EP1238146A1 - Procede et machine de fabrication de papier d'impression ou de carton - Google Patents

Procede et machine de fabrication de papier d'impression ou de carton

Info

Publication number
EP1238146A1
EP1238146A1 EP00931804A EP00931804A EP1238146A1 EP 1238146 A1 EP1238146 A1 EP 1238146A1 EP 00931804 A EP00931804 A EP 00931804A EP 00931804 A EP00931804 A EP 00931804A EP 1238146 A1 EP1238146 A1 EP 1238146A1
Authority
EP
European Patent Office
Prior art keywords
press
roll
shoe
web
nip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP00931804A
Other languages
German (de)
English (en)
Other versions
EP1238146B1 (fr
Inventor
Jorma Tapio Laapotti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Valmet Technologies Oy
Original Assignee
Metso Paper Oy
Valmet Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from SE9901754A external-priority patent/SE514097C2/sv
Application filed by Metso Paper Oy, Valmet Oy filed Critical Metso Paper Oy
Publication of EP1238146A1 publication Critical patent/EP1238146A1/fr
Application granted granted Critical
Publication of EP1238146B1 publication Critical patent/EP1238146B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00Press section of machines for making continuous webs of paper
    • D21F3/02Wet presses
    • D21F3/04Arrangements thereof
    • D21F3/045Arrangements thereof including at least one extended press nip
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F3/00Press section of machines for making continuous webs of paper
    • D21F3/02Wet presses
    • D21F3/04Arrangements thereof

Definitions

  • the present invention relates to a method for manufacturing printing paper or paperboard with a grammage of 30-200 g/m 2 in a paper or paperboard machine, comprising a wet section, a press section and a drying section, in which method a web, formed in the wet section, is pressed in a roll press with a double-felted roll-press nip and, thereafter, in a shoe press with an extended single or double-felted shoe-press nip.
  • the invention also relates to a paper or paperboard machine for manufacturing printing paper or paperboard at high speed, which printing paper or paperboard has a grammage of 30-200 g/m 2 , comprising a wet section, a press section and a drying section, which press section includes a roll press, having a double-felted roll-press nip, and a shoe press, having an extended single or double-felted shoe-press nip.
  • US-4,561,939 describes a paper machine with a press section, consisting of a double-felted roll press and a double-felted shoe press.
  • the roll press is of a conventional type having grooved rolls with rigid envelope surfaces. Such a configuration precludes high web speeds.
  • a suction shoe is arranged in the loop of the lower press felt, which suction shoe is intended to act so that the web accompanies the lower press felt. At high speeds, however, such a suction shoe cannot ensure such behaviour of the web.
  • the suction shoe is an important element in the press section, according to this patent specification, which therefore does not disclose or suggest other suction devices to ensure the correct web behaviour at high speeds.
  • Said specification employs a suction shoe after the second double-felted press nip as well, which therefore contributes to a further limitation of this known paper machine in respect of web speed.
  • Said patent specification is limited to a double-felted shoe press for the second press nip and, thus, it does not disclose a transfer belt to replace one of the press felts to enable a secure web run and, thereby, higher speeds. Neither does it recognize the possibility of operating with a transfer belt at very high speeds and obtaining good dry-solids content also for mechanical pulp, which is used for manufacturing newsprint, LWC base paper and SC paper.
  • the known paper machine further lacks blowing boxes that generate partial vacuums to secure the firm attachment of the web to the press felt so as to enable high speeds, which result in strong air flows, which can easily detach the web from the press felt.
  • the object of the present invention is to provide an improved method and an improved paper or paperboard machine that enables the manufacture of printing paper or paperboard at very high speeds and that further enables high efficiency and a great increase in productivity.
  • the method in accordance with the invention, is characterized in that - the web is pressed in a deflection-compensating roll press, having said double-felted roll-press nip and open press rolls,
  • the machine is operated at a web speed of at least 1,200 m/min.
  • the web in said roll-press nip is subjected to a linear load ranging from 100 to 300 kN/m, preferably from 120 to 250 kN/m, and a specific pressure ranging from 5 to 15 MPa, preferably from 8 to 11 MPa,
  • the web in said shoe-press nip is subjected to a linear load ranging from 500 to 1,500 kN/m, preferably from 700 to 1,200 kN/m, and a specific pressure ranging from 4 to 13 MPa, preferably from 4 to 8 MPa, - to obtain a dewatered web with a dry-solids content of at least 35 per cent, preferably at least 38 per cent, after the roll-press nip and at least 45 per cent after the shoe-press nip.
  • the paper or paperboard machine in accordance with the invention, is characterized in that the roll press has open press rolls with deflection-compensating, rotatably journalled envelope surfaces and in that the machine is arranged to be operated at a web speed of at least
  • Figure 1 shows schematically parts of a machine, in accordance with a first embodiment of the invention, for manufacturing a web of cellulosic fiber material .
  • Figure la shows parts of a press section, modified in relation to the one in the machine in accordance with Figure 1.
  • Figure 2 shows schematically parts of a machine, in accordance with a second embodiment of the invention.
  • Figure 3 shows schematically parts of a machine, in accordance with a third embodiment of the invention.
  • Figure 3a shows parts of a machine, the press section of which is modified in relation to the one in the machine in accordance with Figure 3.
  • Figure 4 shows schematically parts of a machine, in accordance with a fourth embodiment of the invention.
  • FIG. 5 shows in detail the special roll press that forms part of the embodiments shown in accordance with Figures 1-4.
  • FIGS 1-4 show schematically parts of paper or paperboard machines for manufacturing printing paper or paperboard in a continuous web W.
  • Each of the machines comprises a wet section 1, a press section 2 and a drying section 3.
  • the wet section 1, of which the downstream part alone is shown, comprises a forming wire 4, running in a loop around guide rolls 5.
  • a suction roll 46 is arranged in the loop of the forming wire 4 immediately upstream of a pick-up point .
  • Such a suction roll is not always used in wire parts of more recent design, as illustrated in Figures 2-4.
  • the drying section 3 comprises a plurality of drying cylinders 7 and rolls 8, which can be grooved rolls or blind-drilled rolls, as shown, or, alternatively, smooth rolls or conventional suction rolls with or without an inner suction box with sealing devices (in the latter case with interior vacuum) or so-called "Vac" rolls, which have grooves, holes in the grooves and a partial vacuum inside the roll.
  • the press section 2 comprises a double-felted roll press 9 and, downstream of the roll press 9, a shoe press 10, which can be a single-felted shoe press in accordance with Figures 1 and 3 or a double-felted shoe press in accordance with Figures 2 and 4.
  • the roll press 9 comprises an open upper press roll 11 and an open lower press roll 12, which press rolls 11, 12 co-operate with each other to create a roll-press nip between them. Further, the roll press 9 comprises an upper endless press felt 13, upper felt, running in a loop through the roll-press nip around a plurality of guide rolls 14, and a lower endless press felt 15, lower felt, running in a loop through the roll-press nip around a plurality of guide rolls 16.
  • the upper felt 13 of the roll press acts as a pick-up felt and has, in its loop, a pick-up suction roll 18, arranged in close proximity to the forming wire 4 to transfer the web W from the forming wire 4 to the upper felt 13.
  • the lower felt 15 acts as the transfer felt, carrying the web W from the roll-press nip to the shoe press 10, whilst in the embodiments in accordance with Figures 3 and 4, the upper felt 13 acts as the transfer felt.
  • blowing boxes generating partial vacuum or suction boxes 17 are arranged downstream of the press nip within the zone where the press felt 13 or 15, respectively, carries the web W.
  • a suction roll 6 is additionally arranged in the loop of the lower felt 15 at a point downstream of the roll-press nip where the press felts 13, 15 diverge from each other, the suction roll 6 ensuring that the web W accompanies the lower felt 15.
  • a steam box 19 is arranged in proximity to the outside of the upper felt 13 downstream of the pick-up suction roll 18 for favourable conditioning of the web W with steam before its pressing in the first press nip.
  • the shoe press 10 comprises a shoe-press roll 20 and a counter roll 21, which rolls 20, 21 co-operate with each other to create an extended shoe-press nip.
  • the shoe press 10 further comprises a first, endless press clothing 22 in the shape of a press felt, running in a loop through the extended shoe-press nip around the shoe-press roll 20, around a plurality of guide rolls 23 and around a pick-up suction roll 24, which is arranged in close proximity to the web-carrying lower felt 15 or upper felt 13, respectively, of the roll press 9 to remove and transfer the web W from the web-carrying lower felt 15 or upper felt 13, respectively, of the roll press 9 to the press felt 22 of the shoe press 10, allowing the press felt 22 of the shoe press 10 to act as a pick-up felt as well.
  • Blowing boxes generating partial vacuum or suction boxes 25 are arranged in the loop of the press felt 22 of the shoe press 10, downstream of the pick-up suction roll 24, to retain the web W on the outside of the press felt 22 of the shoe press 10 before the extended shoe press nip.
  • the loop of the press felt 22 accommodates a suction roll 30 downstream of the extended press nip and a subsequent blowing box that generates a partial vacuum or suction box 31.
  • the shoe press 10 further comprises a second, endless press clothing 26, running in a loop through the extended shoe-press nip around the counter roll 21 and around a plurality of guide rolls 27.
  • the second press clothing 26 is a press felt 26a, whilst in the embodiments in accordance with Figures 1 and 3, it is an impermeable or substantially impermeable transfer belt 26b having a smooth web-contacting surface.
  • the first press clothing i.e.
  • the press felt 22, in the loop of which the shoe-press roll 20 is located is arranged in a top position (as is the shoe-press roll 20) in the embodiments in accordance with Figures 1 and 2, whilst it is arranged in a bottom position (as is the shoe-press roll 20) in the embodiments in accordance with Figures 3 and 4.
  • a suction roll 28 and a subsequent blowing box generating partial vacuum or suction box 29 are situated downstream of the extended press nip in the loop of the press felt 26a, which accommodates the counter roll 21.
  • the counter roll 21 of the shoe press 10 is shown as a grooved roll or a blind-drilled roll.
  • the counter roll is a smooth roll.
  • the web W is transferred from the lower felt 15 of the roll press 9 to the upper felt 22 of the shoe press 10, whilst in the embodiments in accordance with Figures 3 and 4, the web W is transferred from the upper felt 13 of the roll press 9 to the lower felt 22 of the shoe press 10.
  • the lower clothing 26 of the shoe press 10, in the embodiments in accordance with Figures 1 and 2 , and the lower clothing 22 of the shoe press 10, in the embodiment in accordance with Figure 4 , are arranged to carry the web W after the extended shoe-press nip up to the drying section 3; whilst, in the embodiment in accordance with Figure 3, the upper clothing 26 of the shoe press 10 in the form of the transfer belt 26b is arranged to carry the web W after the extended shoe-press nip.
  • the drying section 3 comprises an endless, permeable drying clothing 32 in the form of a mesh dryer or dryer felt, running in a loop around a plurality of guide rolls 33, the drying cylinders 7 and the rolls 8.
  • the mesh dryer or the dryer felt 32 also runs around a pick-up suction roll 34, arranged in close proximity to the lower clothing 22 alternatively 26a or 26b of the shoe press 10 so that the pressed web W is transferred from the lower clothing 22 alternatively 26a or 26b to the mesh dryer or dryer felt 32.
  • Blowing boxes generating partial vacuum or suction boxes 35 are arranged in suitable locations in the loop of the mesh dryer or dryer felt 32.
  • the embodiment in accordance with Figure 3 employs a separate, endless pick-up clothing 36, which can be a wire or a felt and which runs in a loop around a plurality of guide rolls 37 and a pick-up suction roll 38, arranged in close proximity to the second press clothing 26 of the shoe press 10, i.e. the transfer belt 26b, to transfer the pressed web W from the transfer belt 26b to the pick-up clothing 36.
  • a blowing box generating partial vacuum or suction box 39 is arranged downstream of the pick-up suction roll 38 in the loop of the pick-up wire or pick-up felt 36.
  • the first upstream roll 8 in the drying section is arranged in close proximity to the pick-up wire or pick-up felt 36 so that the pressed web W is transferred from the pick-up wire or pick-up felt 36 to the mesh dryer or dryer felt 32.
  • a steam box 40 is arranged in a free space, where the underside of the web W is exposed, situated between the lower felt 15 of the roll press 9 and the lower clothing 22 or 26, respectively, of the shoe press 10, in close proximity either to the upper felt 13 of the roll press 9 in accordance with Figure 3, for instance, or to the upper clothing 26 or 22, respectively, of the shoe press in accordance with Figure 1.
  • Designation number 41 denotes suitable equipment for conditioning the press felts 13, 15, 22, 26a.
  • the press section has a closed web run from the wet section to the drying section and provides good runability for all grades of printing paper as well as enabling very high operating speeds.
  • the press section has two press nips optimized to achieve good runability and dry-solids content.
  • the suction roll and the blowing boxes after the roll nip result in good runability.
  • the second press nip is a shoe-press nip where a very high nip load can be used and a very high dry-solids content can be achieved.
  • suction rolls are present to ensure that the web is transferred from one clothing to another, as well as blowing boxes generating partial vacuum or suction boxes to ensure that the web is retained adhered to the clothing. These measures, furthermore, contribute to good runability and enabling operation at very high speeds without web ruptures occurring.
  • the partial vacuum in the suction roll 6 is in the range of about 10-30 kPa, in the suction roll 24 about 15-40 kPa and in the suction roll 28 about 10-30 kPa, if this is used.
  • the partial vacuum in the suction roll 34 is in the range of about 15-40 kPa.
  • the blowing boxes 17, 25, 29 generating partial vacuum provide a partial vacuum of about 300-1,000 Pa.
  • a web transfer of the type shown in Figures 3 and 4 for transferring the web from the roll press to the shoe press is particularly suitable for manufacturing paperboard, as there are open, wedge-shaped gaps after the roll-press nip and before the shoe-press nip.
  • Figure la shows parts of a press section similar to the one in the machine in accordance with Figure 1, but with a modified configuration of the shoe press 10 in respect of the run of the lower press clothing 26, i.e. the transfer belt 26b, relative to the upper felt 22 before the extended shoe-press nip.
  • the guide roll 27a located nearest to the shoe-press nip is elevated and arranged close to the upper felt 22 so that, in the direction away from the elevated guide roll 27a, the transfer belt 26b runs in contact with the upper felt 22, enclosing the web W between them to form a sandwich construction.
  • An additional guide roll 23a is arranged in the loop of the upper felt 22 at the position of said elevated guide roll 27a to create a nip not compressing the web.
  • the shoe press in the machine in accordance with Figure 2 can be modified in the same way as shown in Figure la.
  • the use of such a sandwich construction, which follows after the steam box 40, means that the distance between the web W and the steam box 40 becomes very precise.
  • the number of blowing boxes generating partial vacuum or suction boxes 25 can, in the embodiment shown in Figure la, be reduced to a single one.
  • Figure 3a shows part of a machine similar to the one in accordance with Figure 3, but with a modified configuration of the roll press 9 and the shoe press 10 in respect of the run of the lower press clothings 15, 22 and the upper press clothings 13, 26 relative to each other after and before the press nip.
  • a suction roll 47 is arranged downstream of the roll-press nip to guide the upper felt 13 into contact with the lower felt 15 so that the upper and lower felts 13, 15 and the web W enclosed therebetween form a sandwich construction after the roll-press nip.
  • a web run of the type shown in Figure 3a for conveying the web from the roll-press nip to the shoe-press nip is particularly suitable for manufacturing printing paper at high speeds, as the open, wedge-shaped gaps after the roll-press nip and before the shoe-press nip have been eliminated.
  • the press rolls of the roll press are of the deflection-compensating type, as illustrated in detail in Figure 5.
  • Each press roll has a rotatable envelope surface 42 and an inner, static I-shaped beam 43, extending axially between the end walls and supporting an elongate shoe member 44 that comprises a plurality of hydrostatic and hydrodynamic slide shoes, arranged in a row and hydraulically loaded between the I beam 43 and the envelope surface 42 by way of power cylinders 45, a thin film of oil being maintained between each slide shoe and the inside of the envelope. Thanks to such a construction, the vibrations in the press rolls are damped in a very effective manner.
  • the two shoe members 44 act against the insides of the envelope surfaces within the roll-press nip and can be controlled section by section in relation to each other to compensate for deflections in the envelope surfaces of the press rolls.
  • the press rolls are blind-drilled or grooved.
  • the envelope surface of each press roll has an outer layer of steel, exhibiting grooves with a width of about 0.5 mm, for instance, and a depth of about 5 mm, for instance, the cc distance between two adjacent parallel grooves being about 2.25 mm, for instance.
  • the grooved press roll has a very large aggregate groove volume, namely 1.1 dm 3 /m 2 of envelope surface with the specified groove values.
  • Such a high groove volume has been found to be favourable for avoiding streams of water and crushing.
  • the narrowness of the grooves (0.5 mm) avoids groove markings in the web.
  • the grooved layer is made of steel, the groove volume remains constant during pressing even at very high linear loads in the roll-press nip.
  • the described properties of the press rolls therefore contribute to high web speeds being feasible and high levels of dry-solids content being obtained already after the first press nip without the web being crushed.
  • the aggregate groove or void volume is in the range of 0.7-1.8 dm 3 /m 2 of envelope surface .
  • the linear load in the roll-press nip is in the range of 100-300 kN/m, preferably 120-250 kN/m, and in the shoe-press nip 500-1,500 kN/m, preferably 700-1,200 kN/m.
  • the specific pressure in the roll-press nip is in the range of 5-15 MPa, preferably 8-11 MPa, and in the shoe-press nip 4-13 MPa, preferably 4-8 MPa.
  • the dry-solids content of the web after the wet section is generally in the range of 15-22 per cent, depending on the type of printing paper, the dry-solids content for fine paper normally being 18-22 per cent, for newsprint and LWC base paper, 16-18 per cent, and for SC paper, 15-17 per cent.
  • the web speed is currently generally in the range of 1,200-1,700 m/min. depending on the type of printing paper, amongst other factors, the speed for fine paper in modern paper machines and press sections typically being about 1,200-1,500 m/min., for newsprint about 1,300-1,700 m/min., for LWC base paper about 1,400-1,600 m/min. and for SC paper about 1,400-1,600 m/min.
  • the shoe press 10 is preferably provided with a transfer belt, which is more favourable in the bottom position, i.e. in accordance with Figure 1.
  • Fine paper Chemical pulp, filler content about 12-18 per cent, filler usually calcium carbonate, grammage 40-200 g/m 2 .
  • SC paper Mechanical pulp 70-80 per cent and chemical pulp 30-20 per cent, kaolin filler about 30 per cent, grammage about 42-56 g/m 2 .
  • LWC base paper Mechanical pulp 55-60 per cent, chemical pulp 45-40 per cent, filler about 5-15 per cent, grammage 33-45 g/m .
  • Type of printing paper LWC base paper
  • Linear load in 1st press 200 kN/m
  • Linear load in 2nd press 1,000 kN/m Specific pressure in 1st press; 9.0 MPa Specific pressure in 2nd press 6.2 MPa
  • Linear load in 1st press 250 kN/m
  • Linear load in 2nd press 1,200 kN/m Specific pressure in 1st press; 10.0 MPa Specific pressure in 2nd press: 7.5 MPa
  • a press section with a first press in the shape of a double-felted roll press and a second press in the shape of a shoe press constitute a cheaper configuration than a press section with two shoe presses.
  • the first roll press provides very good levels of dry-solids content with linear loads in the roll -press nip of 120-250 kN/m, which in some cases is much better than is provided by a shoe press with a linear load of
  • the described deflection-compensating, open press rolls in top and bottom positions very effectively prevent vibrations that constitute a problem with ordinary, solid press rolls when the linear load and the web speed are high.
  • the two deflection-compensating, open press rolls described have their shoe members acting against each other and the stresses on the envelope surfaces of the press rolls will therefore be low at high linear loads in the roll-press nip.
  • the deflection-compensating, open press rolls do not require cambering and therefore the CD profile in the roll-press nip can be controlled so that it becomes very straight. Furthermore, the moisture profile of the press felts will be good and the service life of the felts will increase.

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  • Paper (AREA)
EP00931804A 1999-05-14 2000-05-02 Procede et machine de fabrication de papier d'impression ou de carton Expired - Lifetime EP1238146B1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
SE9901754A SE514097C2 (sv) 1999-05-14 1999-05-14 Sätt och maskin för framställning av tryckpapper eller kartong
SE9901754 1999-05-14
US13963499P 1999-06-17 1999-06-17
US139634P 1999-06-17
PCT/SE2000/000826 WO2000070142A1 (fr) 1999-05-14 2000-05-02 Procede et machine de fabrication de papier d'impression ou de carton

Publications (2)

Publication Number Publication Date
EP1238146A1 true EP1238146A1 (fr) 2002-09-11
EP1238146B1 EP1238146B1 (fr) 2005-02-23

Family

ID=26663571

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00931804A Expired - Lifetime EP1238146B1 (fr) 1999-05-14 2000-05-02 Procede et machine de fabrication de papier d'impression ou de carton

Country Status (7)

Country Link
EP (1) EP1238146B1 (fr)
JP (1) JP4494651B2 (fr)
AT (1) ATE289643T1 (fr)
CA (1) CA2373205C (fr)
DE (1) DE60018304T2 (fr)
ES (1) ES2237428T3 (fr)
WO (1) WO2000070142A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6730192B1 (en) 1999-05-14 2004-05-04 Metso Paper, Inc. Method and machine for manufacturing printing paper or paperboard
FI113973B (fi) * 1999-12-02 2004-07-15 Metso Paper Inc Menetelmä rainan tukemiseksi ja rainantuentalaite
DE10249040A1 (de) * 2002-10-22 2004-05-19 Voith Paper Patent Gmbh Übergabeanordnung
JP5755721B2 (ja) * 2005-06-20 2015-07-29 大王製紙株式会社 塗工紙の製造方法及びその製造設備

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4561939A (en) * 1984-03-26 1985-12-31 Beloit Corporation Extended nip press arrangement
JPS63501433A (ja) * 1986-04-29 1988-06-02 ベロイト・コーポレイション 可動ウエブをプレスするプレス装置及び方法
BR8806893A (pt) * 1987-04-14 1989-10-31 Voith Gmbh J M Maquina para fabricar folhas de massa fibrosa
FI96789C (fi) * 1990-11-23 1996-08-26 Valmet Paper Machinery Inc Menetelmä ja laite veden poistamiseksi paperiradasta puristamalla
US5639351A (en) * 1991-12-23 1997-06-17 Valmet Corporation Press section of a paper machine, in particular for printing paper qualities
FI98843C (fi) * 1995-10-03 1997-08-25 Valmet Corp Menetelmä ja laite veden poistamiseksi paperi- tai kartonkiradasta puristamalla
JP3765149B2 (ja) * 1996-02-29 2006-04-12 王子製紙株式会社 パルプ、紙及び塗被紙

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0070142A1 *

Also Published As

Publication number Publication date
ES2237428T3 (es) 2005-08-01
ATE289643T1 (de) 2005-03-15
EP1238146B1 (fr) 2005-02-23
WO2000070142A1 (fr) 2000-11-23
DE60018304T2 (de) 2006-04-13
CA2373205C (fr) 2006-11-28
JP2002544408A (ja) 2002-12-24
CA2373205A1 (fr) 2000-11-23
DE60018304D1 (de) 2005-03-31
JP4494651B2 (ja) 2010-06-30

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