EP1070861B1 - Coated fastener inserts and method of producing the same - Google Patents

Coated fastener inserts and method of producing the same Download PDF

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Publication number
EP1070861B1
EP1070861B1 EP00306143A EP00306143A EP1070861B1 EP 1070861 B1 EP1070861 B1 EP 1070861B1 EP 00306143 A EP00306143 A EP 00306143A EP 00306143 A EP00306143 A EP 00306143A EP 1070861 B1 EP1070861 B1 EP 1070861B1
Authority
EP
European Patent Office
Prior art keywords
fastener
insert
coating
coated
cylindrical body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00306143A
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German (de)
French (fr)
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EP1070861A2 (en
EP1070861A3 (en
Inventor
William J. Lutkus
William Giannakakos
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Newfrey LLC
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Newfrey LLC
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Publication date
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Publication of EP1070861A2 publication Critical patent/EP1070861A2/en
Publication of EP1070861A3 publication Critical patent/EP1070861A3/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16BDEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B37/00Nuts or like thread-engaging members
    • F16B37/12Nuts or like thread-engaging members with thread-engaging surfaces formed by inserted coil-springs, discs, or the like; Independent pieces of wound wire used as nuts; Threaded inserts for holes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16BDEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B33/00Features common to bolt and nut
    • F16B33/004Sealing; Insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S411/00Expanded, threaded, driven, headed, tool-deformed, or locked-threaded fastener
    • Y10S411/90Fastener or fastener element composed of plural different materials
    • Y10S411/901Core and exterior of different materials
    • Y10S411/902Metal core
    • Y10S411/903Resinous exterior

Definitions

  • the present invention relates to coated fastener inserts and a method for coating such fastener inserts and, more particularly, to coating fastener inserts to prevent the galvanic corrosion in fastener assemblies.
  • Fastener assemblies come in a variety of shapes, sizes, designs and materials. Many fastener assemblies include not only a fastener such as a bolt, pin or screw, but also will include a fastener insert to be positioned within a tapped hole.
  • tapped threads are strengthened due to the inherent flexibility of helically coiled wire inserts since the insert provides a more balanced distribution of dynamic and static loads throughout the length of thread engagement. This is especially important when the substrate including tapped holes is formed from a relatively soft metal, i.e., aluminum and magnesium. The inherent flexibility also compensates for variation in lead and angle error.
  • Helically coiled wire inserts allow for the use of smaller bosses, flanges and fasteners than other inserts, thus presenting a cost savings, particularly for high volume applications.
  • helically coiled wire inserts are generally useful as anchoring mechanisms for threaded fasteners in order to be used in high strength applications, such inserts must be formed from high strength metals such as 302/304 stainless steel.
  • high strength metals such as 302/304 stainless steel.
  • the use of stainless steel inserts in association with substrates or fasteners formed from other alloys leads to certain perceived problems such as the possibility of galvanic corrosion occurring over time.
  • galvanic corrosion it is meant the electrochemical corrosion resulting from the current caused in a galvanic cell between two dissimilar metals in an electrolyte because of the difference in potential (emf) of the two metals.
  • Stainless steel fastener inserts have been coated with zinc chromate in an effort to prevent galvanic corrosion.
  • application of the zinc chromate requires strict quantitative controls and is considered labor intensive.
  • the application of too much zinc chromate can restrict movement.
  • the installation tools would require frequent cleaning to prevent build up of the zinc chromate on mandrels of the tool which is undesirable.
  • the application of too little zinc chromate leads to certain other problems such as inadequate corrosion protection, for example.
  • a metallic fastener insert according to the preamble of claim 1 is disclosed in GB-A-536 959 .
  • the present invention relates to a coated metallic fastener insert for securing a fastener within a tapped hole of a metallic substrate, said insert being formed from a high strength metal, in particular stainless steel, and comprising:
  • the present invention further relates to a method of producing a fastener insert for securing a threaded fastener within a tapped hole of a metallic substrate, which insert is resistant to galvanic corrosion in use, said method comprising the steps of
  • a fastener assembly 10 for use in association with a substrate 12 having one or more tapped holes 14 including inwardly projecting threads 16.
  • the fastener assembly 10 includes a fastener 20 and fastener insert 22 insertable within the tapped hole 14.
  • the fastener 20 generally includes a head 24 and a shank 26 having radially outwardly projecting threads 28.
  • the fastener insert 22 may be of any form capable of retaining the fastener within a tapped hole but preferably is in the form of a helically wound wire 30 including a body 32 having a plurality of convolutions 34 disposed between first and second ends, 36 and 38, respectively. At least one of the ends may be provided with a driving tang or notch for tangless embodiments for assistance in the installation or removal process.
  • the fastener inserts 22 are larger in diameter, before installation than the tapped holes 14 such that upon installation they become firmly secured within the tapped holes, as shown most clearly in Fig. 2 .
  • the coils provide permanent convolution 60° internal screw threads which accommodate virtually any standard threaded bolt or screw.
  • the insert Prior to inserting the fastener insert 22 within the tapped hole 14, the insert is coated with a resin bonded fluoropolymer composition such as XYLAN® 5251, available from Whitford Corporation of Westchester, Pennsylvania or E/M® 6219, which is available from Engineered Coating Solutions, Inc. of Peachtree City, Georgia, by way of non-limiting example.
  • a resin bonded fluoropolymer composition such as XYLAN® 5251, available from Whitford Corporation of Westchester, Pennsylvania or E/M® 6219, which is available from Engineered Coating Solutions, Inc. of Peachtree City, Georgia, by way of non-limiting example.
  • the composition be thoroughly agitated such that the fluoropolymer is adequately dispersed in solution.
  • the fluoropolymer composition may be applied via dip spin or air spray techniques.
  • the fluoropolymer composition may also serve to reduce galling. It is preferred that the dry film thickness be in the range of between 0,762 to about 12,7 ⁇ m. (0.03 to about 0.5 mils). As such, it is preferred that under dip spin applications that at least two coats are applied to obtain the preferred thickness. Using conventional spray application techniques, a single coat of between about 15,24 to 25,4 ⁇ m (0.6 to 1.0 mils.) is possible.
  • a preferred viscosity is generally in the range of between about 20 - 30 seconds at 25°C.
  • the fastener inserts be free of contaminants such as oil, grease, metal shavings, etc., since contaminants may cause poor adhesion of the coating to the fastener insert or defects in the dry coating composition.
  • the fastener inserts be cleaned, i.e., degreased prior to coating using a chlorinated or fluorinated solvent, detergents, or a high temperature burnout process wherein the part is exposed to temperatures roughly between 400 to 425°C for ten to twenty minutes to ensure that any petroleum based contaminants are fully carbonized.
  • each fastener insert should be solvent rinsed to flush out any grit residue.
  • the fastener inserts be pre-treated with a primer which is heat stable calcium or magnesium modified phosphate having a relatively fine crystalline structure.
  • a primer which is heat stable calcium or magnesium modified phosphate having a relatively fine crystalline structure.
  • Commercially available compositions which are useful as primers include Aerocoat #3 available from Aerocoat Corporation of Houston, Texas and Whitford's XYLAN® P-5211 primer or XYLAN® P-5212 primer, particularly wherein the fastener assembly will be subjected to acid rain conditions.
  • each fastener insert is dipped for between about five to ten seconds and subsequently spun for five to fifteen seconds in each direction changing direction at least three times. Thereafter, the fastener insert is cured for between about 7 to 10 minutes at temperatures of between about 190°C to about 240°C. The part is preferably allowed to cool to ambient temperatures of less than about 38°C prior to carrying out the aforementioned dip spinning steps to apply the second coat.
  • Air spray techniques generally involve application at line pressures of between 276 to 345 kPa (40 to 50 psi) and pop pressures in the range of between 20,7 to 48,3 kPa (3 to 7 psi) at ambient temperatures of less than about 38°C.
  • the fastener inserts are cured for between about 7 to 10 minutes at temperatures of between about 180°C to about 240°C.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)

Abstract

Disclosed is a method for preventing galvanic corrosion in fastener assemblies by coating fastener inserts with a resin bonded fluoropolymer composition having an average viscosity of between about 20 to 30 seconds at 25 DEG C. Also disclosed is a method for providing coated inserts as well as the coated inserts produced. <IMAGE>

Description

  • The present invention relates to coated fastener inserts and a method for coating such fastener inserts and, more particularly, to coating fastener inserts to prevent the galvanic corrosion in fastener assemblies.
  • Fastener assemblies come in a variety of shapes, sizes, designs and materials. Many fastener assemblies include not only a fastener such as a bolt, pin or screw, but also will include a fastener insert to be positioned within a tapped hole.
  • The type of fastener insert needed for a particular fastening operation will in large part dictated the type of fastener to be employed. While the present invention is applicable to various fastener assemblies wherein galvanic corrosion is a potential problem, the invention will hereinafter be described with reference to fastener assemblies with metallic helically coiled wire fastener inserts. By way of non-limiting example, certain metallic helically coiled wire inserts useful in association with a threaded fastener is described in U.S. Patent No. 2,672,070 entitled Wire Coil Screw Thread Insert for Molded Material. Other fastener inserts which can be coated in accordance with the teachings of the present invention are described in U.S. Patent Nos. 2,512,316 ; 2,586,007 ; 2,708,265 ; 2,755,699 ; 2,874,741 ; 2,934,123 ; 3,018,684 , each of which is expressly incorporated by reference.
  • Generally speaking, tapped threads are strengthened due to the inherent flexibility of helically coiled wire inserts since the insert provides a more balanced distribution of dynamic and static loads throughout the length of thread engagement. This is especially important when the substrate including tapped holes is formed from a relatively soft metal, i.e., aluminum and magnesium. The inherent flexibility also compensates for variation in lead and angle error.
  • Additionally, no stress is initially introduced to the substrate because the helically coiled insert does not exhibit staking, locking or swaying and does not require keying in place. Helically coiled wire inserts allow for the use of smaller bosses, flanges and fasteners than other inserts, thus presenting a cost savings, particularly for high volume applications.
  • While such helically coiled wire inserts are generally useful as anchoring mechanisms for threaded fasteners in order to be used in high strength applications, such inserts must be formed from high strength metals such as 302/304 stainless steel. The use of stainless steel inserts in association with substrates or fasteners formed from other alloys leads to certain perceived problems such as the possibility of galvanic corrosion occurring over time. By the phrase "galvanic corrosion", it is meant the electrochemical corrosion resulting from the current caused in a galvanic cell between two dissimilar metals in an electrolyte because of the difference in potential (emf) of the two metals.
  • Stainless steel fastener inserts have been coated with zinc chromate in an effort to prevent galvanic corrosion. However, application of the zinc chromate requires strict quantitative controls and is considered labor intensive. The application of too much zinc chromate can restrict movement. Additionally, the installation tools would require frequent cleaning to prevent build up of the zinc chromate on mandrels of the tool which is undesirable. The application of too little zinc chromate leads to certain other problems such as inadequate corrosion protection, for example.
  • A metallic fastener insert according to the preamble of claim 1 is disclosed in GB-A-536 959 .
  • From FR-A-2051891 it is known to provide the contacting surfaces of screws, nuts or the like with an insulating and self lubricating film of a fluorocarbon or polyimide resin. To obtain corrosion-resistance US-A-4074011 teaches to first coat bolts, nuts and washers with an undercoat consisting of metal phosphate, and with a top coating consisting of a chromium compound and one or more of a metal salt of higher fatty acid, polyolefin and polytetrafluoride dissolved or dispersed in a vehicle.
  • In view of the foregoing, it is an object of the present invention to prevent galvanic corrosion in fastener assemblies employing a metallic fastener insert and a fastener for use in a tapped hole.
  • The present invention relates to a coated metallic fastener insert for securing a fastener within a tapped hole of a metallic substrate, said insert being formed from a high strength metal, in particular stainless steel, and comprising:
    • a substantially cylindrical body of helically wound wire including a plurality of convolutions providing internal screw threads upon insertion within the inwardly projecting threads of the tapped hole, wherein the cylindrical body has a larger diameter before installation than the tapped hole, and the entire exterior surface is coated with a resin composition with dispersed fluoropolymer, and wherein said coating has an average dry thickness of between about 0,762 to 12,7 µm (0.3 to 0.5 mils).
  • The present invention further relates to a method of producing a fastener insert for securing a threaded fastener within a tapped hole of a metallic substrate, which insert is resistant to galvanic corrosion in use, said method comprising the steps of
    1. a) forming a substantially cylindrical body of helically wound wire including a plurality of convolutions from a high strength metal such as stainless steel, the cylindrical body having a larger diameter before installation than the tapped hole; and
    2. b) coating the entire surface of said cylindrical body with a resin composition with dispersed fluoropolymer, wherein said coating applied to said fastener insert has an average dry thickness of between about 0,762 to 12,7 µm.
  • As a result of coating the fastener insert, it is a primary object of the present invention to extend the useful life of fastener applications by preventing galvanic corrosion within a fastener assembly.
    • Fig. 1 is a blown apart perspective view of a fastener assembly including a helically wound insert;
    • Fig. 2 is an assembly view in cross-section of the fastener assembly of Fig. 1;
    • Fig. 3 is a perspective view illustrating the spray coating of a helically wound insert;
    • Fig. 4 is a perspective view illustrating the dip coating of a helically wound insert; and
    • Fig. 5 is a cross-sectional view of a convolution taken along line 5-5 of Fig. 1 of a coated fastener insert.
  • Referring to Fig. 1, there is shown a fastener assembly 10 for use in association with a substrate 12 having one or more tapped holes 14 including inwardly projecting threads 16. The fastener assembly 10 includes a fastener 20 and fastener insert 22 insertable within the tapped hole 14.
  • The fastener 20 generally includes a head 24 and a shank 26 having radially outwardly projecting threads 28. The fastener insert 22 may be of any form capable of retaining the fastener within a tapped hole but preferably is in the form of a helically wound wire 30 including a body 32 having a plurality of convolutions 34 disposed between first and second ends, 36 and 38, respectively. At least one of the ends may be provided with a driving tang or notch for tangless embodiments for assistance in the installation or removal process.
  • Preferably, the fastener inserts 22 are larger in diameter, before installation than the tapped holes 14 such that upon installation they become firmly secured within the tapped holes, as shown most clearly in Fig. 2. Further, when the helically wound inserts are disposed within the tapped holes, the coils provide permanent convolution 60° internal screw threads which accommodate virtually any standard threaded bolt or screw.
  • Prior to inserting the fastener insert 22 within the tapped hole 14, the insert is coated with a resin bonded fluoropolymer composition such as XYLAN® 5251, available from Whitford Corporation of Westchester, Pennsylvania or E/M® 6219, which is available from Engineered Coating Solutions, Inc. of Peachtree City, Georgia, by way of non-limiting example. Before applying the fluoropolymer coating, it is preferred that the composition be thoroughly agitated such that the fluoropolymer is adequately dispersed in solution.
  • As illustrated with reference to Figs. 3 and 4, the fluoropolymer composition may be applied via dip spin or air spray techniques. In addition to the prevention of galvanic corrosion to which this invention is particularly directed, when the fastener insert is formed from a stainless steel, the fluoropolymer composition may also serve to reduce galling. It is preferred that the dry film thickness be in the range of between 0,762 to about 12,7 µm. (0.03 to about 0.5 mils). As such, it is preferred that under dip spin applications that at least two coats are applied to obtain the preferred thickness. Using conventional spray application techniques, a single coat of between about 15,24 to 25,4 µm (0.6 to 1.0 mils.) is possible.
  • Under certain circumstances it may be necessary to modify the viscosity of the fluoropolymer composition by admixing with a solvent such as methylethylketone (mek) until the desired viscosity is obtained. A preferred viscosity is generally in the range of between about 20 - 30 seconds at 25°C.
  • As noted above, it is preferred that the fastener inserts be free of contaminants such as oil, grease, metal shavings, etc., since contaminants may cause poor adhesion of the coating to the fastener insert or defects in the dry coating composition. Thus, it is recommended that the fastener inserts be cleaned, i.e., degreased prior to coating using a chlorinated or fluorinated solvent, detergents, or a high temperature burnout process wherein the part is exposed to temperatures roughly between 400 to 425°C for ten to twenty minutes to ensure that any petroleum based contaminants are fully carbonized.
  • In addition to cleaning the surface, it is also recommended that the fastener inserts be abraded utilizing conventional techniques such as grit and/or sand blasting. Recommended grit sizes are between about 0,18 to 0,13 mm (80 to 120 mesh) at an air pressure of about 550 kPa (80 pounds per square inch). Once the abrading step has been carried out, each fastener insert should be solvent rinsed to flush out any grit residue.
  • Optionally, particularly for applications wherein the fastener assembly is susceptible to harsh environmental conditions, it is preferred that the fastener inserts be pre-treated with a primer which is heat stable calcium or magnesium modified phosphate having a relatively fine crystalline structure. Commercially available compositions which are useful as primers include Aerocoat #3 available from Aerocoat Corporation of Houston, Texas and Whitford's XYLAN® P-5211 primer or XYLAN® P-5212 primer, particularly wherein the fastener assembly will be subjected to acid rain conditions.
  • To carry out a dip spin application, each fastener insert is dipped for between about five to ten seconds and subsequently spun for five to fifteen seconds in each direction changing direction at least three times. Thereafter, the fastener insert is cured for between about 7 to 10 minutes at temperatures of between about 190°C to about 240°C. The part is preferably allowed to cool to ambient temperatures of less than about 38°C prior to carrying out the aforementioned dip spinning steps to apply the second coat.
  • Air spray techniques generally involve application at line pressures of between 276 to 345 kPa (40 to 50 psi) and pop pressures in the range of between 20,7 to 48,3 kPa (3 to 7 psi) at ambient temperatures of less than about 38°C. Following the application of the fluoropolymer composition, the fastener inserts are cured for between about 7 to 10 minutes at temperatures of between about 180°C to about 240°C.
  • Upon fully curing the coating upon the fastener inserts quality control in the form of a visual inspection should be carried out. If bridging of the coating between adjacent coils is present, such coils should be rejected.

Claims (14)

  1. A metallic fastener insert (22) for securing a threaded fastener (20) within a tapped hole (14) of a metallic substrate (12), said insert (22) being formed from a high strength metal, and comprising:
    a substantially cylindrical body (32) of helically wound wire (30) including a plurality of convolutions (34) providing internal screw threads upon insertion within the tapped hole (14) including inwardly projecting threads (16),
    the cylindrical body (32) having a larger diameter before installation than the tapped hole (14), characterised in that
    the entire surface of said cylindrical body (32) is coated with a resin composition with dispersed fluoropolymer, wherein said coating has an average dry thickness of between about 0,762 to 12,7 µm.
  2. The coated metallic fastener insert of Claim 1 wherein said the coils of said insert (22) provide permanent convolution 60° internal screw threads upon insertion within a tapped hole (14).
  3. The coated metallic fastener insert of Claim 1 wherein said insert (22) is formed from a stainless steel.
  4. The coated metallic fastener insert of Claim 1 wherein said fastener insert is pre-coated with a primer prior to the application of said fluoropolymer composition coating.
  5. A fastener assembly including a coated metallic fastener insert (22) according to one of the preceding claims, a metallic fastener (20) and a metallic substrate (12) including a tapped hole (14) with inwardly projecting threads (16), for receiving said insert (22) and said fastener (20), said insert (22) having a larger diameter before installation than the tapped hole (14) and being from a metal alloy which is different from the metal of said fastener (20) or substrate (12).
  6. A method of producing a fastener insert (22) for securing a threaded fastener (20) within a tapped hole (14) of a metallic substrate (12), which insert is resistant to galvanic corrosion in use, said method comprising the steps of:
    a) forming a substantially cylindrical body (32) of helically wound wire (30) including a plurality of convolutions (34) from a high strength metal, in particular stainless steel, the cylindrical body having a larger diameter before installation than the tapped hole (14); and
    b) coating the entire surface of said cylindrical body (32) with a resin composition with dispersed fluoropolymer, wherein said coating applied to said fastener insert has an average dry thickness of between about 0,762 to 12,7 µm.
  7. The method of Claim 6 wherein said fastener insert is cleaned prior to being coated.
  8. The method of Claim 6 wherein said fastener insert is abraded prior to being coated.
  9. The method of Claim 6 wherein said fastener insert is optionally pre-coated with a primer prior to applying said coating.
  10. The method of Claim 6, wherein said coating is applied via a dip spin technique.
  11. The method of Claim 10 wherein said coating is applied by dipping said cylindrical body in a dispersed solution of the fluoropolymer composition for between about 5 to 10 seconds, subsequently spinning said cylindrical body for 5 to 15 seconds in each direction at least three times, and then curing said cylindrical body.
  12. The method of Claim 10 wherein said coating is applied in multiple layers.
  13. The method of Claim 6 wherein said coating is applied via spraying.
  14. The method of Claim 6 wherein said coating is cured upon said fastener insert by baking at a temperature of between about 180°C to about 240°C.
EP00306143A 1999-07-20 2000-07-19 Coated fastener inserts and method of producing the same Expired - Lifetime EP1070861B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/356,988 US6224311B1 (en) 1999-07-20 1999-07-20 Coated fastener inserts and method of producing the same
US356988 1999-07-20

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EP1070861A2 EP1070861A2 (en) 2001-01-24
EP1070861A3 EP1070861A3 (en) 2003-04-23
EP1070861B1 true EP1070861B1 (en) 2009-05-20

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US (1) US6224311B1 (en)
EP (1) EP1070861B1 (en)
JP (1) JP2001059510A (en)
AT (1) ATE431909T1 (en)
DE (1) DE60042228D1 (en)

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US20050238461A1 (en) 2004-04-21 2005-10-27 Lutkus William J Chromate free fluoropolymer coated fastener inserts
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US20070054052A1 (en) * 2005-06-01 2007-03-08 Gregory Alaimo Fluoropolymer coating compositions for threaded fasteners
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GB900672A (en) * 1959-04-16 1962-07-11 Yokohoma Rubber Company Ltd Improved fastening assembly

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
WITHFORD WORLWIDE: "XYLAN 5251 Product data sheet", 1 June 2004 (2004-06-01) *

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US6224311B1 (en) 2001-05-01
ATE431909T1 (en) 2009-06-15
EP1070861A2 (en) 2001-01-24
JP2001059510A (en) 2001-03-06
DE60042228D1 (en) 2009-07-02
EP1070861A3 (en) 2003-04-23

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