EP0900598A2 - Package for dispensing a fluent cosmetic material - Google Patents
Package for dispensing a fluent cosmetic material Download PDFInfo
- Publication number
- EP0900598A2 EP0900598A2 EP98116361A EP98116361A EP0900598A2 EP 0900598 A2 EP0900598 A2 EP 0900598A2 EP 98116361 A EP98116361 A EP 98116361A EP 98116361 A EP98116361 A EP 98116361A EP 0900598 A2 EP0900598 A2 EP 0900598A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- dispensing
- oil
- packaging
- transparent
- microparticles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 9
- 239000000463 material Substances 0.000 title description 6
- 239000011859 microparticle Substances 0.000 claims description 13
- 238000004806 packaging method and process Methods 0.000 claims description 10
- 230000009969 flowable effect Effects 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 claims description 2
- 239000003094 microcapsule Substances 0.000 abstract description 6
- -1 Polyethylene Polymers 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- 230000003750 conditioning effect Effects 0.000 description 7
- 239000002245 particle Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 210000004379 membrane Anatomy 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002775 capsule Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000019271 petrolatum Nutrition 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000606 toothpaste Substances 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 1
- FLPJVCMIKUWSDR-UHFFFAOYSA-N 2-(4-formylphenoxy)acetamide Chemical compound NC(=O)COC1=CC=C(C=O)C=C1 FLPJVCMIKUWSDR-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- 235000019489 Almond oil Nutrition 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229930182556 Polyacetal Natural products 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000008168 almond oil Substances 0.000 description 1
- 230000001166 anti-perspirative effect Effects 0.000 description 1
- 239000003213 antiperspirant Substances 0.000 description 1
- 235000021302 avocado oil Nutrition 0.000 description 1
- 239000008163 avocado oil Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 229960001777 castor oil Drugs 0.000 description 1
- 229940074979 cetyl palmitate Drugs 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000008524 evening primrose extract Nutrition 0.000 description 1
- 229940089020 evening primrose oil Drugs 0.000 description 1
- 239000010475 evening primrose oil Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- PXDJXZJSCPSGGI-UHFFFAOYSA-N hexadecanoic acid hexadecyl ester Natural products CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- 229940119170 jojoba wax Drugs 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940078812 myristyl myristate Drugs 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229940086539 peg-7 glyceryl cocoate Drugs 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000008159 sesame oil Substances 0.000 description 1
- 235000011803 sesame oil Nutrition 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000007762 w/o emulsion Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D83/00—Containers or packages with special means for dispensing contents
- B65D83/0005—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container
- B65D83/0033—Containers or packages provided with a piston or with a movable bottom or partition having approximately the same section as the container the piston being a follower-piston and the dispensing means comprising a hand-operated pressure-device at the opposite part of the container
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/0005—Components or details
- B05B11/0078—Arrangements for separately storing several components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1028—Pumps having a pumping chamber with a deformable wall
- B05B11/1035—Pumps having a pumping chamber with a deformable wall the pumping chamber being a bellow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/10—Pump arrangements for transferring the contents from the container to a pump chamber by a sucking effect and forcing the contents out through the dispensing nozzle
- B05B11/1028—Pumps having a pumping chamber with a deformable wall
- B05B11/1036—Pumps having a pumping chamber with a deformable wall the outlet valve being opened in the direction opposite to the fluid flow downstream the outlet valve by the pressure acting on a valve controlling element
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B11/00—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use
- B05B11/01—Single-unit hand-held apparatus in which flow of contents is produced by the muscular force of the operator at the moment of use characterised by the means producing the flow
- B05B11/02—Membranes or pistons acting on the contents inside the container, e.g. follower pistons
- B05B11/028—Pistons separating the content remaining in the container from the atmospheric air to compensate underpressure inside the container
Definitions
- the invention relates to packaging in the form of a preferably cylindrical or oval Dispensing device, in particular made of a transparent or translucent Plastic material is used for a cosmetic product that is in a transparent, translucent or opaque base containing visible microparticles when dispensing break up and distribute itself homogeneously in the base.
- Cosmetic products that contain visible microparticles in a base Application are destroyed by the pressure exerted thereby and their contents release have been known for a long time.
- EP 590 538 B1 describes a clear, after application on the Hair remaining composition to care for the same, in a transparent Gel base contains microcapsules in which a hair conditioning material is encapsulated and which break open when applied to the hair and the conditioning agent release.
- the disadvantage here is that there is no uniform distribution and Capsule wall residues remain in the hair.
- the invention is therefore based on the task, visible microparticles, the average particle diameter is about 0.1 to 4 mm, containing cosmetic Means, especially hair care products, to create when dispensing the product no residues on the substrate, i.e. to the hair or skin, but are completely and evenly distributed in the base.
- microparticles Means are housed in a package which has an upwardly movable piston and has a closure head which is connected to the body by a valve, and in inside it has an elastic bellows, which at its lower end with the valve is connected and at its upper end opens into a delivery tube, which in one with a Diaphragm-provided discharge opening ends.
- the in particular cylindrical or oval packaging body preferably consists of transparent or translucent material, e.g. Polyethylene, polypropylene or polyacetal, see above that the microparticles can be perceived by the consumer.
- transparent or translucent material e.g. Polyethylene, polypropylene or polyacetal, see above that the microparticles can be perceived by the consumer.
- microparticles are not just microcapsules; it can too Wax particles and other particles, preferably those containing an active material, be used.
- microcapsules that do not have the classic composition of shell (capsule wall) and Have content, but have a consistently homogeneous composition be used.
- microencapsulation of various substances is general specialist knowledge and also with P. Deasy, Manuf. Chemist, vol. 54 / no. 7 (1984), p. 47, in the monographs by M. Gutcho, Capsule Technology and Microencapsulation (1972) and J.R. Nixon, microencapsulation, Vol. 3 of Drugs & Pharmaceutical Science (Marcel Dekker, Inc.) as well as in soap-oil-fat waxes, Vol 106 (1980), pp. 271-272 and Vol. 114 (1989), pp. 94-95, and in the cited therein Described literature to which reference is made.
- compositions are known per se, in addition to EP 590 538, already mentioned B1 is referred to, for example, US-A 4 126 174, US-A 5 082 661, and EP-A 261 754 and referred to DE-C 1 268 316.
- the flowable cosmetic agents to be dispensed according to the invention are preferably around hair care products, in particular transparent or translucent gels such as Hair washing and rinsing agents, hair treatments, conditioners, so-called leave-on products the application remains on the hair, anti-grease and anti-dandruff preparations, etc.
- transparent or translucent gels are preferred. These usually contain about 0.1 to 2.5, in particular about, in an aqueous basis 0.25 to 1.5% by weight of a thickening and suspending aid, for example Hydroxyalkyl celluloses such as hydroxyethyl cellulose or hydroxypropyl methyl cellulose, guar Gum, xanthan gum, polyvinyl pyrrolidone and polyacrylic acid salts.
- a thickening and suspending aid for example Hydroxyalkyl celluloses such as hydroxyethyl cellulose or hydroxypropyl methyl cellulose, guar Gum, xanthan gum, polyvinyl pyrrolidone and polyacrylic acid salts.
- the viscosity of this base is, for example, between approximately 1000 and approximately 100,000, in particular 2500 to 75000, preferably 5000 to 50,000 mPa.s at 20 ° C, measured in Brookfield viscometer (spindle no. 5) at rpm.
- the viscosity of shampoos is of course lower than for leave-on products; the person skilled in the art knows the appropriate values and their setting for the respective product type.
- the microparticles can consist entirely or partially of active ingredients.
- hair conditioning substances are preferred
- Suitable fats and oils are especially natural vegetable oils such as avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, Sunflower oil, almond oil, peach seed oil, wheat germ oil, macadamia nut oil, evening primrose oil, Jojoba oil, castor oil or also olive or soybean oil, lanolin and its derivatives, as well Mineral oils such as paraffin oil and petroleum jelly.
- natural vegetable oils such as avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, Sunflower oil, almond oil, peach seed oil, wheat germ oil, macadamia nut oil, evening primrose oil, Jojoba oil, castor oil or also olive or soybean oil, lanolin and its derivatives, as well Mineral oils such as paraffin oil and petroleum jelly.
- Synthetic oils and waxes are, in particular, silicone oils, such as the known polysiloxanes, polyethylene glycols, etc.
- Natural waxes are, for example, low-melting paraffin waxes, orange wax, apple wax, etc.
- Other suitable conditioning components are fatty alcohols, preferably those with about 8 to 22 carbon atoms in the molecule, such as myristyl, cetyl, stearyl alcohol, wax alcohols and fatty acid esters such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adate, dibutyl adate, dibutyl adate, dibutyl adate , Myristyl myristate, olerlerucate, polyethylene glycol and polyglyceryl fatty acid esters such as PEG-7 glyceryl cocoate, cetyl palm
- microparticles can also be used as or in the microparticles. These are known and therefore do not require any further listing. As already stated at the beginning, the microencapsulation of such substances is known per se and therefore does not require any further explanation. For this purpose, reference is made, for example, to the explanations in EP 590 538 B1 already mentioned.
- the preferred average particle diameter of the microparticles is between approximately 0.5 and 2.5 mm, in particular 0.75 to 2 mm. They are preferably in a color contrast to the aqueous base, so that they are visible to the user in the packaging and have a visual appeal.
- Composition is a skin care product, this is preferably one optionally transparent or translucent oil-in-water or water-in-oil emulsion, however, the use of a gel-like base, for example in the form of a Microemulsion, possible.
- Corresponding skin care products are for example from Schrader, I.C., pp. 387-538 and 583-592 described.
- Further exemplary flowable cosmetic agents are shaving creams, toothpastes, in particular transparent gel-shaped toothpastes with encapsulated active ingredients, Face masks, body deodorants and antiperspirants, etc.
- a gel-shaped, transparent hair treatment composition of the following composition was placed in a cylindrical container made of transparent polyethylene according to FIG. 1.
- Figure 1 When delivering the product from a translucent polypropylene packaging accordingly Figure 1 was a slightly blue colored styling product no longer containing individual particles receive.
Landscapes
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Cosmetics (AREA)
- Closures For Containers (AREA)
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
Abstract
Description
Die Erfindung betrifft eine Verpackung in Form einer vorzugsweise zylindrischen oder ovalen Abgabevorrichtung, die insbesondere aus einem transparenten oder transluzenten Kunststoffmaterial besteht, für ein kosmetisches Mittel, das in einer transparenten, transluzenten oder opaken Grundlage sichtbare Mikroteilchen enthält, die bei der Abgabe aufbrechen und sich homogen in der Grundlage verteilen.The invention relates to packaging in the form of a preferably cylindrical or oval Dispensing device, in particular made of a transparent or translucent Plastic material is used for a cosmetic product that is in a transparent, translucent or opaque base containing visible microparticles when dispensing break up and distribute itself homogeneously in the base.
Kosmetische Mittel, die in einer Grundlage sichtbare Mikroteilchen enthalten, die bei der Applikation durch den dabei ausgeübten Druck zerstört werden und dabei ihren Inhalt freigeben, sind seit langem bekannt.Cosmetic products that contain visible microparticles in a base Application are destroyed by the pressure exerted thereby and their contents release have been known for a long time.
So beschreibt beispielsweise die EP 590 538 B1 eine klare, nach der Anwendung auf dem Haar verbleibende Zusammensetzung zur Pflege desselben, die in einer transparenten Gelgrundlage Mikrokapseln enthält, in denen ein haarkonditionierendes Material verkapselt ist, und die beim Aufbringen auf das Haar aufbrechen und das konditionierende Mittel freigeben. Nachteilig dabei ist, daß eine gleichmaßige Verteilung nicht erfolgt und Kapselwandrückstände im Haar verbleiben.For example, EP 590 538 B1 describes a clear, after application on the Hair remaining composition to care for the same, in a transparent Gel base contains microcapsules in which a hair conditioning material is encapsulated and which break open when applied to the hair and the conditioning agent release. The disadvantage here is that there is no uniform distribution and Capsule wall residues remain in the hair.
Die Erfindung geht daher von der Aufgabenstellung aus, sichtbare Mikroteilchen, deren durchschnittlicher Teilchendurchmesser bei etwa 0,1 bis 4 mm liegt, enthaltende kosmetische Mittel, insbesondere Haarpflegemittel, zu schaffen, die bei der Abgabe des Produktes keinerlei Rückstände auf dem Substrat, d.h. dem Haar oder der Haut hinterlassen, sondern vollständig und gleichmäßig in der Grundlage verteilt sind.The invention is therefore based on the task, visible microparticles, the average particle diameter is about 0.1 to 4 mm, containing cosmetic Means, especially hair care products, to create when dispensing the product no residues on the substrate, i.e. to the hair or skin, but are completely and evenly distributed in the base.
Diese Aufgabe wird erfindungsgemäß dadurch gelöst, daß diese Mikroteilchen enthaltenden Mittel in einer Verpackung untergebracht sind, die einen nach oben beweglichen Kolben und einen Verschlußkopf aufweist, der mit dem Körper durch ein Ventil verbunden ist, und in seinem Innern einen elastischen Balg besitzt, der an seinem unteren Ende mit dem Ventil verbunden ist und an seinem oberen Ende in ein Abgaberohr mündet, das in einer mit einer Membran versehenden Ausgabeöffnung endet. This object is achieved in that they contain microparticles Means are housed in a package which has an upwardly movable piston and has a closure head which is connected to the body by a valve, and in inside it has an elastic bellows, which at its lower end with the valve is connected and at its upper end opens into a delivery tube, which in one with a Diaphragm-provided discharge opening ends.
Bei der Abgabe des Mittels durch Druck auf den Verschlußkopf, weitergegeben durch den elastischen Balg, bewegt sich der Kolben nach oben und drückt das fließfähige Produkt durch das Ventil in das Abgaberohr und schließlich über die mit der Membran versehene Ausgabeöffnung nach außen, wobei die im fließfähigen Produkt enthaltenen Mikroteilchen zerstört und deren Inhalt vollständig im restlichen Produkt integriert wird.When dispensing the agent by pressure on the closure head, passed on by the elastic bellows, the piston moves upwards and pushes the flowable product through the valve into the delivery tube and finally over the membrane Dispensing opening to the outside, the microparticles contained in the flowable product destroyed and their content is fully integrated into the rest of the product.
Vorzugsweise besteht der insbesondere zylindrische oder ovale Verpackungskörper aus transparentem oder transluzenten Material, z.B. Polyethylen, Polypropylen oder Polyacetal, so daß die Mikroteilchen vom Verbraucher wahrgenommen werden können.The in particular cylindrical or oval packaging body preferably consists of transparent or translucent material, e.g. Polyethylene, polypropylene or polyacetal, see above that the microparticles can be perceived by the consumer.
Bei den Mikroteilchen handelt es sich nicht nur um Mikrokapseln; es können auch Wachsteilchen und sonstige Teilchen, vorzugsweise solche, die ein aktives Material enthalten, verwendet werden.The microparticles are not just microcapsules; it can too Wax particles and other particles, preferably those containing an active material, be used.
Auch Mikrokapseln, die nicht die klassische Zusammensetzung aus Hülle (Kapselwand) und Inhalt aufweisen, sondern eine durchgehend homogene Zusammensetzung aufweisen, können eingesetzt werden.Also microcapsules that do not have the classic composition of shell (capsule wall) and Have content, but have a consistently homogeneous composition be used.
Die Mikroverkapselung verschiedener Stoffe ist allgemeines Fachwissen und auch bei P. Deasy, Manuf. Chemist, Vol. 54/No. 7 (1984), S. 47, in den Monographien von M. Gutcho, Capsule Technology and Microencapsulation (1972) und J.R. Nixon, Microencapsulation, Vol. 3 of Drugs & Pharmaceutical Science (Marcel Dekker, Inc.) sowie in Seifen-Öle-Fette-Wachse, Vol 106 (1980), S. 271-272 und Vol. 114 (1989), S. 94-95, und in der dort zitierten Literatur beschrieben, auf die Bezug genommen wird.The microencapsulation of various substances is general specialist knowledge and also with P. Deasy, Manuf. Chemist, vol. 54 / no. 7 (1984), p. 47, in the monographs by M. Gutcho, Capsule Technology and Microencapsulation (1972) and J.R. Nixon, microencapsulation, Vol. 3 of Drugs & Pharmaceutical Science (Marcel Dekker, Inc.) as well as in soap-oil-fat waxes, Vol 106 (1980), pp. 271-272 and Vol. 114 (1989), pp. 94-95, and in the cited therein Described literature to which reference is made.
Derartige Zusammensetzungen sind an sich bekannt, neben der bereits erwähnten EP 590 538 B1 wird beispielsweise auf die US-A 4 126 174, die US-A 5 082 661, und die EP-A 261 754 und die DE-C 1 268 316 verwiesen.Such compositions are known per se, in addition to EP 590 538, already mentioned B1 is referred to, for example, US-A 4 126 174, US-A 5 082 661, and EP-A 261 754 and referred to DE-C 1 268 316.
Bei den erfindungsgemäß abzugebenden fließfähigen kosmetischen Mitteln handelt es sich vorzugsweise um Haarpflegemittel, insbesondere transparente oder transluzente Gele wie Haarwasch- und -spülmittel, Haarkuren, Konditioner, sogenannte Leave on-Produkte, die nach der Applikation auf dem Haar verbleiben, Antifett- und Antischuppenpräparate, etc. The flowable cosmetic agents to be dispensed according to the invention are preferably around hair care products, in particular transparent or translucent gels such as Hair washing and rinsing agents, hair treatments, conditioners, so-called leave-on products the application remains on the hair, anti-grease and anti-dandruff preparations, etc.
Deren Zusammensetzungen sind aus dem Stand der Technik bekannt, beispielsweise aus der Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Aufl. (1989, Hüthig Buch Verlag), S. 676-771. Es wird deshalb auf eine ausführliche Aufzählung aller möglichen Bestandteile verzichtet.Their compositions are known from the prior art, for example from Monograph by K. Schrader, basics and formulations of cosmetics, 2nd ed. (1989, Hüthig Buch Verlag), pp. 676-771. It is therefore based on a detailed list of all possible components waived.
Bevorzugt sind, wie bereits ausgeführt, transparente bzw. transluzente Gele. Solche enthalten in wäßriger Grundlage üblicherweise etwa 0,1 bis 2,5, insbesondere etwa 0,25 bis 1,5 Gew.-% eines Verdickungs- und Suspendierhilfsmittels, beispielsweise Hydroxyalkylcellulosen wie Hydroxyethylcellulose oder Hydroxypropylmethylcellulose, Guar Gum, Xanthan Gum, Polyvinylpyrrolidon und Polyacrylsäuresalze.As already stated, transparent or translucent gels are preferred. These usually contain about 0.1 to 2.5, in particular about, in an aqueous basis 0.25 to 1.5% by weight of a thickening and suspending aid, for example Hydroxyalkyl celluloses such as hydroxyethyl cellulose or hydroxypropyl methyl cellulose, guar Gum, xanthan gum, polyvinyl pyrrolidone and polyacrylic acid salts.
Die Viskosität dieser Grundlage liegt beispielsweise zwischen etwa 1000 und etwa 100 000, insbesondere 2500 bis 75000, vorzugsweise 5000 bis 50 000 mPa.s bei 20°C, gemessen im Brookfield-Viskosimeter (Spindel Nr. 5) bei rpm.The viscosity of this base is, for example, between approximately 1000 and approximately 100,000, in particular 2500 to 75000, preferably 5000 to 50,000 mPa.s at 20 ° C, measured in Brookfield viscometer (spindle no. 5) at rpm.
Für Shampoos liegt die Viskosität natürlich niedriger als für Leave-on-Produkte; dem
Fachmann sind die zweckmäßigen Werte und deren Einstellung für den jeweiligen Produkttyp
bekannt.
Die Mikroteilchen können ganz oder teilweise aus Wirkstoffen bestehen.The viscosity of shampoos is of course lower than for leave-on products; the person skilled in the art knows the appropriate values and their setting for the respective product type.
The microparticles can consist entirely or partially of active ingredients.
Bei Haarpflegemitteln kommen dabei vorzugsweise haarkonditionierende Substanzen in Betracht, beispielsweise Wachse mit einem Schmelzpunkt von weniger als 70°C, vorzugsweise weniger als 50°C.In hair care products, hair conditioning substances are preferred Consider, for example, waxes with a melting point of less than 70 ° C, preferably less than 50 ° C.
Wenn es sich um echte Mikrokapseln, d.h. Mikroteilchen, die aus einer Hülle und einem darin einschlossenen konditionierenden Material, das beim Zerstören des Wandmaterials frei wird, handelt, können praktisch alle konditionierenden Wirkstoffe verwendet werden.When it comes to real microcapsules, i.e. Microparticles made up of a shell and one inside included conditioning material that is released when the wall material is destroyed, acts, practically all conditioning agents can be used.
Solche sind beispielsweise synthetische und natürliche Fette und Öle sowie Fettalkohole und Fettsäureester. Such are, for example, synthetic and natural fats and oils as well as fatty alcohols and Fatty acid esters.
Geeignete Fette und Öle, zu denen auch Wachse zählen, sind insbesondere natürliche pflanzliche Öle wie Avocadoöl, Cocosöl, Palmöl, Sesamöl, Erdnußöl, Spermöl, Sonnenblumenöl, Mandelöl, Pfirsichkernöl, Weizenkeimöl, Macadamianußöl, Nachtkerzenöl, Jojobaöl, Ricinusöl oder auch Oliven- bzw. Sojaöl, Lanolin und dessen Derivate, ebenso Mineralöle wie Paraffinöl und Vaseline.Suitable fats and oils, including waxes, are especially natural vegetable oils such as avocado oil, coconut oil, palm oil, sesame oil, peanut oil, sperm oil, Sunflower oil, almond oil, peach seed oil, wheat germ oil, macadamia nut oil, evening primrose oil, Jojoba oil, castor oil or also olive or soybean oil, lanolin and its derivatives, as well Mineral oils such as paraffin oil and petroleum jelly.
Synthetische Öle und Wachse sind insbesondere Silikonöle, wie die bekannten Polysiloxane,
Polyethylenglykole, etc.
Natürliche Wachse sind beispielsweise niedrigschmelzende Paraffinwachse, Orangenwachs,
Apfelwachs, etc.
Weitere geeignete konditionierende Komponenten sind Fettalkohole, vorzugsweise solche mit
etwa 8 bis 22 Kohlenstoffatomen im Molekül wie Myristyl-, Cetyl-, Stearylalkohol,
Wachsalkohole und Fettsäureester wie Isopropylmyristat, -palmitat, -stearat und -isostearat,
Oleyloleat, Isocetylstearat, Hexyllaurat, Dibutyladipat, Dioctyladipat, Myristylmyristat,
Oleylerucat, Polyethylenglykol- und Polyglycerylfettsäureester wie PEG-7-glycerylcocoat,
Cetylpalmitat, etc.
Selbstverständlich können auch synthetische und natürliche polymere konditionierende Stoffe
als oder in den Mikroteilchen eingesetzt werden.
Diese sind bekannt und bedürfen daher keiner weiteren Aufzählung.
Wie bereits eingangs festgestellt, ist die Mikroverkapselung solcher Stoffe an sich bekannt
und bedarf deshalb ebenfalls keiner weiteren Erläuterung.
Es wird hierzu, beispielhaft, auf die Ausführungen in der bereits erwähnten EP 590 538 B1
verwiesen.
Der bevorzugte mittlere Teilchendurchmesser der Mikroteilchen liegt zwischen etwa 0,5 und
2,5 mm, insbesondere bei 0,75 bis 2 mm.
Sie stehen vorzugsweise in farblichem Kontrast zu der wäßrigen Grundlage, so daß sie für den
Veraucher in der Verpackung sichtbar sind und einen optischen Anreiz ausüben. Synthetic oils and waxes are, in particular, silicone oils, such as the known polysiloxanes, polyethylene glycols, etc.
Natural waxes are, for example, low-melting paraffin waxes, orange wax, apple wax, etc.
Other suitable conditioning components are fatty alcohols, preferably those with about 8 to 22 carbon atoms in the molecule, such as myristyl, cetyl, stearyl alcohol, wax alcohols and fatty acid esters such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adate, dibutyl adate, dibutyl adate, dibutyl adate , Myristyl myristate, olerlerucate, polyethylene glycol and polyglyceryl fatty acid esters such as PEG-7 glyceryl cocoate, cetyl palmitate, etc.
Of course, synthetic and natural polymeric conditioning substances can also be used as or in the microparticles.
These are known and therefore do not require any further listing.
As already stated at the beginning, the microencapsulation of such substances is known per se and therefore does not require any further explanation.
For this purpose, reference is made, for example, to the explanations in EP 590 538 B1 already mentioned.
The preferred average particle diameter of the microparticles is between approximately 0.5 and 2.5 mm, in particular 0.75 to 2 mm.
They are preferably in a color contrast to the aqueous base, so that they are visible to the user in the packaging and have a visual appeal.
Falls es sich bei der erfindungsgemäß abgepackten bzw. abzugebenden fließfähigen Zusammensetzung um ein Hautpflegemittel handelt, ist dieses vorzugsweise eine gegebenenfalls transparente oder transluzente Öl-in-Wasser- oder Wasser-in-Öl-Emulsion, jedoch ist auch die Verwendung einer gelförmigen Grundlage, beispielsweise in Form einer Mikroemulsion, möglich.If it is in the flowable packaged or to be dispensed according to the invention Composition is a skin care product, this is preferably one optionally transparent or translucent oil-in-water or water-in-oil emulsion, however, the use of a gel-like base, for example in the form of a Microemulsion, possible.
Entsprechende Hautpflegemittel sind beispielsweise bei Schrader, l.c., S. 387-538 und 583-592 beschrieben.Corresponding skin care products are for example from Schrader, I.C., pp. 387-538 and 583-592 described.
Weitere beispielhafte fließfähige kosmetische Mittel sind Rasiercremes, Zahnpasten, insbesondere transparente gelförmige Zahnpasten mit eingekapselten Wirkstoffen, Gesichtsmasken, Körperdesodorantien und Antiperspiramtien, etc. Further exemplary flowable cosmetic agents are shaving creams, toothpastes, in particular transparent gel-shaped toothpastes with encapsulated active ingredients, Face masks, body deodorants and antiperspirants, etc.
Die folgenden Ausführungsbeispiele illustrieren die Erfindung.The following exemplary embodiments illustrate the invention.
Ein gelförmiges, transparentes Haarbehandlungsmittel der folgenden Zusammensetzung wurde in einen aus transparentem Polyethylen bestehenden zylindrischen Behälter nach Figur 1 eingebracht.A gel-shaped, transparent hair treatment composition of the following composition was placed in a cylindrical container made of transparent polyethylene according to FIG. 1.
Bei der Abgabe wurde ein schwach rosa gefärbtes Produkt, das keine Mikroteilchen mehr enthielt, erhalten, das sich rückstandsfrei auf menschlichem Haar verteilen ließ.Upon delivery, a pale pink product was removed that no longer contains microparticles contained, obtained, which could be distributed without residue on human hair.
Der Verpackungsbehälter nach Figur 1 ist durch das im folgenden beschriebene Prinzip
gekennzeichnet:
Beim Niederdrücken des Verschlußkopfes wird das im Innenraum des zylindrischen Behälters befindliche Produkt durch die Aufwärtsbewegung des Kolbens, bewirkt über den elastischen Balg, über das Ventil und das Ausgaberohr durch die mit der Membran versehene Abgabeöffnung gedrückt, wobei die Mikrokapseln restlos zerstört werden und deren Inhalt homogen im Produkt verteilt wird. When the closure head is pressed down, this becomes in the interior of the cylindrical container located product by the upward movement of the piston, caused by the elastic Bellows, over the valve and the discharge pipe through the membrane Dispensing opening pressed, the microcapsules are completely destroyed and their contents is distributed homogeneously in the product.
Bei der Abgabe des Produktes aus einer transluzenten Polypropylenverpackung entsprechend Figur 1 wurde ein leicht blau gefärbtes, keine Einzelpartikel mehr enthaltendes Styling-Produkt erhalten.When delivering the product from a translucent polypropylene packaging accordingly Figure 1 was a slightly blue colored styling product no longer containing individual particles receive.
Claims (2)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19738245A DE19738245C2 (en) | 1997-09-02 | 1997-09-02 | Use of a packaging for dispensing a flowable cosmetic product |
DE19738245 | 1997-09-02 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0900598A2 true EP0900598A2 (en) | 1999-03-10 |
EP0900598A3 EP0900598A3 (en) | 1999-04-07 |
EP0900598B1 EP0900598B1 (en) | 2001-02-14 |
Family
ID=7840902
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98116361A Expired - Lifetime EP0900598B1 (en) | 1997-09-02 | 1998-08-28 | Use of a package for dispensing a fluid cosmetic material |
Country Status (3)
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---|---|
EP (1) | EP0900598B1 (en) |
AT (1) | ATE199129T1 (en) |
DE (2) | DE19738245C2 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000007901A1 (en) * | 1998-08-03 | 2000-02-17 | Veresk Biosystems Ltd. | Container valve |
WO2001005358A1 (en) * | 1999-07-16 | 2001-01-25 | Wella Aktiengesellschaft | Encapsulated hair conditioner containing fragrances or active substances and provided in gel form |
FR2797854A1 (en) * | 1999-08-27 | 2001-03-02 | Menarini France | Container for dispensing pharmaceutical substance in gel form comprises cylindrical body with piston in base and two valves |
FR2799993A1 (en) * | 1999-10-22 | 2001-04-27 | Bath & Body Works Inc | VAPORIZER CONTAINING PEARL-LIKE DROPLETS |
FR2945524A1 (en) * | 2009-05-14 | 2010-11-19 | Lrs | Product e.g. pharmaceutical formulation cream, storing and recovering device, has manual recovering unit i.e. pump, for destroying separation unit at time of expulsion to recover ingredient from medium |
WO2015169456A1 (en) * | 2014-05-06 | 2015-11-12 | Beiersdorf Ag | Cosmetic product |
CN110712849A (en) * | 2018-07-12 | 2020-01-21 | 上海艾鲲新材料科技有限公司 | All-round push type toothpaste tube |
EP2942047B1 (en) * | 2014-05-06 | 2020-09-02 | Beiersdorf AG | Cosmetic product |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE20307819U1 (en) | 2003-05-20 | 2003-08-14 | Lindal Ventil Gmbh | dispenser assembly |
FR2921050A1 (en) | 2007-09-13 | 2009-03-20 | Oreal | DISPENSER PUMP FOR A PRODUCT STORAGE AND DISPENSING CONTAINER AND CONTAINER COMPRISING SUCH A PUMP |
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EP0560060A1 (en) * | 1992-03-12 | 1993-09-15 | Raimund Andris GmbH & Co. KG | Meterung pump made of plastics for pasty material |
DE29506682U1 (en) * | 1995-04-19 | 1995-06-29 | Megaplast Dosiersysteme GmbH, 78052 Villingen-Schwenningen | Dispensing pump made of plastic for pasty materials |
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US3393963A (en) * | 1966-02-07 | 1968-07-23 | Nadai Alexander | Liquid dispensing applicator insert |
DE1268316B (en) * | 1967-09-19 | 1968-05-16 | Schwarzkopf Fa Hans | Shampoos |
GB2192404B (en) * | 1986-07-09 | 1990-08-01 | Scherer Ltd R P | Encapsulated products |
DE3928524C2 (en) * | 1989-08-29 | 1994-02-24 | Megaplast Dosiersysteme | donor |
US5082661A (en) * | 1990-09-26 | 1992-01-21 | Elizabeth Arden Co., Division Of Conopco, Inc. | Odorless cosmetic compositions in gelatin capsules |
DE4035922A1 (en) * | 1990-11-12 | 1992-05-14 | Megaplast Dosiersysteme | Dispenser for paste substances - has automatic closure element sealing outlet opening from inside |
DE4206524C2 (en) * | 1992-03-02 | 1997-04-24 | Andris Raimund Gmbh & Co Kg | Dosing pump for viscous, especially paste-like substances |
US6048520A (en) * | 1992-09-24 | 2000-04-11 | Helene Curtis, Inc. | Clear leave-on hair treatment composition and method |
-
1997
- 1997-09-02 DE DE19738245A patent/DE19738245C2/en not_active Expired - Fee Related
-
1998
- 1998-08-28 EP EP98116361A patent/EP0900598B1/en not_active Expired - Lifetime
- 1998-08-28 AT AT98116361T patent/ATE199129T1/en not_active IP Right Cessation
- 1998-08-28 DE DE59800471T patent/DE59800471D1/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2660212A1 (en) * | 1990-03-30 | 1991-10-04 | Toyo Kasei Co Ltd | Process for the preparation of an emulsion and emulsifiable composition |
EP0560060A1 (en) * | 1992-03-12 | 1993-09-15 | Raimund Andris GmbH & Co. KG | Meterung pump made of plastics for pasty material |
DE29506682U1 (en) * | 1995-04-19 | 1995-06-29 | Megaplast Dosiersysteme GmbH, 78052 Villingen-Schwenningen | Dispensing pump made of plastic for pasty materials |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000007901A1 (en) * | 1998-08-03 | 2000-02-17 | Veresk Biosystems Ltd. | Container valve |
WO2001005358A1 (en) * | 1999-07-16 | 2001-01-25 | Wella Aktiengesellschaft | Encapsulated hair conditioner containing fragrances or active substances and provided in gel form |
FR2797854A1 (en) * | 1999-08-27 | 2001-03-02 | Menarini France | Container for dispensing pharmaceutical substance in gel form comprises cylindrical body with piston in base and two valves |
FR2799993A1 (en) * | 1999-10-22 | 2001-04-27 | Bath & Body Works Inc | VAPORIZER CONTAINING PEARL-LIKE DROPLETS |
FR2945524A1 (en) * | 2009-05-14 | 2010-11-19 | Lrs | Product e.g. pharmaceutical formulation cream, storing and recovering device, has manual recovering unit i.e. pump, for destroying separation unit at time of expulsion to recover ingredient from medium |
WO2015169456A1 (en) * | 2014-05-06 | 2015-11-12 | Beiersdorf Ag | Cosmetic product |
CN106456458A (en) * | 2014-05-06 | 2017-02-22 | 拜尔斯道夫股份有限公司 | Cosmetic product |
CN106456458B (en) * | 2014-05-06 | 2019-11-26 | 拜尔斯道夫股份有限公司 | Cosmetic product |
AU2015258135B2 (en) * | 2014-05-06 | 2020-01-16 | Beiersdorf Ag | Cosmetic product |
EP2942047B1 (en) * | 2014-05-06 | 2020-09-02 | Beiersdorf AG | Cosmetic product |
CN110712849A (en) * | 2018-07-12 | 2020-01-21 | 上海艾鲲新材料科技有限公司 | All-round push type toothpaste tube |
Also Published As
Publication number | Publication date |
---|---|
EP0900598A3 (en) | 1999-04-07 |
DE59800471D1 (en) | 2001-03-22 |
DE19738245A1 (en) | 1999-03-04 |
DE19738245C2 (en) | 1999-10-14 |
EP0900598B1 (en) | 2001-02-14 |
ATE199129T1 (en) | 2001-02-15 |
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