EP1416038A1 - Thickened liquid bleaching compositions - Google Patents
Thickened liquid bleaching compositions Download PDFInfo
- Publication number
- EP1416038A1 EP1416038A1 EP20020257478 EP02257478A EP1416038A1 EP 1416038 A1 EP1416038 A1 EP 1416038A1 EP 20020257478 EP20020257478 EP 20020257478 EP 02257478 A EP02257478 A EP 02257478A EP 1416038 A1 EP1416038 A1 EP 1416038A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- amine oxide
- toilet
- hypochlorite
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
Definitions
- the present invention relates to thickened liquid bleaching compositions.
- the invention relates to thickened liquid bleaching compositions which contain hypochlorite and which are particularly suitable for use in toilet rim mounted toilet bowl cleaning devices.
- Toilet bowls require regular cleaning and disinfecting in order to prevent the accumulation of unsightly deposits, reduce odours and inhibit bacterial growth.
- Liquid hypochlorite-based bleaching agents are widely used and effective in this context. Typically the liquid bleaching agent is squirted neat from a bottle around the bowl and under the rim, with manual scrubbing if necessary.
- a liquid hypochlorite-based bleaching agent in a liquid dispensing device for the toilet rim.
- the formulation has to work at high dilution, due to the action of the flush water.
- a shear thinning rheology is desirable for effective liquid dispensing and dosing.
- an adequate foam profile is necessary so that product efficacy can be perceived by the consumer when the liquid is dosed into the toilet bowl.
- US 4,337,163 discloses a thickened bleach composition containing as the thickening agent a mixture of a first detergent such as an amine oxide and a second detergent selected from alkali-metal salts of saturated C 8-18 fatty acids, alkali metal acylsarcosinates, alkali metal alkyltaurides, sugar esters, and alkali metal C 10-18 alkyl ether sulphates with 1 to 10 moles of ethylene oxide and/or propylene oxide.
- a first detergent such as an amine oxide
- a second detergent selected from alkali-metal salts of saturated C 8-18 fatty acids, alkali metal acylsarcosinates, alkali metal alkyltaurides, sugar esters, and alkali metal C 10-18 alkyl ether sulphates with 1 to 10 moles of ethylene oxide and/or propylene oxide.
- WO 86/01823 discloses a thickened hypochlorite solution with less than 4% amine oxide and one or more cosurfactants selected from sarcosinate, alkyl ether sulphate and alkylsulphonate in amounts less than that of the amine oxide.
- US 4,588,514 discloses a thickened hypochlorite solution with a surfactant system including relatively large amounts of amine oxides, soaps or sarcosinates for thickening and a lesser amount of alkyl ether sulphate for storage stability.
- formulations described above are all pourable formulations intended for direct application by the user to the surface to be treated. Because of their increased viscosity, they are said to exhibit superior adhesion to vertical or inclined surfaces such as toilet bowls.
- the present inventors have found that it is possible to formulate a thickened liquid bleaching composition which contains hypochlorite and possess the correct balance of foam profile, rheology and efficacy such that it is suitable for use in toilet rim mounted toilet bowl cleaning devices.
- the present invention provides a liquid hypochlorite bleaching composition which is suitable for use in a toilet rim mounted toilet bowl cleaning device, the composition having a shear thinning rheology and being capable of generating a foam height of at least 3 cm immediately after the toilet flush when used in a toilet rim mounted cleaning device.
- composition of the invention has a shear thinning rheology.
- compositions according to the invention will have a viscosity between 2500 and 5000 mPa s at a shear rate of 1 s -1 and a viscosity between 1000 and 2500 mPa s at a shear rate of 161 s -1 when measured according to the above protocol.
- composition of the invention is capable of generating a foam height of at least 3 cm immediately after the toilet flush when used in a toilet rim mounted cleaning device.
- the foam height is measured when the composition is dosed at 0.17 g per flush from a dispenser mounted on the rim of a Villeroy & Boch toilet model "Magnum”, with 6 litres of water released per flush.
- liquid hypochlorite bleaching compositions which are thickened with a particular combination of amine oxide and sarcosinate surfactants have the desired properties as described above for suitability for use in toilet rim mounted toilet bowl cleaning devices.
- Suitable amine oxide surfactants for use in thickened liquid hypochlorite compositions according to the invention may be generally described as those tertiary amine oxides of the formula R 2 R'NO, in which each R is a lower alkyl group, for instance methyl, and R' is a long chain alkyl group having from 12 to 18 carbon atoms, for instance a lauryl, myristyl, palmityl, cetyl or stearyl group.
- the inventors have found that the chain length of the long chain alkyl group in the amine oxide surfactant is especially important for delivering optimum properties.
- the amine oxide surfactant will be present in the composition of the invention as a blend in which there is a certain quantitative distribution of different long chain alkyl group (R') chain lengths.
- At least 20 wt% of the amine oxide surfactant has an R' of C 12 , such as from 20 to 40 wt%, more preferably from 25 to 30 wt% (by weight based on the total weight of amine oxide surfactant), and at least 40 wt% of the amine oxide surfactant has an R' selected from C 14 , C 16 and C 18 and mixtures thereof, such as from 60 to 80 wt%, more preferably from 70 to 75 wt%, (by weight based on the total weight of amine oxide surfactant).
- the amine oxide surfactant will have a chain length distribution as follows (each by weight based on the total weight of amine oxide surfactant):
- the total amount of amine oxide surfactant used in thickened liquid hypochlorite compositions of the invention is also important for optimum performance, and it is most preferred that the amount is at least 6 wt%.
- the amount will typically range from 6 to 15 wt%, more preferably about 10 wt%, by total weight of amine oxide surfactant based on total weight of the composition.
- Suitable sarcosinate surfactants for use in thickened liquid hypochlorite compositions according to the invention include acyl sarcosinates or mixtures thereof.
- the acyl sarcosinate surfactants are derived from natural fatty acids and the amino-acid sarcosine (N-methyl glycine).
- Preferred are long chain acyl sarcosinates having the formula RCON(CH 3 )CH 2 COOM, in which M is an alkali metal cation, especially sodium or potassium, and R is a branched or straight chain C 8 -C 18 alkyl group.
- Suitable long acyl sarcosinates include sodium lauroyl sarcosinate, sodium myristoyl sarcosinate, sodium stearoyl sarcosinate, the corresponding potassium salts, and mixtures thereof.
- Sodium lauroyl sarcosinate is most preferred. This material is commercially available from Croda Chemical, UK under the trademark CRODASINIC® LS30.
- the amount of sarcosinate surfactant that may be used for use in thickened liquid hypochlorite compositions according to the invention preferably ranges from 0.1 to 10 wt%, more preferably from 1 to 5 wt%, and most preferably from 2 to 3 wt%, by total weight of sarcosinate surfactant based on total weight of the composition.
- compositions of the invention comprise hypochlorite in an aqueous matrix.
- the hypochlorite may be a simple hypochlorite salt such as those of the alkali or alkaline earth metals or a compound which produces hypochlorite on hydrolysis, such as organic N-chloro compounds. It is preferred to use an alkali metal hypochlorite such as sodium hypochlorite.
- the amount of hypochlorite present in thickened liquid hypochlorite compositions according to the invention preferably ranges from 0.1 to 10 wt%, more preferably from 1 to 8 wt%, and most preferably from 3 to 6 wt%, by weight of hypochlorite based on total weight of the composition.
- the composition of the invention also contains a source of alkalinity which keeps its pH at or above 11.5, not only during production of the product but also during storage.
- a source of alkalinity is meant a mixture of ingredients which is able to keep the pH at or above the required level.
- the pH of compositions of the invention will preferably be from 8 to 13, more preferably from 9 to 13.
- Suitable sources of alkalinity are known in the art and are generally made up of highly alkaline compounds such as alkali metal hydroxides and alkali metal salts of weak acids such as alkali metal carbonates and silicates.
- Particularly suitable sources of alkalinity are mixtures of alkali metal hydroxide and alkali metal silicate such as sodium silicate.
- composition of the invention may also contain other optional components to enhance consumer appeal such as such as perfumes and colorants.
- Such components should be sufficiently stable to hypochlorite at the pH of the composition to ensure adequate storage stability.
- Ultramarine Blue (UMB) and copper phthalocyanines are examples of widely used hypochlorite-stable pigments which may be incorporated in the composition of the present invention.
- composition of the invention is particularly suitable for use in toilet rim mounted toilet bowl cleaning devices.
- a preferred type of dispenser for use with the composition of the invention may be generally described as a device which is adapted to be suspended over the toilet rim, and which comprises a cartridge adapted to contain the composition, and a dispensing mechanism for the composition which releases the composition in response to the action of the flush water.
- a most preferred type of dispenser for use with the composition of the invention comprises a reusable holder which is adapted to engage with the cartridge, which is replaceable when empty.
- the holder incorporates a securing means such as a hook which is shaped to be clipped over the rim of the lavatory bowl, and has a distribution plate which projects into the path of flushing water from the lavatory when the dispenser is secured to the rim of the lavatory bowl.
- the plate typically bears a wicking device to spread the composition over the surface of the plate.
- the wicking device may for example be a porous pad, or more preferably a system of channels which direct the passage of the composition by capillary action.
- the composition is delivered from the cartridge to the surface of the plate where it is exposed to flushing water and washed off the plate and carried to the lavatory bowl.
- composition according to the invention was prepared having ingredients as shown in the following Table: INGREDIENT LEVEL wt% sodium lauroyl sarcosinatec 2.00 C12-18 alkyl dimethyl amine oxide blend 10.00 sodium hydroxide 1.00 sodium silicate 1.00 sodium hypochlorite 4.87 Demineralised water, minors To 100%
- composition according to the invention was prepared having ingredients as shown in the following Table: INGREDIENT LEVEL wt% sodium lauroyl sarcosinate (1) 2.00 C12-18 alkyl dimethyl amine oxide blend 10.00 sodium hydroxide 1.00 sodium silicate 1.00 sodium hypochlorite 4.87 Demineralised water, minors to 100%
- Comparative Example A has a shear thinning viscosity profile but does not give sufficient foam when dosed from a toilet rim mounted toilet bowl cleaning device.
- Comparative Example B gives sufficient foam but has a Newtonian viscosity profile which is undesirable for use in a toilet rim mounted toilet bowl cleaning device.
- Examples 1 and 2 each have a shear thinning viscosity profile and give sufficient foam when dosed from a toilet rim mounted toilet bowl cleaning device. It is believed that this is due to the optimal distribution of long chain alkyl group chain lengths in the amine oxide component, which is not present in either of Comparative Examples A or B.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
- The present invention relates to thickened liquid bleaching compositions. In particular, the invention relates to thickened liquid bleaching compositions which contain hypochlorite and which are particularly suitable for use in toilet rim mounted toilet bowl cleaning devices.
- Toilet bowls require regular cleaning and disinfecting in order to prevent the accumulation of unsightly deposits, reduce odours and inhibit bacterial growth.
- Liquid hypochlorite-based bleaching agents are widely used and effective in this context. Typically the liquid bleaching agent is squirted neat from a bottle around the bowl and under the rim, with manual scrubbing if necessary.
- Since the manual cleaning process is laborious and unpleasant for the consumer, various dispensing devices have been developed which automatically supply a dose of liquid to the toilet bowl in response to the action of the flush water.
- Devices of this type for the toilet rim have been described for example in EP 0 538 937, EP 0 785 315, WO 99/66139 and WO 99/66140.
- Such devices, however, have only been used to dispense detergent and/or fragrancing formulations and not liquid hypochlorite-based bleaching agents. This limits their utility insofar as effective sanitisation and disinfecting of the toilet bowl is concerned.
- It would be desirable to use a liquid hypochlorite-based bleaching agent in a liquid dispensing device for the toilet rim. However there are specific performance constraints which govern the suitability of a formulation for use in a liquid dispensing device for the toilet rim. For example, the formulation has to work at high dilution, due to the action of the flush water. Furthermore, a shear thinning rheology is desirable for effective liquid dispensing and dosing. Also, an adequate foam profile is necessary so that product efficacy can be perceived by the consumer when the liquid is dosed into the toilet bowl. These parameters are notoriously difficult to control simultaneously in hypochlorite-based systems.
- The use of various detergents or surface-active agents for providing a thickening function in hypochlorite bleach containing compositions has been described in the literature.
- For example, US 4,337,163 discloses a thickened bleach composition containing as the thickening agent a mixture of a first detergent such as an amine oxide and a second detergent selected from alkali-metal salts of saturated C8-18 fatty acids, alkali metal acylsarcosinates, alkali metal alkyltaurides, sugar esters, and alkali metal C10-18 alkyl ether sulphates with 1 to 10 moles of ethylene oxide and/or propylene oxide.
- WO 86/01823 discloses a thickened hypochlorite solution with less than 4% amine oxide and one or more cosurfactants selected from sarcosinate, alkyl ether sulphate and alkylsulphonate in amounts less than that of the amine oxide.
- US 4,588,514 discloses a thickened hypochlorite solution with a surfactant system including relatively large amounts of amine oxides, soaps or sarcosinates for thickening and a lesser amount of alkyl ether sulphate for storage stability.
- The formulations described above are all pourable formulations intended for direct application by the user to the surface to be treated. Because of their increased viscosity, they are said to exhibit superior adhesion to vertical or inclined surfaces such as toilet bowls.
- The present inventors have found that it is possible to formulate a thickened liquid bleaching composition which contains hypochlorite and possess the correct balance of foam profile, rheology and efficacy such that it is suitable for use in toilet rim mounted toilet bowl cleaning devices.
- In a first aspect, the present invention provides a liquid hypochlorite bleaching composition which is suitable for use in a toilet rim mounted toilet bowl cleaning device, the composition having a shear thinning rheology and being capable of generating a foam height of at least 3 cm immediately after the toilet flush when used in a toilet rim mounted cleaning device.
- The composition of the invention has a shear thinning rheology.
- This is measured at 25°C on a Haake VT500 viscometer using spindle MV2.
- Suitable compositions according to the invention will have a viscosity between 2500 and 5000 mPa s at a shear rate of 1 s-1 and a viscosity between 1000 and 2500 mPa s at a shear rate of 161 s-1 when measured according to the above protocol.
- The composition of the invention is capable of generating a foam height of at least 3 cm immediately after the toilet flush when used in a toilet rim mounted cleaning device.
- The foam height is measured when the composition is dosed at 0.17 g per flush from a dispenser mounted on the rim of a Villeroy & Boch toilet model "Magnum", with 6 litres of water released per flush.
- The inventors have found that liquid hypochlorite bleaching compositions which are thickened with a particular combination of amine oxide and sarcosinate surfactants have the desired properties as described above for suitability for use in toilet rim mounted toilet bowl cleaning devices.
- Suitable amine oxide surfactants for use in thickened liquid hypochlorite compositions according to the invention may be generally described as those tertiary amine oxides of the formula R2R'NO, in which each R is a lower alkyl group, for instance methyl, and R' is a long chain alkyl group having from 12 to 18 carbon atoms, for instance a lauryl, myristyl, palmityl, cetyl or stearyl group.
- The inventors have found that the chain length of the long chain alkyl group in the amine oxide surfactant is especially important for delivering optimum properties.
- Suitably the amine oxide surfactant will be present in the composition of the invention as a blend in which there is a certain quantitative distribution of different long chain alkyl group (R') chain lengths.
- Preferably at least 20 wt% of the amine oxide surfactant has an R' of C12, such as from 20 to 40 wt%, more preferably from 25 to 30 wt% (by weight based on the total weight of amine oxide surfactant), and at least 40 wt% of the amine oxide surfactant has an R' selected from C14, C16 and C18 and mixtures thereof, such as from 60 to 80 wt%, more preferably from 70 to 75 wt%, (by weight based on the total weight of amine oxide surfactant).
- Most preferably the amine oxide surfactant will have a chain length distribution as follows (each by weight based on the total weight of amine oxide surfactant):
- from 20 to 40 wt%, ideally from 25 to 30 wt%: R' is C12;
- from 35 to 75 wt%, ideally from 40 to 60 wt% : R' is C14;
- from 5 to 40 wt%, ideally from 10 to 35 wt%: R' is C16 and/or C18.
-
- The total amount of amine oxide surfactant used in thickened liquid hypochlorite compositions of the invention is also important for optimum performance, and it is most preferred that the amount is at least 6 wt%. The amount will typically range from 6 to 15 wt%, more preferably about 10 wt%, by total weight of amine oxide surfactant based on total weight of the composition.
- Suitable sarcosinate surfactants for use in thickened liquid hypochlorite compositions according to the invention include acyl sarcosinates or mixtures thereof. The acyl sarcosinate surfactants are derived from natural fatty acids and the amino-acid sarcosine (N-methyl glycine). Preferred are long chain acyl sarcosinates having the formula RCON(CH3)CH2 COOM, in which M is an alkali metal cation, especially sodium or potassium, and R is a branched or straight chain C8-C18 alkyl group. Specific examples of suitable long acyl sarcosinates include sodium lauroyl sarcosinate, sodium myristoyl sarcosinate, sodium stearoyl sarcosinate, the corresponding potassium salts, and mixtures thereof.
- Sodium lauroyl sarcosinate is most preferred. This material is commercially available from Croda Chemical, UK under the trademark CRODASINIC® LS30.
- The amount of sarcosinate surfactant that may be used for use in thickened liquid hypochlorite compositions according to the invention preferably ranges from 0.1 to 10 wt%, more preferably from 1 to 5 wt%, and most preferably from 2 to 3 wt%, by total weight of sarcosinate surfactant based on total weight of the composition.
- Compositions of the invention comprise hypochlorite in an aqueous matrix. The hypochlorite may be a simple hypochlorite salt such as those of the alkali or alkaline earth metals or a compound which produces hypochlorite on hydrolysis, such as organic N-chloro compounds. It is preferred to use an alkali metal hypochlorite such as sodium hypochlorite.
- The amount of hypochlorite present in thickened liquid hypochlorite compositions according to the invention preferably ranges from 0.1 to 10 wt%, more preferably from 1 to 8 wt%, and most preferably from 3 to 6 wt%, by weight of hypochlorite based on total weight of the composition.
- Preferably, the composition of the invention also contains a source of alkalinity which keeps its pH at or above 11.5, not only during production of the product but also during storage. By "a source of alkalinity" is meant a mixture of ingredients which is able to keep the pH at or above the required level. The pH of compositions of the invention will preferably be from 8 to 13, more preferably from 9 to 13. Suitable sources of alkalinity are known in the art and are generally made up of highly alkaline compounds such as alkali metal hydroxides and alkali metal salts of weak acids such as alkali metal carbonates and silicates.
- Particularly suitable sources of alkalinity are mixtures of alkali metal hydroxide and alkali metal silicate such as sodium silicate.
- The composition of the invention may also contain other optional components to enhance consumer appeal such as such as perfumes and colorants. Such components should be sufficiently stable to hypochlorite at the pH of the composition to ensure adequate storage stability. Ultramarine Blue (UMB) and copper phthalocyanines are examples of widely used hypochlorite-stable pigments which may be incorporated in the composition of the present invention.
- The composition of the invention is particularly suitable for use in toilet rim mounted toilet bowl cleaning devices.
- A preferred type of dispenser for use with the composition of the invention may be generally described as a device which is adapted to be suspended over the toilet rim, and which comprises a cartridge adapted to contain the composition, and a dispensing mechanism for the composition which releases the composition in response to the action of the flush water.
- A most preferred type of dispenser for use with the composition of the invention comprises a reusable holder which is adapted to engage with the cartridge, which is replaceable when empty. The holder incorporates a securing means such as a hook which is shaped to be clipped over the rim of the lavatory bowl, and has a distribution plate which projects into the path of flushing water from the lavatory when the dispenser is secured to the rim of the lavatory bowl. The plate typically bears a wicking device to spread the composition over the surface of the plate. The wicking device may for example be a porous pad, or more preferably a system of channels which direct the passage of the composition by capillary action. In use, the composition is delivered from the cartridge to the surface of the plate where it is exposed to flushing water and washed off the plate and carried to the lavatory bowl.
- The invention will now be illustrated by the following nonlimiting Examples, in which all percentages are by weight based on total weight, unless otherwise indicated.
- A composition according to the invention was prepared having ingredients as shown in the following Table:
INGREDIENT LEVEL wt% sodium lauroyl sarcosinatec 2.00 C12-18 alkyl dimethyl amine oxide blend 10.00 sodium hydroxide 1.00 sodium silicate 1.00 sodium hypochlorite 4.87 Demineralised water, minors To 100% - A composition according to the invention was prepared having ingredients as shown in the following Table:
INGREDIENT LEVEL wt% sodium lauroyl sarcosinate(1) 2.00 C12-18 alkyl dimethyl amine oxide blend 10.00 sodium hydroxide 1.00 sodium silicate 1.00 sodium hypochlorite 4.87 Demineralised water, minors to 100% - Two comparative compositions were prepared, each having ingredients as shown in the following Tables:
-
INGREDIENT LEVEL wt% CRODASINIC® HT 15.00 sodium hydroxide 1.00 sodium hypochlorite 4.87 Demineralised water, minors to 100% -
INGREDIENT LEVEL wt% sodium lauroyl sarcosinate(1) 1.5 AROMOX® BW 500 33.33 sodium hydroxide 1.00 sodium silicate 1.00 sodium hypochlorite 4.87 Demineralised water, minors To 100% - Comparative Example A has a shear thinning viscosity profile but does not give sufficient foam when dosed from a toilet rim mounted toilet bowl cleaning device.
- Comparative Example B gives sufficient foam but has a Newtonian viscosity profile which is undesirable for use in a toilet rim mounted toilet bowl cleaning device.
- Examples 1 and 2 each have a shear thinning viscosity profile and give sufficient foam when dosed from a toilet rim mounted toilet bowl cleaning device. It is believed that this is due to the optimal distribution of long chain alkyl group chain lengths in the amine oxide component, which is not present in either of Comparative Examples A or B.
Claims (6)
- A liquid hypochlorite bleaching composition which is suitable for use in a toilet rim mounted toilet bowl cleaning device, the composition having a shear thinning rheology and being capable of generating a foam height of at least 3 cm immediately after the toilet flush when used in a toilet rim mounted cleaning device.
- A composition according to claim 1, which is thickened with a combination of amine oxide and sarcosinate surfactants.
- A composition according to claim 2, in which the amine oxide surfactant has the formula R2R'NO, in which each R is a lower alkyl group, and R' is a long chain alkyl group having from 12 to 18 carbon atoms, and in which the distribution of long chain alkyl group (R') chain lengths, each by weight based on the total weight of amine oxide, is as follows:from 25 to 30 wt%: R' is C12;from 40 to 60 wt% : R' is C14;from 10 to 35 wt%: R' is C16 and/or C18.
- A composition according to claim 2 or claim 3, in which the sarcosinate surfactant has the formula RCON(CH3)CH2 COOM, in which M is an alkali metal cation, especially sodium or potassium, and R is a branched or straight chain C8-C18 alkyl group.
- A composition according to any one of claims 2 to 4, in which the amount of amine oxide surfactant ranges from 6 to 15 wt% by total weight of amine oxide surfactant based on total weight of the composition.
- A composition according to any one of claims 1 to 5, in combination with a toilet rim mounted toilet bowl cleaning device.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE60217358T DE60217358T2 (en) | 2002-10-29 | 2002-10-29 | Thickened liquid bleaching compositions |
AT02257478T ATE350452T1 (en) | 2002-10-29 | 2002-10-29 | THICKENED LIQUID BLEACH COMPOSITIONS |
EP02257478A EP1416038B1 (en) | 2002-10-29 | 2002-10-29 | Thickened liquid bleaching compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02257478A EP1416038B1 (en) | 2002-10-29 | 2002-10-29 | Thickened liquid bleaching compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1416038A1 true EP1416038A1 (en) | 2004-05-06 |
EP1416038B1 EP1416038B1 (en) | 2007-01-03 |
Family
ID=32088055
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02257478A Expired - Lifetime EP1416038B1 (en) | 2002-10-29 | 2002-10-29 | Thickened liquid bleaching compositions |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1416038B1 (en) |
AT (1) | ATE350452T1 (en) |
DE (1) | DE60217358T2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007001341A2 (en) | 2005-06-24 | 2007-01-04 | Rhodia, Inc. | Structured surfactant compositions |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10208273B2 (en) | 2012-09-10 | 2019-02-19 | The Clorox Company | Drain formulation for enhanced hair dissolution |
US9487742B2 (en) | 2012-09-10 | 2016-11-08 | The Clorox Company | Drain formulation for enhanced hair dissolution |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0137551A1 (en) * | 1983-09-23 | 1985-04-17 | Unilever N.V. | Liquid thickened bleaching composition |
WO1986001823A1 (en) * | 1984-09-21 | 1986-03-27 | Lesieur-Cotelle | Aqueous thickened cleaning compositions |
WO1995033810A1 (en) * | 1994-06-07 | 1995-12-14 | Reckitt & Colman Inc. | Cleaning compositions thickened with n-alkyl-n-acyl amino acids and myristyl/cetyl dimethyl amine oxides |
WO1997006233A1 (en) * | 1995-08-10 | 1997-02-20 | Reckitt & Colman Inc. | Pigmented rheopectic cleaning compositions with thixotropic properties |
US5693601A (en) * | 1993-07-23 | 1997-12-02 | The Procter & Gamble Company | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants |
-
2002
- 2002-10-29 EP EP02257478A patent/EP1416038B1/en not_active Expired - Lifetime
- 2002-10-29 DE DE60217358T patent/DE60217358T2/en not_active Expired - Lifetime
- 2002-10-29 AT AT02257478T patent/ATE350452T1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0137551A1 (en) * | 1983-09-23 | 1985-04-17 | Unilever N.V. | Liquid thickened bleaching composition |
WO1986001823A1 (en) * | 1984-09-21 | 1986-03-27 | Lesieur-Cotelle | Aqueous thickened cleaning compositions |
US5693601A (en) * | 1993-07-23 | 1997-12-02 | The Procter & Gamble Company | Thickened aqueous detergent compositions with improved cleaning performance with short chain surfactants |
WO1995033810A1 (en) * | 1994-06-07 | 1995-12-14 | Reckitt & Colman Inc. | Cleaning compositions thickened with n-alkyl-n-acyl amino acids and myristyl/cetyl dimethyl amine oxides |
WO1997006233A1 (en) * | 1995-08-10 | 1997-02-20 | Reckitt & Colman Inc. | Pigmented rheopectic cleaning compositions with thixotropic properties |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007001341A2 (en) | 2005-06-24 | 2007-01-04 | Rhodia, Inc. | Structured surfactant compositions |
EP1988985A2 (en) * | 2005-06-24 | 2008-11-12 | Rhodia, Inc. | Structured surfactant compositions |
EP1988985A4 (en) * | 2005-06-24 | 2011-11-09 | Rhodia | Structured surfactant compositions |
Also Published As
Publication number | Publication date |
---|---|
ATE350452T1 (en) | 2007-01-15 |
DE60217358D1 (en) | 2007-02-15 |
DE60217358T2 (en) | 2007-05-16 |
EP1416038B1 (en) | 2007-01-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RU2534526C2 (en) | Spherical toilet seat units, their manufacture method and suspended container with spherical toilet seat units | |
CA2384953C (en) | Toilet bowl cleaning method | |
CA2191343C (en) | Cleaning compositions thickened with n-alkyl-n-acyl amino acids and myristyl/cetyl dimethyl amine oxides | |
CN102367399A (en) | Sanitation bubbles | |
WO1996021721A1 (en) | Concentrated, aqueous, surfactant-containing compositions | |
TW201226552A (en) | Liquid detergent composition for food processing equipment and/or cooking equipment | |
EP1416038B1 (en) | Thickened liquid bleaching compositions | |
CA2342248C (en) | Foaming drain cleaner | |
JP2017002137A (en) | Liquid detergent composition for hard surface | |
JPH0429720B2 (en) | ||
WO1998030672A1 (en) | Improvements in or relating to organic compositions | |
JP2008255310A (en) | Detergent composition to use exclusively for jet nozzle in warm water toilet seat | |
JP6095944B2 (en) | Foam composition | |
KR101857117B1 (en) | Cleaning composition for drain having an excellent cleaning effect | |
JP2001517711A (en) | Tableware solid detergent | |
JPS61287990A (en) | Detergent composition | |
JPH11501976A (en) | Spray bleaching composition with reduced respiratory irritation | |
JP4790130B2 (en) | Liquid bleach detergent composition | |
KR102517756B1 (en) | Cleaning container for sink drain and cleaning method using thereof | |
WO2000020543A1 (en) | Cleaning with short-chain surfactants | |
JPH02145697A (en) | Cleaning agent composition for flush toilet | |
JPH09235592A (en) | Liquid detergent composition | |
JP3635221B2 (en) | Washing soap | |
JP4132915B2 (en) | Bleach composition | |
JP2001316697A (en) | Bleaching agent composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
AX | Request for extension of the european patent |
Extension state: AL LT LV MK RO SI |
|
17P | Request for examination filed |
Effective date: 20040331 |
|
AKX | Designation fees paid |
Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
GRAS | Grant fee paid |
Free format text: ORIGINAL CODE: EPIDOSNIGR3 |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Kind code of ref document: B1 Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR IE IT LI LU MC NL PT SE SK TR |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 60217358 Country of ref document: DE Date of ref document: 20070215 Kind code of ref document: P |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070403 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: BG Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES Effective date: 20070404 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070414 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070604 |
|
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
EN | Fr: translation not filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
26N | No opposition filed |
Effective date: 20071005 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CZ Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070404 Ref country code: FR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070824 Ref country code: IT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071031 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071030 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: EE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20071029 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: TR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20070103 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20091028 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20091026 Year of fee payment: 8 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20101029 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20101029 |
|
REG | Reference to a national code |
Ref country code: DE Ref legal event code: R119 Ref document number: 60217358 Country of ref document: DE Effective date: 20110502 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20110502 |