EP1444477B1 - Revetement de cone de charge creuse - Google Patents
Revetement de cone de charge creuse Download PDFInfo
- Publication number
- EP1444477B1 EP1444477B1 EP02803062A EP02803062A EP1444477B1 EP 1444477 B1 EP1444477 B1 EP 1444477B1 EP 02803062 A EP02803062 A EP 02803062A EP 02803062 A EP02803062 A EP 02803062A EP 1444477 B1 EP1444477 B1 EP 1444477B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- liner
- composition
- nano
- binder
- tungsten
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 22
- 239000010937 tungsten Substances 0.000 claims abstract description 22
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- 239000013078 crystal Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 25
- 239000002360 explosive Substances 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- 229910052755 nonmetal Inorganic materials 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000012255 powdered metal Substances 0.000 claims description 3
- 229910052715 tantalum Inorganic materials 0.000 claims description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 238000000034 method Methods 0.000 description 17
- 230000035515 penetration Effects 0.000 description 11
- 239000007789 gas Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000003129 oil well Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000005474 detonation Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910001080 W alloy Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002707 nanocrystalline material Substances 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013077 target material Substances 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B1/00—Explosive charges characterised by form or shape but not dependent on shape of container
- F42B1/02—Shaped or hollow charges
- F42B1/032—Shaped or hollow charges characterised by the material of the liner
Definitions
- This invention relates to the field of explosive charges and more specifically to liners for shaped charges and the composition of such liners.
- a liner for a shaped change having the features of the preamble of claim 1 is known from EP 0 160 118 A.
- Shaped charges comprise a housing, a quantity of high explosive such as RDX and a liner which is inserted into the high explosive.
- high explosive such as RDX
- the liner is often formed into a conical shape by compressing powdered metal but other shapes can be equally effective.
- liners are made from wrought metals and alloys by a variety of methods in a variety of shapes and sizes.
- Shaped charges are used for a number of military and commercial purposes.
- perforators are used to penetrate oil well casings and the surrounding hydrocarbon bearing rocks.
- Another method for maximising penetration depth is to optimise the entire warhead/perforator design including the method of initiation and the shape of the liner. However, even if this is done the amount of energy that is transferred to the liner is necessarily limited by geometry and the amount of explosive.
- a still further method for maximising penetration depth is to change the liner material used for the shaped charge liner.
- the liners for shaped charges have typically been composed primarily of wrought copper but it is known in the art that other materials exhibit benefits in certain applications.
- green compacted liners are used that comprise a relatively high percentage of tungsten powders in combination with soft metallic and non metallic binders .
- US Patents 5656791 and 5567906 disclose liners for shaped charges having a composition of up to 90% tungsten. Such liners show improved penetration depths over traditional liner compositions but have the drawback of being brittle.
- this invention provides a liner for a shaped charge having a composition comprising greater than 90% by weight of powdered tungsten and up to 10% by weight of a powdered binder, the composition being formed into a substantially conically shaped body and having a crystal structure of substantially equi-axed grains with a grain size of between 25nano-metres to 1 micron.
- penetration depth is proportional to (jet length) x (density ratio of liner material) 1/2 . Therefore, increasing the density of the liner material will increase the penetration depth of the jet.
- Tungsten has a high density and so by using a liner that comprises greater than 90% by weight tungsten the penetration depth is improved over prior art liners, particularly in the oil and gas industry..
- grain size means the average grain diameter as determined using ASTM Designation: E112 Intercept (or Heyn) procedure.
- the jet so produced has properties at least comparable to that derived from a depleted Uranium (DU) liner.
- DU Uranium
- tungsten becomes increasingly attractive as a shaped charge liner material due to its enhanced dynamic plasticity.
- Materials referred to herein with grain sizes less than 100 nano-metres are defined to be "nano-crystalline materials”.
- the liner can be formed either by pressing the composition to form a green compact or by sintering the composition.
- the binder can be any powdered metal or non-metal material but preferably comprises soft dense materials like lead, tantalum, molybdenum and graphite.
- the tungsten can be coated with the binder material which may comprise a metal like lead or a non metal such as a polymeric material.
- the liner can be sintered in order to provide a more robust structure.
- Suitable binders in this case include copper, nickel, iron, cobalt and others either singly or in combination.
- Nano-crystalline tungsten can be obtained via a variety of processes such as chemical vapour deposition (CVD) in which tungsten can be produced by the reduction of hexa-fluoride gas by hydrogen leading to ultra-fine tungsten powders.
- CVD chemical vapour deposition
- Ultra-fine tungsten can also be produced from the gas phase by means of gas condensation techniques. There are many variations to this physical vapour deposition (PVD) condensation technique.
- PVD physical vapour deposition
- Ultra-fine powders comprising nano-crystalline particles can also be produced via a plasma arc reactor as described in PCT/GB01/00553 and WO 93/02787.
- a shaped charge of generally conventional configuration comprises a cylindrical casing 1 of conical form or metallic material and a liner 2 according to the invention of conical form and typically of say 1 to 5% of the liner diameter as wall thickness but may be as much as 10% in extreme cases .
- the liner 2 fits closely in one end of the cylindrical casing 1.
- High explosive material 3 is within the volume defined by the casing and the liner.
- a suitable starting material for the liner may comprise a mixture of 90 % by weight of nano-crystalline powdered tungsten and the remaining percentage 10% by weight of nano-crystalline powdered binder material.
- the binder material comprises soft metals such as lead, tantalum and molybdenum or materials such as graphite.
- the nano-crystalline powder composition material can be obtained via any of the above mentioned processes.
- One method of manufacture of liners is by pressing a measure of intimately mixed and blended powders in a die set to produce the finished liner as a green compact.
- intimately mixed powders may be employed in exactly the same way as described above, but the green compacted product is a near net shape allowing some form of sintering or infiltration process to take place.
- Figure 2 shows the microstructure of a W-Cu liner material following construction.
- the liner has been formed from a mixture of 90 % by weight of nano-crystalline powdered tungsten and the remaining percentage 10% by weight of nano-crystalline powdered binder material, in this case copper. This liner has been formed by sintering the composition.
- Figure 2 is derived from photomicrographs of the surface of the specification at a magnification of 100 times.
- the micro-structure of the liner comprises a matrix of tungsten grains 10 (dark grey) of approximately 5-10 microns and copper grains 20 (light grey). If the liner had been formed as a green compact then the grain size would be substantially less, for example 1 micron or less.
Landscapes
- General Engineering & Computer Science (AREA)
- Engineering & Computer Science (AREA)
- Powder Metallurgy (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
- Apparatus For Radiation Diagnosis (AREA)
- Ceramic Products (AREA)
- Liquid Crystal (AREA)
- Polishing Bodies And Polishing Tools (AREA)
- Photoreceptors In Electrophotography (AREA)
- Paper (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Developing Agents For Electrophotography (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Road Paving Structures (AREA)
Claims (11)
- Revêtement pour une charge creuse dont la composition comprend plus de 90 % en poids de tungstène en poudre et jusqu'à 10 % en poids d'un liant en poudre, la composition étant formée en un corps creux pratiquement conique, caractérisé en ce qu'il a une structure cristalline de grains pratiquement équiaxes dont la grosseur de grain est comprise entre 25 nanomètres et 1 micron.
- Revêtement selon la revendication 1, caractérisé en ce que la grosseur de grain dans la composition est comprise entre 25 et 100 nanomètres.
- Revêtement selon l'une des revendications précédentes, caractérisé en ce que la composition du revêtement est formée par compression sous forme de comprimé non fritté.
- Revêtement selon la revendication 3, caractérisé en ce que le liant comprend un métal nanocristallin en poudre.
- Revêtement selon la revendication 4, caractérisé en ce que le revêtement est choisi parmi le groupe qui comprend le plomb, le cuivre, le tantale, le molybdène et leurs combinaisons.
- Revêtement selon la revendication 3, caractérisé en ce que le liant comprend un non-métal nanocristallin en poudre.
- Revêtement selon la revendication 6, caractérisé en ce que le liant est un matériau polymérique non métallique.
- Revêtement selon l'une des revendications précédentes, caractérisé en ce que le matériau du liant recouvre le tungstène.
- Revêtement selon la revendication 1 ou 2, dans lequel la composition du revêtement est frittée.
- Revêtement selon la revendication 9, caractérisé en ce que le liant comprend du cuivre, du nickel, du fer, du cobalt ou leurs combinaisons nanocristallins en poudre.
- Charge creuse comportant un boîtier, une certaine quantité d'explosif brisant introduite dans le boîtier et un revêtement selon l'une des revendications précédentes et introduit dans le boîtier de telle sorte que l'explosif brisant se trouve entre le revêtement et le boîtier.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0127296 | 2001-11-14 | ||
GB0127296A GB2382122A (en) | 2001-11-14 | 2001-11-14 | Shaped charge liner |
PCT/GB2002/005092 WO2003042625A1 (fr) | 2001-11-14 | 2002-11-12 | Revetement de cone de charge creuse |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1444477A1 EP1444477A1 (fr) | 2004-08-11 |
EP1444477B1 true EP1444477B1 (fr) | 2006-07-26 |
Family
ID=9925740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02803062A Expired - Lifetime EP1444477B1 (fr) | 2001-11-14 | 2002-11-12 | Revetement de cone de charge creuse |
Country Status (11)
Country | Link |
---|---|
US (1) | US7261036B2 (fr) |
EP (1) | EP1444477B1 (fr) |
CN (1) | CN1313798C (fr) |
AT (1) | ATE334375T1 (fr) |
AU (1) | AU2002363806B2 (fr) |
CA (1) | CA2467103C (fr) |
DE (1) | DE60213446T2 (fr) |
GB (1) | GB2382122A (fr) |
NO (1) | NO328843B1 (fr) |
RU (1) | RU2258195C1 (fr) |
WO (1) | WO2003042625A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018234013A1 (fr) * | 2017-06-23 | 2018-12-27 | Dynaenergetics Gmbh & Co. Kg | Revêtement de charge creuse, procédé pour sa fabrication et charge creuse l'incorporant |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0323717D0 (en) * | 2003-10-10 | 2003-11-12 | Qinetiq Ltd | Improvements in and relating to oil well perforators |
GB0323675D0 (en) | 2003-10-10 | 2003-11-12 | Qinetiq Ltd | Improvements in and relating to perforators |
US7360488B2 (en) * | 2004-04-30 | 2008-04-22 | Aerojet - General Corporation | Single phase tungsten alloy |
US8584772B2 (en) * | 2005-05-25 | 2013-11-19 | Schlumberger Technology Corporation | Shaped charges for creating enhanced perforation tunnel in a well formation |
US7762193B2 (en) * | 2005-11-14 | 2010-07-27 | Schlumberger Technology Corporation | Perforating charge for use in a well |
US7849919B2 (en) * | 2007-06-22 | 2010-12-14 | Lockheed Martin Corporation | Methods and systems for generating and using plasma conduits |
US20100132946A1 (en) | 2008-12-01 | 2010-06-03 | Matthew Robert George Bell | Method for the Enhancement of Injection Activities and Stimulation of Oil and Gas Production |
US8171851B2 (en) | 2009-04-01 | 2012-05-08 | Kennametal Inc. | Kinetic energy penetrator |
GB201012716D0 (en) * | 2010-07-29 | 2010-09-15 | Qinetiq Ltd | Improvements in and relating to oil well perforators |
DE102012007203B4 (de) * | 2012-04-12 | 2015-03-05 | TDW Gesellschaft für verteidigungstechnische Wirksysteme mbH | Verfahren und Einrichtung zur Erhöhung der Leistung einer Hohlladung mit kunststoffgebundenem Sprengstoff bei tiefen Temperaturen |
US8985024B2 (en) * | 2012-06-22 | 2015-03-24 | Schlumberger Technology Corporation | Shaped charge liner |
GB201222474D0 (en) * | 2012-12-13 | 2013-01-30 | Qinetiq Ltd | Shaped charge and method of modifying a shaped charge |
US9175936B1 (en) | 2013-02-15 | 2015-11-03 | Innovative Defense, Llc | Swept conical-like profile axisymmetric circular linear shaped charge |
RU2540759C1 (ru) * | 2013-10-08 | 2015-02-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Сибирская государственная геодезическая академия" (ФГБОУ ВПО "СГГА") | Взрывной генератор плоской волны для кумулятивных перфораторов |
US9651509B2 (en) | 2014-03-19 | 2017-05-16 | The United States Of America As Represented By The Secretary Of The Navy | Method for investigating early liner collapse in a shaped charge |
US20160091290A1 (en) * | 2014-09-29 | 2016-03-31 | Pm Ballistics Llc | Lead free frangible iron bullets |
US9976397B2 (en) | 2015-02-23 | 2018-05-22 | Schlumberger Technology Corporation | Shaped charge system having multi-composition liner |
US9360222B1 (en) | 2015-05-28 | 2016-06-07 | Innovative Defense, Llc | Axilinear shaped charge |
US9995562B2 (en) * | 2015-12-11 | 2018-06-12 | Raytheon Company | Multiple explosively formed projectiles liner fabricated by additive manufacturing |
US10364387B2 (en) | 2016-07-29 | 2019-07-30 | Innovative Defense, Llc | Subterranean formation shock fracturing charge delivery system |
US9862027B1 (en) | 2017-01-12 | 2018-01-09 | Dynaenergetics Gmbh & Co. Kg | Shaped charge liner, method of making same, and shaped charge incorporating same |
RU174806U1 (ru) * | 2017-07-28 | 2017-11-02 | Амир Рахимович Арисметов | Облицовка кумулятивного заряда |
RU179027U1 (ru) * | 2018-02-12 | 2018-04-25 | Амир Рахимович Арисметов | Композиционная порошковая облицовка сложной формы для кумулятивных зарядов |
RU191145U1 (ru) * | 2019-05-20 | 2019-07-25 | Федеральное Государственное Бюджетное Образовательное Учреждение Высшего Образования "Новосибирский Государственный Технический Университет" | Кумулятивный заряд |
DE102019116153A1 (de) | 2019-06-13 | 2020-12-17 | Kennametal Inc. | Panzerungsplatte, Panzerungsplattenverbund und Panzerung |
RU2771470C1 (ru) * | 2021-12-14 | 2022-05-04 | Акционерное общество "Научно-производственное объединение "СПЛАВ" им. А.Н. Ганичева | Способ изготовления облицовки кумулятивного заряда |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5331895A (en) * | 1982-07-22 | 1994-07-26 | The Secretary Of State For Defence In Her Britanic Majesty's Government Of The United Kingdon Of Great Britain And Northern Ireland | Shaped charges and their manufacture |
DE3336516C2 (de) * | 1983-10-07 | 1985-09-05 | Bayerische Metallwerke GmbH, 7530 Pforzheim | Auskleidung und Belegung für Hohl-, Flach- und Projektilladungen |
DE3634433A1 (de) * | 1986-10-09 | 1988-04-14 | Diehl Gmbh & Co | Einlage fuer hohlladungen bzw. penetratoren oder wuchtkoerper fuer geschosse |
US4766813A (en) * | 1986-12-29 | 1988-08-30 | Olin Corporation | Metal shaped charge liner with isotropic coating |
SE470204B (sv) * | 1991-05-17 | 1993-12-06 | Powder Tech Sweden Ab | Sätt att framställa en legering med hög densitet och hög duktilitet |
GB9116446D0 (en) | 1991-07-31 | 1991-09-11 | Tetronics Research & Dev Co Li | A twin plasma torch process for the production of ultra-fine aluminium nitride |
US5656791A (en) * | 1995-05-15 | 1997-08-12 | Western Atlas International, Inc. | Tungsten enhanced liner for a shaped charge |
US5567906B1 (en) * | 1995-05-15 | 1998-06-09 | Western Atlas Int Inc | Tungsten enhanced liner for a shaped charge |
US6152040A (en) * | 1997-11-26 | 2000-11-28 | Ashurst Government Services, Inc. | Shaped charge and explosively formed penetrator liners and process for making same |
US6248150B1 (en) * | 1999-07-20 | 2001-06-19 | Darryl Dean Amick | Method for manufacturing tungsten-based materials and articles by mechanical alloying |
US7022155B2 (en) | 2000-02-10 | 2006-04-04 | Tetronics Limited | Plasma arc reactor for the production of fine powders |
CA2335694A1 (fr) * | 2000-02-14 | 2001-08-14 | Jerry L. Walker | Perforateur de tubage de puits de petrole a revetement metallique enduit de poudre metallique de masse volumique elevee |
US7011027B2 (en) * | 2000-05-20 | 2006-03-14 | Baker Hughes, Incorporated | Coated metal particles to enhance oil field shaped charge performance |
US6634300B2 (en) * | 2000-05-20 | 2003-10-21 | Baker Hughes, Incorporated | Shaped charges having enhanced tungsten liners |
US6564718B2 (en) * | 2000-05-20 | 2003-05-20 | Baker Hughes, Incorporated | Lead free liner composition for shaped charges |
US6588344B2 (en) * | 2001-03-16 | 2003-07-08 | Halliburton Energy Services, Inc. | Oil well perforator liner |
-
2001
- 2001-11-14 GB GB0127296A patent/GB2382122A/en not_active Withdrawn
-
2002
- 2002-11-12 AT AT02803062T patent/ATE334375T1/de not_active IP Right Cessation
- 2002-11-12 CA CA002467103A patent/CA2467103C/fr not_active Expired - Fee Related
- 2002-11-12 WO PCT/GB2002/005092 patent/WO2003042625A1/fr active IP Right Grant
- 2002-11-12 AU AU2002363806A patent/AU2002363806B2/en not_active Ceased
- 2002-11-12 RU RU2004117863/02A patent/RU2258195C1/ru not_active IP Right Cessation
- 2002-11-12 DE DE60213446T patent/DE60213446T2/de not_active Expired - Lifetime
- 2002-11-12 EP EP02803062A patent/EP1444477B1/fr not_active Expired - Lifetime
- 2002-11-12 US US10/494,805 patent/US7261036B2/en not_active Expired - Lifetime
- 2002-11-12 CN CNB028224833A patent/CN1313798C/zh not_active Expired - Fee Related
-
2004
- 2004-05-13 NO NO20041980A patent/NO328843B1/no not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2018234013A1 (fr) * | 2017-06-23 | 2018-12-27 | Dynaenergetics Gmbh & Co. Kg | Revêtement de charge creuse, procédé pour sa fabrication et charge creuse l'incorporant |
Also Published As
Publication number | Publication date |
---|---|
US20040255812A1 (en) | 2004-12-23 |
CA2467103C (fr) | 2009-10-27 |
GB2382122A (en) | 2003-05-21 |
CN1585888A (zh) | 2005-02-23 |
DE60213446D1 (de) | 2006-09-07 |
NO20041980L (no) | 2004-06-14 |
NO328843B1 (no) | 2010-05-25 |
CN1313798C (zh) | 2007-05-02 |
RU2004117863A (ru) | 2005-06-10 |
US7261036B2 (en) | 2007-08-28 |
EP1444477A1 (fr) | 2004-08-11 |
RU2258195C1 (ru) | 2005-08-10 |
CA2467103A1 (fr) | 2003-05-22 |
DE60213446T2 (de) | 2007-02-22 |
AU2002363806B2 (en) | 2006-08-10 |
ATE334375T1 (de) | 2006-08-15 |
GB0127296D0 (en) | 2002-01-02 |
WO2003042625A1 (fr) | 2003-05-22 |
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