EP1412093B1 - Liquid or gel product dispenser forming a metering stick - Google Patents

Liquid or gel product dispenser forming a metering stick Download PDF

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Publication number
EP1412093B1
EP1412093B1 EP02772484A EP02772484A EP1412093B1 EP 1412093 B1 EP1412093 B1 EP 1412093B1 EP 02772484 A EP02772484 A EP 02772484A EP 02772484 A EP02772484 A EP 02772484A EP 1412093 B1 EP1412093 B1 EP 1412093B1
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EP
European Patent Office
Prior art keywords
piston
tip
dispenser according
pump casing
container
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP02772484A
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German (de)
French (fr)
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EP1412093A1 (en
Inventor
Jean-Louis Bougamont
François NICOLLE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Silgan Dispensing Systems Le Treport SAS
Original Assignee
Rexam Dispensing Systems SAS
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1001Piston pumps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B11/00Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
    • B05B11/01Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
    • B05B11/10Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
    • B05B11/1094Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle having inlet or outlet valves not being actuated by pressure or having no inlet or outlet valve

Definitions

  • the present invention relates to a liquid or gel product dispenser, such as a cosmetic or pharmaceutical product, ( US 3908870 A ).
  • distributors of the type comprising a reservoir supporting a pump body closed at the bottom by an intake valve and provided in the upper part of a piston defining, with the body, a dosing chamber having at least one orifice of ejection, the pump body cooperating with a dispensing nozzle axially displaceable on the reservoir.
  • these distributors use piston return means in the upper position, in the form of one or more metal springs. Such springs are not always chemically or biologically compatible with the packaged products.
  • the present invention aims to solve these various technical problems satisfactorily.
  • the invention relates to a liquid or gel product dispenser, of the type comprising a reservoir supporting a pump body having in the lower part an intake valve and provided with a piston movable along an axis, delimiting with said body a metering chamber in communication with at least one ejection orifice defined in a dispensing nozzle axially displaceable at the end of said reservoir, characterized in that said piston is frictionally coupled to said dispensing nozzle, which is axially displaceable in the two directions by manual operation, relative to said reservoir, between two predetermined positions, in that said metering chamber comprises, on the one hand, a lower compartment defined between said body and said piston and, on the other hand, a defined upper compartment between the piston and said tip, the two compartments communicating via a conduit formed through said piston and in that a shutter valve is arranged between said piston and said tip to isolate said metering chamber of said orifice.
  • the tip has the shape of a cap arranged to partially envelop said tank, said cap having an upper wall, substantially perpendicular to said axis, in which is formed said ejection orifice.
  • this wall may be relatively thin, the or each ejection orifice is summarized in a short hole in which the amount of product likely to dry is very small.
  • the piston comes directly into contact with this hole, inside and according to another embodiment, the shutter valve comprises a shutter member carried by the piston and which engages with sealed manner in the ejection port itself so that no amount of product is likely to dry.
  • the piston carries a flange, external to the pump body which slides sealingly inside the nozzle by compressing the product in the upper compartment, to push it outwards.
  • the flange comprises an upper shoulder extended at its periphery and downwardly by a lateral skirt. The latter slides with a certain friction in the tip itself.
  • this skirt is provided with a retaining ring cooperating with an upper rim of the pump body, to ensure the abutment of the collar in the upper position.
  • one or more ejection orifices are formed through the upper wall of the nozzle to the right of said collar of the piston.
  • the single ejection orifice is formed through the upper wall of the nozzle in the axis of the central duct of the piston.
  • the shutter member, carried by the piston is likely to engage in this ejection port.
  • the shut-off valve comprises a shutter member projecting from the inner face of said upper wall of the nozzle, axially. This shutter element is able to engage sealingly in the upper part of the central duct of the piston.
  • the pump body is provided, in the upper part, with a peripheral groove in which axially slides an annular sealing lip, integral with said collar of the piston.
  • the reservoir comprises a bottle receiving an internal support sleeve for the pump body.
  • the dispensing tip is movably mounted on this sleeve.
  • the inner wall of the tank comprises a set of flexible, stop fins cooperating with complementary fins carried by the nozzle.
  • the configuration of the dispenser according to the invention provided with a chamber in two compartments forms an airlock promoting a regular distribution of the product.
  • the location of the shutter valve ensures a high seal, which guarantees the hermeticity of the dispenser and the protection of the product.
  • the low seal is reinforced by the locking of the inlet valve in the closed position, by means of the piston itself.
  • the dispenser shown in the figures is more particularly intended for the packaging of cosmetic products or pharmaceuticals.
  • the first embodiment of the dispenser has a cylindrical shape comparable to a stick.
  • This dispenser comprises a tank R supporting a pump body 1 closed at the bottom by an intake valve 2 and extended by a socket tube 11 extending inside the tank.
  • the valve 2 consists of a ball 21 housed in a frustoconical portion 12 of the pump body 1, which delimits a feed channel.
  • the ball has, between two stops, a freedom of axial displacement.
  • the reservoir R is surmounted by a dispensing nozzle E in the wall of which are formed four ejection orifices e.
  • the tip E has the shape of a generally cylindrical cap, as described above.
  • the body 1 is provided, in the upper part, with a piston 3 delimiting with the body 1 and the nozzle E a metering chamber communicating with the ejection orifices e.
  • a shutter valve 5 is defined between the nozzle E and the piston 3.
  • the nozzle E is axially displaceable relative to the tank R, it is possible for example to provide an axial displacement in translation and sliding of the nozzle E relative to the reservoir. or, according to a variant not shown, an axial displacement by screwing / unscrewing the tip E on the tank R.
  • the tank R comprises a bottle F receiving an inner socket d of support of the pump body 1.
  • the bush d is fitted at its lower part in the neck of the tank with a radial clamping. It is shaped to delimit with the reservoir, an annular space 6 in which is housed and moves in translation and / or rotation of the wall of the nozzle E.
  • the pump body 1 is provided with a vent port 14 practiced through its side wall in the part that is inside the tank R and allowing the return of air. This orifice 14 is associated here with a groove 15 because the upper part of the body 1 is also fitted with a slight radial clamping in the neck of the sleeve d.
  • the metering chamber is formed, on the one hand, of a lower compartment 10a located between the body 1 and the cylindrical central portion 3a of the piston 3 and, on the other hand, of an upper compartment 10b situated between the piston 3 and the inner wall of the tip E (see Figures 2C, 2D and 5B ).
  • the lower compartments 10a and 10b are variable volumes and are capable of communicating with each other via a conduit 30 formed here axially through the central portion 3a of the piston 3.
  • the piston 3 carries a flange 31 external to the body 1, which delimits a portion of the compartment 10b and which is slidable sealingly inside the nozzle E to compress the product in the upper compartment 10b.
  • the piston 3 is movable in translation, axially both with respect to the pump body 1 and relative to the endpiece E. It is frictionally coupled to the end piece E, thanks to the skirt 31c. It comes into abutment, downwards, against the ball 21 of the intake valve 2 and upwards against the inner face of the upper wall 7 of the nozzle E. This wall is, as can be seen, substantially perpendicular to the axis of movement of the piston.
  • the piston 3 thus exerts a double action, successively in the lower compartment 10a and then in the upper compartment 10b of the metering chamber, leading to an ejection of the product in two stages.
  • the flange 31 has an upper shoulder 31 has extended at its periphery and downwards by a side skirt 31b sliding with a slight friction against the cylindrical inner side wall of the nozzle E.
  • the lower edge of the skirt 31b is provided a retaining ring 31c cooperating with an upper flange 1a of the body 1, to ensure the upper abutment of the flange 31.
  • the shutter valve 5 is constituted by a shutter element in the form of a needle 4, projecting from the inner face of the wall 7 of the nozzle E.
  • This needle is able to engage with a watertight sliding in the upper part of the conduit 30 of the piston.
  • Four ejection orifices e are arranged around this needle.
  • the sealing of the closing of the shut-off valve is here mainly obtained by the gentle sliding engagement of the needle 4 in the upper part of the conduit 30.
  • the orifices are here formed through the upper wall of the nozzle E , opposite the shoulder 31a of the collar 31, there is a complementary sealing wall.
  • the tip moves by first driving the piston 3 retained by radial clamping, the ejection ports being open and the inlet valve 2 closed.
  • the compression of the product in the lower compartment 10a ensures its ejection.
  • the closing of the intake valve 2 is confirmed and the nozzle E continues its descent by compressing the product in the upper compartment 10b ( Fig. 2D ) until the ejection ports e are closed from the inside.
  • blocking means 46 operating by clipping effect, stabilize the position of the nozzle E relative to the reservoir R.
  • These locking means here consist of an annular ring 47 provided on the outside of the socket d and a corresponding annular groove 48 formed at the base of the inner wall of the nozzle E. These locking means confirm and reinforce the closure of the inlet valve 2 and that of the shutter valve 5.
  • the shutter member is carried by the piston 3 and is able to engage in leaktight sliding in a ejection orifice e ', unique, the endpiece E. It comprises a lug 32 integral with the collar 31 and extending coaxially with the conduit 30.
  • the single ejection orifice e ' is made through the upper wall of the nozzle E in the axis of the duct 30 but here with a diameter greater than that of the orifices e of the embodiment described above.
  • the orifice e ' is of cylindroconic section while the lug 32 is cylindrical.
  • the central duct 30 opens here into the upper compartment 10b of the metering chamber, through openings 34 formed in the shoulder 31a, defined between connecting bridges around the pin 32.
  • the pump body 1 is provided, in the upper part, with a peripheral groove 13 in which slides an annular sealing lip 33 connected to the piston 3. It is carried by the lower face of the shoulder 31 has flange 31.
  • a vent orifice 14 is made between the upper side wall of the body and the groove 13. This orifice is associated with a groove 15 because the upper part of the body 1 is fitted with a slight radial clamping in the socket d. Air can flow between bushing d and ferrule E (see Fig. 5B ).
  • the side wall of the lip 33 has a narrowing 35 on its radially outer face and extending over a height h. This constriction defines a passage for the return of air, in the tank R, via the orifice 14, in the high position of the flange 31.
  • the inner wall of the reservoir R, and more precisely of the bottle F comprises a flexible stop fins game cooperating with complementary ribs a 'carried by the lower part of the outer side wall of the nozzle E.
  • the flexibility of the fins a ' allows the introduction of the lower edge of the nozzle E in the spacer between the bottle F and the sleeve d.
  • This embodiment allows easy packaging of the product in the tank R, filling the sleeve d upside down with the tip E in the closed position.
  • the bottle F is then mounted in the manner of a plug on the socket d to form the bottom of the tank before the dispenser is returned.
  • the volume of the metering chamber is minimal because the tip E is in the low position in contact with the shoulder 31a of the flange 31.
  • the free volumes of the compartments 10a and 10b are virtually zero.
  • the shutter element 32 is engaged in the ejection orifice e '( Fig. 5A ) which guarantees complete sealing of the dispenser without contact of any fraction of the product with the atmosphere.
  • the shutter valve is arranged in the immediate vicinity of the ejection orifices (e or e ') formed in the end wall of the nozzle E.

Abstract

The invention concerns a liquid or gel product dispenser, comprising a reservoir (R) supporting a pump body ( 1 ) including in its lower part an intake valve ( 2 ) and provided with a piston ( 3 ) mobile along an axis, defining with said body a metering chamber communicating with at least an ejection orifice defined in an axially mobile dispensing nozzle at the end of the reservoir; said piston is coupled by friction with said dispensing nozzle, which is axially mobile in both directions by manual actuation, relative to said reservoir; said metering chamber comprises a lower section ( 10 a) and an upper section ( 10 b), both sections communicating via a conduit ( 30 ) arranged across said piston and a closure valve ( 5 ) is arranged between said piston and said nozzle.

Description

La présente invention concerne un distributeur de produit liquide ou en gel, tel qu'un produit cosmétique ou pharmaceutique, ( US 3908870 A ).The present invention relates to a liquid or gel product dispenser, such as a cosmetic or pharmaceutical product, ( US 3908870 A ).

Il existe déjà des distributeurs du type comprenant un réservoir supportant un corps de pompe obturé en partie basse par un clapet d'admission et pourvu en partie haute d'un piston délimitant, avec le corps, une chambre de dosage comportant au moins un orifice d'éjection, le corps de pompe coopérant avec un embout de distribution déplaçable axialement sur le réservoir.There already exist distributors of the type comprising a reservoir supporting a pump body closed at the bottom by an intake valve and provided in the upper part of a piston defining, with the body, a dosing chamber having at least one orifice of ejection, the pump body cooperating with a dispensing nozzle axially displaceable on the reservoir.

Cependant, dans de tels distributeurs, s'il existe un clapet obturateur destiné à arrêter l'échappement du produit, celui-ci est situé dans la pompe et à une distance appréciable de l'orifice d'éjection. Or, la présence d'un reliquat de produit dans la zone au contact de l'atmosphère extérieure est susceptible d'obstruer, par séchage, les voies de distribution et/ou d'induire des risques de contamination.However, in such dispensers, if there is a shutter valve to stop the escape of the product, it is located in the pump and at an appreciable distance from the ejection orifice. However, the presence of a residue of product in the zone in contact with the outside atmosphere is likely to obstruct, by drying, the distribution channels and / or to induce risks of contamination.

En outre, ces distributeurs utilisent des moyens de rappel du piston en position haute, sous forme d'un ou plusieurs ressorts métalliques. De telles ressorts ne sont pas toujours compatibles chimiquement ou biologiquement avec les produits conditionnés.In addition, these distributors use piston return means in the upper position, in the form of one or more metal springs. Such springs are not always chemically or biologically compatible with the packaged products.

Enfin, l'étanchéité de la partie basse du corps de pompe n'est pas suffisamment fiable, ce qui compromet la précision du dosage.Finally, the seal of the lower part of the pump body is not sufficiently reliable, which compromises the accuracy of the dosage.

La présente invention a pour but de résoudre ces différents problèmes techniques de manière satisfaisante.The present invention aims to solve these various technical problems satisfactorily.

Plus particulièrement, l'invention concerne un distributeur de produit liquide ou en gel, du type comprenant un réservoir supportant un corps de pompe comportant en partie basse un clapet d'admission et pourvu d'un piston mobile suivant un axe, délimitant avec ledit corps une chambre de dosage en communication avec au moins un orifice d'éjection défini dans un embout de distribution déplaçable axialement à l'extrémité dudit réservoir, caractérisé en ce que ledit piston est couplé par friction audit embout de distribution, lequel est déplaçable axialement dans les deux sens par actionnement manuel, relativement audit réservoir, entre deux positions prédéterminées, en ce que ladite chambre de dosage comporte, d'une part, un compartiment inférieur défini entre ledit corps et ledit piston et, d'autre part, un compartiment supérieur défini entre le piston et ledit embout, les deux compartiments communiquant via un conduit ménagé au travers dudit piston et en ce qu'un clapet obturateur est agencé entre ledit piston et ledit embout pour isoler ladite chambre de dosage dudit orifice.More particularly, the invention relates to a liquid or gel product dispenser, of the type comprising a reservoir supporting a pump body having in the lower part an intake valve and provided with a piston movable along an axis, delimiting with said body a metering chamber in communication with at least one ejection orifice defined in a dispensing nozzle axially displaceable at the end of said reservoir, characterized in that said piston is frictionally coupled to said dispensing nozzle, which is axially displaceable in the two directions by manual operation, relative to said reservoir, between two predetermined positions, in that said metering chamber comprises, on the one hand, a lower compartment defined between said body and said piston and, on the other hand, a defined upper compartment between the piston and said tip, the two compartments communicating via a conduit formed through said piston and in that a shutter valve is arranged between said piston and said tip to isolate said metering chamber of said orifice.

Selon un mode de réalisation possible, l'embout a la forme d'un capuchon agencé pour envelopper partiellement ledit réservoir, ledit capuchon présentant une paroi supérieure, sensiblement perpendiculaire audit axe, dans laquelle est pratiqué ledit orifice d'éjection. Comme cette paroi peut être relativement mince, le ou chaque orifice d'éjection se résume à un trou de faible longueur dans lequel la quantité de produit susceptible de sécher est infime. Selon l'un des modes de réalisation, le piston vient directement au contact de ce trou, à l'intérieur et selon un autre mode de réalisation, le clapet obturateur comporte un élément d'obturation porté par le piston et qui s'engage de manière étanche dans l'orifice d'éjection lui-même de sorte qu'aucune quantité de produit n'est susceptible de sécher.According to a possible embodiment, the tip has the shape of a cap arranged to partially envelop said tank, said cap having an upper wall, substantially perpendicular to said axis, in which is formed said ejection orifice. As this wall may be relatively thin, the or each ejection orifice is summarized in a short hole in which the amount of product likely to dry is very small. According to one embodiment, the piston comes directly into contact with this hole, inside and according to another embodiment, the shutter valve comprises a shutter member carried by the piston and which engages with sealed manner in the ejection port itself so that no amount of product is likely to dry.

Selon une caractéristique avantageuse, le piston porte une collerette, extérieure au corps de pompe qui coulisse de façon étanche à l'intérieur de l'embout en comprimant le produit dans le compartiment supérieur, pour le refouler vers l'extérieur.According to an advantageous characteristic, the piston carries a flange, external to the pump body which slides sealingly inside the nozzle by compressing the product in the upper compartment, to push it outwards.

Selon une autre caractéristique avantageuse, la collerette comporte un épaulement supérieur prolongé à sa périphérie et vers le bas par une jupe latérale. Cette dernière coulisse avec un certain frottement dans l'embout lui-même.According to another advantageous characteristic, the flange comprises an upper shoulder extended at its periphery and downwardly by a lateral skirt. The latter slides with a certain friction in the tip itself.

De préférence, le bord inférieur de cette jupe est pourvu d'un jonc de retenu coopérant avec un rebord supérieur du corps de pompe, pour assurer la butée de la collerette en position haute.Preferably, the lower edge of this skirt is provided with a retaining ring cooperating with an upper rim of the pump body, to ensure the abutment of the collar in the upper position.

Selon une première variante, un ou plusieurs orifices d'éjection sont ménagés au travers de la paroi supérieure de l'embout au droit de ladite collerette du piston.According to a first variant, one or more ejection orifices are formed through the upper wall of the nozzle to the right of said collar of the piston.

Selon une autre variante, l'orifice d'éjection, unique, est ménagé au travers de la paroi supérieure de l'embout dans l'axe du conduit central du piston. L'élément d'obturation, porté par le piston est susceptible de s'engager dans cet orifice d'éjection.According to another variant, the single ejection orifice is formed through the upper wall of the nozzle in the axis of the central duct of the piston. The shutter member, carried by the piston is likely to engage in this ejection port.

Selon une autre variante, le clapet d'obturation comporte un élément d'obturation faisant saillie de la face interne de ladite paroi supérieure de l'embout, axialement. Cet élément d'obturation est susceptible de s'engager de manière étanche dans la partie haute du conduit centrale du piston.According to another variant, the shut-off valve comprises a shutter member projecting from the inner face of said upper wall of the nozzle, axially. This shutter element is able to engage sealingly in the upper part of the central duct of the piston.

Selon une autre caractéristique, le corps de pompe est pourvu, en partie haute, d'une gorge périphérique dans laquelle coulisse axialement une lèvre annulaire d'étanchéité ,solidaire de ladite collerette du piston.According to another characteristic, the pump body is provided, in the upper part, with a peripheral groove in which axially slides an annular sealing lip, integral with said collar of the piston.

Selon une variante , le réservoir comprend un flacon recevant une douille interne de support du corps de pompe. L'embout de distribution est monté de manière mobile sur cette douille.According to a variant, the reservoir comprises a bottle receiving an internal support sleeve for the pump body. The dispensing tip is movably mounted on this sleeve.

Selon une variante, la paroi interne du réservoir comporte un jeu d'ailettes d'arrêt, flexibles, coopérant avec des ailettes complémentaires portées par l'embout.According to a variant, the inner wall of the tank comprises a set of flexible, stop fins cooperating with complementary fins carried by the nozzle.

La configuration du distributeur selon l'invention, muni d'une chambre en deux compartiments forme un sas d'évacuation favorisant une distribution régulière du produit.The configuration of the dispenser according to the invention, provided with a chamber in two compartments forms an airlock promoting a regular distribution of the product.

Par ailleurs, l'emplacement du clapet obturateur permet d'assurer une étanchéité haute, ce qui garantit l'herméticité du distributeur et la protection du produit.Furthermore, the location of the shutter valve ensures a high seal, which guarantees the hermeticity of the dispenser and the protection of the product.

En outre, l'étanchéité basse est renforcée par le verrouillage du clapet d'admission en position de fermeture, au moyen du piston lui-même.In addition, the low seal is reinforced by the locking of the inlet valve in the closed position, by means of the piston itself.

L'invention sera mieux comprise à la lecture de la description qui va suivre en référence aux dessins sur lesquels :

  • la figure 1 est une vue en perspective d'un premier mode de réalisation du distributeur de l'invention;
  • les figures 2A à 2D représentent des vues en coupe verticale du distributeur de la figure 1 dans différentes positions ;
  • la figure 3 représente une vue en coupe horizontale du distributeur de la figure 1 dans la position de la figure 2A ;
  • la figure 4 est une vue en perspective d'un second mode de réalisation du distributeur de l'invention ; et
  • les figures 5A et 5B représentent des vues en coupe verticale du distributeur de la figure 4 en position, respectivement, de fermeture et d'ouverture.
The invention will be better understood on reading the description which follows with reference to the drawings in which:
  • the figure 1 is a perspective view of a first embodiment of the dispenser of the invention;
  • the Figures 2A to 2D represent vertical section views of the distributor of the figure 1 in different positions;
  • the figure 3 represents a horizontal sectional view of the dispenser of the figure 1 in the position of the Figure 2A ;
  • the figure 4 is a perspective view of a second embodiment of the dispenser of the invention; and
  • the Figures 5A and 5B represent vertical section views of the distributor of the figure 4 in position, respectively, closing and opening.

Le distributeur représenté sur les figures est plus particulièrement destiné au conditionnement de produits cosmétiques ou pharmaceutiques. Comme représenté sur la figure 1, le premier mode de réalisation du distributeur a une forme cylindrique assimilable à un bâton.The dispenser shown in the figures is more particularly intended for the packaging of cosmetic products or pharmaceuticals. As shown on the figure 1 , the first embodiment of the dispenser has a cylindrical shape comparable to a stick.

Ce distributeur comprend un réservoir R supportant un corps de pompe 1 obturé en partie basse par un clapet d'admission 2 et prolongé par un tube de prise 11 s'étendant à l'intérieur du réservoir. Le clapet 2 est constitué d'une bille 21 logée dans une partie tronconique 12 du corps de pompe 1, lequel délimite un canal d'alimentation. La bille dispose, entre deux butées, d'une liberté de déplacement axial.This dispenser comprises a tank R supporting a pump body 1 closed at the bottom by an intake valve 2 and extended by a socket tube 11 extending inside the tank. The valve 2 consists of a ball 21 housed in a frustoconical portion 12 of the pump body 1, which delimits a feed channel. The ball has, between two stops, a freedom of axial displacement.

Le réservoir R est surmonté d'un embout de distribution E dans la paroi duquel sont ménagés quatre orifices d'éjection e. L'embout E a la forme d'un capuchon globalement cylindrique, comme décrit ci-dessus. Le corps 1 est pourvu, en partie haute, d'un piston 3 délimitant avec le corps 1 et l'embout E une chambre de dosage communiquant avec les orifices d'éjection e. Un clapet obturateur 5 est défini entre l'embout E et le piston 3. L'embout E est déplaçable axialement par rapport au réservoir R, on peut par exemple prévoir un déplacement axial en translation et coulissement de l'embout E par rapport au réservoir ou, selon une variante non représentée, un déplacement axial par vissage/dévissage de l'embout E sur le réservoir R.The reservoir R is surmounted by a dispensing nozzle E in the wall of which are formed four ejection orifices e. The tip E has the shape of a generally cylindrical cap, as described above. The body 1 is provided, in the upper part, with a piston 3 delimiting with the body 1 and the nozzle E a metering chamber communicating with the ejection orifices e. A shutter valve 5 is defined between the nozzle E and the piston 3. The nozzle E is axially displaceable relative to the tank R, it is possible for example to provide an axial displacement in translation and sliding of the nozzle E relative to the reservoir. or, according to a variant not shown, an axial displacement by screwing / unscrewing the tip E on the tank R.

Dans le mode de réalisation des figures 2A à 2D, le réservoir R comprend un flacon F recevant une douille interne d de support du corps de pompe 1.In the embodiment of Figures 2A to 2D , the tank R comprises a bottle F receiving an inner socket d of support of the pump body 1.

La douille d est emmanchée à sa partie inférieure dans le col du réservoir avec un serrage radial. Elle est conformée pour délimiter avec le réservoir, un espace annulaire 6 dans lequel est logée et se déplace en translation et/ou en rotation la paroi de l'embout E. Le corps de pompe 1 est pourvu d'un orifice d'évent 14 pratiqué au travers de sa paroi latérale dans la partie qui se trouve à l'intérieur du réservoir R et permettant la reprise d'air. Cet orifice 14 est associé ici à une rainure 15 du fait que la partie haute du corps 1 est aussi emmanchée avec un léger serrage radial dans le col de la douille d.The bush d is fitted at its lower part in the neck of the tank with a radial clamping. It is shaped to delimit with the reservoir, an annular space 6 in which is housed and moves in translation and / or rotation of the wall of the nozzle E. The pump body 1 is provided with a vent port 14 practiced through its side wall in the part that is inside the tank R and allowing the return of air. This orifice 14 is associated here with a groove 15 because the upper part of the body 1 is also fitted with a slight radial clamping in the neck of the sleeve d.

La chambre de dosage est formée, d'une part, d'un compartiment inférieur 10a situé entre le corps 1 et la partie centrale cylindrique 3a du piston 3 et, d'autre part, d'un compartiment supérieur 10b situé entre le piston 3 et la paroi interne de l'embout E (voir figures 2C, 2D et 5B). Les compartiments inférieur 10a et supérieur 10b sont de volumes variables et sont susceptibles de communiquer l'un avec l'autre via un conduit 30 ménagé ici axialement au travers de la partie centrale 3a du piston 3.The metering chamber is formed, on the one hand, of a lower compartment 10a located between the body 1 and the cylindrical central portion 3a of the piston 3 and, on the other hand, of an upper compartment 10b situated between the piston 3 and the inner wall of the tip E (see Figures 2C, 2D and 5B ). The lower compartments 10a and 10b are variable volumes and are capable of communicating with each other via a conduit 30 formed here axially through the central portion 3a of the piston 3.

Le piston 3 porte une collerette 31 extérieure au corps 1, qui délimite une partie du compartiment 10b et qui est susceptible de coulisser de façon étanche à l'intérieur de l'embout E pour comprimer le produit dans le compartiment supérieur 10b.The piston 3 carries a flange 31 external to the body 1, which delimits a portion of the compartment 10b and which is slidable sealingly inside the nozzle E to compress the product in the upper compartment 10b.

Le piston 3 est mobile en translation, axialement à la fois par rapport au corps de pompe 1 et par rapport à l'embout E. Il est couplé par friction à l'embout E, grâce à la jupe 31 c. Il vient en butée, vers le bas, contre la bille 21 du clapet d'admission 2 et vers le haut contre la face interne de la paroi supérieure 7 de l'embout E. Cette paroi est, comme on voit, sensiblement perpendiculaire à l'axe de déplacement du piston.The piston 3 is movable in translation, axially both with respect to the pump body 1 and relative to the endpiece E. It is frictionally coupled to the end piece E, thanks to the skirt 31c. It comes into abutment, downwards, against the ball 21 of the intake valve 2 and upwards against the inner face of the upper wall 7 of the nozzle E. This wall is, as can be seen, substantially perpendicular to the axis of movement of the piston.

Le piston 3 exerce ainsi une double action, successivement dans le compartiment inférieur 10a puis dans le compartiment supérieur 10b de la chambre de dosage, conduisant à une éjection du produit en deux temps.The piston 3 thus exerts a double action, successively in the lower compartment 10a and then in the upper compartment 10b of the metering chamber, leading to an ejection of the product in two stages.

La collerette 31 comporte un épaulement supérieur 31 a prolongé à sa périphérie et vers le bas par une jupe latérale 31 b coulissant avec un léger frottement contre la paroi latérale intérieure cylindrique de l'embout E. Le bord inférieur de la jupe 31 b est pourvu d'un jonc de retenue 31 c coopérant avec un rebord supérieur 1a du corps 1, pour assurer la butée haute de la collerette 31.The flange 31 has an upper shoulder 31 has extended at its periphery and downwards by a side skirt 31b sliding with a slight friction against the cylindrical inner side wall of the nozzle E. The lower edge of the skirt 31b is provided a retaining ring 31c cooperating with an upper flange 1a of the body 1, to ensure the upper abutment of the flange 31.

Dans le mode de réalisation des figures 1 à 3, le clapet obturateur 5 est constitué d'un élément d'obturation sous forme d'un pointeau 4, faisant saillie de la face intérieure de la paroi 7 de l'embout E. Ce pointeau est susceptible de s'engager à coulissement étanche dans la partie haute du conduit 30 du piston. Quatre orifices d'éjection e sont agencés autour de ce pointeau. L'étanchéité de la fermeture du clapet obturateur est ici principalement obtenue par l'engagement à coulissement doux du pointeau 4 dans la partie haute du conduit 30. Cependant, comme les orifices sont ici ménagés au travers de la paroi supérieure de l'embout E, en regard de l'épaulement 31 a de la collerette 31, on dispose d'une paroi obturante complémentaire. Le fonctionnement du mode de réalisation décrit aux figures 1 à 3 est le suivant :In the embodiment of Figures 1 to 3 , the shutter valve 5 is constituted by a shutter element in the form of a needle 4, projecting from the inner face of the wall 7 of the nozzle E. This needle is able to engage with a watertight sliding in the upper part of the conduit 30 of the piston. Four ejection orifices e are arranged around this needle. The sealing of the closing of the shut-off valve is here mainly obtained by the gentle sliding engagement of the needle 4 in the upper part of the conduit 30. However, as the orifices are here formed through the upper wall of the nozzle E , opposite the shoulder 31a of the collar 31, there is a complementary sealing wall. The operation of the embodiment described in Figures 1 to 3 is the next :

A la montée de l'embout E à partir de la position représentée sur la figure 2A, le piston est entraîné vers le haut par friction en restant bloqué dans l'embout E, ce qui provoque l'ouverture du clapet d'admission et le remplissage du compartiment inférieur (fig. 2B) jusqu'à ce que le jonc 31 c du piston arrive en butée contre le rebord 1a du corps de pompe. La poursuite du dévissage sépare l'embout du piston en libérant le compartiment supérieur 10b qui se remplit à son tour. Ce déplacement s'accompagne du dégagement des orifices d'éjection e et prépare le système pour la distribution du produit (fig. 2C).When the end piece E is raised from the position shown on the Figure 2A , the piston is driven upwards by friction while remaining locked in the nozzle E, which causes the opening of the intake valve and the filling of the lower compartment ( Fig. 2B ) until the rod 31 c of the piston abuts against the flange 1a of the pump body. Continued unscrewing separates the tip of the piston by releasing the upper compartment 10b which fills in turn. This displacement is accompanied by the clearance of the ejection orifices e and prepares the system for the distribution of the product ( Fig. 2C ).

A la descente, l'embout se déplace en entraînant d'abord le piston 3 retenu par serrage radial, les orifices d'éjection étant ouverts et le clapet d'admission 2 fermé. La compression du produit dans le compartiment inférieur 10a assure son éjection. Lorsque le piston arrive en butée contre le corps de pompe, la fermeture du clapet d'admission 2 est confirmée et l'embout E poursuit sa descente en comprimant le produit dans le compartiment supérieur 10b (fig. 2D) jusqu'à ce que les orifices d'éjection e soient obturés de l'intérieur.On descent, the tip moves by first driving the piston 3 retained by radial clamping, the ejection ports being open and the inlet valve 2 closed. The compression of the product in the lower compartment 10a ensures its ejection. When the piston comes into abutment against the pump body, the closing of the intake valve 2 is confirmed and the nozzle E continues its descent by compressing the product in the upper compartment 10b ( Fig. 2D ) until the ejection ports e are closed from the inside.

En fin de course, des moyens de blocage 46 fonctionnant par effet de clipsage, stabilisent la position de l'embout E par rapport au réservoir R. Ces moyens de blocage sont ici constitués d'un jonc annulaire 47 prévu à l'extérieur de la douille d et d'une gorge annulaire correspondante 48 ménagée à la base de la paroi intérieure de l'embout E. Ces moyens de blocage confirment et renforcent la fermeture du clapet d'admission 2 et celle du clapet obturateur 5.At the end of the stroke, blocking means 46 operating by clipping effect, stabilize the position of the nozzle E relative to the reservoir R. These locking means here consist of an annular ring 47 provided on the outside of the socket d and a corresponding annular groove 48 formed at the base of the inner wall of the nozzle E. These locking means confirm and reinforce the closure of the inlet valve 2 and that of the shutter valve 5.

Dans le mode de réalisation des figures 4, 5A et 5B, les parties analogues à celles du mode de réalisation des figures 1 à 3 portent les mêmes références alphanumériques. L'élément d'obturation est porté par le piston 3 et est susceptible de s'engager à coulissement étanche dans un orifice d'éjection e', unique, de l'embout E. Il comprend un ergot 32 solidaire de la collerette 31 et s'étendant coaxialement au conduit 30.In the embodiment of Figures 4, 5A and 5B , parts similar to those of the embodiment of the Figures 1 to 3 bear the same alphanumeric references. The shutter member is carried by the piston 3 and is able to engage in leaktight sliding in a ejection orifice e ', unique, the endpiece E. It comprises a lug 32 integral with the collar 31 and extending coaxially with the conduit 30.

L'orifice d'éjection e', unique, est réalisé au travers de la paroi supérieure de l'embout E dans l'axe du conduit 30 mais avec ici un diamètre supérieur à celui des orifices e du mode de réalisation précédemment décrit. L'orifice e' est de section cylindroconique tandis que l'ergot 32 est cylindrique.The single ejection orifice e 'is made through the upper wall of the nozzle E in the axis of the duct 30 but here with a diameter greater than that of the orifices e of the embodiment described above. The orifice e 'is of cylindroconic section while the lug 32 is cylindrical.

Le conduit central 30 débouche ici dans le compartiment supérieur 10b de la chambre de dosage, par des lumières 34 ménagées dans l'épaulement 31 a, définies entre des pontets de liaison, autour de l'ergot 32.The central duct 30 opens here into the upper compartment 10b of the metering chamber, through openings 34 formed in the shoulder 31a, defined between connecting bridges around the pin 32.

Dans ce second mode de réalisation, le corps de pompe 1 est pourvu, en partie haute, d'une gorge périphérique 13 dans laquelle coulisse une lèvre d'étanchéité annulaire 33 raccordée au piston 3. Elle est portée par la face inférieure de l'épaulement 31 a de la collerette 31. Un orifice d'évent 14 est pratiqué entre la paroi latérale supérieure du corps et la gorge 13. Cet orifice est associé à une rainure 15 du fait que la partie haute du corps 1 est emmanchée avec un léger serrage radial dans la douille d. L'air peut s'écouler entre la douille d et l'embout E (voir fig. 5B).In this second embodiment, the pump body 1 is provided, in the upper part, with a peripheral groove 13 in which slides an annular sealing lip 33 connected to the piston 3. It is carried by the lower face of the shoulder 31 has flange 31. A vent orifice 14 is made between the upper side wall of the body and the groove 13. This orifice is associated with a groove 15 because the upper part of the body 1 is fitted with a slight radial clamping in the socket d. Air can flow between bushing d and ferrule E (see Fig. 5B ).

La paroi latérale de la lèvre 33 présente un rétreint 35 sur sa face radialement extérieure et s'étendant sur une hauteur h. Ce rétreint délimite un passage pour la reprise d'air, dans le réservoir R, via l'orifice 14, en position haute de la collerette 31.The side wall of the lip 33 has a narrowing 35 on its radially outer face and extending over a height h. This constriction defines a passage for the return of air, in the tank R, via the orifice 14, in the high position of the flange 31.

La paroi interne du réservoir R et plus précisément du flacon F comporte un jeu d'ailettes d'arrêt flexibles a coopérant avec des ailettes complémentaires a' portées par la partie inférieure de la paroi latérale externe de l'embout E.The inner wall of the reservoir R, and more precisely of the bottle F comprises a flexible stop fins game cooperating with complementary ribs a 'carried by the lower part of the outer side wall of the nozzle E.

La souplesse des ailettes a, a' permet l'introduction du bord inférieur de l'embout E dans l'espace intercalaire situé entre le flacon F et la douille d.The flexibility of the fins a ' allows the introduction of the lower edge of the nozzle E in the spacer between the bottle F and the sleeve d.

Lorsque l'embout E arrive en position haute, les ailettes a' de l'embout viennent se caler en butée contre les ailettes a du flacon et interdisent toute séparation.When the nozzle E arrives in the high position, the fins a 'of the tip are wedged in abutment against the fins a bottle and prohibit any separation.

Ce mode de réalisation permet un conditionnement aisé du produit dans le réservoir R, en remplissant la douille d à l'envers avec l'embout E en position de fermeture. Le flacon F est ensuite monté à la manière d'un bouchon sur la douille d pour former le fond du réservoir avant que le distributeur ne soit retourné.This embodiment allows easy packaging of the product in the tank R, filling the sleeve d upside down with the tip E in the closed position. The bottle F is then mounted in the manner of a plug on the socket d to form the bottom of the tank before the dispenser is returned.

Le mode de fonctionnement du distributeur selon ce second mode de réalisation est décrit ci-après.The mode of operation of the dispenser according to this second embodiment is described below.

Dans la position représentée sur la figures 5A, l'extrémité du piston vient, par le bord inférieur du conduit 30, en appui vers le bas contre la bille 21 pour verrouiller le clapet d'admission en position de fermeture. Les moyens de blocage 46 confirment ce verrouillage.In the position shown on the Figures 5A , the end of the piston comes, by the lower edge of the conduit 30, bearing downwards against the ball 21 to lock the inlet valve in the closed position. The blocking means 46 confirm this lock.

Dans cette position, le volume de la chambre de dosage est minimal du fait que l'embout E est en position basse au contact de l'épaulement 31 a de la collerette 31. Les volumes libres des compartiments 10a et 10b sont pratiquement nuls.In this position, the volume of the metering chamber is minimal because the tip E is in the low position in contact with the shoulder 31a of the flange 31. The free volumes of the compartments 10a and 10b are virtually zero.

L'élément d'obturation 32 est engagé dans l'orifice d'éjection e' (fig. 5A) ce qui garantit une étanchéité complète du distributeur sans contact d'une quelconque fraction du produit avec l'atmosphère.The shutter element 32 is engaged in the ejection orifice e '( Fig. 5A ) which guarantees complete sealing of the dispenser without contact of any fraction of the product with the atmosphere.

Lorsque l'embout E est déplacé à partir de la position précédente, vers le haut, en entraînant avec lui la collerette 31 du piston 3, le clapet d'admission s'ouvre et le compartiment inférieur 10a se remplit de produit. Le mouvement se poursuit jusqu'à ce que le jonc 31 c vienne en butée contre le bord supérieur du corps 1. La poursuite du déplacement de l'embout E entraîne la séparation entre celui-ci et la collerette 31 du piston (fig. 5B) qui reste en butée contre le corps 1. Ceci dégage le conduit central 30 et l'orifice d'éjection e'. On obtient ainsi une ouverture du clapet obturateur.When the tip E is moved from the previous position upwards, by driving with it the flange 31 of the piston 3, the inlet valve opens and the lower compartment 10a fills with product. The movement continues until the rod 31 c abuts against the upper edge of the body 1. The further movement of the tip E causes the separation between the latter and the flange 31 of the piston ( Fig. 5B ) which remains in abutment against the body 1. This releases the central duct 30 and the ejection orifice e '. This gives an opening of the shutter valve.

Ensuite, la poursuite du mouvement de l'embout E s'accompagne du remplissage du compartiment supérieur 10b de la chambre de dosage comme représenté sur la figure 5B, tout en comprimant le produit dans les deux compartiments de la chambre, ce qui assure sa distribution par l'orifice e'.Then, the further movement of the nozzle E is accompanied by the filling of the upper compartment 10b of the metering chamber as shown in FIG. Figure 5B , while compressing the product in the two compartments of the chamber, which ensures its distribution through the orifice e '.

Il est remarquable que dans les deux modes de réalisation décrits ci-dessus, le clapet obturateur est agencé à proximité immédiate du ou des orifices d'éjection (e ou e') ménagés dans la paroi d'extrémité de l'embout E. Ainsi, on évite que du produit soit au contact de l'atmosphère lorsque le distributeur est fermé. On élimine donc le risque de bouchage du dispositif par séchage d'une quantité excessive de produit ainsi que le risque de contamination de ce produit.It is remarkable that in the two embodiments described above, the shutter valve is arranged in the immediate vicinity of the ejection orifices (e or e ') formed in the end wall of the nozzle E. Thus it is avoided that the product is in contact with the atmosphere when the dispenser is closed. This eliminates the risk of clogging the device by drying an excessive amount of product and the risk of contamination of this product.

Claims (13)

  1. A dispenser for a liquid or a gel product, of the type comprising a container (R) supporting a pump casing (1) including, in its lower part, an inlet valve (2) and provided with a piston (3) movable along an axis, defining with said pump casing a discharge chamber communicating with at least one discharge hole defined in a dispensing tip movable axially at the end of said container, characterized in that said piston is frictionally coupled to said dispensing tip which is movable axially in both directions by hand operation with respect to said container, between two predetermined positions, in that said discharge chamber includes on the one hand a lower compartment (10a) defined between said pump casing (1) and said piston (3) and on the other hand an upper compartment (10b) defined between the piston and said tip, both compartments communicating through a conduit (30) arranged through said piston and in that a seal valve (5) is arranged between said piston and said tip for isolating said discharge chamber from said hole.
  2. A dispenser according to claim 1, characterized in that said tip (E) is in the shape of a cap arranged to partially enclose said container, said cap having an upper wall substantially perpendicular to said axis, in which said discharge hole is provided.
  3. A dispenser according to claim 1 or 2, characterized in that said piston (3) has a collar (31) outside the pump casing (1), which sealingly slides inside said tip (E) while compressing the product in the upper compartment (10b).
  4. A dispenser according to claim 2, characterized in that said collar (31) of the piston (3) includes an upper shoulder (31a) extending on its periphery and downwards by a side skirt (31 b), said side skirt sliding inside said tip.
  5. A dispenser according to claim 4, characterized in that the lower edge of said skirt (31 b) is provided with a snap-ring (31 c) co-operating with the upper edge of the pump casing (1) to provide the stoppage of said collar (31) in the upper position.
  6. A dispenser according to one of the preceding claims, characterized in that said lower end of said piston (3) is conformed to lock said inlet valve (2) in a closing position.
  7. A dispenser according to one of claims 3 to 6, characterized in that said discharge hole (e) is arranged through the upper wall of the tip (E), at right angles with said collar (31) of said piston (3).
  8. A dispenser according to one of claims 2 to 6, characterized in that said discharge hole (e') is arranged through the upper wall of the tip (E) in the axis of the central conduit (30) of said piston (3).
  9. A dispenser according to one of claims 2 to 7, characterized in that said seal valve includes a sealing element (4) protruding from the inner face of said upper wall of the tip (E) and likely to engage sealingly with the upper part of the central conduit (30) of the piston.
  10. A dispenser according to claim 8, characterized in that said seal valve includes a sealing element (32) carried by the piston and likely to sealingly engage with the discharge hole (e').
  11. A dispenser according to one of the preceding claims, characterized in that said pump casing (1) is provided, in its upper part, with a peripheral groove (13) in which an annular sealing lip (33) connected outside to said piston (3), slides axially.
  12. A dispenser according to one of the preceding claims, characterized in that said container (R) comprises a flask (F) receiving an inner socket (d) for supporting the pump casing (1) and on which the dispensing tip (E) is mounted movably.
  13. A dispenser according to one of the preceding claims, characterized in that said inner wall of said container (R) includes a set of flexible stop wings (a) co-operating with complementary wings (a') carried by the tip (E).
EP02772484A 2001-08-03 2002-08-02 Liquid or gel product dispenser forming a metering stick Expired - Lifetime EP1412093B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0110445 2001-08-03
FR0110445A FR2828118B1 (en) 2001-08-03 2001-08-03 STICK FOR DISPENSING LIQUID OR GEL PRODUCTS
PCT/FR2002/002796 WO2003013736A1 (en) 2001-08-03 2002-08-02 Liquid or gel product dispenser forming a metering stick

Publications (2)

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EP1412093A1 EP1412093A1 (en) 2004-04-28
EP1412093B1 true EP1412093B1 (en) 2008-02-13

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EP02772484A Expired - Lifetime EP1412093B1 (en) 2001-08-03 2002-08-02 Liquid or gel product dispenser forming a metering stick

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US (1) US6902085B2 (en)
EP (1) EP1412093B1 (en)
JP (1) JP4160900B2 (en)
CN (1) CN1247316C (en)
AT (1) ATE385856T1 (en)
BR (1) BR0211850B1 (en)
CA (1) CA2456074A1 (en)
DE (1) DE60225016T2 (en)
ES (1) ES2301683T3 (en)
FR (1) FR2828118B1 (en)
HK (1) HK1070609A1 (en)
MX (1) MXPA04001017A (en)
WO (1) WO2003013736A1 (en)

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Publication number Priority date Publication date Assignee Title
US20050133539A1 (en) * 2003-12-22 2005-06-23 Valois Sas Fluid dispenser member
FR2884812B1 (en) * 2005-04-22 2010-02-12 Rexam Dispensing Sys DISPENSER OF PASTY OR GEL PRODUCT WHOSE BODY COMPRISES AN OVEN AND AN INTERNAL RESERVOIR
FR2885890B1 (en) * 2005-05-20 2007-07-20 Rexam Dispensing Systems Sas DEVICE FOR DELIVERING AND ADMITTING A LIQUID PRODUCT
GB0915566D0 (en) * 2009-09-07 2009-10-07 Mckay Colin Bone cement mixing apparatus
US20110182652A1 (en) * 2010-01-22 2011-07-28 Hannah Chung Wearable Sanitizing Gel Dispenser, Kit, and Associated Methods
PL2787809T3 (en) * 2011-12-09 2016-09-30 Removal device for a plant protection agent
US8550131B1 (en) 2013-01-02 2013-10-08 Liquid Squeeze, LLC Liquid dispensing device, system and method
FR3043072A1 (en) * 2015-11-02 2017-05-05 Erca DEVICE FOR DELIVERING DOSE QUANTITIES OF LIQUID OR PASTY PRODUCT
CN106742646B (en) * 2015-11-20 2019-04-05 阿蓓亚塑料实业(上海)有限公司 Distributor and container including the distributor
US10588438B2 (en) * 2015-11-25 2020-03-17 King's Flair Marketing Limited Fluid dispenser with reflux mechanism
EP3711801B1 (en) * 2016-07-27 2022-07-06 Aptar Radolfzell GmbH Liquid dispenser, in particular inhaler

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3908870A (en) * 1973-11-15 1975-09-30 Yoshino Kogyosho Co Ltd Manual-type miniature atomizer
US4079865A (en) * 1977-06-30 1978-03-21 John H. Oltman Non-pulsating, non-throttling, vented pumping system for continuously dispensing product
US4410107A (en) * 1981-12-18 1983-10-18 Corsette Douglas Frank Liquid dispensing pump

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WO2003013736A1 (en) 2003-02-20
CA2456074A1 (en) 2003-02-20
CN1538882A (en) 2004-10-20
JP2005505400A (en) 2005-02-24
FR2828118A1 (en) 2003-02-07
ES2301683T3 (en) 2008-07-01
BR0211850B1 (en) 2011-01-11
US6902085B2 (en) 2005-06-07
DE60225016D1 (en) 2008-03-27
EP1412093A1 (en) 2004-04-28
JP4160900B2 (en) 2008-10-08
HK1070609A1 (en) 2005-06-24
CN1247316C (en) 2006-03-29
MXPA04001017A (en) 2005-06-06
FR2828118B1 (en) 2004-08-27
ATE385856T1 (en) 2008-03-15
US20050072810A1 (en) 2005-04-07
DE60225016T2 (en) 2009-04-30
BR0211850A (en) 2004-09-08

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