EP1366531A4 - Cobalt (iii) encapsulated nickel hydroxides and basic carbonates for battery electrodes - Google Patents

Cobalt (iii) encapsulated nickel hydroxides and basic carbonates for battery electrodes

Info

Publication number
EP1366531A4
EP1366531A4 EP02709916A EP02709916A EP1366531A4 EP 1366531 A4 EP1366531 A4 EP 1366531A4 EP 02709916 A EP02709916 A EP 02709916A EP 02709916 A EP02709916 A EP 02709916A EP 1366531 A4 EP1366531 A4 EP 1366531A4
Authority
EP
European Patent Office
Prior art keywords
cobalt
iii
nickel
hydroxide
basic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02709916A
Other languages
German (de)
French (fr)
Other versions
EP1366531A1 (en
Inventor
John Ernest Fittock
Cheryl Christine Lucas
Katherine Fiona Howison
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
QNI Technology Pty Ltd
Original Assignee
QNI Technology Pty Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by QNI Technology Pty Ltd filed Critical QNI Technology Pty Ltd
Publication of EP1366531A1 publication Critical patent/EP1366531A1/en
Publication of EP1366531A4 publication Critical patent/EP1366531A4/en
Withdrawn legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/24—Electrodes for alkaline accumulators
    • H01M4/32—Nickel oxide or hydroxide electrodes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/006—Compounds containing, besides cobalt, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/04—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/04—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/06—Carbonates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/366—Composites as layered products
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/626—Metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/80—Compositional purity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y10T428/294—Coated or with bond, impregnation or core including metal or compound thereof [excluding glass, ceramic and asbestos]
    • Y10T428/2958—Metal or metal compound in coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

A process for producing a cobalt III encapsulated nickel hydroxide or basic nickel carbonate product including the steps of:(i) providing an ammoniacal solution including cobalt ammine complexes and nickel II ammine complexes;(ii) progressively reducing the ammonia content to sequentially precipiate the nickel as an hydroxide or basic carbonate; and(iii) further reduce the ammonia content to precipitate the majority of the cobalt as cobalt III oxide hydroxide; wherein the majority of cobalt III oxide hydroxide coats on the surface of the precipitate nickel hydroxide or basic nickel carbonate to form a coated particle.
EP02709916A 2001-02-08 2002-02-07 Cobalt (iii) encapsulated nickel hydroxides and basic carbonates for battery electrodes Withdrawn EP1366531A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AUPR2953A AUPR295301A0 (en) 2001-02-08 2001-02-08 Process for the preparation of battery chemicals
AUPR295301 2001-02-08
PCT/AU2002/000119 WO2002063704A1 (en) 2001-02-08 2002-02-07 Cobalt (iii) encapsulated nickel hydroxides and basic carbonates for battery electrodes

Publications (2)

Publication Number Publication Date
EP1366531A1 EP1366531A1 (en) 2003-12-03
EP1366531A4 true EP1366531A4 (en) 2008-03-05

Family

ID=3826976

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02709916A Withdrawn EP1366531A4 (en) 2001-02-08 2002-02-07 Cobalt (iii) encapsulated nickel hydroxides and basic carbonates for battery electrodes

Country Status (6)

Country Link
US (1) US7267874B2 (en)
EP (1) EP1366531A4 (en)
JP (1) JP2004523067A (en)
AU (1) AUPR295301A0 (en)
CA (1) CA2436796A1 (en)
WO (1) WO2002063704A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8334067B2 (en) * 2009-01-13 2012-12-18 The Gillette Company Non-uniform conductive coating for cathode active material
JP5610010B2 (en) * 2012-10-25 2014-10-22 住友金属鉱山株式会社 Coated nickel hydroxide powder for positive electrode active material of alkaline secondary battery and method for producing the same
JP2015037069A (en) * 2013-08-16 2015-02-23 輔仁大學學校財團法人輔仁大學 Lithium nickel cobalt positive electrode material powder
KR101913906B1 (en) * 2015-06-17 2018-10-31 주식회사 엘지화학 Positive electrode active material for secondary battery, method for preparing the same, and secondary battery comprising the same
KR101970207B1 (en) * 2016-01-05 2019-04-18 주식회사 에코프로비엠 Manufacturing method of cobalt coated precusor for cathod active material, cobalt coated precusor made by the same, and cathod active material made using the same
WO2018227237A1 (en) * 2017-06-14 2018-12-20 Urban Mining Pty Ltd Method for the production of cobalt and associated oxides from various feed materials
CN111052462B (en) 2017-09-11 2023-06-02 株式会社田中化学研究所 Positive electrode active material for alkaline storage battery and method for producing same
CN114684865B (en) * 2020-12-30 2023-08-08 天津国安盟固利新材料科技股份有限公司 Preparation method of aluminum-doped cobalt carbonate particles

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2879137A (en) * 1956-10-12 1959-03-24 Bethlehem Steel Corp Nickel and cobalt recovery from ammoniacal solutions
US3928068A (en) * 1974-05-20 1975-12-23 Westinghouse Electric Corp Active electrode composition and electrode
US5523182A (en) 1992-11-12 1996-06-04 Ovonic Battery Company, Inc. Enhanced nickel hydroxide positive electrode materials for alkaline rechargeable electrochemical cells
EP0720247B1 (en) 1994-12-16 1998-05-27 Matsushita Electric Industrial Co., Ltd. Manufacturing processes of positive active materials for lithium secondary batteries and lithium secondary batteries comprising the same
US5674643A (en) 1995-02-14 1997-10-07 Sanyo Electric Co., Ltd. Non-sintered nickel electrode for alkaline storage cell
US6040007A (en) * 1996-06-19 2000-03-21 Tanaka Chemical Corporation Nickel hydroxide particles having an α- or β-cobalt hydroxide coating layer for use in alkali batteries and a process for producing the nickel hydroxide
JP3884796B2 (en) * 1996-07-12 2007-02-21 日本化学工業株式会社 Method for producing Ni-Co composite hydroxide
US5955051A (en) 1996-08-02 1999-09-21 Westaim Technologies Inc. Synthesis of lithium nickel cobalt dioxide
JP3223858B2 (en) 1996-12-24 2001-10-29 松下電器産業株式会社 Alkaline storage battery, its positive electrode active material, and method for producing the same
KR100232402B1 (en) * 1996-12-31 1999-12-01 손욱 A method for producing hydroxicarbonate
CN1129198C (en) * 1997-02-03 2003-11-26 松下电器产业株式会社 Manufacturing method of active materials for positive electrode in alkaline storage batteries
JPH10321229A (en) * 1997-05-23 1998-12-04 Sumitomo Metal Mining Co Ltd Positive electrode active material for nonaqueous electrolyte secondary battery and its manufacture
JP3489396B2 (en) * 1997-06-18 2004-01-19 住友金属鉱山株式会社 Metal-coated nickel hydroxide for positive electrode material and method for producing the same
JP2000077070A (en) * 1998-08-31 2000-03-14 Sumitomo Metal Mining Co Ltd Nickel hydroxide powder and its manufacture

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
No further relevant documents disclosed *

Also Published As

Publication number Publication date
US7267874B2 (en) 2007-09-11
US20040091414A1 (en) 2004-05-13
WO2002063704A1 (en) 2002-08-15
AUPR295301A0 (en) 2001-03-08
CA2436796A1 (en) 2002-08-15
JP2004523067A (en) 2004-07-29
EP1366531A1 (en) 2003-12-03

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