EP1195642A3 - Silver halide photographic material and image-forming system in direct X-ray imaging applications - Google Patents

Silver halide photographic material and image-forming system in direct X-ray imaging applications Download PDF

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Publication number
EP1195642A3
EP1195642A3 EP01000462A EP01000462A EP1195642A3 EP 1195642 A3 EP1195642 A3 EP 1195642A3 EP 01000462 A EP01000462 A EP 01000462A EP 01000462 A EP01000462 A EP 01000462A EP 1195642 A3 EP1195642 A3 EP 1195642A3
Authority
EP
European Patent Office
Prior art keywords
silver
direct
image
comprised
silver halide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01000462A
Other languages
German (de)
French (fr)
Other versions
EP1195642B1 (en
EP1195642A2 (en
Inventor
Marc c/o Agfa-Gevaert Van den Zegel
Marleen c/o Agfa Gevaert De Vester
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agfa Gevaert NV
Agfa Gevaert AG
Original Assignee
Agfa Gevaert NV
Agfa Gevaert AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agfa Gevaert NV, Agfa Gevaert AG filed Critical Agfa Gevaert NV
Priority to EP01000462A priority Critical patent/EP1195642B1/en
Publication of EP1195642A2 publication Critical patent/EP1195642A2/en
Publication of EP1195642A3 publication Critical patent/EP1195642A3/en
Application granted granted Critical
Publication of EP1195642B1 publication Critical patent/EP1195642B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/16X-ray, infrared, or ultraviolet ray processes
    • G03C5/17X-ray, infrared, or ultraviolet ray processes using screens to intensify X-ray images
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/0051Tabular grain emulsions
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/09Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/30Hardeners
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/035Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
    • G03C2001/03511Bromide content
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/035Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
    • G03C2001/03594Size of the grains
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/09Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
    • G03C2001/097Selenium
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/29Development processes or agents therefor
    • G03C5/30Developers
    • G03C2005/3007Ascorbic acid
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3022Materials with specific emulsion characteristics, e.g. thickness of the layers, silver content, shape of AgX grains
    • G03C2007/3025Silver content
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C5/00Photographic processes or agents therefor; Regeneration of such processing agents
    • G03C5/26Processes using silver-salt-containing photosensitive materials or agents therefor
    • G03C5/29Development processes or agents therefor
    • G03C5/30Developers

Abstract

A direct X-ray radiographic element has been disclosed and a system for direct X-ray radiography comprised of said element, wherein said element is comprised of a support covered on at least one of its major faces with a tabular grain emulsion layer free from spectrally sensitizing dyes in which at least 50 percent of total grain projected area is accounted for by silver bromo(chloro)iodide tabular grains having an iodide content of at most 1 mole %, based on silver, having an average aspect ratio between 5 and 25, and having a volume between 0,05 and 2µm3, wherein a silver content per coded side, expressed as an equivalent amount of silver nitrate is between 5 and 25 g/m2, and further, being disposed on opposite sides of the radiographic element, two intensifying (metal) screens designed to emit electrons when exposed to X or gamma rays with an energy greater than or equal to 10kVp, characterized in that said tabular grain emulsion(s) have selenium in an amount of 0.5to 20µmole of selenium per mole of silver nitrate.
EP01000462A 2000-10-04 2001-09-14 Silver halide photographic material and image-forming system in direct X-ray imaging applications Expired - Lifetime EP1195642B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP01000462A EP1195642B1 (en) 2000-10-04 2001-09-14 Silver halide photographic material and image-forming system in direct X-ray imaging applications

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP00203438 2000-10-04
EP00203438 2000-10-04
EP01000462A EP1195642B1 (en) 2000-10-04 2001-09-14 Silver halide photographic material and image-forming system in direct X-ray imaging applications

Publications (3)

Publication Number Publication Date
EP1195642A2 EP1195642A2 (en) 2002-04-10
EP1195642A3 true EP1195642A3 (en) 2002-04-24
EP1195642B1 EP1195642B1 (en) 2004-02-25

Family

ID=26072751

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01000462A Expired - Lifetime EP1195642B1 (en) 2000-10-04 2001-09-14 Silver halide photographic material and image-forming system in direct X-ray imaging applications

Country Status (1)

Country Link
EP (1) EP1195642B1 (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB758475A (en) * 1953-04-30 1956-10-03 Norbert Jean Marie Pierre Fran Improvements in and relating to processes, products and devices for measuring dosageof x, gamma and ultra-violet radiations
US5397692A (en) * 1990-05-29 1995-03-14 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material
EP0757286A1 (en) * 1995-08-01 1997-02-05 Kodak-Pathe New element for industrial radiography
US5766837A (en) * 1994-07-20 1998-06-16 Fuji Photo Film Co., Ltd. Silver halide photographic material and method for producing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB758475A (en) * 1953-04-30 1956-10-03 Norbert Jean Marie Pierre Fran Improvements in and relating to processes, products and devices for measuring dosageof x, gamma and ultra-violet radiations
US5397692A (en) * 1990-05-29 1995-03-14 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material
US5766837A (en) * 1994-07-20 1998-06-16 Fuji Photo Film Co., Ltd. Silver halide photographic material and method for producing the same
EP0757286A1 (en) * 1995-08-01 1997-02-05 Kodak-Pathe New element for industrial radiography

Also Published As

Publication number Publication date
EP1195642B1 (en) 2004-02-25
EP1195642A2 (en) 2002-04-10

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