EP1273863A1 - Process for cleaning hot surface for deposits of metal or slag - Google Patents

Process for cleaning hot surface for deposits of metal or slag Download PDF

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Publication number
EP1273863A1
EP1273863A1 EP02013410A EP02013410A EP1273863A1 EP 1273863 A1 EP1273863 A1 EP 1273863A1 EP 02013410 A EP02013410 A EP 02013410A EP 02013410 A EP02013410 A EP 02013410A EP 1273863 A1 EP1273863 A1 EP 1273863A1
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EP
European Patent Office
Prior art keywords
slag
metal
water
cleaned
sprayed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP02013410A
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German (de)
French (fr)
Inventor
Bernd Oberholz
Andreas Holze
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beck U Kaltheuner Feuerfeste Erzeugnissegmbh & Co KG
Original Assignee
Beck U Kaltheuner Feuerfeste Erzeugnissegmbh & Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beck U Kaltheuner Feuerfeste Erzeugnissegmbh & Co KG filed Critical Beck U Kaltheuner Feuerfeste Erzeugnissegmbh & Co KG
Publication of EP1273863A1 publication Critical patent/EP1273863A1/en
Withdrawn legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D25/00Devices or methods for removing incrustations, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag
    • F27D25/008Devices or methods for removing incrustations, e.g. slag, metal deposits, dust; Devices or methods for preventing the adherence of slag using fluids or gases, e.g. blowers, suction units
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/02Cleaning by the force of jets or sprays

Definitions

  • repair material is now applied to such metal and slag layers, so There is therefore no long-lasting repair effect, since the repair material layers applied have not found a cheap prison surface. Comes after Completion of the repair work, the repaired surface again with hot, molten material (metal and / or slag) in contact, so the applied Repair materials detached from their surface and washed away.
  • Such slag and metal layers are removed from refractory surfaces conventionally with the help of mechanical methods and essentially through Chiseling, milling or chain slaps.
  • the heavy blows wear down the remaining material until it is Fracture. Zones of premature wear at slag-air boundaries or metal-slag areas can hardly with the chisel due to their notch-shaped geometry can be cleaned without significant damage to the remaining material and thus causing wasteful refractory material to be wasted.
  • an excavator-like vehicle serves as the tool carrier Radiant heat of the hot surface is largely exposed unprotected. in the In the event of a gutter cleaning, this vehicle runs on the gutter. Because of the dynamic The channel is subjected to high mechanical loads.
  • the invention has for its object a new method for removing Specify slag and metal residues from refractory surfaces with which Help refractory surfaces of transport containers, transport channels and the like residues of slag and metal can be removed gently and safely.
  • the aim of the new procedure is to ensure that the cleaning staff neither due to heat or flying particles, be it the removed slag and metal residues or the underlying refractory material.
  • the new process is also intended to completely remove the metal and slag residues guarantee from the refractory surfaces.
  • the progress that can be achieved with the method results primarily from that with the help of the high-tension water jet a safe, the refractory surface gentle removal of the slag and metal layers to be removed guaranteed by the refractory surfaces. After the cleaning process the cleaned refractory surfaces offer a secure base for sticking on Repair material.
  • the for amount of water that acts on the cleaning surfaces in terms of pressure and amount be chosen carefully.
  • water pressures of at least 2,000 bar preferred, with a water amount of about 15 to 20 l per minute in the form of a thin Sprayed onto the hot surface to be cleaned.
  • the water jet emerges from a nozzle, which at the end of a sufficiently long-dimensioned Tube sits around people or machines handling the said tube, Protect from harmful heat equipment.
  • the amount of water sprayed out of the nozzle in the unit of time is so small that An instant conversion of the water to superheated steam occurs when the water strikes the hot surface to be cleaned. Due to the large, sudden entry Volume change from liquid to gaseous (i.e. from water to water vapor) becomes a detonation of those to be removed adhering to the material to be cleaned Layers, which means that the slags to be removed and peel off metal residues from the underlying refractory material.
  • the high impact pressure of the spray water on the surface to be cleaned also exercises a mechanical removal effect on the surface layers to be removed and on the underlying, destroyed, near-surface refractory material.
  • the application of the surface to be cleaned with the high-tension water jet is preferably continued until it is on the refractory base material Grooves have formed, which in turn is an excellent basis for adhesion to the applied Form repair material.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

Process for removing metal and slag residues from hot surfaces comprises spraying water onto the surface to be cleaned under a pressure of at least 2,000 bar from one or more nozzles in an amount sufficient so that the sprayed water is converted into vapor without leaving a residue. Preferably 15-20 liters per minute of water are sprayed onto the surface to be cleaned. The surface is made from refractory materials.

Description

Bei der Erzeugung von Metallen durch Schmelz- oder Umschmelzprozesse ist es erforderlich, flüssige Metallschmelzen in Transportgefäßen oder mit Hilfe von Rinnen zu transportieren. Diese Gefäße und Rinnen sind stets mit feuerfesten Materialien ausgekleidet, welche im Betrieb einem beträchtlichen Verschleiß unterworfen sind. Dieser Verschleiß erfolgt durch Abrasion als Folge der Relativbewegung zwischen Schmelze und Gefäß bzw. Rinne, ferner durch chemische Reaktionen mit dem Feuerfestmaterial, vor allem in der Grenzfläche Schmelze/Schlacke, begünstigt durch häufige Temperaturwechsel. Die Standzeit des Feuerfestmaterials kann durch Auftragen von geeignetem Reparaturmaterial verlängert werden, was durch Spritzen oder Gießen von Reparaturmaterial auf die Gefäßoberflächen bzw. Rinnenoberflächen erfolgt.When producing metals by melting or remelting processes, it is necessary liquid metal melts in transport containers or with the help of channels transport. These vessels and gutters are always lined with refractory materials, which are subject to considerable wear during operation. This Wear occurs through abrasion as a result of the relative movement between the melt and vessel or channel, furthermore by chemical reactions with the refractory material, especially in the melt / slag interface, favored by frequent temperature changes. The service life of the refractory material can be increased by applying suitable Repair material can be lengthened by spraying or pouring repair material on the vessel surfaces or channel surfaces.

Beim Ausführen solcher Reparaturarbeiten tritt jedoch stets das Problem auf, dass die Oberfläche des zu reparierenden Feuerfestmaterials mit einer Schicht aus Metall und/oder Schlacke überzogen ist. Diese Schichten stammen von dem vorhergehenden Gebrauch des metallurgischen Gefäßes bzw. der metallurgischen Transportrinne.When carrying out such repair work, however, the problem always arises that the Surface of the refractory material to be repaired with a layer of metal and / or slag is coated. These layers come from the previous one Use of the metallurgical vessel or the metallurgical transport trough.

Wird nun Reparaturmaterial auf solche Metall- und Schlackenschichten aufgetragen, so ergibt sich damit kein lang anhaltender Reparatureffekt, da die aufgebrachten Reparaturmaterialschichten keinen günstigen Haftuntergrund gefunden haben. Kommt nach Abschluss der Reparaturarbeiten die reparierte Oberfläche wieder mit heißem, schmelzflüssigem Material (Metall und/oder Schlacke) in Berührung, so werden die aufgebrachten Reparaturmaterialien von ihrem Untergrund gelöst und weggeschwemmt.If repair material is now applied to such metal and slag layers, so There is therefore no long-lasting repair effect, since the repair material layers applied have not found a cheap prison surface. Comes after Completion of the repair work, the repaired surface again with hot, molten material (metal and / or slag) in contact, so the applied Repair materials detached from their surface and washed away.

Das Entfernen solcher Schlacken- und Metallschichten von Feuerfestoberflächen erfolgt herkömmlicherweise mit Hilfe mechanischer Verfahren und zwar im Wesentlichen durch Meißeln, Fräsen oder Kettenschläge.Such slag and metal layers are removed from refractory surfaces conventionally with the help of mechanical methods and essentially through Chiseling, milling or chain slaps.

Meißelschläge beschädigen die Oberfläche des verbleibenden Restmaterials unkontrollierbar. Die schweren Schläge zermürben das verbleibende Restmaterial bis zu dessen Bruch. Zonen voreilenden Verschleißes an Schlacke-Luft-Grenzen oder Metall-Schlacke-Bereichen können durch ihre kerbenförmige Geometrie kaum mit dem Meißel gereinigt werden, ohne erhebliche Beschädigungen am verbleibenden Restmaterial und damit Vergeudung noch brauchbaren Feuerfestmaterials hervorzurufen.Chisel blows uncontrollably damage the surface of the remaining material. The heavy blows wear down the remaining material until it is Fracture. Zones of premature wear at slag-air boundaries or metal-slag areas can hardly with the chisel due to their notch-shaped geometry can be cleaned without significant damage to the remaining material and thus causing wasteful refractory material to be wasted.

Bei dem Einsatz einer Fräse verringert sich der unnötige Oberflächenverschleiß. Auch die Geometrie der Kerben an den Niveaugrenzen kann mit geringerer Zerstörung des noch tauglichen Restmaterials gesäubert werden. Es entstehen jedoch hohe Kosten durch den Verschleiß der Werkzeuge.When using a milling machine, unnecessary surface wear is reduced. Also the geometry of the notches at the level boundaries can be achieved with less destruction of the residual material that is still suitable. However, there are high costs through the wear of the tools.

Als Werkzeugträger dient in beiden Fällen ein baggerartiges Fahrzeug, welches der Strahlungswärme der heißen Oberfläche weitgehend ungeschützt ausgesetzt ist. Im Falle einer Rinnenreinigung fährt dieses Fahrzeug auf der Rinne. Durch die dynamischen Belastungen wird die Rinne stark mechanisch belastet.In both cases, an excavator-like vehicle serves as the tool carrier Radiant heat of the hot surface is largely exposed unprotected. in the In the event of a gutter cleaning, this vehicle runs on the gutter. Because of the dynamic The channel is subjected to high mechanical loads.

Die Reinigung mit Kettenreinigungsmaschinen (EP 0 429 487 B1) erfordert zunächst einen Aufwand, die Maschine in die Reinigungsposition zu bringen. Das Umfeld muss abgesperrt werden, da eine erhebliche Unfallgefahr durch herumfliegende Restmaterialien und verschlissene Kettenglieder besteht.Cleaning with chain cleaning machines (EP 0 429 487 B1) initially requires an effort to bring the machine into the cleaning position. The environment must be cordoned off as there is a significant risk of accidents due to residual materials flying around and worn chain links.

In der DE 43 24 516 A1 wird ein Pulverstrom mit Sauerstoff und Kraftstoffteilchen zur Reinigung von feuerfesten Oberflächen vorgesehen. Dieses Verfahren ist jedoch aufwendig und unfallträchtig.DE 43 24 516 A1 describes a powder stream with oxygen and fuel particles Cleaning of refractory surfaces provided. However, this process is complex and prone to accidents.

Die oben erwähnten gebräuchlichen mechanischen Arbeitsweisen zum Beseitigen von Schlacken- und Metallschichten sind folglich kostenintensiv bzw. unfallträchtig. Die im Feuerfestmaterial enthaltene abstrahlende Restwärme führt dazu, dass zu grob gearbeitet wird und ein großer Teil des unbeschädigten Grundmaterials zerstört oder zermürbt wird.The above-mentioned common mechanical procedures for removing Slag and metal layers are consequently cost-intensive or prone to accidents. The in Refractory residual heat contained in refractory material leads to working too roughly and a large part of the undamaged base material is destroyed or worn down becomes.

Der Erfindung liegt die Aufgabe zugrunde, ein neues Verfahren zum Entfernen von Schlacken- und Metallrückständen von Feuerfestoberflächen anzugeben, mit dessen Hilfe feuerfeste Oberflächen von Transportbehältern, Transportrinnen und dergleichen schonend und sicher von Schlacken- und Metallresten befreit werden können. Insbesondere soll das neue Verfahren gewährleisten, dass das Reinigungspersonal weder durch Hitzeeinwirkung noch durch umherfliegende Partikel, sei es der entfernten Schlacken- und Metallreste oder des darunterliegenden Feuerfestmaterials, gefährdet wird. Ferner soll das neue Verfahren eine vollständige Entfernung der Metall- und Schlackenreste von den Feuerfestoberflächen gewährleisten.The invention has for its object a new method for removing Specify slag and metal residues from refractory surfaces with which Help refractory surfaces of transport containers, transport channels and the like residues of slag and metal can be removed gently and safely. In particular The aim of the new procedure is to ensure that the cleaning staff neither due to heat or flying particles, be it the removed slag and metal residues or the underlying refractory material. The new process is also intended to completely remove the metal and slag residues guarantee from the refractory surfaces.

Diese Aufgabe wird durch das im Patentanspruch 1 angegebene Verfahren gelöst.This object is achieved by the method specified in claim 1.

Der mit Hilfe des Verfahrens erzielbare Fortschritt ergibt sich in erster Linie daraus, dass mit Hilfe des hochgespannten Wasserstrahls ein sicherer, den Feuerfest-Untergrund schonender Abtrag der zu entfernenden Schlacken- und Metallschichten von den Feuerfestoberflächen gewährleistet wird. Nach Abschluss des Reinigungsvorganges bieten die gereinigten Feuerfestoberflächen einen sicheren Haftgrund für aufzubringendes Reparaturmaterial.The progress that can be achieved with the method results primarily from that with the help of the high-tension water jet a safe, the refractory surface gentle removal of the slag and metal layers to be removed guaranteed by the refractory surfaces. After the cleaning process the cleaned refractory surfaces offer a secure base for sticking on Repair material.

Bevorzugte Ausführungsformen und vorteilhafte Ausgestaltungen des erfindungsgemäßen Reinigungsverfahrens sind in den Unteransprüchen angegeben.Preferred embodiments and advantageous configurations of the invention Cleaning procedures are specified in the subclaims.

Für das erfolgreiche Durchführen des erfindungsgemäßen Verfahrens soll die für die zu reinigenden Oberflächen beaufschlagende Wassermenge hinsichtlich Druck und Menge sorgfältig gewählt werden. Derzeit werden Wasserdrücke von mindestens 2 000 bar bevorzugt, wobei eine Wassermenge von etwa 15 bis 20 I je Minute in Form eines dünnen Strahles auf die zu reinigende, heiße Oberfläche gesprüht wird.For the successful implementation of the method according to the invention, the for amount of water that acts on the cleaning surfaces in terms of pressure and amount be chosen carefully. At present, water pressures of at least 2,000 bar preferred, with a water amount of about 15 to 20 l per minute in the form of a thin Sprayed onto the hot surface to be cleaned.

Der Wasserstrahl tritt aus einer Düse aus, die am Ende eines hinreichend langbemessenen Rohres sitzt, um Menschen oder Maschinen, welche das genannte Rohr handhaben, vor schädlicher Hitzeeinrichtung zu schützen.The water jet emerges from a nozzle, which at the end of a sufficiently long-dimensioned Tube sits around people or machines handling the said tube, Protect from harmful heat equipment.

Die in der Zeiteinheit aus der Düse gespritzte Wassermenge ist so gering gewählt, dass eine sofortige Umwandlung des Wassers in überhitzten Dampf erfolgt, wenn das Wasser auf die zu reinigende, heiße Oberfläche auftrifft. Durch die große, schlagartig eintretende Volumenänderung von flüssig zu gasförmig (d.h. von Wasser zu Wasserdampf) wird ein Sprengen der auf dem zu reinigenden Material anhaftenden, zu entfernenden Schichten herbeigeführt, was zur Folge hat, dass die zu entfernenden Schlacken- und Metallreste vom darunterliegenden Feuerfestmaterial abplatzen. The amount of water sprayed out of the nozzle in the unit of time is so small that An instant conversion of the water to superheated steam occurs when the water strikes the hot surface to be cleaned. Due to the large, sudden entry Volume change from liquid to gaseous (i.e. from water to water vapor) becomes a detonation of those to be removed adhering to the material to be cleaned Layers, which means that the slags to be removed and peel off metal residues from the underlying refractory material.

Der hohe Auftreffdruck des Spritzwassers auf der zu reinigenden Oberfläche übt ferner eine mechanische Abtragwirkung auf die zu entfernenden Oberflächenschichten und auf das darunterliegende, zerstörte, oberflächennahe Feuerfestmaterial aus.The high impact pressure of the spray water on the surface to be cleaned also exercises a mechanical removal effect on the surface layers to be removed and on the underlying, destroyed, near-surface refractory material.

In der Fachwelt bekannt und gefürchtet sind so genannte Wasserstoff-Explosionen, welche auftreten, wenn Wasser und Metallschmelzen zusammentreffen. Diese Explosionen treten beispielsweise auf, wenn eine Metallschmelze in ein Gefäß gegeben wird, auf dessen Boden sich Wasser angesammelt hat. Aus Angst vor der gegebenenfalls verheerenden Wirkung solcher Explosionen herrscht in der Fachwelt größte Ablehnung gegenüber Vorschlägen, Wasser in Bereichen zu verwenden, in welche Metallschmelzen gelangen können.So-called hydrogen explosions are known and feared among experts, which occur when water and molten metal meet. These explosions occur, for example, when a molten metal is placed in a vessel, on the bottom of which water has accumulated. Fearing the possibly The devastating effects of such explosions are rejected by experts against proposals to use water in areas where molten metal can reach.

Entgegen der Befürchtungen der Fachwelt entstehen beim Durchführen des erfindungsgemäßen Verfahrens jedoch keine solchen Explosionen, da der hochgespannte Wasserstrahl beim erfindungsgemäßen Verfahren lediglich in einer solchen Menge auf die zu reinigende Oberfläche gespritzt wird, dass das aufgesprühte Wasser sofort ohne Rückstand in Dampf umgewandelt wird. Auf diese Weise wird verhindert, dass sich Wasser im feuerfesten Mauerwerk oder dessen Umgebung ansammelt.Contrary to the fears of the professional world arise when performing the invention However, the process does not involve such explosions because of the high tension Water jet in the method according to the invention only in such an amount the surface to be cleaned is sprayed that the sprayed water immediately without Residue is converted into steam. This will prevent yourself from Water accumulates in the refractory masonry or its surroundings.

Das Beaufschlagen der zu reinigenden Oberfläche mit dem hochgespannten Wasserstrahl wird vorzugsweise so lange fortgeführt, bis sich auf dem feuerfesten Grundmaterial Riefen gebildet haben, die wiederum einen ausgezeichneten Haftgrund für das aufzubringende Reparaturmaterial bilden.The application of the surface to be cleaned with the high-tension water jet is preferably continued until it is on the refractory base material Grooves have formed, which in turn is an excellent basis for adhesion to the applied Form repair material.

Claims (4)

Verfahren zum Entfernen von Metall- und Schlackenrückständen von heißen Oberflächen, dadurch gekennzeichnet, dass Wasser mit einem Druck von mindestens 2000 bar aus einer oder mehreren Düsen in einer solchen Menge auf die zu reinigende Oberfläche gespritzt wird, dass das aufgesprühte Wasser sofort ohne Rückstand in Dampf umgewandelt wird.Process for removing metal and slag residues from hot surfaces, characterized in that water is sprayed at a pressure of at least 2000 bar from one or more nozzles onto the surface to be cleaned in such a quantity that the sprayed water immediately leaves no residue in steam is converted. Verfahren nach Anspruch 1, dadurch gekennzeichnet, dass 15 bis 20 I Wasser je Minute aus einer Düse auf die zu reinigende Oberfläche gespritzt werden.A method according to claim 1, characterized in that 15 to 20 l of water per minute are sprayed from a nozzle onto the surface to be cleaned. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, dass die Oberflächen von feuerfesten Werkstoffen von anhaftenden Metallund/Oder Schlackenschichten befreit werden.Method according to one of the preceding claims, characterized in that the surfaces of refractory materials are freed from adhering metal and / or slag layers. Verfahren nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass das Beaufschlagen der zu reinigenden Oberfläche mit dem hochgespannten Wasserstrahl so lange fortgesetzt wird, bis sich in dem von Metall- und/oder Schlacke befreiten Untergrund Riefen gebildet haben.Method according to one of claims 1 to 3, characterized in that the application of the high-tension water jet to the surface to be cleaned is continued until striations have formed in the substrate freed from metal and / or slag.
EP02013410A 2001-06-29 2002-06-12 Process for cleaning hot surface for deposits of metal or slag Withdrawn EP1273863A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE2001131646 DE10131646A1 (en) 2001-06-29 2001-06-29 Process for cleaning surfaces with hot metal and / or slag residues
DE10131646 2001-06-29

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EP1273863A1 true EP1273863A1 (en) 2003-01-08

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Cited By (2)

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Publication number Priority date Publication date Assignee Title
EP2118567A1 (en) * 2007-02-06 2009-11-18 Fuse Tech, Inc. Glass furnace cleaning system
WO2013148614A3 (en) * 2012-03-29 2014-03-20 Rohm And Haas Chemicals Llc Water resistant polymers for personal care

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DE102005022502B3 (en) * 2005-05-11 2006-09-21 Ise Innomotive Systems Europe Gmbh Removal process for hard welding slag involves blasting weld seam with water and 2000 bar and high throughput of at least 10 l/min

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WO2000047938A1 (en) * 1999-02-12 2000-08-17 Cetek Limited Cleaning using welding lances and blasting media

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US4193158A (en) * 1979-01-05 1980-03-18 Combustion Engineering, Inc. Soot blower for pressurized furnace
DE9402298U1 (en) * 1994-02-11 1994-04-21 Noell Abfall- Und Energietechnik Gmbh, 41464 Neuss Wet purifier
DE19847063A1 (en) * 1998-10-13 2000-04-20 Reinhold Terschluse Cleaning metal engine and machine parts involves prior or basic slide-grinding followed by finishing by highpressure water jet.
WO2000047938A1 (en) * 1999-02-12 2000-08-17 Cetek Limited Cleaning using welding lances and blasting media

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2118567A1 (en) * 2007-02-06 2009-11-18 Fuse Tech, Inc. Glass furnace cleaning system
EP2118567A4 (en) * 2007-02-06 2012-03-07 Fuse Tech Inc Glass furnace cleaning system
WO2013148614A3 (en) * 2012-03-29 2014-03-20 Rohm And Haas Chemicals Llc Water resistant polymers for personal care
CN104379123A (en) * 2012-03-29 2015-02-25 陶氏环球技术有限公司 Water resistant polymers for personal care
US9351916B2 (en) 2012-03-29 2016-05-31 Dow Global Technologies Llc Water resistant polymers for personal care
US9820929B2 (en) 2012-03-29 2017-11-21 Dow Global Technologies Llc Water resistant polymers for personal care

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