EP0907870A1 - Method and arrangement for burning gas in a furnace - Google Patents

Method and arrangement for burning gas in a furnace

Info

Publication number
EP0907870A1
EP0907870A1 EP97928290A EP97928290A EP0907870A1 EP 0907870 A1 EP0907870 A1 EP 0907870A1 EP 97928290 A EP97928290 A EP 97928290A EP 97928290 A EP97928290 A EP 97928290A EP 0907870 A1 EP0907870 A1 EP 0907870A1
Authority
EP
European Patent Office
Prior art keywords
gas
furnace
air
fed
burned
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97928290A
Other languages
German (de)
French (fr)
Inventor
Markku Raiko
Tommy Jacobson
Kari Jääskeläinen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imatran Voima Oy
Original Assignee
Imatran Voima Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imatran Voima Oy filed Critical Imatran Voima Oy
Publication of EP0907870A1 publication Critical patent/EP0907870A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/06Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste gases or noxious gases, e.g. exhaust gases
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C6/00Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion
    • F23C6/04Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection
    • F23C6/045Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure
    • F23C6/047Combustion apparatus characterised by the combination of two or more combustion chambers or combustion zones, e.g. for staged combustion in series connection with staged combustion in a single enclosure with fuel supply in stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00Staged combustion
    • F23C2201/10Furnace staging
    • F23C2201/101Furnace staging in vertical direction, e.g. alternating lean and rich zones
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23CMETHODS OR APPARATUS FOR COMBUSTION USING FLUID FUEL OR SOLID FUEL SUSPENDED IN  A CARRIER GAS OR AIR 
    • F23C2201/00Staged combustion
    • F23C2201/30Staged fuel supply
    • F23C2201/301Staged fuel supply with different fuels in stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23DBURNERS
    • F23D2900/00Special features of, or arrangements for burners using fluid fuels or solid fuels suspended in a carrier gas
    • F23D2900/14Special features of gas burners
    • F23D2900/14002Special features of gas burners of premix or non premix types, specially adapted for the combustion of low heating value [LHV] gas

Definitions

  • the present invention relates to a method according to the preamble of claim 1 for burning fuel gas in a furnace, particularly for burning gases of low heating value in a boiler principally fired with another main fuel.
  • the invention also concerns an arrangement suitable for implementing said method.
  • the invention is particularly suited for firing with gases produced by air gasification, blast-furnace gas and other gases of low heating value.
  • the invention is utilized in, e.g., performing fuel changes in the firing of a boiler and it can also be used for firing gases of high heating value such as natural gas.
  • the product gas obtained from a separate gasifier has been fed into the furnace via burners.
  • the burners must be designed for a low axial velocity in order to assure reliable ignition, whereby the burner dimensions become very large.
  • the gas feed volume rate becomes extremely large, which complicates fuel feed at a low velocity and makes the burner size larger.
  • the adaptation of larger burners in an existing furnace is technically difficult, and additionally, revamping an old boiler with more burners cuts down the available heat transfer surface by a substantial amount. Difficulties in achieving a sufficient residence time in product-gas firing and construction constraints may also cause complications in the arrangement of additional burners.
  • the goal of the invention is achieved by feeding the product gas of a gasifier or other gas to be burned into the lower part of the boiler under oxygen-depleted conditions and then burning the gas in the upper part of the boiler at desired levels of combustion air infeed or at a greater number of combustion air infeed levels.
  • the invention provides significant benefits.
  • existing boiler constructions can use very advantageously gases of rather low heating value with minor modifications in the boiler.
  • the heat transfer surface area of the steam generator need not be reduced and boilers equipped with combustion gas recirculation can use the existing recirculation system for feeding the supplementary fuel gas into the lower part of the boiler.
  • the invention achieves stable combustion and causes only minor changes in the internal flow pattern of the furnace.
  • the flame radiation stabilizes the ignition and burning of the supplementary fuel gas.
  • the novel infeed arrangement offers simpler revamping in an existing boiler, because gas inlet openings are easier to adapt in the furnace than large burners.
  • the novel method is more flexible with respect to the fuel type and facilitates wider possibilities over the prior art to reduce the amount of nitrogen oxides in stack gas by combustion control means.
  • the method achieves strong staging in the furnace by means of a correctly timed air feed scheme, the boiler can be operated in the same fashion as staged low-NOx burners.
  • the hydrocarbon radicals formed from the fuel reduce nitrogen monoxide back to molecular nitrogen thus reducing the total amount of NOx emissions.
  • the method according to the invention can be applied to the combustion of all types of gaseous fuels.
  • the benefits of the method related to boiler construction are best utilized in the combustion of low-caloric-value gases such as gasification gas produced by air gasification, blast-furnace gas and waste gases. Nevertheless, the above-described benefits of improved combustion may also be exploited when burning gases of high caloric value gases such as natural gas.
  • product gas can be burned as the main fuel.
  • the product gas is fed into an air-deficient (reducing) zone in the lower part 10 of the furnace 2, thus assuring sufficient residence time and avoiding furnace explosions.
  • the gas is ignited and. burned only in the combustion air flows which are fed into the upper zones of the furnace.
  • Air can be fed into the boiler via burners 8 feeding other fuels and/or via separate air infeed nozzles 9.
  • the locus of combustion and thereby further the heat-transfer distribution within the steam- generating circuit of the boiler 1 can be effectively controlled by means of the vertical distribution of air infeed, which determines the location of the different zones of the combustion process in the furnace 2.
  • the air feed distribution also offers efficient means for controlling the formation chain of nitrogen oxides in the furnace 2, whereby a correctly staged air infeed scheme can achieve essential reduction of obnoxious emissions.
  • the boiler 1 shown in the diagram is a conventional boiler designed, e.g., for burning coal or peat.
  • Burners 8 used for the infeed of the solid fuel are arranged in rows on the wall of the furnace 2, whereby the combustion air required by the burners is fed into the furnace via air infeed nozzles adapted to the burners 8, and when required, also via auxiliary air infeed nozzles located in the vicinity thereof.
  • the boiler 1 is equipped with at least one top auxiliary air infeed nozzle 9 for feeding air into the upper part of the furnace 2.
  • the upper part of the boiler 1 includes superheaters for high-temperature heating of the steam exiting the steam generator, arranged to surround the furnace 2, and an exit connection of the stack gas duct.
  • the product gas is taken to the lower part 10 of the furnace 2, underneath the burners 8, into a zone of no air infeed thus creating strongly reducing conditions therein.
  • the gas is produced in a gasifier 5, which may be an air gasifier, blast furnace or any other unit in which is produced or is formed a combustible gas.
  • the invention makes it possible to utilize gases of extremely low heating value, thereby exploiting their heat value and simultaneously achieving efficient and cost-effective reduction of obnoxious emissions as the advanced combus- tion process of a large boiler with the stack gas cleaning equipment connected thereto also performs effective combustion/cleaning of the gas produced in a gasifier.
  • the gas to be burned is taken via a large-diameter duct 6 to nozzles 7 located in the lower part 10 of the furnace, wherefrom the gas can flow upward in the furnace.
  • the gas will not ignite in the air-deficient lower part of the furnace, it will be heated and readily ignited in the upper zones under flame radiation of the furnace 2 (that is, the thermal radia- tion of the combustion process) and oxygen introduced via the air nozzles of the burners 8.
  • the combustion process in the furnace is further staged by feeding the rest of the required combustion air to the upper part of the furnace via the top auxiliary air nozzles 9.
  • the method is also applicable to boilers adapted for burning product gas only, whereby separate burners are not necessarily required, but instead, the burners may be replaced by air infeed nozzles alone. However, in this case it may be advisable to assure gas ignition and combustion with the help of, e.g., a natural gas or oil burner. Further, a single boiler can be used for burning product gases from several different gasifiers, which may find advantageous use in the gasification of wastes into fuel.

Landscapes

  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Combustion Of Fluid Fuel (AREA)
  • Solid-Fuel Combustion (AREA)

Abstract

The invention relates to a method and arrangement for burning fuel gas in a furnace (2), particularly for burning gases of low heating value in a boiler (1) principally fired with a main fuel. The invention is based on feeding the product gas of a gasifier (5) or other combustible gas into air-deficient conditions of the lower part (10) of the furnace (2) and the gas is combusted upper in the furnace (2) at a desired level of combustion air infeed, or alternatively, at multiple infeed levels of the combustion air.

Description

Method and arrangement for burning gas in a furnace
The present invention relates to a method according to the preamble of claim 1 for burning fuel gas in a furnace, particularly for burning gases of low heating value in a boiler principally fired with another main fuel.
The invention also concerns an arrangement suitable for implementing said method.
The invention is particularly suited for firing with gases produced by air gasification, blast-furnace gas and other gases of low heating value. The invention is utilized in, e.g., performing fuel changes in the firing of a boiler and it can also be used for firing gases of high heating value such as natural gas.
Conventionally, the product gas obtained from a separate gasifier has been fed into the furnace via burners. If the product gas has a low heating value, the burners must be designed for a low axial velocity in order to assure reliable ignition, whereby the burner dimensions become very large. When firing with low-caloric-value gases such as gases produced by air gasification, the gas feed volume rate becomes extremely large, which complicates fuel feed at a low velocity and makes the burner size larger. Furthermore, the adaptation of larger burners in an existing furnace is technically difficult, and additionally, revamping an old boiler with more burners cuts down the available heat transfer surface by a substantial amount. Difficulties in achieving a sufficient residence time in product-gas firing and construction constraints may also cause complications in the arrangement of additional burners. While product gases of high heating value can be fed at higher axial velocities, the adaptation of new burners in an existing boiler is nonetheless difficult. As boilers are generally designed for a specific fuel and air flow rate, additional burners can cause fouling problems and flow disturbances, because the introduction of new flow rates in the boiler change the flow patterns in the furnace thus altering the fuel combustion process, the flame pattern, stack gas composition and heat transfer on the boiler internal surfaces.
It is an object of the present invention to provide a method suited for burning low-caloric-value gas particularly in existing boilers designed for other type of main fuel without any need for major construction changes in the boiler.
The goal of the invention is achieved by feeding the product gas of a gasifier or other gas to be burned into the lower part of the boiler under oxygen-depleted conditions and then burning the gas in the upper part of the boiler at desired levels of combustion air infeed or at a greater number of combustion air infeed levels.
More specifically, the method according to the invention is characterized by what is stated in the characterizing part of claim 1.
Furthermore, the arrangement according to the invention is characterized by what is stated in the characterizing part of claim 7.
The invention provides significant benefits.
By virtue of the invention, existing boiler constructions can use very advantageously gases of rather low heating value with minor modifications in the boiler. The heat transfer surface area of the steam generator need not be reduced and boilers equipped with combustion gas recirculation can use the existing recirculation system for feeding the supplementary fuel gas into the lower part of the boiler. The invention achieves stable combustion and causes only minor changes in the internal flow pattern of the furnace. In the method, the flame radiation stabilizes the ignition and burning of the supplementary fuel gas. Furthermore, the novel infeed arrangement offers simpler revamping in an existing boiler, because gas inlet openings are easier to adapt in the furnace than large burners.
The novel method is more flexible with respect to the fuel type and facilitates wider possibilities over the prior art to reduce the amount of nitrogen oxides in stack gas by combustion control means. As the method achieves strong staging in the furnace by means of a correctly timed air feed scheme, the boiler can be operated in the same fashion as staged low-NOx burners.
The benefits of the method will be most pronounced when the combustion of a product gas is connected as a supplementary fuel infeed to an existing boiler. By virtue of feeding the product gas via nozzles adapted to the lower part of the furnace or via openings made to a possible combustion gas recirculation system, instead of using burners, changes required on the heat-transfer surfaces remain essentially smaller than when equipping the boiler for product-gas firing by means of burners. Additionally, the above-described combustion process benefits are gained. Furthermore, if a new boiler is particularly designed for mixed fuel use, particularly advantageous conditions depending on the product gas composition can be attained for the reburning effect, which reduces the NOx emissions. Herein, the hydrocarbon radicals formed from the fuel reduce nitrogen monoxide back to molecular nitrogen thus reducing the total amount of NOx emissions. The method according to the invention can be applied to the combustion of all types of gaseous fuels. However, the benefits of the method related to boiler construction are best utilized in the combustion of low-caloric-value gases such as gasification gas produced by air gasification, blast-furnace gas and waste gases. Nevertheless, the above-described benefits of improved combustion may also be exploited when burning gases of high caloric value gases such as natural gas. Furthermore, product gas can be burned as the main fuel.
In the following the invention will be examined in greater detail by making reference to the appended drawing in which an embodiment of the invention is diagrammatically illustrated.
Referring to the diagram, the product gas is fed into an air-deficient (reducing) zone in the lower part 10 of the furnace 2, thus assuring sufficient residence time and avoiding furnace explosions. As no combustion air is fed into this zone, the gas is ignited and. burned only in the combustion air flows which are fed into the upper zones of the furnace. Air can be fed into the boiler via burners 8 feeding other fuels and/or via separate air infeed nozzles 9. The locus of combustion and thereby further the heat-transfer distribution within the steam- generating circuit of the boiler 1 can be effectively controlled by means of the vertical distribution of air infeed, which determines the location of the different zones of the combustion process in the furnace 2. The air feed distribution also offers efficient means for controlling the formation chain of nitrogen oxides in the furnace 2, whereby a correctly staged air infeed scheme can achieve essential reduction of obnoxious emissions.
The boiler 1 shown in the diagram is a conventional boiler designed, e.g., for burning coal or peat. Burners 8 used for the infeed of the solid fuel are arranged in rows on the wall of the furnace 2, whereby the combustion air required by the burners is fed into the furnace via air infeed nozzles adapted to the burners 8, and when required, also via auxiliary air infeed nozzles located in the vicinity thereof. In addition to the burner air infeed nozzles, the boiler 1 is equipped with at least one top auxiliary air infeed nozzle 9 for feeding air into the upper part of the furnace 2. Conventionally, the upper part of the boiler 1 includes superheaters for high-temperature heating of the steam exiting the steam generator, arranged to surround the furnace 2, and an exit connection of the stack gas duct.
The product gas is taken to the lower part 10 of the furnace 2, underneath the burners 8, into a zone of no air infeed thus creating strongly reducing conditions therein. The gas is produced in a gasifier 5, which may be an air gasifier, blast furnace or any other unit in which is produced or is formed a combustible gas. The invention makes it possible to utilize gases of extremely low heating value, thereby exploiting their heat value and simultaneously achieving efficient and cost-effective reduction of obnoxious emissions as the advanced combus- tion process of a large boiler with the stack gas cleaning equipment connected thereto also performs effective combustion/cleaning of the gas produced in a gasifier. From the gasifier, the gas to be burned is taken via a large-diameter duct 6 to nozzles 7 located in the lower part 10 of the furnace, wherefrom the gas can flow upward in the furnace. Although the gas will not ignite in the air-deficient lower part of the furnace, it will be heated and readily ignited in the upper zones under flame radiation of the furnace 2 (that is, the thermal radia- tion of the combustion process) and oxygen introduced via the air nozzles of the burners 8. The combustion process in the furnace is further staged by feeding the rest of the required combustion air to the upper part of the furnace via the top auxiliary air nozzles 9.
In addition to the above-described example, alternative embodiments of the invention may be contemplated.
The method is also applicable to boilers adapted for burning product gas only, whereby separate burners are not necessarily required, but instead, the burners may be replaced by air infeed nozzles alone. However, in this case it may be advisable to assure gas ignition and combustion with the help of, e.g., a natural gas or oil burner. Further, a single boiler can be used for burning product gases from several different gasifiers, which may find advantageous use in the gasification of wastes into fuel.

Claims

Claims :
1. A method of burning gas in a furnace, c h a r a c t e r i z e d in that
- the gas to be burned is fed into a reducing zone in the lower part (10) of said furnace ( 2 ) , and
- combustion air is fed into the furnace (2) in at least one zone located above the infeed zone (10) of the gas to be burned.
2. A method as defined in claim 1, in which method gas is burned in a boiler equipped with at least one burner
(8) for burning some other fuel than the gas to be burned, c h a r a c t e r i z e d in that the gas to be burned is fed into the furnace (2) underneath the burners (8).
3. A method as defined in claim 2, c h a r a c t e r i z e d in that a portion of the combustion air is fed into the furnace (2) via the air nozzles of said burners (8) and another portion via at least one air infeed nozzle (9) adapted above said burners.
4. A method as defined in claim 1, c h a r a c t e r i z e d in that a portion of the combustion air is fed into the furnace (2) in a first stage adapted above the gas infeed point and auxiliary air is fed into the furnace in at least one stage adapted above the first air infeed point.
5. A method as defined in any foregoing claim, c h a r a c t e r i z e d in that the gas to be burned is fed into the furnace (2) via a combustion gas recirculation system.
6. A method as defined in any foregoing claim, c h a r a c t e r i z e d in that the gas to be burned is gas produced by air gasification, blast-furnace gas, waste gas or other gas of low heating value.
7. An arrangement for burning gas in a furnace (2), c h a r a c t e r i z e d by
- openings (7) adapted to the reducing zone in the lower part (10) of said furnace (2) , via which openings the gas is fed into said furnace (2) , and
- at least one air infeed nozzle for feeding combustion air into said furnace (2) in at least one zone located above the infeed zone (10) of the gas to be burned.
8. An arrangement as defined in claim 7, said arrange- ment comprising in its furnace at least one burner (8) for burning other fuel than the gas to be burned, c h a r a c t e r i z e d in that the openings (7) for feeding the gas to be burned into the furnace (2) are adapted below said burners (8) .
9. An arrangement as defined in claim 8, c h a r a c t e r i z e d by air nozzles of said burners (8) , through which nozzles a portion of the combustion air can be fed into the furnace and by at least one air nozzle (9) located above said burners (8) for feeding auxiliary air into the furnace (2) .
10. An arrangement as defined in claim 7, c h a r a c t e r i z e d by air nozzles through which a portion of the combustion air can be fed into the furnace (2) in the first stage adapted above the infeed point of the fuel gas and by at least one auxiliary air nozzle (9) located above the said first air infeed point for feeding auxiliary air in at least one stage into the furnace (2) .
11. An arrangement as defined in any of foregoing claims 7 - 10, c h a r a c t e r i z e d in that the gas to be burned is fed into the furnace (2) via stack gas recirculating system.
12. An arrangement as defined in any of foregoing claims 7 - 11, c h a r a c t e r i z e d in that said arrangement comprises an apparatus (5) for generating the fuel gas and at least one nozzle (6) for feeding the fuel gas into said furnace (2) for combustion therein.
EP97928290A 1996-06-28 1997-06-25 Method and arrangement for burning gas in a furnace Withdrawn EP0907870A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI962669A FI100355B (en) 1996-06-28 1996-06-28 Method and apparatus for combustion of gas in a fireplace
FI962669 1996-06-28
PCT/FI1997/000411 WO1998000675A1 (en) 1996-06-28 1997-06-25 Method and arrangement for burning gas in a furnace

Publications (1)

Publication Number Publication Date
EP0907870A1 true EP0907870A1 (en) 1999-04-14

Family

ID=8546303

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97928290A Withdrawn EP0907870A1 (en) 1996-06-28 1997-06-25 Method and arrangement for burning gas in a furnace

Country Status (12)

Country Link
EP (1) EP0907870A1 (en)
CN (1) CN1228830A (en)
AU (1) AU3264397A (en)
CZ (1) CZ430998A3 (en)
EE (1) EE9800442A (en)
FI (1) FI100355B (en)
HU (1) HUP0101129A3 (en)
LV (1) LV12242B (en)
PL (1) PL330818A1 (en)
RO (1) RO117982B1 (en)
SK (1) SK177498A3 (en)
WO (1) WO1998000675A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109780563A (en) * 2019-02-28 2019-05-21 刘玉满 The high-temperature oxygen-enriched extraordinary pressure overheavy firing purification method of benzene class nuisance in industrial waste gas

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102734810A (en) * 2011-04-12 2012-10-17 无锡市晨光耐火材料有限公司 Residual heat absorbing boiler for CO

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FR2105394A5 (en) * 1970-09-04 1972-04-28 Cimab Sa
US3890084A (en) * 1973-09-26 1975-06-17 Coen Co Method for reducing burner exhaust emissions
US4021186A (en) * 1974-06-19 1977-05-03 Exxon Research And Engineering Company Method and apparatus for reducing NOx from furnaces
FR2290634A1 (en) * 1974-11-06 1976-06-04 Lorraine Houilleres COMPLETE COMBUSTION PROCESS OF HOT GASES WITH LOW CALORIFIC CAPACITY
DE2523852C2 (en) * 1975-05-30 1981-08-13 Kraftwerk Union AG, 4330 Mülheim Firing for a steam generator with pulverized coal and gas burners
JPS5623615A (en) * 1979-08-06 1981-03-06 Babcock Hitachi Kk Burning method for low nox
FI87013C (en) * 1988-01-04 1992-11-10 Tampella Oy Ab Burning process for reducing formation of nitrogen oxides in connection with combustion and apparatus for applying the process

Non-Patent Citations (1)

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Title
See references of WO9800675A1 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109780563A (en) * 2019-02-28 2019-05-21 刘玉满 The high-temperature oxygen-enriched extraordinary pressure overheavy firing purification method of benzene class nuisance in industrial waste gas

Also Published As

Publication number Publication date
LV12242B (en) 1999-06-20
AU3264397A (en) 1998-01-21
CN1228830A (en) 1999-09-15
HUP0101129A2 (en) 2001-08-28
WO1998000675A1 (en) 1998-01-08
EE9800442A (en) 1999-06-15
HUP0101129A3 (en) 2001-12-28
FI962669A0 (en) 1996-06-28
LV12242A (en) 1999-03-20
PL330818A1 (en) 1999-06-07
CZ430998A3 (en) 1999-06-16
FI100355B (en) 1997-11-14
RO117982B1 (en) 2002-11-29
SK177498A3 (en) 2000-04-10

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