EP1179037A1 - Fabric softening compositions - Google Patents
Fabric softening compositionsInfo
- Publication number
- EP1179037A1 EP1179037A1 EP00929672A EP00929672A EP1179037A1 EP 1179037 A1 EP1179037 A1 EP 1179037A1 EP 00929672 A EP00929672 A EP 00929672A EP 00929672 A EP00929672 A EP 00929672A EP 1179037 A1 EP1179037 A1 EP 1179037A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cpe
- rse
- antioxidant
- composition according
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Definitions
- the present invention relates to fabric softening compositions, in particular to those that soften without affecting the absorbency of the fabric and which suffer from a reduced tendency to develop malodour during manufacture, storage or use.
- W098/16538 discloses fabric conditioning compositions comprising liquid or soft solid derivatives of a cyclic polyol or a reduced saccharide which give good softening and retain a ⁇ sorbency of the fabric.
- EP 0 380 406 discloses detergent compositions comprising a saccharide or reduced saccharide ester containing at least one fatty acid chain.
- WO 95/00614 discloses softening compositions comprising polyhyd ⁇ c alcohol esters and catiomsed cellulose.
- WO 96/15213 discloses textile softening agents containing alkyl , alkenyl and/or acyl group containing sugar derivatives, which are solid after esterification, m combination with noniomc and cationic emulsifiers.
- W0 97/13828 discloses fabric conditioning compositions comprising a heavy metal sequestran .
- compositions of the present invention soften fabrics without detriment to the absorbency of the fabric, they are easily manufactured and do not suffer from unacceptable levels of malodour development upon manufacture, storage or use.
- CPEs examples include esters of alkyl (poly) glucosides , m particular alkyl glucoside esters having a degree of polymerisation from 1 to 2.
- Mixtures of any of the aforementioned deposition aids may be used .
- the fabric softening compositions comprise one or more antioxidants m a weight ratio to the CPE or RSE of 20:1 or more .
- any suitable antioxidant may be used according to the invention.
- the antioxidant comprises at least one initiation inhibitor antioxidant or at least one propagation inhibitor. Mixtures of these two types of antioxidants have been found to be particularly beneficial, especially m reducing medium to long term malodour. Any antioxidant referred to in the following examples may be used.
- Suitable initiation inhibitor antioxidants include peroxide decomposers (e.g. sulphides, aryl and alkyl phosphites, metal salts of some thiodipropionates , xanthates and dithiophosphates) .
- peroxide decomposers e.g. sulphides, aryl and alkyl phosphites, metal salts of some thiodipropionates , xanthates and dithiophosphates.
- R Ci 2 H 25 , C 14 H 29 o C 18 H 37 i.e. TNPP (tris- nonylphenylphosphite) available as Irgafos 186; Sandostab P- EPQ; and Irgafos P-EPQ respectively.
- peroxide decomposers are preferably present at a level of between 0.001% to 0.5% by weight, most preferably 0.005% to 0.1%.
- Propagation inhibitor antioxidants consist primarily of hindered phenols/polyphenols . These can include those which are commonly used m the foods or plastics industries, such as butylated hydroxyanisole (BHA) ; butylated hydroxytoluene (BHT) ; tert -butyl hydroqu one (TBHQ) ; tocopherols ; tocot ⁇ enols ; ascorbic acid; ascobyl palmitate; octyl gallate; propyl gallate; lauryl gallate; N, N-bis (ethyl 3 5' -di -tert -butyl -4 -hydroxybenzoate; 2- (N, N-dimethyl - ammo) ethyl 3 5' -di-tert -butyl -4 ' hydroxybenzoate-N- cocoamme; 2 - (N-methyl -N-cocammo) ethyl 3 ' , 5 '
- Inhibitor antioxidants are preferably present at a level of 0.0001% to 0.5% by weight, based on the total weight of the composition, more preferably 0.0002% to 0.05%, most preferably 0.0002% to 0.02%.
- the composition can also contain one or more optional ingredients, selected from electrolytes, non-aqueous solvents, pH buffering agents, perfumes, perfume carriers, fluorescers, colorants, hydrotropes, antifoam g agents, antiredeposition agents, polymeric and other thickeners, enzymes, optical brightening agents, opacifiers, anti- shrinking agents, anti-wrmkle agents, anti-spottmg agents, germicides, fungicides, anti -corrosion agents, drape imparting agents, antistatic agents, sunscreens, colour care agents and ironing aids.
- optional ingredients selected from electrolytes, non-aqueous solvents, pH buffering agents, perfumes, perfume carriers, fluorescers, colorants, hydrotropes, antifoam g agents, antiredeposition agents, polymeric and other thickeners, enzymes, optical brightening agents, opacifiers, anti- shrinking agents, anti-wrmkle agents, anti-spottmg agents, germicides, fung
- any viscosity control agent used with rinse conditioners is suitable for use with the present invention, for example biological polymers such as Xanthum gum (Kelco ex Kelsan and Rhodopol ex Rhone- Poulenc) , Guar gum (Jaguar ex Rhone-Poulenc) , starches and cellulose ethers.
- biological polymers such as Xanthum gum (Kelco ex Kelsan and Rhodopol ex Rhone- Poulenc) , Guar gum (Jaguar ex Rhone-Poulenc) , starches and cellulose ethers.
- Synthetic polymers are useful viscosity control agents such as polyacrylic acid, poly vinyl pyrrolidone, polyethylene, carbomers, cross linked polyacrylamides such as Acosol 880/882 polyethylene and polyethylene glycols.
- compositions are substantially free of bleaches.
- compositions are entirely free of bleaches .
- %'s are by weight based on the total weight of the composition and represent the amount of active compound. Examples 1 and 14 are controls which do not contain antioxidant. In Ryoto 0-170, 85% or greater of the fatty acid chains contain an unsaturated bond.
- Examples 2 to 13 were prepared by dissolving the propagation inhibitor antioxidant (Irganox 1330 or Irganox 1010) m the CPE (Ryoto 0-170) and adding this to a separate mixture of a cationic and water (in an amount to make the composition up to 100 weight %) .
- the resultant composition was mixed using a low shear Heidolph mixer to produce an emulsion.
- the initiation inhibitor antioxidant (Dequest 2066) was post-dosed to this emulsion.
- Examples 14 to 24 were prepared by mixing the cationic surfactant (CTAC) with water and then addin ⁇ to this mixture the CPE (Ryoto O-170) at room temperature under conditions of high shear to produce an emulsion.
- CAC cationic surfactant
- the propagation inhibitor antioxidant (Irganox 1010) was dissolved m the CPE prior to emulsification.
- the initiation inhibitor antioxidant (Dequest 2066, DTPA or Na IDS) was post-dosed into the final emulsion.
- sucrose pentaoleate from Mitsubishi-Kagaku Food Corporation
- cetyl trimethyl ammonium chloride from Aldrich (as a 25% solution)
- diethylene triammepenta methylene phosphonate
- A is Irganox 1330; 1 , 3 , 5-t ⁇ methyl-2 , 4 , 6- t ⁇ s- (3 ' , 5 ' di- tert -butyl -4 ' -hydroxybenzyl ) benzene .
- B is Irganox 1010; Tetrakis [methylene (3 , 5-d ⁇ -tert-butyl • 4 -hydroxyhydrocmnamate )] methane (Both from Ciba Geigy) .
- the samples were stored m screw-top glass bottles at 37°C to 45 °C. At the intervals given m Tables 3 and 4 the bottles were removed from storage and the samples assessed for the development of malodour (which was determined by assessing the level of a rancid 'fatty' smell present) . Before each assessment the samples allowed to equilibrate at room temperature. The malodour was assessed at room temperature by sniffing the odours from the equilibrated sample and assigning a value between 0 and 5 to indicated the level of malodour. Zero was given if the sample had no perceivable rancid smell and five was given for a very strong rancid smell . At least ten people assessed each sample and the average value was calculated from their response.
- Example 1 - 13 and 14 - 24 are shown m Tables 3 and 4 respect ively .
- Table 3 shows the malodour values determined for examples 1-13 over a 27 week testing period with storage between 37 C-45°C.
- Table 4 shows the malodour values determined for examples 14-24 over a 4 week testing period with storage at
- compositions which have improved malodour suppression m the presence of propagation and the initiation inhibitor are given m the following examples.
- Examples 25 to 28 in Table 5 below were prepared by mixing the listed components together m water.
- Irganox 1010, Dequest 2066 and CTAC are described above.
- the Ryoto products are available from Mitsubishi -Kagaku Food
- HEQ is 1,2 bis [hardened tallowoyloxy] -3 - trimethylammonium propane chloride available from Hoechst .
- Arquad 2-HT is ditallow dimethyl ammonium chloride Example 35
- Example 35 was prepared as a 5% total active emulsion/dispersion m water comprising 4.5% sucrose tetraerucate (oily liquid, Ryoto ER 290), 0.5% CTAC, 0.01% Dequest 2066, 0.0045% Irganox 1010 and 0.2% of a polymer deposition aid as given below: -
- Example 35a FlocAid 34 (ex National Starch)
- Example 35b Softgel BDA (ex Avebe)
- Example 36 was prepared as a 1:4 emulsion/dispersion (5% total active) of DEEDMAC : sucrose pentaoleate (Ryoto 0-170) by mixing at high temperatures. To this is added , 0.01% Dequest 2066 and 0.004% Irganox 1010.
- a fully formulated fabric softening composition as according to the present invention was prepared as below:
- Coco alcohol 15EO (ex Cla ⁇ ant) dodec l benzene sulphomc acid sodium salt (ex Aldrich Chemical Company) C Softqel BDA (ex Aveoe)
- Table 8 shows the T 2 NMR solid: liquid ratio of CPEs and RSEs used according to the present invention. The ratios were measured at 20 C. The degree of esterification /ethe ⁇ fication is stated.
- compositions m table 9 were prepared as follows: The propagation inhibitor was dissolved in the sucrose tetraoleate a weight ratio of 99.9:0.1. This mixture was then comelted with the TEA and Coco-15EO and then added to water at 60 C with stirring using a low shear Heidolph mixer. The resulting mixture was stirred for 10 minutes before being cooled to room temperature. Where an initiation inhibitor was used, it was post-dosed to the final mixture as a 5% solution m water with mixing.
- Table 10 shows the malodour values determined for examples 39-52 over a 9 week testing period with storage at
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Biochemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Fats And Perfumes (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9911434.0A GB9911434D0 (en) | 1999-05-17 | 1999-05-17 | Fabric softening compositions |
GB9911434 | 1999-05-17 | ||
PCT/GB2000/001699 WO2000070004A1 (en) | 1999-05-17 | 2000-05-03 | Fabric softening compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1179037A1 true EP1179037A1 (en) | 2002-02-13 |
EP1179037B1 EP1179037B1 (en) | 2006-03-29 |
Family
ID=10853610
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00929672A Expired - Lifetime EP1179037B1 (en) | 1999-05-17 | 2000-05-03 | Fabric softening compositions |
Country Status (21)
Country | Link |
---|---|
EP (1) | EP1179037B1 (en) |
JP (1) | JP2002544406A (en) |
CN (1) | CN1225530C (en) |
AR (1) | AR023998A1 (en) |
AT (1) | ATE321835T1 (en) |
AU (1) | AU768506B2 (en) |
BR (1) | BR0010574B1 (en) |
CA (1) | CA2367033C (en) |
CZ (1) | CZ298908B6 (en) |
DE (1) | DE60026988T2 (en) |
ES (1) | ES2258006T3 (en) |
GB (1) | GB9911434D0 (en) |
HU (1) | HU228798B1 (en) |
MX (1) | MXPA01011697A (en) |
MY (1) | MY154358A (en) |
PL (1) | PL191651B1 (en) |
RO (1) | RO121134B1 (en) |
RU (1) | RU2227804C2 (en) |
TR (1) | TR200103291T2 (en) |
WO (1) | WO2000070004A1 (en) |
ZA (1) | ZA200107246B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3733824A1 (en) * | 2019-05-03 | 2020-11-04 | The Procter & Gamble Company | Methods of using antioxidants in fabric treatment compositions for treating elastane-containing fabrics |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9930435D0 (en) * | 1999-12-22 | 2000-02-16 | Unilever Plc | Fabric softening compositions |
GB9930430D0 (en) * | 1999-12-22 | 2000-02-16 | Unilever Plc | A method of preparing fabric softening compositions |
GB0024689D0 (en) | 2000-10-09 | 2000-11-22 | Unilever Plc | Deodorant products |
US6846786B1 (en) * | 2003-10-09 | 2005-01-25 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Process for making low surfactant, high sugar bars |
GB0412854D0 (en) | 2004-06-09 | 2004-07-14 | Unilever Plc | Fabric care composition |
US7776813B2 (en) | 2004-09-15 | 2010-08-17 | The Procter & Gamble Company | Fabric care compositions comprising polyol based fabric care materials and deposition agents |
GB0501006D0 (en) * | 2005-01-18 | 2005-02-23 | Unilever Plc | Fabric conditioning compositions |
GB0511313D0 (en) * | 2005-06-03 | 2005-07-13 | Unilever Plc | Incorporation of antioxidant in detergent composition |
EP1960590B1 (en) * | 2005-12-15 | 2013-01-23 | The Procter & Gamble Company | Fabric care compositions for softening, static control and fragrance benefits |
US7749952B2 (en) | 2006-12-05 | 2010-07-06 | The Procter & Gamble Company | Fabric care compositions for softening, static control and fragrance benefits |
JP6982917B1 (en) * | 2021-04-27 | 2021-12-17 | 株式会社 きものブレイン | Softener |
JP2024517798A (en) | 2021-05-04 | 2024-04-23 | ニュートリション・アンド・バイオサイエンシーズ・ユーエスエー・フォー,インコーポレイテッド | Compositions Comprising Insoluble Alpha-Glucans |
CN117616054A (en) | 2021-07-13 | 2024-02-27 | 营养与生物科学美国4公司 | Cationic dextran ester derivatives |
WO2023081341A1 (en) | 2021-11-05 | 2023-05-11 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising one cationic alpha- 1,6-glucan derivative and one alpha- 1,3-glucan |
WO2023114942A1 (en) | 2021-12-16 | 2023-06-22 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising cationic alpha-glucan ethers in aqueous polar organic solvents |
WO2024015769A1 (en) | 2022-07-11 | 2024-01-18 | Nutrition & Biosciences USA 4, Inc. | Amphiphilic glucan ester derivatives |
WO2024081773A1 (en) | 2022-10-14 | 2024-04-18 | Nutrition & Biosciences USA 4, Inc. | Compositions comprising water, cationic alpha-1,6-glucan ether and organic solvent |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4800038A (en) * | 1988-01-21 | 1989-01-24 | Colgate-Palmolive Company | Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners |
FI921148A (en) * | 1991-09-06 | 1993-03-07 | Colgate Palmolive Co | TYGMJUKGOERANDE PRODUKTER BASERADE PAO EN KOMBINATION AV EN PENTAERYTRITOLFOERINING OCH BENTONIT |
US5474691A (en) * | 1994-07-26 | 1995-12-12 | The Procter & Gamble Company | Dryer-added fabric treatment article of manufacture containing antioxidant and sunscreen compounds for sun fade protection of fabrics |
DE4440620A1 (en) * | 1994-11-14 | 1996-05-15 | Henkel Kgaa | Textile softeners |
JPH08158258A (en) * | 1994-12-09 | 1996-06-18 | Kao Corp | Antimicrobial softener composition |
AU723907B2 (en) * | 1996-10-16 | 2000-09-07 | Unilever Plc | Fabric softening composition |
-
1999
- 1999-05-17 GB GBGB9911434.0A patent/GB9911434D0/en not_active Ceased
-
2000
- 2000-05-03 ES ES00929672T patent/ES2258006T3/en not_active Expired - Lifetime
- 2000-05-03 PL PL351739A patent/PL191651B1/en not_active IP Right Cessation
- 2000-05-03 JP JP2000618411A patent/JP2002544406A/en not_active Withdrawn
- 2000-05-03 DE DE60026988T patent/DE60026988T2/en not_active Expired - Lifetime
- 2000-05-03 AU AU47679/00A patent/AU768506B2/en not_active Ceased
- 2000-05-03 MX MXPA01011697A patent/MXPA01011697A/en active IP Right Grant
- 2000-05-03 WO PCT/GB2000/001699 patent/WO2000070004A1/en active IP Right Grant
- 2000-05-03 CA CA2367033A patent/CA2367033C/en not_active Expired - Fee Related
- 2000-05-03 TR TR2001/03291T patent/TR200103291T2/en unknown
- 2000-05-03 RU RU2001133737/04A patent/RU2227804C2/en not_active IP Right Cessation
- 2000-05-03 CZ CZ20014054A patent/CZ298908B6/en not_active IP Right Cessation
- 2000-05-03 EP EP00929672A patent/EP1179037B1/en not_active Expired - Lifetime
- 2000-05-03 CN CN00807530.1A patent/CN1225530C/en not_active Expired - Fee Related
- 2000-05-03 AT AT00929672T patent/ATE321835T1/en not_active IP Right Cessation
- 2000-05-03 RO ROA200101223A patent/RO121134B1/en unknown
- 2000-05-03 HU HU0201469A patent/HU228798B1/en not_active IP Right Cessation
- 2000-05-03 BR BRPI0010574-0A patent/BR0010574B1/en not_active IP Right Cessation
- 2000-05-16 MY MYPI20002148A patent/MY154358A/en unknown
- 2000-05-16 AR ARP000102348A patent/AR023998A1/en not_active Application Discontinuation
-
2001
- 2001-08-31 ZA ZA200107246A patent/ZA200107246B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO0070004A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3733824A1 (en) * | 2019-05-03 | 2020-11-04 | The Procter & Gamble Company | Methods of using antioxidants in fabric treatment compositions for treating elastane-containing fabrics |
WO2020227037A1 (en) * | 2019-05-03 | 2020-11-12 | The Procter & Gamble Company | Methods of using antioxidants in fabric treatment compositions for treating elastane-containing fabrics |
Also Published As
Publication number | Publication date |
---|---|
HU228798B1 (en) | 2013-05-28 |
AU4767900A (en) | 2000-12-05 |
DE60026988T2 (en) | 2006-09-21 |
ATE321835T1 (en) | 2006-04-15 |
CA2367033A1 (en) | 2000-11-23 |
HUP0201469A2 (en) | 2002-08-28 |
AU768506B2 (en) | 2003-12-11 |
CZ298908B6 (en) | 2008-03-12 |
GB9911434D0 (en) | 1999-07-14 |
MY154358A (en) | 2015-05-29 |
CA2367033C (en) | 2010-04-06 |
PL351739A1 (en) | 2003-06-02 |
WO2000070004A1 (en) | 2000-11-23 |
CZ20014054A3 (en) | 2002-08-14 |
CN1350572A (en) | 2002-05-22 |
JP2002544406A (en) | 2002-12-24 |
DE60026988D1 (en) | 2006-05-18 |
ES2258006T3 (en) | 2006-08-16 |
BR0010574A (en) | 2002-02-19 |
CN1225530C (en) | 2005-11-02 |
PL191651B1 (en) | 2006-06-30 |
RU2227804C2 (en) | 2004-04-27 |
MXPA01011697A (en) | 2002-05-14 |
ZA200107246B (en) | 2002-09-02 |
RO121134B1 (en) | 2006-12-29 |
BR0010574B1 (en) | 2009-08-11 |
TR200103291T2 (en) | 2002-04-22 |
AR023998A1 (en) | 2002-09-04 |
EP1179037B1 (en) | 2006-03-29 |
HUP0201469A3 (en) | 2004-03-01 |
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