EP1266040A1 - A transfer member for imparting a finish leather - Google Patents

A transfer member for imparting a finish leather

Info

Publication number
EP1266040A1
EP1266040A1 EP99962502A EP99962502A EP1266040A1 EP 1266040 A1 EP1266040 A1 EP 1266040A1 EP 99962502 A EP99962502 A EP 99962502A EP 99962502 A EP99962502 A EP 99962502A EP 1266040 A1 EP1266040 A1 EP 1266040A1
Authority
EP
European Patent Office
Prior art keywords
layer
transfer member
layers
coat layer
combination
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP99962502A
Other languages
German (de)
French (fr)
Other versions
EP1266040B1 (en
Inventor
Pushpinder Kumar Kaushik
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Max India Ltd
Original Assignee
Max India Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Max India Ltd filed Critical Max India Ltd
Publication of EP1266040A1 publication Critical patent/EP1266040A1/en
Application granted granted Critical
Publication of EP1266040B1 publication Critical patent/EP1266040B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00—Surface finishing of leather
    • C14C11/003—Surface finishing of leather using macromolecular compounds

Definitions

  • This invention relates to a transfer member for treatment of leather so as to impart gloss properties thereto.
  • split leather was subjected to the step of lamination, pigmentation or transfer foil so as to upgrade or improve the quality of split leather.
  • split leather is impregnated with binder and waxes so that when compressed a release takes place from the plate. After impregnation it is then laminated, pigmented or treated with a transfer foil.
  • a disadvantage is that the fiber bundles do not get concealed and continue to be in a standing position.
  • An object of this invention is to propose a transfer member for treatment of leather and so as to impart gloss properties thereto.
  • Another object of this invention is to propose a transfer member for treatment of leather and so as to provide a uniform feel to leather.
  • Still another object of this invention is to propose a transfer member for treatment of leather and which provides good plate releasing properties.
  • Yet another object of this invention is to propose a transfer member for treatment of leather and which provides a good sealing of fibers.
  • a further object of this invention is to propose a transfer member for treatment of leather and which provides grain flatness.
  • Another object of this invention is to propose a transfer member for imparting a gloss together with a colour, print or metallic finish to leather.
  • a transfer member for imparting gloss properties to leather comprising a gloss film of at least two co- extruded layers and, wherein, the inner layer is the active or gloss layer and the outer layer is a colayer, a carrier or substrate layer releasably held to said outer layer.
  • the gloss film preferably comprises three coextruded layers and wherein the inner layer has the gloss properties, an intermediate layer is the colayer which contributes to the bulk properties of the film and further is a storage layer for the migratory chemicals, and an outer layer which is a colayer.
  • a carrier such as paper is adhered to the outer layer.
  • the inner layer comprises a resin layer of isotactic polypropylene singularly or in combination with random ethylene propylene copolymer present in an amount of 0 to 40% by weight.
  • the intermediate layer comprises isotactic polypropylene and migratory additives, which are antistatic and slip agents.
  • the outer layer also comprises isotatic polypropylene with an additive, which is an antiblock agent.
  • a stiffener such as paper is adhered to the outer layer by means of an adhesive.
  • the inner layer may additionally comprise migratory chemicals present in the amount of 0-5%, migratory chemicals being antistatic and slip agents selected from erucamide stearamide, silicon oil, stearic acid and stearates used singularly or in any combination thereof. Further, the inner layer may comprise an antiblock agent present in the amount of 500-4000 PPM. The antiblock agents are selected from silica, silicate, clay, talc and quartz comprising singularly or in any combination thereof. The haziness or glossy- ness of the inner layer is varied by changing the thickness of the inner layer and quantity of migratory chemicals and antiblock agents in the composition.
  • the migratory chemicals comprising said antistatic and slip agents are present in the amount of 500- 10000 PPM by weight in the intermediate layer.
  • the outer layer is identical to the inner layer and comprises isotatic polypropylene in combination with rendom co-polymer of ethylene propylene, and where ethylene propylene is present in the amount of 0 to 40% by weight.
  • the film further comprises a paper layer adhered to the outer layer.
  • the paper layer is a cellulosic paper such as cromo art paper and
  • the isotatic polypropylene present in the layers has an average molecular wt . of 25000 to 1 , 000 , 00 , a melt flow index of 1-25 at 230°C/2.16 kgs and density of 0.892 to 0.92.
  • an antiblock agent is provided in the outer layer.
  • the antiblock agent may or may not be provided in the outer layer.
  • an antiblock agent is provided in the outer and in the inner layer.
  • the outer layer may be subjected to a corona treat- ment, flame treatment or chemical treatment so as apply an adhesive thereon to secure a paper layer therewith.
  • the paper layer acts as a stiffener and absorbs excess heat during the plating of the leather.
  • the transfer member of the present invention has a thickness of 8 to 45 microns. If the thickness is greater than 45 microns, it does not affect the workability or properties of the film, but no advantages are derived therefrom and only adds to the end cost of the film. If the thickness is less than 8 microns, the required quality and properties are then not achieved. Both the inner and outer layers should have sufficient thickness in the instance of two layers film, in order to store and release the chemicals therefrom. Similarly, the inner, intermediate and outer layers should have sufficient thickness in an three layers structure for storage and release of said chemicals. Preferably, and without implying any limitation thereto the transfer member has a thickness of 12 to 45 microns.
  • the inner and intermediate layers have each a thickness of 2 to 8 microns and preferably a thickness of 2 to 5 microns. If the thickness of the inner layer is less than 2 microns, then gloss would reduce. If the thickness is more than 8 microns, and the outer, intermediate and inner layers are extruded then problems may arise in the coextrusion of the 1 ayer s .
  • the transfer member of the present invention also envisages a transfer member having a foil in addition to the gloss film, said foil being selected from a colour, print or metallized foil.
  • the transfer member comprises a carrier or substrate having the gloss ilm, the foil being provided on said film.
  • the foil comprises of a plurality of layers with at least an outermost layer being an adhesive layer adapted to contact the leather surface, an inner most layer being a release layer in contact with the film and an active layer provided therebetween, and wherein the active layer is either a print, colour or metallized layer.
  • the colour foil further comprises a feel modifier layer with or without top protecting coat layer on said release coating, said colorant layer provided onto said feel modifier layer.
  • the intermediate layers comprise a top coat layer on said release layer, said metallized layer being provided onto said top coat layer to provide metal finish to the leather.
  • the print foil intermediate layers comprise a feel modifier layer provide onto said release layer, a print coat layer provided onto said feel modifier layer.
  • a top coat layer may or may not be provided on said feel modifier layer.
  • the feelmodifier layer in itself comprises a plurality of layers.
  • the feel modifier layer comprises atleast two layers.
  • One of said layer is a mixture of feel modifiers and a top coat or feel modifier and cover coat.
  • the feel modifier layer comprises three layers namely a feel modifier layer adjacent to the release layer, a top coat layer adjacent to the feel modifier layer, and a covering layer adjacent the top coat layer.
  • the feel modifier layer comprises a combination of or only a single wax such as microcrys tal lene wax, paraffin, natural or synthetic waxes in solution or emulsion form.
  • the waxes incorporated in the feel modifier imparts a waxy feel to leather.
  • the feel modifier layer also comprises oils used singularly or in combination with polydialkyl siloxane, olefin modified siloxanes, diethylene modified silicon oils, epoxy modified silicon oils alcohol modified silicon oils.
  • the feel modifier layer comprises a combination of waxes and lubricants as this also improves the scuff resistance properties. If a waxy feel is required, then the content of waxes present in the feel modifier layer is greater than that of the lubricants. However, if a silky feel is required then the content of lubricants present in the feel modifier layer is greater than the waxes.
  • the feel modifier layer can consist of a combination of waxes and lubricants, or separate layers of waxes and lubricants.
  • the top coat layer is a protective coating for protecting the covering coat layer.
  • the coat layer consists of lacquer and lacquer emulsions of various resins, such as nitrocellulose copolymer of vinyl chloride and vinyl acetate, polyurethane and poly- amides with or without cross linking agents with or without fillers, such as silica.
  • the covering coat layer comprises essentially of natural resins such as shellac, caesin, albumin and gelatene or pi as t icizer s .
  • the covering coat layer may be selected from natural resins or synthetic resins such as acrylic, methacrylic, synthetic rubber, vinyl resin, nitrocellulose resins or polyurethane.
  • the natural resin may be present with the synthet i c resin.
  • the covering coat layer may also include colourents with or without dispersing agents, with or without cross linking or curing agents.
  • the colourants may be selected from metallic pigments, pearl pigments of organic or inorganic nature or dyestuffs.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Decoration By Transfer Pictures (AREA)
  • Laminated Bodies (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Gloves (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

A transfer member for imparting a finish to leather. The transfer member has at least a gloss film supported on a carrier so as to impart a gloss finish to leather. The transfer member may additionally comprise a foil on said film, said foil being either a colour, print or metallized.

Description

A TRANSFER MEMBER FOR IMPARTING A FINISH LEATHER
This invention relates to a transfer member for treatment of leather so as to impart gloss properties thereto.
PRIOR ART
It is generally known that hide is subjected to a chemical treatment to produce leather. However, if an appearance or finish is required, it was hitherto necessary to subject leather to an additional step of chemical treatment so as to impart a gloss appearance. It would be apparent that such a known process had the disadvantage of an additional step of chemical treatment.
A further disadvantage of the known art is that associated with split leathers. In accordance with the known art, split leather was subjected to the step of lamination, pigmentation or transfer foil so as to upgrade or improve the quality of split leather. Thus, split leather is impregnated with binder and waxes so that when compressed a release takes place from the plate. After impregnation it is then laminated, pigmented or treated with a transfer foil. A disadvantage is that the fiber bundles do not get concealed and continue to be in a standing position.
Yet another disadvantage is that of the chemical adhering to the plate.
OBJECTS OF THE INVENTION
An object of this invention is to propose a transfer member for treatment of leather and so as to impart gloss properties thereto.
Another object of this invention is to propose a transfer member for treatment of leather and so as to provide a uniform feel to leather.
Still another object of this invention is to propose a transfer member for treatment of leather and which provides good plate releasing properties.
Yet another object of this invention is to propose a transfer member for treatment of leather and which provides a good sealing of fibers.
A further object of this invention is to propose a transfer member for treatment of leather and which provides grain flatness.
Another object of this invention is to propose a transfer member for imparting a gloss together with a colour, print or metallic finish to leather.
DESCRIPTION OF INVENTION
According to this invention there is provided a transfer member for imparting gloss properties to leather comprising a gloss film of at least two co- extruded layers and, wherein, the inner layer is the active or gloss layer and the outer layer is a colayer, a carrier or substrate layer releasably held to said outer layer.
The gloss film preferably comprises three coextruded layers and wherein the inner layer has the gloss properties, an intermediate layer is the colayer which contributes to the bulk properties of the film and further is a storage layer for the migratory chemicals, and an outer layer which is a colayer. A carrier such as paper is adhered to the outer layer.
The inner layer comprises a resin layer of isotactic polypropylene singularly or in combination with random ethylene propylene copolymer present in an amount of 0 to 40% by weight. The intermediate layer comprises isotactic polypropylene and migratory additives, which are antistatic and slip agents. The outer layer also comprises isotatic polypropylene with an additive, which is an antiblock agent. A stiffener such as paper is adhered to the outer layer by means of an adhesive.
The inner layer may additionally comprise migratory chemicals present in the amount of 0-5%, migratory chemicals being antistatic and slip agents selected from erucamide stearamide, silicon oil, stearic acid and stearates used singularly or in any combination thereof. Further, the inner layer may comprise an antiblock agent present in the amount of 500-4000 PPM. The antiblock agents are selected from silica, silicate, clay, talc and quartz comprising singularly or in any combination thereof. The haziness or glossy- ness of the inner layer is varied by changing the thickness of the inner layer and quantity of migratory chemicals and antiblock agents in the composition.
The migratory chemicals comprising said antistatic and slip agents are present in the amount of 500- 10000 PPM by weight in the intermediate layer. The outer layer is identical to the inner layer and comprises isotatic polypropylene in combination with rendom co-polymer of ethylene propylene, and where ethylene propylene is present in the amount of 0 to 40% by weight. The film further comprises a paper layer adhered to the outer layer. The paper layer is a cellulosic paper such as cromo art paper and
2 having a granrmage of 30 to 100 gms/m .
The isotatic polypropylene present in the layers has an average molecular wt . of 25000 to 1 , 000 , 00 , a melt flow index of 1-25 at 230°C/2.16 kgs and density of 0.892 to 0.92.
As herein described above an antiblock agent is provided in the outer layer. However, in the instance of a film having three layers, the antiblock agent may or may not be provided in the outer layer. In accordance with another embodiment, an antiblock agent is provided in the outer and in the inner layer. The outer layer may be subjected to a corona treat- ment, flame treatment or chemical treatment so as apply an adhesive thereon to secure a paper layer therewith. The paper layer acts as a stiffener and absorbs excess heat during the plating of the leather.
The transfer member of the present invention has a thickness of 8 to 45 microns. If the thickness is greater than 45 microns, it does not affect the workability or properties of the film, but no advantages are derived therefrom and only adds to the end cost of the film. If the thickness is less than 8 microns, the required quality and properties are then not achieved. Both the inner and outer layers should have sufficient thickness in the instance of two layers film, in order to store and release the chemicals therefrom. Similarly, the inner, intermediate and outer layers should have sufficient thickness in an three layers structure for storage and release of said chemicals. Preferably, and without implying any limitation thereto the transfer member has a thickness of 12 to 45 microns.
The inner and intermediate layers have each a thickness of 2 to 8 microns and preferably a thickness of 2 to 5 microns. If the thickness of the inner layer is less than 2 microns, then gloss would reduce. If the thickness is more than 8 microns, and the outer, intermediate and inner layers are extruded then problems may arise in the coextrusion of the 1 ayer s .
In the following table the properties of the gloss film are given in comparison with the predetermined speci f icat ions .
COMPARISON PROPERTIES OF GLOSSY FILM
S.No. PROPERTIES UNIT SPEC ACTUAL SPEC ACTUAL
RESULTS RESULTS
1. AVG.GAUGE MICRONS 15 14.9 20 20.1
2. HAZE % 1.5 1.2 1.5 1.3 (MAX) (MAX)
3. GLOSS 95 98 95 97 (MIN) (MIN)
4. COEFFICIENT OF FRICTION STATIC 0 . 55 0.50 0.45 0.56 DYNAMIC 0.55 0.48 0.55 0.54 5. SHRINKAGE MD % 4.0 3.5 4.0 3.0
TM % 2.0 1.0 2.0 0 . 5 (MAX) (MAX)
TREATMENT DYNES/CM 38 40 38 40 (MIN) (MIN)
Reference has been made hereinabove to a transfer member comprising only the gloss film on a carrier or substrate. The transfer member of the present invention also envisages a transfer member having a foil in addition to the gloss film, said foil being selected from a colour, print or metallized foil.
In such an embodiment the transfer member comprises a carrier or substrate having the gloss ilm, the foil being provided on said film.
In each instance, the foil comprises of a plurality of layers with at least an outermost layer being an adhesive layer adapted to contact the leather surface, an inner most layer being a release layer in contact with the film and an active layer provided therebetween, and wherein the active layer is either a print, colour or metallized layer.
The colour foil further comprises a feel modifier layer with or without top protecting coat layer on said release coating, said colorant layer provided onto said feel modifier layer.
In the instance of a metallized transfer foil, the intermediate layers comprise a top coat layer on said release layer, said metallized layer being provided onto said top coat layer to provide metal finish to the leather. The print foil intermediate layers comprise a feel modifier layer provide onto said release layer, a print coat layer provided onto said feel modifier layer. A top coat layer may or may not be provided on said feel modifier layer.
The feelmodifier layer in itself comprises a plurality of layers. According to one embodiment, the feel modifier layer comprises atleast two layers. One of said layer is a mixture of feel modifiers and a top coat or feel modifier and cover coat.
According to another embodiment the feel modifier layer comprises three layers namely a feel modifier layer adjacent to the release layer, a top coat layer adjacent to the feel modifier layer, and a covering layer adjacent the top coat layer.
The feel modifier layer comprises a combination of or only a single wax such as microcrys tal lene wax, paraffin, natural or synthetic waxes in solution or emulsion form. The waxes incorporated in the feel modifier imparts a waxy feel to leather.
According to an embodiment the feel modifier layer also comprises oils used singularly or in combination with polydialkyl siloxane, olefin modified siloxanes, diethylene modified silicon oils, epoxy modified silicon oils alcohol modified silicon oils.
According to another embodiment the feel modifier layer comprises a combination of waxes and lubricants as this also improves the scuff resistance properties. If a waxy feel is required, then the content of waxes present in the feel modifier layer is greater than that of the lubricants. However, if a silky feel is required then the content of lubricants present in the feel modifier layer is greater than the waxes. The feel modifier layer can consist of a combination of waxes and lubricants, or separate layers of waxes and lubricants.
The top coat layer is a protective coating for protecting the covering coat layer. The coat layer consists of lacquer and lacquer emulsions of various resins, such as nitrocellulose copolymer of vinyl chloride and vinyl acetate, polyurethane and poly- amides with or without cross linking agents with or without fillers, such as silica.
The covering coat layer comprises essentially of natural resins such as shellac, caesin, albumin and gelatene or pi as t icizer s . Alternatively, the covering coat layer may be selected from natural resins or synthetic resins such as acrylic, methacrylic, synthetic rubber, vinyl resin, nitrocellulose resins or polyurethane. In accordance with another embodi- ment, the natural resin may be present with the synthet i c resin.
In accordance with yet another embodiment, the covering coat layer may also include colourents with or without dispersing agents, with or without cross linking or curing agents. The colourants may be selected from metallic pigments, pearl pigments of organic or inorganic nature or dyestuffs.

Claims

WE CLAIM:
1. A transfer member for imparting gloss properties to leather comprising a gloss film of at least two coextruded layers and, wherein, the inner layer is the active or gloss layer and the outer layer is a colayer, a carrier or substrate layer releasably held to said outer layer.
2. A transfer member as claimed in claim 1 wherein said gloss film comprises three layers being said inner layer, an intermediate layer and said outer 1 ayer .
3. A transfer member as claimed in claim 1 wherein the inner layer comprises isotatic polypropylene alone or in combination with random ethylene propylene 5 co-po 1 yme r present in the amount of 0 to 40% by weight, and optionally additives being antistatic and slip agents present in an amount of 0 to 5% by wt . , and optionally a further additive being an anti block agent present in an amount 500-4000 ppm by o weight of isotatic polypropylene.
4. A transfer member as claimed in claim 2 wherein the intermediate layer comprises isotatic polypropylene and said additives present in the amount of 500-10000 PPM by wt . of isotatic polypropylene.
5 5. A transfer membe r as c 1 a imed in claim 1 whe re i n the outer layer comprises isotatic polypropylene alone or in combination with randon ethylene propylene copolymer .
6. A transfer member as claimed in claims 1 to 5 0 wherein said antistatic and slip agents are selected from erucamide stearamide, silicon oil, stearic acid and stearates used singularly or in any combination thereof, said antiblock agents selected from silica, silicate clay, talc and quartz singularly or in any combination thereof.
7. A transfer member as claimed in claim 1 wherein the thickness each of said inner and outer layer is 2 to 8 microns .
8. A transfer member as claimed in claim 1 wherein the thickness of said member is 8 to 45 microns.
9. A transfer member as claimed in claim 1 comprising a foil provided on said film, said foil selected from a print, colour or metallized foil.
10. A transfer member as claimed in claim 9 wherein 5 each of said foils comprise a plurality of layers with at least an outermost layer being an adhesive layer adapted to contact the leather surface and inner most layer being a release layer in contact with the film and an active layer provided there- o between, and wherein the active layer is either a print, colour or metallized layer.
11. A transfer member as claimed in claim 10 wherein the print and colour foil has each a feel modifier 5 layer comprising a plurality of layers and wherein one of the layers is a feel modifier layer and the other layer is a top coat layer or a cover coat layer.
12. A transfer member as claimed in claim 10 wherein the print and colour foil has each a feel modifier 0 layer comprising a plurality of layers and wherein one of the layers is a feel modifier layer adjacent to the release coat, a top coat layer adjacent to the feel modifier layer, and a cover layer adjacent to the top coat layer.
13. A transfer member as claimed in claim 10 wherein the metallized foil includes a top coat layer on said release coat layer.
14. A transfer member as claimed in claims 11 and 12 wherein the feel modifier comprises a combination of or only a single wax such as mi crocrys tal 1 ene wax, paraffin, natural or synthetic waxes in solution or emu 1 s i on form.
15. A transfer member as claimed in claims 11 and 12 wherein the feel modifier layer also comprises oils used singularly or in combination with polydialkyl siloxane, olein modified siloxanes, dieth- ylene modified silicon oils, epoxy modified silicon oils alcohol modified silicon oils.
16. A transfer member as claimed in claims 11 and 12 wherein the feel modifier layer comp rises comb i na- tion of waxes and lubricants of separate layers of waxes and lubricants.
17. A transfer member as claimed in claim 11 to 13 wherein the top coat layer comprises lacquer and lacquer emulsions of various resins, such as nitrocellulose copolymer of vinyl chloride and vinyl acetate, polyurethane and polyamides with or without cross linking agents with or without fillers, such as si 1 ica.
18. A transfer member as claimed in claims 11 and 12 wherein the covering coat layer comprises essentially of natural resins such as shellac, caesin, albumin and gelatene or pi as t ici zer s .
19. A transfer member as claimed in claims 11 and 12 wherein the covering coat layer comprises synthetic resins such as acryliclic, methacrylic, synthetic rubber, vinyl resin, nitrocellulose resins or polyurethane or a combination of said natural and synthetic resins.
20. A transfer member as claimed in claims 11 and 12 wherein the covering coat layer may also include coiourents with or without dispersing agents, with or without cross linking or curing agents.
21. A transfer member as claimed in claim 13 wherein a print coat layer is provided between said metallized layer and top coat layer.
EP99962502A 1999-11-01 1999-11-01 A transfer member for imparting a finish leather Expired - Lifetime EP1266040B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IN1999/000058 WO2001032938A1 (en) 1999-11-01 1999-11-01 A transfer member for imparting a finish leather

Publications (2)

Publication Number Publication Date
EP1266040A1 true EP1266040A1 (en) 2002-12-18
EP1266040B1 EP1266040B1 (en) 2004-09-22

Family

ID=11076674

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99962502A Expired - Lifetime EP1266040B1 (en) 1999-11-01 1999-11-01 A transfer member for imparting a finish leather

Country Status (7)

Country Link
EP (1) EP1266040B1 (en)
CN (1) CN1177941C (en)
AT (1) ATE277201T1 (en)
DE (1) DE69920535T2 (en)
HK (2) HK1047962A1 (en)
TR (1) TR200201184T2 (en)
WO (1) WO2001032938A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2424256C2 (en) * 2006-08-04 2011-07-20 Плейтекс Продактс, Инк. Articles with good lubricating property, swab applicator, shaft and piston of swab applicator
JP5209280B2 (en) * 2007-11-20 2013-06-12 株式会社ジェイテクト Sealing device
CN104074057B (en) * 2014-06-26 2016-05-04 江苏宝泽高分子材料股份有限公司 A kind of use for synthetic leather variable color polishing agent and preparation method thereof
CN105755187A (en) * 2016-02-19 2016-07-13 北京泛博化学股份有限公司 Antistatic agent as well as preparation method and application thereof
CN111548241A (en) * 2020-06-28 2020-08-18 上海集瀛汽车安全技术有限公司 Novel gas generating agent for MGG

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS602989B2 (en) * 1977-08-01 1985-01-25 スコツト ペ−パ− コンパニ− Release sheet and its manufacturing method
DE3401677A1 (en) * 1984-01-19 1985-07-25 Oike Industrial Co., Ltd., Kyoto Transfer film
JPH05124394A (en) * 1991-11-07 1993-05-21 Toppan Printing Co Ltd Leather expression transfer foil

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0132938A1 *

Also Published As

Publication number Publication date
CN1177941C (en) 2004-12-01
DE69920535T2 (en) 2005-09-29
CN1375014A (en) 2002-10-16
HK1047962B (en) 2005-07-15
ATE277201T1 (en) 2004-10-15
WO2001032938A1 (en) 2001-05-10
TR200201184T2 (en) 2002-09-23
HK1047962A1 (en) 2003-03-14
DE69920535D1 (en) 2004-10-28
EP1266040B1 (en) 2004-09-22

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