EP1439264B1 - Pulp molded article and method and apparatus for producing pulp molded article - Google Patents
Pulp molded article and method and apparatus for producing pulp molded article Download PDFInfo
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- EP1439264B1 EP1439264B1 EP02755695A EP02755695A EP1439264B1 EP 1439264 B1 EP1439264 B1 EP 1439264B1 EP 02755695 A EP02755695 A EP 02755695A EP 02755695 A EP02755695 A EP 02755695A EP 1439264 B1 EP1439264 B1 EP 1439264B1
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- European Patent Office
- Prior art keywords
- fiber layer
- pulp fiber
- pulp
- molded article
- density
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21J—FIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
- D21J3/00—Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds
- D21J3/10—Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds of hollow bodies
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21J—FIBREBOARD; MANUFACTURE OF ARTICLES FROM CELLULOSIC FIBROUS SUSPENSIONS OR FROM PAPIER-MACHE
- D21J7/00—Manufacture of hollow articles from fibre suspensions or papier-mâché by deposition of fibres in or on a wire-net mould
Definitions
- the present invention relates to a pulp molded article and a method and an apparatus for producing the same. More particularly, it relates to a thin-walled, lightweight, and yet highly heat-insulating pulp molded article and a method and an apparatus for producing the same.
- JP-A-11-301753 Known techniques pertinent to pulp molded heat-insulating containers include the technique disclosed in JP-A-11-301753 .
- This technique relates to a heat-insulating double container comprising a main container and an outer container which is provided on the outside of the main container with a prescribed gap therebetween.
- Such a heat-insulating container must have an outer container provided on the outside of the main container to achieve heat insulation. Accordingly, the container has an increased thickness as a whole. Further, there is a limit in achieving weight reduction of the container because of its double layer structure.
- the present invention provides a novel pulp molded article which is thin, lightweight, and excellent in heat-insulating performance and a method and an apparatus for producing the pulp molded article efficiently.
- the pulp molded article according to the present invention is defined in claim 1.
- the present invention also relates to a method of producing a pulp molded article according to claim 10.
- the present invention also relates to an apparatus for producing a pulp molded article according to claim 13.
- Fig. 1 shows an embodiment of the pulp molded article according to the present invention, which is a heat-insulating container used to hold a food such as an instant noodle.
- numerical reference 1 indicates the heat-insulating container; 23, a line indicative of the level to which hot water is to be poured; and 24, a stacking shoulder.
- the heat-insulating container 1 comprises a cup-shaped main body 20 of the container (hereinafter referred to as a container main body) formed of a pulp fiber layer 2.
- the container has a flange 21 of prescribed thickness formed around its brim.
- the inner side of the container main body 20 (pulp fiber layer 2) and the flange 21 are coated with the coating layer 3.
- the pulp fiber layer 2 has a single layer structure formed by papermaking from a single slurry (stock) described later.
- the body 22 of the container main body 20 is provided with a density distribution such that the density of the pulp fiber layer 2 increases from its inside toward the outside:
- the pulp fiber layer has a density distribution
- the size of the interstitial voids (void or void volume) between pulp fibers bound in the pulp fiber layer has a distribution in the thickness direction.
- the larger the voids the smaller the density of the pulp fiber layer.
- the smaller the voids the larger the density. Accordingly, if the interfiber voids are equal in size in the thickness direction, the pulp fiber layer has no density distribution.
- the density change in the pulp fiber layer 2 be continuous for obtaining high strength or be discontinuous (stepwise) for securing high heat insulation.
- the thickness of the body 22 having the density distribution is preferably 0.5 to 3.0 mm, more preferably 0.5 to 2.0 mm. Strength and heat-insulation required of a noodle container are not secured with a body thickness smaller than 0.5 mm. Containers with a body thickness exceeding 3.0 mm would be too heavy as a noodle container.
- the bulk density (bulk density after drying) of the body 22 having the density distribution preferably ranges from 0.1 to 0.6 g/cm 3 , particularly 0.2 to 0.5 g/cm 3 .
- a bulk density less than 0.1 g/cm 3 results in a failure to secure strength necessary for use as a noodle container.
- a bulk density more than 0.6 g/cm 3 results in insufficient heat-insulating properties so that a user can hardly hold the container by the hand.
- the bulk density of the bottom portion is preferably in the same range as that of the body.
- the bulk density (bulk density after drying) of the portions other than the body 22 is preferably 0.2 to 0.9 g/cm 3 .
- the density of a portion which needs strength, in particular, is preferably 0.3 to 0.9 g/cm 3 .
- the pulp fiber layer 2 is preferably made solely of pulp fiber.
- the pulp fiber includes wood pulp, such as virgin pulp and recycled pulp; nonwood pulp, such as cotton pulp, linter pulp, bamboo and straw; and hydrophobilized pulp fiber obtained by mercerizing or crosslinking these pulps.
- the hydrophobilized pulp fiber preferably includes HBA-LA, HBA-S, and HBA-FF, all available from Weyerhauser, U.S.A. Two or more of these pulp fibers can be used as a mixture in an appropriate ratio.
- the pulp fiber layer 2 preferably contains a bulking agent in addition to the pulp fiber in order to improve heat insulating properties and surface properties.
- Useful bulking agents include anionic surface active agents, cationic surface active agents, nonionic surface active agents, and amphoteric surface active agents. These bulking agents can be used either individually or as a mixture thereof.
- KB-115 or KB-08W available from Kao Corp. is preferably used as a bulking agent bringing about improved heat insulating properties.
- the pulp fiber layer 2 can contain, in addition to the bulking agent, other additives such as pigments, fixing agents, antifungal agents, and sizes.
- the coating layer 3 imparts such functions as waterproofness, oil resistance, and gas barrier properties, to the heat-insulating container 1.
- the thickness of the coating layer 3 is decided according to the desired function.
- the coating layer 3 is formed by laminating with a resin film.
- the resin film which can be used as the coating layer 3 includes a film of thermoplastic resins, such as polyolefin resins, e.g., polyethylene and polypropylene, polyester resins, e.g., polyethylene terephthalate, polyamide resins, e.g., nylon, polyvinyl resins, e.g., polyvinyl chloride, and styrene resins, e.g., polystyrene; and a film of biodegradable resins, such as modified polyethylene terephthalate and aliphatic polyesters.
- Polyolefin resins are preferred for the cost of production and formability, and biodegradable resin films are preferred in view of disposability from the consideration for the environment.
- the coating layer may be formed by laminating with two or more of these resin films.
- a preferred apparatus for producing the pulp molded article of the present invention will then be described with particular reference to an apparatus for producing the container main body 20 of the heat-insulating container 1 by referring to Fig. 2 .
- Fig. 2 shows an embodiment of the apparatus for producing a pulp molded article according to the present invention, applied to the production of a heat-insulating container for holding a food, such as an instant noodle.
- numerical reference 10 indicates the apparatus.
- the apparatus 10 has a drying mold 11 in which a pulp fiber layer 2 is fitted and an elastically deformable pressing member 16 which presses the pulp fiber layer 2 from the inside toward the cavity-forming wall of the drying mold 11.
- the drying mold 11 has a pair of splits 12 and 12.
- the splits 12 and 12 are joined together to form a cavity 110 corresponding to the contour of the container main body 20.
- Evacuation holes 13 connecting to the outside are made on the inner wall of the drying mold 11 in the portion facing the part of the pulp fiber layer 2 where a density distribution is not to be created.
- the cavity-forming wall of the drying mold 11 has no evacuation holes for steam escape in its portion facing the body 22 of the container main body 20.
- Evacuation holes 13 for steam escape are made on the cavity-forming wall in the portions facing the flange 21 and the bottom portion (including the base and the rising part of the wall).
- Each evacuation hole preferably has a slit form from the viewpoint of the surface smoothness of the resulting molded article, evacuation efficiency, and prevention of clogging of the evacuation holes.
- the width of each evacuation hole is preferably 0.1 to 0.5 mm, more preferably 0.1 to 0.3 mm.
- the total open area of the evacuation holes is preferably 100 to 1500 mm 2 , more preferably 200 to 1000 mm 2 , for obtaining container strength and preventing stains.
- the evacuation holes 13 are connected to an evacuation line 130 equipped with an on-off valve 131.
- the end of the evacuation line 130 is connected to an evacuation source (not shown).
- the drying mold 11 has a lid 15 which shuts the upper opening 111.
- the lid 15 has an opening 14 which connects to the opening 111 and through which a pressing member 16 is let in and out.
- Each split 12 constituting the drying mold 11 has a heating unit 120 attached thereto.
- the pressing member 16 is a bag which is elastic and therefore expandable and shrinkable.
- Materials of the pressing member 16 include urethane, fluororubber, silicone rubber, elastomers and etc., which are excellent in tensile strength, impact resilience, and stretchability.
- the pressing member 16 is connected to a pipe line 17 for feeding a pressurizing fluid into the pressing member 16.
- the pipe line 17 has an on-off valve 18.
- the end of the pipe line 17 is connected alternately to an evacuation source (not shown) and a pressurizing source (not shown).
- the method of producing the heat-insulating container 1 includes the step of papermaking and dewatering the pulp fiber layer 2 forming the container main body 20, the step of drying the dewatered pulp fiber layer 2, and the step of forming the coating layer 3.
- the pulp fiber 2 having a single layer structure is formed by papermaking from a single slurry (a single stock).
- a papermaking mold composed of a pair of splits is used, the splits being joined together to form a cavity of prescribed shape corresponding to the container main body 20.
- the cavity has an opening at the top.
- Each split constituting the papermaking mold has a plurality of interconnecting passageways which connect the cavity and the outside.
- Each interconnecting passageway is led to a sucking unit, such as a suction pump (not shown).
- the total open area ratio of the interconnecting passageways on the inner wall of the splits is preferably 4 to 20%, more preferably 3 to 50%, in view of reduction of drain time and moldability.
- the cavity-forming wall preferably has drainage channels leading to each interconnecting passageway.
- the total open area ratio of the drainage channels on the cavity-forming wall is preferably 50 to 90%, more preferably 60 to 80%, from the standpoint of prevention of deformation of a papermaking screen, molding capabilities, drainage, and prevention of clogging of the papermaking screen.
- the width of the drainage channel is preferably 1 to 10 mm, more preferably 2 to 5 mm, from the standpoint of prevention of deformation of a papermaking screen, molding capabilities, drainage, and prevention of clogging of the papermaking screen.
- the drainage channels are preferably formed in a checkered pattern so as to connect the interconnecting passageways to each other.
- the inner wall of each split is covered with a prescribed papermaking screen.
- the papermaking screen includes a single net fabricated of natural fiber, synthetic fiber or metal fiber or a combination of a plurality of these nets. Synthetic fiber is preferred of these materials for ease of fabricating into a net and durability.
- the natural fiber includes vegetable fiber and animal fiber.
- the synthetic fiber includes synthetic resin fibers made of thermoplastic resins, thermosetting resins or semi-synthetic resins.
- the metal fiber includes stainless steel fiber and copper fiber.
- the fibers of the papermaking screen are preferably surface-modified to improve slip and durability.
- the wire diameter of the papermaking screen is preferably 0.05 to 1.0 mm, more preferably 0.05 to 0.5 mm, and the distance between wires is preferably 0.15 to 2.0 mm, more preferably 0.15 to 1.5 mm.
- a predetermined amount of the slurry is injected into the cavity, and the cavity is sucked by means of a suction pump through the drainage channels and the interconnecting passageways.
- a suction pump through the drainage channels and the interconnecting passageways.
- the injection pressure of the slurry into the cavity is preferably 0.05 to 1.0 MPa, more preferably 0.05 to 0.5 MPa, for shortening the slurry injection time and securing moldability.
- the inner pressure of the cavity evacuated through the interconnecting passageways is preferably 10 to 90 kPa, more preferably 20 to 70 kPa, for shortening the dewatering time and securing moldability.
- the single slurry used to form the pulp fiber layer 2 by papermaking preferably consists of pulp fiber and water.
- the pulp fiber includes wood pulp, such as virgin pulp and recycled pulp; nonwood pulp, such as cotton pulp, linter pulp, bamboo and straw; and hydrophobilized pulp fiber obtained by mercerizing or crosslinking these pulps.
- the hydrophobilized pulp fiber is particularly preferred. Examples of preferred hydrophobilized pulp fiber are HBA-LA, HBA-S, and HBA-FF, all available from Weyerhauser, U.S.A. Two or more of these pulp fibers can be used as a mixture in an appropriate ratio.
- the pulp fiber content in the slurry is preferably 0.05 to 10 wt%, more preferably 0.05 to 4 wt%.
- Additives such as the above-recited bulking agents, sizes, pigments, fixing agents, and antifungal agents, can be added to the single slurry used to form the pulp fiber layer 2 by papermaking in appropriate ratios.
- a pressurizing fluid is fed into the cavity while continuing evacuating the cavity through the interconnecting passageways, whereby the pulp fiber layer 2 is dewatered.
- the pressurizing fluid used for dewatering includes air, steam, and superheated steam.
- the pressure of the pressurizing fluid for dewatering is preferably 0.05 to 1.0 MPa, more preferably 0.05 to 0.5 MPa, from the standpoint of dewatering efficiency.
- the water content of the pulp fiber layer 2 after dewatering is preferably 50 to 85%, more preferably 60 to 80%, from the viewpoint of drying efficiency, surface smoothness and heat insulating properties of the container after drying, and for preventing the container from suffering surface scorching on drying.
- the pulp fiber layer 2 is dewatered to a desired water content, the pulp fiber layer 2 is separated from the cavity-forming wall, and the undried pulp fiber layer 2 is transferred into the drying mold 11.
- the cavity-forming wall of the drying mold 11 has no evacuation holes for steam escape in its portion facing the body 22 of the container main body 20, while evacuation holes 13 for steam escape, which are led to the outside, are provided on the cavity-forming wall in the portions facing the flange 21 and the bottom portion (including the base and the rising part of the wall).
- the pulp fiber layer 2 is set in the drying mold 11, and the upper opening 111 of the drying mold 11 is shut by the lid 15 having the insertion opening 14.
- the drying mold 11 is then heated to a prescribed temperature by the heating unit 120.
- the temperature of the drying mold 11 is preferably 150 to 300°C, more preferably 170 to 250°C, for preventing the pulp fiber layer 2 from scorching and for improving drying efficiency.
- the pressing member 16 is inserted into the cavity 110 of the drying mold 11 through the insertion opening 14 of the lid 15 to close the cavity 110.
- a pressurizing fluid is supplied into the pressing member 16 to inflate the pressing member 16 within the cavity 110, whereby the pulp fiber layer 2 is heat dried while being pressed to the cavity-forming wall.
- the pressing force of the pressing member 16 during heat drying is preferably 0.05 to 1.0 MPa, more preferably 0.1 to 0.3 MPa, from the standpoint of heat insulating properties, drying efficiency, and surface smoothness.
- the pressure for the forcible evacuation is preferably 4 to 60 kPa, more preferably 4 to 10 kPa, for securing drying efficiency and making the container bulky.
- the pressurizing fluid is withdrawn from the pressing member 16. And the forcible evacuation through the evacuation holes 13 is stopped while the pressing member 16 shrinks to reduce the inner pressure of the cavity 110 as shown in Fig. 3(c) .
- the step of pressing the pulp fiber layer 2 by the pressing member 16 with forcible evacuation and the step of stopping the forcible evacuation and shrinking the pressing member 16 can be conducted repeatedly if needed.
- the splits 12 and 12 are separated apart to take out the container main body 20 as shown in Fig. 3(d) . If necessary, the container main body is finished by trimming and the like.
- the inner surface and the flange 21 of the container main body 20 i.e., the pulp fiber layer 2 is coated with the coating layer 3.
- the above-described resin film can be formed into the coating layer 3 by known' techniques, such as pressure forming and vacuum forming.
- the coating layer can be formed by use of a vacuum forming mold 5 and a plug 6 having a heater 60 as shown in Figs. 4(a) and (b) .
- the vacuum forming mold 5 is substantially the same size as the drying mold 10 used in the pulp fiber layer 2 drying step. It has air flow channels 51 arranged in a checkered pattern on the cavity-forming wall 50 and an evacuation path 52 connecting the air flow channels and the outside.
- the container main body 20 is fitted into the vacuum forming mold 5, and a preheated and softened resin film 30 is set on the opening of the container main body 20 to cover the opening.
- a plug 6 is brought down to press the resin film 30 into the container main body 20.
- the container main body 20 being air permeable, is evacuated through the air flow channels 51 and the evacuation path 52 to thereby bring the resin film 30 into intimate contact with the inner surface and the flange 21 of the container main body 20.
- the unnecessary part of the resin film 30 is cut off to complete the production of the heat-insulating container 1.
- the container main body 20 is formed of a single-layered pulp fiber layer 2 having, in its body 22, distribution of density increasing from the inner side toward the outer side in the thickness direction, it is thin, lightweight, and excellent in heat insulating properties and exhibits desired strength on its outer side.
- the heat-insulating container which contains no blowing agent for lowering the density, can be made environmentally friendly by using a biodegradable material to form the pulp fiber layer and the coating layer.
- the flange 21, the body 22, and the bottom are integrally molded with no joint seams in the body 22 and the bottom, the container is excellent in mechanical strength (compressive strength and durability). Additionally, the outer surface of the pulp fiber layer 2 has a high density and smoothness and is therefore excellent in printability.
- the container main body 20 is made of the pulp fiber layer 2 formed by a single papermaking operation using a single slurry, the production of the heat-insulating container 1 enjoys simplification and time reduction compared with conventional methods. Accordingly, the production efficiency of the heat-insulating container 1 is greatly improved over the conventional methods.
- the pulp molded article of the present invention is the heat-insulating container 1 as in the above-described embodiment
- the density distribution in the pulp fiber layer be provided in the body of the container main body
- the portion where the density distribution is to be provided can be decided according to the use, the shape, etc. of the pulp molded article.
- the pulp fiber layer can be designed to have the density distribution over the entire pulp fiber layer.
- the density distribution of a single-layered pulp fiber layer of the pulp molded article of the present invention is preferably such that the density increases in the thickness direction from the inner side to the outer side as in the heat-insulating container 1 of the above-described embodiment.
- containers which are primarily intended to protect the contents, industrial parts having a sound absorbing function, and like articles may have a single-layered pulp fiber layer with such a density distribution that the density decreases in the thickness direction from the inner side toward the outer side.
- the flange 21 of the pulp molded article of the invention be formed while the pulp fiber layer 2 is being deposited by papermaking as in the aforementioned embodiment, while the flange may be formed by bending the pulp fiber layer.
- the shape of the flange is not limited to the outward curl at a prescribed curvature, and other shapes can be formed.
- the coating layer 3 of the pulp molded article of the invention is preferably formed of a resin film as in the aforementioned embodiment, it may be formed by applying a coating composition. Coating methods include spreading a coating composition and dipping the container main body 2 in a coating composition, and like techniques.
- the outer surface of the pulp molded article of the present invention may be coated with another pulp fiber layer having a higher density than the fiber layer 2 thereby to improve printability, strength, water resistance, and like properties.
- the pulp fiber layer of the pulp molded article of the present invention is preferably formed by papermaking by use of a papermaking mold composed of a set of splits which are joined to form a cavity of prescribed shape as in the above-mentioned embodiment, but use of such a split mold is not always necessary for producing some shapes of pulp molded articles. Further, other papermaking methods are employable.
- papermaking can be carried out by using a male mold.
- the male mold comprises a projected papermaking part corresponding to the contour of a container main body and having a large number of liquid flow holes open to the outer surface thereof and a prescribed papermaking screen covering the papermaking part.
- the male mold is immersed in the slurry, and the slurry is sucked up through the liquid flow holes to deposit the pulp fiber on the surface of the papermaking screen to form the pulp fiber layer.
- the male mold may be made of a rigid material or an elastic material.
- the pulp molded article of the present invention can also be produced by placing the pulp fiber layer formed by papermaking into a female mold configured to the contour of the pulp fiber layer and fitting a heated male mold having a given clearance with the female mold into the female mold to effect drying the pulp fiber layer.
- the pulp molded article of the present invention can also be produced by setting a dried high-density pulp molded article (another pulp fiber layer) in a female mold, uniting a wet pulp fiber layer formed by papermaking with the another pulp fiber layer, fitting a heated male mold having a given clearance with the female mold into the female mold to dry the united two pulp fiber layers.
- the wet pulp fiber layer is dried while being expanded by steam generated from the wet pulp fiber layer.
- a pulp molded article having its outer side covered with a high-density pulp fiber layer and having its density increased from the outer side toward the inner side.
- the resulting pulp molded article is very excellent in printability, strength, and water resistance and also excellent in inner surface properties.
- the "another pulp fiber layer" as referred to above is formed by an ordinary papermaking method using the fiber employable to form the pulp fiber layer 2.
- the pulp molded article of the present invention is especially suitable as a flanged heat-insulating container as in the above-described embodiment, the application of the present invention is not limited thereto.
- the present invention is applicable to containers of various shapes, such as bowls, bottles, and trays; hollow articles, such as cylindrical shapes; and plate-shaped articles.
- Heat-insulating containers were made according to Example 1 and Comparative Example 1 and evaluated for performance. The results of evaluation are shown in Table 1.
- a pulp fiber layer was formed by papermaking under the following conditions using a papermaking mold having the following specification.
- the papermaking mold was composed of a pair of splits which were joined to form a cavity corresponding to the container main body having the above-described geometry.
- a pressurizing fluid was fed into the cavity under the following conditions to dewater the pulp fiber layer to a water content of 75%.
- a drying mold having evacuation holes specified below was prepared.
- the evacuation holes were provided in the portions corresponding to the periphery of the flange and the bottom (including the base and the rising part of the wall) of the container main body to be produced.
- the pulp fiber layer was fitted into the drying mold and pressed by a pressing member having the following specification simultaneously with forcible evacuation through the evacuation holes. The forcible evacuation was stopped, and the pressing member was shrunken to produce the container main body.
- a coating layer was formed on the resulting container main body under the following conditions to produce a heat-insulating container.
- a heat-insulating container was produced in the same manner as in Example 1, except for using a drying mold additionally having evacuation holes on the portion corresponding to the body of the container main body (0.15 mm wide slits over the whole circumference arranged in the vertical direction at a 10 mm interval).
- Pieces cut out of different portions of the resulting container main body were measured for apparent volume and weight, from which a bulk density was calculated.
- the resulting container was dried at 105°C for 1 hour in a low-humidity chamber and then weighed.
- thermocouple was attached to the outer side of the body of the resulting container. Hot water at 80°C was poured into the container. After 3 minutes from the pouring, the temperature of the outer side of the body was measured, and whether the container containing the hot water could be held by the hand (graspability) was examined.
- thermocouple
- the resulting container was measured for vertical compressive strength and transverse compressive strength with a compression tester (Tensilon RTA-500, supplied by Orientec) in accordance with the following methods.
- the resulting container was placed upside down on a stage.
- An indenter was pressed down from the bottom of the container at a crosshead speed of 20 mm/min to obtain the compressive strength of the container body.
- the resulting container was placed on its side on a stage having a groove, into which the flange was fitted.
- a rounded rod indenter having a diameter of 10 mm was pressed down from the container body at a crosshead speed of 20 mm/min to obtain the compressive strength of the body.
- the measured strength was rated as follows in comparison with the value of a commercially available foamed polystyrene container. O ... Equal to or higher than the strength of a foamed polystyrene container (the strength necessary for withstanding packaging, transportation, and use). X ... Lower than the strength of a foamed polystyrene container. TABLE 1 Example 1 Compara.
- Example 1 Layer structure* 1 double layer double layer Density distribution* 2 yes no Each layer thickness* 3 (mm) 1.4/0.03 0.6/0.03 Bulk density* 4 (g/cm 3 ) 0.4/0.25/0.35 - Heat insulating properties O X Strength O O Absolute dry weight* 5 (g) 13 13 *1 Container main body + coating layer *2 Density distribution in the container main body (body) *3 Container main body (body)/coating layer *4 Flange/body/bottom *5 Dried at 105°C for 1 hour
- Example 1 As is shown in Table 1, the heat-insulating container of Example 1 was confirmed to be thinner, lighter, and more heat-insulating than that of Comparative Example 1 and sufficiently usable as a container for instant noodles.
- the present invention provides a novel pulp molded article which is thin, lightweight, and excellent in heat-insulating performance and a method and an apparatus for producing the pulp molded article efficiently.
Abstract
Description
- The present invention relates to a pulp molded article and a method and an apparatus for producing the same. More particularly, it relates to a thin-walled, lightweight, and yet highly heat-insulating pulp molded article and a method and an apparatus for producing the same.
- Known techniques pertinent to pulp molded heat-insulating containers include the technique disclosed in
JP-A-11-301753 - Such a heat-insulating container must have an outer container provided on the outside of the main container to achieve heat insulation. Accordingly, the container has an increased thickness as a whole. Further, there is a limit in achieving weight reduction of the container because of its double layer structure.
- The present invention provides a novel pulp molded article which is thin, lightweight, and excellent in heat-insulating performance and a method and an apparatus for producing the pulp molded article efficiently.
- The pulp molded article according to the present invention is defined in
claim 1. - The present invention also relates to a method of producing a pulp molded article according to claim 10.
- The present invention also relates to an apparatus for producing a pulp molded article according to
claim 13. -
-
Fig. 1 is a vertical half cross-section of a heat-insulating container as an embodiment of the pulp molded article according to the present invention. -
Fig. 2 schematically illustrates an embodiment of the apparatus for producing a pulp molded article according to the present invention. -
Fig. 3(a), Fig. 3(b), Fig. 3(c) and Fig. 3(d) schematically illustrates the step of drying a pulp fiber layer which forms the main body of the heat-insulating container, whereinFig. 3(a) shows a pulp fiber layer formed by papermaking and fitted into a drying mold;Fig. 3(b) shows the pulp fiber layer being pressed in the cavity of the drying mold by a pressing member;Fig. 3(c) shows the pressing member being shrinking; andFig. 3(d) shows the main body of the container removed from the mold. -
Fig. 4(a) and Fig. 4(b) schematically illustrate the step of forming a coating layer of the heat-insulating container, in whichFig. 4(a) shows a resin film which is being superposed on the inner side of the main body of the container by vacuum forming; andFig. 4(b) is an enlarged view of an essential part of the main body of the container laminated with the resin film. - The present invention will be described based on its preferred embodiments by referring to the accompanying drawings.
-
Fig. 1 shows an embodiment of the pulp molded article according to the present invention, which is a heat-insulating container used to hold a food such as an instant noodle. InFig. 1 ,numerical reference 1 indicates the heat-insulating container; 23, a line indicative of the level to which hot water is to be poured; and 24, a stacking shoulder. - As shown in
Fig. 1 , the heat-insulatingcontainer 1 comprises a cup-shapedmain body 20 of the container (hereinafter referred to as a container main body) formed of apulp fiber layer 2. The container has aflange 21 of prescribed thickness formed around its brim. The inner side of the container main body 20 (pulp fiber layer 2) and theflange 21 are coated with thecoating layer 3. - The
pulp fiber layer 2 has a single layer structure formed by papermaking from a single slurry (stock) described later. Thebody 22 of the containermain body 20 is provided with a density distribution such that the density of thepulp fiber layer 2 increases from its inside toward the outside: - The language "the pulp fiber layer has a density distribution" as used throughout the description means that the size of the interstitial voids (void or void volume) between pulp fibers bound in the pulp fiber layer has a distribution in the thickness direction. The larger the voids, the smaller the density of the pulp fiber layer. The smaller the voids, the larger the density. Accordingly, if the interfiber voids are equal in size in the thickness direction, the pulp fiber layer has no density distribution.
- It is preferred that the density change in the
pulp fiber layer 2 be continuous for obtaining high strength or be discontinuous (stepwise) for securing high heat insulation. - From the standpoint of strength, heat insulation, and lightness of the container, the thickness of the
body 22 having the density distribution is preferably 0.5 to 3.0 mm, more preferably 0.5 to 2.0 mm. Strength and heat-insulation required of a noodle container are not secured with a body thickness smaller than 0.5 mm. Containers with a body thickness exceeding 3.0 mm would be too heavy as a noodle container. - The bulk density (bulk density after drying) of the
body 22 having the density distribution preferably ranges from 0.1 to 0.6 g/cm3, particularly 0.2 to 0.5 g/cm3. A bulk density less than 0.1 g/cm3 results in a failure to secure strength necessary for use as a noodle container. A bulk density more than 0.6 g/cm3 results in insufficient heat-insulating properties so that a user can hardly hold the container by the hand. Where the bottom portion is provided with a density distribution, the bulk density of the bottom portion is preferably in the same range as that of the body. - The bulk density (bulk density after drying) of the portions other than the
body 22 is preferably 0.2 to 0.9 g/cm3. The density of a portion which needs strength, in particular, is preferably 0.3 to 0.9 g/cm3. - The
pulp fiber layer 2 is preferably made solely of pulp fiber. The pulp fiber includes wood pulp, such as virgin pulp and recycled pulp; nonwood pulp, such as cotton pulp, linter pulp, bamboo and straw; and hydrophobilized pulp fiber obtained by mercerizing or crosslinking these pulps. In particular, the hydrophobilized pulp fiber preferably includes HBA-LA, HBA-S, and HBA-FF, all available from Weyerhauser, U.S.A. Two or more of these pulp fibers can be used as a mixture in an appropriate ratio. - The
pulp fiber layer 2 preferably contains a bulking agent in addition to the pulp fiber in order to improve heat insulating properties and surface properties. Useful bulking agents include anionic surface active agents, cationic surface active agents, nonionic surface active agents, and amphoteric surface active agents. These bulking agents can be used either individually or as a mixture thereof. In particular, KB-115 or KB-08W available from Kao Corp. is preferably used as a bulking agent bringing about improved heat insulating properties. - The
pulp fiber layer 2 can contain, in addition to the bulking agent, other additives such as pigments, fixing agents, antifungal agents, and sizes. - The
coating layer 3 imparts such functions as waterproofness, oil resistance, and gas barrier properties, to the heat-insulatingcontainer 1. The thickness of thecoating layer 3 is decided according to the desired function. Thecoating layer 3 is formed by laminating with a resin film. - The resin film which can be used as the
coating layer 3 includes a film of thermoplastic resins, such as polyolefin resins, e.g., polyethylene and polypropylene, polyester resins, e.g., polyethylene terephthalate, polyamide resins, e.g., nylon, polyvinyl resins, e.g., polyvinyl chloride, and styrene resins, e.g., polystyrene; and a film of biodegradable resins, such as modified polyethylene terephthalate and aliphatic polyesters. Polyolefin resins are preferred for the cost of production and formability, and biodegradable resin films are preferred in view of disposability from the consideration for the environment. The coating layer may be formed by laminating with two or more of these resin films. - A preferred apparatus for producing the pulp molded article of the present invention will then be described with particular reference to an apparatus for producing the container
main body 20 of the heat-insulatingcontainer 1 by referring toFig. 2 . -
Fig. 2 shows an embodiment of the apparatus for producing a pulp molded article according to the present invention, applied to the production of a heat-insulating container for holding a food, such as an instant noodle. InFig.2 , numerical reference 10 indicates the apparatus. - The apparatus 10 has a drying mold 11 in which a
pulp fiber layer 2 is fitted and an elastically deformable pressingmember 16 which presses thepulp fiber layer 2 from the inside toward the cavity-forming wall of the drying mold 11. - The drying mold 11 has a pair of
splits splits cavity 110 corresponding to the contour of the containermain body 20. -
Evacuation holes 13 connecting to the outside are made on the inner wall of the drying mold 11 in the portion facing the part of thepulp fiber layer 2 where a density distribution is not to be created. - In this particular embodiment, the cavity-forming wall of the drying mold 11 has no evacuation holes for steam escape in its portion facing the
body 22 of the containermain body 20. Evacuation holes 13 for steam escape are made on the cavity-forming wall in the portions facing theflange 21 and the bottom portion (including the base and the rising part of the wall). - Each evacuation hole preferably has a slit form from the viewpoint of the surface smoothness of the resulting molded article, evacuation efficiency, and prevention of clogging of the evacuation holes. The width of each evacuation hole (slit width) is preferably 0.1 to 0.5 mm, more preferably 0.1 to 0.3 mm. In the present embodiment the total open area of the evacuation holes is preferably 100 to 1500 mm2, more preferably 200 to 1000 mm2, for obtaining container strength and preventing stains. Where it is desired to form a molded article with a clear corner or edge, it is preferred to make the
evacuation hole 13 open at the part facing to the corner or edge to be formed. - The evacuation holes 13 are connected to an
evacuation line 130 equipped with an on-offvalve 131. The end of theevacuation line 130 is connected to an evacuation source (not shown). - The drying mold 11 has a
lid 15 which shuts theupper opening 111. Thelid 15 has anopening 14 which connects to theopening 111 and through which a pressingmember 16 is let in and out. Each split 12 constituting the drying mold 11 has aheating unit 120 attached thereto. - The pressing
member 16 is a bag which is elastic and therefore expandable and shrinkable. Materials of the pressingmember 16 include urethane, fluororubber, silicone rubber, elastomers and etc., which are excellent in tensile strength, impact resilience, and stretchability. The pressingmember 16 is connected to a pipe line 17 for feeding a pressurizing fluid into the pressingmember 16. The pipe line 17 has an on-offvalve 18. The end of the pipe line 17 is connected alternately to an evacuation source (not shown) and a pressurizing source (not shown). - A preferred method of producing the pulp molded article of the present invention will be described with reference to the production of the heat-insulating
container 1. - The method of producing the heat-insulating
container 1 includes the step of papermaking and dewatering thepulp fiber layer 2 forming the containermain body 20, the step of drying the dewateredpulp fiber layer 2, and the step of forming thecoating layer 3. - In the step of papermaking and dewatering the
pulp fiber layer 2, thepulp fiber 2 having a single layer structure is formed by papermaking from a single slurry (a single stock). In this papermaking step, a papermaking mold composed of a pair of splits is used, the splits being joined together to form a cavity of prescribed shape corresponding to the containermain body 20. The cavity has an opening at the top. - Each split constituting the papermaking mold has a plurality of interconnecting passageways which connect the cavity and the outside. Each interconnecting passageway is led to a sucking unit, such as a suction pump (not shown).
- The total open area ratio of the interconnecting passageways on the inner wall of the splits (the cavity-forming side) is preferably 4 to 20%, more preferably 3 to 50%, in view of reduction of drain time and moldability.
- The cavity-forming wall preferably has drainage channels leading to each interconnecting passageway. The total open area ratio of the drainage channels on the cavity-forming wall is preferably 50 to 90%, more preferably 60 to 80%, from the standpoint of prevention of deformation of a papermaking screen, molding capabilities, drainage, and prevention of clogging of the papermaking screen. The width of the drainage channel is preferably 1 to 10 mm, more preferably 2 to 5 mm, from the standpoint of prevention of deformation of a papermaking screen, molding capabilities, drainage, and prevention of clogging of the papermaking screen. The drainage channels are preferably formed in a checkered pattern so as to connect the interconnecting passageways to each other.
- The inner wall of each split is covered with a prescribed papermaking screen. The papermaking screen includes a single net fabricated of natural fiber, synthetic fiber or metal fiber or a combination of a plurality of these nets. Synthetic fiber is preferred of these materials for ease of fabricating into a net and durability. The natural fiber includes vegetable fiber and animal fiber. The synthetic fiber includes synthetic resin fibers made of thermoplastic resins, thermosetting resins or semi-synthetic resins. The metal fiber includes stainless steel fiber and copper fiber. The fibers of the papermaking screen are preferably surface-modified to improve slip and durability.
- Taking into consideration papermaking properties, durability, easy pass of solid matter of the slurry, and prevention of clogging, the wire diameter of the papermaking screen is preferably 0.05 to 1.0 mm, more preferably 0.05 to 0.5 mm, and the distance between wires is preferably 0.15 to 2.0 mm, more preferably 0.15 to 1.5 mm.
- A predetermined amount of the slurry is injected into the cavity, and the cavity is sucked by means of a suction pump through the drainage channels and the interconnecting passageways. Thus, the water content of the slurry is removed by suction, and a pulp fiber layer is deposited on the papermaking screen covering the cavity-forming wall.
- The injection pressure of the slurry into the cavity is preferably 0.05 to 1.0 MPa, more preferably 0.05 to 0.5 MPa, for shortening the slurry injection time and securing moldability.
- The inner pressure of the cavity evacuated through the interconnecting passageways is preferably 10 to 90 kPa, more preferably 20 to 70 kPa, for shortening the dewatering time and securing moldability.
- The single slurry used to form the
pulp fiber layer 2 by papermaking preferably consists of pulp fiber and water. - The pulp fiber includes wood pulp, such as virgin pulp and recycled pulp; nonwood pulp, such as cotton pulp, linter pulp, bamboo and straw; and hydrophobilized pulp fiber obtained by mercerizing or crosslinking these pulps. The hydrophobilized pulp fiber is particularly preferred. Examples of preferred hydrophobilized pulp fiber are HBA-LA, HBA-S, and HBA-FF, all available from Weyerhauser, U.S.A. Two or more of these pulp fibers can be used as a mixture in an appropriate ratio.
- The pulp fiber content in the slurry is preferably 0.05 to 10 wt%, more preferably 0.05 to 4 wt%.
- Additives, such as the above-recited bulking agents, sizes, pigments, fixing agents, and antifungal agents, can be added to the single slurry used to form the
pulp fiber layer 2 by papermaking in appropriate ratios. - After a predetermined amount of the slurry has been injected into the cavity, a pressurizing fluid is fed into the cavity while continuing evacuating the cavity through the interconnecting passageways, whereby the
pulp fiber layer 2 is dewatered. - The pressurizing fluid used for dewatering includes air, steam, and superheated steam.
- The pressure of the pressurizing fluid for dewatering is preferably 0.05 to 1.0 MPa, more preferably 0.05 to 0.5 MPa, from the standpoint of dewatering efficiency.
- The water content of the
pulp fiber layer 2 after dewatering is preferably 50 to 85%, more preferably 60 to 80%, from the viewpoint of drying efficiency, surface smoothness and heat insulating properties of the container after drying, and for preventing the container from suffering surface scorching on drying. - After the
pulp fiber layer 2 is dewatered to a desired water content, thepulp fiber layer 2 is separated from the cavity-forming wall, and the undriedpulp fiber layer 2 is transferred into the drying mold 11. - In making the container
main body 20 with theflange 21 as in the present embodiment, the cavity-forming wall of the drying mold 11 has no evacuation holes for steam escape in its portion facing thebody 22 of the containermain body 20, while evacuation holes 13 for steam escape, which are led to the outside, are provided on the cavity-forming wall in the portions facing theflange 21 and the bottom portion (including the base and the rising part of the wall). As shown inFig. 3(b) , thepulp fiber layer 2 is set in the drying mold 11, and theupper opening 111 of the drying mold 11 is shut by thelid 15 having theinsertion opening 14. The drying mold 11 is then heated to a prescribed temperature by theheating unit 120. - The temperature of the drying mold 11 (mold temperature) is preferably 150 to 300°C, more preferably 170 to 250°C, for preventing the
pulp fiber layer 2 from scorching and for improving drying efficiency. - While the pulp fiber layer is dried in the drying mold as shown in
Fig.3(b) , the pressingmember 16 is inserted into thecavity 110 of the drying mold 11 through theinsertion opening 14 of thelid 15 to close thecavity 110. A pressurizing fluid is supplied into the pressingmember 16 to inflate the pressingmember 16 within thecavity 110, whereby thepulp fiber layer 2 is heat dried while being pressed to the cavity-forming wall. - The pressing force of the pressing
member 16 during heat drying is preferably 0.05 to 1.0 MPa, more preferably 0.1 to 0.3 MPa, from the standpoint of heat insulating properties, drying efficiency, and surface smoothness. - Steam generated from the
pulp fiber layer 2 during the heat drying is expelled by forcible evacuation through the evacuation holes 13. In the portions of thepulp fiber layer 2 facing the cavity-forming wall with no evacuation holes, water remaining among fibers partially vaporizes before reaching the evacuation holes and expands the interfiber voids. It follows that the density of the pulp fiber layer in the inner side of these portions is lowered. On the other hand, in the opening portion and the bottom portion of the containermain body 20, where the evacuation holes 13 are formed, since the vaporized water is allowed to immediately escape through the evacuation holes, thepulp layer 2 increases its density while being compressed by the pressing force of the pressing member. - The pressure for the forcible evacuation is preferably 4 to 60 kPa, more preferably 4 to 10 kPa, for securing drying efficiency and making the container bulky.
- On sufficiently drying the
pulp fiber layer 2, the pressurizing fluid is withdrawn from the pressingmember 16. And the forcible evacuation through the evacuation holes 13 is stopped while the pressingmember 16 shrinks to reduce the inner pressure of thecavity 110 as shown inFig. 3(c) . - The step of pressing the
pulp fiber layer 2 by the pressingmember 16 with forcible evacuation and the step of stopping the forcible evacuation and shrinking the pressingmember 16 can be conducted repeatedly if needed. - After a sufficient density distribution is created in the
body 22 of the containermain body 20, thesplits main body 20 as shown inFig. 3(d) . If necessary, the container main body is finished by trimming and the like. - In the step of forming the
coating layer 3, the inner surface and theflange 21 of the container main body 20 (i.e., the pulp fiber layer 2) is coated with thecoating layer 3. - The above-described resin film can be formed into the
coating layer 3 by known' techniques, such as pressure forming and vacuum forming. - Where vacuum forming is adopted, the coating layer can be formed by use of a
vacuum forming mold 5 and aplug 6 having aheater 60 as shown inFigs. 4(a) and (b) . Thevacuum forming mold 5 is substantially the same size as the drying mold 10 used in thepulp fiber layer 2 drying step. It hasair flow channels 51 arranged in a checkered pattern on the cavity-formingwall 50 and anevacuation path 52 connecting the air flow channels and the outside. The containermain body 20 is fitted into thevacuum forming mold 5, and a preheated and softenedresin film 30 is set on the opening of the containermain body 20 to cover the opening. Aplug 6 is brought down to press theresin film 30 into the containermain body 20. At the same time, the containermain body 20, being air permeable, is evacuated through theair flow channels 51 and theevacuation path 52 to thereby bring theresin film 30 into intimate contact with the inner surface and theflange 21 of the containermain body 20. The unnecessary part of theresin film 30 is cut off to complete the production of the heat-insulatingcontainer 1. - Since the container
main body 20 is formed of a single-layeredpulp fiber layer 2 having, in itsbody 22, distribution of density increasing from the inner side toward the outer side in the thickness direction, it is thin, lightweight, and excellent in heat insulating properties and exhibits desired strength on its outer side. The heat-insulating container, which contains no blowing agent for lowering the density, can be made environmentally friendly by using a biodegradable material to form the pulp fiber layer and the coating layer. Further, because theflange 21, thebody 22, and the bottom are integrally molded with no joint seams in thebody 22 and the bottom, the container is excellent in mechanical strength (compressive strength and durability). Additionally, the outer surface of thepulp fiber layer 2 has a high density and smoothness and is therefore excellent in printability. - Since the container
main body 20 is made of thepulp fiber layer 2 formed by a single papermaking operation using a single slurry, the production of the heat-insulatingcontainer 1 enjoys simplification and time reduction compared with conventional methods. Accordingly, the production efficiency of the heat-insulatingcontainer 1 is greatly improved over the conventional methods. - The present invention is not limited to the heat-insulating
container 1 according to the above-described embodiment, and appropriate changes and modifications can be made therein without departing from the scope of the appended claims. - In cases where the pulp molded article of the present invention is the heat-insulating
container 1 as in the above-described embodiment, while it is preferred that the density distribution in the pulp fiber layer be provided in the body of the container main body, the portion where the density distribution is to be provided can be decided according to the use, the shape, etc. of the pulp molded article. - Where the pulp molded article is a container which requires heat insulation as a whole, such as a bowl or a tray, the pulp fiber layer can be designed to have the density distribution over the entire pulp fiber layer.
- The density distribution of a single-layered pulp fiber layer of the pulp molded article of the present invention is preferably such that the density increases in the thickness direction from the inner side to the outer side as in the heat-insulating
container 1 of the above-described embodiment. In contrast, containers which are primarily intended to protect the contents, industrial parts having a sound absorbing function, and like articles may have a single-layered pulp fiber layer with such a density distribution that the density decreases in the thickness direction from the inner side toward the outer side. - It is preferred that the
flange 21 of the pulp molded article of the invention be formed while thepulp fiber layer 2 is being deposited by papermaking as in the aforementioned embodiment, while the flange may be formed by bending the pulp fiber layer. The shape of the flange is not limited to the outward curl at a prescribed curvature, and other shapes can be formed. - While the
coating layer 3 of the pulp molded article of the invention is preferably formed of a resin film as in the aforementioned embodiment, it may be formed by applying a coating composition. Coating methods include spreading a coating composition and dipping the containermain body 2 in a coating composition, and like techniques. - The outer surface of the pulp molded article of the present invention may be coated with another pulp fiber layer having a higher density than the
fiber layer 2 thereby to improve printability, strength, water resistance, and like properties. - The pulp fiber layer of the pulp molded article of the present invention is preferably formed by papermaking by use of a papermaking mold composed of a set of splits which are joined to form a cavity of prescribed shape as in the above-mentioned embodiment, but use of such a split mold is not always necessary for producing some shapes of pulp molded articles. Further, other papermaking methods are employable.
- For example, papermaking can be carried out by using a male mold. The male mold comprises a projected papermaking part corresponding to the contour of a container main body and having a large number of liquid flow holes open to the outer surface thereof and a prescribed papermaking screen covering the papermaking part. The male mold is immersed in the slurry, and the slurry is sucked up through the liquid flow holes to deposit the pulp fiber on the surface of the papermaking screen to form the pulp fiber layer. The male mold may be made of a rigid material or an elastic material.
- In producing the pulp molded article of the present invention, while it is preferred to use a hollow pressing member to heat dry the
pulp fiber layer 2 because of the capability of applying uniform pressure to thepulp fiber layer 2 however complicated the pulp fiber layer may be shaped, it is possible to use a solid pressing member to heat dry thepulp fiber layer 2. - The pulp molded article of the present invention can also be produced by placing the pulp fiber layer formed by papermaking into a female mold configured to the contour of the pulp fiber layer and fitting a heated male mold having a given clearance with the female mold into the female mold to effect drying the pulp fiber layer.
- The pulp molded article of the present invention can also be produced by setting a dried high-density pulp molded article (another pulp fiber layer) in a female mold, uniting a wet pulp fiber layer formed by papermaking with the another pulp fiber layer, fitting a heated male mold having a given clearance with the female mold into the female mold to dry the united two pulp fiber layers. According to this drying method, the wet pulp fiber layer is dried while being expanded by steam generated from the wet pulp fiber layer. As a result, there is obtained a pulp molded article having its outer side covered with a high-density pulp fiber layer and having its density increased from the outer side toward the inner side. The resulting pulp molded article is very excellent in printability, strength, and water resistance and also excellent in inner surface properties. The "another pulp fiber layer" as referred to above is formed by an ordinary papermaking method using the fiber employable to form the
pulp fiber layer 2. - While the pulp molded article of the present invention is especially suitable as a flanged heat-insulating container as in the above-described embodiment, the application of the present invention is not limited thereto. For example, the present invention is applicable to containers of various shapes, such as bowls, bottles, and trays; hollow articles, such as cylindrical shapes; and plate-shaped articles.
- The present invention will now be illustrated in greater detail with reference to Examples.
- Heat-insulating containers were made according to Example 1 and Comparative Example 1 and evaluated for performance. The results of evaluation are shown in Table 1.
- Geometry of container main body:
- Height H: 106 mm
- Inner diameter of opening (φ1): 90 mm
- Outer diameter of bottom (φ2): 68.5 mm
- Maximum outer diameter of flange (φ3): 96 mm
- Flange thickness T: 3 mm
- Body thickness T22: 1.4mm
- Bottom thickness T25: 1.2 mm
- A pulp fiber layer was formed by papermaking under the following conditions using a papermaking mold having the following specification. The papermaking mold was composed of a pair of splits which were joined to form a cavity corresponding to the container main body having the above-described geometry.
-
- Material: aluminum
- Total open area of interconnecting passageways: 1287 mm2 (54 holes x φ 3mm(= 382 mm2) in the portions corresponding to the body and the bottom and 3 mm wide slits (905 mm2) in the portion corresponding to the whole peripheral surface of the flange)
- Total open area of drainage channels (in checkered pattern): 25071 mm2
- Drainage channel width: 3 mm
- Total open area ratio of drainage channels on cavity-forming wall: 75%
- Papermaking screen: double screen composed of a 20 mesh PET net and a 80 mesh PET net
-
- Pulp slurry concentration: 0.1 wt%
- Pulp fiber: 50 wt% crosslinked pulp (HBA-LF supplied by Weyerhauser; U.S.A.) + 50 wt% bleached kraft pulp (BKP)
- Bulking agent: KB 115 available from Kao Corp. (5% based on the pulp fiber weight)
- Size: AS262 available from Japan PMC Corp. (2% based on the pulp fiber weight)
-
- Slurry feed: 15 liters (once)
- Slurry feed pressure: 0.2 MPa
- Cavity suction pressure: 0.06 MPa
- A pressurizing fluid was fed into the cavity under the following conditions to dewater the pulp fiber layer to a water content of 75%.
-
- Pressurizing fluid: compressed air
- Pressing force: 0.2 MPa x 15 seconds
- Cavity suction pressure: 0.06 MPa
- A drying mold having evacuation holes specified below was prepared. The evacuation holes were provided in the portions corresponding to the periphery of the flange and the bottom (including the base and the rising part of the wall) of the container main body to be produced. The pulp fiber layer was fitted into the drying mold and pressed by a pressing member having the following specification simultaneously with forcible evacuation through the evacuation holes. The forcible evacuation was stopped, and the pressing member was shrunken to produce the container main body.
-
- Material: aluminum
- Slit width of each evacuation hole: 0.15 mm
- Portion corresponding to flange: 4 slits arranged in the vertical direction at a 3 mm pitch around the peripheral surface of the flange, one of which was open to the part corresponding to the edge between the peripheral surface and the lower side of the flange.
- Portion corresponding to bottom: 4 slits at a 5 mm pitch on the base (per split); 5 slits arranged in the vertical direction at a 3 mm pitch over the whole peripheral surface of the part rising from the base.
- Total open area of evacuation holes on cavity-forming wall: 396 mm2
- Total open area ratio of evacuation holes on cavity-forming wall: 1.2%
-
- Material: silicone rubber
- Pressurizing fluid: compressed air
-
- Mold temperature: 200°C
- Pressing force of pressing member: 0.2 MPa x 15 seconds
- Forcible evacuation pressure: 5 kPa
- A coating layer was formed on the resulting container main body under the following conditions to produce a heat-insulating container.
- Resin film: polyethylene (LDPE/HDPE double layer structure)
- Resin film thickness: 150 µm
- Vacuum forming apparatus: PLAVAC-FE36PHS supplied by Sanwa-Kogyo Co., Ltd.
- Film heating system: infrared heater (heater-to-resin film distance: 110 mm)
- Film heating temperature: 255°C (temperature displayed on forming machine)
- Film heating time: 35 seconds
- Plug dimension: 60 mm in diameter x 127 mm in length
- Plug material: aluminum, surface-coated with Teflon (registered trade name)
- Plug temperature: 110°C (measured surface temperature)
- Vacuum forming mold: opening diameter φ, 89.8 mm; bottom diameter φ, 68.5 mm; height, 93.5 mm
- Vacuum forming mold temperature: 100°C (measured temperature of the inner surface)
- Forming time: 8 seconds
- A heat-insulating container was produced in the same manner as in Example 1, except for using a drying mold additionally having evacuation holes on the portion corresponding to the body of the container main body (0.15 mm wide slits over the whole circumference arranged in the vertical direction at a 10 mm interval).
- Pieces cut out of different portions of the resulting container main body were measured for apparent volume and weight, from which a bulk density was calculated.
- Different portions of the resulting container were observed under a field emission scanning electron microscope (Model S-4000, supplied by Hitachi, Ltd.) at a magnification of 50 times to examine density distribution.
- The resulting container was dried at 105°C for 1 hour in a low-humidity chamber and then weighed.
- A thermocouple was attached to the outer side of the body of the resulting container. Hot water at 80°C was poured into the container. After 3 minutes from the pouring, the temperature of the outer side of the body was measured, and whether the container containing the hot water could be held by the hand (graspability) was examined.
-
- O ... Lower than 60°C
- Δ ... 60 to 65°C
- X ... Higher than 65°C
-
- O ... The container felt warm.
- Δ ... The container felt slightly hot and yet was graspable.
- X ... The container felt hot and was not graspable.
- The resulting container was measured for vertical compressive strength and transverse compressive strength with a compression tester (Tensilon RTA-500, supplied by Orientec) in accordance with the following methods.
- The resulting container was placed upside down on a stage. An indenter was pressed down from the bottom of the container at a crosshead speed of 20 mm/min to obtain the compressive strength of the container body.
- O ... 25 kgf or higher (the strength required in packaging, transportation, and use)
X ... Lower than 25 kgf - The resulting container was placed on its side on a stage having a groove, into which the flange was fitted. A rounded rod indenter having a diameter of 10 mm was pressed down from the container body at a crosshead speed of 20 mm/min to obtain the compressive strength of the body. The measured strength was rated as follows in comparison with the value of a commercially available foamed polystyrene container.
O ... Equal to or higher than the strength of a foamed polystyrene container (the strength necessary for withstanding packaging, transportation, and use).
X ... Lower than the strength of a foamed polystyrene container.TABLE 1 Example 1 Compara. Example 1 Layer structure*1 double layer double layer Density distribution*2 yes no Each layer thickness*3 (mm) 1.4/0.03 0.6/0.03 Bulk density*4 (g/cm3) 0.4/0.25/0.35 - Heat insulating properties O X Strength O O Absolute dry weight*5 (g) 13 13 *1 Container main body + coating layer
*2 Density distribution in the container main body (body)
*3 Container main body (body)/coating layer
*4 Flange/body/bottom
*5 Dried at 105°C for 1 hour - As is shown in Table 1, the heat-insulating container of Example 1 was confirmed to be thinner, lighter, and more heat-insulating than that of Comparative Example 1 and sufficiently usable as a container for instant noodles.
- The present invention provides a novel pulp molded article which is thin, lightweight, and excellent in heat-insulating performance and a method and an apparatus for producing the pulp molded article efficiently.
Claims (13)
- A pulp molded article (1) having a pulp fiber layer (2) of single layer structure which is formed by papermaking from a single raw material composition and has a portion (22) having a density that changes in the thickness direction of said pulp fiber layer (2).
- The pulp molded article (1) according to claim 1, wherein the density of said portion (22) increases or decreases in the thickness direction of said pulp fiber layer (2).
- The pulp molded article (1) according to claim 1, wherein at least one of the inner surface and the outer surface of said pulp fiber layer (2) is coated with a coating layer (3).
- The pulp molded article (1) according to claim 1, wherein the outer surface of said pulp fiber layer (2) is coated with another pulp fiber layer.
- The pulp molded article (1) according to claim 4, wherein said another pulp fiber layer has a density higher than the highest density of said pulp fiber layer (2).
- The pulp molded article (1) according to claim (3), wherein said pulp fiber layer (2) and said coating layer (3) are each made from a biodegradable material.
- The pulp molded article (1) according to claim 1, wherein said pulp fiber layer is the main body (20) of a cup-shaped container (1) and has a flange (21) around the brim of the main body (20).
- The pulp molded article (1) according to claim 7, wherein said main body (20) comprises a body portion (22) and a bottom portion and wherein the body portion (22) of said main body (20) is provided with said changing density in the thickness direction of said pulp fiber layer (2).
- The pulp molded article according to claim 8, wherein said flange (21) and said bottom portion of said main body (20) have a higher density than the body portion (22) of said main body (20).
- A method of producing a pulp molded article (1) comprising a papermaking and dewatering step in which a pulp fiber layer (2) is made from a single raw material composition by papermaking and dewatered and a drying step in which the dewatered pulp fiber layer (2) is fitted into a drying mold (11) and dried while creating in a portion (22) of said pulp fiber layer (2) a density that changes in the thickness direction of said pulp fiber layer (2) wherein:said drying mold (11) has steam evacuation holes (13) connecting to the outside on the inner wall thereof only in the portion corresponding to the portion of said pulp fiber layer (2) where a changing density in the thickness direction of said pulp fiber layer (2) is not to be created,said pulp fiber layer (2) fitted in said drying mold (11) is pressed onto the inner wall of said drying mold (11) by an elastically deformable pressing member (16), while the drying mold (11) is forcibly evacuated through said evacuation holes (13),the pressing force by said pressing member (16) is reduced and, the evacuation through said evacuation holes (13) is stopped to separate said pressing member (16) from said pulp fiber layer (2) to obtain said pulp fiber layer (2) provided in a portion thereof with a density that changes in the thickness direction of said pulp fiber layer (2)
- The method of producing a pulp molded article (1) according to claim 10, wherein the step of pressing said pulp fiber layer (2) by said pressing member (16) and the step of reducing the pressing force of said pressing member (16) and stopping the evacuation are repeated to dry said pulp fiber layer (2).
- The method of producing a pulp molded article (1) according to claim 10, which further comprises a step of coating at least one of the inner surface and the outer surface of said pulp fiber layer (2) with a coating layer (3).
- An apparatus for carrying out the method of producing a pulp molded article (1) according to claim 10, which comprises a drying mold (11) into which a pulp fiber layer (2) is fitted and an elastically deformable pressing member (16) which presses the pulp fiber layer (2) fitted into said drying mold (11) from the inside of the pulp fiber layer (2) toward the inner wall of said drying mold, (11) said drying mold (11) having steam evacuation holes (13) connecting to the outside on the inner wall thereof only in the portion corresponding to the part of the pulp fiber layer (2) where a changing density in the thickness direction of said pulp fiber layer (2) is not to be created.
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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JP2001235859 | 2001-08-03 | ||
JP2001235858 | 2001-08-03 | ||
JP2001235859 | 2001-08-03 | ||
JP2001235858 | 2001-08-03 | ||
PCT/JP2002/007757 WO2003014471A1 (en) | 2001-08-03 | 2002-07-30 | Molded pulp product, and method and apparatus for production thereof |
Publications (3)
Publication Number | Publication Date |
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EP1439264A1 EP1439264A1 (en) | 2004-07-21 |
EP1439264A4 EP1439264A4 (en) | 2006-06-21 |
EP1439264B1 true EP1439264B1 (en) | 2011-06-08 |
Family
ID=26619886
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02755695A Expired - Fee Related EP1439264B1 (en) | 2001-08-03 | 2002-07-30 | Pulp molded article and method and apparatus for producing pulp molded article |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1439264B1 (en) |
CN (1) | CN1265057C (en) |
WO (1) | WO2003014471A1 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1533419B1 (en) * | 2002-05-10 | 2009-09-23 | Kao Corporation | Production mold for formed fiber |
GB2450872B (en) * | 2007-07-07 | 2011-12-21 | St Neots Packaging Ltd | Improvements in or relating to food packaging |
CN103452008B (en) * | 2013-01-16 | 2016-07-06 | 王高原 | The two-sided paper mould bowl cover without reticulate pattern and manufacture method thereof |
DE102014114187B4 (en) | 2014-09-30 | 2018-06-21 | Sig Technology Ag | Method and device for producing a fiber molded part and fiber molded part produced thereafter |
CN107386014B (en) * | 2017-07-06 | 2023-06-20 | 江苏绿森包装有限公司 | Pulp moulding negative angle container and its processing technology |
CN109518541A (en) * | 2018-11-08 | 2019-03-26 | 上海纳旭实业有限公司 | Preparation method of modified high-molecular fiber and paper fiber composite material and products thereof and application |
CN109518539A (en) * | 2018-11-08 | 2019-03-26 | 上海纳旭实业有限公司 | Preparation method of modified lignin resin and paper fiber composite material and products thereof and application |
CN110219210B (en) | 2019-01-31 | 2024-02-27 | 浙江舒康科技有限公司 | Pulp molding production line and processing method |
WO2022219526A1 (en) * | 2021-04-12 | 2022-10-20 | Stora Enso Oyj | A multilayered moulded product and method for the preparation thereof |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4850003A (en) * | 1971-11-01 | 1973-07-14 | ||
JPS51139838A (en) * | 1975-05-30 | 1976-12-02 | Dai Showa Giken Kogyo:Kk | A pulp moulded container. |
JPH11301753A (en) * | 1998-04-22 | 1999-11-02 | Toppan Printing Co Ltd | Paper heat-insulated container |
JP2000034699A (en) * | 1998-07-13 | 2000-02-02 | Oji Paper Co Ltd | Hot-pressing mold for pulp molded product and production of pulp molded product |
JP2000192400A (en) * | 1998-12-22 | 2000-07-11 | Oji Packaging Systems Co Ltd | Production of valve mold |
JP3249792B2 (en) * | 1999-08-04 | 2002-01-21 | 花王株式会社 | Dry mold for pulp mold |
JP2001055695A (en) * | 1999-08-09 | 2001-02-27 | Kao Corp | Drying mold for molded pulp product |
-
2002
- 2002-07-30 WO PCT/JP2002/007757 patent/WO2003014471A1/en active Application Filing
- 2002-07-30 CN CN 02803918 patent/CN1265057C/en not_active Expired - Fee Related
- 2002-07-30 EP EP02755695A patent/EP1439264B1/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP1439264A1 (en) | 2004-07-21 |
WO2003014471A1 (en) | 2003-02-20 |
EP1439264A4 (en) | 2006-06-21 |
CN1265057C (en) | 2006-07-19 |
CN1488021A (en) | 2004-04-07 |
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