EP0952485B1 - Farbphotographisches Element mit elementarem Silber und stickstoffhaltigem Heterozyclus in einer lichtunempfindlichen Schicht - Google Patents

Farbphotographisches Element mit elementarem Silber und stickstoffhaltigem Heterozyclus in einer lichtunempfindlichen Schicht Download PDF

Info

Publication number
EP0952485B1
EP0952485B1 EP99201571A EP99201571A EP0952485B1 EP 0952485 B1 EP0952485 B1 EP 0952485B1 EP 99201571 A EP99201571 A EP 99201571A EP 99201571 A EP99201571 A EP 99201571A EP 0952485 B1 EP0952485 B1 EP 0952485B1
Authority
EP
European Patent Office
Prior art keywords
silver
epo
layer
element according
nitrogen heterocycle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP99201571A
Other languages
English (en)
French (fr)
Other versions
EP0952485A1 (de
Inventor
Bernard A. C/O Eastman Kodak Company Clark
Jane Sarah c/o Eastman Kodak Company Boff
Phillip Arthur c/o Eastman Kodak Company Allway
Louis Elbert c/o Eastman Kodak Company Friedrich
Stephen Paul C/O Eastman Kodak Company Singer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of EP0952485A1 publication Critical patent/EP0952485A1/de
Application granted granted Critical
Publication of EP0952485B1 publication Critical patent/EP0952485B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392—Additives
    • G03C7/39208—Organic compounds
    • G03C7/3924—Heterocyclic
    • G03C7/39244—Heterocyclic the nucleus containing only nitrogen as hetero atoms
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G03C1/8255—Silver or silver compounds therefor
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392—Additives
    • G03C7/39208—Organic compounds
    • G03C7/3924—Heterocyclic
    • G03C7/39244—Heterocyclic the nucleus containing only nitrogen as hetero atoms
    • G03C7/39256—Heterocyclic the nucleus containing only nitrogen as hetero atoms three nitrogen atoms
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/34—Fog-inhibitors; Stabilisers; Agents inhibiting latent image regression
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/76—Photosensitive materials characterised by the base or auxiliary layers
    • G03C1/825—Photosensitive materials characterised by the base or auxiliary layers characterised by antireflection means or visible-light filtering means, e.g. antihalation
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C2200/00—Details
    • G03C2200/25—Filter layer
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C2200/00—Details
    • G03C2200/33—Heterocyclic
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/3029—Materials characterised by a specific arrangement of layers, e.g. unit layers, or layers having a specific function
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/305—Substances liberating photographically active agents, e.g. development-inhibiting releasing couplers
    • G03C7/30541—Substances liberating photographically active agents, e.g. development-inhibiting releasing couplers characterised by the released group
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392—Additives
    • G03C7/39208—Organic compounds
    • G03C7/39212—Carbocyclic
    • G03C7/39216—Carbocyclic with OH groups

Definitions

  • This invention relates to a color photographic element containing elemental silver and a certain nitrogen heterocycle compound in a non-light sensitive layer.
  • an object of silver halide-based color photographic materials to create an image of an object in an accurate manner, both in terms of color and image structure characteristics such as graininess and sharpness. It is well known that the perceived sharpness of photographic images can be degraded through halation effects; that is, the reflection and subsequent diffusion of light within the light capturing element; in particular, reflection from the support. It is well known to use antihalation layers between the support and the sensitized layers in films to reduce light reflection. To be effective, an antihalation layer contains materials that absorb light and prevent reflection. In general, it is highly desirable for the light absorbing materials to be totally removed from the film element (or otherwise made colorless) after development in order to avoid increased background density.
  • colloidal or finely divided elemental or metallic silver also referred to as 'grey' silver.
  • This type of silver metal is in a filamentary form and, in such form, absorbs light across the visible spectrum appearing grey or black. It is generally easily removed from the film element by the normal bleaching and fixing steps used to remove imaging silver from the element. This silver metal is not light sensitive and does not contribute to image formation.
  • T.H. James The Theory of the Photographic Process, 4 th Edition, p. 579, US 3,434,839, JP 09-067122A2 and Y.J. Zahng et al , Chin. Chem. Lett. 7 (7), 687-690(1996).
  • colloidal or finely divided elemental or metallic silver is as a blue light absorbing filter.
  • This form commonly referred to as Carey-Lea silver, differs from 'grey' silver by being spherical in form.
  • Carey-Lea silver differs from 'grey' silver by being spherical in form.
  • This material is generally located in a non-imaging layer (commonly referred to as a yellow filter layer) farther away from the exposing source than or "underneath" the blue light sensitive emulsion layer.
  • the function of this layer is to absorb any blue light not captured by the blue sensitized layers, thus avoiding undesired exposure by blue light of the underlying green and red sensitized emulsion layers, which retain some inherent sensitivity to blue light.
  • a problem associated with the use of elemental silver in both antihalation and yellow filter layers is an undesired increase in fog in nearby imaging layers.
  • silver ions are released and/or made soluble from the imaging layer. These silver ions can migrate to a non-light sensitive layer where the elemental silver is present.
  • the silver can serve as nuclei for the reduction of the migrating silver ions to silver metal with concurrent oxidation of developer to oxidized developer.
  • This process is called solution physical development (for references, see T.H. James, ibid., Chapter 13) and is non-imagewise.
  • the oxidized developer can diffuse out of the antihalation layer and back into the nearby imaging layer where it can react with the couplers present and form dye in a non-imagewise fashion. This process is often highly process sensitive and can lead to variations in Dmin during photofinishing.
  • elemental silver in non-imaging layers can absorb inhibitor fragments and other silver absorbing materials. This results in lower effective concentrations of the free species in the imaging layers. Restricted diffusion of such species through the layer containing the elemental silver can also occur.
  • Solution physical development can be promoted by materials that form soluble silver salts.
  • materials that release low molecular weight water solubilized thiols which are used as bleach accelerators, can increase the amount of solution physical development.
  • Couplers that release such thiols are known are bleach accelerator releasing couplers; for examples, see EP 193389, US 4,861,701; US 4,959,299; US 4,912,024; US 5,300,406 and US 5,358.828.
  • Substituted triazoles including 1,2,3-triazoles, 1,2,4-triazoles (including tetraazaindenes) and benzotriazoles, are commonly known in the art as inhibitor fragments and as antifoggants; for example, as in US 3,671,255.
  • As inhibitor fragments they are attached to a coupling moiety through a nitrogen atom and do not interact with silver until coupling occurs and the nitrogen atom is freed.
  • antifoggants these materials are added directly to silver emulsions before coating of the film or added directly to the developer solutions.
  • JP-60-29390 describes the use of ballasted benzotriazoles for use as inhibitor fragments attached to couplers to form Development Inhibitor Releasing Couplers (DIRs).
  • DIRs Development Inhibitor Releasing Couplers
  • U.S. Patent No. 5,508,154 describes the use of bicyclic heterocycles that contain a minimum of 4 nitrogen atoms as antifoggants in systems that contain inhibitor releasing couplers.
  • DE 1 95 07913 A1 describes the use of ballasted benzimidazoles to improve granularity particularly with certain pyrazolone image couplers.
  • EP 0 369 486 B I describes the use of various heterocyclic thiols with fine silver chloride emulsions to remove inhibiting species.
  • US 4,871,658 describes the use of tetrazoles with silver iodobromide emulsions to decrease fog. All of these materials are used for control of imaging silver halide emulsions in light sensitive layers and are not used in non-imaging layers.
  • a problem to be solved is to provide a photographic element containing a non-light sensitive layer containing elemental silver which has a reduced tendency to increase the Dmin of nearby light sensitive layers.
  • the invention provides a reduction in Dmin values of the imaging layers.
  • the photographic element of the present invention is generally as described in the Summary of the Invention. Typically, it relates to a light sensitive color photographic element with at least one red sensitive silver halide emulsion layer containing at least one non-diffusing cyan coupler, at least one green sensitive silver halide emulsion layer having at least one non-diffusing magenta coupler and at least one blue sensitive silver halide emulsion layer having at least one non-diffusing yellow coupler, and at least one non-light sensitive layer containing both a form of elemental silver metal and a nitrogen heterocycle in accordance with the invention.
  • An example of such a compound is represented by Formula I:
  • the bonds (shown as dotted lines) between the nitrogen and carbon atoms are single or double as necessary to complete the ring.
  • Any carbon atom that is present in the ring may have a hydrogen atom or other substitutent such as an alkyl group, a phenyl group, an ether group, a thioether group, a nitrogen group such as amino, aminocarbonyl or aminosulfonyl, an oxygen, a sulfoxide group, a sulfone group, a halide such a chloro or bromo, a cyano group, a nitro group, a carbonyl group such as keto, carboxylic acid, carboxylate ester or carbamoyl or such other substituent group as described generally hereafter.
  • a hydrogen atom or other substitutent such as an alkyl group, a phenyl group, an ether group, a thioether group, a nitrogen group such as amino, aminocarbonyl or aminosulfonyl, an oxygen, a sulfoxide group, a sulfone group, a halide such a chloro or
  • substitutents may be connected to others to form additional ring systems and benzo-, naptho- or hetero- rings may be annulated to the heterocyclic ring nucleus.
  • Triazole rings and diazole rings fused to one or more further azole rings are conveniently employed.
  • Some examples of the ring systems of Formula I of the invention are 1,2,3 triazoles, 1,2,4 triazoles, benzotriazoles, tetraazaindenes, pentaazaindenes, purines, tetrazoles and pyrazolotriazoles.
  • the materials of Formula I are not couplers and do not react with oxidized developer. Such reaction would adversely affect for example, image forming efficiency and color.
  • the oil/water partition coefficient can be calculated using the software program Medchem 3.54 to predict this value as ClogP (Calculated log partition coefficient).
  • Medchem version 3.54 is a software program produced by the Medicinal Chemistry Project, Pomona College, Pomona California. It is believed that, in order to obtain the desired reduction of Dmin and fog in nearby imaging layers, the water solubility cannot be so low that the material is unable to interact effectively with the silver surface. Thus, it is preferred that the overall ClogP of the heterocycles of Formula I are not greater than 10.5 and most preferred that the ClogP is not greater than 10.
  • the water solubility cannot be so high that the material can diffuse away from the layer containing the elemental silver into adjacent imaging layers thereby causing a loss in light sensitivity.
  • the ClogP of the heterocycle of Formula I be at least 4.5 or most preferably at least 5.5.
  • the molar ratio of the heterocycle of Formula I to silver should be at least 0.1 mmole to mole of silver and more preferably, at least 1.0 mmole but less than 100 mmole and, more preferably, less than 50 mmole.
  • heterocycles used in the invention are conveniently employed with the compounds typically used as scavengers for oxidized developer.
  • scavengers are described in Research Disclosure as described hereinafter and include, for example, phenolic and hydroquinone derivatives such as 2,4-di-t-octylhydroquinone.
  • the materials of the invention can be added to a solution containing silver before coating or be mixed with the silver just prior to or during coating. In either case, additional components like dyes, doctors, surfactants, hardeners and other materials that are typically present in such solutions may also be present at the same time.
  • the materials of the invention are not water soluble and cannot be added directly to the solution. They may be added directly if dissolved in an organic water miscible solution such as methanol, acetone or the like or more preferably as a dispersion.
  • a dispersion incorporates the material in a stable, finely divided state in a hydrophobic organic solvent that is stabilized by suitable surfactants and surface active agents usually in combination with a binder or matrix such as gelatin.
  • the dispersion may contain one or more permanent coupler solvens that dissolve the material and maintain it in a liquid state.
  • suitable permanent coupler solvents are tricresylphosphate, N,N-diethyllauramide, N,N'-dibutyllauramide, p-dodecylphenol, dibutylpthalate, di-n-butyl sebacate, N-n-butylacetanilide, 9-octadecen-1-ol, trioctylamine and 2-ethyl-hexylphosphate.
  • the dispersion may require an auxiliary coupler solvent to initially dissolve the component but is removed afterwards, usually either by evaporation or by washing with additional water.
  • auxiliary coupler solvents are ethyl acetate, cyclohexanone and 2-(2-butoxy-ethoxy)ethyl acetate.
  • the dispersion may also be stabilized by addition of polymeric materials to form stable latexes.
  • suitable polymers for this use generally contain water solubilizing groups or have regions of high hydrophilicity.
  • suitable dispersing agents or surfactants are Alkanol XC or saponin.
  • the materials of the invention may also be dispersed as an admixture with another component of the system such as a dye or a oxidized developer scavenger so that both are present in the same oil droplet.
  • a substituent group when a substituent group contains a substitutable hydrogen, it is intended to encompass not only the substituent's unsubstituted form, but also its form further substituted with any group or groups as herein mentioned, so long as the group does not destroy properties necessary for photographic utility.
  • a substituent group may be halogen or may be bonded to the remainder of the molecule by an atom of carbon, silicon, oxygen, nitrogen, phosphorous, or sulfur.
  • the substituent may be, for example, halogen, such as chlorine, bromine or fluorine; nitro; hydroxyl; cyano; carboxyl; or groups which may be further substituted, such as alkyl, including straight or branched chain or cyclic alkyl, such as methyl, trifluoromethyl, ethyl, t -butyl, 3-(2,4-di-t-pentylphenoxy) propyl, and tetradecyl; alkenyl, such as ethylene, 2-butene; alkoxy, such as methoxy, ethoxy, propoxy, butoxy, 2-methoxyethoxy, sec -butoxy, hexyloxy, 2-ethyl-hexyloxy, tetradecyloxy, 2-(2,4-di- t -pentylphenoxy)ethoxy, and 2-dodecyloxyethoxy; aryl such as phenyl, 4-t-butyl
  • substituents may themselves be further substituted one or more times with the described substituent groups.
  • the particular substituents used may be selected by those skilled in the art to attain the desired photographic properties for a specific application and can include, for example, hydrophobic groups, solubilizing groups, blocking groups, releasing or releasable groups, etc.
  • the above groups and substituents thereof may include those having up to 48 carbon atoms, typically 1 to 36 carbon atoms and usually less than 24 carbon atoms, but greater numbers are possible depending on the particular substituents selected.
  • the materials of the invention can be used in any of the ways and in any of the combinations known in the art. It is essential that the heterocyclic compounds used in the invention are incorporated in a non-sensitized layer on a support to form part of a photographic element.
  • ballast groups include substituted or unsubstituted alkyl or aryl groups containing 8 to 48 carbon atoms.
  • substituents on such groups include alkyl, aryl, alkoxy, aryloxy, alkylthio, hydroxy, halogen, alkoxycarbonyl, aryloxycarbonyl, carboxy, acyl, acyloxy, amino, anilino, carbonamido, carbamoyl, alkylsulfonyl, arylsulfonyl, sulfonamido, and sulfamoyl groups wherein the substituents typically contain 1 to 42 carbon atoms. Such substituents can also be further substituted.
  • the photographic elements can be single color elements or multicolor elements.
  • Multicolor elements contain image dye-forming units sensitive to each of the three primary regions of the spectrum.
  • Each unit can comprise a single emulsion layer or multiple emulsion layers sensitive to a given region of the spectrum.
  • the layers of the element, including the layers of the image-forming units, can be arranged in various orders as known in the art.
  • the emulsions sensitive to each of the three primary regions of the spectrum can be disposed as a single segmented layer.
  • a typical multicolor photographic element comprises a support bearing a cyan dye image-forming unit comprised of at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, and a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler.
  • the element can contain additional layers, such as filter layers, interlayers, overcoat layers and subbing layers.
  • the photographic element can be used in conjunction with an applied magnetic layer as described in Research Disclosure, November 1992, Item 34390 published by Kenneth Mason Publications, Ltd., Dudley Annex, 12a North Street, Emsworth, Hampshire P010 7DQ, ENGLAND, and as described in Hatsumi Kyoukai Koukai Gihou No. 94-6023, published March 15, 1994, available from the Japanese Patent Office.
  • inventive materials in a small format film, Research Disclosure, June 1994, Item 36230, provides suitable embodiments.
  • the silver halide emulsion containing elements employed in this invention can be either negative-working or positive-working as indicated by the type of processing instructions (i.e. color negative, reversal, or direct positive processing) provided with the element.
  • Suitable emulsions and their preparation as well as methods of chemical and spectral sensitization are described in Sections I through V.
  • Various additives such as UV dyes, brighteners, antifoggants, stabilizers, light absorbing and scattering materials, and physical property modifying addenda such as hardeners, coating aids, plasticizers, lubricants and matting agents are described, for example, in Sections II and VI through VIII. Color materials are described in Sections X through XIII.
  • Coupling-off groups are well known in the art. Such groups can determine the chemical equivalency of a coupler, i.e., whether it is a 2-equivalent or a 4-equivalent coupler, or modify the reactivity of the coupler. Such groups can advantageously affect the layer in which the coupler is coated, or other layers in the photographic recording material, by performing, after release from the coupler, functions such as dye formation, dye hue adjustment, development acceleration or inhibition, bleach acceleration or inhibition, electron transfer facilitation or color correction.
  • the presence of hydrogen at the coupling site provides a 4-equivalent coupler, and the presence of another coupling-off group usually provides a 2-equivalent coupler.
  • Representative classes of such coupling-off groups include, for example, chloro, alkoxy, aryloxy, hetero-oxy, sulfonyloxy, acyloxy, acyl, heterocyclyl, sulfonamido, mercaptotetrazole, benzothiazole, mercaptopropionic acid, phosphonyloxy, arylthio and arylazo.
  • Image dye-forming couplers may be included in the element such as couplers that form cyan dyes upon reaction with oxidized color developing agents which are described in such representative patents and publications as: “Farbkuppler-eine Literaturement,” published in Agfa Mitteilungen, Band III, pp. 156-175 (1961) as well as in U.S. Patent Nos.
  • Couplers that form magenta dyes upon reaction with oxidized color developing agent are described in such representative patents and publications as: “Farbkuppler-eine Literaturehold,” published in Agfa Mitteilungen, Band III, pp. 126-156 (1961) as well as U.S.
  • Couplers that form yellow dyes upon reaction with oxidized color developing agent are described in such representative patents and publications as: “Farbkuppler-eine Literaturement,” published in Agfa Mitteilungen; Band III; pp. 112-126(1961); as well as U.S.
  • Couplers that form colorless products upon reaction with oxidized color developing agent are described in such representative patents as: UK. 861,138; U.S. Pat. Nos. 3,632,345; 3,928,041; 3,958,993 and 3,961,959.
  • couplers are cyclic carbonyl containing compounds that form colorless products on reaction with an oxidized color developing agent.
  • Couplers that form black dyes upon reaction with oxidized color developing agent are described in such representative patents as U.S. Patent Nos. 1,939,231; 2,181,944; 2,333,106 and 4,126,461; German OLS No. 2,644,194 and German OLS No. 2,650,764.
  • couplers are resorcinols or m-aminophenols that form black or neutral products on reaction with oxidized color developing agent.
  • Couplers of this type are described, for example, in U.S. Patent Nos. 5,026,628, 5,151,343 and 5,234,800.
  • couplers any of which may contain known ballasts or coupling-off groups such as those described in U.S. Patent 4,301,235; U.S. Patent 4,853,319 and U.S. Patent 4,351,897.
  • the coupler may contain solubilizing groups such as described in U.S. Patent 4,482,629.
  • the coupler may also be used in association with "wrong" colored couplers (e.g. to adjust levels of interlayer correction) and, in color negative applications, with masking couplers such as those described in EP 213.490; Japanese Published Application 58-172,647; U.S. Patent Nos.
  • the invention materials may be used in association with materials that release Photographically Useful Groups (PUGS) that accelerate or otherwise modify the processing steps e.g. of bleaching or fixing to improve the quality of the image.
  • PGS Photographically Useful Groups
  • These bleach releasing materials may or may not be couplers as described in the background.
  • Bleach accelerator releasing couplers such as those described in EP 193,389; EP 301,477; U.S. 4,163,669; U.S. 4,865,956; and U.S. 4,923,784, may be useful.
  • Also contemplated is use of the compositions in association with nucleating agents, development accelerators or their precursors (UK Patent 2,097,140; UK. Patent 2,131,188); electron transfer agents (U.S. 4,859,578; U.S.
  • antifogging and anti color-mixing agents such as derivatives of hydroquinones, aminophenols, amines, gallic acid; catechol; ascorbic acid; hydrazides; sulfonamidophenols and non color-forming couplers.
  • the invention materials may also be used in combination with filter dye layers comprising colloidal silver sol or yellow, cyan, and/or magenta filter dyes, either as oil-in-water dispersions, latex dispersions or as solid particle dispersions. Additionally, they may be used with "smearing" couplers (e.g. as described in U.S. 4,366,237; EP 96,570; U.S. 4,420,556; and U.S. 4,543,323.) Also, the compositions may be blocked or coated in protected form as described, for example, in Japanese Application 61/258,249 or U.S. 5,019,492.
  • the invention materials may further be used in combination with image-modifying compounds that release PUGS such as "Developer Inhibitor-Releasing” compounds (DIRs).
  • DIRs useful in conjunction with the compositions of the invention are known in the art and examples are described in U.S. Patent Nos.
  • DIR Couplers for Color Photography
  • C.R. Barr J.R. Thirtle and P.W. Vittum in Photographic Science and Engineering, Vol. 13, p. 174 (1969).
  • the developer inhibitor-releasing (DIR) couplers include a coupler moiety and an inhibitor coupling-off moiety (IN).
  • the inhibitor-releasing couplers may be of the time-delayed type (DIAR couplers) which also include a timing moiety or chemical switch which produces a delayed release of inhibitor.
  • inhibitor moieties are: oxazoles, thiazoles, diazoles, triazoles, oxadiazoles, thiadiazoles, oxathiazoles, thiatriazoles, benzotriazoles, tetrazoles, benzimidazoles, indazoles, isoindazoles, mercaptotetrazoles, selenotetrazoles, mercaptobenzothiazoles, selenobenzothiazoles, mercaptobenzoxazoles, selenobenzoxazoles, mercaptobenzimidazoles, selenobenzimidazoles, benzodiazoles, mercaptooxazoles, mercaptothiadiazoles, mercaptothiazoles, mercaptotriazoles, mercaptooxadiazoles, mercaptodiazoles, mercaptooxathiazoles, telleurotetrazoles or benz
  • the inhibitor moiety or group is selected from the following formulae: wherein R I is selected from the group consisting of straight and branched alkyls of from 1 to about 8 carbon atoms, benzyl, phenyl, and alkoxy groups and such groups containing none, one or more than one such substituent; R II is selected from R I and -SR I ; R III is a straight or branched alkyl group of from 1 to about 5 carbon atoms and m is from 1 to 3; and R IV is selected from the group consisting of hydrogen, halogens and alkoxy, phenyl and carbonamido groups, -COOR V and -NHCOOR V , wherein R V is selected from substituted and unsubstituted alkyl and aryl groups.
  • the coupler moiety included in the developer inhibitor-releasing coupler forms an image dye corresponding to the layer in which it is located, it may also form a different color as one associated with a different film layer. It may also be useful that the coupler moiety included in the developer inhibitor-releasing coupler forms colorless products and/or products that wash out of the photographic material during processing (so-called "universal" couplers).
  • a compound such as a coupler may release a PUG directly upon reaction of the compound during processing, or indirectly through a timing or linking group.
  • a timing group produces the time-delayed release of the PUG such groups using an intramolecular nucleophilic substitution reaction (U.S. 4,248,962); groups utilizing an electron transfer reaction along a conjugated system (U.S. 4,409,323; 4,421,845; 4,861,701, Japanese Applications 57-188035; 58-98728; 58-209736; 58-209738); groups that function as a coupler or reducing agent after the coupler reaction (U.S. 4,438,193; U.S. 4,618,571) and groups that combine the features describe above.
  • an intramolecular nucleophilic substitution reaction U.S. 4,248,962
  • groups utilizing an electron transfer reaction along a conjugated system U.S. 4,409,323; 4,421,845; 4,861,701, Japanese Applications 57-188035; 58-987
  • timing group is of one of the formulae: wherein IN is the inhibitor moiety, Z is selected from the group consisting of nitro, cyano, alkylsulfonyl; sulfamoyl (-SO 2 NR 2 ); and sulfonamido (-NRSO 2 R) groups; n is 0 or 1; and R VI is selected from the group consisting of substituted and unsubstituted alkyl and phenyl groups.
  • the oxygen atom of each timing group is bonded to the coupling-off position of the respective coupler moiety of the DIAR.
  • the timing or linking groups may also function by electron transfer down an unconjugated chain.
  • Linking groups are known in the art under various names. Often they have been referred to as groups capable of utilizing a hemiacetal or iminoketal cleavage reaction or as groups capable of utilizing a cleavage reaction due to ester hydrolysis such as U.S. 4,546,073.
  • This electron transfer down an unconjugated chain typically results in a relatively fast decomposition and the production of carbon dioxide, formaldehyde or other low molecular weight by-products.
  • the groups are exemplified in EP 464,612, EP 523,451, U.S. 4,146,396, Japanese Kokai 60-249148 and 60-249149.
  • suitable developer inhibitor-releasing couplers that may be included in photographic light sensitive emulsion layer include, but are not limited to, the following:
  • tabular grain silver halide emulsions are those having two parallel major crystal faces and having an aspect ratio of at least 2.
  • the term "aspect ratio” is the ratio of the equivalent circular diameter (ECD) of a grain major face divided by its thickness (t).
  • t the thickness of a grain major face divided by its thickness
  • the average useful ECD of photographic emulsions can range up to about 10 micrometers, although in practice emulsion ECDs seldom exceed about 4 micrometers. Since both photographic speed and granularity increase with increasing ECDs, it is generally preferred to employ the smallest tabular grain ECDs compatible with achieving aim speed requirements.
  • Emulsion tabularity increases markedly with reductions in tabular grain thickness. It is generally preferred that aim tabular grain projected areas be satisfied by thin (t ⁇ 0.2 micrometer) tabular grains. To achieve the lowest levels of granularity it is preferred that aim tabular grain projected areas be satisfied with ultrathin (t ⁇ 0.07 micrometer) tabular grains. Tabular grain thicknesses typically range down to about 0.02 micrometer. However, still lower tabular grain thicknesses are contemplated. For example, Daubendiek et al U.S. Patent 4,672,027 reports a 3 mole percent iodide tabular grain silver bromoiodide emulsion having a grain thickness of 0.017 micrometer. Ultrathin tabular grain high chloride emulsions are disclosed by Maskasky U.S. 5,217,858.
  • tabular grains of less than the specified thickness account for at least 50 percent of the total grain projected area of the emulsion.
  • tabular grains satisfying the stated thickness criterion account for the highest conveniently attainable percentage of the total grain projected area of the emulsion.
  • tabular grains satisfying the stated thickness criteria above account for at least 70 percent of the total grain projected area.
  • tabular grains satisfying the thickness criteria above account for at least 90 percent of total grain projected area.
  • Suitable tabular grain emulsions can be selected from among a variety of conventional teachings, such as those of the following: Research Disclosure, Item 22534, January 1983, published by Kenneth Mason Publications, Ltd., Emsworth, Hampshire P010 7DD, England; U.S. Patent Nos.
  • tabular grain emulsions can lie in either ⁇ 111 ⁇ or ⁇ 100 ⁇ crystal planes.
  • the mean ECD of tabular grain emulsions rarely exceeds 10 micrometers and more typically is less than 5 micrometers.
  • tabular grain emulsions are high bromide ⁇ 111 ⁇ ⁇ tabular grain emulsions.
  • Such emulsions are illustrated by Kofron et al U.S. Patent 4,439,520, Wilgus et al U.S. Patent 4,434,226, Solberg et al U.S. Patent 4,433,048, Maskasky U.S. Patents 4,435,501, 4,463,087 and 4,173,320, Daubendiek et al U.S.
  • Patents 4,414,310 and 4,914,014 Sowinski et al U.S. Patent 4,656,122, Piggin et al U.S. Patents 5,061,616 and 5,061,609, Tsaur et al U.S. Patents 5,147,771, '772, '773, 5,171,659 and 5,252,453, Black et al 5,219,720 and 5,334,495, Delton U.S. Patents 5,310,644, 5,372,927 and 5,460,934, Wen U.S. Patent 5,470,698, Fenton et al U.S. Patent 5,476,760, Eshelman et al U.S. Patents 5,612,,175 and 5,614,359, and Irving et al U.S. Patent 5,667,954.
  • Ultrathin high bromide ⁇ 111 ⁇ tabular grain emulsions are illustrated by Daubendiek et al U.S. Patents 4,672,027, 4,693,964, 5,494,789, 5,503,971 and 5,576,168, Antoniades et al U.S. Patent 5,250,403, Olm et al U.S. Patent 5,503,970, Deaton et al U.S. Patent 5,582,965, and Maskasky U.S. Patent 5,667,955.
  • High chloride ⁇ 100 ⁇ tabular grain emulsions are illustrated by Maskasky U.S. Patents 5,264,337, 5,292,632, 5,275,930 and 5,399,477, House et al U.S. Patent 5,320,938, House et al U.S. Patent 5,314,798, Szajewski et al U.S. Patent 5,356,764, Chang et al U.S. Patents 5,413,904 and 5,663,041, Oyamada U.S. Patent 5,593,821, Yamashita et al U.S. Patents 5,641,620 and 5,652,088, Saitou et al U.S. Patent 5,652,089, and Oyamada et al U.S. Patent 5,665,530.
  • Ultrathin high chloride ⁇ 100 ⁇ tabular grain emulsions can be prepared by nucleation in the presence of iodide, following the teaching of House et al and Chang et al, cited above.
  • the emulsions can be surface-sensitive emulsions, i.e., emulsions that form latent images primarily on the surfaces of the silver halide grains, or the emulsions can form internal latent images predominantly in the interior of the silver halide grains.
  • the emulsions can be negative-working emulsions, such as surface-sensitive emulsions or unfogged internal latent image-forming emulsions, or direct-positive emulsions of the unfogged, internal latent image-forming type, which are positive-working when development is conducted with uniform light exposure or in the presence of a nucleating agent. Tabular grain emulsions of the latter type are illustrated by Evans et al. U.S. 4,504,570.
  • Photographic elements can be exposed to actinic radiation, typically in the visible region of the spectrum, to form a latent image and can then be processed to form a visible dye image.
  • Processing to form a visible dye image includes the step of contacting the element with a color developing agent to reduce developable silver halide and oxidize the color developing agent. Oxidized color developing agent in turn reacts with the coupler to yield a dye.
  • a color negative film is designed for image capture.
  • Speed the sensitivity of the element to low light conditions
  • Such elements are typically silver bromoiodide emulsions and may be processed, for example, in known color negative processes such as the Kodak C-41 process as described in The British Journal of Photography Annual of 1988, pages 191-198.
  • a color negative film element is to be subsequently employed to generate a viewable projection print as for a motion picture, a process such as the Kodak ECN-2 process described in the H-24 Manual available from Eastman Kodak Co. may be employed to provide the color negative image on a transparent support.
  • Color negative development times are typically 3' 15" or less and desirably 90 or even 60 seconds or less.
  • the photographic element of the invention can be incorporated into exposure structures intended for repeated use or exposure structures intended for limited use, variously referred to by names such as “single use cameras”, “lens with film” or “photosensitive material package units”.
  • a reversal element is capable of forming a positive image without optical printing.
  • the color development step is preceded by development with a non-chromogenic developing agent to develop exposed silver halide, but not form dye, and followed by uniformly fogging the element to render unexposed silver halide developable.
  • a non-chromogenic developing agent to develop exposed silver halide, but not form dye
  • uniformly fogging the element to render unexposed silver halide developable Such reversal emulsions are typically sold with instructions to process using a color reversal process such as the Kodak E-6 process.
  • a direct positive emulsion can be employed to obtain a positive image.
  • the above emulsions are typically sold with instructions to process using the appropriate method such as the mentioned color negative (Kodak C-41) or reversal (Kodak E-6) process.
  • Preferred color developing agents are p -phenylenediamines such as:
  • Development is usually followed by the conventional steps of bleaching, fixing, or bleach-fixing, to remove silver or silver halide, washing, and drying.
  • the aqueous mixture was extracted with ethyl acetate (200ml) and the extract dried over magnesium sulphate and concentrated under reduced pressure to give a gum.
  • a solution of potassium hydroxide (2.8g, 50mmol) in methanol (20ml) was added to a stirred solution of the gum dissolved in methanol (150ml). After stirring at room temperature for 0.25 hour, the solution was poured into 3N hydrochloric acid (300ml). The aqueous solution was extracted with ethyl acetate (2 x 150ml) and the extract dried over magnesium sulphate and concentrated under reduced pressure.
  • the crude material was purified by column chromatography eluting with 1:9 60-80 petroleum ether : ethyl acetate to give a glass.
  • the glass was crystallized from ethyl acetate (100ml) / 60-80 petroleum ether (20ml) to give a pale pink solid, 14.2g (63%).
  • Bilayer photographic elements were prepared by coating the following layers on a cellulose triacetate film support (coverages are in g/m 2 ). Unless otherwise noted, all comparative and inventive compounds were dispersed in twice their own weight of N,N-dibutyllauramide:
  • Sample BL-2 shows the effect of adding a hydroquinone scavenger for oxidized developer to the antihalation layer, a common method for removing unwanted oxidized developer.
  • this alternative is not as effective at lowering red Dmin as are the compounds of the invention.
  • BL-3 demonstrates that the ClogP must be sufficiently high to prevent wandering of the heterocycle into imaging layers and causing losses in light sensitivity.
  • This sample achieves reducion in Dmin but exhibits an undesired reduction in Relative Red Sensitivity at the same time.
  • Samples BL-4 to BL-8 show that the compounds of the invention are useful for controlling the Dmin of adjacent layers without significantly affecting their light sensitivity.
  • Samples BL-5 and BL-8 show that the combination of the inventive materials with an oxidized developer scavenger is even more effective.
  • the invention can be further illustrated in the following multilayer experiments.
  • Component laydowns are provided in units of gm/m 2 .
  • Bislvinylsulfonyl)methane hardener was added at 1.55% of total gelatin weight.
  • Antifoggants including 4-hydroxy-6-methyl- 1,3,3a,7-tetraazaindene
  • surfactants including 4-hydroxy-6-methyl- 1,3,3a,7-tetraazaindene
  • coating aids including 4-hydroxy-6-methyl- 1,3,3a,7-tetraazaindene
  • coupler solvents including 2-hydroxy-6-methyl- 1,3,3a,7-tetraazaindene
  • emulsion addenda emulsion addenda
  • sequestrants lubricants
  • matte and tinting dyes were added to the appropriate layers as is common in the art.
  • the structures of the additional compounds used in the multilayer examples are as follows.
  • Multilayer examples ML-1 to 8 which all employ the same basic formula with variations in the AHU with and without an interlayer are summarized in Table III. Samples of each element were given a stepped exposure and processed in the KODAK FLEXICOLOR (C-41) process as described in British Journal of Photography Annual, 1988, pp 196-198.
  • Variability of Dmin within a multilayer film is very undesirable. While addition of an interlayer (layer E) between the AHU and imaging layers does decrease red Dmin, it requires an undesirable increase in film thickness as well as an additional layer. As demonstrated by examples ML-2 and ML-3, black colloidal silver (BCS) in the AHU Layer plays a significant role in causing increased red Dmin. Comparison of examples ML-2 and ML-4 shown that red Dmin is further increased when a bleach accelerating releasing coupler (C-3) is present. The addition of the inventive materials like H-A to the AHU layer containing black colloidal silver gave low red Dmin even when the protective interlayer was omitted (Examples ML-6 and ML-4).
  • Multilayer Example ML-8 relative to ML-5 shows that compounds like ILS-1 in combination with H-A further improves control of red Dmin.
  • Multilayer examples ML-9 to ML-13 (with layer E present and with 0.15 black collodial silver in layer F) were prepared, exposed and processed as above to demonstrate the utility of the inventive compounds to reduce increases in Dmin caused by the use of yellow collodial silver (Carey-Lea silver) in the yellow filter layer (YFL). Results are shown in Table IV.
  • Multilayer Formulation Variations in YFL and Blue or Green Dmins Example Comp/Inv Layer C (YFL) Blue Dmin Green Dmin ML-9 Comp YFD-1 0.723 0.608 ML-10 Comp CLS (0.065) 0.813 0.650 ML-11 Comp CLS (0.065) 0.872 0.651 ML-12 Inv CLS (0.065) + H-A (0.024) 0.739 0.622 ML-12 Inv CLS (0.0.65) + H-A (0.024) 0.799 0.616
  • the element of the invention results not only in lower Dmin and fog in adjacent imaging layers but also causes reduced processing variability in the trade.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)

Claims (10)

  1. Farbfotografisches Element mit einer nicht lichtempfindlichen Schicht, die elementares Silber und eine heterozyklische Stickstoffverbindung mit einem mittels der Medchem 3.54 Software berechneten Öl-/Wasser-Teilungskoeffizienten ClogP von mindestens 4,5 aufweist, wobei die Verbindung ein Ringsystem aus einem oder mehreren kondensierten Ringen umfasst, die mindestens eine -N-H Bindung beinhaltet, und das Ringsystem insgesamt mindestens drei Stickstoff-Ringelemente und die zugehörigen Bindungen umfasst; unter der Voraussetzung, dass die Verbindung keine -SH Gruppe oder >C=S Gruppe enthält und nicht mit einem oxidierten Entwickler reagiert.
  2. Farbfotografisches Element nach Anspruch 1, dadurch gekennzeichnet, dass die heterozyklische Stickstoffverbindung ein Benzotriazol ist.
  3. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, dadurch gekennzeichnet, dass der ClogP der heterozyklischen Stickstoffverbindung mindestens 5,5 beträgt.
  4. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, dadurch gekennzeichnet, dass das elementare Silber ein kolloidales Silber und farbneutral ist.
  5. Farbfotografisches Element nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass das elementare Silber ein kolloidales Silber und gelbfarbig ist.
  6. Farbfotografisches Element nach Anspruch 1, dadurch gekennzeichnet, dass die heterozyklische Stickstoffverbindung aus der Gruppe ausgewählt ist, die folgendes umfasst:
    Figure 00430001
    Figure 00430002
    Figure 00430003
    Figure 00430004
    Figure 00430005
    Figure 00440001
    Figure 00440002
    Figure 00440003
    Figure 00440004
    Figure 00440005
    Figure 00440006
  7. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, dadurch gekennzeichnet, dass die heterozyklische Stickstoffverbindung aus der Klasse ausgewählt ist, die folgendes umfasst:
    Figure 00450001
    Figure 00450002
    Figure 00450003
  8. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, dadurch gekennzeichnet, dass die die heterozyklische Stickstoffverbindung enthaltende Schicht zudem ein Zwischenschicht-Maskiermittel umfasst.
  9. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, dadurch gekennzeichnet, dass die heterozyklische Stickstoffverbindung in einem hydrophoben organischen Medium dispergiert ist.
  10. Farbfotografisches Element nach einem der vorausgehenden Ansprüche, das zusätzlich mindestens ein Bleichbeschleuniger-Freisetzungsmaterial enthält.
EP99201571A 1998-01-29 1999-01-18 Farbphotographisches Element mit elementarem Silber und stickstoffhaltigem Heterozyclus in einer lichtunempfindlichen Schicht Expired - Lifetime EP0952485B1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US1485598A 1998-01-29 1998-01-29
US14855 1998-01-29
US18684498A 1998-11-05 1998-11-05
US186844 1998-11-05
EP99200145 1999-01-18

Related Parent Applications (2)

Application Number Title Priority Date Filing Date
EP99200145 Division 1998-01-29 1999-01-18
EP99200145.3 Division 1999-01-18

Publications (2)

Publication Number Publication Date
EP0952485A1 EP0952485A1 (de) 1999-10-27
EP0952485B1 true EP0952485B1 (de) 2003-10-08

Family

ID=27240064

Family Applications (1)

Application Number Title Priority Date Filing Date
EP99201571A Expired - Lifetime EP0952485B1 (de) 1998-01-29 1999-01-18 Farbphotographisches Element mit elementarem Silber und stickstoffhaltigem Heterozyclus in einer lichtunempfindlichen Schicht

Country Status (1)

Country Link
EP (1) EP0952485B1 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6319660B1 (en) * 1998-12-28 2001-11-20 Eastman Kodak Company Color photographic element containing speed improving compound
US6190848B1 (en) * 1999-07-21 2001-02-20 Eastman Kodak Company Color photographic element containing ballasted triazole derivative and inhibitor releasing coupler
EP1160620A3 (de) * 2000-05-22 2008-11-12 Eastman Kodak Company Ein Antischleiermittel enthaltendes photographisches Element
US6350564B1 (en) * 2000-10-17 2002-02-26 Eastman Kodak Company Color photographic element containing speed improving compound in combination with reflecting material

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6029390B2 (ja) * 1976-02-03 1985-07-10 富士写真フイルム株式会社 ベンゾトリアゾ−ル化合物
JPS6029391B2 (ja) * 1976-02-04 1985-07-10 富士写真フイルム株式会社 ベンゾトリアゾ−ル化合物
US5246823A (en) * 1991-05-14 1993-09-21 Eastman Kodak Company Photographic element having improved antihalation layer containing tabular silver grains
US5508154A (en) * 1993-12-15 1996-04-16 Fuji Photo Film Co., Ltd. Silver halide photographic light-sensitive material, developer, and image-forming process

Also Published As

Publication number Publication date
EP0952485A1 (de) 1999-10-27

Similar Documents

Publication Publication Date Title
US6455242B1 (en) Color photographic element containing speed improving compound
US6350564B1 (en) Color photographic element containing speed improving compound in combination with reflecting material
US6426180B1 (en) Color photographic element containing speed improving compound in combination with electron transfer agent releasing compound
US7629112B1 (en) Color photographic materials with yellow minimum density colorants
US6054257A (en) Photographic element containing particular coupler and inhibitor releasing coupler
US6190848B1 (en) Color photographic element containing ballasted triazole derivative and inhibitor releasing coupler
US6197488B1 (en) Color photographic element containing a coupler releasing derivative with at least three heteroatoms with specific hydrophobicity
US6043013A (en) Color photographic element containing elemental silver and heterocyclic thiol in a non-light sensitive layer
US7632632B1 (en) Color photographic materials with magenta minimum density dyes
US6140029A (en) Color photographic element containing elemental silver and nitrogen heterocycle in a non-light sensitive layer
US7175975B2 (en) Photographic material with improved development inhibitor releases
EP0952485B1 (de) Farbphotographisches Element mit elementarem Silber und stickstoffhaltigem Heterozyclus in einer lichtunempfindlichen Schicht
US6190849B1 (en) Photographic element containing ballasted tetrazole derivative and inhibitor releasing coupler
EP1070987B1 (de) Farbphotographisches Element, das ein N-heterocyclisches Derivat und einen Entwicklungsinhibitor freisetzenden Kuppler enthält
US6416943B1 (en) Color photographic element containing coupler useful for forming neutral silver-based image
US6887656B2 (en) Color photographic element containing improved heterocyclic speed enhancing compound
US20090234131A1 (en) Infrared dye for silver halide-based photographic elements
US6228572B1 (en) Color photographic element containing ballasted mercaptodiazole derivative and inhibitor releasing coupler
US5532117A (en) Photographic element containing certain azoaniline dyes
EP1016916A1 (de) Kuppler hoher Farbausbeute enthaltendes photographisches Element
US6458521B1 (en) Color photographic element containing coupler useful for forming neutral silver-based image
US6780573B1 (en) Color photographic element containing coupler moiety with improved amino acid timing group
GB2306688A (en) Photographic films with methine dyes
EP1160620A2 (de) Ein Antischleiermittel enthaltendes photographisches Element
EP1215534A1 (de) Photographische Schichten mit verringerter Schleierbildung, die einen monosubstituierten Chinon enthalten

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): DE FR GB

17P Request for examination filed

Effective date: 20000329

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

RBV Designated contracting states (corrected)

Designated state(s): DE GB

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE GB

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 69911836

Country of ref document: DE

Date of ref document: 20031113

Kind code of ref document: P

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20040709

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20041210

Year of fee payment: 7

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20050131

Year of fee payment: 7

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060118

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF THE APPLICANT RENOUNCES

Effective date: 20060221

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20060118