EP1070152A1 - TiAl BASE ALLOY - Google Patents
TiAl BASE ALLOYInfo
- Publication number
- EP1070152A1 EP1070152A1 EP99913284A EP99913284A EP1070152A1 EP 1070152 A1 EP1070152 A1 EP 1070152A1 EP 99913284 A EP99913284 A EP 99913284A EP 99913284 A EP99913284 A EP 99913284A EP 1070152 A1 EP1070152 A1 EP 1070152A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- alloy
- tial
- tial base
- base alloy
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C14/00—Alloys based on titanium
Definitions
- the invention relates to a TiAl base alloy with a composition of titanium aluminide with 42 to 54 at.% Al, the remainder being titanium, to which further alloying elements can be added up to 12 at.
- the invention is based on the object of modifying a TiAl base alloy in such a way that it has better properties than conventional alloys based on it in several respects. In particular, improved castability, formability and ductility with higher strength is sought.
- a TiAl base alloy which contains 0.1 to 5 at.% Cu, preferably 0.2 to 1 at.% Cu.
- the alloy may contain 0.1 to 2 at.% Si, preferably 0.1 to 0.3 at.% Si, and / or 0.1 to 5 at.% Mo, preferably 0.4 to 1, 2 at.% Mo, and / or 0.1 to 5 at.% Cr, preferably 0.4 to 1.2 at.% Cr, and up to a total of 12 at.% Further alloy elements.
- one or more of the strength-increasing elements Nb, Mn, V, B, W, Ti, Ta, Zr m of the alloy can be contained as "further alloy elements".
- the invention has proven to be particularly advantageous for the following alloys: - 2 -
- the addition of copper to TiAl provided according to the invention results in a greatly reduced grain size or a significantly finer structured casting structure compared to TiAl base alloys without the addition of copper.
- Lamellar TiAl base alloys with copper addition also have reduced lamella spacing. These effects are reinforced by the addition of silicon.
- the addition of copper leads to an increased strength of TiAl base alloys with increased ductility compared to comparable alloys. Arm formability is also improved. As a result, the forming of TiAl base alloys with copper addition can be carried out with lower forces or at lower temperatures than with comparable alloys.
- At least 0.1 at% Cu is required to achieve the desired effects. More than 5 at.-o cause embrittlement and are therefore not useful. Even small amounts of the order of magnitude up to 0.2 at.% Cu improve the castability by reducing the melt viscosity and, compared to comparable alloys without the addition of Cu, result in a significantly finer structured casting structure.
- Figure 1 shows the solidification structure of a T1AIM0S1 alloy.
- TiAl base alloys with copper addition represented by the T ⁇ 52 Al 4 6 sCu.Sio 2 ⁇ alloy according to Figure 2
- Figures 3 and 4 show, the grain-refining influence of the - 3 -
- Copper additive to TiAl is also pronounced after the alloy has been annealed for 30 mm at 1400 ° C.
- Figure 5 shows the temperature-dependent fracture upsets of modified TiAl alloys with copper addition compared to a TI 52 A1 P and a TiAlMoSi alloy.
- the strength of TiAl base alloys is significantly increased by the addition of copper to TiAl provided according to the invention.
- the comparatively steep drop in strength at temperatures> 800 ° C for the TiAl base alloys with copper addition leads to improved hot formability.
- R c S ⁇ 2- alloy has, for example with upsetting boundaries between 580 MPa at room temperature and 538 MPa at 800 ° C, a higher compression strength than an already high strength T I 5 Al "M ⁇ S ⁇ 0 -? Alloy.
- the TiAl base alloy according to the invention is suitable as a construction material for cast female parts, but also for parts which are produced by extrusion, isothermal forging and / or superplastic forming to the desired final shape.
- Application examples are valves for internal combustion engines, piston crown segments, turbocharger rotors and components for turbines and compressors.
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19812444 | 1998-03-21 | ||
DE19812444A DE19812444B4 (en) | 1998-03-21 | 1998-03-21 | TiAl-based alloy |
PCT/EP1999/001868 WO1999049090A1 (en) | 1998-03-21 | 1999-03-20 | TiAl BASE ALLOY |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1070152A1 true EP1070152A1 (en) | 2001-01-24 |
EP1070152B1 EP1070152B1 (en) | 2004-03-03 |
Family
ID=7861797
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP99913284A Expired - Lifetime EP1070152B1 (en) | 1998-03-21 | 1999-03-20 | TiAl BASE ALLOY |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1070152B1 (en) |
AT (1) | ATE260996T1 (en) |
AU (1) | AU3146799A (en) |
DE (1) | DE19812444B4 (en) |
WO (1) | WO1999049090A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2339040A1 (en) * | 2006-03-17 | 2011-06-29 | University of Tsukuba | Actuator and engine |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3492118B2 (en) * | 1996-10-28 | 2004-02-03 | 三菱重工業株式会社 | TiAl intermetallic compound based alloy |
WO2006136785A2 (en) * | 2005-06-21 | 2006-12-28 | University Of Leeds | Electrode |
GB0512836D0 (en) * | 2005-06-21 | 2005-08-03 | Jha Animesh | Inert alloy anodes for aluminium electrolysis cell using molten salt bath confidential |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1179006B (en) * | 1952-12-18 | 1964-10-01 | Crucible Steel Internat | Titanium alloys |
US4865666A (en) * | 1987-10-14 | 1989-09-12 | Martin Marietta Corporation | Multicomponent, low density cubic L12 aluminides |
JP2952924B2 (en) * | 1990-01-30 | 1999-09-27 | 日本鋼管株式会社 | TiAl-based heat-resistant alloy and method for producing the same |
JP2817427B2 (en) * | 1991-01-08 | 1998-10-30 | 三菱マテリアル株式会社 | Method for producing TiAl intermetallic compound Ti alloy excellent in strength and ductility |
JPH05230570A (en) * | 1992-02-21 | 1993-09-07 | Toyota Motor Corp | Tial-base alloy with high ductility |
JPH06116692A (en) * | 1992-10-05 | 1994-04-26 | Honda Motor Co Ltd | Ti-al intermetallic compound excellent in high temperature strength and its production |
-
1998
- 1998-03-21 DE DE19812444A patent/DE19812444B4/en not_active Expired - Fee Related
-
1999
- 1999-03-20 AT AT99913284T patent/ATE260996T1/en not_active IP Right Cessation
- 1999-03-20 EP EP99913284A patent/EP1070152B1/en not_active Expired - Lifetime
- 1999-03-20 AU AU31467/99A patent/AU3146799A/en not_active Abandoned
- 1999-03-20 WO PCT/EP1999/001868 patent/WO1999049090A1/en active IP Right Grant
Non-Patent Citations (1)
Title |
---|
See references of WO9949090A1 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2339040A1 (en) * | 2006-03-17 | 2011-06-29 | University of Tsukuba | Actuator and engine |
EP2341158A1 (en) * | 2006-03-17 | 2011-07-06 | University of Tsukuba | Actuator and Engine |
Also Published As
Publication number | Publication date |
---|---|
DE19812444A1 (en) | 1999-09-30 |
AU3146799A (en) | 1999-10-18 |
WO1999049090A1 (en) | 1999-09-30 |
EP1070152B1 (en) | 2004-03-03 |
DE19812444B4 (en) | 2004-02-19 |
ATE260996T1 (en) | 2004-03-15 |
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