548195 經濟部智慧財產局員工消費合作社印制农 A7 五、發明說明（1 ) 曼ϋ之拮術頜垃 本發明係有關一種用於皮革·處理之轉移元件，以對其 提供無光性質。 1·知技藝 一般已知生皮係經由一化學處理以產生皮革。然而， 右需要表面處理或外觀，則皮革需經過一個另外的化學處 理步驟，以提供一外觀或表面處理。顯而易見地，該已知 方法具有一相附加的化學處理步驟之缺點。 技藝中已知的另一個缺點，係與對開皮革有關。依據 習知技藝，對開皮革係經由層壓、著色或轉移箔材之步驟 以提昇或改良皮革品質。因而，對開皮革係以膠合劑與蠟 予以浸潰，使得當壓縮時自貼板產生剝離作用。在浸潰作 用之後，再將其層壓、著色或以轉移箔材處理。缺點之一 在於纖維束並未隱蔽起來，而持續位於立式姿勢。 另一個缺點在於化學物質黏著於貼板之上。 發明之目檁 本發明之一目標係倡議一種新的轉移元件構造，其可 有利地用於提供皮革一無光表面處理。 本發明之另一目標係倡議一種轉移元件，以提供皮革 一無光澤的以及彩色的、印染的或金屬化的表面處理。 本發明之另一目標係倡議一種轉移元件，以用於具有 適宜的貼板剝離性質之皮革應用。 本發明之另一目標係倡議一種轉移元件，以用於具有 本紙張尺度適用中國國家標準（CNS>A4規格（210 X 297公釐）548195 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. A7. V. Description of the invention (1) Manchu's jawbrush This invention relates to a transfer element for leather and processing to provide it with matt properties. 1. Know-how. It is generally known that hides are produced through a chemical treatment. However, if a surface treatment or appearance is required, the leather needs to undergo an additional chemical treatment step to provide an appearance or surface treatment. Obviously, this known method has the disadvantage of an additional chemical treatment step. Another disadvantage known in the art is related to split leather. According to the known art, the split leather is a step of laminating, coloring or transferring foil to improve or improve the quality of the leather. Therefore, the split leather is impregnated with an adhesive and wax, so that a peeling effect is generated from the veneer when compressed. After impregnation, they are laminated, coloured or treated with transfer foil. One of the disadvantages is that the fiber bundles are not concealed, but remain in an upright position. Another disadvantage is that the chemicals adhere to the board. OBJECTS OF THE INVENTION An object of the present invention is to propose a new transfer element construction which can be advantageously used to provide a matte surface treatment of leather. Another object of the invention is to propose a transfer element to provide a matte and colored, printed or metalized surface treatment of leather. Another object of the present invention is to propose a transfer element for leather applications having suitable board release properties. Another object of the present invention is to propose a transfer element for use with the paper size applicable to the Chinese national standard (CNS > A4 specification (210 X 297 mm)
;ί--------^---------線- (請先閱讀背，面之注意事項再填寫本頁) 4 A7; ί -------- ^ --------- line- (please read the back and front notes before filling out this page) 4 A7
548195 五、發明說明（2 ) 均一的觸感性質之皮革應用。 發明之詳細說明 如本發明提供一種用於提供皮革無光性質之轉移元件 ’其包括一基底或承載部件，其係以可剝離之方式支撐包 含至少三種樹脂之一無光薄膜，該樹脂係選自乙烯丙烯聚 合物、乙烯丙烯丁烯聚合物、高密度聚乙烯、等規立構聚 丙婦及添加劑。 如本發明的一個具體例，該無光薄膜包括一個作為活 性層之具有無光性質的内層，及一個作為共層之外層。 如另一個具體例，該無光薄膜較佳包括3個共擠壓層 ，及其中内層具有無光性質，中間層係為構成該薄膜的體 積性質與進一步為流動性化學物質的儲存層之一個共層， 及一個作為共層之外層。 如上述’内層包含至少三種樹脂之一組成物，該樹脂 係選自乙烯丙烯聚合物、乙烯丙烯丁烯聚合物、高密度聚 乙烯及等規立構聚丙烯。中間層包含等規立構聚丙烯以及 抗靜電劑與助滑劑之添加劑。外層亦包含等規立構聚丙稀 與抗阻滯劑。在外層係為一密封層之情況下，其則可包含 乙烯丙稀之無規共聚物，其中乙婦係以該共聚物之1至8部 份的量存在，及較佳為3至5部份。 用於内層之樹脂組成物包括10-30重量％之乙婦丙嫦 聚合物、0-50重量％之乙稀丙稀丁稀聚合物、25-65重量％ 之高密度聚乙烯及0-50重量％之等規立構聚丙烯。 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） •丨 — — — — — — — — — — I- . I I ! I I I — I!!!· (請^閱讀背面之注意事項再填寫本頁> 經濟部智慧財產局員工消費合作社印製 5 548195 經濟部智慧財產局員工消費合作社印製 A7 五、發明說明（3 ) 用於内層之組成物可附加地包括以〇·5 %之一量存在 的添加劑。該等添加劑可為移動性化學物質，諸如選自瓢 爾菜醯胺、硬脂醯胺、矽油、硬脂酸與硬脂酸酯之抗靜電 劑與助滑劑，其係單獨使用或以其任一的組合物使用。更 進步’用於内層之添加劑亦可包括以500-4000 ppm之一 1存在的抗阻滯劑。該抗阻滯劑係選自氧化矽、矽酸酯、 黏土、滑石及石英，其係單獨存在或以其任一的組合物存 在。該無光層之渾濁度係藉由變化該無光層的厚度及/或 内層組成物之添加劑的量，而加以改變。 該中間層包含等規立構聚丙稀與添加劑。該添加劑係 為以等規立構聚丙烯重量之500_1〇〇〇〇 ppm的量存在之抗 靜電劑與助滑劑。 如上述地，該外層包含等規立構聚丙烯與抗阻滯劑。 在外層係為一密封層之情況下，其則可包含乙烯丙烯之無 規共聚物，其中乙烯係以該共聚物之丨至8部份的量存在， 及較佳為3至5部份。該外層亦可單獨地或以與前述共聚物 之組合物方式包含乙烯丙烯丁烯聚合物。 存在於該寺層中之等規立構聚丙稀，其平均分子量為 25000至1，000,000，於2r之熔化流動指數為丨_25，而密度 為 0.892至 0.92。 如上述’在外層中具有抗阻滯劑。然而，在無光薄膜 僅包含外層與内層之情況下，在外層中可能不具有抗阻滯 劑。在無光薄膜包含外層、中間層及内層之情況下，較佳 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） ^--------^---------線 f 〆 > (請先閱讀背面之注意事項再填寫本頁) 6 548195 A7 五、發明說明（4 ) 在外層以及内層中具有抗阻滞劑。外層可能以電暈處理、 火焰處理或化學處理之活化作用 '步驟，加以處理。 如上述，當無光薄膜僅具有二層時，外層包含等規立 、構聚丙烯，及移動性化學物質係存在於該層中。 參照上述具有二或三個分離的層之無光薄膜。然而， 如另一個具體例，該無光薄膜並未含有分離的層，及該無 光薄膜係以該等樹脂與添加劑之單一混合物形成，然後將 其擠壓塗覆於一基底或承載部件上。 本發明之無光薄膜的厚度為8至45微米。若薄膜的厚 度大於45微米’其並不會影響該薄膜的可加工性或性質， 但亦未產生任何的優點，而僅增加該薄膜的最終成本。若 薄膜的厚度小於8微米，則無法達成所需的品質與性質。 在二層薄膜的情況下，外層與内層皆應具有足夠的厚度， 以自其儲存與釋出移動性化學物質。類似地，在三層薄膜 構造的情況下，外層、中間層與内層皆應具有足夠的厚度 ,以儲存與釋出該化學物質。較佳地，及在無意設限之下 ’該無光薄膜的厚度為12至30微米。 該外層與内層之厚度各為2至8微米，而較佳之厚度為 2至5微米。若内層之厚度小於2微米，則將降低渾濁度。 右厚度大於8微米，而且係將外層、中間層與内層擠壓時 ，則將在該等層之共擠壓物中產生問題。 參照上述於一承載部件或基底上僅包含一無光薄膜之 個轉移7C件。本發明之轉移元件在該無光薄膜之外，亦 本紙張尺I適用規格⑽X 297公楚 548195 M濟部智慧財產局員工消費合作社印制衣 A7 B7 五、發明說明（5 ) 規畫一箔材，該箔材係選自一彩色的、印染的或金屬化的 箔材。 在該具體例中，轉移元件包括一個具有無光薄膜之承 載部件或基底，而箔材係提供於該薄膜之上。 箔材之結構係依是否將彩色的、印染的或金屬化的性 質賦予皮革表面而定，而對各性質而言係提供各別的箔材 在各情況下，箔材至少包含數層，而最外層係一個適 於接觸皮革表面的黏著層，最内層係一個與薄膜接觸的剝 離層，而於其間係提供一活性層，其中該活性層係為一個 彩色的、印染的或金屬化層。 彩色箔材進一步在該剝離塗層上包含一個具有或不具 有表面保護塗層之觸感改良層，而在該觸感改良層上提供 該染色層。 在金屬化轉移箔材之情況下，夾於其間之層在該剝離 層上包含一個表面塗層，該金屬化層係提供於該表面塗層 之上，以提供皮革金屬表面處理。 印染落材的夾層，係在該剝離層上包含一個觸感改良 層，及在該觸感改良層上提供一個印染塗層。在該觸感改 良層上可具有或不具有一表面塗層。 觸感改良層本身包含數層。如一個具體例，觸感改良 層至少包含二層。該層之一係為觸感改良劑與一表面塗層 或觸感改良劑與覆蓋塗層之混合物。 (請^閱讀背*面之注意事項再填寫本頁) -ϋ ϋ ϋ ϋ ϋ ·1 ϋ^OJ· ϋ n mm— ϋ H ϋ I · - 8 經濟部智慧財產局員工消費合作社印製 548195 A7 _ B7 五、發明說明（6 ) 如另一個具體例，觸感改良層包含三層，分別為鄰近 剝離層之一個觸感改良層，鄰近觸感改良層之一個表面塗 層，及鄰近表面塗層之一個覆蓋層。 觸感改良層包含蠟的組合物或單一種蠟，諸如微晶瑕 、石蠟、溶液或乳化液形式的天然或合成蠟。在觸感改良 劑中納入該等蠟，以賦予皮革臘狀的觸感。 如一個具韹例，觸感改良層亦包含油類，其係單獨使 用或與聚《一烧基梦氧院、稀經改良型梦氧院、二乙稀改良 型石夕油、環氧基改良型石夕油、醇改良型石夕油併用。 如另一個具體例，觸感改良層包含蠟與潤滑劑之一組 合物，因其亦增進耐磨損性質。若需要臘狀的觸感，則存 在於觸感改良層中之蠟的含量高於潤滑劑的含量。然而， 若需要絲綢般的觸感，則存在於觸感改良層中之潤滑劑的 含里南於堰的含1。觸感改良層可包含壤與潤滑劑之一組 合物，或蠟與潤滑劑之分離的層。 表面塗層係一個保護塗層，用以保護該覆蓋塗層。塗 層包括各種樹脂之塗漆或塗漆乳化液，諸如氣乙烯或醋酸 乙烯酯之硝化纖維素共聚物、聚尿烷與聚醯胺，其具有或 不具有交聯劑’以及具有或不具有填料諸如氧化石夕。 覆蓋塗層實質包含天然樹脂，諸如蟲膠、酪蛋白、白 蛋白及明膠或塑化劑。另擇地，覆蓋塗層可選自天然樹脂 或合成樹脂，諸如丙烯酸樹脂、曱基丙烯酸樹脂、合成橡 膠、乙烯基樹脂、硝化纖維素樹脂或聚尿烷。如 個具 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公釐） — — — — — — — — — — — — — -111 — — — — ^ ·1111111· (請七閱讀背面之注意事項再填寫本頁) 9 _ 經濟部智慧財產局員工消費合作社印？衣 548195 a7 B7 五、發明說明（7 ) 體例，天然樹脂可與合成樹脂共同存在。 如另一個具體例，覆蓋塗層亦可包括著色劑，及具有 或不具有分散劑，以及具有或不具有交聯劑或熟化劑。該 著色劑可選自金屬色素、有機或無機性質的珍珠色素、或 染料。 在彩色箔材之情況下，該箔材的結構包含一個適於接 觸皮革接收表面之黏著劑外層，一個與該黏著層接觸之覆 蓋及/或彩色層，一個與該覆蓋及/或彩色層接觸及具有或 不具有表面保護塗層之觸感改良層，一個與該觸感改良層 接觸之剝離層。該彩色箔材具有無光薄膜。 在金屬化箔材之情況下，該箔材的結構包含一個適於 接觸皮革表面之黏著劑外層，一個與該黏著層接觸之金屬 化層，一個與該金屬化層接觸之表面塗層，一個與該表面 塗層接觸之剝離層，該無光薄膜係與該剝離層接觸。 藉由將轉移箔材通過一真空室及使金屬蒸汽澱積於表 面塗層上，而於該表面塗層上提供金屬化層。該金屬層之 厚度依熔化金屬與真空室之溫度、加工輥之溫度及金屬塗 層的光學密度而定。較佳，該金屬層之厚度為1 ·8-2.5光學 密度。 在需要耐磨損性質之情況下，可在表面塗層添加蠟及 /或潤滑劑，但僅為了賦予耐磨損性質而非觸感性質。另 擇地，可在剝離塗層添加蠟及/或潤滑劑。 如另一個具體例，在該表面塗層與剝離塗層之間，可 本紙張尺度適用中國國家標準（CNS)A4規格（210 X 297公爱） (請先閱讀背-面之注意事項再填寫本頁) >!1 訂！ I!線· 10 548195 經濟部智慧財產局員工消費合作社印製 A7 B7 五、發明說明（8 ) 提供一個分開的耐磨損性、濕式耐磨與乾式耐磨抗性塗層 〇 本發明規晝一轉移箔材之另一個具體例，其在該金屬 化層與表面塗層之間具有一印染塗層。該印染塗層包括單 色或多色之任何圖案或設計。可使用印刷著色塗漆。 在印染箔材之情況下，該箔材的結構包含一個適於接 觸皮革表面之黏著劑外層，一個與該黏著層接觸之印染塗 層’一個與該印染層接觸及具有或不具有覆蓋塗層之觸感 改良層，一個與該觸感改良層接觸之剝離層，該無光薄膜 係與該剝離層接觸。 如另一個具體例，該印染塗層係與該黏著層結合。 該印染塗層包括單色或多色之圖案或設計。可使用印 刷著色塗漆。 剝離塗層之厚度係介於卜3 GMS(克/平方公尺）之間（ 固態）。觸感改良層/表面保護層之厚度係為1_6〇1^8(固態） 。活性塗層之厚度係為1-5 GMS(固態），而黏著層之厚度 係為2-50 GMS(固態）。 在下列實例中，說明為外層/無光層所製備之組成物 〇 第1例 在一均質機之容器中加入70部份等規立構聚丙稀、2〇 部份乙烯丙烯聚合物、10部份高密度聚乙烯及2部份氧化 矽，將該内容物彼此混合而得一均質的摻合物。藉由使用 本紙張尺度適用中國國家標準（CNS)A4規格（210 χ 297公釐） — — I! t —1— $ (請先閲讀t面之注意事項再填寫本頁) 11 548195 A7 B7 經濟部智慧財產局員工消費合作社印製 五、發明說明（9 上述組成物作為一無光層，而使用一種雙轴向聚丙烤設備 以傳統方式製造一無光薄膜。· 發現下列的性質。 1·厚度-19微米 2·薄膜密度-0.91克/西西 3·渾濁度（最小值）-40% 4.光澤度（最大值）-40% 5·抗張強度 i )機器方向-1100公斤/平方公分 ϋ )橫向-2200公斤/平方公分 6·適用的熱範圍-H5至145°C(5.2巴，1秒）。 第2例 在一均質機之容器中加入40部份等規立構聚丙烯、5 部份乙烯丙烯聚合物、6部份乙烯丙烯丁烯聚合物、49部 份南後、度聚乙烯及1.2%添加劑（瓢爾菜醒胺），將該内容物 彼此混合而得一均質的摻合物。藉由使用上述組成物作為 一無光層，而使用一種雙軸向聚丙烯設備以傳統方式製造 一無光薄膜。 發現下列的性質。 1.厚度-25微米 2·薄膜密度-0.9克/西西 3·渾濁度（最小值）-80% 4·光澤度（最大值）_5% (請先閱讀背·面之注意事項再填寫本頁)548195 V. Description of the invention (2) Leather application with uniform tactile properties. DETAILED DESCRIPTION OF THE INVENTION As the present invention provides a transfer element for providing the matte nature of leather, which includes a substrate or a carrier member that peelably supports a matte film comprising one of at least three resins, the resin is selected From ethylene propylene polymer, ethylene propylene butene polymer, high density polyethylene, isotactic polypropylene and additives. As a specific example of the present invention, the matte film includes an inner layer having matte properties as an active layer, and an outer layer as a co-layer. As another specific example, the matte film preferably includes three co-extruded layers, and the inner layer has matte properties. The intermediate layer is one of the volume properties of the film and a storage layer that is further a fluid chemical substance. Co-layer, and one outer layer as co-layer. As described above, the 'inner layer contains a composition of at least one of three resins selected from the group consisting of ethylene propylene polymer, ethylene propylene butene polymer, high density polyethylene, and isotactic polypropylene. The middle layer contains isotactic polypropylene and additives for antistatic agents and slip agents. The outer layer also contains isotactic polypropylene and antiblocking agents. In the case where the outer layer is a sealing layer, it may contain a random copolymer of ethylene propylene, wherein the ethylenimine is present in an amount of 1 to 8 parts of the copolymer, and preferably 3 to 5 parts Serving. The resin composition for the inner layer includes 10-30% by weight of ethacene polymer, 0-50% by weight of styrene-butadiene polymer, 25-65% by weight of high-density polyethylene, and 0-50 Stereotactic polypropylene, etc. by weight. This paper size applies to China National Standard (CNS) A4 (210 X 297 mm) • 丨 — — — — — — — — — I-. II! III — I !!! · (Please read the notes on the back Please fill in this page again.> Printed by the Employees ’Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 5 548195 Printed by the Employees’ Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs A7. 5. Description of the invention (3) The composition for the inner layer may additionally include 〇 · Additives present in an amount of 5%. These additives may be mobile chemicals such as antistatic agents and slip agents selected from the group consisting of piramine, stearylamine, silicone oil, stearic acid and stearates. Agent, which is used alone or in any combination thereof. More advanced 'additives for the inner layer may also include antiblocking agents present at one of 500-4000 ppm. 1. The antiblocking agent is selected from Silica, silicate, clay, talc, and quartz, which exist alone or in any combination thereof. The turbidity of the matte layer is changed by changing the thickness of the matte layer and / or the composition of the inner layer. The amount of additives is changed. Contains isotactic polypropylene and additives. The additives are antistatic agents and slip aids present in an amount of 500-10,000 ppm by weight of isotactic polypropylene. As mentioned above, the outer layer contains isotactic Stereo polypropylene and anti-blocking agent. In the case where the outer layer is a sealing layer, it may contain a random copolymer of ethylene and propylene, wherein the ethylene is present in an amount of 8 to 8 parts of the copolymer, And preferably 3 to 5. The outer layer may also contain an ethylene propylene butene polymer alone or in a composition with the aforementioned copolymer. The isotactic polypropylene present in the temple layer, its average The molecular weight is 25,000 to 1,000,000, the melt flow index at 2r is 丨 _25, and the density is 0.892 to 0.92. As mentioned above, there is an anti-blocking agent in the outer layer. However, the matte film only contains the outer layer and the inner layer. In the case, there may be no anti-blocking agent in the outer layer. In the case that the matte film includes the outer layer, the middle layer and the inner layer, it is better that this paper size applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) ^ -------- ^ --------- line f 〆 > (Please read the notes on the back before filling this page) 6 548195 A7 V. Description of the invention (4) The anti-blocking agent is provided in the outer layer and the inner layer. The outer layer may be activated by corona treatment, flame treatment or chemical treatment The action 'step is processed. As described above, when the matte film has only two layers, the outer layer contains isotactic, structural polypropylene, and mobile chemicals are present in the layer. Refer to the above with two or three separations However, as another specific example, the matte film does not contain a separate layer, and the matte film is formed of a single mixture of the resin and the additive, and then extruded and coated. On a substrate or carrier. The matte film of the present invention has a thickness of 8 to 45 microns. If the thickness of the film is greater than 45 m ', it does not affect the processability or properties of the film, but it does not produce any advantages, but only increases the final cost of the film. If the thickness of the film is less than 8 microns, the required quality and properties cannot be achieved. In the case of a two-layer film, both the outer layer and the inner layer should have sufficient thickness to store and release mobile chemicals from it. Similarly, in the case of a three-layer thin film structure, the outer layer, the middle layer, and the inner layer should have sufficient thickness to store and release the chemical substance. Preferably, and under an unintentional limit, the thickness of the matte film is 12 to 30 m. The outer layer and the inner layer each have a thickness of 2 to 8 microns, and a preferred thickness is 2 to 5 microns. If the thickness of the inner layer is less than 2 microns, the turbidity will be reduced. The right thickness is greater than 8 microns, and when the outer layer, the middle layer, and the inner layer are squeezed, problems will occur in the co-extrusion of these layers. Refer to the above-mentioned transfer 7C member which contains only a matte film on a carrier member or substrate. The transfer element of the present invention is in addition to the matte film, and the paper rule I is also applicable to the specifications: X 297 Gongchu 548195 M. Ministry of Economic Affairs and Intellectual Property Bureau Employees' Clothing Cooperative Printing A7 B7 V. Description of the invention (5) Planning a foil The foil is selected from a colored, printed or metallized foil. In this specific example, the transfer element includes a carrier member or substrate having a matte film, and a foil is provided on the film. The structure of the foil depends on whether the colored, printed or metallized properties are imparted to the leather surface, and for each property a separate foil is provided. In each case, the foil contains at least several layers, and The outermost layer is an adhesive layer suitable for contacting the surface of the leather, the innermost layer is a release layer in contact with the film, and an active layer is provided therebetween, wherein the active layer is a colored, printed or metalized layer. The colored foil further includes a tactile-improving layer with or without a surface protective coating on the release coating, and the colored layer is provided on the tactile-improving layer. In the case of a metallized transfer foil, the intervening layer includes a surface coating on the release layer, and the metallization layer is provided on the surface coating to provide a leather metal surface treatment. The interlayer of printing and dyeing blanks comprises a tactile-improving layer on the release layer, and a printing and dyeing coating is provided on the tactile-improving layer. The touch-improving layer may or may not have a surface coating layer. The touch improvement layer itself includes several layers. As a specific example, the touch-improving layer includes at least two layers. One of the layers is a mixture of a touch modifier and a surface coating or a touch modifier and a cover coating. (Please read the precautions on the back side and fill in this page) -ϋ ϋ ϋ ϋ ϋ · 1 ϋ ^ OJ · ϋ n mm— ϋ H ϋ I ·-8 Printed by the Intellectual Property Bureau of the Ministry of Economic Affairs and Consumer Cooperatives 548195 A7 _ B7 V. Description of the invention (6) As another specific example, the touch-improving layer includes three layers, one is a touch-improving layer adjacent to the peeling layer, one is a surface coating adjacent to the touch-improving layer, and the adjacent surface is coating One of the overlays. The touch-improving layer comprises a wax composition or a single wax, such as a natural or synthetic wax in the form of microcrystalline flaws, paraffin, solution or emulsion. These waxes are incorporated in a touch improver to give a waxy feel to leather. As an example, the tactile improvement layer also contains oils, which are used alone or in combination with the polyoxymethylene-based dream oxygen hospital, the dilute modified dream oxygen hospital, the diethyl modified modified xixi oil, and epoxy groups. The modified Shixi oil and the alcohol-modified Shixi oil are used together. As another specific example, the touch-improving layer contains a combination of a wax and a lubricant because it also improves abrasion resistance. If a waxy touch is required, the content of wax in the touch improvement layer is higher than the content of the lubricant. However, if a silk-like touch is required, the lubricant containing Linan in the weir contained in the touch-improving layer 1 contains. The touch-improving layer may include a combination of soil and lubricant, or a separate layer of wax and lubricant. The surface coating is a protective coating to protect the cover coating. Coatings include painted or painted emulsions of various resins, such as nitrocellulose copolymers of gaseous ethylene or vinyl acetate, polyurethanes and polyamides, with or without a cross-linking agent, and with or without Fillers such as oxidized stone. The cover coat essentially contains natural resins such as shellac, casein, albumin, and gelatin or plasticizers. Alternatively, the cover coat may be selected from natural resins or synthetic resins, such as acrylic resins, acrylic resins, synthetic rubbers, vinyl resins, nitrocellulose resins, or polyurethanes. For each paper size, the Chinese National Standard (CNS) A4 specification (210 X 297 mm) is applicable. — — — — — — — — — — — — 111 — — — — ^ Read 1111111 on the back Please fill in this page for the matters needing attention) 9 _ Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs? Clothing 548195 a7 B7 V. Description of the invention (7) In general, natural resins can coexist with synthetic resins. As another specific example, the overcoat layer may also include a colorant, and with or without a dispersant, and with or without a crosslinking agent or a curing agent. The colorant may be selected from metallic pigments, pearl pigments of organic or inorganic nature, or dyes. In the case of a colored foil, the structure of the foil includes an outer layer of an adhesive adapted to contact the leather receiving surface, a covering and / or colored layer in contact with the adhesive layer, and a contact with the covering and / or colored layer And a touch-improving layer with or without a surface protective coating, and a peeling layer in contact with the touch-improving layer. This colored foil has a matte film. In the case of a metallized foil, the structure of the foil includes an outer layer of an adhesive adapted to contact the leather surface, a metallized layer in contact with the adhesive layer, a surface coating in contact with the metallized layer, a For the release layer in contact with the surface coating layer, the matte film is in contact with the release layer. A metallization layer is provided on the surface coating by passing the transfer foil through a vacuum chamber and depositing metal vapor on the surface coating. The thickness of the metal layer depends on the temperature of the molten metal and the vacuum chamber, the temperature of the processing roll, and the optical density of the metal coating. Preferably, the thickness of the metal layer is 1 · 8-2.5 optical density. Where abrasion resistance is required, waxes and / or lubricants may be added to the surface coating, but only to impart abrasion resistance and not tactile properties. Alternatively, wax and / or lubricant may be added to the release coating. As another specific example, between the surface coating and the release coating, the Chinese paper standard (CNS) A4 (210 X 297 public love) can be applied to this paper size. (Please read the back-to-side precautions before filling in This page) >! 1 Order! I! Line · 10 548195 Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs A7 B7 V. Description of the invention (8) Provide a separate abrasion resistance, wet abrasion and dry abrasion resistance coating. Another specific example of the day-to-day transfer foil has a printing coating between the metallization layer and the surface coating. The print coating includes any pattern or design in single or multiple colors. Can be printed with a printed tint. In the case of printing and dyeing foils, the structure of the foil includes an adhesive outer layer suitable for contacting the leather surface, a printing coating in contact with the adhesive layer ', a contact with the printing layer and with or without a cover coating A touch-improving layer, a release layer in contact with the touch-improving layer, and the matte film is in contact with the release layer. As another specific example, the printing and dyeing coating is combined with the adhesive layer. The printing and dyeing coating includes a single-color or multi-color pattern or design. Can be painted with a print. The thickness of the release coating is between 3 GMS (g / m²) (solid state). The thickness of the touch-improving layer / surface protection layer is 1_601 ^ 8 (solid state). The thickness of the active coating is 1-5 GMS (solid), and the thickness of the adhesive layer is 2-50 GMS (solid). In the following examples, the composition prepared for the outer layer / matt layer is illustrated. The first example is to add 70 parts of isotactic polypropylene, 20 parts of ethylene propylene polymer, and 10 parts in a container of a homogenizer. Parts of high-density polyethylene and 2 parts of silica, and the contents were mixed with each other to obtain a homogeneous blend. By using this paper size, the Chinese National Standard (CNS) A4 specification (210 χ 297 mm) is applicable — — I! T —1 — $ (Please read the precautions on the t side before filling out this page) 11 548195 A7 B7 Economy Printed by the Ministry of Intellectual Property Bureau's Consumer Cooperatives V. Invention Description (9 The above composition is used as a matte layer, and a biaxial polypropylene baking equipment is used to make a matte film in the traditional way. · The following properties were found. 1 · Thickness -19 microns 2 · Film density-0.91 g / Sicilian 3 · Haze (minimum) -40% 4.Gloss (maximum) -40% 5 · Tensile strength i) Machine direction -1100 kg / cm² ϋ) Transverse -2200 kg / cm2 6. Applicable thermal range -H5 to 145 ° C (5.2 bar, 1 second). The second example is to add 40 parts of isotactic polypropylene, 5 parts of ethylene propylene polymer, 6 parts of ethylene propylene butene polymer, 49 parts of South Hou, degree of polyethylene and 1.2 in a homogenizer container. % Additive (Spiral amine), the contents are mixed with each other to obtain a homogeneous blend. By using the above composition as a matte layer, a biaxial polypropylene apparatus is used to manufacture a matte film in a conventional manner. The following properties were found. 1.Thickness -25 microns 2 · Density of film-0.9g / Sisi 3 · Haze (minimum) -80% 4 · Gloss (maximum) _5% )
I I I I ! 1 訂· — I I I I I 12 548195 A7 B7_ 五、發明說明（l〇) 5.抗張強度 i )機器方向-1100公斤/平方公分 η )橫向-2200公斤/平方公分 6·適用的熱範圍-115至145°C(5.2巴，1秒）。 (請先閱讀背面之注意事項再填寫本頁) 經濟部智慧財產局員工消費合作社印製 本紙張尺度適用中國國家標準（CNS〉A4規格（210 X 297公釐） 13IIII! 1 Order · — IIIII 12 548195 A7 B7_ V. Description of the invention (10) 5. Tensile strength i) Machine direction-1100 kg / cm² η Transverse-2200 kg / cm² 6 · Applicable thermal range- 115 to 145 ° C (5.2 bar, 1 second). (Please read the precautions on the back before filling out this page) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs This paper applies Chinese national standards (CNS> A4 specification (210 X 297 mm) 13