EP0963162A1 - Composite ice confections - Google Patents
Composite ice confectionsInfo
- Publication number
- EP0963162A1 EP0963162A1 EP97936639A EP97936639A EP0963162A1 EP 0963162 A1 EP0963162 A1 EP 0963162A1 EP 97936639 A EP97936639 A EP 97936639A EP 97936639 A EP97936639 A EP 97936639A EP 0963162 A1 EP0963162 A1 EP 0963162A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- ice
- water ice
- water
- confection
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000009508 confectionery Nutrition 0.000 title claims abstract description 57
- 239000002131 composite material Substances 0.000 title description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 108
- 239000000203 mixture Substances 0.000 claims abstract description 38
- 235000013336 milk Nutrition 0.000 claims abstract description 31
- 239000008267 milk Substances 0.000 claims abstract description 31
- 210000004080 milk Anatomy 0.000 claims abstract description 31
- 238000000518 rheometry Methods 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 26
- 238000001816 cooling Methods 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 7
- 239000003349 gelling agent Substances 0.000 claims description 5
- 239000008234 soft water Substances 0.000 abstract description 3
- 239000000047 product Substances 0.000 description 30
- 235000010420 locust bean gum Nutrition 0.000 description 25
- 238000009472 formulation Methods 0.000 description 24
- 239000010410 layer Substances 0.000 description 21
- 235000015243 ice cream Nutrition 0.000 description 19
- 235000010418 carrageenan Nutrition 0.000 description 18
- 239000000679 carrageenan Substances 0.000 description 18
- 229920001525 carrageenan Polymers 0.000 description 18
- 229940113118 carrageenan Drugs 0.000 description 18
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 18
- 238000007598 dipping method Methods 0.000 description 14
- GJCOSYZMQJWQCA-UHFFFAOYSA-N 9H-xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 11
- 229920001285 xanthan gum Polymers 0.000 description 11
- 108010010803 Gelatin Proteins 0.000 description 10
- 229920000159 gelatin Polymers 0.000 description 10
- 239000008273 gelatin Substances 0.000 description 10
- 235000019322 gelatine Nutrition 0.000 description 10
- 235000011852 gelatine desserts Nutrition 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000000499 gel Substances 0.000 description 4
- 239000001814 pectin Substances 0.000 description 4
- 235000010987 pectin Nutrition 0.000 description 4
- 229920001277 pectin Polymers 0.000 description 4
- PYMYPHUHKUWMLA-UHFFFAOYSA-N 2,3,4,5-tetrahydroxypentanal Chemical compound OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 3
- 244000303965 Cyamopsis psoralioides Species 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229910003460 diamond Inorganic materials 0.000 description 3
- 239000010432 diamond Substances 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 235000013572 fruit purees Nutrition 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000010008 shearing Methods 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 229920001817 Agar Polymers 0.000 description 2
- 229920000161 Locust bean gum Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000005273 aeration Methods 0.000 description 2
- 239000008272 agar Substances 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229960001031 glucose Drugs 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000000711 locust bean gum Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 240000006766 Cornus mas Species 0.000 description 1
- 235000003363 Cornus mas Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920002774 Maltodextrin Polymers 0.000 description 1
- 239000005913 Maltodextrin Substances 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 239000005862 Whey Substances 0.000 description 1
- 102000007544 Whey Proteins Human genes 0.000 description 1
- 108010046377 Whey Proteins Proteins 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 235000020244 animal milk Nutrition 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000011950 custard Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- -1 emulsifierε Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229940014259 gelatin Drugs 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000004213 low-fat Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 229940035034 maltodextrin Drugs 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 235000020183 skimmed milk Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000013322 soy milk Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 235000013618 yogurt Nutrition 0.000 description 1
Definitions
- the invention relates to ice confections and their method of preparation.
- the invention relates to ice confections which comprise a mass of a milk containing ice confection, for example ice cream, with at least one discrete element of water ice which is preferably present as a surface layer covering the mass of milk containing ice confection.
- a well known ice confection on the market is a traditional split product comprising an ice cream core and an outer layer of water ice on a stick. These products are produced by filling a mould with a water ice solution, cooling the mould such that a layer of water ice is frozen to the mould, removing the still liquid water ice solution from the centre, filling the centre with ice cream, inserting a stick and final cooling to fully freeze the product.
- the consumer desires a soft water ice layer of high quality.
- WO 95/20883 proposes to produce the water ice layer via a dipping process, whereby the surface of the ice cream core is pre-cooled to -15°C or below to effect the quick freezing of the water ice layer, the water ice layer is then hardened. This method indeed results in products of good quality having a soft water ice layer texture.
- EP 500 940 discloses a process to provide a two component ice confection having a rugged surface .
- An ice confection core is dipped into a semi-frozen ice mixture.
- EP 560 052 discloses a process for coating a frozen confectionery product which comprises applying a gelatin sol to the confectionery product.
- the gelatin sol may contain up to 10% gelatin and preferably contains from 1.5 to 3% by weight based on the total weight of the gelatin sol.
- the gelatin sol is applied by a dipping process, the temperature of the sol being from 10 to 25°C during this dipping process.
- the coated product may advantageously be re- frozen in a freezing tunnel to complete the setting process if necessary.
- the gelatin sol must be at a relatively high temperature during the dipping process which results in some melting of the ice confection core, providing a loss of quality.
- the finished coating has a tendency to become sticky and adhere to the paper in which the ice confection is packaged.
- the invention relates to a process for producing an ice confection comprising a mass of milk containing ice confection and a discrete element of water ice, wherein;
- a mass of milk containing ice confection is contacted with a water ice solution having a rheometry value of more than about 1.0 to cause the water ice solution to adhere to the mass of milk containing ice confection;
- the water ice solution has a rheometry value of 1.1 to 1.8, more preferred 1.2 to 1.6.
- a suitable method of measuring the rheometry value is described in the examples .
- Suitable measures may for example be selected from variation of type and amount of solids, use of thickeners or gelling agents, inclusion of other phases e.g. aeration etc, and mixtures thereof.
- the rheometry value will increase if the solids content of the water ice solution increases. For example a low amount of sugar in the formulation will provide low rheometry values, while an increase in sugar level will increase this parameter. Also the inclusion of high levels of fruit puree or other solids result in an increase .
- Specific minor ingredients can also be used for increasing the rheometry value.
- one or more thickeners or gelling agents can be used.
- suitable ingredients are for example locust bean gum, xanthan, agar, guar, carrageenan, alginate, pectin, microcrystalline cellulose, gelatin, maltodextrin etc. Levels of these ingredients may be selected to obtain the desired rheometry values.
- suitable levels are from 0.5 to 1.5 wt%, more preferred 0.65 to 1.2 wt% .
- processing conditions of the water ice solution can be adapted to influence the rheometry index. For example aeration of the water ice solution may lead to a higher rheometry value .
- the water ice solution is preferably maintained at a temperature at or below 8°C, preferably at or below 5°C.
- the maintenance of a low temperature has two advantages . Firstly any melting of the surface of the mass of milk containing ice confection on application of the water ice solution is minimised and thus a high quality product is provided. Secondly it is hygienically advantageous to process at cooler temperatures.
- the requirement to maintain the water ice solution at a temperature of at or below 8°C, whilst still being able to apply the water ice solution to the mass of milk containing ice confection is achieved by producing a smooth paste of the gel .
- the smooth paste is provided by shearing the water ice mixture either during or after gelation. Examples of suitable shearing devices include scraped surface heat exchangers, stirred vessel, spray driers followed by rehydration, static mixers and colloid mills.
- the total soluble solids level of the water ice solution is between l and 70 wt%, most preferred 2-60 wt%.
- Low soluble solids levels may for example advantageously be used for the formulation of isotonic water ice solutions. While higher soluble solids levels result in more traditional water ice solutions.
- the water ice solution is chosen such that it forms a smooth layer on the mass of milk containing ice confection.
- the water ice solution is substantially liquid and does not contain ice crystals.
- the water ice solution will be at a temperature above its freezing point.
- the smooth layer formed on the mass of milk containing ice confection preferably has a thickness of 0.5 to 6 mm, more preferred 1 to 5, most preferred 2 to 4 mm.
- the layer is a single layer and not a composite layer e.g. produced by multiple applications.
- the mass of milk containing ice confection contains proteins and this class of products includes, ice cream, frozen yoghurt, sherbet, sorbet, ice milk and frozen custards.
- the usual form of protein will be animal milk, but vegetable sources e.g. soy milk are also usable.
- the level of fat in the mass of milk containing ice confection may vary in a broad range, for example 0-3 wt% for zero to low fat products, 3 to 6 wt% for medium fat, 6-10 wt% for creamy products and above 10wt% for super- premium products.
- the mass of milk containing ice confection is aerated to an overrun of 30 to 300%, more preferred 40 to 200%, most preferred 50 to 150%.
- a problem of known ice confection coatings is that they have a tendency to become sticky and adhere to the inner surface of the wrapper in which the ice confection is packaged. Thus the consumer of the product has difficulty unwrapping the product for consumption.
- the adhered water ice solution is subjected to a rapid cooling step such that a temperature of -15°C or below is achieved throughout the water ice.
- rapid cooling is meant that the cooling environment has a temperature of -50°C or below (inclusive of wind chill factor) , preferably -60°C or below (inclusive of wind chill factor) , most preferably -70°C or below (inclusive of wind chill factor) .
- a liquid cryogen such as liquid nitrogen
- the rapid cooling is achieved by dipping in liquid nitrogen.
- the wind chill factor may be calculated using the following formulation (as used by the US National Weather Service) ;
- T ⁇ c is the wind chill (°C)
- T is the actual temperature (°C)
- V is the wind speed (km/hr) . This formula is only applicable at wind speeds above about
- the invention also provides an ice confection comprising a mass of milk containing ice confection and a discrete element of water ice, wherein the water ice is essentially non-sticky and has a composition which in the form of a water ice solution has a rheometry value of more than about 1.0.
- the surface of the mass of milk containing ice confection has a temperature of less than -5°C when contacting with the water ice, more preferred less than -8°C, most preferred less than -10°C.
- the temperature will be more than -40°C, more preferred more than -25°C.
- Especially preferred for low cost production are temperatures of more than -14 °C, more preferred more than -12°C.
- the mass of milk containing ice confection can be contacted with the water ice solution in any convenient manner, for example spraying, dipping, smearing, rolling etc. Most preferred is the dipping of the mass of milk containing ice confection into the water ice solution. Also preferably the core is provided with a stick which can act as a grip during the dipping operation.
- the discrete element of water ice is preferably present as a layer, most preferably as a surface layer. It is particularly preferred that the water ice solution is contacted with the mass of milk containing ice confection in such a way that a water ice layer is produced which predominantly covers the mass of milk containing ice confection without leaving substantial uncoated areas .
- Ice confections according to the invention may contain a number of optional ingredients normally present in ice cream or water ice.
- optional ingredients are flavouring materials, emulsifier ⁇ , stabilisers, colorants etc .
- a water ice solution having the following composition was prepared by mixing the ingredients into water at 60°C under gentle stirring:
- pick-up amounts of approximately 20 to 50g, more preferably approximately 25 to 40g, typically correspond to rheometry values according to the invention.
- the rheometry value can be measured as shown in Example II.
- the rheometry value can be determined as follows:
- a solid stainless steel cylinder having a length of 80mm and a diameter of 38 mm was provided with 1.2 pitch diamond knurl grooves of depth 0.5mm extending for 40mm along the length of the cylinder.
- a 1.2 pitch knurl defines that the distance between the grooves is 1.2mm.
- the diamond knurl defines that the grooves intersect to form a diamond pattern.
- the included angle at the top and bottom apex is 60°, whilst the included angle between is 120°
- the grooves are at an angle of 30° to the vertical.
- the cross-section of the groove is triangular, w th a right angle at the tip.
- the total depth is 0.5mm
- the remaining 40mm length of the cylinder was smooth.
- the cylinder was cooled to 2°C and the patterned end of the cylinder was dipped into the water ice solution at 2°C for 5 seconds.
- the depth of dipping was 40 mm (i.e. for the full extent of the grooves) .
- the bottom surface was wiped clean and the cylinder was weighed to determine the amount of water ice solution adhered to it From the surface area of the cylinder (exclusive of grooves), the weight of pick-up and the density of the water ice solution, the average layer thickness adhering to the cylinder is calculated in mm's. This is the rheometry value.
- the surface area (excluding the grooves) is 4780mm 2 . If 7g of water ice solution of density 1.1 g cm 3 is adhered, the volume of water ice is 6360mm"'. Therefore the rheometry value is
- An ice cream formulation was prepared of the following composition:
- the ice cream was prepared with an overrun of 60% and extruded through a shaped nozzle to give a cylinder of 52g and a stick was inserted.
- the ice cream was frozen in a blast freezer such that the surface temperature was -10°C.
- the ice cream was then dipped for 5 seconds into water ice solutions at 2°C having the following formulations;
- the adhering water ice solution was then rapidly cooled in a blast freezer operating between -32°C and -34°C (wind speed factor of 5 ms "1 ) for 15 minutes (cooling environment of the blast freezer was therefore -5l°C inclusive of wind chill factor) .
- the rheometry value for each formulation was measured as in Example II.
- the rheometry value was 0.8, for formulation B 1.4, and for formulation C 0.8.
- Formulation B resulted in highly preferred products having a smooth appearance, good thickness of the single water ice layer and with a soft attractive texture.
- Formulations A and C resulted in a layer which was too thin after the single dip in water ice solution.
- Example III was repeated except that the ice cream was cooled to -12°C prior to dipping in the water ice solution.
- formulation A (measured as in example I) was 11 g, while for formulation B this was 32 g and for formulation C this was I2g.
- Formulation B resulted in highly preferred products having a smooth appearance, good thickness of the single water ice layer and with a soft attractive texture.
- Formulations A and C resulted in a layer which was too thin after a single dip in the water ice solution.
- a water ice solution of formulation B in Example III was produced and cooled to 2oC.
- the water ice solution provided was a soft gel -type substance. This gel was sheared for approximately 30 seconds in a domestic blender to form a smooth flowable paste.
- Ice cream prepared as in Example III was frozen in a blast freezer such that the surface temperature was -9°C.
- the ice cream was then dipped for 5 seconds in the water ice solution at 3°C.
- the adhering water ice solution was then rapidly cooled by immersion in liquid nitrogen for 12 seconds.
- the product was then wrapped in a waxed paper wrapper and stored at -25°C.
- the product did not significantly adhere to the wrapper.
- Example V was repeated except that the product was not rapidly cooled after immersion in the water ice solution but cooled in a cold store at -25°C.
Landscapes
- Confectionery (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9700231.5A GB9700231D0 (en) | 1997-01-08 | 1997-01-08 | Low temperature food product |
GB9700231 | 1997-01-08 | ||
PCT/EP1997/003720 WO1998004149A1 (en) | 1996-07-26 | 1997-07-10 | Composite ice confections |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0963162A1 true EP0963162A1 (en) | 1999-12-15 |
Family
ID=10805639
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP97936639A Withdrawn EP0963162A1 (en) | 1997-01-08 | 1997-07-10 | Composite ice confections |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0963162A1 (enrdf_load_stackoverflow) |
GB (1) | GB9700231D0 (enrdf_load_stackoverflow) |
IN (1) | IN183717B (enrdf_load_stackoverflow) |
-
1997
- 1997-01-08 GB GBGB9700231.5A patent/GB9700231D0/en active Pending
- 1997-07-10 EP EP97936639A patent/EP0963162A1/en not_active Withdrawn
- 1997-07-21 IN IN433BO1997 patent/IN183717B/en unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9804149A1 * |
Also Published As
Publication number | Publication date |
---|---|
IN183717B (enrdf_load_stackoverflow) | 2000-03-25 |
GB9700231D0 (en) | 1997-02-26 |
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