EP0985673A3 - Composés oxy-aluminium, catalyseur de polymèrisation, et procédé de polymériser oléfines et monomères aromatiques - Google Patents

Composés oxy-aluminium, catalyseur de polymèrisation, et procédé de polymériser oléfines et monomères aromatiques Download PDF

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Publication number
EP0985673A3
EP0985673A3 EP99117418A EP99117418A EP0985673A3 EP 0985673 A3 EP0985673 A3 EP 0985673A3 EP 99117418 A EP99117418 A EP 99117418A EP 99117418 A EP99117418 A EP 99117418A EP 0985673 A3 EP0985673 A3 EP 0985673A3
Authority
EP
European Patent Office
Prior art keywords
polymerization catalyst
compound
oxy compound
aromatic hydrocarbon
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP99117418A
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German (de)
English (en)
Other versions
EP0985673B1 (fr
EP0985673A2 (fr
Inventor
Masayuki Fujita
Masaaki Nabika
Tatsuya Miyatake
Tsuyoshi Watanabe
Yoshinori Seki
Nobuo Oi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
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Filing date
Publication date
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Publication of EP0985673A2 publication Critical patent/EP0985673A2/fr
Publication of EP0985673A3 publication Critical patent/EP0985673A3/fr
Application granted granted Critical
Publication of EP0985673B1 publication Critical patent/EP0985673B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
    • C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
EP99117418A 1998-09-09 1999-09-07 Composé oxy-aluminium modifiö, catalyseur de polymèrisation et procédé d ' obtention de polymères d' oléfines et de polymères aromatiques d'hydrocarbures d'alkényles Expired - Lifetime EP0985673B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP25528798 1998-09-09
JP25528798 1998-09-09

Publications (3)

Publication Number Publication Date
EP0985673A2 EP0985673A2 (fr) 2000-03-15
EP0985673A3 true EP0985673A3 (fr) 2001-06-06
EP0985673B1 EP0985673B1 (fr) 2006-11-22

Family

ID=17276674

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99117418A Expired - Lifetime EP0985673B1 (fr) 1998-09-09 1999-09-07 Composé oxy-aluminium modifiö, catalyseur de polymèrisation et procédé d ' obtention de polymères d' oléfines et de polymères aromatiques d'hydrocarbures d'alkényles

Country Status (6)

Country Link
EP (1) EP0985673B1 (fr)
KR (1) KR20000022955A (fr)
CN (1) CN1130389C (fr)
AT (1) ATE346075T1 (fr)
DE (1) DE69934061T2 (fr)
SG (1) SG74749A1 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6046347A (en) * 1998-09-24 2000-04-04 Akzo Nobel Nv Aluminoxane synthesis employing reduced amount of trialkylaluminum compound
SG93255A1 (en) * 1999-08-31 2002-12-17 Sumitomo Chemical Co Olefin polymerization catalyst and process for producing olefin polymer
JP2003514931A (ja) * 1999-11-19 2003-04-22 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー エチレンとジエンの共重合
EP1113026B1 (fr) 1999-12-27 2009-12-09 Sumitomo Chemical Company, Limited Composant catalytique pour la polymérisation par addition, catalyseur pour la polymérisation par addition, et procédé pour la production de polymères d'addition
EP1650236A1 (fr) * 2004-10-21 2006-04-26 Total Petrochemicals Research Feluy Agents d'activation pour des composés de l'hafnium du type métallocène
JP2011122134A (ja) * 2009-11-10 2011-06-23 Kanazawa Univ アルキレンオキシド重合触媒の製造方法およびポリ（アルキレンオキシド）の製造方法
WO2016036559A1 (fr) * 2014-09-03 2016-03-10 Univation Technologies, Llc Activateurs catalytiques, procédés de préparation et utilisation dans des procédés de polymérisation
GB201607989D0 (en) * 2016-05-06 2016-06-22 Scg Chemicals Co Ltd Catalytic support and the uses thereof
EP3318544B1 (fr) * 2016-11-07 2020-03-18 Scg Chemicals Co. Ltd. Procédé de préparation de cire de polyéthylène polymérisé
CN113571768B (zh) * 2021-09-23 2022-02-18 浙江金羽新能源科技有限公司 改性铝基化聚合物及制备方法、耐高压固态聚合物电解质膜及制备方法、金属锂二次电池

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0269002A2 (fr) * 1986-11-21 1988-06-01 Texas Alkyls, Inc. Composés fluoralkoxyaluminium et leur usage dans les procédés de polymérisation
EP0561476A1 (fr) * 1992-03-18 1993-09-22 Akzo Nobel N.V. Solution de polyméthylaluminoxane avec stabilisation améliorée de la solution
US5391793A (en) * 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
WO1995032095A1 (fr) * 1994-05-25 1995-11-30 W.R. Grace & Co.-Conn. Film contenant un copolymere aromatique alpha-olefine/vinyle
EP0726271A1 (fr) * 1995-02-08 1996-08-14 Phillips Petroleum Company Produit organoaluminoxy, systèmes catalitiques, leur préparation et utilisation
US5648440A (en) * 1992-12-08 1997-07-15 Mitsubishi Chemical Corporation Catalyst components for polymerization of olefins and use thereof
DE19711304A1 (de) * 1996-03-19 1997-10-30 Sumitomo Chemical Co Eine Aluminiumverbindung enthaltender fester Katalysatorbestandteil, Katalysator für Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers
EP0906914A2 (fr) * 1997-09-03 1999-04-07 Mitsui Chemicals, Inc. Aluminoxane solide comme support pour catalyseur, son préparation et utilisation
DE19917985A1 (de) * 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
DE19917984A1 (de) * 1999-04-21 2000-11-09 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystem zur Herstellung von Polyolefinen
EP1081167A1 (fr) * 1999-08-31 2001-03-07 Sumitomo Chemical Company, Limited Catalyseur pour la polymérisation d'oléfines et procédé de préparation de polyoléfines

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5939346A (en) * 1992-11-02 1999-08-17 Akzo Nobel N.V. Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0269002A2 (fr) * 1986-11-21 1988-06-01 Texas Alkyls, Inc. Composés fluoralkoxyaluminium et leur usage dans les procédés de polymérisation
EP0561476A1 (fr) * 1992-03-18 1993-09-22 Akzo Nobel N.V. Solution de polyméthylaluminoxane avec stabilisation améliorée de la solution
US5416229A (en) * 1992-03-18 1995-05-16 Akzo Nobel Chemicals Inc. Polymethylaluminoxane of enhanced solution stability
US5391793A (en) * 1992-11-02 1995-02-21 Akzo Nobel N.V. Aryloxyaluminoxanes
US5648440A (en) * 1992-12-08 1997-07-15 Mitsubishi Chemical Corporation Catalyst components for polymerization of olefins and use thereof
WO1995032095A1 (fr) * 1994-05-25 1995-11-30 W.R. Grace & Co.-Conn. Film contenant un copolymere aromatique alpha-olefine/vinyle
EP0726271A1 (fr) * 1995-02-08 1996-08-14 Phillips Petroleum Company Produit organoaluminoxy, systèmes catalitiques, leur préparation et utilisation
DE19711304A1 (de) * 1996-03-19 1997-10-30 Sumitomo Chemical Co Eine Aluminiumverbindung enthaltender fester Katalysatorbestandteil, Katalysator für Olefinpolymerisation und Verfahren zur Herstellung eines Olefinpolymers
EP0906914A2 (fr) * 1997-09-03 1999-04-07 Mitsui Chemicals, Inc. Aluminoxane solide comme support pour catalyseur, son préparation et utilisation
DE19917985A1 (de) * 1999-04-21 2000-10-26 Targor Gmbh Katalysatorsystem
DE19917984A1 (de) * 1999-04-21 2000-11-09 Targor Gmbh Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystem zur Herstellung von Polyolefinen
EP1081167A1 (fr) * 1999-08-31 2001-03-07 Sumitomo Chemical Company, Limited Catalyseur pour la polymérisation d'oléfines et procédé de préparation de polyoléfines

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LINDNER, EKKEHARD ET AL: "Poly(Alumosiloxanes) as Matrixes for the Immobilization of Catalytically Active Ruthenium(II) Complexes", CHEM. MATER., vol. 10, no. 1, 1998, pages 217 - 225, XP000990977 *

Also Published As

Publication number Publication date
EP0985673B1 (fr) 2006-11-22
EP0985673A2 (fr) 2000-03-15
SG74749A1 (en) 2000-08-22
ATE346075T1 (de) 2006-12-15
DE69934061D1 (de) 2007-01-04
KR20000022955A (ko) 2000-04-25
CN1248584A (zh) 2000-03-29
CN1130389C (zh) 2003-12-10
DE69934061T2 (de) 2007-06-21

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