EP0906453B1 - Relaxation-resistant steel spring - Google Patents

Relaxation-resistant steel spring Download PDF

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Publication number
EP0906453B1
EP0906453B1 EP96919601A EP96919601A EP0906453B1 EP 0906453 B1 EP0906453 B1 EP 0906453B1 EP 96919601 A EP96919601 A EP 96919601A EP 96919601 A EP96919601 A EP 96919601A EP 0906453 B1 EP0906453 B1 EP 0906453B1
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EP
European Patent Office
Prior art keywords
weight percent
spring
steel spring
wire
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP96919601A
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German (de)
French (fr)
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EP0906453A1 (en
Inventor
Joachim Heinke
Klaus Wanke
Otto Zehendner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Datec Scherdel Datentechnik Forschungs und Entwicklungs GmbH
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Datec Scherdel Datentechnik Forschungs und Entwicklungs GmbH
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Publication of EP0906453A1 publication Critical patent/EP0906453A1/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/02Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for springs
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires

Definitions

  • the invention relates to a steel spring operating at relatively high working temperatures has a good resistance to relaxation.
  • Feathers are known to consist of patented drawn spring steel wires made of unalloyed carbon steels. Such springs are essentially free of scale and residual dirt particles, but are suitable for operating temperatures of Can only be used to a limited extent above 80 ° C. The use is made with greatly reduced Working voltages, their compensation only over a higher application mass the spring can be done, as is known from economic but also brings considerable disadvantages for design reasons. Regarding springs show the relaxation behavior at higher operating temperatures from oil-quenched and tempered unalloyed spring steel and valve spring wires same disadvantages. In addition, as a result of the final oil tariff Surface with scale or residues of other residues release the spring function and in sensitive work areas such as automatic transmissions and fuel injection systems in motor vehicles to significant malfunctions or the complete failure of such units being able to lead.
  • Austenitic springs are used to eliminate these disadvantages stainless spring wires, for example of the grade X 12 CrNi 17.7. As a result of the much higher Alloy expenditure and the technological peculiarities however arise unacceptably high material costs for the Spring elements.
  • a wire is known from JP-A-2057637 which austenitizes and isothermally kept at 250-500 ° C and then deformed into a spring becomes.
  • the holding temperature of 250-500 ° C leads to a so-called Bainite coating with a low ductile bainite structure.
  • a subsequent pulling process as used to increase tensile strength would be desirable in itself, at this level Technology not possible.
  • the invention has for its object a high-strength increased operating temperatures relaxation-resistant wire springs with scale and residual dirt-free surface and relative to create low material costs.
  • a relaxation-proof and heat-resistant tension spring with the following dimensions: Wire diameter 3.6 mm Spring body diameter 41.5 mm Unstretched length L o 268 mm Tensioned spring length L 1 384 mm L2 570 mm is made of 8 mm ⁇ rolled steel with the following composition: 0.68 Weight percent carbon 1.48 Weight percent silicon 0.52 Weight percent chrome 0.65 Weight percent manganese and steel typical accompanying elements.
  • This rolled steel is austenitized at 900 ° C, isothermally converted at 540 ° C and then cold drawn to 3.6 mm. A strength Rm of 1900 N / mm 2 is achieved.
  • This wire is formed fully automatically into a tension spring with the above-mentioned dimensions and then annealed at 300 ° C for one hour with low stress. Relaxation loss after testing for L2 at 145 ° C one hour: 4.8%

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Springs (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)

Abstract

The invention concerns a very strong steel spring having a bright surface which is free from residual dirt, the spring also being resistant to relaxation at high operating temperatures. A spring of this type is produced from a steel wire of the following composition: between 0.45 and 0.85 wt % carbon; between 0.2 and 1.60 wt % silicon; between 0.3 and 1.50 wt % manganese; between 0.4 and 1.2- wt % chromium; the remainder being iron and unavoidable impurities. The wire is austenitized and then treated isothermally at temperatures ranging from 450 to 650 DEG C. The wire is then drawn to a tensile strength of between 1600 and 2300 N/mm<2> at a contraction in area when breaking of at least 40 %. The wire is cold formed to produce a spring and is then stress-free annealed at temperatures ranging from 200 to 350 DEG C.

Description

Die Erfindung betrifft eine Stahlfeder, die bei relativ hohen Arbeitstemperaturen eine gute Relaxationsfestigkeit besitzt.The invention relates to a steel spring operating at relatively high working temperatures has a good resistance to relaxation.

Bekannt sind Federn aus patentiert gezogenen Federstahldrähten bestehend aus unlegierten Kohlenstoffstählen. Solche Federn sind im wesentlichen frei von Zunder und Restschmutzteilchen, sind aber für Betriebstemperaturen von über 80 °C nur bedingt einsetzbar. Der Einsatz erfolgt mit stark reduzierten Arbeitsspannungen, deren Kompensation nur über eine höhere Einsatzmasse der Feder erfolgen kann, die bekanntlicher Weise aus wirtschaftlichen aber auch aus konstruktiven Gründen erhebliche Nachteile bringt. Hinsichtlich des Relaxationsverhaltens bei höheren Betriebstemperaturen zeigen Federn aus ölschlußvergüteten unlegierten Federstahl- und Ventilfederdrähten die gleichen Nachteile. Hinzu kommt, daß infolge der Ölschlußvergütung die Oberfläche mit Zunder oder Resten anderer Rückstände behaftet ist, sich bei der Federfunktion lösen und in sensiblen Arbeitsbereichen wie beispielsweise automatischen Getrieben und Kraftstoffeinspritzsystemen in Kraftfahrzeugen zu erheblichen Störungen oder zum gänzlichen Ausfall derartiger Aggregate führen können.Feathers are known to consist of patented drawn spring steel wires made of unalloyed carbon steels. Such springs are essentially free of scale and residual dirt particles, but are suitable for operating temperatures of Can only be used to a limited extent above 80 ° C. The use is made with greatly reduced Working voltages, their compensation only over a higher application mass the spring can be done, as is known from economic but also brings considerable disadvantages for design reasons. Regarding springs show the relaxation behavior at higher operating temperatures from oil-quenched and tempered unalloyed spring steel and valve spring wires same disadvantages. In addition, as a result of the final oil tariff Surface with scale or residues of other residues release the spring function and in sensitive work areas such as automatic transmissions and fuel injection systems in motor vehicles to significant malfunctions or the complete failure of such units being able to lead.

Zur Erhöhung des Relaxationsverhaltens bei höheren Arbeitstemperaturen ist der Einsatz von Federn aus CrV-, SiCr- und SiCrV - legierten Federstahldrähten bereits praxisbekannt. Hiermit lassen sich Grenztemperaturen von 160 °C realisieren. Diese legierten Stähle erfordern ebenfalls eine Ölschlußvergütung. Es treten also die gleichen Nachteile wie bei Federn aus unlegierten Federstählen auf., d.h., ebenfalls hier haften an der Oberfläche Reste von Zunder, der gelöst, infolge der Federfunktion, zu Ausfällen hochempfindlicher technischer Systeme führen kann. Ein weiterer wesentlicher Nachteil besteht darin, daß das bei der Vergütung entstandene martensitische Gefüge außerordentlich empfindlich beim Beizen oder einer Oberflächenbehandlung reagiert, die mit einer Wasserstoffdiffusion in den Federwerkstoff verbunden ist. Die sogenannte Wasserstoffversprödung, wie sie beim Beizen oder elektrolytischen Beschichten entsteht, führt zum vorzeitigen Ausfall des Federelementes und damit zur Funktionsmüdigkeit komplizierter und teurer Mechanismen. Neben diesen funktionellen Nachteilen haftet den Federn dieser Werkstoffgruppe ein wesentlicher technologischer Nachteil an. Nach dem Umformen müssen derartige Federelemente ohne Zeitverzug einer Entspannungsglühung (Anlassen) unterzogen werden. Treten hier Verzögerungen ein, bilden sich Eigenspannungsanrisse, die zum vorzeitigen Bruch des oder der Federelemente führen. To increase the relaxation behavior at higher working temperatures the use of springs made of CrV, SiCr and SiCrV alloy spring steel wires already known in practice. This allows limit temperatures of 160 ° C realize. These alloyed steels also require an oil tempering. So there are the same disadvantages as with springs made of unalloyed Spring steels on., I.e. here, too, remains of Tinder, which loosened, due to the spring function, highly sensitive to failures technical systems can lead. Another major disadvantage is in the fact that the martensitic structure created during the remuneration is extraordinary sensitive to pickling or surface treatment, which is associated with hydrogen diffusion in the spring material. The so-called hydrogen embrittlement, as used in pickling or electrolytic Coating occurs, leads to premature failure of the spring element and thus the functional fatigue of complicated and expensive mechanisms. In addition to these functional disadvantages, the springs of this material group are liable a major technological disadvantage. After reshaping Such spring elements must have a relaxation annealing without delay Undergo. If delays occur here, form residual stress cracks leading to the premature breakage of the spring element or elements to lead.

Zur Beseitigung dieser Nachteile sind Federn aus austenitichen nichtrostenden Federdrähten, beispielsweise der Sorte X 12 CrNi 17.7, entwickelt worden. Infolge des wesentlich höheren Legierungsaufwandes und der technologischen Besonderheiten entstehen jedoch unvertretbar hohe Materialkosten für die Federelemente.Austenitic springs are used to eliminate these disadvantages stainless spring wires, for example of the grade X 12 CrNi 17.7. As a result of the much higher Alloy expenditure and the technological peculiarities however arise unacceptably high material costs for the Spring elements.

Aus der JP-A-2057637 ist ein Draht bekannt, der austenitisiert und isotherm auf 250-500° C gehalten und dann zur Feder verformt wird. Die Haltetemperatur von 250-500° C führt zu einer sogenannten Bainitvergütung mit einem wenig duktilen Bainitgefüge. Ein nachfolgender Ziehvorgang, wie er zur Erhöhung der Zugfestigkeit an sich wünschenswert wäre, ist bei diesem Stand der Technik nicht möglich.A wire is known from JP-A-2057637 which austenitizes and isothermally kept at 250-500 ° C and then deformed into a spring becomes. The holding temperature of 250-500 ° C leads to a so-called Bainite coating with a low ductile bainite structure. A subsequent pulling process as used to increase tensile strength would be desirable in itself, at this level Technology not possible.

Aus der GB-A-2210299 und der EP-A-368638 ist es ferner bekannt, Federn aus ölschlußgehärtetem Federstahl, aus vergütetem Stahl zu formen oder aus dem ungehärteten Draht geformte Federn zu vergüten.From GB-A-2210299 and EP-A-368638 it is also known Springs made of oil-hardened spring steel, made of tempered steel too shape or springs formed from the uncured wire compensate.

Der Erfindung liegt die Aufgabe zugrunde, eine hochfeste, bei erhöhten Betriebstemperaturen relaxationsbeständige Drahtfedern mit zunder- bzw. restschmutzfreier Oberfläche und relativ geringen Materialkosten zu schaffen.The invention has for its object a high-strength increased operating temperatures relaxation-resistant wire springs with scale and residual dirt-free surface and relative to create low material costs.

Diese Aufgabe wird erfindungsgemäß mit den Merkmalen des Anspruchs 1 gelöst.This object is achieved with the features of Claim 1 solved.

Vortailhafte Ausführungsbeispiele ergeben sich aus den Unteransprüchen.Pretailored embodiments result from the Dependent claims.

Die Erfindung wird nachfolgend anhand zweier Ausführungsbeispiele näher erläutert. The invention is described below using two exemplary embodiments explained in more detail.

Beispiel 1:Example 1:

Eine relaxationsfeste und warmfeste Zugfeder mit folgenden Abmessungen: Drahtdurchmesser 3,6 mm Federkörperdurchmesser 41,5 mm Ungespannte Länge Lo 268 mm Gespannte Federlänge L1 384 mm L2 570 mm wird hergestellt aus einem Walzstahl mit 8 mm Ø und folgender Zusammensetzung: 0,68 Gewichtsprozente Kohlenstoff 1,48 Gewichtsprozente Silizium 0,52 Gewichtsprozente Chrom 0,65 Gewichtsprozente Mangan und stahltypische Begleitelemente. A relaxation-proof and heat-resistant tension spring with the following dimensions: Wire diameter 3.6 mm Spring body diameter 41.5 mm Unstretched length L o 268 mm Tensioned spring length L 1 384 mm L2 570 mm is made of 8 mm Ø rolled steel with the following composition: 0.68 Weight percent carbon 1.48 Weight percent silicon 0.52 Weight percent chrome 0.65 Weight percent manganese and steel typical accompanying elements.

Dieser Walzstahl wird bei 900 °C austenitisiert, bei 540 °C isothermisch umgewandelt und nachfolgend an 3,6 mm kaltgezogen. Dabei wird eine Festigkeit Rm von 1900 N/mm2 erreicht. Dieser Draht wird vollautomatisch zu einer Zugfeder mit vorstehend genannten Abmessungen umgeformt und anschließend bei 300 °C eine Stunde spannungsarm geglüht. Relaxationsverlust nach Prüfung auf L2 bei 145 °C
eine Stunde: 4,8 %
This rolled steel is austenitized at 900 ° C, isothermally converted at 540 ° C and then cold drawn to 3.6 mm. A strength Rm of 1900 N / mm 2 is achieved. This wire is formed fully automatically into a tension spring with the above-mentioned dimensions and then annealed at 300 ° C for one hour with low stress. Relaxation loss after testing for L2 at 145 ° C
one hour: 4.8%

Beispiel 2:Example 2:

Ein weiteres Beispiel bezieht sich auf die Herstellung einer Schraubendruckfeder. Aus einem Walzstahl 5,5 mm Ø mit einer Zusammensetzung wie im Beispiel 1 wird eine analoge Wärme- und Kaltziehbehandlung bei der Zugfeder ausgeführt und eine Druckfeder für eine Kraftstoffeinspritzpumpe mit folgenden Federdaten erzeugt: Drahtdurchmesser 1,4 mm Außendurchmesser 7,3 mm Ungespannte Länge 25,4 mm Relaxationsprüfung bei L2 = 15,4 mm und 150 °C
zwölf Stunden: 3,5 %
Another example relates to the manufacture of a helical compression spring. From a rolled steel 5.5 mm Ø with a composition as in Example 1, an analog heat and cold drawing treatment is carried out on the tension spring and a compression spring for a fuel injection pump with the following spring data is generated: Wire diameter 1.4 mm outer diameter 7.3 mm Unstretched length 25.4 mm Relaxation test at L 2 = 15.4 mm and 150 ° C
twelve hours: 3.5%

Claims (5)

  1. High-strength, relaxation-resistant steel spring produced from a steel wire with the composition
    a) 0.45 to 0.85 weight percent of carbon
    0.2 to 1,60 weight percent of silicon
    0.3 to 1.50 weight percent of manganese
    0.4 to 1.2 weight percent of chromium
    and selectably also
    b) 0.05 to 0.30 weight percent of vanadium additional constituent and/or
    c) 0.005 to 0.05 weight percent of titanium,
    0.01 to 0.02 weight percent of niobium and/or tantalum
    0.05 to 0.5 weight percent of molybdenum
    d) and/or with complete or partial substitution of the elements chromium and silicon by
       0.003 to 0.01 weight percent of boron
    e) and the balance iron and unavoidable additional constituents,
    wherein the said steel wire has been
    f) austenitised and then isothermally thermally treated in the temperature range between 450 and 650°C,
    g) subsequently drawn to a tensile strength of 1600 to 2300 N/mm2 with a contraction of at least 40% in breakage,
    h) cold-formed into a spring and
    i) subsequently stress-free annealed in the temperature range of 200 to 350°C.
  2. Steel spring according to claim 1, characterised in that it has a helical form.
  3. Steel spring according to claim 1 or 2, characterised in that the mean spring core diameter is equal to or less than quadruple the wire diameter.
  4. Steel spring according to one of claims 1 to 3, characterised in that it has been shot-peened for increase in service life.
  5. Steel spring according to one of claims 1 to 4, characterised in that it has been preset by deformation beyond the elastic limit selectably at room temperature and/or at temperatures up to 400°C.
EP96919601A 1996-05-29 1996-05-29 Relaxation-resistant steel spring Expired - Lifetime EP0906453B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/DE1996/000935 WO1997045565A1 (en) 1996-05-29 1996-05-29 Relaxation-resistant steel spring

Publications (2)

Publication Number Publication Date
EP0906453A1 EP0906453A1 (en) 1999-04-07
EP0906453B1 true EP0906453B1 (en) 2001-08-22

Family

ID=6918350

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96919601A Expired - Lifetime EP0906453B1 (en) 1996-05-29 1996-05-29 Relaxation-resistant steel spring

Country Status (6)

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EP (1) EP0906453B1 (en)
AT (1) ATE204612T1 (en)
AU (1) AU5810896A (en)
CA (1) CA2256384A1 (en)
DE (1) DE59607551D1 (en)
WO (1) WO1997045565A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018183499A1 (en) 2017-03-28 2018-10-04 National Oilwell DHT, L.P. Valves for actuating downhole shock tools in connection with concentric drive systems
CN107557671B (en) * 2017-10-26 2019-05-14 山东汽车弹簧厂淄博有限公司 Microalloying spring steel and preparation method thereof
CN107587079B (en) * 2017-10-26 2019-05-14 山东汽车弹簧厂淄博有限公司 Nitrogenous microalloying spring steel and preparation method thereof
CN109161629A (en) * 2018-08-16 2019-01-08 敬业钢铁有限公司 A kind of LF refining method of spring steel

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE404703C (en) * 1976-09-20 1986-06-23 Garphytte Bruk Ab VALVE SPRING ROW OF LAYER ALLOY STEEL
JPS5925024B2 (en) * 1980-06-26 1984-06-13 株式会社神戸製鋼所 steel for suspension springs
JPH0796697B2 (en) * 1986-10-24 1995-10-18 大同特殊鋼株式会社 High strength spring steel
JP2613601B2 (en) * 1987-09-25 1997-05-28 日産自動車株式会社 High strength spring
JPH0257637A (en) * 1988-08-23 1990-02-27 Nippon Steel Corp Manufacture of spring with high fatigue strength and steel wire for spring for use therein
CA2002138C (en) * 1988-11-08 1999-12-14 Susumu Yamamoto High-strength coil spring and method of producing same
JPH02240240A (en) * 1989-03-10 1990-09-25 Aisin Seiki Co Ltd Diaphragm spring of clutch for automobile use

Also Published As

Publication number Publication date
DE59607551D1 (en) 2001-09-27
WO1997045565A1 (en) 1997-12-04
CA2256384A1 (en) 1997-12-04
EP0906453A1 (en) 1999-04-07
AU5810896A (en) 1998-01-05
ATE204612T1 (en) 2001-09-15

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