EP1368588A1 - Quick connect coupling - Google Patents
Quick connect couplingInfo
- Publication number
- EP1368588A1 EP1368588A1 EP02717585A EP02717585A EP1368588A1 EP 1368588 A1 EP1368588 A1 EP 1368588A1 EP 02717585 A EP02717585 A EP 02717585A EP 02717585 A EP02717585 A EP 02717585A EP 1368588 A1 EP1368588 A1 EP 1368588A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- hose
- connection portion
- improvement
- fixture
- cylindrical surface
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L19/00—Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
- F16L19/02—Pipe ends provided with collars or flanges, integral with the pipe or not, pressed together by a screwed member
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L19/00—Joints in which sealing surfaces are pressed together by means of a member, e.g. a swivel nut, screwed on or into one of the joint parts
- F16L19/02—Pipe ends provided with collars or flanges, integral with the pipe or not, pressed together by a screwed member
- F16L19/0231—Pipe ends provided with collars or flanges, integral with the pipe or not, pressed together by a screwed member with specially adapted means for positioning the threaded member behind the collar
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16L—PIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
- F16L37/00—Couplings of the quick-acting type
- F16L37/08—Couplings of the quick-acting type in which the connection between abutting or axially overlapping ends is maintained by locking members
- F16L37/084—Couplings of the quick-acting type in which the connection between abutting or axially overlapping ends is maintained by locking members combined with automatic locking
- F16L37/088—Couplings of the quick-acting type in which the connection between abutting or axially overlapping ends is maintained by locking members combined with automatic locking by means of a split elastic ring
Definitions
- This invention relates generally to flexible hose couplings. More particularly, it relates to a novel and improved quick connect hose coupling. Specifically, it relates to an improved high- pressure push-to-connect and threaded disconnect flexible hose coupling.
- a body assembly or fixture portion may be pre-assembled on associated fixtures, machinery or equipment.
- the hose connection portion including a hose stem portion and a ferrule, are attached to an open end of the hose to be connected to the fixture, machinery or equipment.
- the hose stem portion has a hose insert portion, which is inserted into the open end of the hose.
- the ferrule is then compressed about the hose end containing the insert causing all portions to be permanently affixed. Merely pressing the hose connection portion into the body assembly or fixture portion subsequently completes the hose connection.
- Such quick connect couplings are particularly desirable when the hose must be connected in a location which is not readily accessible since it eliminates the need for starting the threads and the danger of cross threading. Further, since the body assembly or fixture portion may be threaded into place as a pre-assembly operation, it is easy to insure that the body assembly or fixture portion receives proper torque. Further, the time of assembly and in turn the assembly costs are reduced.
- the disconnection of quick connect couplings includes the body assembly or fixture portion having a threaded portion that allows the unscrewing of the body assembly or fixture portion from the machine or fixture to which the hose is attached.
- the mentioned threaded portion being between separable portions of the body assembly.
- one part of the body assembly remains with the machine or fixture.
- the other part separates from the first part and remains with the hose connection portion.
- connection is a quick single stroke process
- the disconnection requires a slower unthreading process to provide the opportunity to discover that the fitting is under internal pressure before being completely disconnected. Reconnection is effected, from this point forward, by the inverse of the disconnection process.
- Quick connect couplings provide means to seal between the hose stem portion and the body assembly or fixture portion and to provide a mechanical locking of the hose stem portion in the body assembly or fixture portion.
- such coupling must allow substantial tolerance in axial and lateral misalignment of the hose stem portion in relation to the body assembly portion when the process of connection is first begun. Such tolerance facilitates effective connection even when minimum time or minimum access is available during the connection process.
- the hose stem portion must seat securely upon completion of connection, and should result in a stable and durable connection. If stability is inadequate, movement between the hose stem portion and the body assembly portion leads to excessive wear of the interior of the coupling and premature failure, particularly of the sealing elements.
- the present invention has as an object the provision of a quick connect hose coupling with an improvement in the combination of characteristics including forgiveness in axial and lateral misalignment of the hose stem portion and the body assembly portion during connection and a high degree of stability of stability.
- the present invention is an improved quick connect hose coupling for connecting a hose to a fixture of the type having a hose stem portion including a hose insert portion, having a fixture portion including a fixture connection portion, and having a joinder portion.
- the joinder portion includes a male connection portion and a female connection portion. Each of the male connection portion and the female connection portion are adapted to join in a sealing and locking manner upon being pushed together.
- the coupling further includes threads and wrench mating flats adapted to disconnect the hose from the fixture.
- the male connection portion being a unitary structure having a leading support cylindrical surface, a following support cylindrical surface, and a transition surface intermediate therein between.
- the leading support cylindrical surface has a leading radius.
- the following support cylindrical surface has a following radius. The following radius is larger than the leading radius.
- FIG. 1 is an exploded elevation with one quarter cut-away of a preferred embodiment
- FIG. 2 is an elevation, with one quarter cut-away, of a preferred embodiment
- FIG. 3 is an elevation, of a snap ring, of a preferred embodiment
- FIG. 4 is an exploded' elevation, with one quarter cut-away, of a preferred embodiment
- FIG. 5 is an elevation, with one quarter cut-away, of a preferred embodiment of a body assembly
- FIG. 6 is an exploded elevation, with one quarter cut-away, of a preferred embodiment
- FIG. 7 is an elevation, with one quarter cut away, of a preferred embodiment of a hose stem including a female connection portion
- FIG. 8 is an elevation, with one quarter cut away, of a preferred embodiment of a male connection portion
- FIG. 9 is an elevation, with one quarter cut away, of a preferred embodiment of a male connection portion
- FIG. 10 is an elevation, with one quarter cut away, of a preferred embodiment of a male connection portion.
- one preferred embodiment of this quick connect coupling 1 invention includes body assembly or fixture portion 10 and hose stem 11. They are illustrated in FIG. 1 prior to the insertion of hose stem 11 into body assembly 10.
- the body assembly 10 includes adapter 12 having fixture connection portion 39 formed with central wrenching section 13 and fixture end 14 which has external threads for mounting body assembly 10 onto associated fixtures, machinery or equipment.
- adapter 12 is illustrated 5 as having external threads at fixture end 14, other types of end connections can be utilized. These include internal threads at fixture end 14, or adapter 12 being formed integral to the associated fixture or equipment.
- joinder end 16 of adapter 12 is also externally threaded to receive nut 17. It is contemplated that adapter 12 can include joinder end 16 having internal threads for mating with alternate
- body assembly 10 preferred embodiment of body assembly 10 of the form depicted in FIG. 5. This alternated preferred embodiment of body assembly 10, depicted in FIG. 5, is discussed below.
- nut 17 is threaded onto adapter 12 with proper torque p ⁇ or to installation of body assembly 10 on an associated fixture, machine or equipment.
- Female abutment 41 of adapter 12 abuts male abutment 42 of nut 17 when nut 17 is properly positioned with respect to adapter 12
- Adapter 12 in cooperation with nut 17, provides a female connection portion 37 including a
- TOM tip-of male
- BOM base-of-male
- the rearward end of TOM receiving portion 21 is has a transition matching surface, in this instance conical flaring section 28.
- Nut 17 has an interior annular groove 29 forward spaced from BOM receiving portion 22.
- Groove 29 is preferably formed with a substantially radial forward face 30 and an inclined rearward face 31, which function as discussed below. Positioned within groove 29 of nut 17 is expandable lock ring or snap ring 32 shaped as illustrated in FIG. 3. Nut 17 has wrenching flats 33 so that nut 17 may be threaded onto and off of adapter 12. Joinder end 16, nut 17, and snap
- hose stem 11 includes male connection portion 38 and debris barrier wall 50.
- Male connection portion includes, rearward peripheral depression 48 in which resides second 0-ring seal 46, following support cylindrical surface 54, intermediate peripheral depression 44 for receiving lock ring 32 upon final assembly of coupling 1 , transition surface or camming ramp 43, leading support cylindrical surface 52, forward peripheral depression 40 in which resides 0-ring spacer 27 and first 0-ring seal 26, and annular lead-in surface 56.
- Female connection portion 37 and male connection portion 38, in combination with first O-ring seal 26, 0-ring spacer 27, snap ring 37, and second O-ring seal 46 are joinder portion 20, for this embodiment and for the embodiment of FIG. 6. While the transition surface of this preferred embodiment is a frustoconical camming ramp
- transition surface 43 can also be a step, a concave partial spheroid, a convex partial spheroid, as detailed in FIGS. 8 through 10, or a combination thereof.
- transition matching surface 28 can either remain frustoconical, as depicted, or can be conformed to the shape of the transition surface.
- Such a step form of transition surface 43 and matching surface 28 is less supportive of the allowable misalignment- function of coupling 1 , but can enhance the stability function.
- Support cylindrical surface 54 can be limited to spanning only the distance between rearward peripheral depression 48 and intermediate peripheral depression 44, as depicted, can continue forward beyond intermediate peripheral depression 44 until meeting camming ramp 43, or beyond rearward peripheral depression 48 until meeting debris barrier wall 50, or both. In which cases, intermediate peripheral depression 44 or rearward peripheral depression 48, or both, bisects following support cylindrical surface 54.
- Leading support cylindrical surface 52 can likewise be limited to spanning the distance between camming ramp 43 and forward peripheral depression 40, as depicted, or can continue forward to meet annular lead-in surface 56. In which case, forward peripheral depression 40 bisects leading annular support surface 52.
- Annular lead-in surface 56 can be frustoconical, as depicted or substantially cylindrical with an outer radius smaller than the outer radius of leading support cylindrical surface 52. Outer radius of leading support cylindrical surface 52 is smaller than outer radius of following support cylindrical surface 54.
- the progressively larger radii of the various surfaces, including those that may be frustoconical, provide the guiding function that allows substantial misalignment of hose stem 11 in relation to body assembly 10 in the initial phase of joinder.
- O-ring spacer 27 is provided to increase the pressure to which coupling 1 can be subjected before fluid begins to by-pass O-ring 26 and coupling 1 begins to leak. Construction of O-ring spacer 27 varies depending upon the fluid pressure of the associated application of coupling 1 and is well know in the art.
- Hose stem 11 also includes hose insert portion 34 which extends inwardly from hose stop 35 and is adapted to fit snugly with the connection end of a hose (not depicted). Hose insert portion 34 includes barbs 36 to facilitate increased resistance to separation of hose stem 11 from the associated hose.
- a ferrule (not depicted) is crimped about the end of the hose in which hose insert portion 34 extends and about hose stop 35 to increase the resistance to separation of hose stem 11 from the hose.
- FIG. 2 The assembled position is illustrated in FIG. 2. Initially all items of body assembly 10 are assembled including nut 17 threaded upon adapter 12 with proper torque and lock ring 32 is placed within interior annular groove 29. Hose stem 11 is pressed into body assembly 10. Male connection portion 38 of hose stem 11 extends through BOM receiving portion 22 and into TOM receiving portion 21 of adapter 12 with a close fit. The various proportions are arranged so that O-ring seal 26 has an unstressed outside diameter less than the inside diameter of TOM receiving portion 21 so that the movement of male connection portion 38 to the assembled position of FIG. 2 causes radial compression of O-ring seal 26. In such condition O-ring seal 26 provides a fluid tight joint between the male connection portion 38 and adapter 12.
- camming ramp 43 engages lock ring 32 and radially expands lock ring 32 from its unstressed condition out into the interior groove 29.
- lock ring 32 is urged forward by camming ramp 43 and engages forward radial face 30. Because face 30 is radial, lock ring 32 can expand easily as camming ramp 43 is moved into the assembled position.
- lock ring 32 is formed with an unstressed radius sized so that its outer periphery has a radius greater than the radius of the inner extremities of faces 30 and 31 of groove 29 and its inner periphery has a radius less than the radius of the male connection portion 38 on the two opposite sides of the intermediate peripheral depression 44. Consequently, lock ring 32 is trapped within groove 29 of nut 17 prior to assembly, but snaps into intermediate peripheral depression 44 upon assembly of hose stem 1 1 within the body assembly 10.
- the rearward face 31 insures that lock ring 32 is cammed inwardly into intermediate peripheral depression 44 when hose stem 11 is subjected to forces tending to pull hose stem 1 1 out of body assembly 10.
- Such axial force on hose stem 11 occurs from pressure within the coupling but merely causes lock ring 32 to be cammed inward along rearward face 31 to a position in which the interior of lock ring 32 bottoms out on the inner faces of intermediate peripheral depression 44.
- the maximum radius of camming ramp 43 is selected to be less than the radius of BOM receiving portion 22 by an amount less than the diameter of the wire forming lock ring 32.
- lock ring 32 is formed with a uniform radius throughout the major portion of its length, as illustrated in FIG. 3.
- the depth of the interior groove 29 is proportioned to be at least as great as the diameter of the wire forming lock ring 32.
- body assembly 10 is installed on the associated fixture, machinery or equipment with nut 17 and lock ring 32 each properly in position. Completion of the assembly is accomplished thereafter by merely pressing hose stem 1 1 into body assembly 10 to its assembled position in which it is permanently locked within nut 17 by operation of lock
- Hose stem 11 is preferably provided with debris barrier wall 50 which is aligned with the end of nut 17 when hose stem 11 is in the assembled position.
- debris barrier wall 50 blocks certain debris from entering body assembly 10. The reduction of the entrance of debris is greatly enhanced by the presence of second O-ring seal 46 at rearward peripheral depression 48. Second O-ring seal 46 seals the gap that would otherwise exist at the interface between male connection portion 38 and BOM receiving portion 22 upon joinder of hose stem 11 with body assembly 10.
- FIGS. 1 and 3 can be assembled and disassembled without removal of adapter 12 from the associated fixture, machinery or equipment. However, during the first assembly, hose stem 11 is installed by merely pressing it into adapter 12.
- the conical flaring section 28 performs a dual function. It provides clearance for male connection portion 38. Also, the cooperation of conical flaring section 28 with camming ramp 43 assists in allowing for substantial axial and lateral misalignment at the initial insertion of hose stem ' 11 into body assembly 10 by guiding male connection portion 38 into TOM receiving portion 21 of body assembly 10. Once male connection portion 38 is fully seated within body assembly 10, a close fit occurs between leading support cylindrical surface 52 and TOM receiving portion 21 and between following support cylindrical surface 54 and BOM receiving portion 22. Accordingly, leading support cylindrical surface 52 cooperates with TOM receiving portion 21 and following support cylindrical surface 54 cooperates with BOM receiving portion 22 to provide a high degree of angular stability of hose stem 11 in relation to body assembly 10.
- the high degree of stability reduces the movement at the interface of hose stem 11 and body assembly 10 when torque loads are applied upon hose coupling 1. This reduces wear upon all parts that come into contact with each other and most particularly first and second O-ring seals 26 and 46. O-ring seals tend to be items of relatively short life within hose couplings giving rise to unacceptable leakage.
- FIG. 4 illustrates a second preferred embodiment of this invention in which adapter 12 is provided with an inner annular seal groove 25 intermediate the ends of TOM receiving portion 21 and transition matching surface 28.
- O-ring 26 and O-ring spacer 27 are positioned therein, respectively rearward.
- forward peripheral depression 40 is absent from male connection portion 38.
- This preferred embodiment also lacks rearward peripheral depression 48 and associated second O-ring seal 46. It follows that joinder end 16, nut 17, snap ring 32, O-ring seal 26 and O-ring spacer 27 form part of female connection portion 37. In all other significant respects, this preferred embodiment assembles and disassembles the same as the previously described preferred embodiment.
- FIG. 5 illustrates another preferred embodiment of body assembly 10.
- body assembly 10 has threads at fixture end 14 like the previous embodiment. There is no nut 17. However, lock ring 32 is still inserted into interior annular groove 29. Final assembly is the same using this embodiment of body assembly 10 as for the previous embodiment. ' However, disconnection does not involve separation of nut 17 and hose stem 1 1 from adapter 12. Rather, the entire body assembly 10 is unthreaded from the associated fixture or machine.
- the salient features of all embodiments of body assembly 10 giving rise to improved stability without sacrificing forgivingness during final assembly are present for all preferred embodiments depicted. Reversal of location of first O-ring seal 26 and O-ring spacer, between hose stem 11 and body assembly 10, as occurred in the embodiment depicted in FIG. 4, is also contemplated.
- FIG. 6 depictes a preferred embodiment where female connection portion 37 and male connection portion 38 of joinder portion 20 are reversed as among hose stem 1 1 and adapter 12, in contrast to the preferred embodiment of FIG. 1.
- nut 17 will be normally properly torqued upon hose stem 11 prior to final assembly connecting the hose to the fixture.
- Male connection portion 38 includes forward peripheral depression 40, transition surface 43, intermediate peripheral depression 44 rearward peripheral depression 48 leading support cylindrical surface 52, following support surface 54, and annular lead-in surface 56. In the depressions reside first O-ring seal 26, O-ring spacer 27, and second O-ring seal 46, respectively. In all other significant respects this preferred embodiment assembles and disassembles the same as the preferred embodiment depicted in FIG. 1.
- joinder end 16 can include annular seal groove 25 in exchange for the loss of intermediate peripheral depression 44 from male connection portion 38.
- FIG. 7 depicts hose stem 1 1 having female connection portion 37 instead of male connection portion 38. This configuration is appropriate to use in connection with adapter 12 of the embodiment of FIG. 6.
- Female connection portion 37 can also include annular seal groove 25.
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Quick-Acting Or Multi-Walled Pipe Joints (AREA)
- Mechanical Coupling Of Light Guides (AREA)
- Handcart (AREA)
- Earth Drilling (AREA)
- Joints With Pressure Members (AREA)
- Seal Device For Vehicle (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Dowels (AREA)
- Lubricants (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US27467001P | 2001-03-09 | 2001-03-09 | |
US274670P | 2001-03-09 | ||
PCT/US2002/007044 WO2002073077A1 (en) | 2001-03-09 | 2002-03-08 | Quick connect coupling |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1368588A1 true EP1368588A1 (en) | 2003-12-10 |
EP1368588B1 EP1368588B1 (en) | 2005-08-31 |
Family
ID=23049151
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02717585A Expired - Lifetime EP1368588B1 (en) | 2001-03-09 | 2002-03-08 | Quick connect coupling |
Country Status (17)
Country | Link |
---|---|
US (2) | US7014215B2 (en) |
EP (1) | EP1368588B1 (en) |
JP (1) | JP4043365B2 (en) |
KR (1) | KR100599639B1 (en) |
CN (1) | CN1263974C (en) |
AT (1) | ATE303548T1 (en) |
AU (1) | AU2006201861B2 (en) |
BR (1) | BR0207713B1 (en) |
CA (1) | CA2440286C (en) |
CZ (1) | CZ303242B6 (en) |
DE (1) | DE60205874T2 (en) |
ES (1) | ES2248536T3 (en) |
HK (1) | HK1064429A1 (en) |
MX (1) | MXPA03009166A (en) |
PL (1) | PL202872B1 (en) |
RU (1) | RU2272211C2 (en) |
WO (1) | WO2002073077A1 (en) |
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DE102004026789B4 (en) * | 2004-06-02 | 2008-11-06 | Eaton Fluid Power Gmbh | connecting device |
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US20060243453A1 (en) * | 2005-04-27 | 2006-11-02 | Mckee L M | Tubing connector |
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US9657874B2 (en) * | 2014-04-25 | 2017-05-23 | Kohler Co. | Plumbing fitting adapter |
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CN111373185B (en) * | 2017-11-16 | 2021-11-26 | 康斯博格汽车部件集团股份公司 | Hose connector assembly |
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USD969964S1 (en) | 2020-03-06 | 2022-11-15 | Pentair Residential Filtration, Llc | Filtration system |
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- 2002-03-08 CZ CZ20032320A patent/CZ303242B6/en not_active IP Right Cessation
- 2002-03-08 US US10/094,171 patent/US7014215B2/en not_active Expired - Lifetime
- 2002-03-08 ES ES02717585T patent/ES2248536T3/en not_active Expired - Lifetime
- 2002-03-08 BR BR0207713A patent/BR0207713B1/en not_active IP Right Cessation
- 2002-03-08 JP JP2002572302A patent/JP4043365B2/en not_active Expired - Fee Related
- 2002-03-08 WO PCT/US2002/007044 patent/WO2002073077A1/en active IP Right Grant
- 2002-03-08 RU RU2003129897A patent/RU2272211C2/en active
- 2002-03-08 CA CA 2440286 patent/CA2440286C/en not_active Expired - Lifetime
- 2002-03-08 AT AT02717585T patent/ATE303548T1/en active
- 2002-03-08 CN CNB028062299A patent/CN1263974C/en not_active Expired - Lifetime
- 2002-03-08 EP EP02717585A patent/EP1368588B1/en not_active Expired - Lifetime
- 2002-03-08 KR KR1020037011607A patent/KR100599639B1/en active IP Right Grant
- 2002-03-08 DE DE2002605874 patent/DE60205874T2/en not_active Expired - Lifetime
- 2002-03-08 PL PL367416A patent/PL202872B1/en unknown
- 2002-03-08 MX MXPA03009166A patent/MXPA03009166A/en not_active Application Discontinuation
-
2004
- 2004-09-17 HK HK04107126A patent/HK1064429A1/en not_active IP Right Cessation
-
2006
- 2006-03-16 US US11/377,724 patent/US9039045B2/en not_active Expired - Lifetime
- 2006-05-03 AU AU2006201861A patent/AU2006201861B2/en not_active Expired
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2001044707A1 (en) | 1999-12-15 | 2001-06-21 | Oystertec Plc | Hydraulic connectors |
Also Published As
Publication number | Publication date |
---|---|
EP1368588B1 (en) | 2005-08-31 |
CZ303242B6 (en) | 2012-06-13 |
CZ20032320A3 (en) | 2004-04-14 |
US7014215B2 (en) | 2006-03-21 |
DE60205874T2 (en) | 2006-06-08 |
JP2004537684A (en) | 2004-12-16 |
RU2272211C2 (en) | 2006-03-20 |
US20060175834A1 (en) | 2006-08-10 |
RU2003129897A (en) | 2005-04-10 |
AU2006201861B2 (en) | 2008-09-04 |
AU2006201861A1 (en) | 2006-05-25 |
KR100599639B1 (en) | 2006-07-12 |
BR0207713B1 (en) | 2011-05-31 |
DE60205874D1 (en) | 2005-10-06 |
BR0207713A (en) | 2004-09-08 |
HK1064429A1 (en) | 2005-01-28 |
US9039045B2 (en) | 2015-05-26 |
PL367416A1 (en) | 2005-02-21 |
MXPA03009166A (en) | 2004-02-17 |
US20020140221A1 (en) | 2002-10-03 |
PL202872B1 (en) | 2009-07-31 |
WO2002073077A1 (en) | 2002-09-19 |
ATE303548T1 (en) | 2005-09-15 |
CA2440286C (en) | 2008-05-13 |
JP4043365B2 (en) | 2008-02-06 |
KR20030082957A (en) | 2003-10-23 |
CN1496461A (en) | 2004-05-12 |
ES2248536T3 (en) | 2006-03-16 |
CA2440286A1 (en) | 2002-09-19 |
CN1263974C (en) | 2006-07-12 |
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