EP1002230A1 - Dispositif de detection de gaz et procede - Google Patents

Dispositif de detection de gaz et procede

Info

Publication number
EP1002230A1
EP1002230A1 EP98937671A EP98937671A EP1002230A1 EP 1002230 A1 EP1002230 A1 EP 1002230A1 EP 98937671 A EP98937671 A EP 98937671A EP 98937671 A EP98937671 A EP 98937671A EP 1002230 A1 EP1002230 A1 EP 1002230A1
Authority
EP
European Patent Office
Prior art keywords
electrode
flow passages
detection device
gases
gas detection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP98937671A
Other languages
German (de)
English (en)
Inventor
Christopher David Jones
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
UK Secretary of State for Defence
Original Assignee
UK Secretary of State for Defence
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by UK Secretary of State for Defence filed Critical UK Secretary of State for Defence
Publication of EP1002230A1 publication Critical patent/EP1002230A1/fr
Ceased legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/62—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
    • G01N27/64—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode using wave or particle radiation to ionise a gas, e.g. in an ionisation chamber
    • G01N27/66—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode using wave or particle radiation to ionise a gas, e.g. in an ionisation chamber and measuring current or voltage
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0022—General constructional details of gas analysers, e.g. portable test equipment using a number of analysing channels
    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/0004—Gaseous mixtures, e.g. polluted air
    • G01N33/0009—General constructional details of gas analysers, e.g. portable test equipment
    • G01N33/0027—General constructional details of gas analysers, e.g. portable test equipment concerning the detector
    • G01N33/0031—General constructional details of gas analysers, e.g. portable test equipment concerning the detector comprising two or more sensors, e.g. a sensor array

Definitions

  • the invention relates to a gas detection device, and method, which is suitable for environmental pollution monitoring, atmospheric tracer detection and monitoring gas or vapour emitting processes.
  • the device is capable of detecting and distinguishing between two simultaneously emitted gases so that the individual contributions of each gas to the total concentration may be determined.
  • tracer materials have been used in the past, for example fluorescent particles, sulphur dioxide and radioactive isotopes of gases such as krypton. Sulphur hexafluoride has also been used widely as a tracer although it is expensive. In particular, as it can be detected down to very low levels (typically 1 part in l ⁇ '°) it is useful for long range studies, up to several hundred kilometres. For detection in the region of 1-2 km downwind oi ' a source, tracer gases such as propylene have been used successfully. Any suitable detection system for measuring such tracer materials at a range of several kilometres from source must be capable of operating in field conditions.
  • a suitable detector with this capability is the Ultra Violet Ionisation Chamber detector, or the UVIC® detector, as described in US patent 5 572 137.
  • the UVIC® detector is an ultra violet exciter device comprising an ultra violet lamp for emitting ultra violet radiation into an inlet tube into which the tracer gas is introduced.
  • the energy of the ultra violet radiation is such that the tracer gas, for example propylene, is ionised and electrons are collected further downstream to give a measure of the tracer gas concentration.
  • the UVIC detector is capable of measuring concentration fluctuations arising from a single source.
  • One known system for achieving this includes a UVIC detector and a Flame Ionisation Detector (FID) in co-location.
  • the FID uses a controlled hydrogen flame as an ionising agent as opposed to the ultra violet lamp in the UVIC detector.
  • the ions produced by the flame are advected both electrically and mechanically towards a small biased electrode where they are collected.
  • this system is capable of providing useful data on two tracer gases emitted simultaneously, the FID is not suited for operation in field conditions.
  • the logistics requirements posed by the ⁇ need for a hydrogen supply and the heavy electrical power demands of the FID are inconvenient for field use.
  • the water vapour generated by the combustion of hydrogen tends to condense on some of the inner surfaces of the instrument. This compromises the integrity of the electrical insulation, leading to noisy and unstable signals and therefore low data quality.
  • the present invention overcomes the problems associated with the UVIC/FID system in that it removes the need for a hydrogen supply and does not have high electrical power demands. Furthermore, the device is convenient for use in field conditions, and performs reliably even under adverse conditions, for example, blowing dust, rain and mist.
  • the device is capable of measuring the behaviour of a pair of simultaneously emitted tracer gases, at a single point, so that the individual contributions to the total concentration can be determined and the concentration fluctuations of the two gases may be measured. This is an important aspect of the development of models and other tools for describing a hazard or nuisance of a substance.
  • the accuracy with which this measurement can be made provides a significant improvement over conventional single source summing techniques which do not allow for non-linear processes.
  • the system has particular application in the field of environmental pollution monitoring, atmospheric tracer detection and in the monitoring of gas or vapour emitting processes.
  • each flow passage having at least one inlet and at least one outlet and an exciter zone and each having a longitudinally extending axis
  • gas induction means for drawing the sample into and through the flow passages
  • the radiation emitted into one of the flow passages is of sufficient energy to be capable of ionising at least one of the gases and the radiation emitted into the other flow passage is of sufficient energy to be capable of ionising both of the gases, such that upon irradiation by one or more of the sources the gases may be ionised and generate ions,
  • each of the electrode arrangements comprising at least one bias electrode and at least one collector electrode, having voltage supply means for supplying a voltage to the one or more bias electrode such that they may be differently charged to the collector electrode or electrodes, wherein each of the electrode arrangements is mounted within a different one of the flow passages such that the one or more collector electrode in each collects the ions produced in a different one of the flow passages, and
  • the gas detection device comprises an input passage, having an inner wall, and means for segregating at least part of the input passage so as to provide two flow passages, each having an outer wall.
  • the input passage and the flow passages may have any one of a substantially circular, elliptical, rectangular or hexagonal cross-section.
  • the device may also comprise means for substantially preventing the flow of the sample along the longitudinally extending axis, between the inner wall of the input passage and the outer wall of the flow passages.
  • the gas detection device may comprise a single source of ultra violet radiation having means for selectively transmitting radiation of selected energy into each of the flow passages such that the sample in each of the flow-passages is irradiated with radiation of different energy.
  • the device may comprise two sources of ultra violet radiation, each for emitting radiation into a different one of the flow passages, such that the sample in each of the flow passages is irradiated with radiation of different energy.
  • the two sources of ultra violet radiation may have different emission spectra. Alternatively, they may have substantially the same emission spectra and each source may comprise filtering means for selectively transmitting radiation of the required energy into the flow passages.
  • the device may comprise any of a krypton lamp and a xenon lamp, an argon lamp and a deuterium lamp or a xenon lamp and a krypton lamp.
  • the device may comprise a krypton lamp for emitting radiation having energy of less than 10.95 eV into one of the flow passages and an argon lamp for emitting radiation having energy of greater than 10.95 eV into the other flow passage.
  • the argon lamp may comprise a LiF window through which ultra violet radiation is transmitted into one of the flow passages and the krypton lamp may comprise a MgF 2 window through which ultra violet radiation is transmitted into the other flow passage.
  • the device is capable of distinguishing propane and propylene gases.
  • the distance between the exciter region in each of the flow passages and the corresponding electrode arrangement may be varied.
  • the gas flow induction means may be a fan which may be operated at a variable speed such that the rate of flow of gas through the input passage may be varied.
  • Each of the electrode arrangements may comprise a substantially tubular outer electrode extending substantially along the longitudinal axis of at least part of the length of the input passage and a rod inner electrode, wherein the outer electrode is mounted concentrically around the rod inner electrode.
  • Any one of the outer electrode and the rod electrode in each of the electrode arrangements may comprise one or more electrode sections.
  • the outer electrode in each electrode arrangement may be biased by the voltage supply means such that it is differently charged to the corresponding rod electrode such that ions generated as a result of the ionisation of the tracer gas or gases are collected at the inner electrode.
  • the rod electrode in each electrode arrangement may be biased such that it is differently charged to the corresponding outer electrode and ions generated as a result of the ionisation of the tracer gas or gases are collected at the outer electrode.
  • the voltage applied to the bias electrode in each electrode arrangement is substantially the same.
  • a method for distinguishing two different gases in a sample comprises the steps of;
  • the method comprises the further step of;
  • Figure 1 shows a diagram of a conventional UVIC device which may be used to measure concentration fluctuations of a gas arising from a single source
  • Figure 2 shows a diagram of the gas detection device of the present invention
  • FIG 3 shows an enlarged view of the electrode arrangement included in the gas detection device shown in Figure 2
  • FIG 4 shows a black diagram of the circuitry which may be used in the gas detection device shown in Figure 2,
  • Figure 5 shows a diagram of the exterior of the gas detection device shown in Figure 2 and
  • Figure 6 shows test results obtained using the gas detection device of the present invention.
  • FIG. 1 shows a diagrammatic cross sectional view of a conventional Ultra Violet Ionisation Chamber (UVIC) detector 1.
  • the UVIC detector 1 comprises an input tube 2 having an open inlet 3 at one end and a fan unit 4 at the opposite end so that, in operation, the device draws air through the inlet 3 and along the length of the tube 2.
  • An ultra violet lamp 5 is mounted externally of the tube so that ultra violet radiation 6 is emitted into the tube 2 into an exciter zone 7 through an aperture 8 in the tube wall.
  • An electrode unit 9 is situated downstream of the exciter zone comprising an outer electrode 10 coaxial along the length of the tube and a rod inner electrode 11.
  • the outer electrode 10 is biased by means of a DC power unit (not shown) by a wire 12 passing through as insulating plug 13 in the tube wall.
  • the rod inner electrode 11 lies with its longitudinal axis along the longitudinal axis of both the tube 2 and the outer electrode 10 and is connected to the other leg of the DC power supply unit via a wire 14.
  • the ultra violet lamp is a krypton lamp which provides radiation 6 at 10.03 eV and 10.65 eV and is capable of ionising propylene (having an ionisation potential of 9.73 eV). If, for example, a propylene tracer gas enters through the inlet 3 to the tube it is irradiated with ultra violet radiation 6 and is ionised.
  • the electrons generated as a result of the ionisation process pass downstream and are collected at the electrode unit 9.
  • the concentration of propylene in the tube 2 may be determined.
  • the UVIC detector 1 also has a strong response to ammonia (NH 3 ) since its ionisation potential (10.16 eV) is close to and just below that of one of the two principle emission bands of the ultra violet krypton lamp 5.
  • the UVIC detector 1 is capable of measuring gas concentration fluctuations arising from a single source, in practice it is common for there to be several closely spaced gas sources emitting simultaneously. The measurement of concentration fluctuations of two simultaneously emitted tracer gases at a single point has been achieved using a gas detection system comprising the UVIC device, as shown in Figure 1, in co-location with a Flame Ionisation Detector (FID), as described previously.
  • FID Flame Ionisation Detector
  • a problem with the FID detector is that its behaviour in field conditions can be unreliable. Also, it is not particularly convenient for use in the field due to the need for a hydrogen supply and the FID also requires a high power supply.
  • the gas detection device 15 of the present invention comprises an input passage 16, or tube, having an open inlet 17 at one end and a fan unit 18 at the opposite end having a power supply (not shown).
  • the fan unit 18 may be any means for inducing gas flow in the tube 16 such that in operation air is drawn into the tube 1 at the inlet 17, is drawn along a length of the tube 16 and is output from an outlet 18a.
  • a combination of any of air, gas or vapour may be drawn through the tube 16.
  • gas shall be taken to mean a gas or a vapour.
  • the tube 16 may typically be a length of tubing which may have more than one inlet and outlet at the respective ends.
  • the tube may be rigid or, in some application, it may be useful if the end portion is flexible to aid probing.
  • the device 15 also comprises a flow separator 19 having its longitudinal axis substantially parallel with the longitudinal axis of the tube 16. The flow separator 19 is situated substantially at the centre of the tube 16 such that it divides the tube into two separate flow passages 20a.20b.
  • the device also comprises two lamps 21,22, each lamp having an associated power supply 23,24, for emitting ultra violet radiation 23.
  • the lamps 21,22 are mounted on substantially opposite sides of the tube 16 such that each emits radiation 23 into a different one of the flow passages 20a,20b.
  • the mounting of the lamps 21,22 on the side of the tube 16 may be such that the radiation 23 is emitted into the flow passages 20a,20b via apertures 25 in the tube wall.
  • the mounting of the lamps 21,22 may be such that the surface of the ultra violet lamp through which radiation is emitted forms part of the wall of the tube 16. It may be preferable to mount the lamps 21,22 at a slight recess from the tube wall (i.e. not protruding into the flow passages 20a,20b) so as to maximise the flow of air and/or gas through the respective flow passages 20a,20b.
  • Each lamp has a dedicated coaxial ion collection electrode arrangement which is mounted within the tube and is situated downstream of the flow passages.
  • An enlarged diagram of the electrode arrangements is shown in Figure 3 but, for clarity, is not drawn in full detail in Figure 2.
  • each electrode arrangement 26a,26b may comprise a tubular outer electrode 27a,27b, which may be biased by means of a bias supply 28 (i.e. a "bias" electrode 27a,27b), and an inner electrode 29a,29b (i.e. a "collector” electrode).
  • the tubular outer electrode, 27a and 27b may be concentrically mounted around the inner electrode, 29a and 29b respectively, such that the inner electrode extends longitudinally along the length of the outer electrode 27a,27b.
  • Each of the outer electrodes 27a.27b and the inner electrodes 29a,29b may be a single electrode or, alternatively, each may comprise a plurality of electrode sections.
  • the longitudinal axes of the electrode arrangements 26a,26b are preferably substantially parallel to the longitudinal axis of the tube 16 so as to maintain the passage of flow between the inlet 17 and the fan unit 18.
  • the bias supply 28 provides a suitable voltage to the outer electrodes 27a,27b such that each may be differently charged from the associated inner electrode 29a,29b respectively.
  • Each inner electrode 29a,29b is connected to subsequent electronic components 30a (not shown in detail in Figure 2), for example for reducing the drift and noise and for measuring the electrode currents at outputs S. and S .
  • the tube 16 may be of substantially circular cross-section, although it may also take other cross-sectional forms, such as rectangular, hexagonal or elliptical.
  • the flow passages 20a,20b may have substantially equal diameters.
  • the outer electrodes 27a,27b may have substantially the same cross- sectional shape as the flow passages 20a,20b.
  • the inner wall of the tube 16 may conveniently be fabricated from a metal of relatively high electrical resistance and, more preferably, of reasonably high workfunction with regard to the emission of electrons upon irradiation with ultra violet radiation. Furthermore, it is preferable if the inner wall material does not retain traces of gases used upon its surface. Suitable materials from which the tube 16 may be made are, for example, aluminium and steel.
  • the outer electrodes 27a,27b must be insulated from the inner wall of the tube wall.
  • the insulation of the outer electrodes 27a,27b from the tube 16 may be achieved by mounting the outer electrodes 27a,27b on insulating rings or spacers 50 (as shown in Figure 3) which also serve as support means for the outer electrodes 27a,27b.
  • the insulating rings 50 may be placed between the outer electrodes 27a,27b and the inner sidewall of the tube 16 such that they circle the circumference of the outer electrodes 27a,27b.
  • the insulating rings also prevent air and/or gas from flowing around the outside of the outer electrodes 29a,29b.
  • the inner electrodes 29a,29b may conveniently be rod electrodes which preferably extend along substantially the full length of the corresponding outer electrode, except that a portion of each of the inner electrodes 29a,29b may be bent to penetrate the wall of the tube 16 through an insulating plug (not shown) for subsequent connection to the electronic circuitry 30a. Connecting the bent portion of the inner electrodes 27a,27b to the tube wall at the insulating plug provides a suitable means of supporting the inner electrodes 27a,27b.
  • the object of the invention is to provide a system which is capable of detecting two tracer gases emitted simultaneously from a single point. Therefore, typically in operation, a sample of gas is drawn into the tube 16, via the inlet 17, by the gas induction means 18 wherein the gas sample will typically comprise two such tracer gases in air.
  • the tracer gases are irradiated in the flow passage regions 20a.20b by the ultra violet radiation 23 emitted from the lamps 22,21 respectively. If upon irradiation the tracer gas becomes ionised, oppositely charged ion pairs, or an ion and an electron, are produced which are then drawn into the electrode arrangements 26a,26b, by the gas flow induction means.
  • the outer electrode and the inner electrode are oppositely charged such that the inner electrode in each case is a "collector" electrode for positively charged ions produced by the ultra violet ionisation process.
  • the choice of the particular lamps and tracer gases used is determined by the need for both of the tracer gases to be ionisable by radiation emitted from one of the lamps and for just one of the tracer gases to be ionisable by radiation emitted from both the lamps. That is, the lamp emitting the higher energy radiation must be able to ionise both gases and the lamp emitting the low energy radiation must only be able to ionise one gas (i.e. the lower ionisation potential gas).
  • the device 15 may comprise an argon lamp (21) and a krypton lamp (22).
  • the krypton lamp 22 is emits radiation at 10.03 eV and 10.65 eV and the argon lamp 21 emits more energetic radiation at 1 1.60 eV and 1 1.80 eV.
  • the argon lamp comprises a LiF (lithium fluoride) coated window (not shown) which permits radiation at 11.60 eV and 11.80 eV to be transmitted.
  • the krypton lamp may typically comprise a MgF 2 (magnesium fluoride) coated window (not shown) which permits radiation at 10.03 eV and 10.65 eV to be transmitted.
  • the device comprising a krypton lamp and an argon lamp may conveniently be used to simultaneously measure propane and propylene tracer gas concentrations.
  • the ionisation potential of propylene (C 3 H 6 ) is 9.73 eV and therefore propylene gas will be ionised by radiation 23 emitted from both the krypton lamp 22 (at 10.03 eV and 10.65 eV) and the argon 21 lamp (at 11.60 eV and 11.80 eV).
  • Propane (C 3 H g ) has an ionisation potential of 10.95 eV and therefore a propane tracer gas will only be ionised by the higher energy radiation emitted from the argon lamp 21.
  • the current collected at the inner electrode 29a associated with the krypton lamp 22 will therefore be in proportion to the concentration of propylene gas in the flow passage 20a.
  • the current collected at the inner electrode 29b associated with the argon lamp 21 arises as a result of the ionisation of both the propylene and propane tracer gases in the flow passage 20b and therefore this current is proportional to the total concentration of both gases.
  • the output signals, at S j and S 2 , generated from the argon lamp and krypton lamp electrode arrangements 26b and 26a respectively, may be related to the individual propylene (C 3 H 6 ) and propane (C 3 H g ) tracer concentrations in the following way;
  • the linear calibration constants may be determined in an exposure chamber prior to measurement. Knowing these values, it is then possible to extract the propane and propylene concentrations from the signals output from the device at Sj and S 2 .
  • the calibration process may conveniently be carried out in a sealed air-filled chamber.
  • the chamber would typically comprise means of injecting the required quantities of tracer gas into the chamber and a mixing fan which would be required to ensure a uniform concentration of the gas was achieved quickly following injection into the chamber.
  • the device 15 would first be exposed to a range of concentrations of the individual tracer gases and then to a mixture of the two.
  • the concentrations of the tracer gas in air would typically be in the range of between 0-2000 ppm by volume for this purpose.
  • krypton and argon lamps in the device 15, several other lamp and tracer gas combinations may also be envisaged which satisfy the requirements for dual-gas measurement.
  • a krypton lamp may be used in combination with a xenon lamp, or an argon lamp may be used in combination with a deuterium lamp.
  • propane and propylene tracer gases other tracer gas combinations may be used, such as ammonia and propane, or ethylene and propane.
  • a xenon and krypton lamp combination may be used with a benzene and propylene tracer gas combination. In practice, environmental and economic factors are likely to limit the choice of tracer gas which may be used.
  • two sources of ultra violet radiation having the same emission spectra to irradiate both flow passages 20a,20b, for example two krypton sources.
  • the two sources will have the same emission spectra (i.e. emit radiation comprising the same wavelength components and energies) but the window of each source may be fitted with a suitable filter, so that radiation of the required energy or energies may be selectively passed into the flow passages 20a,20b.
  • ionic recombination is likely to occur in the region between the portion of the separate passages 20a,20b the ultra violet radiation irradiates and the point at which ions are collected further downstream in the electrode arrangements 26a,26b. This is an undesirable effect as it prejudices the accuracy of the measurement.
  • These recombination processes may be minimised by reducing the distance through which the ionised gas passes prior to collection at the inner electrodes 27a,27b and also be increasing the flow speed.
  • the use of the flow separator 19 ensures that two separate regions are created in the tube 16 (passages 20a,20b).
  • the flow passages 20a,20b may be formed within the tube 16 by the presence of the flow separator 19, as shown in Figure 2).
  • the separate flow passages 20a,20b may be formed from two separate tube sections, within each of which the associated electrode arrangement 26a,26b is situated downstream of the ultra violet lamp positions.
  • the common input section of the tube i.e. length / on Figure 2 is absent. Whilst this arrangement may be suitable for some applications, a slight uncertainty is introduced in that the two gases ionised in the separate flow passages are not sampled at a precise single point.
  • the region of the separate flow passages which is irradiated with the radiation 23 may be as close to the electrodes as possible, so that the ionised gas or gases have as short a distance as possible to travel before they are collected. For some applications, however, it may be useful if this distance is variable. In any case, it is preferable to avoid significant ionisation of the gas or gases in the space between the electrodes.
  • the amount of radiation impinging on the electrodes 27a,27b,29a,29b should be kept to a minimum or avoided altogether. If very high flow rates are to be used, the irradiation zone within the separated flow passages 20a,20b may be further upstream than shown in Figure 2.
  • the tube 16 is moveable along its longitudinal axis with respect to the electrode arrangements 26a,26b such that the position of the irradiated regions in the separated flow passages 20a,20b may be varied by an operator depending on the intended use of the device. This may be achieved if the windows or apertures on both sides of the tube, through which the radiation 23 enters the tube 16, extend along a continuous length of the tube 16.
  • the tube 16 may comprise several apertures on each side of the tube 16. By uncovering selected apertures on each side of the tube and moving the tube along its longitudinal axis, the selected apertures may be aligned with the lamps 21,22, providing a variable distance between the regions irradiated by the lamps and the electrode arrangements 26a,26b. In either case, slidable covers would be required for placement over the apertures when not in use or the portion of the aperture not in use.
  • FIG. 4 shows a block diagram of one circuit which may be used to control the gas detection device 15 shown in Figure 2.
  • the operation of the circuit shown in the figure would be conventional to one familiar with the art.
  • the features of the circuit are as follows; EHTG; EHT generator, MPS: main power supply, EM; electrometer, OS; off-set control, FSC; fan speed controller, SGA; switched gain amplifier, RS; range switch, LPF; low pass filter, INIA; inverting/non-inverting amplifier, 1(1); current corresponding to output S,, 1(2); current corresponding to output S 2 .
  • the currents 1(1) and 1(2) measured at the outputs S, , S 2 may be displayed on a visual display 31.
  • the operation of the circuit shown in Figure 4 would be conventional to one familiar with electrical circuits and the circuit is one of many circuits which may be used to control the device and measure the charge collected at the electrodes 29a,29b.
  • the current sensing part of the circuitry is sensitive to the effects of ions being neutralised upon the surfaces of the electrodes collecting the ions, such that an output dependent upon the amount of each tracer gas (or gases) ionised within the flow passage is provided and the amount of each individual tracer gas at the measurement point may be determined.
  • the lamp power supply units 23,24 and the bias supply 28 are connected to main power supplies.
  • the fan unit 18 is also connected to a main power supply via a fan speed controller (FSC) which enables the rate of flow of " gas through the tube to be adjusted.
  • FSC fan speed controller
  • the gas flow induction means 18 may be in the form of an electric fan. Flow rates of around 4 x 10 "4 m s " may be 3 - 1 ⁇ conveniently achieved using a radial fan, but for increased flow rates e.g. at least 4 x 10 " m s it may be convenient to use a centrifugal fan.
  • FIG. 5 A schematic diagram of an example of the exterior of the complete gas detection device 15 is shown in Figure 5.
  • the tube 16, preferably having the interior configuration shown in Figures 2 and 3, is preferably mounted on a support 35 such that it may be moved along its longitudinal axis with respect to the support 35.
  • This support 35 may also form an ultra violet source box for housing the ultra violet lamps 21,22.
  • the ultra violet support box may be mounted on separate housing means 36 for housing the bias supply 28 and the circuitry for measuring the electrode currents and for reducing the drift and noise, as shown in Figure 4.
  • the housing means 36 may be provided separately from the ultra violet source box 35 and tube 16.
  • the gas flow induction means 18 are situated at the outlet of the tube 16 and means for supplying power to this unit 18 may be held within the ultra violet source box 35 or the housing means 36.
  • the device may be a hand held device or a fixed device and a carrying strap or handle may also be provided (not shown).
  • the device 15 comprises a control 37 for activating the ultra violet lamps (or controls for activating both lamps independently) which may have an associated visual display 38 for indicating lamp operation.
  • the device also comprises controls 39 for varying the sensitivity of the current sensing part of the circuitry, a control for backing off the zero reading (i.e. the off-set controls) 40 and a control for activating the electrodes bias voltage 41.
  • the device 15 may also comprise a visual indicator 31 (as indicated in Figure 4) to give an indication of the current measured at each electrode, from which the individual concentrations of the tracer gases may be deduced.
  • Figure 6 shows the performance that can be achieved with the device of the present invention when tested under field conditions.
  • the device under test comprised an argon and a krypton lamp.
  • each of the outer electrodes 27a,27b has a length of several centimetres, e.g. 3-5 cm and the radial spacing of the inner and outer electrodes, 27a,29a and 27b,29b, in each arrangement 26a.26b may be between 0.2 and 1.0 cm.
  • the voltage across each of the outer and inner electrodes, 27a,29a and 27b,29b may typically be between 20-1000V with currents of the order of 10 nA generated by near-maximal ionised tracer gas levels contacting the electrodes.
  • the voltage should be selected such that the device operates in the saturation region, that is a further increase in the bias voltage does not result in an increased collection of ions.
  • the bias voltage applied to the outer electrodes 29a,29b may be either positive or negative with respect to the virtually earthed inner electrode.
  • the current display 31 will have a sensitivity of between 300 pA to 30-100 nA.
  • Both of the outer electrodes 27a,27b may be biased by means of the same bias supply, as shown in Figure 2, and may be electrically at the same potential. However, it may also be possible to bias the outer electrodes 27a,27b with different voltages depending on the intended application of the device 15. If the bias voltages applied are substantially different, it may be preferable to mechanically re-arrange the two electrode arrangements 26a.26b. In an alternative embodiment to that shown in Figure 2, the inner electrodes 27a,27b may be biased with respect to the outer electrodes 29a,29b such that the latter operate as the "collector" electrodes from which fhe ' output signals may be taken.
  • the electrodes may be made from any suitably conductive metal, such as stainless steel or copper and, preferably, may be made from a relatively inert material such as gold plated brass.
  • the ring seals or spacers for providing the insulation of the electrodes 27a,27b from the wall of the tube 16 may be made of a suitably insulating material, such as polytetra-fluoroethylene (PTFE) and Darvic (IBM RTM).
  • PTFE polytetra-fluoroethylene
  • IBM RTM Darvic
  • the gas detection device is particularly suitable for operation in field conditions, including conditions of blowing dust, rain and mist. Furthermore, it may conveniently take the form of a hand held device. It may be used to examine the behaviour, at a single point, of the concentrations in air of simultaneously emitted tracer gases and is compatible for operation with gases are which are convenient and suitable for release into the open air.

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Abstract

La présente invention concerne un dispositif de détection de gaz permettant de distinguer en un seul point deux gaz émis simultanément et, en particulier, de mesurer la concentration individuelle de chaque gaz en ce point. Le dispositif comprend deux passages de flux dans lesquels on introduit un échantillon comprenant les deux gaz, des moyens d'aspiration de gaz permettant d'attirer l'échantillon dans et à travers les passages de flux et des moyens permettant d'irradier chacun des passages de flux avec des rayonnements ultraviolets d'énergie différente. Le dispositif peut comprendre deux sources de rayonnements ultraviolets, chacune des sources (par exemple, une lampe à krypton et un lampe à argon) émettant des rayonnements dans l'un des passages de flux. L'irradiation des gaz (par exemple du propane et du propylène) de l'échantillon permet d'ioniser ces gaz, l'un d'eux étant ionisé par le rayonnement dans l'un des passages de flux et l'autre étant ionisé par le rayonnement dans les deux passages de flux. A chaque passage de flux sont associées une électrode de polarisation et une électrode collectrice qui sont disposées en aval des passages de flux irradiés. Les courants dans l'électrode collectrice fournissent une indication du ou des gaz ionisés dans chaque passage de flux. L'invention se rapporte également à un procédé permettant de mesurer, en un seul point, les concentrations individuelles des deux gaz émis simultanément. On peut utiliser cette mesure pour la mise au point de modèles et d'autres instruments permettant de déterminer les dangers ou nuisances dues aux gaz. Le dispositif et le procédé de la présente invention possèdent une application particulière dans la surveillance de la pollution, la détection de gaz de dépistage atmosphérique et dans le suivi des processus d'émission de gaz ou de vapeurs.
EP98937671A 1997-08-07 1998-08-05 Dispositif de detection de gaz et procede Ceased EP1002230A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB9716701.9A GB9716701D0 (en) 1997-08-07 1997-08-07 Gas detection device and method
GB9716701 1997-08-07
PCT/GB1998/002354 WO1999008102A1 (fr) 1997-08-07 1998-08-05 Dispositif de detection de gaz et procede

Publications (1)

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EP1002230A1 true EP1002230A1 (fr) 2000-05-24

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EP98937671A Ceased EP1002230A1 (fr) 1997-08-07 1998-08-05 Dispositif de detection de gaz et procede

Country Status (4)

Country Link
EP (1) EP1002230A1 (fr)
CA (1) CA2299365A1 (fr)
GB (2) GB9716701D0 (fr)
WO (1) WO1999008102A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6320388B1 (en) * 1999-06-11 2001-11-20 Rae Systems, Inc. Multiple channel photo-ionization detector for simultaneous and selective measurement of volatile organic compound
JP4164399B2 (ja) * 2003-04-11 2008-10-15 キヤノン株式会社 Ｅｕｖ光源のガス流量計測装置および測定方法
EP4260056A1 (fr) * 2020-12-14 2023-10-18 Molex, LLC Détecteur de photo-ionisation et procédé associé d'activation
KR102611218B1 (ko) * 2021-11-22 2023-12-08 한국전자기술연구원 광이온화 가스 센서

Family Cites Families (5)

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Publication number Priority date Publication date Assignee Title
JPS4827936B1 (fr) * 1968-08-26 1973-08-28
WO1993002354A1 (fr) * 1991-07-19 1993-02-04 The Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland Procede et dispositif de detection de gaz
DE4305704B4 (de) * 1993-02-25 2006-02-16 Matter + Siegmann Ag Verfahren und Vorrichtung zur Untersuchung von in einem Gas befindlichen Partikeln
AU6146394A (en) * 1993-03-05 1994-09-26 Secretary Of State For Defence In Her Britannic Majesty's Government Of The United Kingdom Of Great Britain And Northern Ireland, The Gas detection devices
RU2063093C1 (ru) * 1994-06-01 1996-06-27 Фирма - Ауергеселшафт Ультрафиолетовая лампа для фотоионизационного детектирования

Non-Patent Citations (1)

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Title
See references of WO9908102A1 *

Also Published As

Publication number Publication date
GB2343003A (en) 2000-04-26
WO1999008102A1 (fr) 1999-02-18
CA2299365A1 (fr) 1999-02-18
GB0001867D0 (en) 2000-03-22
GB9716701D0 (en) 1997-10-15

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