EP1297903B1 - Process for manufacturing painted automotive body parts from aluminium alloy - Google Patents

Process for manufacturing painted automotive body parts from aluminium alloy Download PDF

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Publication number
EP1297903B1
EP1297903B1 EP01810950A EP01810950A EP1297903B1 EP 1297903 B1 EP1297903 B1 EP 1297903B1 EP 01810950 A EP01810950 A EP 01810950A EP 01810950 A EP01810950 A EP 01810950A EP 1297903 B1 EP1297903 B1 EP 1297903B1
Authority
EP
European Patent Office
Prior art keywords
strip
rolled
cold
process according
body parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01810950A
Other languages
German (de)
French (fr)
Other versions
EP1297903B8 (en
EP1297903A1 (en
Inventor
Ehard Saur
Rainer Kossak
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novelis Inc Canada
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Novelis Inc Canada
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Novelis Inc Canada filed Critical Novelis Inc Canada
Priority to AT01810950T priority Critical patent/ATE335550T1/en
Priority to DE50110714T priority patent/DE50110714D1/en
Priority to EP01810950A priority patent/EP1297903B8/en
Publication of EP1297903A1 publication Critical patent/EP1297903A1/en
Publication of EP1297903B1 publication Critical patent/EP1297903B1/en
Application granted granted Critical
Publication of EP1297903B8 publication Critical patent/EP1297903B8/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/05Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys of the Al-Si-Mg type, i.e. containing silicon and magnesium in approximately equal proportions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/20Metallic substrate based on light metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2701/00Coatings being able to withstand changes in the shape of the substrate or to withstand welding
    • B05D2701/10Coatings being able to withstand changes in the shape of the substrate or to withstand welding withstanding draw and redraw process, punching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate

Definitions

  • the invention relates to a method for producing painted automobile body parts according to the preamble of claim 1.
  • the invention has for its object to provide a simplified method for producing painted automotive body parts of an aluminum alloy of the type mentioned, which is suitable for forming in the painted state.
  • the core of the invention lies in the combination of the heat treatment state T4 generated by the cold aging with the following, relatively weak cold working with a thickness decrease of max. 18%. This ensures that the softened as a result of solution annealing and therefore susceptible to surface damage of all kinds band to prevent such damage again has sufficient strength.
  • the increase in strength is claimed in the claimed Kaltverfomungs Scheme such that on the one hand still sufficient reserve for the deformation of the painted strip to the painted automotive body parts remains, on the other hand, the strength in the painted body parts is considerably higher than in the clean state T4.
  • the solution annealing of the rolled to the intermediate thickness strip is mandatory in a continuous band-pass annealing furnace.
  • the conversion layer here is the known pretreatment of aluminum surfaces such as e.g. Chromating or chromium-free process understood. With the conversion layer, the adhesion of the paint layers on the aluminum surface is significantly improved.
  • the final thickness rolled strip before applying the conversion layer to a surface texture to provide.
  • the reduction in thickness provided for cold rolling of the cold-laid strip to final thickness should be taken into account, ie the total reduction in thickness must not exceed the maximum value of 18%.
  • a surface texture to the final thickness rolled strip is conveniently accomplished via a corresponding surface roughness pattern applied to the surface of work rolls which is transferred to the strip in a single rolling operation.
  • the surface topographies of the work roll and the tapes embossed therewith are complementary to one another, i. Tips or elevations on the roll surface become valleys or depressions in the strip surface and vice versa.
  • the aforementioned painted automotive body parts are for example modules, such as roof modules for sunroofs or complete roofs or other components that are brought from the painted strip by cold forming in the desired shape.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Metal Rolling (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Body Structure For Vehicles (AREA)

Abstract

Production of lacquered car chassis parts made from aluminum alloy comprises: cold working a hot-rolled strip; solution annealing the strip; cooling at specified rate; aging to produce the heat treatment state T4; cold rolling to a final thickness having a thickness reduction of 1.5-18%; applying a conversion layer to strip; applying one or more lacquer layers; and deforming to form chassis parts. <??>Production of lacquered car chassis parts made from an aluminum alloy containing alloying additions of 0.3-0.9 wt.% magnesium and 0.5-1.2 wt.% silicon comprises: cold working a hot-rolled strip; solution annealing the rolled strip for 10-100 seconds at 540-575 degrees C; cooling at a rate of 20-300 degrees C/second to 200 degrees C or less; aging to produce the heat treatment state T4; cold rolling to a final thickness having a thickness reduction of 1.5-18%; applying a conversion layer to the strip; applying one or more lacquer layers; and deforming to form the chassis parts. <??>Preferred Features: A surface texture is applied to the finished strip using a working roller roughened according electrical discharge texturing.

Description

Die Erfindung betrifft ein Verfahren zur Herstellung lackierter Automobil-Karosserieteile nach dem Oberbegriff von Auspruch 1.The invention relates to a method for producing painted automobile body parts according to the preamble of claim 1.

Bei der Herstellung lackierter Automobil-Karosserieteile aus Aluminiumlegierungen ist allgemein bekannt, Karosserieteile aus Blech zunächst in die endgültige Form zu bringen und das fertige Karosserieteil anschliessend, d.h. erst nach der Umformung des Bleches zum Karosserieteil zu lackieren. In einem oder mehreren Schritten erfolgt sodann ein Einbrennen des Lackes bei Temperaturen, die gleichzeitig zu einem Festigkeitsanstieg im Blech führen.In the production of painted automotive body parts made of aluminum alloys, it is generally known to bring body parts of sheet metal first into the final shape and then to finish the finished body part, i. to be painted only after the deformation of the sheet to the body part. In one or more steps then takes place a baking of the paint at temperatures that simultaneously lead to an increase in strength in the sheet.

Aus Murtha S. J. et al., "Anisotropy Effects in the Forming of Aluminum Sheet", SAE Special Publications, XX, XX, 1995, Seiten 103 - 111, XP008005835, ISSN: 0099-5908 ist ein zur Herstellung von Automobil-Karosserieteilen geeignetes Band aus der Legierung 6009 im Zustand T4 mit einer EDT-Oberflächentopografie zur Verbesserung des Umformverhaltens bekannt.From Murtha SJ et al., "Anisotropic Effects in the Forming of Aluminum Sheet," SAE Special Publications, XX, XX, 1995, pages 103-111, XP008005835, ISSN: 0099-5908 is a tape suitable for the manufacture of automotive body parts from alloy 6009 in state T4 with an EDT surface topography for improving the forming behavior.

Der Erfindung liegt die Aufgabe zugrunde, ein vereinfachtes Verfahren zur Herstellung lackierter Automobil-Karosserieteile aus einer Aluminiumlegierung der eingangs erwähnten Art zu schaffen, welches zum Umformen im lackierten Zustand geeignet ist.The invention has for its object to provide a simplified method for producing painted automotive body parts of an aluminum alloy of the type mentioned, which is suitable for forming in the painted state.

Zur erfindungsgemässen Lösung der Aufgabe führt ein Verfahren mit den Merkmalen von Auspruch 1. Der Kern der Erfindung liegt in der Kombination des durch die Kaltauslagerung erzeugten Wärmebehandlungszustandes T4 mit der darauf folgenden, verhältnismässig schwachen Kaltumformung mit einer Dickenabnahme von max. 18%. Dadurch wird sichergestellt, dass das infolge des Lösungsglühens weich gewordene und deshalb auf Oberflächenbeschädigungen aller Art anfällige Band zur Verhinderung derartiger Beschädigungen wieder eine ausreichende Festigkeit aufweist. Gleichzeitig ist der Festigkeitsanstieg im beanspruchten Kaltverfomungsbereich derart bemessen, dass einerseits noch genügend Reserve für die Umformung des lackierten Bandes zu den lackierten Automobil-Karosserieteilen verbleibt, anderseits die Festigkeit in den lackierten Karosserieteilen erheblich höher ist als im reinen Zustand T4.For the inventive solution of the problem leads a method having the features of claim 1. The core of the invention lies in the combination of the heat treatment state T4 generated by the cold aging with the following, relatively weak cold working with a thickness decrease of max. 18%. This ensures that the softened as a result of solution annealing and therefore susceptible to surface damage of all kinds band to prevent such damage again has sufficient strength. At the same time the increase in strength is claimed in the claimed Kaltverfomungsbereich such that on the one hand still sufficient reserve for the deformation of the painted strip to the painted automotive body parts remains, on the other hand, the strength in the painted body parts is considerably higher than in the clean state T4.

Das Lösungsglühen des auf die Zwischendicke gewalzten Bandes erfolgt zwingend in einem kontinuierlich arbeitenden Banddurchlauf-Glühofen.The solution annealing of the rolled to the intermediate thickness strip is mandatory in a continuous band-pass annealing furnace.

Unter Konversionsschicht wird hier die bekannte Vorbehandlung von Aluminiumoberflächen wie z.B. Chromatieren oder chromfreie Verfahren verstanden. Mit der Konversionsschicht wird die Haftung der Lackschichten auf der Aluminiumoberfläche entscheidend verbessert.The conversion layer here is the known pretreatment of aluminum surfaces such as e.g. Chromating or chromium-free process understood. With the conversion layer, the adhesion of the paint layers on the aluminum surface is significantly improved.

In gewissen Fällen kann es sich als vorteilhaft erweisen, das auf Enddicke gewalzte Band vor dem Aufbringen der Konversionsschicht mit einer Oberflächentextur zu versehen. Bei einer mit dem Texturieren der Oberfläche allenfalls durch einen Prägeschritt verursachten Dickenreduktion wäre die beim Kaltwalzen des kaltausgelagerten Bandes auf Enddicke vorgesehene Dickenabnahme zu berücksichtigen, d.h. die totale Dickenreduktion darf den Maximalwert von 18% nicht überschreiten.In certain cases, it may prove advantageous to strip the final thickness rolled strip before applying the conversion layer to a surface texture to provide. In the case of a thickness reduction caused by the texturing of the surface, if necessary by an embossing step, the reduction in thickness provided for cold rolling of the cold-laid strip to final thickness should be taken into account, ie the total reduction in thickness must not exceed the maximum value of 18%.

Das Aufbringen einer Oberflächentextur auf das auf Enddicke gewalzte Band erfolgt in zweckmässiger Weise über ein entsprechendes, auf die Oberfläche von Arbeitswalzen aufgebrachtes Rauheitsmuster, welches in einem einzigen Walzvorgang auf das Band übertragen wird. Wie bei jedem Prägevorgang sind die Oberflächentopographien der Arbeitswalze und der damit geprägten Bänder zueinander komplementär, d.h. Spitzen bzw. Erhebungen auf der Walzenoberfläche werden zu Tälern bzw. Vertiefungen in der Bandoberfläche und umgekehrt.Application of a surface texture to the final thickness rolled strip is conveniently accomplished via a corresponding surface roughness pattern applied to the surface of work rolls which is transferred to the strip in a single rolling operation. As with any embossing operation, the surface topographies of the work roll and the tapes embossed therewith are complementary to one another, i. Tips or elevations on the roll surface become valleys or depressions in the strip surface and vice versa.

Zur Durchführung des erfindungsgemässen Verfahrens geeignete Rauheitsmuster ergeben sich durch Prägen einer Oberflächentextur mit Arbeitswalzen, deren Oberfläche nach den folgenden Verfahren aufgerauht sind:

  • Funkenerodierverfahren (EDT-Electrical Discharge Texturing). Beim EDT-Verfahren wird die Walze längs einer Reihe von Elektroden bei gleichzeitiger axialer Oszillation gedreht und dabei die Oberfläche auf eine vorgewählte Rauhtiefe texturiert. Durch die Entladung elektrischer Energie zwischen der Walzenoberfläche und den über eine dieelektrische Flüssigkeit getrennten Elektroden werden auf der Walzenoberfläche kleine Krater gebildet. Die Rauheit der Walze kann auf bekannte Weise durch eine Reihe von Maschinen-Parametern eingestellt werden. Das Rauheitsmuster ist eine statistische Verteilung von Spitzen und Tälern. Das EDT-Verfahren ermöglicht die Einstellung von Mittenrauhwerten Ra zwischen 0,5 und 2 µm. Mittenrauhwert und Spitzenzahl sind miteinander weitgehend verknüpft. Für das erfindungsgemässe Verfahren besonders geeignet ist eine Oberflächentextur mit niedriger Rauheit und hoher Spitzenzahl.
  • Isomill-Verfahren. Beim Isomill-Verfahren sind in die Oberfläche der Arbeitswalzen in Umfangrichtung und quer dazu in Achsenrichtung oder in einem Winkel von je 45° zur Walzrichtung zur Erzeugung eines im wesentlichen quadratischen Rauheitsmusters Rillen eingraviert.
  • Millfinish-Verfahren. Beim Millfinish-Verfahren sind in die Oberfläche der Arbeitswalzen in Umfangrichtung feine Rillen eingraviert. Bei Übertragung dieses Rauheitsmusters auf das Blech entsteht die Oberfläche "Millfinish".
Roughness patterns suitable for carrying out the method according to the invention are obtained by embossing a surface texture with work rolls whose surface has been roughened by the following methods:
  • Spark EDM (EDT Electrical Discharge Texturing). In the EDT process, the roll is rotated along a series of electrodes with simultaneous axial oscillation, thereby texturing the surface to a preselected roughness. By discharging electrical energy between the roll surface and the electrodes separated by a dielectric liquid, small craters are formed on the roll surface. The roughness of the roll can be adjusted in a known manner by a number of machine parameters. The roughness pattern is a statistical distribution of peaks and valleys. The EDT method allows the adjustment of average roughness values R a between 0.5 and 2 μm. Mean roughness and number of peaks are largely linked. Particularly suitable for the process according to the invention is a surface texture with low roughness and a high number of tips.
  • Isomill method. In the Isomill process grooves are engraved in the surface of the work rolls circumferentially and transversely thereto in the axial direction or at an angle of 45 ° to the rolling direction to produce a substantially square roughness pattern.
  • Millfinish method. In the Millfinish process, fine grooves are circumferentially engraved in the surface of the work rolls. When this roughness pattern is transferred to the sheet, the surface "Millfinish" is created.

Die erwähnten lackierten Automobil-Karosserieteile sind beispielsweise Module, wie Dachmodule für Sonnendächer oder komplette Dächer oder auch andere Komponenten, die aus dem lackierten Band durch eine Kaltumformung in die gewünschte Form gebracht werden.The aforementioned painted automotive body parts are for example modules, such as roof modules for sunroofs or complete roofs or other components that are brought from the painted strip by cold forming in the desired shape.

Claims (8)

  1. Process for the production of lacquered car body parts from an aluminium alloy containing 0.3 to 0.9 wt.% of magnesium and 0.5 to 1.2 wt.% of silicon, wherein
    - a hot-rolled strip is cold-rolled in one or more reduction passes,
    - the cold-rolled strip is subjected to a solution heat treatment,
    - the strip subjected to the solution heat treatment is cooled, and
    - the cooled strip is naturally aged to attain heat-treated condition T4,
    wherein
    - the hot-rolled strip is cold-rolled to an intermediate thickness,
    - the strip cold-rolled to the intermediate thickness is subjected to a solution heat treatment in a continuous strip annealing furnace for 10 to 100 sec at a temperature of 540 to 575°C, and
    - the strip subjected to the solution heat treatment is cooled to 200°C or below at a rate of 20 to 300°C/sec,
    characterized in that
    - the strip naturally aged to attain heat-treated condition T4 is cold-rolled to the final thickness with a thickness reduction of 1.5 to 18%,
    - a conversion layer is applied to the strip cold-rolled to the final thickness,
    - one or more coats of lacquer are applied to the strip provided with the conversion layer, and
    - the lacquered strip is shaped into the lacquered car body parts.
  2. Process according to Claim 1, characterized in that, as the last step, a surface texture is applied to the strip cold-rolled to the final thickness.
  3. Process according to Claim 2, characterized in that the surface texture is transferred to the strip in a single rolling operation by means of a roughness pattern applied to the surface of working rolls.
  4. Process according to Claim 3, characterized in that the surface of the working rolls is roughened by the EDT (Electrical Discharge Texturing) process.
  5. Process according to Claim 3, characterized in that grooves are engraved in the surface of the working rolls in the peripheral direction and transversely thereto in the axial direction, or at an angle of 45° to the rolling direction in each case, in order to produce a substantially square roughness pattern (isomill process).
  6. Process according to Claim 3, characterized in that grooves are engraved in the surface of the working rolls in the peripheral direction in order to produce a millfinish pattern.
  7. Process according to one of Claims 1 to 6, characterized in that sheets cut out of the lacquered strip are shaped into the lacquered car body parts by cold forming.
  8. Process according to one of Claims 1 to 7 wherein the lacquered car body parts are used as modules such as roof modules for sun roofs or complete roofs.
EP01810950A 2001-09-28 2001-09-28 Process for manufacturing painted automotive body parts from aluminium alloy Expired - Lifetime EP1297903B8 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AT01810950T ATE335550T1 (en) 2001-09-28 2001-09-28 METHOD FOR PRODUCING PAINTED AUTOMOBILE BODY PARTS FROM AN ALUMINUM ALLOY
DE50110714T DE50110714D1 (en) 2001-09-28 2001-09-28 Method for producing painted automotive body parts from an aluminum alloy
EP01810950A EP1297903B8 (en) 2001-09-28 2001-09-28 Process for manufacturing painted automotive body parts from aluminium alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP01810950A EP1297903B8 (en) 2001-09-28 2001-09-28 Process for manufacturing painted automotive body parts from aluminium alloy

Publications (3)

Publication Number Publication Date
EP1297903A1 EP1297903A1 (en) 2003-04-02
EP1297903B1 true EP1297903B1 (en) 2006-08-09
EP1297903B8 EP1297903B8 (en) 2007-06-13

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP01810950A Expired - Lifetime EP1297903B8 (en) 2001-09-28 2001-09-28 Process for manufacturing painted automotive body parts from aluminium alloy

Country Status (3)

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EP (1) EP1297903B8 (en)
AT (1) ATE335550T1 (en)
DE (1) DE50110714D1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20200033893A (en) 2017-07-21 2020-03-30 노벨리스 인크. System and method for controlling flatness of metal substrate by low pressure rolling
CN115011848B (en) * 2022-05-11 2023-03-28 北京理工大学 High-purity aluminum alloy conductor and preparation method thereof

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH685346A5 (en) * 1993-04-06 1995-06-15 Alusuisse Lonza Services Ag A method for joining metal components.
DE19781671B4 (en) * 1996-03-27 2008-11-06 Toyo Kohan Co., Ltd. Thermo-resin coated aluminum alloy sheet
WO1998049360A1 (en) * 1997-04-25 1998-11-05 Toyo Kohan Co., Ltd. Resin-coated aluminum alloy sheet for drawn and ironed cans

Also Published As

Publication number Publication date
EP1297903B8 (en) 2007-06-13
DE50110714D1 (en) 2006-09-21
ATE335550T1 (en) 2006-09-15
EP1297903A1 (en) 2003-04-02

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