EP1153651B1 - Static mixer with profiled layers - Google Patents

Static mixer with profiled layers Download PDF

Info

Publication number
EP1153651B1
EP1153651B1 EP01810360A EP01810360A EP1153651B1 EP 1153651 B1 EP1153651 B1 EP 1153651B1 EP 01810360 A EP01810360 A EP 01810360A EP 01810360 A EP01810360 A EP 01810360A EP 1153651 B1 EP1153651 B1 EP 1153651B1
Authority
EP
European Patent Office
Prior art keywords
mixer
layers
static mixer
accordance
elements
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01810360A
Other languages
German (de)
French (fr)
Other versions
EP1153651A1 (en
Inventor
Markus Fleischli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sulzer Chemtech AG
Original Assignee
Sulzer Chemtech AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sulzer Chemtech AG filed Critical Sulzer Chemtech AG
Priority to EP01810360A priority Critical patent/EP1153651B1/en
Publication of EP1153651A1 publication Critical patent/EP1153651A1/en
Application granted granted Critical
Publication of EP1153651B1 publication Critical patent/EP1153651B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/432Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction with means for dividing the material flow into separate sub-flows and for repositioning and recombining these sub-flows; Cross-mixing, e.g. conducting the outer layer of the material nearer to the axis of the tube or vice-versa
    • B01F25/4322Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction with means for dividing the material flow into separate sub-flows and for repositioning and recombining these sub-flows; Cross-mixing, e.g. conducting the outer layer of the material nearer to the axis of the tube or vice-versa essentially composed of stacks of sheets, e.g. corrugated sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/40Static mixers
    • B01F25/42Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
    • B01F25/43Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
    • B01F25/434Mixing tubes comprising cylindrical or conical inserts provided with grooves or protrusions

Definitions

  • the invention relates to a static mixer with profiled layers as well Uses of such a mixer.
  • EP-A 0 697 374 is a static mixer with an annular space shape known, in the corrugated layers of a cross-channel structure with inclined, itself forming open intersecting flow channels.
  • the layers are flat and parallel to a main flow direction.
  • DE-A-32 29 486 discloses a static mixer according to the preamble of claim 1 with profiled layers, which are arranged in an annular space.
  • the Layers consist of concentric tubes, on their inner and / or outer surface each helical grooves are arranged. Such Location has a geometry that does not fold by a foil-like Material strip can be produced.
  • annular space mixer When drilling for oil and / or natural gas is a Drilling channel generated in which between a jacket tube and a Drill pipe an annular space channel remains open. Through the annulus Material is conveyed in the axial direction, which is released at the drill head and that is a fluid mixture of liquids (water, petroleum) and gases may include. In depth and at a vertical distance from the Deposits, the advance of such holes is usually from the vertical direction deflected in a direction in which the hole in the Extreme case runs horizontally.
  • the object of the invention is a static mixer for a fluid mixture to create, which consists of phases of different density and that in Axial direction is to be transported through an annular space, wherein the axis of the annulus may be horizontal or inclined. This task is done by solved defined in claim 1 mixer.
  • the static mixer includes profiled layers that are in an annulus are arranged and inclined to a central axis, intersecting Contain flow channels.
  • a fluid mixture is in the axial direction under a To transport mixed action.
  • Each layer extends over an area the transverse to the axis a closed or largely closed Scope forms.
  • Each layer includes equivalent channels that are on one inner or outer side of the situation about at least approximately the same long stretches from a first to a second cross section of the Annular space extend so that each channel to him flowing through Fluid mixture imposes an azimuthal velocity component for all equivalent channels are essentially the same size.
  • Figures 1 and 2 show a mixer according to the invention with two Concentric layers 1 and 2, an oblique view of the layers and a cross section.
  • the two layers 1, 2, taken together, a mixer element 30th form, are in an annular space 3 between a jacket tube 10 and a Inner tube 20 is arranged.
  • a central axis z and an angle ⁇ ( Azimuth) drawn.
  • the widths of the layers 1 and 2 with a or b denotes the corresponding ring surfaces with A and B.
  • the layers 1, 2 form a cross-channel structure with open-ended flow channels 14 and 24; There is a thorough mixing.
  • the marginal channels 14 'and 24' force an azimuthal rearrangement.
  • Each layer 1, 2 extends over a surface that is transverse to the axis z a closed perimeter forms.
  • the channels 14, 14 ', 24 and 24' respectively form equivalent channels: you extend on an inner or outer side of the layer 1, 2 via equal distances from a first to a second cross section of Annulus, so that the channels to the fluid mixture flowing through a imposing azimuthal velocity components 40 and 41, respectively, in all equivalent channels is largely the same size. It is now assumed that the central axis z is aligned horizontally and a Gas / liquid mixture partially segregated in the mixer element 30th flows. Thanks to the azimuthal velocity components 40 and 41 the gas phase is transported down, the liquid phase up, so that results in a mixing of the two phases. An inhomogeneity decreases thanks to the azimuthal velocity components 40 and 41 strong from.
  • the layers 1, 2 do not necessarily have along their circumference be completely closed. It is sufficient if the layers to cylinders formed strips are formed, which extend in the axial direction Strip ends in each case form a joint. Instead of the shock may also there is a gap or an overlap. Between the layers 1, 2 can also be inserted a sheet, so that the channels 14, 24 are not open cross. In this case, the fluid mixture through the channels in subdivided differently directed sub-streams; a mixture takes place Exit from the mixer element 30 instead.
  • the layers 1, 2 are made by folding strips of material. Each folded strip is formed into a cylinder which is attached to a lateral, axially oriented impact point completely or - up to a narrow open strip - almost completely closed.
  • the Profiling of the layers 1, 2 is advantageously designed so that the Channel walls on the aforementioned impact point match.
  • Fig. 3 shows a piece of a folded film 1 ', the part of a layer 1 of inventive mixer.
  • the same film (1 ') in unfolded Condition is shown in Fig. 4.
  • an outer folding edge 11 (as Double line shown) and an inner fold edge 12 (double line) is located approximately parallelogram-shaped surface piece 16, in which the through Faltkanten 11 and 12 formed side edges only approximately parallel to each other.
  • piece 16 is a diagonal folding edge. 6 (simple line) provided.
  • the folding edge 6 divides the patch 16 in two Triangles 16a and 16b, between the edges 11 and 6 or 12 and 6 lie. Thanks to the diagonal folding edge 6, the two triangles 16 a and 16b just trained. It can also be the other diagonal of the patch 16 can be selected as folding edge.
  • the strip 1 'of the Fig. 4 so fold that the edges 12 a cylindrical surface 5 (for example the surface of the inner wall 20 in Fig. 2) on a circle 50 in points 15th touch. Each edge 12 intersects the circle 50 at the same angle.
  • the free ends 13 of the layer 1 and the circle 50 lie on parallel planes (not shown) with respect to which the z-axis is perpendicular. in the unfolded state, see Fig. 4, the free ends 13 form a Zigzag line.
  • mixer elements 31, 32, 33 which have small heights h, axially to each other arranged as follows: see Fig. 5 So that also a radial mixing is possible, mixer elements 7 can be inserted, the radial, Also, a cross channel structure forming layers 71, 72 include: Fig. 6. Such mixer elements 7 are already known.
  • the mixer according to the invention comprises at least two consecutive arranged mixer elements 31, 32, so they can azimuthally be offset from each other.
  • At the junction 80 (FIG. 5) of FIG Mixer elements 31, 32 then exist between layers 1, in the axial Direction adjacent, passages from inner to outer channels or vice versa from outer to inner channels. In such a Arrangement flows fluid from the outer to the inner channels and vice versa.
  • FIGS. 7-10 show an overview of four different configurations. wherein that of Fig. 7 corresponds to the configuration shown in Fig. 5.
  • FIG. 8 shows a configuration in which gaps 8 between adjacent ones Mixer elements of the elements 31 - 33 are left open. In these Gaps 8 may take place a radial mixing. The length of the gap 8 is advantageously smaller than five times the radial width of the annular space 3.
  • FIG. 9 shows a configuration in which mixing elements 7 are provided according to FIG. 6.
  • FIG. 10 shows a configuration. at the adjacent mixer elements 31, 32 'or 32', 33 each one opposite inclined channel direction in corresponding positions 1 or 2 (see Fig. 1, 5).
  • more than two layers 1, 2 in a mixer element 30 may be provided.
  • their number is even, especially then if it is desired that the total spin of the pumped fluid be practical Is zero. So that the total spin largely disappears, is at a even number of layers to request that the layers in one Cross-section of the annulus stress subfaces, which for each layer have at least approximately the same size areas.
  • the ply widths a and b must be chosen so that the Ring surfaces A and B are the same size.
  • the embodiments shown in the drawings show static Mixers with channels whose cross sections are triangular.
  • the profiles of the layers can also be wavy or otherwise formed; for example, the Channel cross-sections be trapezoidal.
  • the mixer according to the invention can advantageously be used for axial transport a fluid mixture can be used through an annular space 3, if the to be transported fluid mixture 4 of different density phases consists. It can be a group or several groups of Be provided mixer elements, each having a plurality of the same and comprise successively arranged mixer elements.
  • the Central axis z of the mixer can be compared to a horizontal plane one Inclination angle included, which is smaller than 90 ° and in extreme cases even 0 °.
  • One use of the mixer according to the invention is in a bore particularly suitable for crude oil and / or natural gas.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)

Description

Die Erfindung betrifft einen statischen Mischer mit profilierten Lagen sowie Verwendungen eines solchen Mischers.The invention relates to a static mixer with profiled layers as well Uses of such a mixer.

In statischen Mischern werden mittels feststehender Einbauten Fluide, die diese Einbauten durchstömen, homogenisiert. Es gibt eine Vielfalt von Bauformen. Bei den meisten statischen Mischern sind die Einbauten in Form gleichartiger Elemente in einem Rohr oder einem Kanal eingebaut. Sie sind dabei regelmässig angeordnet, so dass sich über den ganzen Rohrquerschnitt eine Homogensierung der zu mischenden Komponenten ergibt. Es sind auch statische Mischer bekannt, bei denen die Einbauten jeweils in einem Ringraum zwischen zwei konzentrischen Wänden angeordnet sind. In einem Übersichtsartikel mit dem Titel "Statische Mischer und ihre Anwendung" (M. H. Pahl, E. Muschelknautz; Chem.-Ing.-Techn. 52 (1980) Nr. 4, S. 285 - 291) ist ein Mischer dieser Art beschrieben (Abb. 1e): Eine Serie von jeweils vier verdrillten Leitblechen sind abwechselnd links- und rechtsgängig auf einem zylindrischen Innenkörper befestigt.In static mixers are by means of fixed internals fluids, the poke through these internals, homogenized. There is a diversity of Designs. For most static mixers, the internals are in shape similar elements installed in a pipe or a channel. you are doing so regularly, so that spread over the whole Tube cross-section homogenization of the components to be mixed results. There are also static mixer known in which the internals each in an annulus between two concentric walls are arranged. In a review entitled "Static Mixers and their application "(M.H.Pahl, E. Muschelknautz, Chem.-Ing.-Techn (1980) No. 4, pp. 285-291) a mixer of this type is described (Fig. 1e): A series of four twisted baffles are alternately left and right-handed mounted on a cylindrical inner body.

Aus der EP-A 0 697 374 ist ein statischer Mischer mit einer Ringraumform bekannt, in dem gewellte Lagen eine Kreuzkanalstruktur mit geneigten, sich offen kreuzenden Strömungskanälen bilden. Die Lagen sind eben und parallel zu einer Hauptströmungsrichtung. DE-A- 32 29 486 offenbart einen statischen Mischer gemäß Oberbegriff des Anspruchs 1 mit profilierten Lagen, die in einem Ringraum angeordnet sind. Die Lagen bestehen aus konzentrischen Rohren, auf deren inneren und/oder äusseren Oberfläche jeweils helixförmige Nuten angeordnet sind. Eine solche Lage weist eine Geometrie auf, die sich nicht durch Falten eines folienartigen Materialstreifens herstellen lässt. From EP-A 0 697 374 is a static mixer with an annular space shape known, in the corrugated layers of a cross-channel structure with inclined, itself forming open intersecting flow channels. The layers are flat and parallel to a main flow direction. DE-A-32 29 486 discloses a static mixer according to the preamble of claim 1 with profiled layers, which are arranged in an annular space. The Layers consist of concentric tubes, on their inner and / or outer surface each helical grooves are arranged. Such Location has a geometry that does not fold by a foil-like Material strip can be produced.

Es gibt Problemstellungen im Zusammenhang mit Homogenisierungen von Fluiden, für deren Lösung sich Ringraummischer als besonders vorteilhaft anbieten. Ein Beispiel: Bei Bohrungen nach Erdöl und/oder Erdgas wird ein Bohrkanal erzeugt, bei dem zwischen einem Mantelrohr und einem Bohrgestänge ein ringraumförmiger Kanal offen bleibt. Durch den Ringraum wird in axialer Richtung Material gefördert, das beim Bohrkopf freigesetzt wird und das ein Fluidgemisch aus Flüssigkeiten (Wasser, Erdöl) und Gasen umfassen kann. In der Tiefe und in einem vertikalen Abstand von den Lagerstätten wird der Vortrieb solcher Bohrungen in der Regel aus der vertikalen Richtung in eine Richtung umgelenkt, in der die Bohrung im Extremfall horizontal verläuft. Es wird eine Vielzahl solcher Bohrungen hergestellt, die strahlenförmig von einer zentralen Bohrung gegen die Peripherie eines Feldes führen, aus dem Erdgas und/oder Erdöl gewonnen werden soll. Beim Fördern der zu gewinnenden Stoffen liefern die einzelnen Bohrungen in der Regel Stoffgemische unterschiedlicher Qualität. Es sind zur Überwachung der Qualität Überwachungsgeräte vorgesehen, die in den Bohrkanälen bis zur Tiefe der Lagerstätten eingeschoben werden. Mit Hilfe von Sensoren in den Überwachungsgeräten können die Anteile der Phasen (Oel, Wasser und/oder Gas) im durchströmenden Fluidgemisch bestimmt werden.There are problems related to homogenisations of Fluids, for the solution of annular space mixer are particularly advantageous to offer. An example: When drilling for oil and / or natural gas is a Drilling channel generated in which between a jacket tube and a Drill pipe an annular space channel remains open. Through the annulus Material is conveyed in the axial direction, which is released at the drill head and that is a fluid mixture of liquids (water, petroleum) and gases may include. In depth and at a vertical distance from the Deposits, the advance of such holes is usually from the vertical direction deflected in a direction in which the hole in the Extreme case runs horizontally. There will be a variety of such holes made radiating from a central bore against the Periphery of a field lead, obtained from the natural gas and / or oil shall be. When conveying the substances to be won deliver the individual Drilling usually mixtures of different quality. It is to Monitoring quality monitoring devices provided in the Drilling channels are pushed to the depth of the deposits. With help of sensors in the monitoring devices, the proportions of the phases (Oil, water and / or gas) determined in the flowing fluid mixture become.

Um repräsentative Messresultate sicherzustellen, ist es bei der Überwachung der Qualität erforderlich, dass die verschiedenen Phasen des Fluidgemisches, die unterschiedliche Dichten haben, mit einer gleichmässigen Verteilung durch die Messbereiche der Sensoren strömen. Daher sind in einem dem Überwachungsgerät vorgelagerten Homogenisierungsbereich statische Mischerelemente einzubauen. Da in einem horizontalen oder geneigten Rohr verschieden dichte Phasen sich entmischen, muss der statische Mischer so ausgebildet sein, dass eine solche Entmischung weitgehend verhindert wird oder - falls bereits eingetreten - rückgängig gemacht werden kann. Den bekannten Ringraummischern fehlt diese Eigenschaft weitgehend.To ensure representative measurement results, it is in the monitoring the quality required that the different phases of the fluid mixture, which have different densities, with a uniform distribution flow through the measuring ranges of the sensors. Therefore, in a the Monitor upstream homogenization area static Install mixer elements. As in a horizontal or inclined tube different dense phases segregate, the static mixer must be so be formed such that such segregation is largely prevented or - if already occurred - can be reversed. The known annular space mixers lack this property largely.

Aufgabe der Erfindung ist es, einen statischen Mischer für ein Fluidgemisch zu schaffen, das aus Phasen unterschiedlicher Dichte besteht und das in axialer Richtung durch einen Ringraum zu transportieren ist, wobei die Achse des Ringraums horizontal oder geneigt sein kann. Diese Aufgabe wird durch den im Anspruch 1 definierten Mischer gelöst.The object of the invention is a static mixer for a fluid mixture to create, which consists of phases of different density and that in Axial direction is to be transported through an annular space, wherein the axis of the annulus may be horizontal or inclined. This task is done by solved defined in claim 1 mixer.

Der statische Mischer umfasst profilierte Lagen, die in einem Ringraum angeordnet sind und die zu einer Zentralachse geneigte, sich kreuzende Strömungskanäle enthalten. Ein Fluidgemisch ist in Achsrichtung unter einer Mischeinwirkung zu transportieren. Jede Lage erstreckt sich über eine Fläche, die quer zur Achse einen geschlossenen oder weitgehend geschlossenen Umfang bildet. Jede Lage umfasst äquivalente Kanäle, die sich auf einer inneren oder äusseren Seite der Lage über zumindest angenähert gleich lange Strecken von einem ersten zu einem zweiten Querschnitt des Ringraums erstrecken, so dass jeder Kanal dem ihn durchströmenden Fluidgemisch eine azimutale Geschwindigkeitskomponente aufzwingt, die für alle äquivalenten Kanäle im wesentlichen gleich gross ist.The static mixer includes profiled layers that are in an annulus are arranged and inclined to a central axis, intersecting Contain flow channels. A fluid mixture is in the axial direction under a To transport mixed action. Each layer extends over an area the transverse to the axis a closed or largely closed Scope forms. Each layer includes equivalent channels that are on one inner or outer side of the situation about at least approximately the same long stretches from a first to a second cross section of the Annular space extend so that each channel to him flowing through Fluid mixture imposes an azimuthal velocity component for all equivalent channels are essentially the same size.

Die abhängigen Ansprüche 2 bis 8 betreffen vorteilhafte Ausführungsformen des erfindungsgemässen Mischers. Verwendungsmöglichkeiten des erfindungsgemässen Mischers sind jeweils Gegenstand der Ansprüche 9 und 10.The dependent claims 2 to 8 relate to advantageous embodiments of the mixer according to the invention. Uses of the The mixer according to the invention are each the subject matter of claims 9 and 10th

Nachfolgend wird die Erfindung anhand der Zeichnungen erläutert. Es zeigen:

Fig. 1
zwei konzentrische Lagen eines erfindungsgemässen Mischers, die eine Kreuzkanalstruktur bilden,
Fig. 2
ausschnittsweise einen Querschnitt durch den erfindungsgemässen Mischer,
Fig. 3
ein Stück einer gefalteten Folie, die sich zur Ausbildung einer Lage des erfindungsgemässen Mischers eignet,
Fig. 4
die Folie der Fig. 3 vor dem Falten mit eingezeichneten Faltkanten,
Fig. 5
eine Konfiguration mit mehreren Mischerelementen, die einen erfindungsgemässen Mischer bilden,
Fig. 6
ein Mischerelement nach dem Stand der Technik, das radiale Lagen einer Kreuzkanalstruktur enthält,
Fig. 7
eine stark vereinfachte Darstellung der Konfiguration der Fig. 5,
Fig. 8 - 10
weitere Konfigurationen.
The invention will be explained with reference to the drawings. Show it:
Fig. 1
two concentric layers of a mixer according to the invention, which form a cross-channel structure,
Fig. 2
a detail of a cross section through the mixer according to the invention,
Fig. 3
a piece of folded film suitable for forming a layer of the mixer according to the invention,
Fig. 4
the film of FIG. 3 before folding with pleated edges,
Fig. 5
a configuration with several mixer elements, which form a mixer according to the invention,
Fig. 6
a mixer element according to the prior art, which contains radial layers of a cross-channel structure,
Fig. 7
a highly simplified representation of the configuration of FIG. 5,
Fig. 8 - 10
further configurations.

Die Figuren 1 und 2 zeigen zu einem erfindungsgemässen Mischer mit zwei konzentrische Lagen 1 und 2 ein Schrägbild der Lagen und einen Querschnitt. Die beiden Lagen 1, 2, die zusammen genommen ein Mischerelement 30 bilden, sind in einem Ringraum 3 zwischen einem Mantelrohr 10 und einem Innenrohr 20 angeordnet. In Fig. 1 sind eine Zentralachse z und ein Winkel ϕ (= Azimut) eingezeichnet. In Fig. 2 sind die Breiten der Lagen 1 und 2 mit a bzw. b bezeichnet, die entsprechenden Ringflächen mit A und B. Die Lagen 1, 2 bilden eine Kreuzkanalstruktur mit sich offen kreuzenden Strömungskanälen 14 und 24; dort findet eine Durchmischung statt. Die randständigen Kanäle 14' und 24' erzwingen eine azimutale Umlagerung. Jede Lage 1, 2 erstreckt sich über eine Fläche, die quer zur Achse z einen geschlossenen Umfang bildet. Die Kanäle 14, 14', 24 bzw. 24' bilden jeweils äquivalente Kanäle: Sie erstrecken sich auf einer inneren oder äusseren Seite der Lage 1, 2 über gleich lange Strecken von einem ersten zu einem zweiten Querschnitt des Ringraums, so dass die Kanäle dem sie durchströmenden Fluidgemisch eine azimutale Geschwindigkeitskomponente 40 bzw. 41 aufzwingen, die in allen äquivalenten Kanälen weitgehend gleich gross ist. Es sei nun angenommen, dass die Zentralachse z horizontal ausgerichtet ist und ein Gas/Flüssigkeitsgemisch teilweise entmischt in das Mischerelement 30 einströmt. Dank der azimutalen Geschwindigkeitskomponenten 40 und 41 wird die Gasphase nach unten, die Flüssigkeitsphase nach oben befördert, so dass sich eine Vermischung der beiden Phasen ergibt. Eine Inhomogenität nimmt dank den azimutalen Geschwindigkeitskomponenten 40 und 41 stark ab.Figures 1 and 2 show a mixer according to the invention with two Concentric layers 1 and 2, an oblique view of the layers and a cross section. The two layers 1, 2, taken together, a mixer element 30th form, are in an annular space 3 between a jacket tube 10 and a Inner tube 20 is arranged. In Fig. 1, a central axis z and an angle φ (= Azimuth) drawn. In Fig. 2, the widths of the layers 1 and 2 with a or b denotes the corresponding ring surfaces with A and B. The layers 1, 2 form a cross-channel structure with open-ended flow channels 14 and 24; There is a thorough mixing. The marginal channels 14 'and 24' force an azimuthal rearrangement. Each layer 1, 2 extends over a surface that is transverse to the axis z a closed perimeter forms. The channels 14, 14 ', 24 and 24' respectively form equivalent channels: you extend on an inner or outer side of the layer 1, 2 via equal distances from a first to a second cross section of Annulus, so that the channels to the fluid mixture flowing through a imposing azimuthal velocity components 40 and 41, respectively, in all equivalent channels is largely the same size. It is now assumed that the central axis z is aligned horizontally and a Gas / liquid mixture partially segregated in the mixer element 30th flows. Thanks to the azimuthal velocity components 40 and 41 the gas phase is transported down, the liquid phase up, so that results in a mixing of the two phases. An inhomogeneity decreases thanks to the azimuthal velocity components 40 and 41 strong from.

Die Lagen 1, 2 müssen nicht notwendigerweise längs ihres Umfangs vollständig geschlossen sein. Es genügt, wenn die Lagen aus zu Zylindern geformten Streifen gebildet sind, deren in axialer Richtung verlaufenden Streifenenden jeweils eine Stossstelle bilden. Statt der Stossstelle darf auch eine Lücke oder eine Überlappung vorliegen. Zwischen den Lagen 1, 2 kann auch ein Blech eingelegt sein, so dass sich die Kanäle 14, 24 nicht offen kreuzen. In diesem Fall wird das Fluidgemisch durch die Kanäle in verschieden gerichtete Teilströme unterteilt; eine Vermischung findet nach Austritt aus dem Mischerelement 30 statt.The layers 1, 2 do not necessarily have along their circumference be completely closed. It is sufficient if the layers to cylinders formed strips are formed, which extend in the axial direction Strip ends in each case form a joint. Instead of the shock may also there is a gap or an overlap. Between the layers 1, 2 can also be inserted a sheet, so that the channels 14, 24 are not open cross. In this case, the fluid mixture through the channels in subdivided differently directed sub-streams; a mixture takes place Exit from the mixer element 30 instead.

Die Lagen 1, 2 werden durch Falten von Materialstreifen hergestellt. Dabei wird jeder gefaltete Streifen zu einem Zylinder geformt, der an einer seitlichen, in Achsrichtung orientierten Stossstelle vollständig oder - bis auf einen schmalen offenen Streifen - beinahe vollständig geschlossen ist. Die Profilierung der Lagen 1, 2 wird mit Vorteil so ausgebildet ist, dass die Kanalwände an der genannten Stossstelle aufeinander passen.The layers 1, 2 are made by folding strips of material. Each folded strip is formed into a cylinder which is attached to a lateral, axially oriented impact point completely or - up to a narrow open strip - almost completely closed. The Profiling of the layers 1, 2 is advantageously designed so that the Channel walls on the aforementioned impact point match.

Fig. 3 zeigt ein Stück einer gefalteten Folie 1', das Teil einer Lage 1 des erfindungsgemässen Mischers ist. Die gleiche Folie (1') in nicht gefaltetem Zustand ist in Fig. 4 abgebildet. Zwischen einer äusseren Faltkante 11 (als Doppellinie dargestellt) und einer inneren Faltkante 12 (Doppellinie) liegt ein angenähert parallelogrammförmiges Flächenstück 16, bei dem die durch die Faltkanten 11 und 12 gebildeten Seitenränder nur näherungsweise parallel zueinander sind. In diesem Flächenstück 16 ist eine diagonale Faltkante 6 (einfache Linie) vorgesehen. Die Faltkante 6 teilt das Flächenstück 16 in zwei Dreiecke 16a und 16b, die zwischen den Kanten 11 und 6 bzw. 12 und 6 liegen. Dank der diagonalen Faltkante 6 sind die beiden Dreiecke 16a und 16b eben ausgebildet. Es kann auch die andere Diagonale des Flächenstücks 16 als Faltkante gewählt werden.Fig. 3 shows a piece of a folded film 1 ', the part of a layer 1 of inventive mixer. The same film (1 ') in unfolded Condition is shown in Fig. 4. Between an outer folding edge 11 (as Double line shown) and an inner fold edge 12 (double line) is located approximately parallelogram-shaped surface piece 16, in which the through Faltkanten 11 and 12 formed side edges only approximately parallel to each other. In this area piece 16 is a diagonal folding edge. 6 (simple line) provided. The folding edge 6 divides the patch 16 in two Triangles 16a and 16b, between the edges 11 and 6 or 12 and 6 lie. Thanks to the diagonal folding edge 6, the two triangles 16 a and 16b just trained. It can also be the other diagonal of the patch 16 can be selected as folding edge.

Bei richtiger Wahl der Abmessungen, die sich berechnen oder mit Methoden der darstellenden Geometrie bestimmen lassen, lässt sich der Streifen 1' der Fig. 4 so falten, dass die Kanten 12 eine zylindrische Fläche 5 (beispielsweise die Oberfläche der Innenwand 20 in Fig. 2) auf einem Kreis 50 in Punkten 15 berühren. Jede Kante 12 schneidet den Kreis 50 im gleichen Winkel. Die freien Enden 13 der Lage 1 und der Kreis 50 liegen auf parallelen Ebenen (nicht dargestellt), bezüglich denen die z-Achse senkrecht steht. Im ungefalteten Zustand, siehe Fig. 4, bilden die freien Enden 13 eine Zickzacklinie. With correct choice of dimensions that can be calculated or with methods of the representative geometry, the strip 1 'of the Fig. 4 so fold that the edges 12 a cylindrical surface 5 (for example the surface of the inner wall 20 in Fig. 2) on a circle 50 in points 15th touch. Each edge 12 intersects the circle 50 at the same angle. The free ends 13 of the layer 1 and the circle 50 lie on parallel planes (not shown) with respect to which the z-axis is perpendicular. in the unfolded state, see Fig. 4, the free ends 13 form a Zigzag line.

Im gefalteten Zustand besteht am Ende 13 eine Lücke zwischen den Faltkanten 12 und der Zylinderfläche 5, deren senkrecht zur Zylinderfläche 5 gemessene Breite in Fig 3 mit c bezeichnet ist. Je kleiner die Höhe h der Lage 1 ist, desto kleiner ist c. Die Höhe h soll so gross gewählt werden, dass sich die Kanten 11 und 12 der Lagen 1 bzw. 2 mindestens zweimal kreuzen, so dass sich die Lagen 1, 2 an den Kreuzungspunkten miteinander verbinden lassen. Die genannte Lücke der Breite c soll möglichst klein und folglich die Höhe h kurz sein. In der Ausführungsform der Fig. 1 ist dies nicht der Fall. Daher ist dort eine Taillierung der Lage 1 gut erkennbar. Eine Taillierung liegt zwar immer vor; sie soll aber weniger ausgeprägt als in Fig. 1 sein. Durch geeignete Wahl der Lagenbreite a und des Neigungswinkels der Faltkanten 11, 12 kann eine optimale Höhe h bestimmt werden.In the folded state is at the end of 13 a gap between the Faltkanten 12 and the cylindrical surface 5, whose perpendicular to the cylindrical surface. 5 measured width in Figure 3 is denoted by c. The smaller the height h of the location 1 is, the smaller is c. The height h should be chosen so large that the edges 11 and 12 of the layers 1 and 2 intersect at least twice, so that the layers 1, 2 connect to each other at the crossing points to let. The said gap of the width c should be as small as possible and consequently the Height h be short. In the embodiment of Fig. 1 this is not the case. Therefore, there is a waist of the situation 1 well recognizable. A sidecut lies while always ahead; but it should be less pronounced than in Fig. 1. By suitable choice of the layer width a and the angle of inclination of the folded edges 11, 12, an optimal height h can be determined.

Um eine gute Mischwirkung zu erzielen, wird eine Vielzahl von Mischerelementen 31, 32, 33, die kleine Höhen h haben, axial aufeinander folgend angeordnet: siehe Fig. 5 Damit auch eine radiale Vermischung möglich ist, können Mischerelemente 7 eingeschoben werden, die radiale, ebenfalls eine Kreuzkanalstruktur bildende Lagen 71, 72 enthalten: Fig. 6. Solche Mischerelemente 7 sind bereits bekannt.To achieve a good mixing effect, a variety of Mixer elements 31, 32, 33, which have small heights h, axially to each other arranged as follows: see Fig. 5 So that also a radial mixing is possible, mixer elements 7 can be inserted, the radial, Also, a cross channel structure forming layers 71, 72 include: Fig. 6. Such mixer elements 7 are already known.

Umfasst der erfindungsgemässe Mischer mindestens zwei hintereinander angeordnete Mischerelemente 31, 32, so können diese azimutal gegeneinander versetzt angeordnet werden. An der Stossstelle 80 (Fig. 5) der Mischerelemente 31, 32 bestehen dann zwischen Lagen 1, die in axialer Richtung benachbart sind, Durchgänge von inneren zu äusseren Kanälen bzw. umgekehrt von äusseren zu inneren Kanälen. Bei einer solchen Anordnung strömt Fluid aus den äusseren in die inneren Kanäle und umgekehrt.The mixer according to the invention comprises at least two consecutive arranged mixer elements 31, 32, so they can azimuthally be offset from each other. At the junction 80 (FIG. 5) of FIG Mixer elements 31, 32 then exist between layers 1, in the axial Direction adjacent, passages from inner to outer channels or vice versa from outer to inner channels. In such a Arrangement flows fluid from the outer to the inner channels and vice versa.

Die Figuren 7 - 10 zeigen im Überblick vier verschiedene Konfigurationen, wobei jene der Fig. 7 der in Fig. 5 dargestellten Konfiguration entspricht. Fig. 8 zeigt eine Konfiguration, bei der Lücken 8 zwischen benachbarten Mischerelementen der Elemente 31 - 33 offen gelassen sind. In diesen Lücken 8 kann eine radiale Vermischung stattfinden. Die Länge der Lücke 8 ist mit Vorteil kleiner als das Fünffache der radialen Breite des Ringraums 3. FIGS. 7-10 show an overview of four different configurations. wherein that of Fig. 7 corresponds to the configuration shown in Fig. 5. FIG. 8 shows a configuration in which gaps 8 between adjacent ones Mixer elements of the elements 31 - 33 are left open. In these Gaps 8 may take place a radial mixing. The length of the gap 8 is advantageously smaller than five times the radial width of the annular space 3.

Fig. 9 stellt eine Konfiguration dar, bei der zusätzlich Mischerelemente 7 gemäss der Fig. 6 vorgesehen sind. In Fig. 10 ist eine Konfiguration zu sehen, bei der benachbarte Mischerelemente 31, 32' oder 32', 33 jeweils eine entgegengesetzt geneigte Kanalrichtung in entsprechenen Lagen 1 oder 2 (vgl. Fig. 1, 5) aufweisen.FIG. 9 shows a configuration in which mixing elements 7 are provided according to FIG. 6. FIG. 10 shows a configuration. at the adjacent mixer elements 31, 32 'or 32', 33 each one opposite inclined channel direction in corresponding positions 1 or 2 (see Fig. 1, 5).

Selbstverständlich können mehr als zwei Lagen 1, 2 in einem Mischerelement 30 vorgesehen sein. Mit Vorteil ist deren Anzahl gerade, insbesondere dann, wenn gewünscht wird, dass der Gesamtdrall des geförderten Fluids praktisch Null ist. Damit der Gesamtdrall weitgehend verschwindet, ist bei einer geradzahligen Anzahl der Lagen zu fordern, dass die Lagen in einem Querschnitt des Ringraums Teilfächen beanspruchen, die für jede Lage zumindest angenähert gleich grosse Flächeninhalte aufweisen. Im Beispiel der Fig. 2 müssen die Lagenbreiten a und b so gewählt werden, dass die Ringflächen A und B gleich gross sind.Of course, more than two layers 1, 2 in a mixer element 30 may be provided. Advantageously their number is even, especially then if it is desired that the total spin of the pumped fluid be practical Is zero. So that the total spin largely disappears, is at a even number of layers to request that the layers in one Cross-section of the annulus stress subfaces, which for each layer have at least approximately the same size areas. For example 2, the ply widths a and b must be chosen so that the Ring surfaces A and B are the same size.

Die in den Zeichnungen dargestellten Ausführungsbeispiele zeigen statische Mischer mit Kanälen, deren Querschnitte dreieckig sind. Die Profile der Lagen können auch gewellt oder anders ausgebildet sein; beispielsweise können die Kanalquerschnitte trapezförmig sein.The embodiments shown in the drawings show static Mixers with channels whose cross sections are triangular. The profiles of the layers can also be wavy or otherwise formed; for example, the Channel cross-sections be trapezoidal.

Der erfindungsgemässe Mischer kann mit Vorteil beim axialen Transport eines Fluidgemisches durch einen Ringraum 3 verwendet werden, wenn das zu transportierende Fluidgemisch 4 aus Phasen unterschiedlicher Dichte besteht. Es kann dabei eine Gruppe oder mehrere Gruppen von Mischerelementen vorgesehen sein, die jeweils eine Mehrzahl gleicher und aufeinander folgend angeordneter Mischerelemente umfassen. Die Zentralachse z des Mischers kann gegenüber einer horizontalen Ebene einen Neigungswinkel einschliessen, der kleiner als 90° ist und der im Extremfall sogar 0° beträgt.The mixer according to the invention can advantageously be used for axial transport a fluid mixture can be used through an annular space 3, if the to be transported fluid mixture 4 of different density phases consists. It can be a group or several groups of Be provided mixer elements, each having a plurality of the same and comprise successively arranged mixer elements. The Central axis z of the mixer can be compared to a horizontal plane one Inclination angle included, which is smaller than 90 ° and in extreme cases even 0 °.

Eine Verwendung des erfindungsgemässen Mischers ist bei einer Bohrung nach Erdöl und/oder Erdgas besonders geeignet. Bei dieser Verwendung wird ein Ringraum eines Bohrkanals mit Einbauten des statischen Mischers ausgestattet, die bei einem Überwachungsgerät angeordnet werden, wobei das Überwachungsgerät für ein den Ringraum durchströmendes Fluidgemisch vorgesehen ist, um eine Messung von Phasenanteilen des Fluidgemisches durchzuführen.One use of the mixer according to the invention is in a bore particularly suitable for crude oil and / or natural gas. In this use will an annulus of a drilling channel with built-in static mixer equipped, which are arranged at a monitor, wherein the monitoring device for a flowing through the annulus Fluid mixture is provided to measure a phase of the Perform fluid mixture.

Beispiele für weitere Verwendungsmöglichkeiten sind wie folgt:

  • a) Vermischung zweier Fluide in einem Ringraum, wobei mindestens eines der Fluide so eingespeist wird, dass beim Eintritt in den Ringraum eine über den Umfang ungleichmässige Konzentrationsverteilung vorliegt.
  • b) Temperaturausgleich in einer Gasturbine vor der Zufuhr der Verbrennungsgasen zu den Turbinenschaufeln.
  • c) Durchführung einer chemischen Reaktion, beispielsweise einer Verbrennung, auf der Oberfläche einer Mischerstruktur, die katalytisch aktives Material trägt; falls die Reaktion in einem Ringraum durchzuführen ist.
  • Examples of other uses are as follows:
  • a) mixing two fluids in an annular space, wherein at least one of the fluids is fed so that when entering the annulus is present over the circumference uneven concentration distribution.
  • b) temperature compensation in a gas turbine before the supply of combustion gases to the turbine blades.
  • c) performing a chemical reaction, such as combustion, on the surface of a mixer structure carrying catalytically active material; if the reaction is to be carried out in an annulus.
  • Claims (10)

    1. A static mixer with profiled layers (1,2) which are arranged in a ring space (3) and which contain mutually crossing flow channels (14, 24) which are inclined relative to a central axis (z), wherein
      a fluid mixture (4) is to be transported in the axial direction in the presence of a mixing action,
      each layer extends over a surface which forms a closed or largely closed periphery transverse to the axis (z),
      each layer includes equivalent channels (14, 14', 24 and 24' respectively) which extend on an inner or outer side of the layer over at least approximately equally long paths from a first to a second cross-section of the ring space, so that each channel imposes an azimuthal velocity component (40, 41) onto the fluid mixture which flows through it which is substantially equally large for all equivalent channels,
      characterized in that the layers (1) are produced by folding material strips and each folded strip is shaped into a cylinder.
    2. Static mixer in accordance with claim 1, characterized in that the ring space (3) is bounded by at least one circular cylindrical surface, for example by the inner surface of a jacket tube (10) and/or the outer surface of an inner tube (20).
    3. Static mixer in accordance with claim 1 or claim 2, characterized in that the layers (1, 2) are arranged in a plurality of mixer elements (31, 32, 33) which follow one another axially; and in that gaps (8) without installed elements can be present between all or individual mixer elements (31, 32, 33), with the length of the gap advantageously being less than five times the radial width of the ring space (3).
    4. Static mixer in accordance with claim 3, characterized in that further mixer elements (7) which have radial layers (71, 72) with profiling are arranged between all or individual mixer elements (31, 32).
    5. Static mixer in accordance with any one of the claims 1 to 4, characterized in that the profiling of the layer (1) is formed such that the channel walls fit onto one another at the ends of the strips oriented in the axial direction.
    6. Static mixer in accordance with claim 5, characterized in that an approximately parallelogram-shaped surface element (16) lies in the layers (1) in each case between an outer and an inner folded edge (11 and 12 respectively); and in that a diagonal folded edge (6) is provided in this surface element.
    7. Static mixer in accordance with any one of the claims 1 to 6, characterized in that the number of layers (1, 2) is even, in particular amounts to two; and in that the layers occupy partial surfaces (A, B) in a cross-section of the ring space (3) which have at least approximately equally large areas for each layer.
    8. Static mixer in accordance with any one of the claims 1 to 6, characterized in that at least two mixer elements (31, 32) are arranged one behind the other and, in this process, are arranged mutually displaced azimuthally, so that passages arise from inner to outer channels and/or vice versa from outer to inner channels respectively at the meeting point (80) of the mixer elements between layers (1) which are adjacent in the axial direction.
    9. Use of a static mixer in accordance with any one of the claims 4 to 8, characterized in that the fluid mixture (4) to be transported consists of phases of different density; in that one or more groups of mixer elements (31, 32, 33) are provided which in each case include a plurality of mixer elements which are the same and are arranged to follow one another; and in that in particular the central axis (z) of the mixer includes an angle of inclination with respect to a horizontal plane which is less than 90° and which amounts to 0° in the extreme case.
    10. Use of a static mixer in accordance with claim 9 in a borehole for petroleum and/ or natural gas, in which a ring space of a borehole passage is equipped with installed elements of the static mixer and in which a monitoring device for a fluid mixture which flows through the ring space is provided by means of which a measurement of phase components of the fluid mixture can be carried out.
    EP01810360A 2000-05-08 2001-04-10 Static mixer with profiled layers Expired - Lifetime EP1153651B1 (en)

    Priority Applications (1)

    Application Number Priority Date Filing Date Title
    EP01810360A EP1153651B1 (en) 2000-05-08 2001-04-10 Static mixer with profiled layers

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    EP00810391 2000-05-08
    EP00810391 2000-05-08
    EP01810360A EP1153651B1 (en) 2000-05-08 2001-04-10 Static mixer with profiled layers

    Publications (2)

    Publication Number Publication Date
    EP1153651A1 EP1153651A1 (en) 2001-11-14
    EP1153651B1 true EP1153651B1 (en) 2005-10-05

    Family

    ID=26073873

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP01810360A Expired - Lifetime EP1153651B1 (en) 2000-05-08 2001-04-10 Static mixer with profiled layers

    Country Status (1)

    Country Link
    EP (1) EP1153651B1 (en)

    Cited By (1)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US10898872B2 (en) 2015-11-13 2021-01-26 Re Mixers, Inc. Static mixer

    Family Cites Families (8)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    BE811142A (en) * 1973-02-23 1974-06-17 LIQUID MIXING DEVICE
    CH563802A5 (en) * 1973-04-18 1975-07-15 Sulzer Ag
    US4111402A (en) * 1976-10-05 1978-09-05 Chemineer, Inc. Motionless mixer
    JPS5549133A (en) * 1978-10-02 1980-04-09 Tokumitsu Kuromatsu Two fluid mixer
    DE3229486C2 (en) * 1982-08-07 1985-01-24 Franz 2000 Hamburg Cukrowicz Static pipe mixer
    JPS6242728A (en) * 1985-08-14 1987-02-24 Ono Bankin Kogyosho:Kk Fluid mixer
    US5407274A (en) * 1992-11-27 1995-04-18 Texaco Inc. Device to equalize steam quality in pipe networks
    DE59409236D1 (en) * 1994-08-15 2000-04-27 Sulzer Chemtech Ag Winterthur Device for treating fluids with UV radiation

    Cited By (2)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US10898872B2 (en) 2015-11-13 2021-01-26 Re Mixers, Inc. Static mixer
    US11786876B2 (en) 2015-11-13 2023-10-17 Re Mixers, Inc. Static mixer

    Also Published As

    Publication number Publication date
    EP1153651A1 (en) 2001-11-14

    Similar Documents

    Publication Publication Date Title
    EP0619133B1 (en) Mixing receptacle
    DE69420732T2 (en) DEVICE FOR MIXING INGREDIENTS IN FLOWING LIQUIDS
    DE60021263T2 (en) STATIC SWIVEL MIXER AND METHOD FOR USE THEREOF
    EP1510247B1 (en) Static mixer with polymorphous structure
    EP0151693B1 (en) Material exchange column
    EP1967806B1 (en) Device for heat exchange and mixing treatment of fluid mediums
    WO2009000642A1 (en) Static mixing element
    DE19501241A1 (en) Static mixer and mixer element for mixing gases, fluids or powders
    DE102016212399B4 (en) rocket engine
    EP3489501B1 (en) Engine, injection head for an engine, missile and method for producing an injection head
    DE8019476U1 (en) STATIC MIXING DEVICE
    WO2008141472A1 (en) Flow channel for a mixer-heat exchanger
    DE3307972A1 (en) TELESCOPIC COLUMN WITH CYLINDRICAL TUBES
    EP0809001A1 (en) Exhaust manifold
    EP3408014A1 (en) Hollow chamber x-mixer heat exchanger
    DE3116557A1 (en) DEVICE FOR INVERTING AND MIXING FLOWING SUBSTANCES
    DE3420290C1 (en) Static mixing part
    DE202011101066U1 (en) Static mixer
    DE2844753A1 (en) METHOD AND DEVICE FOR EXTRUSION PRESSING
    WO2011138162A1 (en) Mixing process and mixing arrangement
    DE2262016A1 (en) Flow mixer tube with serial helical divider strips - with adjacent strips of opposite hand and defining constant total flow area
    EP2714229B1 (en) Filtering device for highly viscous fluids
    EP1153651B1 (en) Static mixer with profiled layers
    DE2811489A1 (en) PIPE MIXER
    EP1467018A1 (en) Device and method for mixing a liquid into a fibrous suspension

    Legal Events

    Date Code Title Description
    PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

    Free format text: ORIGINAL CODE: 0009012

    AK Designated contracting states

    Kind code of ref document: A1

    Designated state(s): CH DE GB LI NL

    Kind code of ref document: A1

    Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

    AX Request for extension of the european patent

    Free format text: AL;LT;LV;MK;RO;SI

    17P Request for examination filed

    Effective date: 20020418

    AKX Designation fees paid

    Free format text: CH DE GB LI NL

    17Q First examination report despatched

    Effective date: 20030819

    GRAP Despatch of communication of intention to grant a patent

    Free format text: ORIGINAL CODE: EPIDOSNIGR1

    GRAS Grant fee paid

    Free format text: ORIGINAL CODE: EPIDOSNIGR3

    GRAA (expected) grant

    Free format text: ORIGINAL CODE: 0009210

    AK Designated contracting states

    Kind code of ref document: B1

    Designated state(s): CH DE GB LI NL

    REG Reference to a national code

    Ref country code: GB

    Ref legal event code: FG4D

    Free format text: NOT ENGLISH

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: EP

    GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

    Effective date: 20051005

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: NV

    Representative=s name: SULZER MANAGEMENT AG PATENTABTEILUNG/0067

    REF Corresponds to:

    Ref document number: 50107590

    Country of ref document: DE

    Date of ref document: 20051110

    Kind code of ref document: P

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: CH

    Payment date: 20060418

    Year of fee payment: 6

    PLBE No opposition filed within time limit

    Free format text: ORIGINAL CODE: 0009261

    STAA Information on the status of an ep patent application or granted ep patent

    Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

    26N No opposition filed

    Effective date: 20060706

    REG Reference to a national code

    Ref country code: CH

    Ref legal event code: PL

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: CH

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20070430

    Ref country code: LI

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20070430

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: DE

    Payment date: 20090422

    Year of fee payment: 9

    Ref country code: NL

    Payment date: 20090415

    Year of fee payment: 9

    PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

    Ref country code: GB

    Payment date: 20090421

    Year of fee payment: 9

    REG Reference to a national code

    Ref country code: NL

    Ref legal event code: V1

    Effective date: 20101101

    GBPC Gb: european patent ceased through non-payment of renewal fee

    Effective date: 20100410

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: NL

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20101101

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: DE

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20101103

    PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

    Ref country code: GB

    Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

    Effective date: 20100410