an object, but also provides a method of making a unique surface or object treating agent, and also provides the unique surface or object treating agent.
  • the surface or object treating agent of the present invention is an effective, non-toxic agent that can be used for industrial as well as domestic applications.
  • the surface or object treating agent of the present invention can be used in several ways.
  • the powder or gel can be placed directly on the surface or object that is to be treated, or can be placed on a sponge or cloth.
  • the surface (or object) or cloth can be first moistened.
  • the ground glasses and dry powders were mixed together in a drum mixer for 10-15 minutes.
  • the scent liquid was then slowly added and mixing continued for an additional 10-15 minutes.
  • the ground glasses and dry powders were mixed together in a paddle mixer for 10-15 minutes.
  • the liquids were separately mixed together.
  • the dry mixture was then slowly added to the liquid and mixed together for 10-15 minutes.
  • the final mixture was mixed for 10-15 minutes at high speed while being pulled through a fine screen to thoroughly mix in any dry powder lumps.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Processing Of Solid Wastes (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Glass Compositions (AREA)

Abstract

A ground glass surface or object treating agent, a use therefor, and a method of making the same are provided. The agent comprises at least ground foamed glass, and if in dry form can also include disinfectant powder and/or surfactant powder. If in gel form, the agent can also include water as well as binder, thickener and/or surfactant. The ground glass is virgin glass, recycled glass or a mixture thereof, and preferably has a particle size of no greater than 12 mesh.

Description

GROUND GLASS SURFACE OR OBJECT TREATING AGENT, USE THEREFOR, AND METHOD OF MAKING SAME
Technical Field
The present invention relates to a surface or object treating agent that includes ground glass, as well as the use for this agent and a method of making such an agent.
Numerous products are known for treating surfaces and objects, in particular for polishing or cleaning objects and surfaces as well as for removing unwanted or undesirable material from such objects and surfaces. Unfortunately, many of the known products contain toxic or otherwise environmentally unfriendly chemicals. In addition, some of these products are expensive to produce, and are not always particularly effective.
It is therefore an object of the present invention to provide a non-toxic economical and effective surface or object treating agent that is specifically formulated, as well as a method of making the same. Disclosure of the Invention
This object, and other objects and advantages of the present invention, will appear more clearly from the following specification in conjunction with the accompanying Examples.
The surface or object treating method of the present invention is characterized primarily by the steps of providing an agent that comprises at least ground foamed glass, and contacting a surface or object that is to be treated with the agent and then providing relative movement between the agent and the surface or object to treat the surface or object. Whereas currently known products contain one type of abrasive with one grit size, pursuant to the current invention, the round ground glass particles act as a more gentle abrasive while the sharp particles of ground foamed glass are a more aggressive abrasive. A large number of combinations of glass types and grit sizes can produce many very specific abrasion levels for many different applications. Detailed Description of Preferred Embodiments
Pursuant to one aspect of the present invention, the agent is a dry agent that is a mixture of 1.0 to 99.9% by weight ground foamed glass, 0.0 to 98.9% by weight ground glass, and 0.1 to 10% by weight of a disinfectant powder and/or a surfactant powder. The disinfectant powder is an antibacterial substance, and can, for example, be citrus based, such as the grapefruit seed extract CITRICIDAL. The surfactant is, for example, a coconut oil based soap, such as MACKANATE CM-100F.
The agent mixture can also include a fragrance, which can be a powder or can be in liquid form. One example of a suitable scent liquid is D-LIMONENE.
Pursuant to another exemplary specific embodiment of the present invention, the surface or object treating agent can be in liquid or gel form. In such a case, the agent can be a mixture of 1.0 to 88.0% by weight ground foamed glass, 0.0 to 81.0% by weight ground glass, 10.0 to 90.0 % by weight water, along with 2.0 to 10.0% by weight binder, plus optionally 0.5 to 5.0 % by weight thickener and/or 0.5 to 10% by weight surfactant. An example of a suitable binder could be GERMABEN II, and an example of a suitable thickener could be CARBOPOL 940 POLYMER, which is a water-soluble resin from the B.F. Goodrich Chemical Company and has good gel forming properties. An example of a suitable surfactant for the inventive surface or object treating agent in the form of a gel could be sodium hydroxide. The gel agent mixture could additionally include 0.1 to 5.0% by weight fragrance and/or color. One example of a suitable fragrance would be lemon fragrance B.S., and examples of suitable colors could be FD&C Yellow No.5 and D&C Green No. 3.
The ground foamed glass could be manufactured from virgin glass, recycled glass or a mixture thereof. The ground glass could be a virgin glass, recycled glass, or a mixture thereof. In addition, the ground foamed glass could be a waste product of a foamed glass manufacturing process of other products.
As indicated above, the glass and foamed glass in the inventive surface or object treating agent is ground. In particular, the glass is ground or otherwise converted to small or very small particles in any suitable manner, for example by means of a ball mill. In this application the term "ground" is used to refer to the conversion of glass into particles regardless of the process used to produce the particles. In addition, the glass is ground so that it has a particle size of no greater than 12 mesh. The presently preferred size range for the glass particles is 12 to 400 mesh, although the ground glass or foamed glass could also contain finer powder. To ensure that the agent mixture contains no particles of a size greater than 12 mesh, the ground glass particles, either prior to being mixed with any additional substituents or subsequent to being mixed with other substituents, can be passed through an appropriate sieve or screen.
The present invention not only provides a unique method for treating a surface or an object, but also provides a method of making a unique surface or object treating agent, and also provides the unique surface or object treating agent. The surface or object treating agent of the present invention is an effective, non-toxic agent that can be used for industrial as well as domestic applications.
The surface or object treating agent of the present invention can be used in several ways. For example, the powder or gel can be placed directly on the surface or object that is to be treated, or can be placed on a sponge or cloth. In the case of the dry agent, the surface (or object) or cloth can be first moistened.
It should also be noted that for certain applications, it could be expedient to additionally add to the ground glass of the agent another abrasive and/or a suitable chemical such as an aggressive chemical capable of dissolving material on an object or a surface.
The present invention will now be explained further in conjunction with the following two examples.
EXAMPLE 1
To make a dry surface or object treating agent the following substituents were provided:
WT.% Abrasive 200 mesh recycled glass 90.0
Abrasive 60 mesh recycled foamed glass 5.9
Disinfectant Powder CITRICIDAL Grapefruit Seed 0.1
Extract Scent Liquid D-LIMONENE - technical grade 1.5
Surfactant powder MACKANATE CM-200F 2.5
The ground glasses and dry powders were mixed together in a drum mixer for 10-15 minutes. The scent liquid was then slowly added and mixing continued for an additional 10-15 minutes.
EXAMPLE 2
To provide the inventive surface or object treating agent in gel form, the following substituents were provided: WT.%
Water 68.6%o
Recycled glass and foamed glass mixture ECOMAX 20.0
Binder GERMABEN II 5.0
Thickener CARBOPOL 940 Polymer 2.5
Surfactant Sodium Hydroxide 2.5
Fragrance Lemon Fragrance B. S. 1.0
Color FD&C Yellow No. 5 0.2
D&C Green No. 3 0.2
The ground glasses and dry powders were mixed together in a paddle mixer for 10-15 minutes. The liquids were separately mixed together. The dry mixture was then slowly added to the liquid and mixed together for 10-15 minutes. The final mixture was mixed for 10-15 minutes at high speed while being pulled through a fine screen to thoroughly mix in any dry powder lumps.
The present invention is, of course, in no way restricted to the specific disclosure of the specification and Examples, but also encompasses any modifications within the scope of the appended claims.

Claims

CLAIMS:
1. A method of treating a surface or an object, characterized by the steps of: providing an agent that comprises at least ground foamed glass, and contacting a surface or an object with said agent and providing relative movement between said agent and said surface or object to treat said surface or object.
2. A method of making a surface or object treating agent, characterized by the step of: grinding at least foamed glass to form glass particles of a size no greater than 12 mesh.
3. A method according to claim 1 or 2, characterized in that said agent is a mixture comprising 1.0 to 99.9% by weight ground foamed glass, 0.0 to 98.9% by weight ground glass, and at least one of a disinfectant powder and surfactant powder, and may also include a fragrance.
4. A method according to claim 1 or 2, characterized in that said agent is a mixture comprising 1.0 to 88.0% by weight ground foamed glass, 0.0 to 87.0%> by weight ground glass, 10.0 to 90.0%) by weight water, and 2.0 to 10.0% by weight binder, and said mixture may additionally include at least one of a thickener, a surfactant, fragrance and color.
5. A method according to claim 1 or 2, characterized in that said glass is at least one of virgin and recycled glass.
6. A method according to claim 1 , characterized in that said ground glass essentially has a particle size no greater than 12 mesh.
7. A surface or object treating agent comprising at least ground foamed glass.
8. A surface or object treating agent according to claim 7, characterized in that said agent further includes at least one of a disinfectant powder and surfactant powder, and may also include a fragrance.
9. A surface or object treating agent according to claim 7, characterized in that said agent further includes water and a binder, and may additionally include at least one of a thickener, a surfactant, fragrance and color.
10. A surface or object treating agent according to claim 7, characterized in that said glass is at least one of virgin and recycled glass.
EP02776402A 2001-10-31 2002-10-31 Ground glass surface or object treating agent, use thereof, and method of making same Withdrawn EP1448755A4 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US3927 1998-01-07
US392701A 2001-10-31 2001-10-31
US10/273,764 US20030087589A1 (en) 2001-10-31 2002-10-18 Foamed glass and ground glass surface or object treating agent, use therefor, and method of making same
US273764 2002-10-18
PCT/US2002/035011 WO2003038024A1 (en) 2001-10-31 2002-10-31 Ground glass surface or object treating agent, use thereof, and method of making same

Publications (2)

Publication Number Publication Date
EP1448755A1 true EP1448755A1 (en) 2004-08-25
EP1448755A4 EP1448755A4 (en) 2005-07-20

Family

ID=26672380

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02776402A Withdrawn EP1448755A4 (en) 2001-10-31 2002-10-31 Ground glass surface or object treating agent, use thereof, and method of making same

Country Status (6)

Country Link
US (1) US20030087589A1 (en)
EP (1) EP1448755A4 (en)
JP (1) JP2005534719A (en)
CN (1) CN1589315A (en)
BR (1) BR0213789A (en)
WO (1) WO2003038024A1 (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2826174A1 (en) * 1978-06-15 1979-12-20 Collo Gmbh Detergent compsns. for cleaning refractory vitreous materials - contg. adduct of polar organic cpd. and fluorine cpd.
US4188447A (en) * 1976-07-20 1980-02-12 Collo Gmbh Polymeric foam cleaning product
DE2843234A1 (en) * 1978-10-04 1980-04-17 Collo Gmbh Protective coating for glass and ceramics - contg. silicone resin and silicone oil
WO1988000613A1 (en) * 1986-07-24 1988-01-28 Technova Ipari Feijlesztési Bank Scrubbing and cleaning product harmless to the environment
EP0574830A1 (en) * 1992-06-12 1993-12-22 Dennert Poraver GmbH Method for raising fabrics
WO1997036835A1 (en) * 1996-03-29 1997-10-09 Ungerleider, Andrew Foamed glass article for preparing surfaces, use therefor, and method of making same
US5783543A (en) * 1994-03-30 1998-07-21 Henkel Kommanditgesellschaft Auf Aktien Scatterable carpet cleaning formulation containing rollable particles
US6135127A (en) * 1996-03-06 2000-10-24 Pieper; Gerard Process and machine for treating flat surfaces

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3874861A (en) * 1968-09-05 1975-04-01 Kurz Fredrik W A Method of producing foamed glass
US3673746A (en) * 1971-02-03 1972-07-04 Engelhard Hanovia Inc Method of polishing glass
US4207114A (en) * 1976-02-07 1980-06-10 Schneider Gmbh & Co. Foamed ceramic element and process for making same
US4155870A (en) * 1976-04-19 1979-05-22 Minnesota Mining And Manufacturing Company Skin cleaning compositions containing water-insoluble glass bubbles
US4541842A (en) * 1980-12-29 1985-09-17 Norton Company Glass bonded abrasive agglomerates
DE3428165A1 (en) * 1984-07-31 1986-02-06 Dennert, Hans Veit, 8602 Burghaslach METHOD FOR PRODUCING FOAM GLASS MOLDED BODIES
DE3469145D1 (en) * 1984-08-14 1988-03-10 Johan Szucs Stone and metal cleaning system
DE4102744A1 (en) * 1991-01-30 1992-08-06 Henkel Kgaa LOW-FOAMING SCRUBBING POWDER
US5928773A (en) * 1994-02-15 1999-07-27 Vitric Corporation Foamed glass articles and methods of making same and methods of controlling the pH of same within specific limits
US5782939A (en) * 1997-08-08 1998-07-21 Norton Company Low cost coated abrasives

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4188447A (en) * 1976-07-20 1980-02-12 Collo Gmbh Polymeric foam cleaning product
DE2826174A1 (en) * 1978-06-15 1979-12-20 Collo Gmbh Detergent compsns. for cleaning refractory vitreous materials - contg. adduct of polar organic cpd. and fluorine cpd.
DE2843234A1 (en) * 1978-10-04 1980-04-17 Collo Gmbh Protective coating for glass and ceramics - contg. silicone resin and silicone oil
WO1988000613A1 (en) * 1986-07-24 1988-01-28 Technova Ipari Feijlesztési Bank Scrubbing and cleaning product harmless to the environment
EP0574830A1 (en) * 1992-06-12 1993-12-22 Dennert Poraver GmbH Method for raising fabrics
US5783543A (en) * 1994-03-30 1998-07-21 Henkel Kommanditgesellschaft Auf Aktien Scatterable carpet cleaning formulation containing rollable particles
US6135127A (en) * 1996-03-06 2000-10-24 Pieper; Gerard Process and machine for treating flat surfaces
WO1997036835A1 (en) * 1996-03-29 1997-10-09 Ungerleider, Andrew Foamed glass article for preparing surfaces, use therefor, and method of making same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO03038024A1 *

Also Published As

Publication number Publication date
CN1589315A (en) 2005-03-02
BR0213789A (en) 2005-08-30
US20030087589A1 (en) 2003-05-08
EP1448755A4 (en) 2005-07-20
JP2005534719A (en) 2005-11-17
WO2003038024A1 (en) 2003-05-08

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