EP1106373B1 - Tintenstrahlaufzeichnungselement - Google Patents

Tintenstrahlaufzeichnungselement Download PDF

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Publication number
EP1106373B1
EP1106373B1 EP00204059A EP00204059A EP1106373B1 EP 1106373 B1 EP1106373 B1 EP 1106373B1 EP 00204059 A EP00204059 A EP 00204059A EP 00204059 A EP00204059 A EP 00204059A EP 1106373 B1 EP1106373 B1 EP 1106373B1
Authority
EP
European Patent Office
Prior art keywords
recording element
ink jet
image
dye
poly
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00204059A
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English (en)
French (fr)
Other versions
EP1106373A2 (de
EP1106373A3 (de
Inventor
Lori Jeanne Shaw-Klein
Elizabeth Ann Gallo
Eric Lee Dillenbeck
Scott Edward Derry
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
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Filing date
Publication date
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Publication of EP1106373A2 publication Critical patent/EP1106373A2/de
Publication of EP1106373A3 publication Critical patent/EP1106373A3/de
Application granted granted Critical
Publication of EP1106373B1 publication Critical patent/EP1106373B1/de
Anticipated expiration legal-status Critical
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/508—Supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5218—Macromolecular coatings characterised by inorganic additives, e.g. pigments, clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5227—Macromolecular coatings characterised by organic non-macromolecular additives, e.g. UV-absorbers, plasticisers, surfactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5236—Macromolecular coatings characterised by the use of natural gums, of proteins, e.g. gelatins, or of macromolecular carbohydrates, e.g. cellulose
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/256—Heavy metal or aluminum or compound thereof
    • Y10T428/257—Iron oxide or aluminum oxide
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/258—Alkali metal or alkaline earth metal or compound thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259—Silicic material

Definitions

  • the present invention relates to a substantially transparent, porous ink jet image-recording element.
  • ink droplets are ejected from a nozzle at high speed towards a recording element or medium to produce an image on the medium.
  • the ink droplets, or recording liquid generally comprise a recording agent, such as a dye or pigment, and a large amount of solvent.
  • the solvent, or carrier liquid typically is made up of water and an organic material such as a monohydric alcohol, a polyhydric alcohol or mixtures thereof.
  • An ink jet recording element typically comprises a support having on at least one surface thereof an ink-receiving or image-recording layer, and includes those intended for reflection viewing, which have an opaque support, and those intended for viewing by transmitted light, which have a transparent support.
  • Medical images such as radiographic images, are typically viewed on a blue transparent support.
  • porous receivers have been developed which provide nearly instantaneous drying as long as they have sufficient thickness and pore volume to effectively contain the liquid ink.
  • a porous receiver can be manufactured by cast coating, in which a particulate-containing coating is applied to a support and is dried in contact with a polished smooth surface.
  • EP 813,978 relates to an ink jet recording element comprising an ink absorption layer containing solid fine particles, a binder and oil drops.
  • an ink absorption layer containing solid fine particles, a binder and oil drops.
  • an objectionable white appearance results due to scattering of visible light, as described above.
  • EP-A-893 270 discloses an inkjet recording element, which comprises a substantially transparent support, for use in an overhead projector (OHP).
  • OHP overhead projector
  • the disclosure of EP-A-893 270 lists, among conventional additives, coloring dyes, coloring pigments, and fluorescent brighteners.
  • EP-A-893 270 is concerned with preventing a change of color tone in the printed portions and no discoloration (yellowing) of unprinted portions.
  • EP-A-893 270 is silent with respect to the problem solved by the present invention, which is reducing whiteness, but rather is concerned with increasing the whiteness or brightness of an image-recording layer.
  • EP-A-878 322 mentions coloring materials in a list of possible additives for either opaque or transparent media, but is silent as to using a coloring material specifically in a transparent support to reduce whiteness.
  • EP-A-803 374 also discloses a transparent support, specifically used for OHP, in which the ink-receiving layer may optionally contain a coloring material.
  • EP-A-803 374 has the object of providing an inkjet recording element having brightness, and the coloring materials are mentioned with respect to media having an opaque support.
  • an ink jet recording element prior to image recording, comprising a substantially transparent support having thereon an image-recording layer comprising a polymeric binder, a colorant, and porous, colorless aggregates of particles having a primary particle size of from 7 to 40 nm in diameter and being aggregated up to 300 nm, the colorant being a cationic or an anionic dye which is present in an amount effective to reduce the white appearance of the ink jet recording element due to light scattering.
  • Another embodiment of the invention relates to an ink jet printing process comprising:
  • a fast-drying image can be produced which has a reduced white appearance due to scattering of visible light.
  • Particles useful in the invention include alumina, boehmite, clay, calcium carbonate, titanium dioxide, calcined clay, aluminosilicates, silica, barium sulfate, or polymeric beads.
  • the particles are metallic oxides, such as alumina. While many types of inorganic and organic particles are manufactured by various methods and commercially available for an ink receiving layer, porosity is necessary in order to obtain very fast ink drying. The pores formed between the particles must be sufficiently large and interconnected so that the printing ink passes quickly through the layer and away from the outer surface to give the impression of fast drying. At the same time, the particles must be arranged in such a way so that the pores formed between them are sufficiently small that they do not scatter visible light.
  • the most preferred particle type providing the above requirements are aggregates of small particles.
  • the aggregates are typically 150-300 nm in dimension and are comprised of smaller primary particles 7-40 nm in diameter.
  • the pores in a dried coating of such aggregates fall within the range necessary to ensure low optical scatter yet sufficient ink vehicle uptake.
  • Silica and alumina fumed oxides are well known, and alumina fumed oxides are preferred. Fumed oxides are available in dry form or as dispersions of the aggregates mentioned above.
  • the polymeric binder is a hydrophilic polymer.
  • hydrophilic materials include, but are not limited to, polyvinyl alcohols and their derivatives, polyvinyl pyrrolidone, sulfonated or phosphated polyesters, cellulose ethers and their derivatives, poly(2-ethyl-2-oxazoline), gelatin, casein, zein, albumin, chitin, chitosan, dextran, pectin, collagen derivatives, collodian, agar-agar, arrowroot, guar, carrageenan, tragacanth, xanthan, rhamsan, sulfonated polystyrenes, acrylamides and their derivatives, poly(alkylene oxides) and the like.
  • the hydrophilic polymer is poly(vinyl alcohol), hydroxypropyl cellulose, hydroxypropyl methyl cellulose or a poly(alkylene oxides) and the like.
  • the binder material should be chosen so that it is compatible with the aforementioned particles.
  • the amount of binder used should be sufficient to impart cohesive strength to the ink jet receiver, but should also be minimized so that the interconnected pore structure formed by the aggregates is not filled in by the binder.
  • the volume ratio of binder to particles is from 1:4 to 1:2.
  • the void volume must be sufficient to absorb all of the printing ink. For example, if a porous layer has 60 volume % open pores, in order to instantly absorb 32 cc/m 2 of ink, it must have a physical thickness of at least 54 ⁇ m.
  • Suitable support materials useful in the invention include polymeric film materials such as tinted or untinted poly(ethylene terephthalate), polyethylene naphthalate, poly-1,4-cyclohexane dimethylene terephthalate, polyvinyl chloride, polyimide, polycarbonate, polystyrene, cellulose acetate, or cellulose acetate propionate.
  • the support is poly(ethylene terephthalate).
  • film materials may be pretreated with an adhesion promoting layer, an antistatic layer, or a curl control layer as known in the art.
  • the support generally has a thickness of from 50 to 500 ⁇ m, preferably from 75 to 300 ⁇ m.
  • Antioxidants, antistatic agents, plasticizers, and other known additives may be incorporated into the support, if desired.
  • the surface of the support may be subjected to a corona-discharge treatment prior to applying the image-recording layer.
  • the colorant in the image-recording layer is a dye chosen to match the color of the tinted transparency
  • a clear support may be used with the image-recording layer providing both the desired background color and ink receptive properties.
  • Colorants useful in the invention are dyes. If a dye is used, the dye molecules are dispersed or solvated by the liquid or solid medium, so that each individual dye molecule is surrounded by molecules of the liquid or solid medium. Dyes are soluble in aqueous and organic solvents, thus particles are not observable under a microscope.
  • Cationic dyes are those dyes which yield colored cations in aqueous solution
  • anionic dyes are those dyes which yield colored anions in aqueous solution.
  • Cationic dyes usually contain quaternary nitrogen groups as the ionic moiety and encompass all basic dyes.
  • Anionic dyes usually contain sulfonic or carboxylic acid groups as the ionic moiety and encompass all acid groups.
  • Types of cationic dyes that may be used include the C. I. Basic dyes, e.g., Basic Yellows 9, 11, 13 and 51 for yellow dyes; Basic Reds 1 and 3 and Basic Violets 7, 10 and 23 for magenta dyes; Basic Blues 3, 9 and 75 for cyan dyes; and Basic Blacks 2 and 8 for black dyes; and the C. I. Mordant dyes, e.g. Mordant Green 13, that are designed to bind acidic sites on substrates such as fibers.
  • Basic dyes e.g., Basic Yellows 9, 11, 13 and 51 for yellow dyes
  • Basic Reds 1 and 3 and Basic Violets 7, 10 and 23 for magenta dyes
  • Basic Blues 3, 9 and 75 for cyan dyes
  • Basic Blacks 2 and 8 for black dyes
  • C. I. Mordant dyes e.g. Mordant Green 13 that are designed to bind acidic sites on substrates such as fibers.
  • Useful cationic dyes include azine compounds, oxazine compounds, thiazine compounds, azo compounds, diphenylmethane compounds, triarylmethane compounds, xanthene compounds, acridine compounds, quinoline compounds, methine or polymethine compounds, thiazole compounds, indamine or indophenol compounds, among others, all of which are well known to those skilled in the art.
  • Anionic dyes that may be used in the invention include the C. I. Acid, Direct, Food, Mordant and Reactive dyes such as Acid Blue 9, Direct Blue 199, Acid Red 52, Reactive Red 23, Acid Yellow 23, Direct Yellow 132, Food Black 2 and Reactive Black 31.
  • Useful anionic dyes include nitroso compounds, nitro compounds, azo compounds, stilbene compounds, triarylmethane compounds, xanthene compounds, quinoline compounds, thiazole compounds, azine compounds, oxazine compounds, thiazine compounds, aminoketone compounds, anthraquinone compounds, indigoid compounds and phthalocyanine compounds, among others, all of which are well known to those skilled in the art.
  • Especially preferred are the lactate salts of Dye 1 (protonated C.I. Basic Blue 75) and Dye 2 illustrated below:
  • the colorant may be present in any amount effective for the intended purpose. In general, good results have been obtained when the colorant is present in an amount of from 0.01 g/m 2 to 0.05 g/m 2 .
  • the particles forming the porous image-recording layer are primarily anionic, such as fumed silica, anionic dyes preferred. If particles having a high point of zero charge, such as fumed alumina are employed, cationic dyes are preferably used in order to provide melt stability.
  • Coating compositions employed in the invention may be applied by any number of well known techniques, including dip-coating, wound-wire rod coating, doctor blade coating, gravure and reverse-roll coating, slide coating, bead coating, extrusion coating, curtain coating and the like.
  • Known coating and drying methods are described in further detail in Research Disclosure no. 308119, published Dec. 1989, pages 1007 to 1008.
  • Slide coating is preferred, in which the base layers and overcoat may be simultaneously applied. After coating, the layers are generally dried by simple evaporation, which may be accelerated by known techniques such as convection heating.
  • the image-recording layer may contain dye mordants as additives to improve water resistance.
  • dye mordants as additives to improve water resistance.
  • the printing dyes are primarily anionic, quaternary ammonium or phosphonium containing polymers, surfactants, etc may be added.
  • other mordanting materials well known in the art may be selected, such as amine containing polymers or simply a polymer or species carrying positive charges.
  • crosslinkers which act upon the binder discussed above may be added in small quantities. Such an additive improves the cohesive strength of the layer.
  • Crosslinkers such as carbodiimides, polyfunctional aziridines, aldehydes, isocyanates, epoxides, polyvalent metal cations, and the like may all be used.
  • UV stabilizers and absorbers may also be added to the image-recording layer as is well known in the art.
  • coating aids In order to obtain adequate coatability, additives known to those familiar with such art such as surfactants, defoamers, alcohol and the like may be used.
  • a common level for coating aids is 0.01 to 0.30 per cent active coating aid based on the total solution weight.
  • These coating aids can be nonionic, anionic, cationic or amphoteric. Specific examples are described in MCCUTCHEON's Volume 1: Emulsifiers and Detergents, 1995, North American Edition.
  • the coating composition can be coated either from water or organic solvents, however water is preferred.
  • the total solids content should be selected to yield a useful coating thickness in the most economical way, and for particulate coating formulations, solids contents from 10-40% are typical.
  • the ink jet inks used to image the recording elements of the present invention are well-known in the art.
  • the ink compositions used in ink jet printing typically are liquid compositions comprising a solvent or carrier liquid, dyes or pigments, humectants, organic solvents, detergents, thickeners, preservatives, and the like.
  • the solvent or carrier liquid can be solely water or can be water mixed with other water-miscible solvents such as polyhydric alcohols.
  • Inks in which organic materials such as polyhydric alcohols are the predominant carrier or solvent liquid may also be used. Particularly useful are mixed solvents of water and polyhydric alcohols.
  • the dyes used in such compositions are typically watersoluble direct or acid type dyes.
  • Such liquid compositions have been described extensively in the prior art including, for example, US-A-4,381,946; US-A-4,239,543 and US-A-4,781,758.
  • Pen plotters operate by writing directly on the surface of a recording medium using a pen consisting of a bundle of capillary tubes in contact with an ink reservoir.
  • This element was made by coating a support with a liquid of fumed alumina, CEP10AK97003, (Cabot Corporation) and polyvinyl alcohol, Elvanol ® 52/22, (DuPont Corp) such that the weight ratio of alumina to PVA was 90 to 10 and the total solid content in water was 30% by weight.
  • the liquid was coated using a wound wire rod at a wet thickness of 100 ⁇ m and dried at 100 °C.
  • the support was a clear transparent poly(ethylene terephthalate) having an adhesion promoting layer comprised of a terpolymer of acrylonitrile, vinylidene chloride and acrylic acid.
  • This element was prepared the same as Element 1 except that the support was a blue transparent poly(ethylene terephthalate) support which had an adhesion promoting "sub" comprised primarily of gelatin.
  • This element used the support of Element 2 without any coating.
  • This element was the same as Element 1 except that it contained Dye 1 in an amount of 0.024 g/m 2 and Dye 2 above in an amount of 0.012 g/m 2 .
  • This element was the same as Element 2 except that it contained Dye 1 in an amount of 0.024 g/m 2 and Dye 2 above in an amount of 0.012 g/m 2 .
  • each neutral dye was added at a level of 0.7% by weight to a water/lactic acid solution (95/5 ratio by weight). Then, 2% of the cationic cyan dye solution and 1% of the cationic magenta dye solution by weight were added to the melt and it was coated as described above.

Landscapes

  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Ink Jet (AREA)

Claims (8)

  1. Tintenstrahl-Aufzeichnungselement, das vor der Bildaufzeichnung einen praktisch transparenten Träger mit einer hierauf aufgetragenen Bildaufzeichnungsschicht mit einem polymeren Bindemittel, einem Färbemittel und porösen Aggregaten von Teilchen mit einer primären Teilchengröße von 7 bis 40 nm im Durchmesser, die bis zu 300 nm aggregiert sind, aufweist, wobei das Färbemittel ein kationischer oder ein anionischer Farbstoff ist, der in einer Menge vorliegt, die wirksam ist zur Verminderung des weißen Aussehens des Tintenstrahl-Aufzeichnungselementes aufgrund einer Streuung von sichtbarem Licht.
  2. Aufzeichnungselement nach Anspruch 1, in dem das polymere Bindemittel ein hydrophiles Polymer ist.
  3. Aufzeichnungselement nach Anspruch 2, in dem das hydrophile Polymer Poly(vinylalkohol), Hydroxypropylcellulose, Hydroxypropylmethylcellulose oder ein Poly(alkylenoxid) ist.
  4. Aufzeichnungselement nach Anspruch 1, in dem das polymere Bindemittel Poly(vinylalkohol) ist.
  5. Aufzeichnungselement nach Anspruch 1, in dem die Teilchen aus metallischen Oxiden oder Aluminiumoxid bestehen.
  6. Aufzeichnungselement nach Anspruch 1, in dem der kationische Farbstoff das Lactatsalz des protonisierten Farbstoffes C.I. Basic Blue 75 ist.
  7. Aufzeichnungselement nach Anspruch 6, das ferner den folgenden Farbstoff enthält:
    Figure 00150001
  8. Tintenstrahl-Druckverfahren, das umfasst:
    a) die Bereitstellung eines Tintenstrahl-Aufzeichnungselementes nach Anspruch 1, und
    b) das Aufbringen von flüssigen Tintentröpfchen in bildweiser Form.
EP00204059A 1999-12-02 2000-11-17 Tintenstrahlaufzeichnungselement Expired - Lifetime EP1106373B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/453,159 US6391427B1 (en) 1999-12-02 1999-12-02 Ink jet recording element
US453159 1999-12-02

Publications (3)

Publication Number Publication Date
EP1106373A2 EP1106373A2 (de) 2001-06-13
EP1106373A3 EP1106373A3 (de) 2001-08-29
EP1106373B1 true EP1106373B1 (de) 2005-01-12

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US (1) US6391427B1 (de)
EP (1) EP1106373B1 (de)
JP (1) JP2001199161A (de)
DE (1) DE60017345T2 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6613418B2 (en) * 2000-06-06 2003-09-02 Mitsubishi Paper Mills Limited Ink-jet recording material and use of the same
US20030124935A1 (en) * 2000-07-06 2003-07-03 Nicole Smith Scrub pad with printed rigid plates and associated methods
US20050041084A1 (en) * 2003-02-03 2005-02-24 Deba Mukherjee Quick drying, waterfast inkjet recording media
US7022406B1 (en) * 2004-03-24 2006-04-04 Morgan Adhesives Company Breathable film cover for window panes
CN101426865B (zh) * 2004-11-08 2011-02-16 阿克佐诺贝尔公司 水分散体系形式的颜料组合物
RU2012101797A (ru) 2009-06-26 2013-08-10 Акцо Нобель Кемикалз Интернэшнл Б.В. Мелованная основа и способ ее получения
US20110039077A1 (en) * 2009-08-12 2011-02-17 Klemann Bruce M Stain-Resistant Overcoat
US8133556B2 (en) * 2009-08-12 2012-03-13 Brady Worldwide, Inc. Durable multilayer inkjet recording media topcoat

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5928127A (en) * 1995-04-03 1999-07-27 Asahi Glass Company Ltd. Alumina sol and recording sheet
US6238784B1 (en) 1996-06-20 2001-05-29 Konica Corporation Ink-jet recording sheet
DE69800584T2 (de) * 1997-05-22 2001-10-18 Oji Paper Co., Ltd. Tintenstrahlaufzeichnungsschicht, die Kieselsäureteilchen enthält, und Verfahren zu deren Herstellung
EP0893270B1 (de) * 1997-07-23 2001-01-31 Mitsubishi Paper Mills, Ltd. Tintenstrahl-Aufzeichnungsblatt
US5804531A (en) * 1997-12-22 1998-09-08 Eastman Kodak Company Thermal dye transfer system with polyester ionomer receiver
US6110601A (en) * 1998-12-31 2000-08-29 Eastman Kodak Company Ink jet recording element

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Publication number Publication date
DE60017345T2 (de) 2006-03-02
EP1106373A2 (de) 2001-06-13
US6391427B1 (en) 2002-05-21
DE60017345D1 (de) 2005-02-17
JP2001199161A (ja) 2001-07-24
EP1106373A3 (de) 2001-08-29

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