EP1122299A2 - Laundry composition - Google Patents
Laundry composition Download PDFInfo
- Publication number
- EP1122299A2 EP1122299A2 EP00311581A EP00311581A EP1122299A2 EP 1122299 A2 EP1122299 A2 EP 1122299A2 EP 00311581 A EP00311581 A EP 00311581A EP 00311581 A EP00311581 A EP 00311581A EP 1122299 A2 EP1122299 A2 EP 1122299A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- particles
- composition
- liquid
- agent
- dye
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
and wherein the particles are stable in the acidic liquid but dissolve or disperse under alkaline washing conditions.
Cellulose acetate phthalate (Cellacephate®, CAP), vinyl acetate crotonic acid copolymer (Luviset®), methacrylic acid, (meth)acrylic acid ester copolymer (Eudragit®) and hydroxypropyl methylcellulose phthalate.
Composition | P1 | P2 |
% | % | |
Stearic acid (carrier) | 60 | 50 |
Na HEDP (chelating agent) | 20 | 15 |
EUDRAGIT S100 | 15 | 25 |
Diisopropyl adipate (plasticizer for coating) | 5 | 10 |
Composition | E1 | E2 | V1 |
% | % | % | |
Hydrogen peroxide | 6.50 | 6.50 | 6.50 |
LIALET 125/5 | 7.00 | 7.00 | 7.00 |
Na HEDP | 0.12 | 0.12 | 0.7 |
Particles | 4.37 | 5.00 | 0 |
POLYGEL DA | 0.20 | 0.20 | 0.20 |
Perfume | 0.20 | 0.20 | 0.20 |
Pigment | 0.001 | 0.001 | 0 |
Deionised water | to 100 | to 100 | To 100 |
Viscosity (cps, at 20°C) | 500-1000 | 500-1000 | 1000-1500 |
PH | 4.2 | 4.2 | 4.2 |
Color/fabric | Evaluation type | Composition | Delta | ||
E1 | E2 | V1 | |||
Sirius Blue CLB on cotton | Visual | 2.0 | 3.0 | + 1.0 | |
Instrumental | 6.0 | 9.6 | + 3.6 | ||
Sirius Blue CLB on viscose | Visual | 2.0 | 3.0 | + 1.0 | |
Instrumental | 7.4 | 10.7 | + 3.3 | ||
Sirius Red SLR on cotton | Visual | 2.5 | 3.0 | + 0.5 | |
Instrumental | 5.4 | 11.5 | + 1.8 | ||
Sirius Red SLR on viscose | Visual | 2.0 | 3.0 | + 1.0 | |
Instrumental | 5.4 | 5.8 | + 0.4 | ||
Sirius Yellow SLG on cotton | Visual | 2.5 | 3.5 | + 1.0 | |
Instrumental | 11.4 | 14.0 | +2.6 | ||
Sirius Yellow on viscose | Visual | 2.0 | 3.0 | + 1.0 | |
Instrumental | 8.2 | 9.7 | + 1.5 |
Stearic acid | 81% |
Titania powder (rutile, sub-micron) | 9% |
EUDRAGIT copolymer | 9% |
Diisopropyl adipate | 1% |
Ingredients | % |
Hydrogen peroxide | 6.5% |
Na HEDP | 0.2% |
LIALET 125/5 | 7.0% |
POLYGEL DA | 0.2% |
Blue pigment | 0.001% |
Phthalocyanine green dye | 0.0002% |
Perfume | 0.27% |
Particles | 0.2% |
Sodium hydroxide | to pH 4.3 |
Deionised water | to 100% |
Ingredients | % |
Hydrogen peroxide | 6.5% |
LIALET 125/5 | 7.0% |
VERSENEX 80E | 0.3% |
POLYGEL DA | 0.3% |
Blue dye | 0.0005% |
Perfume | 0.27% |
Particles | 0.2% |
Sodium hydroxide | to pH 4.3 |
Deionised water | to 100% |
Ingredients | % |
Hydrogen peroxide | 6.5% |
LIALET 125/5 | 7.0% |
DETAREX | 0.12% |
POLYGEL DA | 0.3% |
Blue dye | 0.0005% |
Perfume | 0.27% |
Particles | 0.2% |
Sodium hydroxide | to pH 4.3 |
Deionised water | to 100% |
Ingredients | % |
Hydrogen peroxide | 6.5% |
LIALET 125/5 | 7.0% |
ACRILAM C20 | 0.2% |
POLYGEL DA | 0.20% |
OXY RITE | 0.15% |
Blue dye | 0.0005% |
Perfume | 0.27% |
Particles | 0.2% |
Sodium hydroxide | to pH 4.3 |
Deionised water | to 100% |
% PVNO in particles | Reflectance value - white part | Reflectance value -colored part |
0 (comparison) | 4.7 | 4.2 |
10 (composition E7) | 3.4 | 4.3 |
20 (composition E8) | 2.2 | 4.3 |
30 (composition E9) | 1.1 | 4.4 |
40 (composition E10) | 0.8 | 4.5 |
Ingredients | % |
Hydrogen peroxide | 6.5% |
LIALET 125/5 | 7.0% |
ACRILAM C20 | 0.3% |
POLYGEL DA | 0.2% |
Xanthan gum (stabiliser) | 0.05% |
Blue pigment | 0.001% |
Phthalocyanine green dye | 0.0002% |
Perfume | 0.27% |
Particles (see above) | 0.2% |
Sodium hydroxide | To pH 4.3 |
Deionised water | To 100% |
Viscosity: after 24 h at 20°C (cps) | 1400 | ||
After 6 days | 2°C | 1180 | All particles remain in homogenous suspension |
20°C | 1340 | ||
40°C | 1540 | ||
After 1 month | 2°C | 1120 | All particles remain in homogenous suspension |
20°C | 1340 | ||
40°C | 1650 | ||
After 2.5 months | 2°C | 1000 | All particles remain in homogenous suspension |
20°C | 1200 | ||
40°C | 1100 | ||
After 3 months | 2°C | 1130 | All particles remain in homogenous suspension |
20°C | 1380 | ||
40°C | 900 |
Claims (10)
- A laundry composition comprising:a) an acidic liquid containing hydrogen peroxide, andb) particles suspended in the liquid
and wherein the particles are stable in the acidic liquid but dissolve or disperse under alkaline washing conditions. - A composition as claimed in claim 1, wherein the core includes a chelating agent.
- A composition as claimed in claim 2, wherein the chelating agent comprises a compound selected from a phosphonate and a polyacetic derivative and a polyacrylic derivative.
- A composition as claimed in any preceding claim, wherein the core includes a dye-transfer inhibitor.
- A composition as claimed in any of claims 2 to 4, wherein the core additionally includes one or more compounds selected from an anti-fading agent, an anti-bacterial agent, a fabric softener, a transition metal compound and an optical brightener.
- A composition as claimed in any preceding claim, wherein the particles are of mean size 0.5 mm to 3 mm.
- A composition as claimed in any preceding claim, wherein the particles have a density which is within 0.2 g/cm3 of the density of the liquid.
- A composition as claimed in any preceding claim, wherein the liquid contains a nonionic surfactant.
- A composition as claimed in any preceding claim, wherein the liquid contains a chelating agent.
- A method of laundering fabrics, using a laundry detergent and, in addition, a composition as claimed in any preceding claim.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20000311581 EP1122299B1 (en) | 1999-12-28 | 2000-12-22 | Laundry composition |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP99125979 | 1999-12-28 | ||
EP99125979A EP1113069A1 (en) | 1999-12-28 | 1999-12-28 | Liquid peroxide bleaches comprising speckles in suspension |
EP20000311581 EP1122299B1 (en) | 1999-12-28 | 2000-12-22 | Laundry composition |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1122299A2 true EP1122299A2 (en) | 2001-08-08 |
EP1122299A3 EP1122299A3 (en) | 2001-10-04 |
EP1122299B1 EP1122299B1 (en) | 2005-07-06 |
Family
ID=26073391
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP20000311581 Expired - Lifetime EP1122299B1 (en) | 1999-12-28 | 2000-12-22 | Laundry composition |
Country Status (1)
Country | Link |
---|---|
EP (1) | EP1122299B1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009047745A2 (en) * | 2009-01-29 | 2009-04-16 | The Procter & Gamble Company | Encapsulates |
WO2009083941A2 (en) * | 2009-01-29 | 2009-07-09 | The Procter & Gamble Company | Encapsulates |
EP2208776A1 (en) * | 2009-01-16 | 2010-07-21 | The Procter and Gamble Company | Bleaching compositions containing perfume microcapsules |
WO2012164266A1 (en) * | 2011-05-27 | 2012-12-06 | Reckitt Benckiser N.V. | Composition |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0201958A1 (en) * | 1985-05-07 | 1986-11-20 | Akzo N.V. | Pourable detergent and bleach compositions |
US4642198A (en) * | 1984-05-01 | 1987-02-10 | Lever Brothers Company | Liquid bleaching compositions |
WO1987007292A1 (en) * | 1986-05-21 | 1987-12-03 | Novo Industri A/S | Coated detergent enzymes |
DE4040654A1 (en) * | 1990-12-19 | 1992-06-25 | Henkel Kgaa | GRANULES WITH COVERED BLEACH ACTIVATOR |
WO1995014077A1 (en) * | 1993-11-16 | 1995-05-26 | Warwick International Group Limited | Bleach activator compositions |
US5460743A (en) * | 1994-05-09 | 1995-10-24 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid cleaning composition containing polyvinyl ether encapsulated particles |
US5641739A (en) * | 1995-05-01 | 1997-06-24 | The Procter & Gamble Company | Aqueous detergent compositions containing chelants which remain undissolved under acidic conditions |
DE29903534U1 (en) * | 1999-02-27 | 1999-06-17 | Henkel Kgaa | Peroxide-containing preparations with colorants in microcapsules |
DE19855346A1 (en) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Preparations containing peroxide with stabilized optical brighteners |
-
2000
- 2000-12-22 EP EP20000311581 patent/EP1122299B1/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4642198A (en) * | 1984-05-01 | 1987-02-10 | Lever Brothers Company | Liquid bleaching compositions |
EP0201958A1 (en) * | 1985-05-07 | 1986-11-20 | Akzo N.V. | Pourable detergent and bleach compositions |
WO1987007292A1 (en) * | 1986-05-21 | 1987-12-03 | Novo Industri A/S | Coated detergent enzymes |
DE4040654A1 (en) * | 1990-12-19 | 1992-06-25 | Henkel Kgaa | GRANULES WITH COVERED BLEACH ACTIVATOR |
WO1995014077A1 (en) * | 1993-11-16 | 1995-05-26 | Warwick International Group Limited | Bleach activator compositions |
US5460743A (en) * | 1994-05-09 | 1995-10-24 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid cleaning composition containing polyvinyl ether encapsulated particles |
US5641739A (en) * | 1995-05-01 | 1997-06-24 | The Procter & Gamble Company | Aqueous detergent compositions containing chelants which remain undissolved under acidic conditions |
DE19855346A1 (en) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Preparations containing peroxide with stabilized optical brighteners |
DE29903534U1 (en) * | 1999-02-27 | 1999-06-17 | Henkel Kgaa | Peroxide-containing preparations with colorants in microcapsules |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2208776A1 (en) * | 2009-01-16 | 2010-07-21 | The Procter and Gamble Company | Bleaching compositions containing perfume microcapsules |
WO2010083125A1 (en) * | 2009-01-16 | 2010-07-22 | The Procter & Gamble Company | Bleaching compositions containing perfume microcapsules |
WO2009047745A2 (en) * | 2009-01-29 | 2009-04-16 | The Procter & Gamble Company | Encapsulates |
WO2009083941A2 (en) * | 2009-01-29 | 2009-07-09 | The Procter & Gamble Company | Encapsulates |
WO2009083941A3 (en) * | 2009-01-29 | 2009-12-10 | The Procter & Gamble Company | Encapsulates |
WO2009047745A3 (en) * | 2009-01-29 | 2009-12-10 | The Procter & Gamble Company | Encapsulates |
JP2012516371A (en) * | 2009-01-29 | 2012-07-19 | ザ プロクター アンド ギャンブル カンパニー | Inclusion body |
WO2012164266A1 (en) * | 2011-05-27 | 2012-12-06 | Reckitt Benckiser N.V. | Composition |
Also Published As
Publication number | Publication date |
---|---|
EP1122299B1 (en) | 2005-07-06 |
EP1122299A3 (en) | 2001-10-04 |
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