EP1012455A2 - Catalytic converter for a small-size engine - Google Patents
Catalytic converter for a small-size engineInfo
- Publication number
- EP1012455A2 EP1012455A2 EP97950069A EP97950069A EP1012455A2 EP 1012455 A2 EP1012455 A2 EP 1012455A2 EP 97950069 A EP97950069 A EP 97950069A EP 97950069 A EP97950069 A EP 97950069A EP 1012455 A2 EP1012455 A2 EP 1012455A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- stack
- housing
- catalytic converter
- sheet metal
- silencer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 33
- 239000002184 metal Substances 0.000 claims abstract description 41
- 230000003584 silencer Effects 0.000 claims abstract description 30
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 239000011149 active material Substances 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000005516 engineering process Methods 0.000 claims description 5
- 238000005304 joining Methods 0.000 claims description 4
- 238000009434 installation Methods 0.000 claims description 3
- 230000005489 elastic deformation Effects 0.000 abstract 1
- 238000005192 partition Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 208000031872 Body Remains Diseases 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000003863 metallic catalyst Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000036316 preload Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
- B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2882—Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices
- F01N3/2885—Catalytic reactors combined or associated with other devices, e.g. exhaust silencers or other exhaust purification devices with exhaust silencers in a single housing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/40—Honeycomb supports characterised by their structural details made of a single sheet, foil or plate
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/02—Fitting monolithic blocks into the housing
Definitions
- the present invention relates to a catalytic converter for a small motor, in which a honeycomb body coated with catalytically active material is arranged in a silencer housing arranged close to the motor.
- DE-OS 38 29 668 already provides an example of an exhaust silencer for two-stroke engines, which contains a catalytic converter for exhaust gas purification in its interior.
- EP 0 470 113 B1 also discloses a metallic catalyst carrier body which is particularly suitable for fastening in the partition of a silencer housing.
- the object of the present invention is therefore a catalytic converter for a small engine, which is very inexpensive to manufacture, requires the smallest possible design changes to existing small engines and their exhaust systems, and yet can remove a considerable proportion of the pollutants from the exhaust gas catalytically.
- a catalytic converter according to claim 1 is used to achieve this object, a corresponding manufacturing method being specified in claim 11.
- Advantageous refinements are specified in the respective dependent claims.
- Catalytic converters usually contain honeycomb bodies in order to provide a sufficiently large surface for a catalytic conversion in a partial volume of the exhaust system.
- honeycomb bodies are produced in particular from metal sheets, at least some of these metal sheets being structured in such a way that channels which are permeable to exhaust gas result overall.
- alternating smooth and corrugated sheet layers are used.
- a large number of structures come into consideration for the present invention, so that sheet metal layers with two different corrugations or sheet metal layers with corrugations arranged alternately obliquely to one another can also be used.
- this method has many advantages in terms of production technology and leads to a simple, but durable catalytic converter.
- a silencer housing for small engines consists of two or more individual parts, in particular half-shells and a partition, which can be connected by means of a simple connection process, e.g. B. flanging or welding. These housing parts can Assembling can be used simultaneously for the shaping of the honeycomb body, without the need for additional tools.
- a stack of sheet metal layers with a larger volume than the partial volume to be filled in the muffler housing is simply placed in the intended position when the housing is assembled and squeezed into its final position and shape when the housing parts are assembled. Even if 15 to 30% of the channels are plastically and / or elastically deformed, namely at the lateral ends of the stack and in the outer edge areas, enough cells remain gas-permeable, so that effective catalytic cleaning is ensured.
- the lateral ends of the stack should be held on or in the walls of the housing in a preferred embodiment.
- the sheets are already coated with catalytically active material before being fitted in the silencer housing, either by using sheets already coated for the entire production process or by coating a prefabricated stack of sheet metal layers as a whole.
- a major advantage of the catalytic converter according to the invention is that the considerable deformation of the channels is partly plastic and partly elastic, so that the honeycomb body remains under a pretension which prevents the sheet metal layers from loosening under all operating conditions, in particular thermal alternating loads.
- the honeycomb body will be under maximum prestress in a catalytic converter manufactured according to the invention, since it is deformed everywhere beyond the elastic limit. This prevents relative movements between the sheet layers even with decreasing elasticity with increasing temperature.
- sheet metal layers with so-called transverse microstructures which are known in the prior art, are also particularly suitable for the present invention. These microstructures increase the effectiveness of the catalytic conversion and also cause the sheet metal layers to be clamped together, so that they cannot move against each other, especially under the high elastic preload, even under the most unfavorable conditions. This also applies if not all sheet metal layers, but only a part of them, are attached to the silencer housing with their ends.
- the stack to be squeezed into the muffler housing is adapted in its initial form to the shape of the partial volume to be filled and to the degree of deformation of the individual regions to be expected during the crushing, although the volume of the stack is preferably at least 5%, preferably should be at least 10% larger than the partial volume to be filled.
- silencer housings composed of at least two parts
- clamp the crimped ends of the stack in the joint between these parts in order to enclose the honeycomb body to fix overall.
- This can be carried out both in the case of stacks formed from individual sheets, and in the case of stacks which are wound, folded or laid in a meandering shape from one or more sheets after the ends have been squeezed together.
- the ends of the stack can be included in the technology previously used for assembling the silencer housing, so that the attachment can be carried out, for example, by flanging, welding with a weld seam or spot welding.
- the catalytically active coating on the metal sheets generally does not interfere, so that no additional processing steps are necessary to remove them.
- FIG. 1 shows a longitudinal section through a muffler housing with a schematically indicated installation location of a catalytic converter
- FIG. 2 shows in cross section the parts of a silencer housing, including a stack, shortly before assembly,
- FIG. 3 shows a cross section along the section line III-III in Figure 1 by a silencer housing after assembly
- Figures 4, 5, 6, 7 and 8 different forms of stacks of at least partially structured sheet metal layers.
- Figure 1 shows schematically in longitudinal section a silencer housing 3 for a small engine.
- the exhaust gas enters the exhaust gas inlet 1
- Lower part 3.2 of the muffler housing from where it reaches the upper part 3.1 of the muffler housing through openings in a partition 3.3. From here it flows through the channels 7 of a honeycomb body 4 and then reaches the exhaust gas outlet 2.
- Upper part 3.1 and lower part 3.2 of the muffler housing and the partition 3.3 are connected to one another in the area of a parting joint 3.4, for example by flanging or by a weld.
- FIG. 2 schematically illustrates in cross section the joining of upper part 3.1, lower part 3.2, partition 3.3 of the muffler housing and a stack 8 of sheet metal layers 5, 6, the process of joining being indicated by arrows.
- the stack 8 is formed from alternately arranged individual smooth sheet metal layers 5 and corrugated sheet metal layers 6, which together form a multiplicity of channels 7 which are permeable to the exhaust gas.
- the sheet metal layers 5, 6 are coated with catalytically active material 10. This coating can either be applied to the sheet metal layers 5, 6 in a continuous process before all other processing steps, or else can be applied together after the stack 8 has been layered.
- FIG. 3 shows in cross section along the line III-III in Figure 1 an essentially completely assembled silencer housing with a crimped honeycomb body. It can be seen that the lateral ends 9 of the stack 8, which is still undeformed in FIG. 2, are now squeezed together, with numerous channels 7.1 also being plastically deformed in the edge regions of the honeycomb body. Nevertheless, especially in the inner region of the honeycomb body, there remain sufficient channels which are not plastically deformed and which are sufficient for the catalytic conversion of exhaust gas passed therethrough. However, these channels 7 are deformed considerably elastically by the squeezing forces exerted on the entire honeycomb body, so that the whole honeycomb body is under considerable pretension.
- the crimped lateral ends 9 of the stack of sheets are clamped between the upper part 3.1 and the partition 3.3 of the muffler housing and can be included in the usual connection technology of the muffler housing. As shown on the right side of FIG. 3, this can be a flanging 3.5. However, a welded connection 3.6 indicated on the left side of FIG. 3 is also possible, which also includes the ends of the sheet metal layers 5, 6 of the upper part 3.1, the lower part 3.2 and the partition 3.3.
- FIGS. 4, 5, 6, 7 and 8 show different initial shapes for the honeycomb body 4 to be integrated into the silencer housing 3 as a selection of the shapes that are possible overall.
- Figure 4 shows a trapezoidal sheet metal stack 11, made of smooth sheet metal layers 5 and corrugated sheet metal layers 6, in the lateral end regions 9 of the sheet metal stack 11 those sheet metal layers are longer, the ends of which have a longer path to the parting joint after assembly. In this way it is ensured that the ends of practically all sheet metal layers can be held reliably.
- FIG. 5 shows a meandering stack of sheets 12.1 in which a corrugated sheet layer 6 is layered in a meandering manner, with individual smooth sheets 5 being arranged between the individual layers. A similar configuration is shown in FIG.
- FIG. 7 shows an oval sheet stack 13 made of a smooth 5 and a corrugated sheet 6 as the starting stack.
- Such a stack can be achieved in a conventional manner by flattening a spiral sheet stack stacked with a cylindrical cavity.
- Figure 8 finally shows a particularly preferred embodiment in which only the smooth sheet metal layers 5 are to be included in the connection of the parting line. For this reason, the ends of the smooth sheet metal layers protrude to different degrees, depending on their way to the parting line.
- the corrugated sheet metal layers 6 are shorter and in their respective lengths adapted to the cross-sectional shape of the muffler housing and in turn equipped with a certain excess of volume, which is later reduced by plastic deformation.
- the smooth 5 and the corrugated sheet metal layers 6 are equipped with interlocking structures. Microstructures extending transversely to the direction of flow, as are known from the prior art, are particularly suitable for this purpose.
- the present invention creates the possibility of being able to apply exhaust gas catalysts to small engines on a broad basis in order to relieve the environment and the operating personnel of the small engines.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19646242 | 1996-11-08 | ||
DE19646242A DE19646242C2 (en) | 1996-11-08 | 1996-11-08 | Catalytic converter for a small engine |
PCT/EP1997/006044 WO1998021453A2 (en) | 1996-11-08 | 1997-11-03 | Catalytic converter for a small-size engine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1012455A2 true EP1012455A2 (en) | 2000-06-28 |
EP1012455B1 EP1012455B1 (en) | 2002-03-20 |
Family
ID=7811120
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97950069A Expired - Lifetime EP1012455B1 (en) | 1996-11-08 | 1997-11-03 | Catalytic converter for a small-size engine |
Country Status (12)
Country | Link |
---|---|
US (1) | US6403039B1 (en) |
EP (1) | EP1012455B1 (en) |
JP (1) | JP3251299B2 (en) |
KR (1) | KR100495383B1 (en) |
CN (1) | CN1093908C (en) |
AU (1) | AU5316098A (en) |
DE (2) | DE19646242C2 (en) |
ES (1) | ES2174315T3 (en) |
MY (1) | MY122028A (en) |
RU (1) | RU2160371C1 (en) |
TW (1) | TW364038B (en) |
WO (1) | WO1998021453A2 (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7090487B2 (en) * | 2002-01-22 | 2006-08-15 | Catacel Corp. | Catalytic combustor having high cell density |
DE10339468B4 (en) * | 2003-08-27 | 2008-11-13 | Oberland Mangold Gmbh | Catalyst body and exhaust system for a small engine and method for producing the catalyst body |
DE10345910A1 (en) * | 2003-10-02 | 2005-04-21 | Emitec Emissionstechnologie | Method for producing a metallic honeycomb body with a layer length difference |
US7464543B2 (en) * | 2004-05-25 | 2008-12-16 | Cameron International Corporation | Two-stroke lean burn gas engine with a silencer/catalytic converter |
DE102005028044A1 (en) * | 2005-06-17 | 2006-12-28 | Emitec Gesellschaft Für Emissionstechnologie Mbh | Honeycomb body for after-treatment of exhaust gas in automobile sector has housing and layers with curved gradient and of specific length, which in each case comprises partly structured metal film |
DE102010039082A1 (en) * | 2010-08-09 | 2012-02-09 | Behr Gmbh & Co. Kg | Method for producing an exhaust gas heat exchanger for a motor vehicle |
US9388718B2 (en) | 2014-03-27 | 2016-07-12 | Ge Oil & Gas Compression Systems, Llc | System and method for tuned exhaust |
DE102017205147B4 (en) | 2017-03-27 | 2019-04-04 | Continental Automotive Gmbh | Process for producing a honeycomb body |
US10385745B2 (en) * | 2017-10-23 | 2019-08-20 | Honda Motor Co., Ltd. | Exhaust purifying device for internal combustion engine |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4094645A (en) * | 1977-01-24 | 1978-06-13 | Uop Inc. | Combination muffler and catalytic converter having low backpressure |
DE2856030C2 (en) * | 1978-12-23 | 1987-02-12 | Süddeutsche Kühlerfabrik Julius Fr. Behr GmbH & Co KG, 7000 Stuttgart | Method for producing a carrier matrix wound from metal foils for an exhaust gas cartridge |
DE3532408A1 (en) * | 1985-09-11 | 1987-03-19 | Sueddeutsche Kuehler Behr | CARRIER MATRIX, ESPECIALLY FOR A CATALYTIC REACTOR FOR EXHAUST GAS CLEANING IN INTERNAL COMBUSTION ENGINES |
DE3729477C3 (en) * | 1987-09-03 | 1999-09-09 | Stihl Maschf Andreas | Exhaust silencer for two-stroke engines, especially for portable tools such as chainsaws |
FR2624202A1 (en) * | 1987-12-08 | 1989-06-09 | Stihl Andreas | QUIET FOR TWO-STROKE ENGINES |
DE3829668C3 (en) * | 1987-12-08 | 1998-08-13 | Stihl Maschf Andreas | Exhaust silencer for a two-stroke engine in a portable tool |
US4894987A (en) * | 1988-08-19 | 1990-01-23 | Ap Parts Manufacturing Company | Stamp formed muffler and catalytic converter assembly |
DE8905415U1 (en) * | 1989-04-28 | 1990-08-30 | Emitec Gesellschaft für Emissionstechnologie mbH, 5204 Lohmar | Metallic catalyst carrier body fixed in a partition wall |
JPH04122418A (en) * | 1990-09-13 | 1992-04-22 | Nippon Steel Corp | Catalyst converter for purification of exhaust gas automobile |
JP2603033B2 (en) * | 1991-08-30 | 1997-04-23 | ブリッグス アンド ストラットン コーポレイション | Exhaust muffler |
DE4243079C2 (en) * | 1992-12-18 | 1996-03-14 | Oberland Mangold Gmbh | Honeycomb body and process for its manufacture |
US5548955A (en) * | 1994-10-19 | 1996-08-27 | Briggs & Stratton Corporation | Catalytic converter having a venturi formed from two stamped components |
US6109386A (en) * | 1998-02-03 | 2000-08-29 | Emitec Gesellschaft Fuer Emissionstechnologie Mbh | Honeycomb body with a flattened cross-sectional region and a method for producing the honeycomb body |
JP4122418B2 (en) * | 1998-02-17 | 2008-07-23 | 東芝電池株式会社 | Air zinc battery |
-
1996
- 1996-11-08 DE DE19646242A patent/DE19646242C2/en not_active Expired - Fee Related
-
1997
- 1997-10-27 MY MYPI97005066A patent/MY122028A/en unknown
- 1997-11-03 DE DE59706715T patent/DE59706715D1/en not_active Expired - Lifetime
- 1997-11-03 KR KR10-1999-7004066A patent/KR100495383B1/en not_active IP Right Cessation
- 1997-11-03 AU AU53160/98A patent/AU5316098A/en not_active Abandoned
- 1997-11-03 RU RU99111497/06A patent/RU2160371C1/en not_active IP Right Cessation
- 1997-11-03 ES ES97950069T patent/ES2174315T3/en not_active Expired - Lifetime
- 1997-11-03 JP JP52210798A patent/JP3251299B2/en not_active Expired - Fee Related
- 1997-11-03 CN CN97199558A patent/CN1093908C/en not_active Expired - Fee Related
- 1997-11-03 WO PCT/EP1997/006044 patent/WO1998021453A2/en active IP Right Grant
- 1997-11-03 EP EP97950069A patent/EP1012455B1/en not_active Expired - Lifetime
- 1997-11-07 TW TW086116612A patent/TW364038B/en not_active IP Right Cessation
-
1999
- 1999-05-10 US US09/309,181 patent/US6403039B1/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO9821453A2 * |
Also Published As
Publication number | Publication date |
---|---|
RU2160371C1 (en) | 2000-12-10 |
CN1093908C (en) | 2002-11-06 |
KR100495383B1 (en) | 2005-06-14 |
ES2174315T3 (en) | 2002-11-01 |
DE59706715D1 (en) | 2002-04-25 |
JP2001505274A (en) | 2001-04-17 |
WO1998021453A2 (en) | 1998-05-22 |
KR20000053136A (en) | 2000-08-25 |
WO1998021453A3 (en) | 1999-12-23 |
US6403039B1 (en) | 2002-06-11 |
AU5316098A (en) | 1998-06-03 |
TW364038B (en) | 1999-07-11 |
MY122028A (en) | 2006-03-31 |
EP1012455B1 (en) | 2002-03-20 |
CN1258336A (en) | 2000-06-28 |
JP3251299B2 (en) | 2002-01-28 |
DE19646242A1 (en) | 1998-05-14 |
DE19646242C2 (en) | 2001-02-22 |
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