EP1366905B1

EP1366905B1 - Method for manufacturing an ink jet head

Info

Publication number: EP1366905B1
Application number: EP03008359A
Authority: EP
Inventors: Norio Ohkuma
Original assignee: Canon Inc
Current assignee: Canon Inc
Priority date: 2002-04-11
Filing date: 2003-04-10
Publication date: 2007-12-12
Anticipated expiration: 2023-04-10
Also published as: EP1366905A1; US6766579B2; DE60317970D1; TW200304874A; CN1241744C; KR20030081127A; CN1449917A; DE60317970T2; US20030198899A1; JP2003300323A; KR100492828B1; TWI236430B

Description

BACKGROUND OF THE INVENTION

Field of the Invention

The present invention relates to an ink jet head for generating fine recording droplets used for the ink jet recording method, and also, relates to the method of manufacture therefore. More particularly, the invention relates to a water-repellent process given to the surface of the head. Related Background Art
For the ink jet head applicable to the ink jet recording method, there have been made various proposals to enhance the performance thereof, such as to obtain a higher image quality at higher speed, among some others. The applicant hereof has made them in Japanese Patent Application Laid-Open No. 04-10940 to Japanese Patent Application Laid Open No. 04-10942 as the ink jet recording method that makes higher image quality possible.
Also, the applicant hereof has proposed in the specification of Japanese Patent Application Laid-Open No. 06-286149 a method for manufacturing an ink jet recording head, which is more preferable to the ink jet recording methods disclosed in the specifications of the aforesaid Japanese Patent Application Laid-Open Nos. 04-10940 to 04-10942 . Further, the applicant hereof has proposed separately the water-repellent composition optimally usable for the ink jet head and the mode of utilization thereof, a method for burying a water-repellent member on the recessed portion formed on the surface of a head, or the like with respect to the water-repellent process of the head surface.
Also, regarding the water-repellent process of the head surface, the applicant hereof has proposed in Japanese Patent Application Laid-Open No. 06-210859 (see also EP-A-0 960 733 ) a method for improving print quality with the provision of water-repellent area and non-water-repellent area for the nozzle surface. In other words, in the specification thereof, it is disclosed that when the entire area of the nozzle surface is made water-repellent, ink mist is integrated to become the ink droplet at the time of continuous printing or the like, which is sucked into the discharge port, and may cause non-discharge to occur. On the other hand, according to such disclosure, if the nozzle surface is partially provided with hydrophilic portion, it becomes possible get ink mist together on the hydrophilic portion and prevent it from forming droplet to be grown.
However, in accordance with the method disclosed in the specifications of aforesaid Japanese Patent Application Laid-Open Nos. 04-10940 to 04-10942, and the optimal method of manufacture disclosed in the specification of the aforesaid Japanese Patent Application Laid-Open No. 06-286149 , the nozzle formation member and the water-repellent member are formed altogether by means of patterning exposure and development process. This formation brings about a mode in which the water-repellent member remains on the nozzle surface under any circumstances. Therefore, it is difficult to improve the print quality with the provision of water-repellent area and non-water-repellent area as disclosed in the aforesaid Japanese Patent Application Laid-Open No. 06-210859 .
Meanwhile, for the improvement of print quality with the provision of the water-repellent area and the non-water-repellent area for the nozzle surface as disclosed in the specification of Japanese Patent Application Laid-Open No. 06-210859 , it is arranged to remove the water-repellent material locally by ablation given by the application of excimer laser after the water-repellent member is formed uniformly on the nozzle surface. As a result, there may occur residues by the ablation, and also, it is difficult to make positioning with the discharge ports precisely, thus leading inevitably to the increased numbers of processing steps among some other disadvantages. Here, therefore, the method still has a room for improvement.

SUMMARY OF THE INVENTION

Here, the present invention is designed with a view to solving the aforesaid problems. It is an object of the invention to provide an ink jet head capable of providing the water-repellent area and non-water-repellent area for the nozzle surface with the formation of the water-repellent portion and hydrophilic portion for the nozzle surface thereof in exact positioning precision without increasing the number of processing steps, thus attempting the enhancement of print quality, and also, to provide the method of manufacture thereof.
In order to solve the problems described above, the present invention provides a method for manufacturing an ink jet head, the structure of which is arranged as given below.
The method for manufacturing an ink jet head is defined in Claim 1.

BRIEF DESCRIPTION OF THE DRAWINGS

Figs. 1A, 1B, and 1C are views that illustrate the forming process of an ink jet head embodying the present invention in accordance with a first embodiment thereof.
Figs. 2A, 2B, and 2C are views that illustrate the forming process of an ink jet head embodying the present invention in accordance with a first embodiment thereof in continuation of those represented in Figs. 1A, 1B and 1C.
Figs. 3A and 3B are views that illustrate the forming process of an ink jet head embodying the present invention in accordance with a first embodiment thereof in continuation of those represented in Figs. 2A, 2B and 2C.
Fig. 4A is a view that shows the mask structure used of the formatting process of the ink jet head in accordance with the first embodiment of the present invention, and Fig. 4B is a view that shows the forming process of the ink jet head in accordance with the second embodiment of the present invention.
Fig. 5 is a view that shows the mask structure used of the forming process of the ink jet head in accordance with the second embodiment of the present invention.
Figs. 6A, 6B, 6C, 6D, and 6E are views that illustrate the forming process of the ink jet head using an anisotropic conduction sheet (ACF) in accordance with a third embodiment of the present invention.
Figs. 7A and 7B are views that illustrate the forming process of the ink jet head using a spacer in accordance with the third embodiment of the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

In accordance with the embodiments of the present invention, it is possible to attempt the enhancement of print quality by means of photolithographical technology and technique with the adoption of the aforesaid structure, because the water-repellent portion and hydrophilic portion can be formed for the nozzle surface of an ink jet head in exact positioning precision without increasing the number of processing steps.
Hereunder, in conjunction with the accompanying drawings, the description will be made of the embodiments of the present invention.
Figs. 1A to 3B are views that schematically illustrate the formation processes of an ink jet head in accordance with one embodiment of the present invention.
Fig. 1A shows the state where the heater material 2, that serves as ink discharge pressure generating element, is arranged on the substrate 1. The heater 2 has electrodes (not shown) connected therewith and give heat when energized, thus enabling ink to be vaporized for discharging fine ink droplet.
Fig. 1B is a cross-sectional view taken along line 1B - 1B in Fig. 1A.
In accordance with the formation processes shown in Figs. 1A to 3B, the description will be made of a method for manufacturing an ink jet head embodying the present Invention.
At first, on the substrate 1, the die-resist 3, which becomes the die for ink flow path, is formed (Fig. 1C). Next, further, on the aforesaid die-resist 3, a first photosensitive resin layer 4 is formed to be a nozzle formation member (Fig. 2A).
Further, on the first photosensitive resin layer 4, there is formed the second photosensitive resin layer 5, which has mainly water-repellency (Fig. 2B).
Next, by means of the usual photolithographic techniques, the first photosensitive resin layer 4 and the second photosensitive resin layer 5 are exposed and developed through masks so as to form the hydrophilic portion 7, which can be formed in any positions on the discharge port 6 and the nozzle surface (Fig. 2C).
Here, in accordance with the present embodiment, the mask pattern is set for the ink discharge port formation member in a size to enable the first photosensitive resin layer 4 and the second photosensitive resin layer 5 to be patterned (so that these layers should not remain after development), and also, the mask patter is set for the hydrophilic portion in a size to enable the second photosensitive resin layer 5 to be patterned, but the first photosensitive resin layer 4 not to be patterned (that is, not to be penetrated at the time of development). On the hydrophilic portion, the second photosensitive resin layer 5, which has water-repellency, is locally lost, and the first photosensitive resin layer 4 is exposed. Therefore, the water-repellency is not developed. This is attainable in such a way that when the patterning exposure is executed, the exposing area of the portion that should be exposed is locally controlled to make the depths of latent images different in order to form the first pattern of latent image (that is, the portion where discharge port is formed), which reaches the bottom portion of the first photosensitive resin layer, and the second pattern of latent image (that is, the hydrophilic portion), which is beyond the second photosensitive resin layer, but does not reach the bottom portion of the first photosensitive resin layer.
Usually, the film thickness of the die-resist 3 is selected in a range of approximately 10 to 40 µm; the film thickness of the first photosensitive resin layer 4, approximately 10 to 40 µm; and the discharge port, approximately ϕ 10 to 30 µm. Consequently, it is needed to set an aspect ration at approximately 1 : 1 to 1 : 4 (the width of the discharge port : the film thickness of the first photosensitive resin layer 4) when the first photosensitive resin layer 4 is patterned.
Also, since the second photosensitive resin layer 5 is used to obtain the surface water-repellency, and the film thickness thereof is usually adjusted to be approximately 0.1 to 3 µm, the aspect ratio (the width of the discharge port : the film thickness of the second photosensitive resin layer 5), it is good enough if it is set at approximately 1 : 1. For the so-called resist performance, it is preferable to make the aspect ratio higher, but in practice, it is extremely difficult to attain an aspect ratio of 1 : 4 or more with the exception of some specially arranged condition (such as X-ray exposure).
Here, if a mask the width pattern of which is sufficiently small against the discharge port diameter for the formation of hydrophilic portion, it is possible to carry out the patterning of the hydrophilic portion. In other words, if a mask pattern of approximately ϕ 1 to 3 µm is used, the patterning can be executed sufficiently in consideration of the aspect ratio, because the film thickness of the second photosensitive resin layer 5 is approximately 0.1 to 3 µm. However, since the film thickness of the first photosensitive resin layer 4 is approximately 10 to 40 µm, the patterning can hardly be executed completely.
In this manner, with the mask designing being made in consideration of the ratio of the film thickness of the first photosensitive resin layer 4 and the second photosensitive resin layer 5, the discharge port can be formed and the hydrophilic portion can be made in any positions on the nozzle surface by means of one-time patterning (exposure and development processes). This indicates that the discharge port position and the relatively positional precision of the hydrophilic portion can be determined univocally, and that there is no need for increasing the processing steps for the formation of the hydrophilic portion.
The aforesaid description is made of one embodiment of the present invention, but the invention is not necessarily limited to such embodiment. For example, in order to pattern only the second photosensitive resin layer, there is the following besides it:
The arrangement is made to change developers used for the first photosensitive resin layer 4 and the second photosensitive resin layer 5 (setting is made so that the developer used for the second photosensitive resin layer 5 does not develop the first photosensitive resin layer 4).
The arrangement is made to change the sensitivities of the first photosensitive resin layer 4 and the second photosensitive resin layer 5 so as to control and set the aspect ratio of both photosensitive layers at an optimal value.
Like these, with the appropriate adoption of techniques, it becomes possible to form the discharge port and the hydrophilic portion more stable at the same time.
In this way, after the discharge port and the hydrophilic portion are formed, the ink supply port is appropriately formed as shown in Fig. 3A. Further, as shown in Fig. 3B, the die-resist 3 is appropriately removed to produce an ink jet head.
Next, the description will be made of the constituents used for the present invention.
At first, for the first photosensitive resin layer, it is preferable to use the negative type resist, because this layer, being a part of nozzle member, should provide a high mechanical strength, ink-resistance property, and close contact capability with the substrate. It is particularly preferable to use cation polymeric substance of epoxy resin.
For the second photosensitive resin layer, it is preferable to use the negative type resist that contains the functional group, such as fluorine from which water-repellency against ink is obtainable, and silicon or the like that has water-repellency.

(Embodiments)

Hereunder, the description will be made of the embodiments in accordance with the present invention.

(First Embodiment)

In accordance with the first embodiment of the invention, an ink jet head is produced through the processing steps shown in Figs. 1A to 3B.
At first, Si wafer is used for the substrate 1, and TaN is used as the heater material.

Then, ODUR manufactured by Tokyo Ohka Kagaku Kogyo K.K. is used as the die-resist for the formation of the ink flow path pattern (in a film thickness of 13 µm (Fig. 1C)). Further, as the first photosensitive resin layer, the composition shown in the Table 1 given below is formed on the ink flow path pattern by means of spin coating (in a film thickness of 12 µm (Fig. 2A)).

Table 1

Item	Product Name	Weight%
Epoxy resin	EHPE (manufactured by Daicel Chemical Industries, LTD.)	100
Added resin	1,4-HFAB (Central Glass K. K.)	20
Silane coupling material	A-187 (Nippon Unika K.K.)	5
Photo-cation Polymer catalyst	SP170 (Asai Denka kogyo K.K.)	2
Solvent	Ethyl Cellsolve	75

Composition shown in the Table 1 is cation polymeric composition having negative type photosensitive property. Further, on the first photosensitive resin layer, the second photosensitive resin layer is formed (Fig. 2B).

The second photosensitive resin layer is composition shown in the Table 2 given below.

Table 2

Item	Structure	Weight%
Fluoric epoxy resin A		35
Fluoric epoxy resin B		60
Photo-cation polymer catalyst	SP170 (Asahi Denka Kokgyo K.K.)	5
Solvent	Methyl isobutyl ketone	200
	Diglyme	200

The second photosensitive resin layer has the sensitive group that contains fluoric atom in the structure thereof, and demonstrates water-repellency, while it becomes negative type photosensitive composition with epoxy group and photo-cation polymer catalyst.
When the second photosensitive resin layer is formed, the first photosensitive resin layer has not reacted as yet. Consequently, there is a need for the provision of a structure that does not produce any adverse effect on the first photosensitive resin layer when a coating solvent or the like is selected. For the present embodiment, the composition shown on the Table 2 is applied onto PET film, which is dried to form a dry film, thus completing the formation (in a film thickness of 0.5 µm) by laminating it, while appropriately giving heat and pressure onto the first photosensitive resin layer.
Then, by use of the mask aligner MPA 600 manufactured by Canon Inc., exposure is given to the first and second photosensitive resin layers thus formed in an exposure amount of 1.0J/ cm² through the mask, which is provided with the patterns of discharge port and hydrophilic portion. The dimension of the discharge port 6 on the mask is φ 22 µm. For the area where the hydrophilic portion is formed, a line 21 of 2 µm is formed (at an interval of 7 µm between each of them) (Fig. 4A). After the exposure, it is heated at 90°C for 4 minutes, and immersed in a developer of methyl isobutyl ketone/xylene = 2/3, and then, rinsed with xylene to form the discharge port portion and the hydrophilic area.
The pattern thus obtained is formed in a dimension of φ 20.2 µm at the discharge port portion, and the first and second photosensitive resin layers are removed. On the other hand, in the hydrophilic area, the line 21 of 2 µm on the mask is formed to be 1.8 µm with a depth of 0.7 µm. In other words, whereas the second photosensitive resin layer is removed, the first photosensitive resin layer is scarcely removed. On the line thus formed, there is no second photosensitive resin layer that has water-repellency, and the first photosensitive resin layer is exposed. In this way, it becomes the hydrophilic portion to ink (Fig. 2C).
Next, an ink supply port is formed on the Si wafer by means of anisotropic etching from the base side thereof (Fig. 3A). Lastly, the die-resist is removed. Then, for the purpose to cure the first and second photosensitive resin layers completely, heat treatment is given at a temperature of 200°C for one hour, thus completing the nozzle (Fig. 3B). For the nozzle obtained in this manner, electrical connections and ink supply means are arranged to make it an ink jet head.
Also, for comparison, an ink jet head of the mode having discharge port formed but not any hydrophilic portion is prepared at the same time.
The ink jet head thus produced is filled with black ink, and the solid printing, which is made by discharging ink from all the discharge ports, is continuously performed on an A-4 sized recording sheet in order to observe whether or not disabled discharge occurs by the suction of ink droplets generated by ink mist into any of the nozzles. This observation of disabled discharge is carried out by eye-sight to confirm the presence of white strips (results of non-discharges) on the solidly printed sheet. Here, the evaluation standard is as follows:

A: Almost no white stripe is recognized.
B: One to two white stripes are recognized.
C: Five or more white stripes are recognized.

(Second Embodiment)

In accordance with a second embodiment of the present invention, an ink jet head is formed with the pattern of the hydrophilic area being changed. All other aspects are the same as those of the first embodiment.

The mask used for the present embodiment is formed by the discharge port portion and the hatched area as shown in Fig. 4B, and for the hatched area, masks of each 2 µm square each are arranged at pitches of 2 µm (see Fig. 5). The finished area corresponding to the mask of 2 µm square is formed to be 1.8 to 2.0 µm square with a depth of 2 µm. The evaluation is made in the same manner as the first embodiment. The results thereof are shown in Table 3.

Table 3

	Partial Hydrophilic area	First sheet	Second sheet	Third sheet	Fourth sheet	Fifth sheet
Embodiment 1	present	A	A	A	A	B
Embodiment
2	present	A	A	A	A	A
Comparative Sample	absent	A	B	B	B	C

As clear from the above results, when the hydrophilic area is partially provided for the nozzle surface, it is possible to improve the print quality in the continuous printing.
The size and arrangement position of the area where the hydrophilic treatment is given can be selected appropriately in accordance with the mode to be adopted.

(Embodiment 3)

A third embodiment of the present invention is the example in which the present invention is applied to the electrical assembly in addition to the hydrophilic area provided for the nozzle surface.
Although there are various methods for making electrical connection with the substrate where heaters and nozzles are formed. In recent years, there has been practiced the one for which an anisotropic conduction sheet (hereinafter referred to as ACF) is adopted as a technique capable of executing assembling in high density, among some others.
Figs. 6A to 6E are views that illustrate the fundamental process when the ACF (anisotropic conduction sheet) is used.
Fig. 6A is a cross-sectional view that shows the chip on which nozzles are formed in a mode where AL pads 9 are arranged around the chip for electrical connection. The portion surrounded by a circle is the nozzle portion 20. Next, on the AL pads, each bump 10 is formed (Fig. 6B). Further, the ACF is positioned (Fig. 6C), and heat and pressure are given to the ACF - bump connecting portion to collapse the ACF so that it demonstrates conductivity for the electrical connection (Fig. 6D).
Lastly, the connected portion is sealed to complete the process (Fig. 6E).
However, with this method, heat and pressure are given not only to the bump portion when the ACF is heated and pressed, but also, heat and pressure are given across the substrate and ACF. As a result, conduction is made with the substrate side to bring about drawback in some cases. Under the circumstances, therefore, as shown in Fig. 7A, there has been proposed to arrange a pattern that becomes a spacer 13 around the AL pads by use of the first and second photosensitive resin layer that form the nozzle. With the space 13 thus arranged, there is no possibility to allow conduction with the substrate side when the ACF is heated under pressure for bonding to make it possible to increase margin for the condition of thermo-pressure bonding (Fig. 7B). Nevertheless, when the spacer 13 is formed by use of the first and second photosensitive layers, there is some case where sealant is repelled when the sealing process is executed, because the second photosensitive resin layer has water-repellency. Here, therefore, the partial hydrophilic process of the present invention is applied to the spacer portion 13 in order to prevent the sealant from being repelled, hence making the complete sealing process and the prevention of conduction across the substrate and the ACF compatible. A circle surrounds the nozzle portion 20 for the indication thereof.
As the executable mode of the present embodiment, the space is formed by the hydrophilic process having the same steps as those of partial hydrophilic process for the nozzle portion of the first embodiment. The spacer is formed in a pattern of 50 µm square on the mask, and the surface is made hydrophilic by arranging a line of 2 µm each at interval of 8 µm. When the chip thus obtained is electrically assembled by use of the ACF, there occurs any drawback due to conduction across the substrate and the ACF. Further, there is no case at all where sealant is repelled on the spacer portion when the sealing process is executed.
As described above, in accordance with the present invention, it becomes possible to attempt the enhancement of print quality with the formation of the water-repellent portion and hydrophilic portion on the nozzle surface of an ink jet head in exact positioning precision without increasing the number of processing steps.

Claims

A method for manufacturing an ink jet head provided with a discharge port member having discharge ports for discharging ink arranged therefor, comprising the following steps of:
forming an ink flow-path pattern by soluble resin (3) on a substrate (1) having ink discharge pressure generating element (2) formed thereon;

laminating on said ink flow-path pattern a first photosensitive resin layer (4) for forming said discharge port member;

laminating on said first photosensitive resin layer, a second photosensitive resin layer (5) having water-repellency for forming said discharge port member;

forming a first latent-image pattern reaching the bottom portion of said first photosensitive resin layer, and a second latent-image pattern exceeding the second photosensitive resin layer, but not reaching the bottom portion of the first photosensitive resin layer by giving pattern exposure to said first photosensitive resin layer and second photosensitive resin layer simultaneously by use of mask, while controlling partially the exposed area of the exposed portion at the time of giving said pattern exposure so as to make the depths of latent images different;

forming a hydrophilic portion (7) and a discharge port portion (6) by developing said pattern-exposed first photosensitive resin layer and second photosensitive resin layer to remove the first and second photosensitive resin layers (4, 5) at the discharge port portion (6) and to expose the first photosensitive layer (4) at the hydrophilic portion (7); and

removing said ink flow-path pattern formed by soluble resin.
A method for manufacturing an ink jet head according to Claim 1, wherein said first photosensitive resin layer and second photosensitive resin layer are negative type photosensitive resin layers.
A method for manufacturing an ink jet head according to Claim 1, wherein said second latent-image pattern is formed by the pattern-exposure smaller than the resolution limit of said first photosensitive resin layer.
A method for manufacturing an ink jet head according to Claim 1, wherein the thickness of said first photosensitive resin layer is larger than the thickness of said second photosensitive resin layer.
A method for manufacturing an ink jet head according to claim 2, wherein the thickness of said first photosensitive resin layer is 10 or more times the thickness of said photosensitive resin layer.
A method for manufacturing an ink jet head according to claim 1, further comprising the following step of:
making an electrical connection by use of an anisotropic conduction sheet after said discharge port member is formed.
A method for manufacturing an ink jet head according to claim 6, further comprising the following step of:
arranging a spacer between the area of the substrate having said second photosensitive resin layer partially removed, and said anisotropic conduction sheet when the electrical connection is made by use of said anisotropic conduction sheet.