EP1409559A4 - Ethylen-alkylacrylat-copolymere mit verbesserter wärmebeständigkeit - Google Patents
Ethylen-alkylacrylat-copolymere mit verbesserter wärmebeständigkeitInfo
- Publication number
- EP1409559A4 EP1409559A4 EP02709086A EP02709086A EP1409559A4 EP 1409559 A4 EP1409559 A4 EP 1409559A4 EP 02709086 A EP02709086 A EP 02709086A EP 02709086 A EP02709086 A EP 02709086A EP 1409559 A4 EP1409559 A4 EP 1409559A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- copolymer
- acrylate
- melt
- alkyl
- ethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
Definitions
- the present invention is directed to novel ethylene alkyl acrylate and ethylene alkyl methacrylate copolymers.
- the invention provides copolymers of ethylene and alkyl acrylates or alkyl methacrylates having improved heat resistance, such as higher peak melting temperatures, and processes for producing such copolymers.
- These novel copolymers are particularly suitable for use as hot melt adhesives, or as components of hot melt adhesive formulations.
- Ethylene is copolymerized with comonomers such as alkyl acrylate or alkyl methacrylate esters or vinyl esters, to create polymers with a different set of properties and attributes not obtainable from homopolymers themselves.
- Some attributes like adhesion and low temperature toughness, are significantly improved as the content of comonomer(s) is increased.
- increasing comonomer content invariably leads to lower peak melting temperatures, sometimes significantly lower peak melting temperatures, especially in copolymers containing more than about 5 mol % comonomer.
- ethylene vinyl acetate (EVA) and ethylene methyl acrylate (EMA) grades show a significant decrease in peak melting temperature as comonomer content is increased, as shown in Figure 1 (prior art). These lower peak melting temperatures indicate smaller crystallite sizes that result from shorter runs of uninterrupted, repeating ethylene units in the polymer's backbone. Thus, it is difficult to achieve high melting points with even moderate amounts of comonomer.
- EVA ethylene vinyl acetate
- EMA ethylene methyl acrylate
- Data for commercially available, nominally 28 weight % vinyl acetate (VA) copolymers shows a decrease from about 73°C at 2.3 g/10 min melt index to 63°C at 420 g/10 min melt index, as shown in Figure 2 (prior art).
- the first commercial, continuous process developed to produce ethylene alkyl acrylate and alkyl methacrylate copolymers was a tubular reactor process developed by Union Carbide (see US 2,953,551).
- Tubular reactors are known to be capable of producing ethylene alkyl acrylate and alkyl methacrylate ester copolymers having higher melting temperatures than the same copolymers polymerized i a high pressure autoclave.
- Commercially available ethylene ethyl acrylate copolymers, produced and sold by Union Carbide since the early 1960's, have relatively high peak melting temperatures compared to autoclave polymerized ethylene methyl acrylate copolymers at the same mole percent comonomer.
- the melting points of copolymers obtainable from these technologies are still undesirably low for some applications.
- copolymers of the present invention have peak melting temperatures which exceed substantially those obtained from conventional autoclave polymerization. Even at a higher concentration of n-butyl acrylate comonomer, which should lead to lower peak melting temperatures, the products of the present invention have higher peak melting temperatures than the improved products disclosed in U.S. Patent Nos. 5,543,477 and 5,631,325, and exceed by more than 8°C the upper melt-point temperature limit calculated from the equation given in U.S. Patent No. 5,631,325.
- ethylene alkyl acrylate or alkyl methacrylate ester copolymers characterized by high peak melting temperatures, a high level of comonomer and optionally a high melt index
- Peak melting temperatures for the copolymers of the present invention are at least 5 °C to more than 50 °C higher than the peak melting temperatures of similar copolymers made using conventional high pressure autoclave process technology, and at least 5 °C to as much as 25 °C higher than similar copolymers made using conventional high pressurf; tubular reactors which inject initiator at only one point.
- the present invention provides a copolymer of ethylene and at least 5 mol % of comonomer units derived from an alkyl acrylate or alkyl methacrylate, wherein the copolymer has a melt index of from 1 to 10,000 g/10 min, and a maximum peak melting temperature as defined herein of at least 100 °C.
- the alkyl group of the alkyl acrylate or alkyl methacrylate can be a linear or branched C j to C ]2 group, such as methyl, ethyl, butyl, hexyl and octyl, particularly n-butyl.
- the copolymer shows increased heat resistance as characterized by a temperature required to melt 50 % of the copolymer of at least 80 °C, a temperature required to melt 80 % of the copolymer of at least 100 °C, a temperature required to melt 100 % of the copolymer of at least 110 °C.
- the present invention provides a copolymer of ethylene and at least 5 mol % comonomer, the comonomer including a first comonomer component and a second comonomer component.
- the first comonomer component includes alkyl acrylates, alkyl methacrylates, or mixtures thereof.
- the second comonomer component includes monomers with a reactivity ratio r 2 of 2 or less or of 1.5 or less or of 1.2 or less or of about 1, relative to ethylene. Examples of such monomers include vinyl esters, such as vinyl acetate, vinyl formate or vinyl propionate.
- the copolymer has a melt index of from 1 to 10,000 g/10 min, and a maximum peak melting temperature as defined herein of at least 80 °C.
- the alkyl group of the alkyl acrylate or alkyl methacrylate can be a linear or branched C j to C 12 group, such as methyl, ethyl, butyl, hexyl and octyl, particularly n-butyl. Additional comonomers, such as acrylic acid, methacrylic acid, partial esters of maleic acid, and carbon monoxide can also be included.
- the copolymer shows increased heat* resistance as characterized by a temperature required to melt 50 % of the copolymer of at least 40 °C, a temperature required to melt 80 % of the copolymer of at least 70 °C, and a temperature required to melt 100 % of the copolymer of at least 80 °C.
- the present invention provides a process for copolymerizing ethylene and an alkyl acrylate or ⁇ .'-.cyl methacrylate comonomer, the process including the steps of feeding a mixture of ethylene and at least one alkyl acrylate or alkyl methacrylate into a high pressure tubular reactor under polymerization conditions and in the presence of one or more free radical initiators to form an ethylene alkyl acrylate or alkyl methacrylate copolymer, wherein the free radical initiator is injected into the tubular reactor in at least two reaction zones, preferably, at least three reaction zones, along the length of the tubular reactor.
- monomer and comonomer are provided to the tubular reactor in only a single reaction zone.
- the present invention provides an ethylene alkyl acrylate or alkyl methacrylate copolymer produced by the inventive process.
- Figure 2 shows the peak melting temperature obtained by differential scanning calorimetry (DSC) for commercially available ethylene vinyl acetate (EVA) copolymers, as a function of the copolymer melt index, using DSC Method 1 as defined herein.
- DSC differential scanning calorimetry
- Figure 3 shows the differential scanning calorimetry (DSC) thermograms for a copolymer of the present invention (Example 4) and a comparative non-inventive copolymer (Comparative Example B), using DSC Method 1 as defined herein.
- Figure 4 shows the differential scanning calorimetry (DSC) thermograms for a copolymer of the present invention (Example 1) and a comparative non-inventive copolymer (Comparative Example G), using DSC Method 1 as defined herein.
- Figure 5 shows the differential scanning calorimetry (DSC) thermograms for the copolymer of Example 2 compared to the peak melting temperature of a single- point tubular copolymer of approximately the same comonomer content (Comparative Example H), using DSC Method 2 as deD'ied herein.
- DSC differential scanning calorimetry
- FIG. 6 shows the differential scanning calorimetry (DSC) thermograms for a copolymers of the invention (Examples 3, 7 and 8) and a conventional autoclave copolymer (Comparative Example A), using DSC Method 1 as defined herein. 5.
- DSC differential scanning calorimetry
- the copolymers of the present invention are copolymers of ethylene and at least one comonomer, wherein the comonomer is an alkyl acrylate or alkyl methacrylate ester.
- Suitable comonomers include the acrylic acid and methacrylic acid esters of Cl to C12 linear or branched alcohols, preferably acrylic acid and methacrylic acid esters of Cl to C8 linear or branched alcohols.
- alkyl acrylate or alkyl methacrylate esters suitable for use as comonomers include methyl acrylate, ethyl acrylate, n-butyl acrylate, iso-butyl acrylate, t-butyl acrylate, n-hexyl acrylate, 2-ethylbutyl acrylate, and 2-ethylhexyl acrylate, as well as the acrylic acid esters of neo-isomers of C5 to C12 alcohols.
- a particularly preferred comonomer is n-butyl acrylate.
- the copolymer can contain at least 5 mol %, preferably from 5 mol % to 20 mol %, 5 mol % to 15 mol %, 6 mol % to 14 mol %, or 7 mol % to 12 mol % comonomer derived units.
- the copolymer contains a lower limit of at least 5 mol % or at least 6 mol % or at least 7 mol % comonomer-derived units, and an upper limit of 20 mol % or 14 mol % or 12 mol % comonomer derived units, with ranges from any lower limit to any upper limit being contemplated.
- the alkyl acrylate or methacrylate ester monomers can be used alone or in mixtures. Monomers other than ethylene and the alkyl acrylate or alkyl methacrylate esters can optionally be included. These additional monomers include vinyl esters, such as vinyl acetate, and monomers such as acrylic acid, methacrylic acid, or partial esters of maleic acid, and carbon monoxide. Thus, as used herein the term "copolymer" includes polymers made from two, three or more comonomers.
- the copolymer includes ethylene; an alkyl acrylate or alkyl methacrylate, or mixtures thereof; and a comonomer having a reactivity ratio r relative to ethylene of 2 or less, or 1.5 or less, or 1.2 or less, or about 1.
- exemplary comonomers naving such a reactivity ratio include vinyl esters, such as vinyl acetate, vinyl formate, and vinyl propionate.
- Reactivity ratios r are well known in the art, and are described, for example, in Encyclopedia of Polymer Science and Engineering, Vol. 6, p.401-403 (1986) (John Wiley, New York); and Encyclopedia of Chemical Technology, 4th Ed., Vol. 17, p.
- the ethylene alkyl acrylate or alkyl methacrylate copolymers of the invention can be produced in a high pressure tubular reactor.
- High pressure tubular reactors for producing ethylene alkyl acrylate or alkyl methacrylate ester copolymers are well known; see, e.g., U.S. Patent No. 2,953,551, the disclosure of which is incorporated by reference herein for purposes of U.S. patent practice.
- the present invention is not limited to any specific tubular reactor design, operating pressure or temperature variables, or initiator system, provided that the tubular reactor is capable of injection of initiator into the reaction stream at at least two, preferably at least three, and more preferably at least four locations along the reaction tube.
- tubular ethylene alkyl acrylate or alkyl methacrylate copolymer means a copolymer produced in such a multi-initiator-injection, high pressure tubular reactor.
- the tubular reactor may be an elongated jacketed tube or pipe, usually in sections or blocks, of suitable strength and diameter.
- a typical tubular reactor can have a length to diameter ratio of from about 1000 to 1 to about 60,000 to 1.
- the tubular reactor is typically operated at pressures from about 1000 to 3500 bar, although pressures higher than 3500 bar can be used if desired.
- the temperature maintained in the reactor is variable, and is primarily controlled by and dependent on the specific initiator system employed. Temperatures are usually within the range of about 100 °C to 350 °C, and can vary in the different reaction zones.
- the polymerization reaction is carried out in the presence of free radical initiators.
- free radical initiators include oxygen; peroxide compounds such as hydrogen peroxide, decanoyl peroxide, t-butyl peroxy neodecanoate, t-butyl peroxy pivalate, 3,5,5-trimethyl hexanoyl peroxide, diethyl peroxide, t-butyl peroxy-2-ethyl hexanoate, t-butyl peroxy isobutyrate, benzoyl peroxide, t-butyl peroxy acetate, t-butyl peroxy benzoate, di-t-butyl peroxide, t-amyl peroxy neodecanoate, t-amyl peroxy pivalate, t- amyl peroxy-2-ethyl hexanoate and 1,1,3,3-tetramethyl butyl
- Preferred initiators are organic peroxides. Mixtures of such initiators can also be used, and different initiators and/or different initiator mixtures can be used in the different initiator injections.
- the initiator can be added to the reaction stream in any suitable manner, such as neat, dissolved in a suitable solvent, and/or mixed with the monomer or comonomer feed stream.
- an initiator is injected into the reaction stream at at least two locations, preferably at least three locations, and more preferably at least four locations.
- monomers and comonomers are introduced into the tubular reactor at a single location, so that injection of additional initiator at second, third, fourth, and subsequent locations, is not accompanied by injection of any additional ethylene or comonomer.
- chain transfer agents include non- copolymerizable chain transfer agents, such as: saturated aliphatic aldehydes, such as formaldehyde, acetaldehyde, or propionaldehyde; saturated aliphatic ketones, such as acetone, diethyl ketone and diamyl ketone; saturated aliphatic alcohols, such as methanol, ethanol and propanol; paraffins and cycloparaffins such as pentane, hexane and cyclohexane; aromatic compounds, such as toluene, diethylbenzene and xylene; and other compounds which act as chain terminating agents such as propylene, carbon tetrachloride and chloroform.
- Preferred chain transfer agents are non- copolymerizable, with acetaldehyde being particularly preferred.
- copolymerizable chain transfer agents including propylene, isobutylene, 1-butene, etc.
- polymers made using copolymerizable chain transfer agents will usually have peak melting temperatures less than the maximum attainable for the copolymer composition and reactor conditions used.
- the tubular ethylene alkyl acrylate and alkyl methacrylate copolymers of the invention are characterized by the following properties:
- Total comonomer content from 5 mol % to 20 mol %. These mole percents represent the total moles of comonomer-derived units in the copolymer as a percentage of the total number of moles of monomer-derived and comonomer-derived units in the copolymer. Alternative lower limits of the comonomer-derived unit content can be at least 6%, at least 7%, or at least 8% (mole percents). It is a particular feature of the copolymers of the present invention that relatively large amounts of comonomer can be incorporated in the copolymer, while still maintaining the favorable properties described herein.
- the copolymers of the present invention preferably include at least 2 mol % or at least 3 mol % or at least 4 mol % of the alkyl acrylate or alkyl methacrylate comonomer, and at least 0.5 mol % or at least 1 mol %. or at least 1.5 mol % of the comonomer having a reactivity ratio r 2 relative to ethylene of 2 or less, with the total comonomer content being as described above.
- Alternative preferred lower limits of the melt index can be at least 100 g/10 min, at least 300 g/10 min, at least 600 g/10 min, at least 900 g/10 min, at least 1500 g/10 min, or at least 2000 g/10 min.
- Heat resistance Percent melted at 60 °C.
- the copolymers of the present invention and adhesive formulations using them show increased heat resistance relative to comparable conventional materials. For many applications, heat resistance at 60 °C is required, since the product incorporating the adhesive or a molded or extruded article made from the copolymer might be exposed to temperatures of up to about 60 °C during shipping, storage or in use.
- differential scanning calorimetry can be used to measure the amount of the copolymer melted at 60 °C as an indicator of heat resistance.
- the copolymers of the present invention show a percent melted at 60 °C of less than 40%, preferably less than 30%, and more preferably less than 25%.
- the copolymers of the present invention show a percent melted at 60 °C of less than 70% or less than 60% or less than 50%.
- Heat resistance Temperature at % melted.
- An alternate measure of heat resistance is the temperature required to melt a predetermined percentage of the copolymer, and this temperature can also be measured by DSC.
- the copolymers of the present invention show increased heat resistance over conventional comparable copolymers, as shown in the Examples herein; e , a higher temperature is required to melt a given percentage of the copolymer.
- the temperature required to melt 50% of a sample of the copolymers of the present invention can be at least 80 °C, preferably at least 85 °C, and more preferably at least 90 °C; the temperature required to melt 80% of a sample of the copolymers of the present invention can be at least 100 °C, preferably at least 105 °C; and the temperature required to melt 100% of a sample of the copolymers of the present invention can be at least 110 °C, preferably at least 115 °C, more preferably at least 120 °C.
- the temperature required to melt 50% of a sample of the copolymers of the present invention can be at least 40 °C or at least 50 °C or at least 60 °C; the temperature required to melt 80% of a sample of the copolymers of the present invention can be at least 70 °C or at least 80 °C or at least 85 °C; and the temperature required to melt 100% of a sample of the copolymers of the present invention can be at least 80 °C or at least 90 °C or at least 100 °C.
- Vicat Softening Point Another measure of the higher heat resistance of copolymers of the present invention is shown by the Vicat Softening Point as determined by the modified ASTM procedure described in the Examples section herein using a 200 g load instead of a 1000 g load. Using this measure, in some embodiments copolymers of the present invention can have a Vicat Softening Point of at least 45 °C, preferably at least 50 °C, more preferably at least 55 °C, and still more preferably at least 60 °C.
- copolymers of the present invention can have a Vicat Softening Point of at least 30 °C or at least 35 °C or at least 40 °C.
- Peak Melting Point Peak Melting Point
- Copolymers of the present invention show a higher peak melting point, determined by DSC, relative to conventional copolymers having the same overall composition.
- peak melting point Tm
- maximum peak melting temperature refer to the temperature of the peak having the highest melting temperature, such as, for example, the 111.5 °C peak of Example 2 below. It should be noted in this connection that the maximum peak melting temperature can be located on a peak that appears on the DSC trace to be a higher temperature shoulder on a larger peak, such as, for example, the maximum peak melting temperature of 99.86 °C for Example 8, shown in Figure 6.
- copolymers of the present invention can have a peak melting point of at least 100 °C, preferably at least 105 °C, more preferably at least 110 °C. In some embodiments, the copolymers of the present invention can have a peak melting point at least 25 °C greater, preferably at least 35 °C greater, and more preferably at least 50 °C greater than the peak melting temperature of a uniformly homogeneous copolymer of the same chemical composition, such as those produced in autoclave reactors.
- copolymers of the present invention can have a peak melting point of at least 80 °C or at least 90 °C or at least 95 °C.
- copolymers of the invention are suitable for use as hot melt adhesives, or in the production of molded or extruded articles with improved temperature resistance.
- articles fabricated using these copolymers should be less susceptible to damage when exposed to higher temperatures, and also less susceptible to high frequency fatigue, which generates heat in the article.
- copolymers of the invention may also be useful in hot melt adhesives for applications requiring substantial retention of performance and strength at elevated temperatures.
- melt Viscosity was determined using test method ASTM D3236 (spindle 27) with the following exception; the melt temperature was 190°C.
- Density (g/cm 3 ) was determined using chips cut from plaques compression molded in accordance with ASTM D-1292 Procedure C, aged in accordance with ASTM D-618 Procedure A, and measured according to ASTM D-1505. Comonomer contents were determined using either an FTIR procedure using calibration standards with assigned values measured by proton NMR, or by using proton NMR directly.
- n-butyl acrylate in ethylene n-butyl acrylate copolymers was determined from a proton NMR spectrum with the temperature probe set for 120 °C. Prior to data collection, the sample was prepared by dissolving approximately 30 mg of the sample in about 3 mL of tetrachloroethane-d2 at 130 °C. Moles of n-butyl acrylate were calculated by dividing the integrated area of the region between 3.5 and 4.5 ppm by a factor of two. Moles of ethylene were calculated by subtracting ten times the number of moles of n-butyl acrylate from the integrated area of the region between 0.5 and 3.0 ppm and diving this result by four.
- ethyl acrylate concentration in ethylene ethyl acrylate copolymers was also determined from proton NMR spectra with the temperature probe set for 120 °C. Moles of ethyl acrylate were calculated by dividing the integrated area of the region between 3.5 and 4.5 ppm by a factor of two. Moles of ethylene were calculated by subtracting six times the number of moles of ethyl acrylate from the integrated area of the region between 0.5 and 3.0 ppm and dividing this result by four.
- DSC Differential Scanning Calorimetry
- Procedure A and measured in accordance with ASTM D-1525, Rate B, with the exception that a non-standard 200 g load was used instead of the standard 1000 g load.
- Ethylene n-butyl acrylate copolymers of the present invention were produced in a high pressure tubular reactor similar in design to the tubular reactor disclosed in U.S. Patent No. 4,135,044, but without side-streams feeding the reactor.
- the monomers were of conventional, commercial purity and there were no efforts to increase purity or modify them in any way.
- the n-butyl acrylate monomer was not stripped of oxygen or storage stabilizer.
- the polymerization was initiated using the following mixture of initiators at the indicated amounts by weight: t-amyl peroxy neodecanoate, 39.5%, t-amyl peroxy pivalate, 23.7%, and t-amyl peroxy-2-ethylhexanoate, 36.8%. These were dissolved in a hydrocarbon solvent at 34.3 wt % initiator mixture to 65.1 wt % solvent.
- Reactor throughput was held constant at 18.5 metric tons/hour. Reactor conditions and production results are shown in Table 1 below. Throughout the campaign, no significant reactor or preheater fouling was apparent.
- LPS low pressure separator
- HPS high pressure separator
- the tubular reactor was configured for either 3-point initiator injection or 4-point initiator injection.
- the dashed lines "--" in Table 1 indicate runs in which only 3-point initiation injection was used.
- the total initiator feed to the downstream injection points is given in Table 1 below. Initiator feed to each of the individual downstream injection points was apportioned between all of them to get the indicated peak temperatures.
- Acetaldehyde was used as the chain transfer agent for all these samples.
- the acetaldehyde feed rate that had been calculated from plant experience with autoclave polymerized ethylene n-butyl acrylate was found to be well below the amount actually needed to get the desired melt index. More than double the calculated flow rate was actually needed for Examples 1-5.
- n-butyl acrylate in the Example copolymers was checked during the run for the purpose of process control by the plant Quality Control Laboratory using an FTIR method they had developed and use routinely for autoclave polymerized ethylene n-butyl acrylate copolymer made at the same plant. This method requires appropriate calibration standards to yield correct values.
- the comonomer contents of the Example copolymers were also subsequently determined by proton NMR as described above, and lower values were obtained. Proton NMR is an absolute analytical method that does not require any calibration standards to determine correct values.
- the difference in values determined by the two methods indicates that the more crystalline tubular reactor copolymers of the present invention have infrared absorbance characteristics which are different than the infrared absorbance characteristics of conventional autoclave-produced ethylene n-butyl acrylate copolymers.
- Initiator Feed Rate Sum of 19.4 19.4 19.4 23.4 25.2 All Downstream Injection Points (kg/hr)
- n-butyl acrylate comonomer contains relatively high levels of n-butyl acrylate comonomer, from about 7 mol % to over 10 mol %.
- Melt index ranged from a low of about 364 g/10 min to over an estimated 2500; melt viscosity at 190°C was used in place of melt index for the grades with greater than 330 MI. Melt viscosity ranged from as high as about 48,000 mPa-s to as low as about 2400 mPa-s.
- composition, melt viscosity (or melt index I 2 16 ) and density of the copolymers, labeled as Examples 1-5, are shown in Table 2.
- peaks were assigned based on DSC curves as shown in Figure 5. For example, referring to Figure 5 and Table 4, the DSC trace for Example 2 shows a small peak at 89 °C, and overlapping peaks at about 107 °C and 111 °C. These are the three peaks reported in Table 4.
- Comparative Examples A and B were made using a well back-mixed, high pressure autoclave to form ethylene n-butyl acrylate copolymers of the indicated melt viscosity and comonomer content. Comparative Examples A and B are most closely comparable to Examples 5 and 4 respectively. Comparative Examples C and D are experimental ethylene n-butyl acrylate copolymers produced by ExxonMobil Chemical in a well back-mixed, high pressure autoclave. Comparative Examples E, F and G are commercially available ethylene ethyl acrylate copolymers made by Union Carbide Corporation (a subsidiary of Dow Chemical Company) and denoted DPD- 6169NT, DPD-6182 and DPD-9169 respectively. Comparative Example H is was made in a high pressure tubular reactor as described below in connection with Examples 6-11, except using only single-point injection. Composition, density, and melt viscosity properties of these comparative examples are shown in Table 5.
- Example 6 The procedure above describes preparation of Examples 1-5. Similar procedures and conditions were used to prepare Comparative Example H and Examples 6-11. In Example 6, four-point injection was used. In Examples 7-11, three-point injection was used. In Comparative Example H, only a single-point initiator injection was used. In Examples 6-11, the monomer mixture included ethylene, n-butyl acrylate and vinyl acetate. Reactor throughput for these examples varied from 21.3 to 23.0 metric tons per hour. The process conditions are shown in Table 8.
- the improvements in thermal properties of the copolymers of the present invention are demonstrated by: (1) increases in peak melting temperature; (2) various measures of how much polymer has melted at various points along the DSC trace; and (3) increases in Vicat Softening Point at 200 g load.
- the peak melting temperatures of the copolymers of the present invention, Examples 4 and 5, are 50 °C or more higher than the peak melting temperatures of the corresponding Comparative Examples A & B, as shown in Figure 3.
- the improvement over conventional tubular reactor EEA copolymers can be seen in Figure 4.
- Figure 5 shows the higher peak melting temperature of the copolymer of Example 2 compared to the peak melting temperature of a single-point tubular copolymer of approximately the same comonomer content.
- inventive examples show performance similar to Comparative Examples E, F and G in this comparison, even though the inventive examples contain at least 15%) more to greater than double the concentration of comonomer on a molar basis; this is contrary to expectations, since higher comonomer content should lead to poorer performance in this measurement.
- Similar improvement in heat resistance of the Examples can be seen in the significantly higher temperatures needed to melt 50, 80 and 100%) of the inventive examples compared to the temperatures needed to melt comparable amounts of Comparative Examples A through D.
- the most significant differences in performance between the inventive examples and Comparative Examples E, F and G are the temperatures needed to melt 100% of the samples.
- a third indication of the higher heat resistance of the products of the present invention is seen in the increases in Vicat Softening Point determined using a non- standard 200 g load instead of the 1000 g load specified in ASTM D-1525. (All of the inventive examples, and Comparative Examples A and B, were too soft to be tested using the standard 1000 g load). Examples 4 and 5 had results which were about 20°C higher than the corresponding Comparative Examples A and B. Ethylene n-butyl acrylate vinyl acetate (EnBA V A) copolymers of the present invention (Examples 6 through 11) also have improved heat resistance over Comparative Examples A through D. This is shown by the increases in DSC Melting Peaks and the amount of material melted at various points on the DSC traces.
- Figure 6 shows the increased peak melting temperatures for an EnBA copolymer of the invention (Example 3), EnBAVA copolymers of the invention (Examples 7 and 8) and a conventional autoclave copolymer (Comparative Example A). Increased Vicat Softening Points were also found comparing Examples 6 through 11 with Comparative Examples A and B, even though A and B are higher in viscosity than Examples 6 through 11; it is known in the art that Vicat Softening Points increase significantly with the viscosity of the polymer hence the improvement is even more dramatic. Comparative Examples C and D, which are very much higher in viscosity (well beyond the typical range of the instrument used to measure the viscosities of the Examples), had Vicat Softening Points that were in the range of Examples 1 through 11.
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US26300201P | 2001-01-19 | 2001-01-19 | |
US263002P | 2001-01-19 | ||
PCT/US2002/001471 WO2002057354A2 (en) | 2001-01-19 | 2002-01-18 | Ethylene alkyl acrylate copolymers with improved heat resistance |
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US20040266927A1 (en) * | 2003-06-27 | 2004-12-30 | Prejean George Wyatt | Filled blends of tubular reactor produced ethylene/alkyl acrylate copolymers modified with organic acids |
ATE532805T1 (de) | 2008-03-13 | 2011-11-15 | Dow Global Technologies Llc | Langkettige und verzweigte block- oder vernetzte copolymere aus ethylen in kombination mit einem anderen polymer |
KR101717831B1 (ko) * | 2012-04-13 | 2017-03-17 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 극성 공단량체를 포함하는 폴리에틸렌 중합체의 제조 방법 및 중합체 조성물 |
WO2016077512A2 (en) * | 2014-11-13 | 2016-05-19 | Dow Global Technologies Llc | Lubricant compositions for improved high pressure free-radical polymerizations |
WO2019027525A1 (en) * | 2017-07-31 | 2019-02-07 | Exxonmobil Chemical Patents Inc. | HIGH PRESSURE POLYMERIZATION PROCESS FOR THE PRODUCTION OF ETHYLENE COPOLYMERS |
EP4004065A1 (de) * | 2019-07-31 | 2022-06-01 | Dow Global Technologies LLC | Ethylenbasierte polymerzusammensetzung mit verzweigung |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3217973A1 (de) * | 1982-05-13 | 1983-11-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von copolymerisaten des ethylens mit acrylsaeureestern in einem zweizonenreaktor bei druecken oberhalb 500 bar |
DE3404744A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
US5234986A (en) * | 1992-03-02 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Hot-melt adhesives for PVC with good high temperature utility |
WO2000058093A1 (en) * | 1999-03-30 | 2000-10-05 | Cryovac, Inc. | Oriented cook-in film with good interply adhesion |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4764546A (en) * | 1986-04-25 | 1988-08-16 | Sumitomo Chemical Co., Ltd. | Filler-containing polypropylene resin composition and process for producing the same |
US4988781A (en) * | 1989-02-27 | 1991-01-29 | The Dow Chemical Company | Process for producing homogeneous modified copolymers of ethylene/alpha-olefin carboxylic acids or esters |
US5482977A (en) * | 1995-05-08 | 1996-01-09 | Eastman Chemical Company | Foamable branched polyesters |
US6388026B1 (en) * | 1997-08-05 | 2002-05-14 | S. C. Johnson Commercial Markets, Inc. | Process for the preparation of macromers |
-
2002
- 2002-01-18 WO PCT/US2002/001471 patent/WO2002057354A2/en active Application Filing
- 2002-01-18 CN CNA028051327A patent/CN1551892A/zh active Pending
- 2002-01-18 EP EP02709086A patent/EP1409559A4/de not_active Withdrawn
- 2002-01-18 AU AU2002243591A patent/AU2002243591A1/en not_active Abandoned
- 2002-01-18 KR KR10-2003-7009597A patent/KR20030072600A/ko not_active Application Discontinuation
- 2002-01-18 JP JP2002558422A patent/JP2004527595A/ja active Pending
- 2002-01-18 CA CA002435284A patent/CA2435284A1/en not_active Abandoned
- 2002-01-21 TW TW091100875A patent/TW593358B/zh not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3217973A1 (de) * | 1982-05-13 | 1983-11-17 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von copolymerisaten des ethylens mit acrylsaeureestern in einem zweizonenreaktor bei druecken oberhalb 500 bar |
DE3404744A1 (de) * | 1984-02-10 | 1985-08-14 | Basf Ag, 6700 Ludwigshafen | Copolymerisate des ethylens mit carboxylgruppenhaltigen comonomeren |
US5234986A (en) * | 1992-03-02 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Hot-melt adhesives for PVC with good high temperature utility |
WO2000058093A1 (en) * | 1999-03-30 | 2000-10-05 | Cryovac, Inc. | Oriented cook-in film with good interply adhesion |
Also Published As
Publication number | Publication date |
---|---|
TW593358B (en) | 2004-06-21 |
EP1409559A2 (de) | 2004-04-21 |
WO2002057354A3 (en) | 2004-02-26 |
CA2435284A1 (en) | 2002-07-25 |
KR20030072600A (ko) | 2003-09-15 |
WO2002057354A2 (en) | 2002-07-25 |
JP2004527595A (ja) | 2004-09-09 |
CN1551892A (zh) | 2004-12-01 |
AU2002243591A1 (en) | 2002-07-30 |
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