AU4767900A - Fabric softening compositions - Google Patents

Description

WO 00/70004 PCT/GBO0/01699 FABRIC SOFTENING COMPOSITIONS Technical Field 5 The present invention relates to fabric softening compositions, in particular to those that soften without affecting the absorbency of the fabric and which suffer from a reduced tendency to develop malodour during manufacture, storage or use. 10 Background and Prior Art Rinse added fabric softener compositions are well known. However, a disadvantage associated with 15 conventional rinse conditioners is that although they increase the softness of a fabric they often simultaneously decrease its absorbency. This means that its ability to take up water decreases. This is particularly disadvantageous with towels where 20 the consumer requires the towel to be soft, and yet, have a high absorbency. W098/16538 (Unilever) discloses fabric conditioning compositions comprising liquid or soft solid 25 derivatives of a cyclic polyol or a reduced saccharide which give good softening and retain absorbency of the fabric. EP 0 380 406 (Colgate-Palmolive) discloses detergent 30 compositions comprising a saccharide or reduced saccharide ester containing at least one fatty acid chain. ('TTD'T'TT' C'TTYr.T" "T. rr ,- WO 00/70004 PCT/GBOO/01699 -2 WO 95/00614 (Kao Corporation) discloses softening compositions comprising polyhydric alcohol esters and cationised cellulose. 5 US 5 447 643 (ni-ils) discloses aqueous fabric softeners comprising nonionic surfactant and mono, di or tri fatty acid esters of certain polyols. 10 WO 96/15213 (Henkel) discloses textile softening aQents containing alkyl, alkenyl and/or acyl group containing sugar derivatives, which are solid after esterification, in combination with nonionic and cationic emulsifiers. 15 Frequently a liquid or soft solid fabric softening agent, e.g. a CPE or RSE as herein-defined which addresses the above absorbency problem, is obtained by using unsaturated, usually predominantly unsaturated , fatty acid chains on the ester or ether functions. However such compositions may 20 suffer from the development of product malodour upon manufacture, storage or use. This is obviously highly undesirable. WO 97/13828 (P&G) discloses fabric conditioning compositions 25 comprising a heavy metal sequestrant. WO 96/21714 and WO 96/21715 (P&G) disclose fabric conditioning compositions comprising chelating agents. 30 WO 96/03481 (P&G) discloses fabric conditioning compositions comprsinl i to 20 wt% antioxidant. CTTDrCTT'rrT CTY vr7 ' /n rrr i.y WO 00/70004 PCT/GBOO/01699 The present invention is directed towards alleviating the above-mentioned problems. 5 The principal advantages of the compositions of the present invention are that they soften fabrics without detriment to the absorbency of the fabric, they are easily manufactured and do not suffer from unacceptable levels of malodour development upon manufacture, storage or use. 10 Definition of the Invention Thus according to one aspect of the invention there is provided a fabric softening composition comprising: 15 i) a liquid or soft solid derivative of a cyclic polyol (CPE) or of a reduced saccharide (RSE) resulting from 35 to 100% of the hydroxyl groups in the polyol or saccharide beina esterified or etherified, the CPE or RSE having 2 or 20 more ester or ether groups independently attached to a C8-C22 alkyl or alkenyl chain , wherein at least one of the chains attached to the ester or ether groups has at least one unsaturated bond, and; 25 ii) a deposition aid; and iii) one or more antioxidant(s) wherein the weight ratio of i) to iii) is 20:1 or greater. 30 CTTDCYTFTTT'r Y Tr' rr TYITT WO 00/70004 PCT/GBOO/01699 -4 It has been found, surprisingly, that the above compositions provide an unexpected combination of simultaneous fabric softening and retention of absorbency and exhibit improved malodour resistance, even, at elevated temperatures. 5 According to a further aspect of the invention, there is provided a method of reducing malodour upon manufacture, storage or use in a composition comprising a CPE or RSE as herein described by the addition of a least one antioxidant. 10 Detailed Description of the Invention In the context of the present invention the initials CPE or RSE stand for a derivative of a cyclic polyol or of a 15 reduced saccharide respectively which results from 35 to 100% of the hydroxyl groups of the cyclic polyol or reduced saccharide being esterified or etherified, the CPE or RSE having two or more ester or ether groups independently of one another attached to a C 8 to C 2 2 alkyl or alkenyl chain, 20 and in which at least one of the chains attached to the ester or ether groups has at least one unsaturated bond. The CPE or RSE 25 The CPE or RSE used according to the invention does not have any substantial crystalline character at 20 C. Instead it is preferably in a liquid or soft solid state as herein defined at 20"C. CTTRCTTTTTT7 CLTCT /DYIZ 77111 WO 00/70004 PCT/GBO0/01699 -5 The liquid or soft solid (as hereinafter defined) CPEs or RSEs of the present invention result from 35 to 100% of the hydroxyl groups of the starting cyclic polyol or reduced saccharide being esterified or etherified with groups such 5 that the CPEs or RSEs are in the required liquid or soft solid state. These groups typically contain unsaturation, branching or mixed chain lengths. Typically the CPEs or RSEs have 3 or more ester or ether 10 groups or mixtures thereof, for example 3 to 8, especially 3 to 5. It is preferred if two or more of the ester or ether groups of the CPE or RSE are independently of one another attached to a C8 to C22 alkyl or alkenyl chain. The C8 to C22 alkyl or alkenyl groups may be branched or linear carbon 15 chains. Preferably 35 to 85% of the hydroxyl groups, most preferably 40-80%, even more preferably 45-75%, such as 45-70% are esterified or etherified. 20 Preferably the CPE or RSE contains at least 35% tri or higher esters, eg at least 40%. The CPE or RSE has at least one of the chains independently 25 attached to the ester or ether groups having at least one unsaturated bond. This provides a cost effective way of making the CPE or RSE a liquid or a soft solid. It is preferred if predominantly unsaturated fatty chains, derived from, for example, rape oil, cotton seed oil, soybean oil, 30 oleic, tallow, palmitoleic, linoleic, erucic or other CTTPCTTTTT CLfV 'ri nrrr r7-,w WO 00/70004 PCT/GB0O/01699 -6 sources of unsaturated vegetable fatty acids, are attached to the ester/ether groups. These chains are referred to below as the ester or ether 5 chains (of the CPE or RSE). The ester or ether chains of the CPE or RSE are preferably predominantly unsaturated. Preferred CPEs or RSEs include sucrose tetratallowate, sucrose tetrarapeate, sucrose 10 tetraoleate, sucrose tetraesters of soybean oil or cotton seed oil, cellobiose tetraoleate, sucrose trioleate, sucrose triapeate, sucrose pentaoleate, sucrose pentarapeate, sucrose hexaoleate, sucrose hexarapeate, sucrose triesters, pentaesters and hexaesters of soybean oil or cotton seed 15 oil, glucose tiroleate, glucose tetraoleate, xylose trioleate, or sucrose tetra-,tri-, penta- or hexa- esters with any mixture of predominantly unsaturated fatty acid chains. The most preferred CPEs or RSEs are those with monosaturated fatty acid chains, i.e. where any 20 polyunsaturation has been removed by partial hydrogenation. However some CPEs or RSEs based on polyunsaturated fatty acid chains, eg sucrose tetralinoleate, may be used provided most of the polyunsaturation has been removed by partial hydrogenation. 25 The most highly preferred liquid CPEs or RSEs are any of the above but where the polyunsaturation has been removed through partial hydrogenation. SUBSTITUTE SHEET (RUIE 26) WO 00/70004 PCT/GB0O/01699 -7 Preferably 40% or more of the fatty acid chains contain an unsaturated bond, more preferably 50% or more, most preferably 60% or more. In most cases 65% to 100%, e.g. 65% to 95% contain an unsaturated bond. CPEs are preferred for use with the present invention. Inositol is a preferred example of a cyclic polyol. Inositol derivatives are especially preferred. 10 In the context of the present invention, :he term cyclic polyol encompasses all forms of saccharides. Indeed saccharides are especially preferred for use with this invention. Examples of preferred saccharides for the CPEs or RSEs to be derived from are monosaccharides and 15 disaccharides. Examples of monosaccharides include xylose, arabinose, galactose, fructose, sorbose and glucose. Glucose is especially preferred. Examples of disaccharides include 20 maltose, lactose, cellobiose and sucrose. Sucrose is especially preferred. An example of a reduced saccharide is sorbitan. The liquid or soft solid CPEs can be prepared by methods 25 well known to those skilled in the art. These include acylation of the cyclic polyol or reduced saccharide with an acid chloride; trans-esterification of the cyclic polyol or reduced saccharide fatty acid esters using a variety of catalysts; acylation of the cyclic polyol or reduced 30 saccharide with an acid anhydride and acylation of the SUBSTITUTE SITFT (RTI7 F%) WO 00/70004 PCT/GBOO/01699 cyclic polyol or reduced saccharide with a fatty acid. See for instance US 4 386 213 and AU 14416/88 (both P&G). It is preferred if the CPE or RSE has 3 or more, preferably 5 4 or more ester or ether groups. If the CPE is a disaccharide it is preferred if the disaccharide has 3 or more ester or ether groups. Particularly preferred CPEs are esters with a degree of esterification of 3 to 5, for example, sucrose tri, tetra and penta esters. 10 Where the cyclic polyol is a reducing sugar it is advantageous if each ring of the CPE has one ether or ester group, preferably at the C 1 position. Suitable examples of such compounds include methyl glucose derivatives. 15 Examples of suitable CPEs include esters of alkyl(poly)glucosides, in particular alkyl glucoside esters having a degree of polymerisation from 1 to 2. 20 The length of the unsaturated (and saturated if present) chains in the CPE or RSE is C 8

-C

2 2 , preferably C1 2

-C

2 2 . It is possible to include one or more chains of Ci-C 8 , however these are less preferred. 25 The liquid or soft solid CPEs or RSEs of the present invention are characterised as materials having a solid:liquid ratio of between 50:50 and 0:100 at 20 0 C as determined by T 2 relaxation time NMR, preferably between 43:57 and 0:100, most preferably between 40:60 and 0:100, SUBSTITUTE S[EIET (R II F 26) WO 00/70004 PCT/GBOO/01699 -9 such as, 20:80 and 0:100. The T 2 NMR relaxation time is commonly used for characterising solid:liquid ratios in soft solid products such as fats and margarines. For the purpose of the present invention, any component of the signal with a 5 T 2 of less than 100 pts is considered to be a solid component and any component with T 2 > 100 Is is considered to be a liquid component. For the CPEs and RSEs, the prefixes (e.g. tetra and penta) 10 only indicate the average degrees of esterification. The compounds exist as a mixture of materials ranging from the monoester to the fully esterified ester. It is the average degree of esterification which is used herein to define the CPEs and RSEs. 15 The HLB of the CPE or RSE is typically between 1 and 3. The CPE or RSE is preferably present in the composition in an amount of 0.5-50% by weight, based upon the total weight 20 of the composition, more preferably 1-30% by weight, such as 2-25%, eg 2-20%. The CPEs and RSEs for use in the compositions include those recited in the following examples, including, sucrose 25 tetraoleate, sucrose pentaerucate, sucrose tetraerucate and sucrose pentaoleate. The Deposition Aid SUBSTITUTE SHEE T (RUL E 26) WO 00/70004 PCT/GB0O/01699 - 10 In the context of the present invention a deposition aid is defined as any material that aids deposition of the selected CPE or RSE onto a fabric during the laundering process. 5 The deposition aid may be selected from cationic compounds, such as cationic surfactants, nonionic surfactants, anionic surfactants, polymeric deposition aids or mixtures thereof. Quaternary ammonium compounds have been found to be particularly advantageous. A class of preferred deposition 10 aids is fabric softening compounds. It is preferred if the deposition aid is cationic in nature. If a cationic surfactant or cationic softening aid is not present in the formulation it is preferred if a cationic 15 polymeric deposition aid is present. Most preferably the deposition aid is both cationic in nature and is a fabric softening compound. Mixtures of deposition aids may be used, for example, a 20 mixture of a cationic surfactant and a nonionic surfactant, or a fabric softening compound and a polymeric deposition aid. Suitable cationic deposition aids include water soluble 25 single chain quaternary ammonium compounds. Examples include cetyl trimethyl ammonium chloride, cetyl trimethyl ammonium bromide, or any of those listed in European Patent No. 258 923 (Akzo Nobel). 30 However, it is preferred if the deposition aid is a substantially water insoluble fabric softening compound. In CTTDCTYTTTTr e V - 'r /nrrr r- 1 WO 00/70004 PCT/GBOO/01699 particular substantially water insoluble quaternary ammonium materials comprising a single alkyl or alkenyl chain having an average length equal to or greater than C 20 are preferred. Even more preferable are compounds comprising a 5 polar head group and two alkyl or alkenyl chains each having an average chain length equal to or greater than C 14 . Preferred fabric softening deposition aids have two long alkyl or alkenyl chains with an average chain length equal 10 to or greater than C 14 . More preferably each chain has an average chain length greater than C 16 . Most preferably at least 50% of each long chain alkyl or alkenyl group has a chain length of C 18 . 15 It is preferred if the long chain alkyl or alkenyl groups of the fabric softening deposition aid are predominantly linear. The fabric softening deposition aids used in the 20 compositions of the invention are molecules which provide excellent softening. "Substantially water insoluble" fabric compounds in the context of this invention are defined as fabric compounds 25 having a solubility less than 1 x 10- wt% in demineralised water at 200C. Preferably the fabric softening deposition aids have a solubility less than 1 x 10 4 wt% Most preferably the fabric softening deposition aids have a SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GB0O/01699 - 12 solubilitv at 20 C in demineralised water from 1 x 10 to 1 x 10 6wt%. Preferred fabric softening deposition aids are quaternary 5 ammonium compounds, preferably those with at least one ester link. It is especially preferred if the fabric softening deposition aid is a water insoluble quaternary ammonium 10 material which comprises a compound having two C 1 2- 18 alkyl or alkenyl groups connected to the molecule via at least one ester link. It is more preferred if the quaternary ammonium material has two ester links present. An especially preferred ester-linked quaternary ammonium material for use 15 in the invention can be represented by the formula (I): 1 R 20 1 + 2 R N (CH 2 )n-T-R X Formula (I) 25

(CH

2 )n-T-R2 30 wherein each R1 group is independently selected from C 1

.

4 alkyl, hydroxyalkyl or C2- 4 alkenyl groups; and wherein SUBSTITUTE SHE E T (R [T E 26) WO 00/70004 PCT/GBOO/01699 - 13 each R2 group is independently selected from C8-28 alkyl or alkenyl groups; 0 0 5 T is -0-C- or -C-0-; X is any suitable anion and n is 0 or an integer from 1-5. 10 Preferred materials of this class include Di(tallowoyloxyethyl) dimethyl ammonium chloride and Methyl bis- [ethyl(tallowyl)]-2-hydroxyethyl ammonium methyl sulphate. 15 A second preferred type of quaternary ammonium material can be represented by the formula (II): 20 OOCR2 (R1)3N+-(CH 2 )n CH X Formula (II) 25

CH

2 00CR 2 1 - 2 wherein R , n, X and R are as defined above. 30 It is advantageous for environmental reasons if the quaternary ammonium material is biologically degradable. Preferred materials of this class such as 1,2 bis[hardened 35 tallowoyloxy] -3 -trimethylammonium propane chloride and their CTCTTTTTTL CTJr2T IDTY 7 1, WO 00/70004 PCT/GBO0/01699 - 14 method of preparation are, for example, described in US 4 137 180 (Lever Brothers) Preferably these materials comprise small amounts of the corresponding monoester as described in US 4 137 180 for example 1-hardened 5 tallowoyloxy -2-hydroxy 3-trimethylammonium propane chloride. The fabric softening deposition aid of the composition may also be compounds having the formula (III): 10 4 0 0 R 3 + 5 ( -C-O-)mA(-O-C-B-N -R )n X Formula (III) 15 6 R wherein X is an anion, A is an (m+n) valent radical 20 remaining after the removal of (m+n) hydroxy groups from an aliphatic polyol having p hydroxy groups and an atomic ratio of carbon to oxygen in the range of 1.0 to 3.0 and up to 2 groups per hydroxy group selected from ethylene oxide and propylene oxide, 25 m is 0 or an integer from 1 to p-n, n is an integer from 1 to p-m, and p is an integer of at least 2, B is an alkylene or alkylidene group containing 1 to 4 carbon atoms, 3 4 5 6 R , R , R and R6 are, independently from each other, 30 straight or branched chain Ci-C 4 8 alkyl or alkenyl groups, optionally with substitution by one or more functional groups and/or interruption by at most 10 ethylene oxide SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 15 and/or propylene oxide groups, or by at most two functional groups selected from 5 0 0 0 0 0 -C-0-, -0-C-, -C-N-, -N-C-, and -0-C-0 or R11 and R12 may form a ring system containing 5 or 6 atoms 10 in the ring, with the proviso that the average compound either has at least one R group having 22-48 carbon atoms, or at least two R groups having 16-20 carbon atoms, or at least three R groups having 10-14 carbon atoms. Preferred compounds of this type are described in EP 638 639 (Akzo). 15 The deposition aid may also comprise a mixture of different fabric softening compounds, for example a mixture of compounds of Formula (I) and Formula (II). 20 The deposition aid may also be a nonionic surfactant, such as a nonionic ethoxylated surfactant having an HLB of from about 10 to about 20. It is advantageous if the surfactant alkyl group contains at least 12 carbon atoms. 25 Suitable polymeric deposition aids for use with the invention include cationic and nonionic polymeric deposition aids. Suitable cationic polymeric deposition aids include cationic 30 guar polymers such as; the Jaguar series of polymers (ex Rhodia), cationic cellulose derivatives such as Celauats, VIRVTTTTT7 rn717TurDTTT V 141 WO 00/70004 PCT/GB0O/01699 - 16 (ex National Starch), Ucare polymers (ex Amerchol), cationic starches e.g. potato starch such as SoftGels and Solvitose such as BDA (ex Avebe), C* bond polymers series from Cerestar, cationic polyacrylamides such as PCG (ex Allied 5 Colloids), Flocaid series of polymers (ex National Starch) and cationic chitosan and derivatives. Cationic polymeric aids are particularly preferred in the absence of any other cationic material in the composition. 10 Suitable nonionic deposition aids include Pluronics (ex BASF), dialkyl PEGs, cellulose derivatives as described in GB 213 730 (Unilever), hydroxy ethyl cellulose, starch, and hydrophobically modified nonionic polyols such as Acusol 880/882 (ex Rohm & Haas). 15 Mixtures of any of the aforementioned deposition aids may be used. In the fabric softening compositions the weight ratio of CPE 20 or RSE to deposition aid is preferably within the range of from 15:1 to 1:10, more preferably within the range from 10:1 to 1:5, most preferably 8:1 to 1:3. If a composition is required to give particularly high 25 absorbency to fabrics it is advantageous if the weight ratio of CPE or RSE to deposition aid is at least 1:1 (especially if the deposition aid is a fabric softening compound). If a highly softening composition is required it is 30 advantageous if the weight ratio of a softening deposition aid to CPE or RSE is at least 2:3, preferably at least 1:1. SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GB0O/01699 - 17 To give excellent softening and hydrophobicity to fabrics it is preferred if the weight ratio of softening deposition aid to CPE or RSE is from 3:2 to 1:10, more preferably from 2:3 5 to 1:10. The fabric softening compositions comprise one or more antioxidants in a weight ratio to the CPE or RSE of 20:1 or more. 10 The deposition aid is preferably present in the compositions in an amount of 0.05-15% by weight, based upon the total weight of the composition, more preferably 0.1-10%, such as 0.5-7.5%. R.VTRT!TTTT TCVFT PT /r? Vr 17 ' WO 00/70004 PCT/GBOO/01699 - 18 Antioxidant Any suitable antioxidant may be used according to the invention. Preferably the antioxidant comprises at least 5 one initiation inhibitor antioxidant or at least one propagation inhibitor. Mixtures of these two types of antioxidants have been found to be particularly beneficial, especially in reducing medium to long term malodour. Any antioxidant referred to in the following examples may be 10 used. The compositions preferably comprise 0.0001% to 1% by weight (in total), based on the total weight of the composition, of antioxidants, more preferably 0.00015% to 0.75%, even more 15 preferably 0.002 to 0.5%, e.g. 0.002 to 0.45%. It has been found that initiation inhibitors antioxidants can give good short and long term malodour suppression but a mixture of propagation inhibitor and initiation inhibitor 20 antioxidants can give a surprisingly good short and long term malodour suppression. Suitable initiation inhibitor antioxidants include peroxide decomposers (e.g. sulphides, aryl and alkyl phosphites, 25 metal salts of some thiodipropionates, xanthates and dithiophosphates). Suitable peroxide decomposers include (RO 2

CCH

2

CH

2

)

2 S where

R=C

1 2

H

2 5 , C 1 4

H

2 9 or CigH 3 7 i.e. TNPP (tris 30 nonylphenylphosphite) available as Irgafos 186; Sandostab P V1'RVTTTTT V-rrrr1T iT 14 w WO 00/70004 PCT/GBOO/01699 - 19 EPQ; and Irgafos P-EPQ respectively. Where used, peroxide decomposers are preferably present at a level of between 0.001% to 0.5% by weight, most preferably 0.005% to 0.1%. 5 Another type of suitable initiation inhibitor antioxidant are metal ion sequestrants or deactivators. Suitable such types include N, N'-disalicylidene-1,2-propanediamine; oxalyl bis- (benzylidenehydrazide); ethylenediaminetetraacetic acid (EDTA); ethylenediamine 10 N,N'-disuccinic acid (EDDS); N-hydroxyethylene-diamine triacetic acid; nitrilotriacetic acid (NTA); ethylene diamine tetrapropionic acid; ethylenediamine-N,N'-diglutamic acid; 2-hydorxypropylenediamine-N,N'-disuccinic acid; triethylenetriamine hexacetic acid; diethylenetriamine 15 pentacetic acid (DETPA); trans 1,2-diaminocyclohexane N,N,N',N'-tetraacetic acid; ethanol diglycine; ethylenediamine tetrakis(methylene phosphonic acid) (EDTMP); 1-hydroxyethane 1,1 diphosphonic acid (HEDP); hydroxyethane dimethylenephosphonic acid; glucoic acid; citric acid; 20 tartaric acid; isopropyl citric acid; oxydisuccinic acid; dipicolinic acid; 4,5 dihydroxy-m-benzenesulphonic acid; 8 hydroxyquincline; sodium dithiocarbamate; sodium tetraphenylboron; ammonium nitrosophenyl hydroxylamine; ethylene diamine mono succinic acid (EDMS); iminodisuccinic 25 acid sodium salt (IDS Na salt); Tetrakis[methylene(3,5-di tert-butyl-4-hydroxyhydrocinnamate)]methane (Irganox 1010); Tetrakis[methylene(3,5-di-tert-butyl-4 hydroxyhydrocinnamate)]methane; 1,3,5-trimethyl-2,4,6-tris (3',5' di-tert-butyl-4'-hydroxybenzyl)benzene (Irganox 1330) 30 and diethylene triaminepenta(methylene phosphonate) (Dequest 2066) SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 20 Metal ion sequestrants are preferably present at a level of between 0.0001% to 0.5% by weight, based on the total weight of the composition, most preferably 0.005% to 0.1%. 5 Propagation inhibitor antioxidants consist primarily of hindered phenols/polyphenols. These can include those which are commonly used in the foods or plastics industries, such as butylated hydroxyanisole (BHA); butylated hydroxytoluene 10 (BHT); tert-butyl hydroquinone (TBHQ); tocopherols; tocotrienols; ascorbic acid; ascobyl palmitate; octyl gallate; propyl gallate; lauryl gallate; N,N-bis(ethyl 31,5'-di-tert-butyl-4-hydroxybenzoate; 2- (N,N-dimethyl amino)ethyl 3',5'-di-tert-butyl-4'hydroxybenzoate-N 15 cocoamine; 2- (N-methyl-N-cocamino)ethyl 3',5'-di-tert-butyl 4'-hydroxybenzoate; 2,2'-methylenebis(4-methyl-6-t butylphenol), 4,4'-butylidenebis (2-tert-butyl-5 methylphenol), n-octadecyl 3,5-di-tert-butyl-4 hydroxyhydrocinnamate, 1,1,3-tris(3-tert-butyl-4-hydroxy-6 20 methylphenyl) butane. Inhibitor antioxidants are preferably present at a level of 0.0001% to 0.5% by weight, based on the total weight of the composition, more preferably 0.0002% to 0.05%, most 25 preferably 0.0002% to 0.02%. The weight ratio of the initiation inhibitor (i) to the propagation inhibitor (ii) is preferably within the range 10:1 to 1:10, more preferably 10:1 to 1:5, even more 30 preferably 8:1 to 1:1, e.g. 6:1 to 1:1. SURSTITUTE R RIFFT (RTJI 17 7I WO 00/70004 PCT/GB0O/01699 - 21 The weight ratio of CPE or RSE to total antioxidant is 20:1 or greater, preferably 50:1 or greater, more preferably 75:1 or greater. The weight ratio may be as high as 1500:1 or greater. It is preferred that the weight ratio has an upper 5 limit of 3000:1, e.g. 2500:1. Composition pH The compositions of the invention preferably have a pH from 10 1.5 to 7, more preferably from 1.5 to 5. Other Ingredients The compositions can also contain fatty acids, for example 15 C 8 - C 24 alkyl or alkenyl monocarboxylic acids, or, polymeric carboxylic acids. Preferably saturated fatty acids are used, in particular, hardened tallow Cis-Cis fatty acids. The composition can also contain one or more optional 20 ingredients, selected from electrolytes, non-aqueous solvents, pH buffering agents, perfumes, perfume carriers, fluorescers, colorants, hydrotropes, antifoaming agents, antiredeposition agents, polymeric and other thickeners, enzymes, optical brightening agents, opacifiers, anti 25 shrinking agents, anti-wrinkle agents, anti-spotting agents, germicides, fungicides, anti-corrosion agents, drape imparting agents, antistatic agents, sunscreens, colour care agents and ironing aids. 30 If the product is a liquid it may be advantageous if a viscosity control agent is present. Any viscositv control CTT RCTTTTT T CTJr'T ID T" r4 WO 00/70004 PCT/GBOO/01699 - 22 agent used with rinse conditioners is suitable for use with the present invention, for example biological polymers such as Xanthum gum (Kelco ex Kelsan and Rhodopol ex Rhone Poulenc), Guar gum (Jaguar ex Rhone-Poulenc), starches and 5 cellulose ethers. Synthetic polymers are useful viscosity control agents such as polyacrylic acid, poly vinyl pyrrolidone, polyethylene, carbomers, cross linked polyacrylamides such as Acosol 880/882 polyethylene and polyethylene glycols. 10 It is preferred that the compositions are substantially free of bleaches. Preferably the compositions are entirely free of bleaches. 15 Also suitable as viscosity modifiers are decoupling polymers and deflocculating polymers. Product Form 20 The compositions may be in any form conventionally used for fabric softening compositions e.g., powder, paste, gel or liquid. Liquids, especially emulsions are preferred. The compositions may be prepared by any suitable method. 25 Where the antioxidant is oil soluble, e.g. the propagation inhibitor, the antioxidant is suitably pre-added with the CPE or RSE. Where the antioxidant is water soluble, e.g. the initiation inhibitor, especially metal sequestrants, the inhibitor is typically post-dosed to a pre-formed emulsion 30 containing the CPE or RSE. SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 23 Examples The invention is illustrated by the following non-limiting examples. Further examples within the scope of the present 5 invention will be obvious to the man skilled in the art. Examples 1-13 and 14-24 The effect of the anti-oxidant in reducing malodour 10 development on storage In fabric softening compositions comprising a CPE of the and a deposition aid is demonstrated below. All %'s are by weight based on the total weight of the 15 composition and represent the amount of active compound. Examples 1 and 14 are controls which do not contain antioxidant. In Ryoto 0-170, 85% or greater of the fatty acid chains contain an unsaturated bond. 20 Examples 2 to 13 were prepared by dissolving the propagation inhibitor antioxidant (Irganox 1330 or Irganox 1010) in the CPE (Ryoto 0-170) and adding this to a separate mixture of a cationic and water (in an amount to make the composition up to 100 weight %). The resultant composition was mixed using 25 a low shear Heidolph mixer to produce an emulsion. In examples 6 to 13, the initiation inhibitor antioxidant (Dequest 2066) was post-dosed to this emulsion. 30 Examples 14 to 24 were prepared by mixing the cationic surfactant (CTAC) with water and then adding to this mixture VTTRCTTT1TT CU-rT/rDTTT V 141w WO 00/70004 PCT/GB00/01699 - 24 the CPE (Ryoto 0-170) at room temperature under conditions of high shear to produce an emulsion. In examples 15 and 22 to 24, the propagation inhibitor 5 antioxidant (Irganox 1010) was dissolved in the CPE prior to emulsification. In example 16 to 24, the initiation inhibitor antioxidant (Dequest 2066, DTPA or Na IDS) was post-dosed into the final emulsion. 10 The formulations of Examples 1-13 and 14-24 are shown in Tables 1 and 2 respectively. SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 25 Table 1 Example Ryoto CTAC initiation propagation propagation 0- b inhibitor inhibitor inhibitor 170a DEQUEST A B 2066c 1 4.5 1.0 (control) 2 4.5 1.0 - 0.00225 3 4.5 1.0 - 0.0045 4 4.5 1.0 - - 0.00225 5 4.5 1.0 - 0.0045 6 4.5 1.0 0.01 0.00225 7 4.5 1.0 0.01 0.0045 8 4.5 1.0 0.01 - 0.00225 9 4.5 1.0 0.01 - 0.0045 10 4.5 1.0 0.05 0.00225 11 4.5 1.0 0.05 0.0045 12 4.5 1.0 0.05 - 0.00225 13 4.5 1.0 0.05 - 0.0045 a sucrose pentaoleate (from Mitsubishi-Kagaku Food 5 Corporation) bcetyl trimethyl ammonium chloride; from Aldrich (as a 25% solution). C diethylene triaminepenta(methylene phosphonate); available from solutia. .FTTR.TTTT7TI7 VU142T rrTT Lr w WO 00/70004 PCT/GBOO/01699 - 26 "A" is Irganox 1330; 1,3,5-trimethyl-2,4,6-tris-(3',5' di tert-butyl-4'-hydroxybenzyl)benzene. "B" is Irganox 1010; Tetrakis[methylene(3,5-di-tert-butyl 4-hydroxyhydrocinnamate)]methane (Both from Ciba Geigy). 5 Table 2 Example % Initiation Water Ryot CTAC propagation Inhibitor (type o 0- Inhibitor and %) 170 Irganox 1010 14 4.5 0.5 - None To 100 (control) 15 4.5 0.5 0.0045 None To 100 16 4.5 0.5 - 0.01 - Dequest To 100 a 2066 17 4.5 0.5 - 0.01 - DTPAb To 100 18 4.5 0.5 - 0.01 - Na IDSc To 100 19 4.5 0.5 - 0.05 - Dequest To 100 2066a 20 4.5 0.5 - 0.05 - DTPAb To 100 21 4.5 0.5 - 0.05 - Na IDSc To 100 22 4.5 0.5 0.0045 0.01 - Dequest To 100 2066a 23 4.5 0.5 0.0045 0.01 - DTPAb To 100 24 4.5 0.5 0.0045 0.01 - Na IDSc To 100 SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GB0O/01699 - 27 diethylene triamine-N,N,N',N'',N''-pentakis methylene phosphoric acid (from Solutia) bdiethylene triamine pentaacetate (from Akzo Nobel) 5 Ciminodisuccinic acid sodium salt (from Bayer) The samples were stored in screw-top glass bottles at 37 0 C to 45 0 C. At the intervals given in Tables 3 and 4 the bottles were removed from storage and the samples assessed 10 for the development of malodour (which was determined by assessing the level of a rancid 'fatty' smell present). Before each assessment the samples allowed to equilibrate at room temperature. The malodour was assessed at room temperature by sniffing the odours from the equilibrated 15 sample and assigning a value between 0 and 5 to indicated the level of malodour. Zero was given if the sample had no perceivable rancid smell and five was given for a very strong rancid smell. At least ten people assessed each sample and the average value was calculated from their 20 response. As a marker of a value of 5 for a rancid fat an emulsion containing 1% CTAC and 4.5% by weight Priolube 1446 (neopentyl glycol dioleate ex Unichema) was stored at 45 0 C 25 for 4 weeks. The malodour values of Examples 1-13 and 14-24 are shown in Tables 3 and 4 respectively. SUBSTITUTE SITEET (RITF 26) WO 00/70004 PCT/GBOO/01699 - 28 Table 3 below shows the malodour values determined for examples 1-13 over a 27 week testing period with storage between 37 0 C-450C. eyr' rCyTrrTFrrr cyrrr-r-r nrr r , WO 00/70004 PCT/GB0O/01 699 -29 (N H ) co 0 o 0 C m 11H Q\ a) m I'D ~ m cri I'D -i m~ 0 -1 -1 H Q) "T IT 7 (TN HiC (N (n M~ Cn r rq~ (N 0 o Lfl H- (N m (N. m~ >o G C) N H- 1-- 0 H- r- ko -z ',D rn (N Lfl 31 71 'z Hi H N (N (N (N (N ,S m (N CN O') l (N I'D Lfl Q) 0nC) c (N L1n CN un mf o >- 0o m Q) M Y m N rn H H -f -~( N (N (N C N 11 c- c-- r-q 'I Y CD 0 ) co a) 'l 11 ,D Q0 ID zT Lfl r 3 N (N CN H- H (N (N (N (N Q) mf >- Ll '3 r (N (N 14, 0 >- >- r 3 m (N (N (N (N rn H CN (N (N 3l (N H n 71 Go H H H (N ( (N H . (N 'T -1 r- 0n Lfl ' O H C) cl 0 - C> 0 o 1 H z m U) -1 N 0 Q) C N Hi H N 0 H H1 H (N (N (N (N C) > - C) 0o M m 1 0 0 Hi H H H 0 H N (N (N (N 0 Q4, C ) 0 HD IH N E-i ~ ~ ~ ~ ~ Hi (N rnCI nI' -c .VTJRVTfTTTT)7 VU17PT IV117 r' '41 WO 00/70004 PCT/GBOO/01699 - 30 The above results demonstrate the suppression of malodour in a sample containing a predominantly unsaturated CPE and a deposition aid by the addition of an antioxidant. Where the antioxidant is a mixture of a propagating inhibitor and 5 an initiation inhibitor then longer term malodour suppression was achieved. Furthermore advantageous synergistic results were obtained by using 0.01% by weight initiation inhibitor with 0.00225 10 0.0045% by weight propagation inhibitor (see examples 6-9). Table 4 below shows the malodour values determined for examples 14-24 over a 4 week testing period with storage at 45 0 C. 15 Table 4 Example Week 1 Week 2 Week 3 Week 4 14 2.50 2.71 2.76 3.00 (control) 15 - 2.43 2.75 2.83 16 1.83 1.86 1.17 1.75 17 1.67 1.79 1.33 1.83 18 1.58 1.93 2.17 1.50 19 2.17 1.86 1.58 1.83 20 2.25 2.00 1.50 1.67 21 1.75 1.93 1.42 1.83 22 1.60 1.07 1.00 1.42 23 1.17 1.57 1.25 0.83 24 1.00 1.21 1.75 1.25 .VTTRCVTTTT7T7 CzrrI- IJT Tr r1 w WO 00/70004 PCT/GBOO/01699 - 31 The results in table 4 demonstrate that when the only antioxidant present is an initiation inhibitor, odour suppression was achieved. Where the antioxidant comprised 5 both a propagation and an initiation inhibitor, significantly improved odour suppression was obtained. This is surprising given that little or no odour suppression was observed when the only antioxidant present was the propagation inhibitor. 10 Therefore, there is a clear synergistic effect between the propagation and the initiation inhibitor. Further compositions which have improved malodour 15 suppression in the presence of propagation and the initiation inhibitor are given in the following examples. Examples 25 to 34 20 Examples 25 to 28 in Table 5 below were prepared by mixing the listed components together in water. VTTRCTTTTTTI7 CUJ1T IDTr V 14 WO 00/70004 PCT/GBOO/01699 - 32 Table 5 (Mixtures with CTAC) Example 125 26 27 28 Cetyl trimethyl ammonium 1 1 1 1 chloride (CTAC) Sucrose pentaoleate (Ryoto 4 0-170) Sucrose tetraoleate (oily 4 liquid) Sucrose pentaerucate (Ryoto 4 ER-190) (soft liquid) Sucrose tetraeureate (Ryoto 4 ER-290) (soft liquid) Irganox 1010 0.002 0.002 0.002 0.002 Dequest 2066 0.01 0.01 0.01 0.01 Water 95 95 95 95 CTAC:oil ratio 1:4 1:4 1:4 1:4 Irganox 1010, Dequest 2066 and CTAC are described above. 5 The Ryoto products are available from Mitsubishi-Kagaku Food Corporation. The Examples in Tables 6 to 9 below were prepared by heating 10 the ingredients together at 80 0 C, and mixing at high shear. SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 33 Table 6: Mixtures with HEQ (fabric softening compound) Example 29 30 31 HEQ 0.86 2.57 1.71 Fatty Acid 0.14 0.43 0.39 Sucrose pentaoleate (Ryoto 0- 4 2 3 170) (oily liquid) Irganox 1010 0.004 0.002 0.003 Dequest 2066 0.01 0.01 0.01 Water 95 95 95 HEQ:oil ratio 1:4 3:2 2:3 HEQ1 is 1,2 bis[hardened tallowoyloxyl-3- trimethylammonium 5 propane chloride available from Hoechst. Table 7; mixtures with Arquad 2-HT Example 32 33 134 Arquad 2-HTa 1 1 1 Sucrose tetraoleate (oily 4 liquid) Sucrose pentaeureate (Ryoto 4 ER-190) (oily liquid) Sucrose tetraeureate (Ryoto 4 ER-290) (oily liquid) _ _ Irganox 1010 0.004 0.004 0.004 Dequest 2066 0.01 0.01 0.01 Water 95 95 95 Arquad 2-HT:oil 1:4 1:4 1:4 10 aArquad 2-HT is ditallow dimethyl ammonium chloride .UTR.TTTTT .VTIRPT (PIrTT Tr 7A WO 00/70004 PCT/GBOO/01699 - 34 Example 35 Example 35 was prepared as a 5% total active 5 emulsion/dispersion in water comprising 4.5% sucrose tetraerucate (oily liquid, Ryoto ER 290), 0.5% CTAC, 0.01% Dequest 2066, 0.0045% Irganox 1010 and 0.2% of a polymer deposition aid as given below: 10 Example 35a FlocAid 34 (ex National Starch) Example 35b Softgel BDA (ex Avebe) Example 36 15 Example 36 was prepared as a 1:4 emulsion/dispersion (5% total active) of DEEDMAC:sucrose pentaoleate (Ryoto 0-170) by mixing at high temperatures. To this is added , 0.01% Dequest 2066 and 0.004% Irganox 1010. 20 Example 37 A fully formulated fabric softening composition as according to the present invention was prepared as below: 25 % by weight a Genapol C150a 1.6 ABSb 0.4 Ryoto 0-170 15.4 Cationic potato starch 2 30 Perfume 0.96 SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBOO/01699 - 35 Preservative Minor Dye Minor Na IDS 0.01 Irganox 1330 0.015 5 Water Balance a Coco alcohol 15EO (ex Clariant) b dodecyl benzene sulphonic acid sodium salt (ex Aldrich Chemical Company) 10 cSoftgel BDA (ex Avebe) Example 38 Table 8 shows the T 2 NMR solid:liquid ratio of CPEs and RSEs 15 used according to the present invention. The ratios were measured at 20 C. The degree of esterification /etherification is stated. Table 8 20 Material Solid:Liquid Degree and % of Physical ratio at 20 0C esterification Form Ryoto 0-170 0:100 5/8 62.5% Liquid Ryoto ER-290 0:100 4/8 50% Liquid Ryoto ER-190 0:100 5/8 50% soft solid Sucrose 0:100 4/8 50% Liquid tetraoleate Sucrose 0:100 8/8 100% Liquid octaoleate The Ryoto materials are described above. SUBSTITUTE SHEET (RTUIR 26) WO 00/70004 PCT/GB00/01699 - 36 Examnles 39 to 52 All the compositions in table 9 were prepared as follows: 5 The propagation inhibitor was dissolved in the sucrose tetraoleate in a weight ratio of 99.9:0.1. This mixture was then comelted with the TEA and Coco-15EO and then added to water at 600C with stirring using a low shear Heidolph mixer. The resulting mixture was stirred for 10 minutes 10 before being cooled to room temperature. Where an initiation inhibitor was used, it was post-dosed to the final mixture as a 5% solution in water with mixing. SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GB00/01699 - 37 Table 9 Example % % % % Initiation % TEA sucrose Coco Propagation Inhibitor Water a tetra 15EO Inhibitor (% and oleateb (Irganox type) 1330) 39 10. 3.6 0.1 0.0036 0.01 - To 6 EDDS C 100 40 10. 3 .6 0.1 0.0036 0.01 - To 6 Dequest 100 2066 41 10. 3.6 0.1 0.0036 0.01 - Na To 6 IDS 100 42 10. '3.6 0.1 0.0036 0.01 - To 6 DTPA 100 43 10. 3.6 0.1 0.0036 0.01 - To 6 EDTAd 100 44 10. 3.6 0.1 0.0036 0.01 - To 6 Dequest 100 2047 45 10. 3.6 0.1 0.0036 None To 6 100 46 7.5 7.5 0.1 0.0075 0.01 - To I _ I_ EDDS 100 47 7.5 7.5 0.1 0.0075 0.01 - To Deauest 100 2066 48 7.5 7.5 0.1 0.0075 0.01 - Na To _IDS 100 49 7.5 7.5 0.1 0.0075 0.01 - To DTPA 100 50 7.5 7.5 0.1 0.0075 0.01 - To I_ I EDTA 100 51 7.5 7.5 0.1 0.0075 0.01 - To Deauest 100 1 2047 52 7.5 7.5 0.1 0.0075 None To 100 SUBSTITUTE SHEET (RULE 26) WO 00/70004 PCT/GBO0/01699 - 38 methyl bis- [ethyl (tallowyl) ] -2-hydroxyethyl ammonium methyl sulphate (available as a 90% paste under the trade name Rewoquat WE18 from Goldschmidt (ex Witco)). b a sucrose polyoleate with an approximate degree of 5 esterification of 4. C ethylene diamine-N, N' disuccinic acid (from Associated Octel). d ethylene diamine tetra acetic acid (from Contract Chemicals). 10 ethylene diamine tetra(methylene phosphonate) from Solutia. Table 10 below shows the malodour values determined for examples 39-52 over a 9 week testing period with storage at 45 0 C. 15 All samples were stored in loosely closed glass bottles at 45 C. At weekly intervals, the samples were removed form the oven and allowed to cool to room temperature prior to panelling. Malodour scores were ranked on a 0 to 5 basis, 20 whereby 0 = no malodour smell and 5 = extremely strong malodour. The results are given in table 10 SUBSTITUTE SHEET (RUTL 261 WO 00/70004 PCT/GBOO/01699 - 39 Table 10 Example Week 1 Week 2 Week 3 Week 4 Week 6 Week 9 35 0.88 1.37 1.28 1.18 1.38 1.30 36 1.59 1.63 1.00 1.27 1.31 1.10 37 1.29 1.47 1.43 1.82 1.23 1.40 38 1.18 1.32 1.07 1.64 1.23 1.65 39 1.12 1.47 1.29 1.36 1.15 1.60 40 1.41 1.32 1.21 1.45 1.08 1.70 41 2.12 1.89 1.71 2.09 1.77 2.50 42 1.65 1.76 1.75 1.73 1.62 1.70 43 1.65 1.47 1.75 1.82 1.62 1.5 44 1.71 1.18 1.92 1.55 1.08 1.10 45 1.82 1.47 1.83 1.18 1.46 1.00 46 1.65 1.53 1.50 1.45 1.38 1.50 47 1.82 1.59 1.75 1.64 1.31 1.40 48 2.12 1.65 2.25 2.27 2.38 2.20 5 The results demonstrate that when only the propagation inhibitor was used in the softening compositions, good odour suppression was observed over the 9 week period. When a mixture of the propagation and initiation inhibitors was 10 used in the softening compositions, significantly better odour suppression was observed over the 9 week period. .CTTRCTTTTT CTJ1WT IDiT r' 'MI

Claims (1)

1. Claims

   1) A fabric softening composition comprising: I) a liquid or soft solid derivative of a cyclic polyol (CPE) or of a reduced saccharide (RSE) resulting from 35 to 100% of the hydroxyl groups m the polyol or saccharide being esterified or etherified, the CPE or RSE having 2 or more ester or ether groups independently attached to a C₈-C22 alkyl or alkenyl chain, wherein at least one of the chains attached to the ester or ether groups has at least one unsaturated bond, and

   II) a deposition aid, and

   III) one or more antioxidant (s) , wherein the weight ratio of 1) to 111) is 20:1 or greater.

   2) A composition according to claim 1 wherein the CPE or RSE contains at least 35% tri or higher esters.

   3) A composition according either claim 1 or claim 2 wherein the CPE or RSE has 40-80%, preferably 45-75%, of the hydroxyl groups esterified and/or etherified.

   4) A composition according to any one of the preceding claims wherein the CPE OR RSE has 4 or more hydroxy groups esterified or etherified. 5) A composition according to any one of the preceding claims wherein the CPE or RSE is derived from a monosaccharide or disaccharide.

   6) A composition according to any one of the preceding claims wherein the deposition aid is selected from cationic surfactants, noniomc surfactants, amonic surfactants, polymeric deposition aids, fabric softening compounds or mixtures thereof .

   7) A composition according to claim 6 wherein the fabric softening compounds are quaternary ammonium compounds.

   8) A composition according to any one of the preceding comprising 0.5%-50% by weight of the CPE or RSE, preferably l%-30%.

   9) A composition according to any one of the preceding claims wherein the one or more antioxidant (s) comprises at least one initiation inhibitor, or at least one propagation inhibitor, or mixtures thereof.

   10) A composition according to any one of the preceding claims wherein the composition comprises 0.0001% to 1% by weight of the one or more antioxidant (s) .

   11) A composition according to any one of the preceding claims wherein the weight ratio of the CPE or RSE to antioxidant (s) is 50:1 or greater , preferably 75 ;1 or greater. 12) A composition according to any preceding claim which is a liquid, preferably an emulsion.

   13) A method of reducing malodour in a composition comprising a CPE or RSE as defined in claim 1 by the addition of at least one antioxidant.

   14) A method according to claim 13 wherein the antioxidant is as defined in any one of claims 9 to 11.