EP1115562A2 - Foamed facer and insulation boards made therefrom - Google Patents
Foamed facer and insulation boards made therefromInfo
- Publication number
- EP1115562A2 EP1115562A2 EP99945214A EP99945214A EP1115562A2 EP 1115562 A2 EP1115562 A2 EP 1115562A2 EP 99945214 A EP99945214 A EP 99945214A EP 99945214 A EP99945214 A EP 99945214A EP 1115562 A2 EP1115562 A2 EP 1115562A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- facer
- insulation board
- mat
- core
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009413 insulation Methods 0.000 title claims abstract description 52
- 239000000203 mixture Substances 0.000 claims abstract description 42
- 239000006260 foam Substances 0.000 claims abstract description 36
- 239000000835 fiber Substances 0.000 claims abstract description 33
- 229920000126 latex Polymers 0.000 claims abstract description 26
- 239000004816 latex Substances 0.000 claims abstract description 24
- 239000011521 glass Substances 0.000 claims abstract description 13
- 238000004519 manufacturing process Methods 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000011347 resin Substances 0.000 claims abstract description 7
- 229920005989 resin Polymers 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 5
- 230000000979 retarding effect Effects 0.000 claims abstract 2
- 238000005728 strengthening Methods 0.000 claims abstract 2
- 238000000576 coating method Methods 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 29
- 239000003365 glass fiber Substances 0.000 claims description 11
- -1 C22 fatty acid Chemical class 0.000 claims description 10
- JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical compound [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 7
- 239000008199 coating composition Substances 0.000 claims description 7
- 239000004604 Blowing Agent Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 238000003475 lamination Methods 0.000 claims description 6
- 229940088990 ammonium stearate Drugs 0.000 claims description 5
- 239000003063 flame retardant Substances 0.000 claims description 5
- 238000005187 foaming Methods 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000012963 UV stabilizer Substances 0.000 claims description 3
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical group O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 239000000546 pharmaceutical excipient Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000003017 thermal stabilizer Substances 0.000 claims description 3
- 239000003086 colorant Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000011256 inorganic filler Substances 0.000 claims description 2
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 2
- 239000013036 UV Light Stabilizer Substances 0.000 claims 1
- 238000009435 building construction Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 239000011230 binding agent Substances 0.000 abstract description 10
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 4
- 230000009974 thixotropic effect Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 2
- 239000012764 mineral filler Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000011162 core material Substances 0.000 description 40
- 239000000126 substance Substances 0.000 description 15
- 238000001723 curing Methods 0.000 description 14
- 239000011888 foil Substances 0.000 description 9
- 229920000582 polyisocyanurate Polymers 0.000 description 9
- 239000011495 polyisocyanurate Substances 0.000 description 9
- 230000032798 delamination Effects 0.000 description 7
- 229920002635 polyurethane Polymers 0.000 description 7
- 239000004814 polyurethane Substances 0.000 description 7
- 239000004800 polyvinyl chloride Substances 0.000 description 7
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 239000010426 asphalt Substances 0.000 description 6
- 239000011152 fibreglass Substances 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 4
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 229920003270 Cymel® Polymers 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000010451 perlite Substances 0.000 description 2
- 235000019362 perlite Nutrition 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 241000208140 Acer Species 0.000 description 1
- GEHMBYLTCISYNY-UHFFFAOYSA-N Ammonium sulfamate Chemical compound [NH4+].NS([O-])(=O)=O GEHMBYLTCISYNY-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000012792 core layer Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 229920001821 foam rubber Polymers 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical group O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 230000004313 glare Effects 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000002085 persistent effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000008257 shaving cream Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
- E04B1/00—Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
- E04B1/62—Insulation or other protection; Elements or use of specified material therefor
- E04B1/74—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
- E04B1/76—Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
- E04B1/78—Heat insulating elements
- E04B1/80—Heat insulating elements slab-shaped
Definitions
- Rigid polymeric foam insulation laminates have been used for many years by the construction industry. Uses include commercial roof insulation boards utilized under asphaltic built-up roof (BUR) membranes as well as under various single ply membranes such as EPDM rubber, PVC, modified bitumen membranes and the like . Other uses include residential insulation, as sheathing under siding, and as roof insulation under asphalt shingles and concrete tiles .
- BUR asphaltic built-up roof
- Such insulation often takes the form of a core polymeric foamed thermoset material such as polyurethane, polyisocyanurate, polyurethane modified polyisocyanurate (often referred to as polyiso) or phenolic resin, applied between two facing sheets .
- a core polymeric foamed thermoset material such as polyurethane, polyisocyanurate, polyurethane modified polyisocyanurate (often referred to as polyiso) or phenolic resin
- insulation boards are generally manufactured on production lines where a liquid core chemical mixture is poured over a bottom facer, foaming up to contact a top facer in a constrained rise laminator.
- the reaction of the chemical mixture causing foaming is generally exothermic, as curing via polymerization and crosslinking occurs in the laminator .
- the curing exotherm lasts well into the time the resulting rigid boards are cut, stacked and warehoused. The exotherm can continue for as long as 4 days and the mixture can reach temperatures as high as 325°F.
- Desirable properties for the facers include flexibility, high tensile and tear strength and resistance to thermal degradation. Facer porosity should be low and the thickness of the facer coating should be sufficient to prevent bleed-through of the liquid chemicals prior to foaming. Additionally, facers should exhibit good adhesion to the core foam insulation and be inert to the effects of extraneous chemicals which may be present in the mixture, especially blowing agents that also behave as solvents . Blowing agents currently in use include chlorofluorocarbons like HCFC-141b and R-22 as well as hydrocarbons such as n-pentane, cyclo-pentane and iso-pentane .
- the facer should provide mechanical stability as well as water and weather resistance since, upon installation, they may be exposed to persistent rain, high humidity, ultraviolet light and excessive heat. Additionally, the facers must be puncture and scuff resistant to survive being nailed and walked on. Withstanding temperatures up to 500°F, as encountered in hot asphalt applications , as well as resistance to the deleterious effects of adhesive solvents used in single ply roofing membrane applications while strongly bonding to the adhesives themselves are also important facer properties .
- facer materials have included asphalt saturated cellulosic felts, fiberglass mats, asphalt emulsion coated fiberglass mats , aluminum foil/Kraft/foil, glass fiber modified cellulosic felts, glass mats onto which polymeric films have been extruded, and glass mats coated with polymeric latex/inorganic binder coatings.
- asphalt- containing products are not compatible with PVC single ply roofing membranes.
- Fiberglass mats are subject to excessive bleed-through of foamable core chemicals. Aluminum facers and foils reflect heat into the foam during processing which leads to disruption of cell structure, delamination and warping.
- glass mats coated with polymer latex/inorganic binder mixtures have been found to be brittle; conversely, glass fiber modified cellulosic felts are susceptible to moisture absorption aggravating board warping in damp or wet environments .
- U.S. Patent No. 5,001,005 describes a facing sheet composed of glass fibers and a non-asphaltic binder .
- the facer contains 60-90% glass fibers, which high fiber content does not provide sufficient binder to close the sheet's pores or to provide desired sheet strength.
- U.S. Patent No. 5,112,678 discloses a facer prepared by applying to a fiberglass mat a flowable polymer latex and an inorganic binder coating.
- Another object is to provide a facer which exhibits superior adhesion to polyiso foam of an insulation board core material .
- the non-asphaltic, non-cellulosic facer of the present invention comprises a dry, preformed fibrous mat substrate on which is coated a pre-frothed or pre-foamed composition containing a natural or synthetic thixotropic latex polymer, a surfactant and an inorganic mineral filler .
- the composition may optionally contain up to about 15 wt.% of extraneous additives, which include a flame retardant, dye, thickener, porosity reducing agent, thermal and/or UV stabilizers and the like, to provide a foamed facer product having, on a dry weight basis, less than 50% fiber in the mat.
- the preferred facer product contains 30 to 46 wt.% of fiber in the composition consisting of mat fiber with binder and latex in the coating mixture .
- the foamed coating composition applied to the preformed mat contains on a dry weight basis between about 15 and about 80 wt.% of the thixotropic polymer latex, between 0.01 and about 80 wt.% filler, between about 0.5 and about 10 wt.% foam supporting surfactant and 0 to 15 wt.% extraneous additives.
- the fibers of the mat employed in this invention include any of the non-cellulosic types, such as fibers of glass, polyester, polypropylene, polyester/polyethylene/teraphthalate copolymers, hybrid types such as polyethylene/glass fibers and other conventional non-cellulosic fibers .
- Mats having glass fibers in random orientation are preferred for their resistance to heat generated during the manufacture of insulation boards and flame resistance in the finished product.
- the fibrous mats of the invention generally of between about 10 and about 30 mils thickness, conventionally contain a binder which is incorporated during mat formation to fix the fibers in a self- sustaining solid web and to prevent loss of fibers during subsequent processing and handling.
- binders include phenol- , melamine- and/or urea- ormaldehyde resins or mixtures thereof.
- the mats having glass fibers in the range of from about 3 to about 20 microns, most desirably 10-18 microns, in diameter and a length of from about 0.25 to about 1.75 inch, most desirably a length of 0.75-1.5 inch.
- the fillers useful in the present coating mixture include conventional inorganic types such as clays, mica, talc, limestone, kaolin, other stone dusts, gypsum, aluminum silicate (e.g. Ecca Tex 561) , flame retardant aluminum trihydrate , ammonium sulfamate , antimony oxide , calcium silicate, calcium sulfate, and mixtures thereof.
- inorganic types such as clays, mica, talc, limestone, kaolin, other stone dusts, gypsum, aluminum silicate (e.g. Ecca Tex 561) , flame retardant aluminum trihydrate , ammonium sulfamate , antimony oxide , calcium silicate, calcium sulfate, and mixtures thereof.
- Surfactants employed in the coating composition are organic types suitable for stabilizing latices , such as for example, ammonium salts of a Cio to C 22 fatty acid, e.g. ammonium stearate (STANFAX 320) .
- One or more surfactants can be employed in the coating composition to promote the formation of foam and to maintain the foam structure of the coating before curing.
- the latex component of the coating composition includes latex polymers of natural rubber as well as synthetic latices including copolymers of styrene and butadiene and acrylic based resins .
- Representative examples of these are polyvinyl chloride, styrene/acrylic or methacrylic esters, ethylene/vinyl chloride and polyurethane , polyisoprene , polyvinylidene chloride , polyvinyl acetate/polyvinyl chloride and synthetic rubbers such as SBS, SBR, neoprene , etc. and any other thixotropic latex polymer and mixtures of the foregoing.
- the mat coating mixture of the invention is obtained from a frothed or foamed 15-80 wt.% aqueous emulsion, dispersion or suspension, which is prefoamed by incorporating air in the aqueous liquid mixture , e.g. by blowing or mixing, with vigorous agitation in the presence or absence of a conventional blowing agent.
- the resulting frothed or foamed, aerated composition is then coated to a thickness of from about 5 to about 100 mils on the preformed mat surface under ambient conditions using a knife blade, a roller or any other convenient method of application.
- the foam coated mat is then dried at below its cure temperature to provide a foamed, self-supporting product having a reduced coating thickness of up to 90 mils which adheres to the mat surface.
- the foamed coated mat is dried and cured simultaneously.
- the resulting facer product of this invention is desirably flexible and possesses low permability to liquid chemicals used for insulation cores as well as superior dimensional stability and high tensile strength after curing.
- This product comprising the mat having an adhered surface coating of a prefoamed latex/filler/surfactant, can be fed directly to insulation board manufacture, e.g. a constricted rise laminator, wherein the uncoated fiber surface of the mat contacts at least one exposed surface of a foamed or foamable thermosetting non-elastomeric core in the manufacture of an insulation board as described hereinaf er .
- the foamed coating of the present facer can be formed in the absence or presence of a blowing agent to provide a composition of reduced density, which density can be reduced from above about 2 g/cc to as little as 0.15 g/cc.
- the consistency of the foam is such that the coating mixture does not penetrate through the mat and ideally simulates the consistency of shaving cream.
- the amount of air incorporated into the foamable mixture prior to coating is between about 5% and about 80% by volume for optimal consistency and the resulting foamed mixture has bubble openings sufficiently small so as to inhibit liquid bleed through the mat.
- Applying a film or laminating a layer of impervious resin or polymer over the foamed surface to provide a trilayered facer member can provide a totally liquid impervious surface on the facer, in special cases where such is desired.
- a top seal coat of a non-foamed latex is suitable for this purpose.
- a thermoplastic such as polyethylene powder or unexpanded polystyrene beads can be used as a filler which melts at the drying/curing temperatures to close substantially all pores of the pervious coating.
- Expandable excipients and additives such as cellulose can also be used for this purpose; although the use of a seal coat is neither needed nor recommended.
- the facer of the invention having a foamed cellular coating contains latent exothermic energy and has a higher potential heat capacity upon entering the laminator; thus lowering the lamination cure time and prolonging the generation of heat by acting as an insulator during curing in the post cure stack.
- This advantage eliminates the need for heat retaining members at the top and bottom of the stack and significantly reduces the prior problem of the board' s susceptibility to cold temperature delamination .
- the foamed coating on the facer is dried and/or cured, the bonding strength between the uncoated fibers and the core material in the resulting product is enhanced due to reduced penetration of the coating mixture into the mat by reason of its prefoamed state.
- the core material is either poured onto the uncoated fibrous surface of the facer or laminated thereto with adhesive or bonding agent .
- Any pressure which may be applied during lamination in the insulation board manufacture is less than that required to cause a 50% reduction in the thickness of the foamed facer coating and insufficient to result in damage or crushing of the mat fibers in the finished insulation board product.
- the weight of the present facer can vary from about 40 to about 300 g/sq. meter and the foamed facer sheet can have a thickness up to about 100 mils depending on the preference of the consumer .
- laticies which can be crosslinked can be selected.
- the present latex coating composition may additionally contain a minor amount, up to 15%, preferably less than about 3 wt.%, of a conventional thickening agent, for example an acrylic polymer thickener, e.g. (ACRYSOL ASE 95NP and/or 60NP) and the like.
- a conventional thickening agent for example an acrylic polymer thickener, e.g. (ACRYSOL ASE 95NP and/or 60NP) and the like.
- Other inert excipients such as a UV or thermal stabilizer, a conventional coloring agent, texturizing agent, reinforcing or crosslinking agent, (e.g. CYMEL 303 resin) and/or blowing agent may also be included in the coating mixture; although addition of these additives in a minor amount of less than 2 wt.% are preferred.
- the insulation boards for which the present facer is particularly suited, comprise conventional thermosetting or thermoplastic foam cores, such as foamed polyurethane or polyurethane modified polyisocyanurate or phenol-formaldehyde cores disposed between a pair of facer members which are laminated to the core surf ces .
- foamed polyurethane or polyurethane modified polyisocyanurate or phenol-formaldehyde cores disposed between a pair of facer members which are laminated to the core surf ces .
- Other non-elastomeric foamable chemicals such as polyvinyl chloride, polystyrene, polyethylene, polypropylene, and others conventionally employed as core material can also be employed as the insulation board core of this invention.
- Rigid foamed cores of this type are described for example in U. S. Patent 4,351,873, incorporated herein by reference .
- the present facers are also suitable for sheathing a siding underlayment generally of a thickness up to about 1 inch and composed of a non-elastic core material of a chemical or chemical mixture similar to that of the insulation core.
- a siding underlayment generally of a thickness up to about 1 inch and composed of a non-elastic core material of a chemical or chemical mixture similar to that of the insulation core.
- instant facer eliminates the need for expensive foil facings which hold and reflect heat and often cause warping and deterioration of wood overlayment. Also, foil and similar facings are easily punctured which gives rise to moisture attack.
- a roll of the present foamed facer sheet product is passed, with its uncoated fiber surface opposite the core surface, to a laminating zone .
- the board core foam precursor chemical or mixture of chemicals can be poured onto the non-coated fiber surface of the facer sheet or the core of the insulation board can be prefoamed to a self-sustaining consistency.
- a first facer of this invention with its uncoated surface abutting the core, is placed below the core .
- the fiber surface of a second facer is positioned and spaced above the core to allow for core expansion, e.g. in a constricted rise laminator, where the assembly undergoes an exothermic reaction and curing is initiated.
- one of the first and second facers can be of the same or of a different composition than that of this invention; although it is preferred that both of these facers be those of the invention described herein. More specifically, one of the facer sheets may be selected from those conventionally employed, such as for example a cellulose or cellulose-glass hybrid felt sheet, perlite, aluminum foil, multilaminated sheets of foil and Kraft, uncoated or coated fiber glass mats; although the second facer sheet of the present invention enhances the advantages described herein.
- the core foam As the core foam is spread on the fibrous surface of the first facer sheet entering the laminator, it undergoes an exothermic reaction which can attain a temperature up to about 200°F.
- the core foam rises to contact the undersurface of the second facer and hardens thereon; thus providing a rigid insulating foam core interposed or sandwiched between two acer sheets .
- the resulting product can then be cut into boards of desired size and shape .
- the heat of the exothermic reaction involving polymerization and/or crosslinking is autogenerated in both the laminator and in the subsequent stacking of insulation boards to insure complete curing of the core and surface coating of the facer. Curing temperatures during stacking can rise up to about 325°F over a period of up to 4 days.
- the top and bottom positioning of the facer sheets can be reversed so that the facer of this invention is fed and spaced above a conventional facer in a manner such that its non-coated fibrous surface faces the foamable insulating core chemical being contacted on its under surface with another facer shee .
- the later procedure is practiced where one facer is a rigid sheet, as in a perlite or particle board facer as opposed to the flexible facer of this invention which can be fed to the laminator as a continuous roll .
- the foamable insulating core chemical is surfaced on the rigid facer member and rises to engage the fibrous uncoated surface of the present facer .
- the latex of the present facer surface layer which, due to its comparatively thick latex foam, and low fiber to coating latex ratio, more efficiently retains heat between the layers of the roll .
- lamination of the core can be completed at a faster rate and stacking accomplished without damage to the laminate .
- this retention of heat during curing improves core bonding and significantly reduces subsequent "cold temperature delamination" in the product, which is caused by failure of the top layer of insulation to completely cure due to cooler temperature exposure during stacking after leaving the laminator.
- the insulation boards incorporating the present facers are useful in commercial roof insulation, residential or commercial wall sheathing etc.
- the present insulation board has a core thickness which may vary widely, for example between about 0.5 and about 4 inches or more .
- Polyurethane or polyisocyanurate are most commonly employed as core materials ; although other non- elastomeric, foamable chemicals are also employed. Examples of the later include polyvinyl chloride , polystyrene, phenolic resins and the like.
- the facers and the insulation board products of this invention exhibit significantly higher tensile strength than those containing 60-90 wt.% fibers.
- the present facers also possess resistance to cracking at low temperatures and exceptionally superior dimensional stability and flame retardance . Because of their superior strength and flexibility, the present facer can find broader application, such as non-foil, non-glare sheathings , as shingle underlayment, separation or barrier sheets and the like .
- a 473 ml metal can with a low shear mixer was employed to combine a 51.5 % aqueous solution of a self crosslinkable acrylic latex (Rohm & Haas, E-693) , a 23.5% aqueous clay slurry (Ecca Tex 561) , a mixture of a melamine crosslinking agent (CYMEL 303) , an ammonium stearate foam stabilizer (STANFAX 320) , an acrylic polymer thickening agent (Acrysol ASE 95NP) and carbon black pigment in amounts shown in following Table 1.
- the above ingredients were thoroughly mixed for about 10 minutes and then foamed using a high speed Kitchen Aid mixer to produce a foam having a density of 0.2 g./cc.
- the Brookfield viscosity of the foamed mixture using an LVT #4 spindle at 30 rpm, was 1,500 cps . TABLE 1
- the above foamed latex mixture was coated onto the upper surface of a preformed glass fiber mat containing 27.5 wt.% urea-formaldehyde binder and having 72.5 wt.% of average ⁇ te inch long filaments of 15.9 micron average diameter. Coating was accomplished using a Gardner drawdown gauge set to achieve a coating thickness of 30 mils on the mat. The resulting sample was dried in an oven at 125°C. for 3 minutes and then cured at 150°C. for an additional 3 minutes .
- Example 1 was repeated except that self- crosslinkable acrylic (RHOPLEX B-959) was substituted for latex (E-693) and the dried prefoamed mixture on the mat was not cured.
- the unfoamed mixture of this example had a Brookfield viscosity of 3,600 cps .
- the uncured, foam-coated mat of this example was introduced to a laminator wherein the uncoated fiber under surface of the mat was contacted with a foamed polyurethane/isocyanurate core of an insulation board and the simultaneous curing of the mat foam and the core was initiated. After about 1-2 minutes in the laminator, at a temperature of about 120° to 200°C, the laminated board was cut into 4 x 8 foot boards and the boards squares stacked in units of 25 members to complete curing over a period of 2.5 days .
- Example 1 was repeated except that an additional 45 g of aluminum trihydrate (ALCOA GRADE C-320) was added to the coating mixture to increase flame retardance of the facer.
- the Brookfield viscosity of the unfoamed mixture was 2,200 cps and the foam had a density of 0.23 g/cc.
- Conventional facers most commonly employed are non- coated, cellulose fiber mats which may or may not be reinforced with a minor amount of glass fibers .
- Examples A and B represent this type .
- Example A is reinforced with 18% of 1M inch long glass fibers
- Example B is reinforced with 13% of less than 1/8 inch long glass ibers .
- a facer of this type is represented as Sample C .
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Architecture (AREA)
- Textile Engineering (AREA)
- Acoustics & Sound (AREA)
- Electromagnetism (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Laminated Bodies (AREA)
- Building Environments (AREA)
- Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
- Paints Or Removers (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Finishing Walls (AREA)
- Refrigerator Housings (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
Claims
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9945198P | 1998-09-08 | 1998-09-08 | |
US99451P | 1998-09-08 | ||
US376247 | 1999-08-18 | ||
US376275 | 1999-08-18 | ||
US09/376,275 US6365533B1 (en) | 1998-09-08 | 1999-08-18 | Foamed facer and insulation boards made therefrom cross-reference to related patent application |
US09/376,247 US6368991B1 (en) | 1998-09-08 | 1999-08-18 | Foamed facer and insulation boards made therefrom |
PCT/US1999/019499 WO2000014358A2 (en) | 1998-09-08 | 1999-08-26 | Foamed facer and insulation boards made therefrom |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1115562A2 true EP1115562A2 (en) | 2001-07-18 |
EP1115562A4 EP1115562A4 (en) | 2001-11-21 |
EP1115562B1 EP1115562B1 (en) | 2005-08-31 |
Family
ID=27378832
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99945214A Expired - Lifetime EP1115562B1 (en) | 1998-09-08 | 1999-08-26 | Foamed facer and insulation boards made therefrom |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1115562B1 (en) |
JP (1) | JP2002524316A (en) |
AT (1) | ATE303245T1 (en) |
AU (1) | AU5786699A (en) |
CA (1) | CA2340451C (en) |
DE (1) | DE69927038T2 (en) |
DK (1) | DK1115562T3 (en) |
ES (1) | ES2249025T3 (en) |
WO (1) | WO2000014358A2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6913816B2 (en) * | 2001-10-02 | 2005-07-05 | Building Materials Investment Corporation | Composite mat product for roofing construction |
US7429544B2 (en) * | 2004-04-16 | 2008-09-30 | Owens Corning Intellectual Capital, Llc | Coated facer |
GB0606468D0 (en) * | 2006-03-31 | 2006-05-10 | Ici Plc | Improved paint compositions |
WO2020131990A1 (en) * | 2018-12-19 | 2020-06-25 | Ocv Intellectual Capital, Llc | Thin layer uv curing coating on non-woven facers |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA1135127A (en) * | 1979-05-07 | 1982-11-09 | George R. Ferment | Process for sealing fiber web of open structure |
WO1990000967A1 (en) * | 1988-07-25 | 1990-02-08 | Interface, Inc. | Latex fusion bonded pile carpets and carpet tile |
US5102728A (en) * | 1990-08-17 | 1992-04-07 | Atlas Roofing Corporation | Method and composition for coating mat and articles produced therewith |
US5001005A (en) * | 1990-08-17 | 1991-03-19 | Atlas Roofing Corporation | Structural laminates made with novel facing sheets |
JPH05286069A (en) * | 1992-04-15 | 1993-11-02 | Matsushita Electric Works Ltd | Phenol-resin molded form and manufacture thereof |
US5635248A (en) * | 1995-06-07 | 1997-06-03 | Rohm And Haas Company | Method of producing coating on reconstituted wood substrate |
US5717012A (en) * | 1995-11-03 | 1998-02-10 | Building Materials Corporation Of America | Sheet felt |
-
1999
- 1999-08-26 JP JP2000569084A patent/JP2002524316A/en active Pending
- 1999-08-26 EP EP99945214A patent/EP1115562B1/en not_active Expired - Lifetime
- 1999-08-26 WO PCT/US1999/019499 patent/WO2000014358A2/en active IP Right Grant
- 1999-08-26 AU AU57866/99A patent/AU5786699A/en not_active Abandoned
- 1999-08-26 AT AT99945214T patent/ATE303245T1/en not_active IP Right Cessation
- 1999-08-26 DK DK99945214T patent/DK1115562T3/en active
- 1999-08-26 ES ES99945214T patent/ES2249025T3/en not_active Expired - Lifetime
- 1999-08-26 DE DE69927038T patent/DE69927038T2/en not_active Expired - Lifetime
- 1999-08-26 CA CA002340451A patent/CA2340451C/en not_active Expired - Lifetime
Non-Patent Citations (2)
Title |
---|
No further relevant documents disclosed * |
See also references of WO0014358A2 * |
Also Published As
Publication number | Publication date |
---|---|
EP1115562A4 (en) | 2001-11-21 |
WO2000014358A2 (en) | 2000-03-16 |
DK1115562T3 (en) | 2006-01-02 |
CA2340451C (en) | 2009-12-15 |
ATE303245T1 (en) | 2005-09-15 |
DE69927038D1 (en) | 2005-10-06 |
EP1115562B1 (en) | 2005-08-31 |
CA2340451A1 (en) | 2000-03-16 |
ES2249025T3 (en) | 2006-03-16 |
DE69927038T2 (en) | 2006-06-08 |
JP2002524316A (en) | 2002-08-06 |
AU5786699A (en) | 2000-03-27 |
WO2000014358A3 (en) | 2000-06-08 |
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