EP1448339A2 - Vermicular cast iron of high machinability and free from microporosities - Google Patents

Vermicular cast iron of high machinability and free from microporosities

Info

Publication number
EP1448339A2
EP1448339A2 EP02782548A EP02782548A EP1448339A2 EP 1448339 A2 EP1448339 A2 EP 1448339A2 EP 02782548 A EP02782548 A EP 02782548A EP 02782548 A EP02782548 A EP 02782548A EP 1448339 A2 EP1448339 A2 EP 1448339A2
Authority
EP
European Patent Office
Prior art keywords
cast iron
vermicular cast
free
microporosities
presenting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02782548A
Other languages
German (de)
French (fr)
Other versions
EP1448339A4 (en
Inventor
Wilson Luiz Guesser
Eitan Rua Albano Schmidt Nr. 1.499 MELLERAS
Isaias Masiero
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tupy Fundicoes Ltda
Original Assignee
Tupy Fundicoes Ltda
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tupy Fundicoes Ltda filed Critical Tupy Fundicoes Ltda
Publication of EP1448339A2 publication Critical patent/EP1448339A2/en
Publication of EP1448339A4 publication Critical patent/EP1448339A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/04Cast-iron alloys containing spheroidal graphite
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon

Definitions

  • the present report is about a vermicular cast iron, of high machinability and free from microporosity. More specifically, a vermicular cast iron of high machinability and free from microporosities that comprises classes between 350 and 500 MEGA PASCAL of ultimate tensile strength.
  • the vermicular cast iron represents a group of Fe-C-Si alloys, with Mn, P, S, and controlled additions of Mg, presenting graphite predominately in vermicular form (form IV according to Standard ASTM A247), with up to 20% of nodules (forms I and II as per Standard ASTM A247) in its microstructure.
  • the addition of complementary pearlitic elements, such as Mn, Cr, Cu and Sn allow one to obtain the desired class, which can vary between 350 and 500 Mega Pascal of ultimate tensile strength.
  • additions of Ti are also carried out to increase the resistance to wear out and to improve the lubrication of the cylinder in engine blocks.
  • Vermicular cast iron has been increasingly applied in automotive components such as internal combustion engine blocks, internal combustion engine heads, disks and brake drums. In general, its application involves the substitution of gray cast iron to increase tensile strength.
  • One of the goals of the present invention is to provide vermicular cast iron of high machinability, free from microporosities that allows the increase in the life of tools to be used with the cast part together with the innovated characteristics.
  • vermicular cast iron of high machinability, free form microporosities that presents a bigger amount of graphite per volume of vermicular cast iron; this increase being the amount of graphite obtained by the addition of nodules in the microstructure so that the percentage of those nodules be also increased in relation to the volume in the conventional vermicular cast iron.
  • the present invention proposes a vermicular cast iron of high machinability and free from microporosities that presents an amount of graphite between 12-15% in volume of vermicular cast iron; the increase in the amount of graphite is obtained with the addition of nodules to the microstructure, resulting in an amount between 20-40% in the volume of vermicular cast iron.
  • the machinability is improved, if compared to the conventional vermicular iron, with the limitation of elements that form carbide or carbonitrides
  • vermicular cast iron of high machinability and free from microporosities has a content of carbon between 3,6 and 3,9%, a content of Si between 2,0 and

Abstract

Vermicular cast iron of high machinability and free from microporosities, comprising classes between 350 and 500 MEGA PASCAL of ultimate tensile strength, presenting a bigger amount of graphite by volume of vermicular cast iron, this increase in the amount of graphite obtained with additional nodules in the microstructure so that the percentage of those nodules is also increased in relation to the volume of vermicular cast iron.

Description

"VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES" .
The present report is about a vermicular cast iron, of high machinability and free from microporosity. More specifically, a vermicular cast iron of high machinability and free from microporosities that comprises classes between 350 and 500 MEGA PASCAL of ultimate tensile strength.
As known to experts in the area, the vermicular cast iron represents a group of Fe-C-Si alloys, with Mn, P, S, and controlled additions of Mg, presenting graphite predominately in vermicular form (form IV according to Standard ASTM A247), with up to 20% of nodules (forms I and II as per Standard ASTM A247) in its microstructure. The addition of complementary pearlitic elements, such as Mn, Cr, Cu and Sn allow one to obtain the desired class, which can vary between 350 and 500 Mega Pascal of ultimate tensile strength.
In some cases, additions of Ti are also carried out to increase the resistance to wear out and to improve the lubrication of the cylinder in engine blocks.
Vermicular cast iron has been increasingly applied in automotive components such as internal combustion engine blocks, internal combustion engine heads, disks and brake drums. In general, its application involves the substitution of gray cast iron to increase tensile strength.
This substitution, however, brings some manufacturing problems not yet entirely solved such as the tendency to form solidification porosities and low machinability of the part.
The said tendency to form solidification porosities results in blanks at places of mass concentration that are usually the last places to solidify. This phenomenon occurs due to the part volumetric shrinkage which takes place when going from a liquid condition to a solid condition.
This problem is partially solved with the use of feeders at places of mass concentration which is not always possible in parts of high geometric complexity such as engine blocks and heads.
The low machinability of conventional vermicular cast iron is already known and reflects in the decrease of a tool life when compared to gray cast iron machining. This decrease depends on the particular machining operation, but in general is not lower than 50%, as in milling and boring operations; it could, though, reach a 95% decrease in the life of the tool in cylinder .hole reaming operations.
One of the goals of the present invention is to provide vermicular cast iron of high machinability, free from microporosities that allows the increase in the life of tools to be used with the cast part together with the innovated characteristics.
This and other goals and advantages of the present invention are achieved with the vermicular cast iron of high machinability, free form microporosities that presents a bigger amount of graphite per volume of vermicular cast iron; this increase being the amount of graphite obtained by the addition of nodules in the microstructure so that the percentage of those nodules be also increased in relation to the volume in the conventional vermicular cast iron.
Particularly, the present invention proposes a vermicular cast iron of high machinability and free from microporosities that presents an amount of graphite between 12-15% in volume of vermicular cast iron; the increase in the amount of graphite is obtained with the addition of nodules to the microstructure, resulting in an amount between 20-40% in the volume of vermicular cast iron.
With this increase in the amount of graphite it is possible to counterbalance the contraction of solidification, producing parts that are free from solidification porosities. At the same time, this increase in the amount of graphite results in the improvement of machinability due to the lubrication effect that the graphite exerts on the cutting tool.
On the other hand, as the increase of the amount of graphite occurs by the addition of a percentage of nodules, the tensile strength properties are not decreased.
In addition, the machinability is improved, if compared to the conventional vermicular iron, with the limitation of elements that form carbide or carbonitrides
(Cr, Mn, Ti) and with the formation of pearlite between 50 and 100% pearlite, according to the class (350 to 500 Mega Pascal), lamellar spacing bigger than 0,5 microns, which is obtained under adequate part cooling at a temperature ranging between 800° and 650°C.
Therefore the vermicular cast iron of high machinability and free from microporosities has a content of carbon between 3,6 and 3,9%, a content of Si between 2,0 and
2,6%, a content of Cr lower than 0,05%, a content of Mn lower than 0,40% and a content of Ti lower than 0,015 %.
The machinability advantages aforementioned are thus increased.
Despite the fact that a preferred constructive concept has been described and illustrated, it is important to mention that changes are feasible and possible to be carried out without deviating from the scope of the present invention.

Claims

Claims
1- "VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES", comprising classes between 350 and 500 MEGA PASCAL of ultimate tensile strength, characterized by presenting a amount of graphite per volume of vermicular cast iron; this increase in the amount of graphite is obtained by additional nodules in the microstructure so that the percentage of those nodules is also increased in relation to the volume of the vermicular cast iron.
2- "VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES", as per claim 1, characterized by presenting machinability equal or bigger than 40% of conventional vermicular cast iron, machinability evaluated by the life of the cutting tool.
3- "VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES", as per claim 1 or 2, characterized by presenting an amount of graphite between 12-15% in volume of vermicular cast iron; and with the presence of nodules in the microstructure ranging between 20-40% in weight of the vermicular cast iron, without the presence of graphite lamellar.
4- "VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES", as per claim 1 or 2 or 3, characterized by presenting a metallic matrix microstructure comprised of ferrite and pearlite, proportion of 50 to 100% pearlite, according to class (350 to 500 Mega Pascal) , and with the pearlite presenting interlamellar spacing of around microns in a section thickness of 5mm.
5- "VERMICULAR CAST IRON OF HIGH MACHINABILITY AND FREE FROM MICROPOROSITIES", as per claim 1 or 2 or 3 or 4, characterized by presenting a content of carbon between 3,6 and 3,9%, a content of Si between 2,0 and 2,6%, a content of Cr lower than 0,05%, a content of Mn lower than 0,40% and a content of Ti lower than 0,015 %.
EP02782548A 2001-11-27 2002-11-26 Vermicular cast iron of high machinability and free from microporosities Withdrawn EP1448339A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
BR0105988A BR0105988B1 (en) 2001-11-27 2001-11-27 High machinability and microporosity-free vermicular cast iron.
BR0105988 2001-11-27
PCT/BR2002/000163 WO2003045624A2 (en) 2001-11-27 2002-11-26 Vermicular cast iron of high machinability and free from microporosities

Publications (2)

Publication Number Publication Date
EP1448339A2 true EP1448339A2 (en) 2004-08-25
EP1448339A4 EP1448339A4 (en) 2005-02-23

Family

ID=3948159

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02782548A Withdrawn EP1448339A4 (en) 2001-11-27 2002-11-26 Vermicular cast iron of high machinability and free from microporosities

Country Status (3)

Country Link
EP (1) EP1448339A4 (en)
BR (1) BR0105988B1 (en)
WO (1) WO2003045624A2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104480377B (en) * 2014-12-15 2017-05-17 山东省源通机械股份有限公司 Vermicular graphite cast iron single cylinder diesel engine body with high vermicular graphite rate and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1069058A (en) * 1965-05-04 1967-05-17 Int Nickel Ltd Cast iron
US4409028A (en) * 1979-10-24 1983-10-11 Moore William H Process for producing cast iron
JPH04128340A (en) * 1990-09-19 1992-04-28 Hitachi Ltd Compact vermicular graphite cast iron and sheave for elevator using the same
EP0769615A1 (en) * 1995-10-17 1997-04-23 Ford Motor Company Limited Engine cylinder block
JPH09202935A (en) * 1996-11-15 1997-08-05 Hitachi Ltd Compacted vermicular graphite cast iron and sliding device using the same

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN85107725B (en) * 1985-10-17 1987-12-23 陕西机械学院 Creeping graphite cast iron for manufacturing mould for glass bottle
US5858127A (en) * 1996-08-02 1999-01-12 Gunite Corporation Metal alloys and brake drums made from such alloys
SE9904257D0 (en) * 1999-11-23 1999-11-23 Sintercast Ab New cast iron alloy

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1069058A (en) * 1965-05-04 1967-05-17 Int Nickel Ltd Cast iron
US4409028A (en) * 1979-10-24 1983-10-11 Moore William H Process for producing cast iron
JPH04128340A (en) * 1990-09-19 1992-04-28 Hitachi Ltd Compact vermicular graphite cast iron and sheave for elevator using the same
EP0769615A1 (en) * 1995-10-17 1997-04-23 Ford Motor Company Limited Engine cylinder block
JPH09202935A (en) * 1996-11-15 1997-08-05 Hitachi Ltd Compacted vermicular graphite cast iron and sliding device using the same

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 0163, no. 94 (C-0976), 21 August 1992 (1992-08-21) & JP 4 128340 A (HITACHI LTD), 28 April 1992 (1992-04-28) *
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 12, 25 December 1997 (1997-12-25) & JP 9 202935 A (HITACHI LTD), 5 August 1997 (1997-08-05) *
ROHRIG, K.: "Cast Iron With Vermicular Graphite-Processing, Properties, Applications.ÄGusseisen mit Vermiculargraphit -Herstellung, Eigenschaften , Anwendung .Ü." KONSTRUIEREN & GIESSEN 16, (1), 7-27, PHOTOMICROGRAPHS, GRAPHS, 29 REF. ISSN: 0341-6615, 1991, XP009041753 *
See also references of WO03045624A2 *

Also Published As

Publication number Publication date
WO2003045624A2 (en) 2003-06-05
WO2003045624A3 (en) 2004-03-18
EP1448339A4 (en) 2005-02-23
BR0105988A (en) 2002-11-12
BR0105988B1 (en) 2009-08-11

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