EP1409152A1 - Method and use of a method for the dry application of barrier and adhesive materiels on webs - Google Patents

Method and use of a method for the dry application of barrier and adhesive materiels on webs

Info

Publication number
EP1409152A1
EP1409152A1 EP01999438A EP01999438A EP1409152A1 EP 1409152 A1 EP1409152 A1 EP 1409152A1 EP 01999438 A EP01999438 A EP 01999438A EP 01999438 A EP01999438 A EP 01999438A EP 1409152 A1 EP1409152 A1 EP 1409152A1
Authority
EP
European Patent Office
Prior art keywords
dry
web
barrier
onto
application
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01999438A
Other languages
German (de)
French (fr)
Other versions
EP1409152B1 (en
Inventor
Juha Maijala
Timo R. Nyberg
Veli KÄSMÄ
Kaisa Putkisto
Petri Peiponen
Toivo Kärnä
Kerstin Meinander
Mikael Skrifvars
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valmet Technologies Oy
Original Assignee
Metso Paper Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Metso Paper Oy filed Critical Metso Paper Oy
Publication of EP1409152A1 publication Critical patent/EP1409152A1/en
Application granted granted Critical
Publication of EP1409152B1 publication Critical patent/EP1409152B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
    • B05D1/04—Processes for applying liquids or other fluent materials performed by spraying involving the use of an electrostatic field
    • B05D1/06—Applying particulate materials
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
    • D21H23/22—Addition to the formed paper
    • D21H23/50—Spraying or projecting
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
    • D21H19/24—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape

Definitions

  • the present invention relates to dry polymeric materials, especially to dry materials useful as barrier or adhesive materials in dry-application onto a surface, such as polymer film, aluminium foil or the like and especially onto a moving web.
  • the invention particularly relates to dry-application of barrier polymers and/or lamination adherents onto a web.
  • Barrier polymers are widely used in packaging materials to avoid or decrease the penetration of water vapour, fat, odours, microbes, etc. through packages. As very few materials stop the penetration of all these media, multilayer structures are often needed.
  • the manufacture of barrier layers is usually performed by extrusion of thermoplastic materials, such as variations of polyethylene and polypropylene, but also by dispersion coating.
  • the required polymers are molten and applied onto the web through a slit as a thin film.
  • the hot film adheres to the web mechanically, or in some cases, by means of an adherent material earlier applied to the web.
  • One major disadvantage of this method is that the polymer material has to be heated until it is completely molten and then it is forced through the slit. Both the heat and the mechanical force (shear stress) lead to the breakdown of the polymer structure, causing decrease in mechanical properties, and sometimes decomposition.
  • solvents or other liquid media are used, which require drying steps and consume energy.
  • An object of the invention is a method for the dry-application of barrier and/or adhesive material(s) onto a surface or a web.
  • a further object of the invention is a method for the manufacture of materials, especially packaging materials and laminates, comprising one or several layers of barrier polymers.
  • a further object of the invention is the use of a dry-application method based on ionic blasting for the application of barrier and/or adhesive material(s) onto a surface or a web.
  • paper, board, polymer film, metal foil or other surface or web optionally a moving web may be coated by using a dry-application method with barrier and/or adhesive materials applicable in dry form.
  • small particles are applied onto a web or a surface without contacting it, by means of ionic blasting provided by high voltage, wherein the particles are charged by the ions formed by corona discharge. Thereafter, an electric field transfers the charged particles onto the web or the surface.
  • Suitable barrier and adhesive materials are polymeric materials, such as polyethylene, polypropylene, ethyl vinylacetate, polyvinyl alcohols, polyamides, ionomeres, copolymers of vinylidene chloride and methyl acrylate and the like, which are frequently used in extrusion applications, and thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers.
  • polystyrene polystyrene
  • polyacrylate polymethacrylate
  • poly(styrene-acrylate)copolymers plastic pigments based on melamin-formaldehyde and urea-formaldehyde or combinations thereof. If the polymeric materials are supplied as aqueous dispersions they must be dried before the dry-application. This procedure is described in patent applications FI-991438 and FI-991742.
  • the essential features of the polymers in the dry-application method are particle size, glass transition temperature (T g ) and electrostatic properties.
  • the typical diameter size of the particles, or particle agglomerates is between 0.01 and 500 ⁇ m, preferable between 1 and 50 ⁇ m.
  • the glass transition temperature (T g ) is preferably more than 40°, depending on the surface or web material used and on characteristics of the polymer.
  • the polymer shall either be grindable or dryable and often a grinder is used in connection with application.
  • the barrier and/or adhesive material i.e. the polymer powder is applied onto the web or the surface, which can optionally be a moving web, by using the dry- application method based on ionic blasting.
  • the web or surface is selected from paper, board, polymeric film, metal foils such as aluminium foil, or the like. If the applied layer is to be the surface of a product and it is intended to be left uncovered, the powder layer may be covered with a film (polyethylene terephthalate or other non-sticking material) to avoid potential sticking of the polymer material to the surface of the calender rolls during fixing.
  • the fixing is performed at temperatures suitable for the powder material, depending on nip pressure and calender speed.
  • the method according to the invention has several advantages over the state of the art.
  • the degrading effect of thermo-mechanical treatment on the polymeric material is decreased.
  • Such materials are for example thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers.
  • the dry-application methods allows the introduction of the adhesive layer in the lamination process without solvents or other liquid media, thus avoiding drying steps and saving energy.
  • the dry-application method allows one or more layers of one or different polymers to be applied before fixation. Also the thickness of the applied dry layer can be varied starting from very thin ( ⁇ 1 g/m 2 ) layers.
  • the fixing parameters such as characteristics of the powder material, temperature, nip pressure and calender speed will define the upper limit for each product.
  • PET-film (17.0 g/m 2 ) and aluminium foil, but depending on the intended use any kind of web material can be used.
  • the dry-application barrier and/or adhesive materials where chosen among materials used in paper coating and lamination, especially in extrusion applications. These materials are usually provided in the form of pellets with a diameter of 1-2 mm, and the material must thus be grounded to a powder before application.
  • the tests were made with powders produced with a laboratory grinder. To avoid sticking the pellets were fed into the grinder together with dry ice. This grinder had a 0.25 mm screen, resulting in that the biggest fraction of the polymer powder was 0.25 mm.
  • the powders were applicated to the webs by a laboratory dry coating device. The feeding was kept constant in all trials (24 g/m 2 ).
  • the produced structures were tested for grammage, thickness and pinholes. For some samples the water vapour transmission rate (WVTR) was measured, too. Additionally the lamination structures were tested for delamination. For all materials the applicability of the material upon the web and the appearance of the produced structure were visually assessed.
  • WVTR water vapour transmission rate
  • Polyethylene powder with a particle size (diameter) below 0.25 mm was applied onto a paper web by using dry-application technique.
  • the application of the polyethylene powder onto the paper was satisfying, however the coating amount varied much, from 12.1 to 26.0 g/m2, the average being 18.2 g/m 2 .
  • the thickness varied between 19.6 and 25.1 ⁇ m, average 22.6 ⁇ m.
  • Table 2 The results are presented in Table 2.
  • the water vapour transmission rate was best (lowest) for samples prepared at 190°C, approximately 145 g/m 2 /day. Table 1. Grammage and thickness of raw materials
  • Saran MA 119 a copolymer of vinylidene chloride and methyl acrylate, was applied onto a paper web by using dry-application technique. The application of
  • Saran was good and quite uniform as can be seen from Table 2. Due to the higher melting temperature of Saran a calender temperature of 190 °C was used at all three nip pressures. Adhesion to both paper and PET film was good, but there was no adhesion of Saran to aluminium foil. There were only a few pinholes in the paper/PET-laminate, at nip pressures 100 and 150 bar about 25 holes/m 2 , but at low nip pressure (50 bar) no pinholes could be found. The PET film itself showed no pinholes. The water vapour transmission rate was 1.4 - 4.7 g/m 2 /day, decreasing with higher nip pressure.
  • Example 3 Example 3:
  • the polylactide sample was a non-commercial sample of poly(L-lactide) with a molecular weight of about 90 000 g/mole.
  • the material was applied to the paper web using the dry-application technique. Uneven ground powder polylactide led to an uneven application result. The adhesion to paper and PET film was, however, good.
  • Superchlon HE-505 a chlorinated polyethylene, was applied onto a paper web by using dry-application technique. The application of Superchlon was good and uniform. The material has a higher melting point than the other polymers used, and needed a calander temperature of at least 210 °C for melting. All three nip pressures were tried. The adhesion to both paper and PET film was good.

Landscapes

  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Wrappers (AREA)

Abstract

The invention relates to dry polymeric materials, especially to dry materials useful as barrier or adhesive materials in dry-application onto a surface, such as polymer film, aluminium foil or the like and especially onto a moving web. The invention particularly relates to dry-application of barrier polymers and/or lamination adherents onto a web. In the method for the dry-application of barrier and/or adhesive materials onto webs or surfaces powdery polymeric material with particle or particle agglomerate size between 0.01 and 500 mu m, preferable between 1 and 50 mu m is dry-applied by ionic blasting onto a web or a surface, which is selected from paper, board, polymer film, metal foil, and which is optionally a moving web.

Description

Method and use of a method for the dry application of barrier and adhesive materiels on webs
The present invention relates to dry polymeric materials, especially to dry materials useful as barrier or adhesive materials in dry-application onto a surface, such as polymer film, aluminium foil or the like and especially onto a moving web. The invention particularly relates to dry-application of barrier polymers and/or lamination adherents onto a web.
Barrier polymers are widely used in packaging materials to avoid or decrease the penetration of water vapour, fat, odours, microbes, etc. through packages. As very few materials stop the penetration of all these media, multilayer structures are often needed. The manufacture of barrier layers is usually performed by extrusion of thermoplastic materials, such as variations of polyethylene and polypropylene, but also by dispersion coating. In the extrusion method, the required polymers are molten and applied onto the web through a slit as a thin film. The hot film adheres to the web mechanically, or in some cases, by means of an adherent material earlier applied to the web. One major disadvantage of this method is that the polymer material has to be heated until it is completely molten and then it is forced through the slit. Both the heat and the mechanical force (shear stress) lead to the breakdown of the polymer structure, causing decrease in mechanical properties, and sometimes decomposition. In the dispersion coating method, solvents or other liquid media are used, which require drying steps and consume energy.
Same methods used for the application of barrier polymers onto a web are used for introduction of adherents, needed in lamination, onto webs. In the manufacture of multi-layer laminates, after coating with the adherent the webs are forced together by mechanical means with or without subsequent heating. Based on the above it can be realised that there exists a need for an improved method for the manufacture of materials, especially packaging materials and laminates comprising one or several layers of barrier polymers.
The preparation of dry hollow or solid pigments or pigment granulates composed of several different materials used in paper and board coating has been described in patent application FI-991438. A water dispersion of pigments or a mixture of pigments and other material used for paper coating was spray-dried to a powder with a dry content of 85-100 %.
The use of such a plastic pigment powder, comprising agglomerates with a particle size of 1-500 μm, for dry-application onto paper and board webs, and a method for the dry-application has further been described in patent application FI-991742. In this dry-application method the powder is applied to the web by means of an electrostatic field and then fixed to the web by heat. The prerequisite for this application method is that the powder is dry (dry content 85-100 %) and fine. A narrow particle size distribution contributes to the even result. The particles become electrically charged by corona treatment and/or by interacting with each other during transportation towards the web. The charged particles stick to the web and stay there until fixation. Paper and board with improved quality are obtained by using this method.
An object of the invention is a method for the dry-application of barrier and/or adhesive material(s) onto a surface or a web.
A further object of the invention is a method for the manufacture of materials, especially packaging materials and laminates, comprising one or several layers of barrier polymers. A further object of the invention is the use of a dry-application method based on ionic blasting for the application of barrier and/or adhesive material(s) onto a surface or a web.
The characteristic features of the method for the dry-application of barrier and/or adhesive materials onto surfaces or webs, of the method for the manufacture of materials, especially packaging materials and laminates, comprising one or several layers of barrier polymers, and of the use of a dry-application method based on ionic blasting for the application of barrier and/or adhesive material(s) onto a web or a surface are stated in the claims.
In the present invention it was discovered that paper, board, polymer film, metal foil or other surface or web, optionally a moving web may be coated by using a dry-application method with barrier and/or adhesive materials applicable in dry form.
In the dry-application method small particles are applied onto a web or a surface without contacting it, by means of ionic blasting provided by high voltage, wherein the particles are charged by the ions formed by corona discharge. Thereafter, an electric field transfers the charged particles onto the web or the surface.
Suitable barrier and adhesive materials are polymeric materials, such as polyethylene, polypropylene, ethyl vinylacetate, polyvinyl alcohols, polyamides, ionomeres, copolymers of vinylidene chloride and methyl acrylate and the like, which are frequently used in extrusion applications, and thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers.
Other suitable polymeric materials are polymers based on polystyrene, polyacrylate, polymethacrylate, poly(styrene-acrylate)copolymers, plastic pigments based on melamin-formaldehyde and urea-formaldehyde or combinations thereof. If the polymeric materials are supplied as aqueous dispersions they must be dried before the dry-application. This procedure is described in patent applications FI-991438 and FI-991742.
The essential features of the polymers in the dry-application method are particle size, glass transition temperature (Tg) and electrostatic properties. The typical diameter size of the particles, or particle agglomerates, is between 0.01 and 500 μm, preferable between 1 and 50 μm. In the case the material is supplied in the form of pellets, it must be ground, optionally with dry ice, to a powder with suitable particle size. The glass transition temperature (Tg) is preferably more than 40°, depending on the surface or web material used and on characteristics of the polymer. The polymer shall either be grindable or dryable and often a grinder is used in connection with application.
The barrier and/or adhesive material i.e. the polymer powder is applied onto the web or the surface, which can optionally be a moving web, by using the dry- application method based on ionic blasting. The web or surface is selected from paper, board, polymeric film, metal foils such as aluminium foil, or the like. If the applied layer is to be the surface of a product and it is intended to be left uncovered, the powder layer may be covered with a film (polyethylene terephthalate or other non-sticking material) to avoid potential sticking of the polymer material to the surface of the calender rolls during fixing. The fixing is performed at temperatures suitable for the powder material, depending on nip pressure and calender speed.
The method according to the invention has several advantages over the state of the art. The degrading effect of thermo-mechanical treatment on the polymeric material is decreased. By using the dry-application method it is possible to introduce materials with good barrier properties but which are too sensitive to thermal degradation or in other ways difficult to be utilised by conventional extrusion coating methods. Such materials are for example thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers.
The dry-application methods allows the introduction of the adhesive layer in the lamination process without solvents or other liquid media, thus avoiding drying steps and saving energy.
The dry-application method allows one or more layers of one or different polymers to be applied before fixation. Also the thickness of the applied dry layer can be varied starting from very thin (< 1 g/m2) layers. The fixing parameters, such as characteristics of the powder material, temperature, nip pressure and calender speed will define the upper limit for each product.
The invention is illustrated in more detail in the following examples, which, however, are not intended to limit the scope of the invention.
Examples
The base materials chosen for the experiments where webs of paper (81,4 g/m2),
PET-film (17.0 g/m2) and aluminium foil, but depending on the intended use any kind of web material can be used. The dry-application barrier and/or adhesive materials where chosen among materials used in paper coating and lamination, especially in extrusion applications. These materials are usually provided in the form of pellets with a diameter of 1-2 mm, and the material must thus be grounded to a powder before application. The tests were made with powders produced with a laboratory grinder. To avoid sticking the pellets were fed into the grinder together with dry ice. This grinder had a 0.25 mm screen, resulting in that the biggest fraction of the polymer powder was 0.25 mm. The powders were applicated to the webs by a laboratory dry coating device. The feeding was kept constant in all trials (24 g/m2). In the lamination trials a PET- film was applied upon the powder, and the structure was led through a hot calender nip for fixing. In the barrier trials the PET film was applied to avoid sticking of the polymer material to the surface of the calender rolls during fixing. Afterwards the film was discharged. The calender speed was kept constant in all trials (about 6 rpm, accounting for about 5 m/min web speed). Three temperature ranges were used, 150, 170 and 190 °C, and three nip pressures, 50, 100 and 150 bar, corresponding to 12, 25 and 37 kN/m linear load, respectively.
The produced structures were tested for grammage, thickness and pinholes. For some samples the water vapour transmission rate (WVTR) was measured, too. Additionally the lamination structures were tested for delamination. For all materials the applicability of the material upon the web and the appearance of the produced structure were visually assessed.
Example 1 :
Barrier coating of paper with polyethylene.
Polyethylene powder with a particle size (diameter) below 0.25 mm was applied onto a paper web by using dry-application technique. The application of the polyethylene powder onto the paper was satisfying, however the coating amount varied much, from 12.1 to 26.0 g/m2, the average being 18.2 g/m2. The thickness varied between 19.6 and 25.1 μm, average 22.6 μm. The results are presented in Table 2. The variation in coating thickness was caused by unevenness of the powder, which also caused pinholes. All tested nip temperatures and pressures worked, giving good adhesion to paper, and bad adhesion to PET film or aluminium foil. Delamination was very easy. The water vapour transmission rate was best (lowest) for samples prepared at 190°C, approximately 145 g/m2/day. Table 1. Grammage and thickness of raw materials
Table 2. Grammage and thickness of coatings and laminate layers
Example 2:
Lamination of PET film to paper using Saran MA 119.
Saran MA 119, a copolymer of vinylidene chloride and methyl acrylate, was applied onto a paper web by using dry-application technique. The application of
Saran was good and quite uniform as can be seen from Table 2. Due to the higher melting temperature of Saran a calender temperature of 190 °C was used at all three nip pressures. Adhesion to both paper and PET film was good, but there was no adhesion of Saran to aluminium foil. There were only a few pinholes in the paper/PET-laminate, at nip pressures 100 and 150 bar about 25 holes/m2, but at low nip pressure (50 bar) no pinholes could be found. The PET film itself showed no pinholes. The water vapour transmission rate was 1.4 - 4.7 g/m2/day, decreasing with higher nip pressure. Example 3:
Barrier coating/lamination of paper with polylactide.
The polylactide sample was a non-commercial sample of poly(L-lactide) with a molecular weight of about 90 000 g/mole. The material was applied to the paper web using the dry-application technique. Uneven ground powder polylactide led to an uneven application result. The adhesion to paper and PET film was, however, good.
Example 4:
Lamination of PET film to paper with Superchlon HE-510.
Superchlon HE-505, a chlorinated polyethylene, was applied onto a paper web by using dry-application technique. The application of Superchlon was good and uniform. The material has a higher melting point than the other polymers used, and needed a calander temperature of at least 210 °C for melting. All three nip pressures were tried. The adhesion to both paper and PET film was good.

Claims

Claims
1. A method for the dry-application of barrier and/or adhesive materials onto webs or surfaces, characterised in that powdery polymeric material with particle or particle agglomerate size between 0.01 and 500 μm, preferable between 1 and
50 μm is dry-applied by ionic blasting onto a web or a surface, which is selected from paper, board, polymer film, metal foil, and which is optionally a moving web.
2. A method according to claim 1, characterised in that the polymeric material is selected from the group comprising polyethylene, polypropylene, ethyl vinylacetate, polyvinyl alcohols, polyamides, ionomeres, polystyrene, polyacrylate, polymethacrylate, poly(styrene-acrylate)copolymers, thermoplastic biodegradable polymers such as polylactides, polyglycolides and their copolymers, plastic pigments based on melamin-formaldehyde and urea- formaldehyde or combinations thereof and polyesters.
3. A method for the manufacture of packaging materials or laminates with barrier polymers, characterised in that powdery polymeric material with particle size between 0.01 and 500 μm, preferable between 1 and 50 μm is dry-applied by ionic blasting onto a web or a surface, which is selected from paper, board, polymer film and metal foil and which is optionally a moving web, followed with fixation with a calender.
4. A method for the manufacture of packaging materials or laminates with barrier polymers according to claim 3, characterised in that the polymeric material is selected from the group comprising polyethylene, polypropylene, ethyl vinylacetate, polyvinyl alcohols, polyamides, ionomeres, polystyrene, polyacrylate, polymethacrylate, poly(styrene-acrylate)copolymers, thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers, plastic pigments based on melamin-formaldehyde and urea- formaldehyde or combinations thereof and polyesters.
5. A method for the manufacture of packaging materials or laminates with barrier polymers according to claim 3 or 4, characterised in that more than one layer comprising same or different polymers are applied on the web or the surface before fixation.
6. A method for the manufacture of packaging materials or laminates with barrier polymers according to any one of claims 3 - 5, characterised in that the surface of the applied layer is covered with a film comprising non-sticking material, before fixation.
7. Use of a dry-application method based on ionic blasting for the application of barrier and/or adhesive material(s) onto a web or a surface, characterised in that powdery polymeric material with particle size between 0.01 and 500 μm, preferable between 1 and 50 μm is dry-applied by ionic blasting onto a web or a surface, which is selected from paper, board, polymer film and metal foil, and which is optionally a moving web.
8. Use according to claim 7, characterised in that the polymeric material is selected from the group comprising polyethylene, polypropylene, ethyl vinylacetate, polyvinyl alcohols, polyamides, ionomeres, polystyrene, polyacrylate, polymethacrylate, poly(styrene-acrylate)copolymers, thermoplastic biodegradable polymers, such as polylactides, polyglycolides and their copolymers, plastic pigments based on melamin-formaldehyde and urea- formaldehyde or combinations thereof and polyesters.
9. Use according to claim 7 or 8, characterised in that more than one layer comprising same or different polymers are applied on the web or the surface before fixation.
10. Use according to any one of claims 7 - 9, characterised in that the surface of the applied layer is covered with a film comprising non-sticking material before fixation.
EP01999438A 2000-12-07 2001-12-05 Method and use of a method for the dry application of barrier and adhesive materiels on webs Expired - Lifetime EP1409152B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI20002678 2000-12-07
FI20002678A FI20002678A0 (en) 2000-12-07 2000-12-07 Method for dry application of barrier and adhesive materials to webs
PCT/FI2001/001059 WO2002045869A1 (en) 2000-12-07 2001-12-05 Method and use of a method for the dry application of barrier and adhesive materiels on webs

Publications (2)

Publication Number Publication Date
EP1409152A1 true EP1409152A1 (en) 2004-04-21
EP1409152B1 EP1409152B1 (en) 2009-07-29

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EP01999438A Expired - Lifetime EP1409152B1 (en) 2000-12-07 2001-12-05 Method and use of a method for the dry application of barrier and adhesive materiels on webs

Country Status (6)

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EP (1) EP1409152B1 (en)
AT (1) ATE437704T1 (en)
AU (1) AU2002216141A1 (en)
DE (1) DE60139425D1 (en)
FI (1) FI20002678A0 (en)
WO (1) WO2002045869A1 (en)

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Publication number Priority date Publication date Assignee Title
FI121810B (en) 2002-03-14 2011-04-29 Metso Paper Inc Procedure for forming a film
FI121087B (en) * 2002-11-14 2010-06-30 Metso Paper Inc Coating procedure
US20040265504A1 (en) * 2003-06-27 2004-12-30 Christophe Magnin Non-metalic substrate having an electostatically applied activatable powder adhesive
DE102009003473A1 (en) 2009-02-12 2010-09-23 Fsd Folienservice Deutschland Gmbh Laminating process and laminating device
FI131665B1 (en) * 2021-07-21 2025-09-03 Metsae Spring Oy Method of producing a coated fibrous article

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1285551A (en) * 1969-05-28 1972-08-16 British Industrial Plastics Production of foils
US4027366A (en) * 1973-08-02 1977-06-07 Beatrice Foods Co. Multilayer coated substrate
US3919345A (en) * 1974-03-04 1975-11-11 Ford Motor Co Powdered coating composition containing polyanhydride, epoxy and anhydride functional copolymer and flow control agent
US4296142A (en) * 1978-06-26 1981-10-20 Union Carbide Corporation Method for coating a tubular food casing
US5176755A (en) * 1990-02-14 1993-01-05 Armco Inc. Plastic powder coated metal strip
FI19991742L (en) * 1999-06-24 2000-12-24 Neste Chemicals Oy Dry-applied polymer pigment

Non-Patent Citations (1)

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Title
See references of WO0245869A1 *

Also Published As

Publication number Publication date
DE60139425D1 (en) 2009-09-10
EP1409152B1 (en) 2009-07-29
AU2002216141A1 (en) 2002-06-18
ATE437704T1 (en) 2009-08-15
FI20002678A0 (en) 2000-12-07
WO2002045869A1 (en) 2002-06-13

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