EP0911420A1 - Aluminium casting alloy - Google Patents

Aluminium casting alloy Download PDF

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Publication number
EP0911420A1
EP0911420A1 EP98810210A EP98810210A EP0911420A1 EP 0911420 A1 EP0911420 A1 EP 0911420A1 EP 98810210 A EP98810210 A EP 98810210A EP 98810210 A EP98810210 A EP 98810210A EP 0911420 A1 EP0911420 A1 EP 0911420A1
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max
weight
alloy
cast
manganese
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EP98810210A
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German (de)
French (fr)
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EP0911420B1 (en
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Hubert Koch
Horst Schramm
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Aluminium Rheinfelden GmbH
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Aluminium Rheinfelden GmbH
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Priority claimed from EP97810756A external-priority patent/EP0908527A1/en
Application filed by Aluminium Rheinfelden GmbH filed Critical Aluminium Rheinfelden GmbH
Priority to EP98810210A priority Critical patent/EP0911420B1/en
Priority to US09/163,822 priority patent/US6309481B1/en
Priority to CA002249762A priority patent/CA2249762A1/en
Priority to BR9803822-2A priority patent/BR9803822A/en
Publication of EP0911420A1 publication Critical patent/EP0911420A1/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon

Definitions

  • the invention relates to an aluminum casting alloy, in particular an aluminum die casting alloy.
  • Die casting technology has developed so far today that it is possible to cast pieces to manufacture with high quality requirements.
  • the quality of a die casting depends not only on the machine setting and the chosen method, but also to a large extent on the chemical composition and structure the cast alloy used. These two latter parameters are known to influence the pourability, the feeding behavior (G. Schindelbauer, J. Czikel “Mold filling capacity and volume deficit of common aluminum die casting alloys” Foundry Research 42, 1990, pp. 88/89), the mechanical Properties and - particularly important in die casting - the service life the casting tools (L.A. Norström, B. Klarenfjord, M. Svenson "General Aspects on Wash-out Mechanism in Aluminum Diecasting Dies ", 17th International NADCA Diecasting Congress 1993, Cleveland OH).
  • AIMg alloys are also known which are distinguished by a high ductility. Such an alloy is disclosed, for example, in US-A-5 573 606. However, these alloys have the disadvantage of high mold wear and cause molding problems, which significantly reduces productivity.
  • the present invention is therefore based on the object of creating a die-casting alloy with a high elongation at break with an acceptable yield strength, which has good castability and sticks as little as possible in the mold.
  • the following minimum values must be achieved in the as-cast state: Elongation (A5): 14% proof stress (Rp 0.2): 100 MPa
  • the alloy should also be easy to weld, a high corrosion resistance and in particular show no susceptibility to stress corrosion cracking.
  • the degree of purity of the aluminum corresponds to the quality of a casing aluminum Al 99.8 H.
  • This alloy has a well molded ⁇ phase in the as-cast state.
  • the eutectic mainly consisting of Mg 2 Si and Al 6 Mn phases, is very fine and therefore leads to a highly ductile fracture behavior.
  • the manganese content prevents sticking in the mold and ensures good mold release.
  • the magnesium content in combination with manganese gives the casting a high level of design stability, so that very little or no distortion can be expected even when demoulded.
  • this alloy can also be used for Use thixocasting or thixo forging.
  • the ⁇ phase forms when it melts again immediately, so that excellent thixotropic properties are available.
  • the following content ranges are preferred for the individual alloy elements: magnesium 2.5 to 3.3% by weight, in particular 2.6 to 3.3% by weight Silicon 0.20 to 0.30% by weight manganese 0.40 to 1.2% by weight, in particular 0.50 to 1.0% by weight iron Max. 0.30% by weight, in particular max. 0.15% by weight
  • the tendency of the casting to stick in the mold can be drastically reduced and the forming behavior can be significantly improved if manganese partially through Cobalt and / or cerium is replaced.
  • the alloy therefore preferably contains 0.10 to 0.60 % By weight, in particular 0.30 to 0.60% by weight of cobalt and / or 0.05 to 0.80% by weight, in particular up to 0.50% by weight of cerium.
  • An optimal effect is achieved if the sum of the cobalt, cerium and manganese contents in the alloy at least Is 0.80% by weight and the alloy contains at least 0.50% by weight of manganese.
  • the aluminum casting alloy according to the invention is particularly suitable for this Thixocasting or thixo forging.
  • alloy is easy to weld, shows excellent casting behavior, a practically negligible tendency to stick and can be shaped well.

Abstract

An aluminum casting (especially die casting) alloy has composition (by wt.): 2.0-3.5 % Mg, 0.15-0.35 % Si, 0.20-1.2 % Mn, NOTGREATER 0.40 % Fe, NOTGREATER 0.10 % Cu, NOTGREATER 0.05 % Cr, NOTGREATER 0.10 % Zn, NOTGREATER 0.003 % Be, NOTGREATER 0.20 % Ti, NOTGREATER 0.60 % Co, NOTGREATER 0.80 % Ce, balance Al and NOTGREATER 0.2 % total ( NOTGREATER 0.02 % each) of impurities.

Description

Die Erfindung betrifft eine Aluminium-Gusslegierung, insbesondere eine Aluminium-Druckgusslegierung.The invention relates to an aluminum casting alloy, in particular an aluminum die casting alloy.

Die Druckgusstechnik hat sich heute soweit entwickelt, dass es möglich ist, Gussstükke mit hohen Qualitätsansprüchen herzustellen. Die Qualität eines Druckgussstückes hängt aber nicht nur von der Maschineneinstellung und dem gewählten Verfahren ab, sondern in hohem Masse auch von der chemischen Zusammensetzung und der Gefügestruktur der verwendeten Gusslegierung. Diese beiden letztgenannten Parameter beeinflussen bekanntermassen die Giessbarkeit, das Speisungsverhalten (G. Schindelbauer, J. Czikel "Formfüllungsvermögen und Volumendefizit gebräuchlicher Aluminiumdruckgusslegierungen" Giessereiforschung 42, 1990, S. 88/89), die mechanischen Eigenschaften und -- im Druckguss ganz besonders wichtig -- die Lebensdauer der Giesswerkzeuge (L.A. Norström, B. Klarenfjord, M. Svenson "General Aspects on Wash-out Mechanism in Aluminium Diecasting Dies", 17. International NADCA Diecastingcongress 1993, Cleveland OH).Die casting technology has developed so far today that it is possible to cast pieces to manufacture with high quality requirements. The quality of a die casting depends not only on the machine setting and the chosen method, but also to a large extent on the chemical composition and structure the cast alloy used. These two latter parameters are known to influence the pourability, the feeding behavior (G. Schindelbauer, J. Czikel "Mold filling capacity and volume deficit of common aluminum die casting alloys" Foundry Research 42, 1990, pp. 88/89), the mechanical Properties and - particularly important in die casting - the service life the casting tools (L.A. Norström, B. Klarenfjord, M. Svenson "General Aspects on Wash-out Mechanism in Aluminum Diecasting Dies ", 17th International NADCA Diecasting Congress 1993, Cleveland OH).

In der Vergangenheit wurde der Entwicklung von speziell für den Druckguss anspruchsvoller Gussstücke geeigneten Legierungen wenig Aufmerksamkeit geschenkt. Die meisten Anstrengungen wurden auf die Weiterentwicklung der Verfahrenstechnik des Druckgussprozesses verwendet. Gerade von Konstrukteuren der Automobilindustrie wird aber immer mehr gefordert, schweissbare Bauteile mit hoher Duktilität im Druckguss zu realisieren, da bei hohen Stückzahlen der Druckguss die kostengünstigste Produktionsmethode darstellt.In the past, the development of especially for die casting became more demanding Little attention was paid to castings of suitable alloys. Most efforts have been made on the further development of process engineering of the die casting process. Especially by designers in the automotive industry But there is an increasing demand for weldable components with high ductility in the To realize die casting, because with large quantities the die casting is the cheapest Represents production method.

Durch die Weiterentwicklung der Druckgusstechnik ist es heute möglich, schweissbare und wärmebehandelbare Gussstücke von hoher Qualität herzustellen. Dies hat den Anwendungsbereich für Druckgussteile auf sicherheitsrelevante Komponenten erweitert. Für derartige Komponenten werden heute üblicherweise AlSiMg-Legierungen eingesetzt, da diese eine gute Giessbarkeit bei geringem Formenverschleiss aufweisen. Damit die geforderten mechanischen Eigenschaften, insbesondere eine hohe Bruchdehnung, erreicht werden können, müssen die Gussteile einer Wärmebehandlung unterzogen werden. Diese Wärmebehandlung ist zur Einformung der Gussphasen und damit zur Erzielung eines zähen Bruchverhaltens notwendig. Eine Wärmebehandlung bedeutet in der Regel eine Lösungsglühung bei Temperaturen knapp unterhalb der Solidustemperatur mit nachfolgendem Abschrecken in Wasser oder einem anderen Medium auf Temperaturen <100°C. Der so behandelte Werkstoff weist nun eine geringe Dehngrenze und Zugfestigkeit auf. Um diese Eigenschaften auf den gewünschten Wert zu heben, wird anschliessend eine Warmauslagerung durchgeführt. Diese kann auch prozessbedingt erfolgen, z.B. durch eine thermische Beaufschlagung beim Lackieren oder durch das Entspannungsglühen einer ganzen Bauteilgruppe.Due to the further development of die casting technology, it is now possible to weld and manufacture heat-treatable castings of high quality. This has the Application area for die-cast parts extended to safety-relevant components. AlSiMg alloys are usually used for such components today used because they have good castability with little mold wear. So that the required mechanical properties, especially a high one Elongation at break, the castings must be heat treated be subjected. This heat treatment is for molding the casting phases and therefore necessary to achieve tough fracture behavior. A heat treatment usually means solution annealing at temperatures scarce below the solidus temperature with subsequent quenching in water or another medium at temperatures <100 ° C. The material treated in this way now has a low yield strength and tensile strength. To these properties Warming up to the desired value then becomes a hot aging process carried out. This can also be done depending on the process, e.g. through a thermal Applying when painting or by relaxing an entire Component group.

Da Druckgussstücke endabmessungsnah gegossen werden, haben sie meist eine komplizierte Geometrie mit dünnen Wandstärken. Während des Lösungsglühens und besonders beim Abschreckprozess muss mit Verzug gerechnet werden, der eine Nacharbeit z.B. durch Richten der Gussstücke oder im schlimmsten Fall Ausschuss nach sich ziehen kann. Die Lösungsglühung verursacht zudem zusätzliche Kosten und die Wirtschaftlichkeit dieser Produktionsmethode könnte wesentlich erhöht werden, wenn Legierungen zur Verfügung stehen würden, die die geforderten Eigenschaften ohne eine Wärmebehandlung erfüllen.Since die castings are cast close to their final dimensions, they usually have one complicated geometry with thin walls. During solution annealing and Especially in the quenching process, delays must be expected Rework e.g. by straightening the castings or, in the worst case, rejects can entail. Solution annealing also causes additional costs and the economy of this method of production could be increased significantly if alloys were available that would have the required properties meet without a heat treatment.

Es sind auch AIMg-Legierungen bekannt, die sich durch eine hohe Duktilität auszeichnen. Eine derartige Legierung ist beispielsweise in der US-A-5 573 606 offenbart. Diese Legierungen haben aber den Nachteil eines hohen Formenverschleisses und bringen Probleme beim Ausformen, was die Produktivität erheblich verringert.AIMg alloys are also known which are distinguished by a high ductility. Such an alloy is disclosed, for example, in US-A-5 573 606. However, these alloys have the disadvantage of high mold wear and cause molding problems, which significantly reduces productivity.

Der vorliegenden Erfindung liegt deshalb die Aufgabe zugrunde, eine Druckgusslegierung mit hoher Bruchdehnung bei noch akzeptabler Dehngrenze zu schaffen, die eine gute Giessbarkeit aufweist und in der Form möglichst wenig klebt. Die folgenden Minimalwerte müssen im Gusszustand erreicht werden:
Dehnung (A5): 14%    Dehngrenze (Rp 0.2): 100 MPa
The present invention is therefore based on the object of creating a die-casting alloy with a high elongation at break with an acceptable yield strength, which has good castability and sticks as little as possible in the mold. The following minimum values must be achieved in the as-cast state:
Elongation (A5): 14% proof stress (Rp 0.2): 100 MPa

Die Legierung soll zudem gut schweissbar sein, einen hohen Korrosionswiderstand aufweisen und insbesondere keine Anfälligkeit für Spannungsrisskorrosion zeigen.The alloy should also be easy to weld, a high corrosion resistance and in particular show no susceptibility to stress corrosion cracking.

Zur erfindungsgemässen Lösung führt, dass die Legierung aus

  • 2.0 bis 3.5 Gew.-% Magnesium
  • 0.15 bis 0.35 Gew.-% Silizium
  • 0.20 bis 1.2 Gew.-% Mangan
  • max. 0.40 Gew.-% Eisen
  • max. 0.10 Gew.-% Kupfer
  • max. 0.05 Gew.-% Chrom
  • max. 0.10 Gew.-% Zink
  • max. 0.003 Gew.-% Beryllium
  • max. 0.20 Gew.-% Titan
  • max. 0.60 Gew.-% Cobalt
  • max. 0.80 Gew.-% Cer
  • The solution according to the invention is that the alloy
  • 2.0 to 3.5% by weight of magnesium
  • 0.15 to 0.35% by weight of silicon
  • 0.20 to 1.2% by weight of manganese
  • Max. 0.40 wt% iron
  • Max. 0.10% by weight copper
  • Max. 0.05 wt% chromium
  • Max. 0.10% by weight zinc
  • Max. 0.003 wt% beryllium
  • Max. 0.20 wt% titanium
  • Max. 0.60% by weight cobalt
  • Max. 0.80% by weight of cerium
  • sowie Aluminium als Rest mit weiteren Verunreinigungen einzeln max. 0.02 Gew.-%, insgesamt max. 0.2 Gew.-%, besteht. Der zur Herstellung der Legierung verwendete Reinheitsgrad des Aluminiums entspricht einem Hüllen-Aluminium der Qualität Al 99.8 H.and aluminum as the rest with further impurities individually max. 0.02% by weight, total max. 0.2% by weight. The one used to make the alloy The degree of purity of the aluminum corresponds to the quality of a casing aluminum Al 99.8 H.

    Diese Legierung weist im Gusszustand eine gut eingeformte α-Phase auf. Das Eutektikum, überwiegend bestehend aus Mg2Si- und Al6Mn-Phasen, ist sehr fein ausgebildet und führt daher zu einem hochduktilen Bruchverhalten. Durch den Anteil an Mangan wird das Kleben in der Form vermieden und eine gute Entformbarkeit gewährleistet. Der Magnesiumgehalt in Verbindung mit Mangan gibt dem Gussstück eine hohe Gestaltsfestigkeit, so dass auch beim Entformen mit sehr geringem bis gar keinem Verzug zu rechnen ist.This alloy has a well molded α phase in the as-cast state. The eutectic, mainly consisting of Mg 2 Si and Al 6 Mn phases, is very fine and therefore leads to a highly ductile fracture behavior. The manganese content prevents sticking in the mold and ensures good mold release. The magnesium content in combination with manganese gives the casting a high level of design stability, so that very little or no distortion can be expected even when demoulded.

    Aufgrund der bereits eingeformten α-Phase lässt sich diese Legierung auch für das Thixocasting bzw. Thixoschmieden einsetzen. Die α-Phase formt sich beim Wiederaufschmelzen sofort ein, so dass hervorragende thixotrope Eigenschaften vorliegen. Due to the already molded α phase, this alloy can also be used for Use thixocasting or thixo forging. The α phase forms when it melts again immediately, so that excellent thixotropic properties are available.

    Bei den üblichen Aufheizgeschwindigkeiten wird eine Komgrösse von <100µm erzeugt.At the usual heating speeds, a grain size of <100 µm is generated.

    Zur Erzielung einer hohen Duktilität ist von wesentlicher Bedeutung, dass der Eisengehalt in der Legierung möglichst tief gehalten wird. Überraschenderweise hat sich gezeigt, dass die erfindungsgemässe Legierungszusammensetzung trotz geringem Eisengehalt nicht zum Kleben in der Form neigt. Entgegen der allgemeinen Ansicht, dass mit hohen Eisengehalten ein Kleben in der Form in jedem Fall verhindert werden kann, hat sich beim erfindungsgemäss vorgeschlagenen Legierungstyp herausgestellt, dass bei Erhöhung des Eisengehalts auf mehr als 0.4 Gew.-% bereits wieder eine Zunahme der Klebeneigung beobachtet wird.To achieve high ductility it is essential that the iron content is kept as deep as possible in the alloy. Surprisingly, has shown that the alloy composition according to the invention despite low Iron content does not tend to stick in the mold. Contrary to popular belief, that with high iron contents, sticking in the mold is prevented in any case has been found in the alloy type proposed according to the invention, that when the iron content is increased to more than 0.4% by weight again an increase in the tendency to stick is observed.

    Für die einzelnen Legierungselemente werden die folgenden Gehaltsbereiche bevorzugt: Magnesium 2.5 bis 3.3 Gew.-%, insbesondere 2.6 bis 3.3 Gew.-% Silizum 0.20 bis 0.30 Gew.-% Mangan 0.40 bis 1.2 Gew.-%, insbesondere 0.50 bis 1.0 Gew.-% Eisen max. 0.30 Gew.-%, insbesondere max. 0.15 Gew.-% The following content ranges are preferred for the individual alloy elements: magnesium 2.5 to 3.3% by weight, in particular 2.6 to 3.3% by weight Silicon 0.20 to 0.30% by weight manganese 0.40 to 1.2% by weight, in particular 0.50 to 1.0% by weight iron Max. 0.30% by weight, in particular max. 0.15% by weight

    Die Klebeneigung des Gussstücks in der Form kann weiter drastisch vermindert und das Ausformverhalten wesentlich verbessert werden, wenn Mangan teilweise durch Cobalt und/oder Cer ersetzt wird. Bevorzugt enthält die Legierung daher 0.10 bis 0.60 Gew.-%, insbesondere 0.30 bis 0.60 Gew.% Cobalt und/oder 0.05 bis 0.80 Gew.-%, insbesondere bis 0.50 Gew.-% Cer. Eine optimale Wirkung wird dann erreicht, wenn die Summe der Gehalte an Cobalt, Cer und Mangan in der Legierung mindestens 0.80 Gew.-% beträgt und die Legierung mindestens 0.50 Gew.-% Mangan enthält.The tendency of the casting to stick in the mold can be drastically reduced and the forming behavior can be significantly improved if manganese partially through Cobalt and / or cerium is replaced. The alloy therefore preferably contains 0.10 to 0.60 % By weight, in particular 0.30 to 0.60% by weight of cobalt and / or 0.05 to 0.80% by weight, in particular up to 0.50% by weight of cerium. An optimal effect is achieved if the sum of the cobalt, cerium and manganese contents in the alloy at least Is 0.80% by weight and the alloy contains at least 0.50% by weight of manganese.

    Die erfindungsgemässe Aluminium-Gusslegierung eignet sich besonders gut für das Thixocasting bzw. Thixoschmieden.The aluminum casting alloy according to the invention is particularly suitable for this Thixocasting or thixo forging.

    Obwohl die erfindungsgemässe Aluminium-Gusslegierung insbesondere zur Verarbeitung im Druckguss vorgesehen ist, kann sie selbstverständlich auch mit anderen Verfahren vergossen werden, z.B.

  • Sandguss
  • Schwerkraftkokillenguss
  • Niederdruckguss
  • Thixocasting/Thixoschmieden
  • Squeeze casting
  • Although the aluminum casting alloy according to the invention is intended in particular for processing in die casting, it can of course also be cast using other methods, for example
  • Sand casting
  • Gravity die casting
  • Low pressure casting
  • Thixocasting / thixo forging
  • Squeeze casting
  • Die grössten Vorteile ergeben sich jedoch bei Giessverfahren, die mit hohen Abkühlungsgeschwindigkeiten ablaufen, wie beispielsweise beim Druckgiessverfahren.The greatest advantages, however, are found in casting processes with high cooling rates run, such as in the die casting process.

    Weitere Vorteile, Merkmale und Einzelheiten der erfindungsgemässen Aluminium-Gusslegierung sowie deren hervorragende Eigenschaften ergeben sich aus der nachfolgenden Beschreibung bevorzugter Ausführungsbeispiele.Further advantages, features and details of the aluminum casting alloy according to the invention as well as their excellent properties result from the following description of preferred embodiments.

    BeispieleExamples

    Aus vier verschiedenen Legierungen wurde auf einer Druckguss-Maschine mit 400 t Schliesskraft jeweils ein Topf mit einer Wanddicke von 3 mm und den Abmessungen 120 x 120 x 60 mm gegossen. Aus den Seitenteilen wurden Probestäbe für Zugversuche herausgearbeitet und an diesen die mechanischen Eigenschaften im Gusszustand gemessen. Die Ergebnisse sind in der nachstehenden Tabelle zusammengefasst. Hierbei bedeuten Rp0.2 die Dehngrenze, Rm die Zugfestigkeit und A5 die Bruchdehnung. Bei den angegebenen Messwerten handelt es sich um Mittelwerte aus 10 Einzelmessungen. Die Legierungen wurden auf der Basis Hütten-Aluminium der Qualität Al 99.8H erschmolzen.Four different alloys were used on a die casting machine weighing 400 t Closing force in each case a pot with a wall thickness of 3 mm and the dimensions Cast 120 x 120 x 60 mm. Test pieces for tensile tests were made from the side parts worked out and on these the mechanical properties in the as-cast state measured. The results are summarized in the table below. Rp0.2 mean the yield strength, Rm the tensile strength and A5 the Elongation at break. The stated measured values are average values 10 single measurements. The alloys were based on the smelter aluminum Quality Al 99.8H melted.

    Die Versuche zeigen, dass mit der erfindungsgemässen Aluminium-Gusslegierung die bezüglich der Dehngrenze und der Bruchdehnung geforderten Minimalwerte im Gusszustand erreicht werden.The tests show that with the aluminum casting alloy according to the invention with regard to the yield strength and the elongation at break required minimum values in the as-cast state can be achieved.

    Die Legierung ist gut schweissbar, zeigt ein ausgezeichnetes Giessverhalten, eine praktisch vemachlässigbare Klebeneigung und lässt sich gut ausformen. Legierung 1 Legierung 2 Legierung 3 Legierung 4 Si [Gew.-%] 0.25 0.25 0.25 0.23 Fe [Gew.-%] 0.25 0.10 0.07 0.10 Mn [Gew.-%] 0.80 0.80 0.77 0.78 Mg [Gew.-%] 2.90 2.40 2.34 2.35 Ce [Gew.-%] - 0.40 0.20 - Co [Gew.-%] 0.30 - - - Rp0.2[N/mm2] 130 107 120 129 Rm [N/mm2] 250 219 205 218 A5 [%] 19.0 20.9 16.3 20.0 The alloy is easy to weld, shows excellent casting behavior, a practically negligible tendency to stick and can be shaped well. Alloy 1 Alloy 2 Alloy 3 Alloy 4 Si [% by weight] 0.25 0.25 0.25 0.23 Fe [% by weight] 0.25 0.10 0.07 0.10 Mn [% by weight] 0.80 0.80 0.77 0.78 Mg [% by weight] 2.90 2.40 2.34 2.35 Ce [% by weight] - 0.40 0.20 - Co [wt%] 0.30 - - - Rp0.2 [N / mm 2 ] 130 107 120 129 Rm [N / mm 2 ] 250 219 205 218 A5 [%] 19.0 20.9 16.3 20.0

    Claims (10)

    Aluminium-Gusslegierung, insbesondere Aluminium-Druckgusslegierung, dadurch gekennzeichnet, dass die Legierung aus 2.0 bis 3.5 Gew.-% Magnesium 0.15 bis 0.35 Gew.-% Silizium 0.20 bis 1.2 Gew.-% Mangan max. 0.40 Gew.-% Eisen max. 0.10 Gew.-% Kupfer max. 0.05 Gew.-% Chrom max. 0.10 Gew.-% Zink max. 0.003 Gew.-% Beryllium max. 0.20 Gew.-% Titan max. 0.60 Gew.-% Cobalt max. 0.80 Gew.-% Cer sowie Aluminium als Rest mit weiteren Verunreinigungen einzeln max. 0.02 Gew.-%, insgesamt max. 0.2 Gew.-%, besteht.Aluminum casting alloy, in particular aluminum die casting alloy, characterized in that the alloy is made of 2.0 to 3.5% by weight of magnesium 0.15 to 0.35% by weight of silicon 0.20 to 1.2% by weight of manganese Max. 0.40 wt% iron Max. 0.10% by weight copper Max. 0.05 wt% chromium Max. 0.10% by weight zinc Max. 0.003 wt% beryllium Max. 0.20 wt% titanium Max. 0.60% by weight cobalt Max. 0.80% by weight of cerium and aluminum as the rest with further impurities individually max. 0.02% by weight, total max. 0.2% by weight. Aluminium-Gusslegierung nach Anspruch 1, dadurch gekennzeichnet, dass die Legierung 2.5 bis 3.3 Gew.-%, insbesondere 2.6 bis 3.3 Gew.-% Magnesium enthält.Cast aluminum alloy according to claim 1, characterized in that the Alloy 2.5 to 3.3 wt .-%, in particular 2.6 to 3.3 wt .-% magnesium contains. Aluminium-Gusslegierung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Legierung 0.20 bis 0.30 Gew.-% Silizium enthält.Cast aluminum alloy according to claim 1 or 2, characterized in that the alloy contains 0.20 to 0.30 wt .-% silicon. Aluminium-Gusslegierung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass die Legierung 0.40 bis 1.2 Gew.-%, insbesondere 0.50 bis 1.0 Gew.-% Mangan enthält.Cast aluminum alloy according to one of Claims 1 to 3, characterized in that that the alloy 0.40 to 1.2 wt .-%, in particular 0.50 to 1.0 Wt .-% contains manganese. Aluminium-Gusslegierung nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass die Legierung max. 0.30 Gew.-%, insbesondere max. 0.15 Gew.-% Eisen enthält. Cast aluminum alloy according to one of Claims 1 to 4, characterized in that that the alloy max. 0.30% by weight, in particular max. 0.15% by weight Contains iron. Aluminium-Gusslegierung nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass die Legierung 0.10 bis 0.60 Gew.-%, insbesondere 0.30 bis 0.60 Gew.-% Cobalt enthält.Cast aluminum alloy according to one of Claims 1 to 5, characterized in that that the alloy 0.10 to 0.60 wt .-%, in particular 0.30 to 0.60 Wt .-% contains cobalt. Aluminium-Gusslegierung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass die Legierung 0.05 bis 0.80 Gew.-%, insbesondere 0.10 bis 0.50 Gew.-% Cer enthält.Cast aluminum alloy according to one of Claims 1 to 6, characterized in that that the alloy 0.05 to 0.80 wt .-%, in particular 0.10 to 0.50 Wt .-% contains cerium. Aluminium-Gusslegierung nach Anspruch 6 oder 7, dadurch gekennzeichnet, dass die Summe der Gehalte an Cobalt, Cer und Mangan in der Legierung min. 0.80 Gew.-% beträgt und die Legierung min. 0.50 Gew.-% Mangan enthält.Cast aluminum alloy according to claim 6 or 7, characterized in that that the sum of the contents of cobalt, cerium and manganese in the alloy min. 0.80 wt .-% and the alloy min. Contains 0.50% by weight of manganese. Aluminium-Gusslegierung nach einem der Ansprüche 1 bis 8, dadurch gekennzeichnet, dass die Legierung als Druckgusslegierung im Gusszustand eine Dehngrenze (Rp0.2) von min. 100 MPa und eine Bruchdehnung (A5) von min. 14% aufweist.Cast aluminum alloy according to one of Claims 1 to 8, characterized in that that the alloy is a die-cast alloy in the as-cast state Yield strength (Rp0.2) of min. 100 MPa and an elongation at break (A5) of min. 14%. Verwendung einer Aluminium-Legierung bestehend aus 2.0 bis 3.5 Gew.-% Magnesium 0.15 bis 0.35 Gew.-% Silizium 0.20 bis 1.2 Gew.-% Mangan max. 0.40 Gew.-% Eisen max. 0.10 Gew.-% Kupfer max. 0.05 Gew.-% Chrom max. 0.10 Gew.-% Zink max. 0.003 Gew.-% Beryllium max. 0.20 Gew.-% Titan max. 0.60 Gew.-% Cobalt max. 0,80 Gew.-% Cer sowie Aluminium als Rest mit weiteren Verunreinigungen einzeln max. 0.02 Gew.-%, insgesamt max. 0.2 Gew.-%, für das Thixocasting oder das Thixoschmieden.Use an aluminum alloy consisting of 2.0 to 3.5% by weight of magnesium 0.15 to 0.35% by weight of silicon 0.20 to 1.2% by weight of manganese Max. 0.40 wt% iron Max. 0.10% by weight copper Max. 0.05 wt% chromium Max. 0.10% by weight zinc Max. 0.003 wt% beryllium Max. 0.20 wt% titanium Max. 0.60% by weight cobalt Max. 0.80% by weight of cerium and aluminum as the rest with further impurities individually max. 0.02% by weight, total max. 0.2% by weight for thixocasting or thixo forging.
    EP98810210A 1997-10-08 1998-03-12 Aluminium casting alloy Expired - Lifetime EP0911420B1 (en)

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    EP98810210A EP0911420B1 (en) 1997-10-08 1998-03-12 Aluminium casting alloy
    US09/163,822 US6309481B1 (en) 1997-10-08 1998-09-30 Aluminum casting alloy
    CA002249762A CA2249762A1 (en) 1997-10-08 1998-10-07 Aluminium casting alloy
    BR9803822-2A BR9803822A (en) 1997-10-08 1998-10-07 Die-cast aluminum alloy

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    EP97810756 1997-10-08
    EP97810756A EP0908527A1 (en) 1997-10-08 1997-10-08 Aluminium casting alloy
    EP98810210A EP0911420B1 (en) 1997-10-08 1998-03-12 Aluminium casting alloy

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    Cited By (5)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP1118685A1 (en) * 2000-01-19 2001-07-25 ALUMINIUM RHEINFELDEN GmbH Aluminium cast alloy
    EP1118686A1 (en) * 2000-01-19 2001-07-25 ALUMINIUM RHEINFELDEN GmbH Aluminium cast alloy
    EP1129228A1 (en) * 1998-09-21 2001-09-05 Gibbs Die Casting Aluminum Corporation Aluminum die cast alloy having high manganese content
    CN109628804A (en) * 2018-12-06 2019-04-16 佛山市三水凤铝铝业有限公司 A kind of high-strength aluminum alloy and preparation method thereof with excellent oxidation effect
    CN111763859A (en) * 2020-06-24 2020-10-13 浙江永杰铝业有限公司 Aluminum alloy for new energy automobile battery box and production method thereof

    Families Citing this family (11)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    DE10116636C2 (en) * 2001-04-04 2003-04-03 Vaw Ver Aluminium Werke Ag Process for the production of AIMn strips or sheets
    FR2833616B1 (en) * 2001-12-17 2004-07-30 Pechiney Aluminium HIGH DUCTILITY AND RESILIENCE ALUMINUM ALLOY PRESSURE CAST PART
    US20050161128A1 (en) * 2002-03-19 2005-07-28 Dasgupta Rathindra Aluminum alloy
    US6908590B2 (en) * 2002-03-19 2005-06-21 Spx Corporation Aluminum alloy
    ATE437972T1 (en) * 2003-01-23 2009-08-15 Rheinfelden Aluminium Gmbh ALUMINUM ALLOY DIE CASTING ALLOY
    US20070102071A1 (en) * 2005-11-09 2007-05-10 Bac Of Virginia, Llc High strength, high toughness, weldable, ballistic quality, castable aluminum alloy, heat treatment for same and articles produced from same
    CN102876937A (en) * 2012-09-27 2013-01-16 无锡宏昌五金制造有限公司 Wear-resistant alkaline-corrosion-resistant aluminum alloy
    CN105463270A (en) * 2016-01-06 2016-04-06 熊超 Die-casting aluminum alloy allowing heat tinting
    CN111378879B (en) * 2018-12-29 2021-05-07 Oppo广东移动通信有限公司 Aluminum alloy structural part and preparation method thereof, middle frame, battery cover and mobile terminal
    CN111809086B (en) * 2019-04-12 2021-12-07 比亚迪股份有限公司 Die-casting aluminum alloy and preparation method and application thereof
    CN112322945A (en) * 2020-10-29 2021-02-05 大力神铝业股份有限公司 Aluminum alloy material for 3C product and preparation method thereof

    Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4645544A (en) * 1982-06-21 1987-02-24 Sumitomo Light Metal Industries Process for producing cold rolled aluminum alloy sheet
    JPH0234740A (en) * 1988-07-25 1990-02-05 Furukawa Alum Co Ltd Heat-resistant aluminum alloy material and its manufacture
    JPH08134579A (en) * 1994-11-14 1996-05-28 Kobe Steel Ltd Aluminum alloy sheet for beverage can lid
    WO1996025528A1 (en) * 1995-02-16 1996-08-22 Gibbs Die Casting Aluminium Corporation Aluminum alloys for die casting
    WO1996030554A1 (en) * 1995-03-31 1996-10-03 Aluminium Company Of America Improved alloy for cast components
    EP0745694A1 (en) * 1995-05-29 1996-12-04 Ube Industries, Ltd. Method and apparatus for shaping semisolid metals

    Family Cites Families (10)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    CN85100585B (en) * 1985-04-01 1988-03-30 南京工学院 Corrosion-resisting al-alloy
    US4847048A (en) * 1986-07-21 1989-07-11 Ryobi Limited Aluminum die-casting alloys
    JPS63183666A (en) 1987-01-26 1988-07-29 Nikon Corp Reference track detecting mechanism
    JPH04371545A (en) * 1991-06-19 1992-12-24 Furukawa Alum Co Ltd Aluminum alloy sheet for pulley
    JPH05156398A (en) * 1991-12-06 1993-06-22 Nippon Light Metal Co Ltd Aluminum alloy for casting excellent in corrosion resistance
    JP2613522B2 (en) * 1992-03-13 1997-05-28 スカイアルミニウム 株式会社 Aluminum alloy plate for stay tub
    JPH0835029A (en) * 1994-07-19 1996-02-06 Toyota Motor Corp Cast aluminum alloy with high strength and high ductility and production thereof
    JPH0874012A (en) * 1994-09-08 1996-03-19 Toyota Motor Corp Production of superplastic aluminum alloy
    JPH10130766A (en) * 1996-10-29 1998-05-19 Furukawa Electric Co Ltd:The Direct cast and rolled sheet excellent in moldability and surface quality and small in secular change and its production
    JPH10152762A (en) * 1996-11-21 1998-06-09 Furukawa Electric Co Ltd:The Production of hard aluminum alloy sheet excellent in di workability

    Patent Citations (6)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US4645544A (en) * 1982-06-21 1987-02-24 Sumitomo Light Metal Industries Process for producing cold rolled aluminum alloy sheet
    JPH0234740A (en) * 1988-07-25 1990-02-05 Furukawa Alum Co Ltd Heat-resistant aluminum alloy material and its manufacture
    JPH08134579A (en) * 1994-11-14 1996-05-28 Kobe Steel Ltd Aluminum alloy sheet for beverage can lid
    WO1996025528A1 (en) * 1995-02-16 1996-08-22 Gibbs Die Casting Aluminium Corporation Aluminum alloys for die casting
    WO1996030554A1 (en) * 1995-03-31 1996-10-03 Aluminium Company Of America Improved alloy for cast components
    EP0745694A1 (en) * 1995-05-29 1996-12-04 Ube Industries, Ltd. Method and apparatus for shaping semisolid metals

    Non-Patent Citations (2)

    * Cited by examiner, † Cited by third party
    Title
    PATENT ABSTRACTS OF JAPAN vol. 014, no. 192 (C - 0711) 19 April 1990 (1990-04-19) *
    PATENT ABSTRACTS OF JAPAN vol. 096, no. 009 30 September 1996 (1996-09-30) *

    Cited By (7)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    EP1129228A1 (en) * 1998-09-21 2001-09-05 Gibbs Die Casting Aluminum Corporation Aluminum die cast alloy having high manganese content
    EP1129228A4 (en) * 1998-09-21 2002-07-31 Gibbs Die Casting Aluminum Aluminum die cast alloy having high manganese content
    EP1118685A1 (en) * 2000-01-19 2001-07-25 ALUMINIUM RHEINFELDEN GmbH Aluminium cast alloy
    EP1118686A1 (en) * 2000-01-19 2001-07-25 ALUMINIUM RHEINFELDEN GmbH Aluminium cast alloy
    US6306342B2 (en) 2000-01-19 2001-10-23 Aluminium Rheinfelden Gmbh Aluminum casting alloy
    CN109628804A (en) * 2018-12-06 2019-04-16 佛山市三水凤铝铝业有限公司 A kind of high-strength aluminum alloy and preparation method thereof with excellent oxidation effect
    CN111763859A (en) * 2020-06-24 2020-10-13 浙江永杰铝业有限公司 Aluminum alloy for new energy automobile battery box and production method thereof

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    BR9803822A (en) 1999-12-14
    CA2249762A1 (en) 1999-04-08

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