EP0954426A1 - Verfahren zum einfügen von dekorationen in einem thermoplastischen teil - Google Patents
Verfahren zum einfügen von dekorationen in einem thermoplastischen teilInfo
- Publication number
- EP0954426A1 EP0954426A1 EP98955682A EP98955682A EP0954426A1 EP 0954426 A1 EP0954426 A1 EP 0954426A1 EP 98955682 A EP98955682 A EP 98955682A EP 98955682 A EP98955682 A EP 98955682A EP 0954426 A1 EP0954426 A1 EP 0954426A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- decoration
- mold
- parts
- injection
- injected
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/16—Making multilayered or multicoloured articles
- B29C45/1671—Making multilayered or multicoloured articles with an insert
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14467—Joining articles or parts of a single article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14467—Joining articles or parts of a single article
- B29C45/14508—Joining juxtaposed sheet-like articles, e.g. for making trim panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14778—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles the article consisting of a material with particular properties, e.g. porous, brittle
- B29C45/14795—Porous or permeable material, e.g. foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C45/14467—Joining articles or parts of a single article
- B29C45/14508—Joining juxtaposed sheet-like articles, e.g. for making trim panels
- B29C2045/14516—Joining juxtaposed sheet-like articles, e.g. for making trim panels the transition area of juxtaposed parts being hidden in a groove of the moulded article
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/14—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
- B29C2045/1486—Details, accessories and auxiliary operations
- B29C2045/14983—Bursting or breakthrough of the insert by the injection pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3014—Door linings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
- B29L2031/3041—Trim panels
Definitions
- the present invention relates to a delimited insertion process of at least one decoration in a thermoplastic support during a low pressure molding and the parts obtained by this process.
- FR-A-2 702 990 describes a process for decorating a thermoplastic support by low-pressure overmolding, according to which:
- thermoplastic material is introduced in the molten state into the mold below the decoration;
- the material is injected at low pressure through at least one nozzle while an inert low pressure gas is simultaneously injected by means of a nozzle working sequentially to orient the molten material in the desired locations of the mold.
- This low pressure injection has the advantage of not deteriorating the decor.
- the folding, or covering of the edges by the decoration can be carried out in the mold but it requires, most of the time, a subsequent operation of manual or automatic recovery.
- the decoration is placed on the side of the mold matrix, then the material is injected in the molten state against the back of the decoration. It is the injection pressure which places the decoration in the cavity of the matrix.
- the decoration thus perfectly fits the cavity of the matrix but frequently overflows from it. Therefore, it is necessary to cut the edges of the decoration after demolding. And humidity can pass from the back side to the front side decorated by capillary action in the decor.
- a part partially covered by a decoration it is known to proceed in two stages.
- a part is coated with a decoration which will be called a medallion.
- the medallion (s) are assembled by conventional connecting means (gluing, welding, clipping, etc.) to form the partially decorated part.
- conventional connecting means glue, welding, clipping, etc.
- the object of the present invention is to overcome these drawbacks and to eliminate recovery operations.
- the decoration is inserted into the thermoplastic material in very precise delimited areas of finishing or semi-finishing to avoid any additional recovery. It makes it possible to obtain a plastic part having a finishing face, integrating different decorations, by successive stages of plastic injection, without one of them being added by gluing, welding or clipping.
- EP-A-332 889 relates to the injection molding of plastic material on a canvas diaphragm. Beads of thermoplastic material are formed on two circumferences, the assembly then being cut inside the smallest of the circumferences and outside the largest. This document does not describe a process for obtaining parts made of thermoplastic material, decorated with at least one decoration, perfectly sealed, and obtained by chemical bonding of parts injected in one or two stages.
- EP-A-636 464 describes a method of overlapping making it possible to integrate the periphery of a decoration in the injected plastic material making it possible to avoid costly manual rework on the edges of the part. This process makes it possible to obtain a good seal by integrating the edge of the decoration in the plastic material.
- a second object of the invention is to propose a method of integrating several different decorations, juxtaposed or not, on an injected thermoplastic part. This process allows various decorations to appear on a thermoplastic part, in different zones, also by integrating functional shapes of said part. It implements specially adapted tools making it possible to integrate in transfer parts of pieces (medallions) previously produced or to obtain these decorations in a single operation comprising sequential phases, without having to open the mold.
- the method of delimited insertion of a decoration in a rigid thermoplastic support by low-pressure overmolding of the textile decoration placed in a mold, in at least two parts, having cavities reserving between them at least one molding cavity , a first decoration being disposed against a part of the mold and pressed against it by the injection pressure is characterized in that the material is injected below the first decoration and penetrates, during the injection, into said cavity through the first decoration to integrate, by chemical bond, the edges of the adjoining pieces of the panel, some of the pieces being covered by a second decoration placed below the first decoration which is then cut opposite said certain pieces.
- the medallions previously made and decorated are introduced into the mold where they are precisely positioned, as well as a general decoration covering the entire external surface of the panel or of the part.
- Plastic material is injected in the molten state at low pressure with sequential nozzles behind the surface of the general decor to bring together the different medallions and form the panel or the room.
- cutting blades in front and at the periphery of the medallions cut the general decor to reveal the local decorations of the medallions. This cutting operation can, of course, be carried out using different cutting techniques.
- a first injection is carried out sequentially behind the local decorations arranged and maintained in the mold by mechanical systems, behind the main decor.
- a second sequential injection is made behind the main decor.
- the material passes through the decoration on the periphery of the local areas (medallions) which makes it possible to obtain the chemical connections for securing the elements. It is thus possible to simply obtain rigid one-piece and waterproof parts without opening the mold.
- This setting up of the decoration makes it possible, in certain zones, to pass the thermoplastic material through the decoration and to obtain an overmolded assembly in which the components are perfectly integrated and waterproof.
- the edge of the textile is inserted into the plastic in the overlap zones, with, if necessary, automatic cutting of the textile or other decorative material in the mold.
- the part obtained can be used as is with local decoration or reinserted in another mold in order to undergo an additional overmolding to obtain an assembly of several parts, flexible-hard, two-tone or any other arrangement.
- - Figure 2 a detailed view of a mold in which it is used mobile blocks.
- - Figure 3 a view of a thermoplastic part comprising two local decorations on a general surface having a third decoration;
- Figure 1 is a section of a part obtained by the method according to the invention. Two pieces of compatible thermoplastic materials 3 and 7 are joined by chemical bond during overmolding.
- the part 3 is coated with a local decoration 2 in a first mold (not shown) as indicated above.
- the part 3 includes a peripheral centering 4 for its precise positioning in a second mold. It is noted that during this first injection, the molten plastic material is passed through the decoration 2 to form the peripheral centering pins 4 and the chemical bond, as symbolized by the arrows, which ensures a tight overlap.
- the part 3 previously obtained is positioned in the cavity of the second mold (not shown).
- the thermoplastic material such as polypropylene or any other suitable thermoplastic material, is injected in the molten state, to constitute the part 7 in the cavity of the second mold. possibly on the back of a general decoration 1 which is stretched in the matrix of this second mold.
- connection between the two parts 3 and 7 is obtained by chemical welding along the surfaces 6 of the parts 7 which are sufficiently dimensioned to maintain a temperature making it possible to heat the corresponding profile of the part 3 and ensure the chemical bond between the two parts.
- this chemical bond is independent of the presence or not of the decoration 1 covering the entire panel.
- the part 3 is surrounded by a part 7 which is injected into the second mold. But it could be two independent parts 7.7a.
- the materials injected for the constitution of parts 7 and 3 can be the same or different but with chemical compatibility.
- the decoration 1 may consist of a textile with or without foam or of a carpet or any other suitable material. Thanks to this method, the part 7a can also be coated with an identical or different decoration from the general decoration 1 which is, beforehand, stretched in the mold or from the local decoration 2. This method allows the insertion of several decorations by realization successive operations. The medallions 3 are then cut at their periphery and the decoration 1 removed to reveal the decoration 2.
- FIG. 2 represents another embodiment of the invention, intended for relatively simple parts, in which, as in the case of FIG. 1, a decoration 2 is inserted locally.
- the mold comprises a first part or punch 21 and a die 20 inside which is mounted movable in translation at least one shim 8 in which a molding cavity 10 is formed.
- the wedges 8 being closed, the plastic material 7 is injected below the decoration 1 which is centered in the mold by a pecking system referenced 4. Then, after having moved the wedges 8, the part or medallion 3 is injected below the decoration 2, the injection of the material 3 making a chemical connection with the part 7.
- phase I consists of injecting a peripheral part 7 under low pressure and sequentially as described in the aforementioned patent. This injection is carried out from the punch 21 below the decoration 1 and outside the movable wedge 8. The excess part of the decoration 2 is thus included in the lower part of the thermoplastic part 7.
- phase II of the process (represented on the right-hand side of FIG. 2), the shim 8 rises inside the matrix 20 which frees up a space of thickness determined by the height of displacement of the shim 8.
- a second injection is then carried out, below the decoration 2, this second injection pressing the decoration 2 against the cavity 10 formed in the wedge 8.
- the plastic material injected during this second injection can be of the same nature as the material introduced into the mold during the first injection. But it can also be different provided that it is chemically compatible with the first material.
- the thermoplastic material passes through the decoration by capillary action and the integration of parts 3 and 7 is obtained by chemical bonding between the two plastic parts in zone 6.
- FIG. 3 is a diagram showing in perspective a thermoplastic part obtained according to the method of the invention and, in the example shown, this part constitutes the internal wall of a motor vehicle door. It comprises a panel A, an upper medallion forming an armrest B and a lower medallion C.
- the panel is coated with a decoration 1 and the armrest B with medallion and the medallion C are coated with a second decor 2 with or without foam under the decor.
- the method according to the invention thus makes it possible to carry out additional finishes enriching the product.
- the final part has a general decor embellished with one or more localized decorations which can be integrated into functional parts such as an armrest in the example shown.
- the present invention achieves this result in one or two steps.
- the medallions or glasses 3 are firstly formed by injection according to a conventional process.
- the local decoration is placed in a first mold (not shown) with or without a layer of padding or “soft” and the medallion is preferably molded by low pressure injection as indicated in the aforementioned French patent which allows spare the decor.
- the medallion (s) are then transferred manually or by an automaton to the male part or punch 21 of a second mold which is schematically represented in FIG. 4, in which an overmolding is carried out.
- Each medallion is held very precisely by small plastic centralizers 4 protruding from the rear of the medallion, formed during the first step of the process, these centralizers coming to be housed in housings (not shown) made in the mold.
- these centralizers coming to be housed in housings (not shown) made in the mold.
- several medallions can thus be mounted on the punch and, in the example shown, two medallions B and C are thus integrated.
- the general decoration 1 of the panel is then deposited in the female part or matrix 20 of the mold, and positioned outside the molding cavity by small needles (not shown) which pierce it outside of the molding part and maintain it when closing the mold.
- the press is progressively locked and the general decor follows, by known tension systems (blank press), the shapes of the part by pressing against the reliefs of the core.
- a movable wedge 8 having an appropriate relief, which is hydraulically locked in the areas before the injection phase of the main panel area.
- the mold being made watertight, the plastic is injected onto the back of the decoration 1 and a chemical bond is obtained between the main part 7 and the inclusions 3.
- This injection is carried out at low pressure so as not to not alter the decor and, preferably, using a sequential injection.
- the part and its local decorations are semi-finished; the mold is opened and the part is ejected.
- the entire surface of the room is covered by the general decoration 1. It is therefore necessary to clear the surface of the medallions so that their local decoration 2 appears and to level the periphery.
- the medallion (s) 3 are produced in a single operation with the main panel 7.
- the local decor 2 is stretched on frames 17,18, the local decoration being plated with a certain elasticity by sliding on the core of the mold 21.
- the mold, including the two decorations is then closed and we proceed, firstly, to the injection of the medallions 3 behind the decoration 2
- the decorations 1 and 2 are thus placed inside the mold cavity.
- the injection continues until the injected material crosses the periphery of the decoration 2 at the level of the frames 17, 18.
- the sequential nozzles are then closed and the injection of the rest of the panel 7 begins using a second series of nozzles (not shown) until the panel and its medallions are completely formed
- Figure 5 shows in section a mold in which the method is implemented.
- a small frame 17 or 18 is provided which surrounds the location of the future medallion and frees up a space in which the localized decoration (s) 2 will be deposited.
- the frame 17.18 makes it possible to tension the local decoration 2 on the shape of the core which corresponds to the medallion to be produced.
- the general decoration 1 is deposited in the matrix 20 which is held there by needles (not shown) external to the molding zone. Then, the mold is closed and the movable wedge 8 which ensures the shape of the medallion is locked which seals its periphery and prevents the passage of plastic.
- the part 7 is injected with the exception of the medallions 3.
- Cavities 10 corresponding to the medallions B and C are formed in the wedges or cores 8, on the back of the decoration general 1.
- the movable wedge 8 is unlocked which is raised in the matrix to clear the space necessary for the injection of the medallion or parts or local areas of the part.
- the local areas are injected in cascade according to the teachings of the aforementioned French patent.
- the mold is opened and the part injected is ejected and coated with the two decorations 1 totally and 2 locally, the decor 1 covering the parts of pieces coated with decor 2. There is generally an excess of decor 1 at the periphery of the room. The excess decoration around the medallions is folded inwards and can remain as it is.
- the finish of the part is obtained by leveling the periphery of the part and by cutting the general decoration 1 opposite the medallions, as described above in the first embodiment in two stages.
- the part can also be finished as indicated in EP-A-636 464. It is also possible to inject in a first phase the medallions and, in a second phase the rest of the part.
- FIG. 6 represents, on an enlarged scale, the zone of the medallion C in the mold 20,21. This figure shows the frame 17 which appears in section at the periphery of the medallion zone C, the movable wedge 8 comprising the mold cavity 10.
- the dashed line 2a symbolizes the position of the frame after it has been released.
- FIG. 7 is a detailed view of the connection between a plastic medallion 3 and the panel 7. As it appears in the figure, part of the medallion 3 has passed through the decoration 2 to form a chemical connection between the parts 3 and 7.
- the decoration 1 is cut by a blade 15 whose movement in the direction of the medallion is synchronized with the opening of the mold. The decoration 1 is thus cut around the medallion (s) after polymerization of the last molded part 3 or 7.
- thermoplastic part coated with an integrated decoration which does not require rework for the overlapping inside the part.
- the connection between the different materials is perfectly sealed.
- the transfer of humidity by capillary action is suppressed whereas in the case of a traditional ply, the humidity can pass from the rear part of the part to the front face thereof.
- the decorations can be constituted as indicated above by textiles covered or not with synthetic foam, by carpet or by leather, leatherette or any other decoration. It is also possible by the method according to the invention to imitate padding.
- the general surface of the panel may have, for example a seed appearance.
- the combination of the different decors makes it possible, for example, to enrich an enriched car door panel and at a lower cost. Compared to conventional manufacturing processes, it provides rigidity, tightness and flexibility in manufacturing.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Adornments (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9714415A FR2771045B1 (fr) | 1997-11-18 | 1997-11-18 | Procede d'insertion de decors dans une piece thermoplastique |
FR9714415 | 1997-11-18 | ||
PCT/FR1998/002456 WO1999025535A1 (fr) | 1997-11-18 | 1998-11-18 | Procede d'insertion de decors dans une piece thermoplastique |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0954426A1 true EP0954426A1 (de) | 1999-11-10 |
Family
ID=9513475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98955682A Withdrawn EP0954426A1 (de) | 1997-11-18 | 1998-11-18 | Verfahren zum einfügen von dekorationen in einem thermoplastischen teil |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0954426A1 (de) |
JP (1) | JP2001508373A (de) |
BR (1) | BR9806779A (de) |
FR (1) | FR2771045B1 (de) |
WO (1) | WO1999025535A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE457221T1 (de) * | 2004-11-08 | 2010-02-15 | Georg Kaufmann Formenbau Ag | Verfahren zum hinterspritzen, hinterpressen oder quellflussprägen und entsprechendes formwerkzeug |
ATE495000T1 (de) * | 2007-09-10 | 2011-01-15 | Peguform Gmbh | Verfahren und vorrichtung zur herstellung von formteilen mit unterschiedlichen dekorbereichen |
EP2070681B1 (de) * | 2007-12-12 | 2011-03-02 | Peguform Gmbh | Verfahren und Vorrichtung zur Herstellung von Kunststoff-Formteilen mit unterschiedlichen Dekorbereichen insbesondere für Innenverkleidungen von Kraftfahrzeugen |
FR3020618B1 (fr) * | 2014-04-30 | 2016-05-27 | Faurecia Interieur Ind | Procede de fabrication d'un element de garnissage et ensemble de fabrication correspondant |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0618724B2 (ja) * | 1989-02-06 | 1994-03-16 | 河西工業株式会社 | 自動車用内装部品の製造方法 |
FR2708512B1 (fr) * | 1993-07-30 | 1995-10-06 | Eurostyle Sa | Procédé d'insertion délimitée d'un décor dans un support thermoplastique. |
FR2720320B1 (fr) * | 1994-05-26 | 1996-09-20 | Cera | Procédé d'inclusion d'un décor, notamment textile, dans une pièce en matière plastique. |
FR2730185B1 (fr) * | 1995-02-06 | 1997-03-14 | Plastic Omnium Cie | Procede de realisation de pieces composites en matiere plastique comportant un revetement de surface, moules pour sa mise en oeuvre et pieces composites ainsi obtenues |
FR2751582B1 (fr) * | 1996-07-26 | 1998-09-04 | Allibert Ind | Procede d'habillage d'une piece injectee par une feuille pincee lors du procede, et moule pour realiser la piece finie |
-
1997
- 1997-11-18 FR FR9714415A patent/FR2771045B1/fr not_active Expired - Fee Related
-
1998
- 1998-11-18 BR BR9806779-6A patent/BR9806779A/pt not_active Application Discontinuation
- 1998-11-18 JP JP52778899A patent/JP2001508373A/ja not_active Ceased
- 1998-11-18 WO PCT/FR1998/002456 patent/WO1999025535A1/fr not_active Application Discontinuation
- 1998-11-18 EP EP98955682A patent/EP0954426A1/de not_active Withdrawn
Non-Patent Citations (1)
Title |
---|
See references of WO9925535A1 * |
Also Published As
Publication number | Publication date |
---|---|
BR9806779A (pt) | 2000-05-16 |
FR2771045A1 (fr) | 1999-05-21 |
FR2771045B1 (fr) | 2000-07-13 |
WO1999025535A1 (fr) | 1999-05-27 |
JP2001508373A (ja) | 2001-06-26 |
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