EP1390002A1 - Produits de soins capillaires aux huiles naturelles - Google Patents

Produits de soins capillaires aux huiles naturelles

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Publication number
EP1390002A1
EP1390002A1 EP02735374A EP02735374A EP1390002A1 EP 1390002 A1 EP1390002 A1 EP 1390002A1 EP 02735374 A EP02735374 A EP 02735374A EP 02735374 A EP02735374 A EP 02735374A EP 1390002 A1 EP1390002 A1 EP 1390002A1
Authority
EP
European Patent Office
Prior art keywords
hair
hair care
acid
solid
care products
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02735374A
Other languages
German (de)
English (en)
Inventor
Wolf Eisfeld
Peter Busch
Ulrich Issberner
Petra Biehl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Cognis IP Management GmbH
Original Assignee
Cognis Deutschland GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cognis Deutschland GmbH and Co KG filed Critical Cognis Deutschland GmbH and Co KG
Publication of EP1390002A1 publication Critical patent/EP1390002A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • the invention is in the field of cosmetic products and relates to hair care products with semi-solid to solid natural oils and glyceryl dioleate, which can preferably be used for the care of dry or damaged hair and for preventing drying out and against split ends, and for styling hair
  • processes that damage the hair through increased dehydration, such as permanent wave application or styling, should be able to be counteracted.
  • the invention relates to the use of hair care products containing semi-solid to solid natural oils and glyceryl dioleate for styling hair, for preventing hair splitting, increasing hair shine, for maintaining dry hair, for improving combability and for producing a balanced water / moisture balance Hair in different weather conditions.
  • Another object of the invention is the use of glyceryl dioleate as a regreasing component in hair cosmetic preparations.
  • the fats used can also be enriched with sterols, tocopherols and / or carotenoids.
  • hair care products with semi-solid to solid natural oils and glyceryl dioleate have an improved action against hair split and dry hair. They are particularly suitable for styling hair, since the frequently observed problem of scalp and hair drying out can be avoided in the long term after the use of styling agents.
  • the glyceryl dioleate has a moisturizing effect, so that such preparations also prophylactically lead to reduced damage to the hair structure and thus contribute to maintaining the hair structure.
  • glyceryl dioleate protects the hair from further dehydration and against split ends, increases the hair shine and ensures a balanced water / moisture balance in different weather conditions.
  • a significantly improved combability of the hair can be observed.
  • the hair care products described are particularly suitable for the treatment of aged hair, dry hair or for protection from weather conditions which increasingly contribute to drying out the hair.
  • the preparations according to the invention contain 0.1 to 20% by weight, preferably 0.5 to 10% by weight and particularly preferably 1.5 to 6.5% by weight of the natural semi-solid to solid oils.
  • Natural oils are to be understood as oils that are of animal or preferably vegetable origin. These are esters of linear C6-C22 fatty acids with linear C6-C22 fatty alcohols, esters of branched C6-Ci3 carboxylic acids with linear C6-C22 fatty alcohols, such as myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate , Myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetylerucate, stea rylmyristat, cat stearyl,
  • liquid mono- / di-fluoride mixtures based on C ⁇ -Ci ⁇ fatty acids are suitable.
  • Appropriate mixtures of the oils can also be used to maintain the semi-solid to solid consistency
  • the natural oils or oil mixtures present as semi-solid to solid at room temperature have a melting range above 20 ° C., preferably above 25 ° C.
  • Sterols can be present in the oils in amounts of 0.01 to 5% by weight, preferably 0.1 to 3% by weight and in particular 1 to 2% by weight, tocopherols in amounts of 0.01 to 5% by weight, preferably 0.03 to 3% by weight and in particular 0.05 to 2% by weight, unsaturated fatty acids in amounts of 0.1 to 90% by weight, preferably 10 to 80% by weight and particularly preferably 30 to 70% by weight and / or carotenoids in amounts of 0.01 to 2% by weight, preferably 0.03 to 1% by weight and in particular 0.05 to 0.5% by weight.
  • Cegesoft® FR-57 (Hydrogenated vegetable glycerides)
  • Cegesoft® previously Cremeol® SH, Shorea Stenoptera Butter, C18: 1 35%, C18: 2 1%, unsaponifiable matter (triterpenes and sterols) 1.4% (thereof 31.5% triterpenes, 4-desmethylsterols 65.3 % + alpha-
  • Cegesoft® VP Matture of vegetable oil, hydrogenated vegetable oil and candelilla wax
  • Cegesoft® previously Cremeol® PS 6, Vegetable oil, C18: 1 84%, C18: 2 5%, unsaponifiable matter
  • phytosterols e.g. ß-sitosterol, campesterol
  • phytosterols e.g. ß-sitosterol, campesterol
  • Cegesoft® previously Cremeol® PFO, Passionflower (Passiflora Incamata) oil, C18: 1 16%, C18: 2 70%, unsaponifiable matter (phytosterols, e.g. ß-sitosterol, campesterol) ⁇ 1 - max. 2.5% (of which ß-sitosterol
  • Cegesoft® previously Cremeol® GPO
  • golden palm Elaeis Guineensis
  • tocopherols + tocotrienols 1000 ppm
  • Cegesoft® previously Cremeol®
  • Shea butter butyrospermum Parkii
  • the semi-solid to solid oils are present in the preparations according to the invention in combination with glyceryl dioleate Cremeol® FR-36.
  • This component is used as a moisturizer in hair cosmetic preparations, so that it has a nourishing and a protective effect.
  • Glyceryl dioleates are used in the preparations in amounts of 0.1 to 5% by weight, preferably 0.5 to 3 and particularly preferably 1 to 2% by weight. It works from surfactant-free and surfactant-containing formulations and is particularly suitable for dry and older hair.
  • the hair care products contain 0.1 to 20% by weight of semi-solid to solid natural oils and 0.1 to 5% by weight of glycerol dioleate, preparations with 0.5 to 10% by weight of semi-solid to solid natural oils and 0, 5 to 3% by weight of glyceryl dioleate and particularly preferably hair care products containing 1.5 to 6.5% by weight of semi-solid to solid natural oils and 1 to 2% by weight of glyceryl dioleate.
  • the preparations according to the invention are used in the form of hair gels, hair waxes, brilliants, foams, gloss sprays and special washing preparations for hair tips.
  • the preparations can also be used for intensive care of the scalp, for increasing hair shine, volume and improving the feel and moisture balance.
  • the hair care products according to the invention can contain, as additional auxiliaries and additives, surfactants, co-emulsifiers, superfatting agents, pearlescent waxes, consistency agents, polymers, silicone compounds, waxes, stabilizers, anti-dandruff agents, film formers, swelling agents, hydrotropes, preservatives, solubilizers, complexing agents, reducing agents, alkalizing agents, antioxidants Perfume oils and the like included.
  • additional auxiliaries and additives surfactants, co-emulsifiers, superfatting agents, pearlescent waxes, consistency agents, polymers, silicone compounds, waxes, stabilizers, anti-dandruff agents, film formers, swelling agents, hydrotropes, preservatives, solubilizers, complexing agents, reducing agents, alkalizing agents, antioxidants Perfume oils and the like included.
  • esterquats Cationic surfactants in the form of esterquats are often used in hair care products.
  • esterquats is generally understood to mean quaternized fatty acid triethanolamine ester salts. These are known substances which can be obtained by the relevant methods of preparative organic chemistry.
  • R 1 GO for an acyl radical with 6 to 22 carbon atoms
  • R 2 and R 3 independently of one another for hydrogen or R 1 CO
  • R 4 for an alkyl radical with 1 to 4 carbon atoms or a (CH2CH2 ⁇ ) q H group
  • m , n and p in total stand for 0 or numbers from 1 to 12
  • q stands for numbers from 1 to 12
  • X stands for halide, alkyl sulfate or alkyl phosphate.
  • ester quats that can be used in the context of the invention are products based on caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, isostearic acid, stearic acid, oleic acid, elaidic acid, arachic acid, behenic acid and erucic acid and their technical mixtures , as they occur, for example, in the pressure splitting of natural fats and oils.
  • Technical C12 / 18 coconut fatty acids and in particular partially hardened Ci6 / ß ⁇ -tallow or palm fatty acids as well as elaidic acid-rich Ci6 / ⁇ fatty acid cuts are preferably used.
  • the fatty acids and the triethanolamine can be used in a molar ratio of 1.1: 1 to 3: 1 to produce the quaternized esters.
  • an application ratio of 1.2: 1 to 2.2: 1, preferably 1.5: 1 to 1.9: 1 has proven to be particularly advantageous.
  • the preferred ester quats are technical mixtures of mono-, di- and triesters with an average degree of esterification of 1.5 to 1.9 and are derived from technical C16 / 18-tallow or palm fatty acid (iodine number 0 to 40) .
  • quaternized fatty acid triethanolamine ester salts of the formula (I) have proven to be particularly advantageous in which R 1 CO for an acyl radical having 16 to 18 carbon atoms, R 2 for R 1 CO, R 3 for hydrogen, R 4 for a methyl group , m, n and p is 0 and X is methyl sulfate.
  • quaternized ester salts of fatty acids with diethanolalkylamines of the formula (II) are also suitable as ester quats.
  • R 3 in which R 1 CO for an acyl radical with 6 to 22 carbon atoms, R 2 for hydrogen or R 1 CO, R 3 and R 4 independently of one another for alkyl radicals with 1 to 4 carbon atoms, m and n in total for 0 or numbers from 1 to 12 and X represents halide, alkyl sulfate or alkyl phosphate.
  • X represents halide, alkyl sulfate or alkyl phosphate.
  • R 1 CO for an acyl radical with 6 to 22 carbon atoms
  • R 2 for hydrogen or R 1 CO
  • R 3 , R 4 and R 5 independently of one another for alkyl radicals with 1 to 4 carbon atoms
  • X represents halide, alkyl sulfate or alkyl phosphate.
  • the esterquats usually come on the market in the form of 50 to 90% strength by weight alcoholic solutions, which can be diluted with water if required.
  • Esterquats can be present in the hair care products in amounts of 0 to 10% by weight, preferably 1 to 5% by weight and particularly preferably 1.5 to 3% by weight.
  • anionic and / or amphoteric or zwitterionic surfactants are soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerin ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxymeamide sulfate, hydroxymether sulfates ether) sulfates, mono- and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and salts
  • anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
  • Typical examples of amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, amino propionates, aminoglycinates, imidazolinium betaines and sulfobetaines.
  • the surfactants mentioned are exclusively known compounds. With regard to the structure and manufacture of these substances, relevant review articles include, for example, J. Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54-124 or J.
  • surfactants can be added to the hair care products as co-emulsifiers, such as:
  • alkyl mono- and oligoglycosides with 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs
  • polyol and especially polyglycerol esters such as e.g. Polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate or polyglycerol dimer isostearate. Mixtures of compounds from several of these classes of substances are also suitable;
  • partial esters based on linear, branched, unsaturated or saturated C6 / 2 2 fatty acids, ricinoleic acid and 12-hydroxystearic acid and glycerol, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (eg sorbitol), alkyl glucosides (eg methyl glucoside, butyl glucoside, butyl glucoside Lauryl glucoside) and polyglucosides (eg cellulose);
  • adducts of ethylene oxide and / or of propylene oxide with fatty alcohols, fatty acids, alkylphenols, sorbitan mono- and diesters of fatty acids or with castor oil are known, commercially available products. These are mixtures of homologs whose average degree of alkoxylation is the ratio of Amounts of ethylene oxide and / or propylene oxide and substrate with which the addition reaction is carried out corresponds.
  • Ci2 / i8 fatty acid monoesters and diesters of addition products of ethylene oxide with glycerol are known from DE 2024051 PS as refatting agents for cosmetic preparations.
  • C ⁇ / i ⁇ alkyl mono- and oligoglycosides their preparation and their use are known from the prior art. They are produced in particular by reacting glucose or oligosaccharides with primary alcohols with 8 to 18 carbon atoms.
  • glycoside residue both monoglycosides in which a cyclic sugar residue is glycosidically bonded to the fatty alcohol and oligomeric glycosides with a degree of oligomerization of up to about 8 are suitable.
  • the degree of oligomerization is a statistical mean value which is based on a homolog distribution customary for such technical products.
  • Zwitterionic surfactants can also be used as emulsifiers.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one carboxylate and one sulfonate group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the coconut acylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxylm -hydroxyethylimidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate
  • Suitable emulsifiers are ampholytic surfactants.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C ⁇ / i ⁇ alkyl or acyl group, contain at least one free amino group and at least one -COOH or -S ⁇ 3H group in the molecule and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and Ci2 / ⁇ -acylsarcosine.
  • Substances such as lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters and fatty acid alkanolamides can be used as superfatting agents, the latter simultaneously serving as foam stabilizers.
  • Suitable consistency agents are primarily fatty alcohols or hydroxy fatty alcohols with 12 to 22 and preferably 16 to 18 carbon atoms and also fatty acids or hydroxy fatty acids. A combination of these substances with alkyl oligoglucosides and / or fatty acid N-methylglucamides of the same chain length and / or polyglycerol poly-12-hydroxystearates is preferred.
  • Polymeric thickeners such as aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids are also used.
  • aerosil types hydrophilic silicas
  • polysaccharides in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl cellulose, and also higher molecular weight polyethylene glycol mono- and diesters of fatty acids are also used.
  • Polyacrylates eg Carbopole® from Goodrich or Synthalene® from Sigma
  • polyacrylamides polyvinyl alcohol and polyvinylpyrrolidone
  • surfactants such as ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with restricted homolog distribution, and electrolytes like table salt and ammonium chloride.
  • Suitable cationic polymers are, for example, cationic cellulose derivatives, such as, for example, a quaternized hydroxyethyl cellulose, which is available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrfolidone-vinylimidazole polymers, " as ", for example: B.
  • cationic cellulose derivatives such as, for example, a quaternized hydroxyethyl cellulose, which is available under the name Polymer JR 400® from Amerchol, cationic starch, copolymers of diallylammonium salts and acrylamides, quaternized vinylpyrfolidone-vinylimidazole polymers, " as ", for example: B.
  • Luviquat® condensation products of polyglycols and amines, quaternized collagen polypeptides, such as, for example, lauryldimonium hydroxypropyl hydrolyzed collagen (Lamequat®L / Grünau), quaternized wheat polypeptides, polyethyleneimine, cationic silicone polymers, such as, for example, amidomethicones, copolymers and copolymers of adipic acid - Minohydroxypropyldiethylenetriamine- (Cartaretine® / Sandoz), - Copolymers of acrylic acid with dimethyldiallylammonium chloride (Merquat® 550 / Chemviron), polyaminopolyamides, as described for example in FR 2252840 A and their crosslinked water-soluble polymers, cationic chitin derivatives such as quaternized chitosan, optionally microcrystalline distribution, condensation products from dihaloalkylene, such as dibromobutane
  • Anionic, zwitterionic, amphoteric and nonionic polymers include, for example, vinyl acetate / crotonic acid copolymers, vinylpyrrolidone / vinyl acrylate copolymers, vinyl acetate / butyl maleate / isobornyl acrylate copolymers, methyl vinyl ether / maleic anhydride copolymers and their esters, polychloride acrylamides and polychloride acrylamides and polychloride acrylamides and polychloride acrylates and polychloride acrylamides and polychloride acrylates and polychloride amide, polychloride amide and polychloride amide, and nonchlorides, polychloride amide and polychloride acrylate and polychloride amide, polychloride and nonchloric acid amide, polychloride and nonchloride / Acrylate copo
  • Pearlescent waxes are: alkylene glycol esters, especially ethylene glycol distearate; Fatty acid alkanolamides, especially coconut fatty acid diethanolamide; Partial glycerides, especially stearic acid monoglyceride; Esters of polyvalent, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; Fatty substances such as fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, which in total min.
  • Suitable silicone compounds are, for example, dimethylpolysiloxanes, methylphenylpolysiloxanes, cyclic silicones and amino-, fatty acid-, alcohol-, polyether-, epoxy-, fluorine-, glycoside- and / or alkyl-modified silicone compounds, which can be both liquid and resinous at room temperature.
  • Simethicones which are mixtures of dimethicones with an average chain length of 200 to 300 dimethylsiloxane units and hydrogenated silicates, are also suitable.
  • a detailed overview of suitable volatile silicones can also be found by Todd et al in Cosm.Toil. 91. 27 (1976) r
  • waxes may also be present in the preparations, in particular natural waxes, such as Candelilla wax, carnauba wax, japan wax, espresso grass wax, cork wax, guaruma wax, rice-germ oil wax, sugar cane wax, ouricury wax, montan wax, beeswax, shellac wax, walrus, lanolin (wool wax), pretzel fat, ceresin, ozokerite (earth wax), petrolatum wax, paraffin wax; chemically modified waxes (hard waxes), e.g. Montanester waxes, Sasol waxes, hydrogenated jojoba waxes and synthetic waxes, such as Polyalkylene waxes and polyethylene glycol waxes.
  • natural waxes such as Candelilla wax, carnauba wax, japan wax, espresso grass wax, cork wax, guaruma wax, rice-germ oil wax, sugar cane wax, ouricury wax, montan wax, beeswa
  • Metal salts of fatty acids such as e.g. Magnesium, aluminum and / or zinc stearate or ricinoleate are used.
  • Piroctone olamine (1-hydroxy-4-methyl-6- (2,4,4-trimythylpentyl) -2- (IH) -pyridinone monoethanolamine salt), Baypival® (Climbazole), Ketoconazol®, (4-acetyl-1 - ⁇ - 4- [2- (2.4-dichlo ⁇ henyl) r-2- (1 H-imidazol-1-ylmethyl) -1, 3-dioxylan-c-4-ylmethoxyphenyl ⁇ piperazine, ketoconazole, elubiol, selenium disulfide, sulfur colloidal , Sulfur polyethylene glycol sorbitan monooleate, sulfur ricinol polyethoxylate, sulfur tar distillates, salicylic acid (or in combination with hexachlorophene), undexylenic acid monoethanolamide sulfosuccinate sodium salt, Lamepon® UD (protein undecylenic acid pyrithione, magnesium
  • Hydrotropes such as ethanol, isopropyl alcohol, or polyols can also be used to improve the flow behavior.
  • Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
  • the polyols can also contain further functional groups, in particular amino groups, or be modified with nitrogen. Typical examples are • glycerin;
  • Alkylene glycols such as, for example, ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols with an average molecular weight of 100 to 1,000 daltons;
  • Methyl compounds such as, in particular, trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;
  • Lower alkyl glucosides in particular those with 1 to 8 carbons in the alkyl radical, such as methyl and butyl glucoside;
  • Sugar alcohols with 5 to 12 carbon atoms such as sorbitol or mannitol,
  • Aminosugars such as glucamine
  • Dialcohol amines such as diethanolamine or 2-amino-1, 3-propanediol.
  • Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid and the other classes of substances listed in Appendix 6, Parts A and B of the Cosmetics Ordinance.
  • secondary light stabilizers of the antioxidant type can also be used, which interrupt the photochemical reaction chain which is triggered when UV radiation penetrates the skin.
  • Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D, L-carnosine, D-carnosine, L-camosine and their derivatives (e.g. anserine) , Chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g.
  • thiols e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and their glycosyl, N-acetyl, methyl, ethyl, Propyl, amyl, butyl and lauryl, palmitoyl, oleyl, ⁇ -linoleyl, cholesteryl and glyceryl esters
  • salts dilaurylthio dipropionate, distearylthiodipropionate, thiodipropionic acid and their derivatives (esters, ethers, peptides, lipids , Nucleotides, nucleosides and salts) as well as sulfoximine compounds (e.g.
  • buthioninsulfoximine homocysteine sulfoximine, butioninsulfones, penta-, hexa-, heptathioninsulfoximine
  • very low tolerable dosages e.g. pmol to ⁇ mol / kg
  • Chelators e.g. ⁇ -hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin
  • ⁇ -hydroxy acids e.g.
  • citric acid lactic acid, malic acid
  • humic acid bile acid
  • bile extracts bilirubin
  • biliverdin biliverdin
  • EDTA biliverdin
  • EGTA folic acid and its derivatives
  • ubiquinone and ubiquinol and their derivatives Derivatives, vitamin C and derivatives (e.g.
  • vitamin A palmitate Mg ascorbyl phosphate, ascorbyl acetate
  • vitamin A palmitate vitamin A palmitate
  • n nose and its derivatives superoxide dismutase, zinc and its derivatives (eg ZnO, ' ZnS ⁇ 4) selenium and its derivatives (eg selenium methionine), stilbenes and their derivatives (eg stilbene oxide, trans-stilbene oxide) and the derivatives suitable according to the invention (Salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids) of these active ingredients.
  • zinc and its derivatives eg ZnO, ' ZnS ⁇ 4
  • selenium and its derivatives eg selenium methionine
  • stilbenes and their derivatives eg stilbene oxide, trans-stilbene oxide
  • the derivatives suitable according to the invention Salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids
  • EDTA EDTA
  • NTA phosphonic acids
  • Triton B Triton B
  • turpinal and phenacetin can be used as complexing agents.
  • Reducing agents such as ascorbic acid, sodium sulfate, sodium thiosulfate and the like may also be included.
  • Ammonia, monoethanolamine (L) arginine, AMP etc. can be used as the alkalizing agent.
  • Perfume oils include mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers (lily, lavender, rose, jasmine, neroli, ylang-ylang), stems and leaves (geranium, patchouli, petitgrain), fruits (anise, coriander, caraway, juniper), fruit peel (bergamot, lemon, Oranges), roots (mace, angelica, celery, cardamom, costus, iris, calmus), wood (pine, sandal, guaiac, cedar, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), Needles and twigs (spruce, fir, pine, mountain pine), resins and balms (galbanum, elemi, benzoin, myrrh, olibanum, opoponax).
  • Typical synthetic fragrance compounds are products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type. Fragrance compounds of the ester type are, for example, benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethyl acetate, linalyl benzoate, benzyl formate, ethyl methylphenylglycinate, allylcyclohexyl benzylatepylpropionate, allyl cyclohexyl propyl pionate.
  • the ethers include, for example, benzyl ethyl ether
  • the aldehydes include, for example, the linear alkanals with 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilial and bourgeonal
  • the ketones include, for example, the jonones, o-isomethyl ionone and methyl cedryl ketone the alcohols anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol and terpineol
  • the hydrocarbons mainly include the terpenes and balsams.
  • fragrance oils of lower volatility which are mostly used as aroma components, are also suitable as perfume oils, for example sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil , Vetiver oil, oliban oil, galbanum oil, labolanum oil and lavandin oil, preferably bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, ⁇ -hexylcinnamaldehyde, geraniol, benzylacetone, cyclamenaldehyde, linalool, boisambrane forte, amelolbrane forte, amolololene forte, amolololene forte, amolololene forte, amololene, amololene, amololene, amololene, amololene, amololene
  • Cremeol types were melted in Plantacare® 818 UP and dissolved with stirring. All other surfactants were then added and homogenized by stirring. Finally, water and Carbopol® EDT were added and the pH was adjusted to pH 6.0 to 6.8 with slow stirring with NaOH.
  • Table 1 Recipes for hair shampoo (amounts in% by weight)
  • the oil phase with the liquid and solid components including Dehyquart F 75 was melted at 75 - 80 ° C.
  • the water phase likewise heated to 75-80 ° C., was added to the hot oil phase and slowly cooled down to 30 ° C. with stirring.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne des produits de soins capillaires, contenant des huiles naturelles solides à semi-solides et du dioléate de glycéryle, ainsi que leur utilisation pour la coiffure, la prévention contre la formation des fourches et le soin des cheveux secs.
EP02735374A 2001-05-31 2002-05-22 Produits de soins capillaires aux huiles naturelles Withdrawn EP1390002A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10126448 2001-05-31
DE10126448A DE10126448A1 (de) 2001-05-31 2001-05-31 Haarpflegemittel mit natürlichen Ölen
PCT/EP2002/005589 WO2003003991A1 (fr) 2001-05-31 2002-05-22 Produits de soins capillaires aux huiles naturelles

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EP1390002A1 true EP1390002A1 (fr) 2004-02-25

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EP02735374A Withdrawn EP1390002A1 (fr) 2001-05-31 2002-05-22 Produits de soins capillaires aux huiles naturelles

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US (1) US20040146481A1 (fr)
EP (1) EP1390002A1 (fr)
JP (1) JP2004533475A (fr)
AR (1) AR034064A1 (fr)
DE (1) DE10126448A1 (fr)
WO (1) WO2003003991A1 (fr)

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US7521404B2 (en) * 2004-12-16 2009-04-21 Georgia-Pacific Consumer Products Lp Antimicrobial liquid hand soap composition with tactile signal comprising a phospholipid surfactant
US7803746B2 (en) * 2004-12-16 2010-09-28 Georgia-Pacific Consumer Products Lp Antimicrobial foam hand soap comprising inulin or an inulin surfactant
JP2011057624A (ja) * 2009-09-11 2011-03-24 Hoyu Co Ltd 毛髪化粧料組成物
FR2958162B1 (fr) * 2010-03-31 2012-06-15 Fabre Pierre Dermo Cosmetique Utilisation cosmetique d'un extrait de feuilles de magnolia pour ameliorer le pouvoir reflechissant des cheveux.
US11590069B1 (en) 2013-11-04 2023-02-28 Jeffrey Alan Deane Pet cleansing composition
WO2023222410A1 (fr) 2022-05-17 2023-11-23 Basf Se Dispersions de paraffine

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US4515784A (en) * 1983-11-16 1985-05-07 Richardson-Vicks Inc. Reducing sebum spreading
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US5576425A (en) * 1988-10-05 1996-11-19 Henkel Kommanditgesellschaft Auf Aktien Process for the direct production of alkyl glycosides
ATE142478T1 (de) * 1990-06-11 1996-09-15 Kao Corp Haarreinigungsmittel
DE4308794C1 (de) * 1993-03-18 1994-04-21 Henkel Kgaa Verfahren zur Herstellung von festen Esterquats mit verbesserter Wasserdispergierbarkeit
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See also references of WO03003991A1 *

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Publication number Publication date
AR034064A1 (es) 2004-01-21
WO2003003991A1 (fr) 2003-01-16
US20040146481A1 (en) 2004-07-29
DE10126448A1 (de) 2002-12-05
JP2004533475A (ja) 2004-11-04

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