EP0899052A1 - Method of manufacturing filled wire with recrystallization anneal - Google Patents

Abstract

A filled metallic tube production process involves recrystallization annealing by h. f. induction heating at a frequency of ≥ 10 kHz. Independent claims are also included for (i) a core-filed wire made by the above process; and (ii) a TIG, MIG, MAG, submerged arc or vertical electroslag welding process employing the above core-filled wire. Preferred Features: The recrystallization anneal is carried out after rolling or drawing of a mild steel tube filled with iron, ferrosilicon, silico-manganese, manganese, ferrosilicon-titanium, magnesium and/or aluminum powder.

Description

The present invention relates to the field of manufacture of welded, filled metal tubes filling elements, such as cored wires intended welding, using one or more stages of high frequency recrystallization annealing.

Conventionally, when one wishes to reduce the diameter of a metal tube containing or not containing filling elements, such as a cored welding wire, subjects said metal tube to one or more stages of rolling and / or drawing thereof.

However, it is also known that the reduction diameter by rolling and / or drawing a tube metallic generates the metallurgical phenomenon hardening.

However, when the rate of work hardening increases, that is to say when the overall reduction rate of the tube increases, there is an increase in the hardness of the material and a decrease in its ability to undergo deformations without break.

In other words, there is a certain threshold or critical reduction rate beyond which appear tube rupture problems.

Currently, to be able to continue rolling and / or the drawing of the tube beyond this threshold or rate critical, we regenerate the material structure by performing a recrystallization annealing thereof.

To this end, the material is heated of the tube, at a temperature higher than the temperature called recrystallization.

This recrystallization temperature depends on the nature of the material constituting the metal tube.

Thus, it is around 600 ° C for a steel mild and around 750 ° C for stainless steel austenitic, for example.

Usually this annealing operation recrystallization is carried out in a static furnace or in a passage oven.

The holding time above the temperature of recrystallization takes a few hours (for an oven static) to a few minutes (for a pass-through oven).

However, it has been observed that when we subjected such recrystallization annealing from a metal tube filled with filling elements, such as a cored wire, it undesirable chemical reactions occur between minus some of the different constituents contained in the filling elements.

Thus, the rutile type flux-cored welding wires generally contain filling elements made up of a mixture of iron powders and ferroalloys which, combined with the shell of the flux-cored wire, gives the weld a suitable chemical composition. at the desired mechanical strength, ionizing elements making it possible to improve the stability of the electric arc, oxides, such as TiO ₂ , Al ₂ O ₃ or SiO ₂ , intended to form a slag whose physical properties, in particular of temperature of melting, viscosity and surface tension, are at the origin of the operating qualities of this type of cored wire, and powerful deoxidizers, such as Mg, Al or AlMg, which make it possible to lower the oxygen content of the molten metal deposited in thus improving the toughness properties of the weld.

However, if such a powder mixture is brought to high temperature, for example at 700 ° C, during a envelope recrystallization annealing treatment external of the tube containing it, reactions occur more or less complete redox between the various constituents of the filling powder, which are likely to make the yarn unfit for its intended purpose.

The aim of the present invention is therefore to propose a process making it possible to obtain an annealing of efficient recrystallization of a metal tube containing filling elements, such as a wire filled with welding, which process generates little or no alteration of the filling elements contained by said tube.

The invention therefore relates to a manufacturing process of a metal tube containing elements of filling, comprising at least one step of annealing recrystallization carried out by induction heating at high frequency.

• la fréquence est d'au moins 10 kHz, de préférence d'au moins 100 kHz, et avantageusement entre 250 kHz et 500 kHz environ;
• au moins une étape de recuit de recristallisation est réalisée subséquemment à au moins une étape de réduction du diamètre du tube par laminage et/ou tréfilage;
• il comprend, subséquemment à une étape de recuit de recristallisation, au moins une étape de refroidissement du tube;
• la température de recristallisation est supérieure ou égale à 700°C, de préférence supérieure ou égale à 750°C;
• les éléments de remplissage du tube comprennent au moins une poudre métallique choisie parmi les poudres de fer, de ferro-silicium, de silico-manganèse, de manganèse, de ferro-silico-titane, de magnésium, d'aluminium et leurs mélanges.
• le tube métallique est un fil fourré.

Depending on the case, the method of the invention may include one or more of the following characteristics:

• the frequency is at least 10 kHz, preferably at least 100 kHz, and advantageously between 250 kHz and 500 kHz approximately;
• at least one recrystallization annealing step is carried out subsequent to at least one step of reducing the diameter of the tube by rolling and / or drawing;
• it comprises, subsequent to a recrystallization annealing step, at least one step of cooling the tube;
• the recrystallization temperature is greater than or equal to 700 ° C, preferably greater than or equal to 750 ° C;
• the filling elements of the tube comprise at least one metal powder chosen from powders of iron, ferro-silicon, silico-manganese, manganese, ferro-silico-titanium, magnesium, aluminum and their mixtures.
• the metal tube is a cored wire.

The invention also relates to a cored wire. likely to be obtained by the aforementioned process, which cored wire may include an envelope metallic in mild steel.

Such cored wire is likely to be used for the implementation of a welding process, such as a TIG, MIG, MAG, submerged arc welding process and vertical under slag.

Specifically, the inventors of this invention have demonstrated that the regeneration of the tubular casing, that is to say the annealing of recrystallization, can be carried out effectively by heating the tube having undergone one or more drawing and / or rolling steps using a high frequency inductor and that by proceeding from the sort, the alteration of the filling elements or powder contained by said tube is almost zero or minimal.

• µ = µ₀. µ_r est la perméabilité (en H.m^-1) magnétique du matériau (ici de l'enveloppe du tube);
• µ ₀ est la perméabilité magnétique du vide (4π.10^-7 H.m^-1);
• µr est la perméabilité relative du matériau;
• ρ est la résistivité du matériau (en Ω.m);
• et f est la fréquence du courant d'induction (en Hz).

Indeed, the depth of penetration of high frequency currents also called "skin" thickness is defined by the following formula: - δ = ρ π µf ≅ 500 ρ µ r f in which:

• µ = µ ₀ . µ _r is the magnetic permeability (in Hm ^-1 ) of the material (here of the envelope of the tube);
• µ ₀ is the magnetic permeability of the vacuum (4π.10 ^-7 Hm ^-1 );
• µr is the relative permeability of the material;
• ρ is the resistivity of the material (in Ω.m);
• and f is the frequency of the induction current (in Hz).

However, about 87% of the heating energy per effect Joule, is released, in this thickness of skin, by induced current.

From there, for a given material, the depth of penetration is therefore inversely proportional to the square root of the frequency of the current in the inductor.

In the case of steels, the penetration depth is also a function of temperature since the magnetic permeability depends on it.

For example, the penetration depth of high frequency currents is 0.7 mm at temperature ambient (around 20 ° C) and 17 mm at 1000 ° C for a frequency of 1 kHz, whereas, for the same temperatures, it is respectively 0.22 mm and 5.4 mm for a frequency of 10 kHz, and 0.04 mm and 1.1 mm for a frequency of 250 kHz.

As part of the production of cored wires intended for welding, recrystallization annealing is generally performed when the diameter of the cored wire is of the order of 4 mm, that is to say for a thickness of the tubular casing on the order of 1.1 mm on average.

In view of the above, to minimize the heating of the filling elements contained in the cored wire and to avoid or minimize reactions chemicals of the various constituents between them, so do not heat only on the external part of the tubular casing using a frequency sufficiently high, that is to say at least 1 kHz; the rest of tubular casing being heated essentially by thermal conduction above the recrystallization temperature.

In other words, the inventors of this invention have demonstrated that by proceeding from the so the rise in temperature of the elements of filling in the cored wire is insufficient to cause unwanted chemical reactions between the various constituents of said elements of filling.

The invention will now be described in more detail. detail using examples given for illustrative purposes but not limiting.

Examples

The following tests were carried out with different types of cored wires intended for welding steels construction, which include a steel casing mild with a carbon content of about 0.04%.

Recrystallization annealing is carried out on drawn and / or rolled wires up to diameters of 4 mm and 4.7 mm, as the case may be, and at frequencies of 250 and 500 kHz; the power in the inductors being adjusted by so as to reach different surface temperatures cored wires.

Subsequent to the annealing step of recrystallization, the cored wires are subjected to a cooling is natural at room temperature, either by spraying water.

After these different treatments, the samples are taken to measure its hardness and examine by metallography if the recrystallization has actually occurred.

The results obtained are reported in Table I below. TYPE OF FURNISHED WIRE TEMPERATURE (in ° C) COOLING Recrystallization VICKERS HARDNESS "dairy free" 600 natural No nd water No nd 670 natural No 202 water No 207 750 natural Yes 110 water Yes 160 800 natural Yes 110 water Yes 155 900 natural Yes 115 water Yes 177 Rutile 600 natural No nd water No nd 670 natural No 217 water No 220 750 natural Yes 116 water Yes 165 800 natural Yes 114 water Yes 188 900 natural Yes 117 water Yes 180 na: not determined

During the tests, similar results were whatever the diameter of the cored wire, the nature of the filling powders and the high frequency used.

However, as shown in the previous table, the temperature reached appears to have an influence important on the recrystallization of the envelope tubular.

Indeed, it appears that in these conditions of very fast heat treatment, it is necessary reach a higher temperature (at least 750 ° C) than during a conventional treatment in a passage oven or a static oven during which the temperature is not, generally only 600 ° C.

In addition, the hardness measurements show that when the temperature reached has allowed obtaining a recrystallization of the tubular envelope, the resulting softening, i.e. the difference in hardness between the non-recrystallized state and the state recrystallized, is very different depending on the mode of chosen cooling despite the very low carbon content of the tubular casing.

More specifically, the recrystallized cored wires and cooled by sprinkling with water retains a hardness relatively high, despite recrystallization, and could not be subsequently drawn until 1.2 mm diameter without breaking, while the wires thickets naturally cooled, i.e. by heat exchange with the ambient atmosphere, present lower hardness and could be drawn without failure up to audit diameter of 1.2 mm.

Such drawn wires with a diameter of 1.2 mm have been compared to cored wires having undergone a treatment of conventional recrystallization at 600 ° C for 1 hour in static oven and, on the other hand, with wires containing the same filling powders and manufactured according to the "Chemetron" process, which does not require intermediate heat treatment since, by this process, the wires are formed and filled with powder 5 mm diameter.

• les fils selon l'invention recuits par haute fréquence et refroidis de manière naturelle ont un comportement opératoire similaire aux fils non recuits obtenus par le procédé "Chemetron";
• les fils traités en four statique conduisent à des arcs électriques beaucoup moins stables et à un taux de projection très supérieur, donc à des qualités opératoires nettement moins bonnes que les fils selon l'invention, ce qui confirme l'existence du problème de réaction entre eux, des différents éléments constituants les éléments de remplissage du fil fourré, lorsque ceux-ci sont soumis à un recuit de recristallisation par un procédé classique.

It follows from these comparative tests that:

• the wires according to the invention annealed by high frequency and naturally cooled have an operating behavior similar to the non-annealed wires obtained by the "Chemetron"process;
• the wires treated in a static oven lead to much less stable electric arcs and to a much higher projection rate, therefore to significantly poorer operating qualities than the wires according to the invention, which confirms the existence of the reaction problem between them, different elements constituting the filling elements of the cored wire, when these are subjected to recrystallization annealing by a conventional process.

In other words, anneal high frequency recrystallization followed by sufficiently slow cooling allows effective recrystallization of the tubular envelope, that is to say, a regeneration thereof, allowing to subsequently subjecting said tube to stages of drawing and / or rolling without causing breakage and while ensuring the operational quality of the cored wire during its implementation in a welding process, since the properties of the elements of filling are not affected by treatment high recrystallization annealing thermal frequency.

According to the invention, frequencies higher than 100 kHz is preferred, for example frequencies between 250 and 500 kHz.

However, it is possible to use frequencies lower, but the minimum usable frequency does not should not be less than 10 kHz.

Indeed, by proceeding in this way, most of energy (87%) is released by the Joule effect in the quarter outside the tubular thickness, when the tube is at low temperature, reaching just over a third of thickness at 700 ° (due to the variation of magnetic permeability), then the entire thickness when the temperature reaches and exceeds the point of Curie (769 ° C for steels).

In addition, the differences observed in the material hardness depending on cooling mode chosen, after recrystallization annealing, can can be explained by the difference in speed of cooling implied by the two modes of chosen cooling (natural or water spray).

Indeed, when the cooling is "natural", it takes about 30 seconds for the cored wire goes from annealing temperature (above 700 ° C) to a temperature of the order of 400 ° C., while a cooling by spraying water leads to a duration cooling down to room temperature the order of the second.

Additional tests (tests 1 to 4) have shown as the final hardness (Vickers final hardness) after recrystallization and cooling down to the room temperature (TA) is, in fact, mainly conditioned by the duration of cooling between the recrystallization temperature (TR) and temperature about 400 ° C.

Thus, the test results given in Table II below show that industrially, it is advantageous to operate only natural cooling (calm air) or then slightly accelerated (by spraying water for example), from the annealing temperature (TR) up to around 400 ° C., then supplementing this cooling with additional cooling by spraying a cooling fluid, such as water, in order to obtain a temperature of the material substantially equal to the temperature (TA), and this by minimizing the length of "buffer" wire in the cooling loops. Test No. Transition from TR to 400 ° C Passage 400 ° C at RT Vickers final hardness MR Duration MR Duration 1 water <1 sec water <1 sec 165 2 calm air 30 sec calm air several minutes 115 3 supply air 10 to 15 sec supply air 1 min 140 4 calm air 30 sec water <1 sec 125 MR: cooling mode

It follows that, preferably, cooling of the tube includes at least one cooling step slow from about recrystallization temperature (TR) up to an intermediate temperature and, optionally, at least one cooling step fast from about the intermediate temperature up to room temperature (TA).

Advantageously, the slow cooling step has a duration of at least 10 seconds, preferably at least minus 20 seconds, and / or the cooling step rapid is achieved by means of a refrigerant and, preferably by spraying water.

Usually the intermediate temperature is between 300 ° C and 550 ° C, preferably of the order 400 ° C.

Advantageously, at least part of the step of induction and / or stage heating slow cooling is carried out under an inert atmosphere protection to avoid or minimize any surface oxidation of the tube.

The inert protective gas used is nitrogen, argon or a mixture of gases containing one to less of these two gases, or any other gas or mixture of gas known to those skilled in the art.

Claims (16)

Method of manufacturing a metal tube containing filling elements, comprising at least minus a recrystallization annealing step carried out by high frequency induction heating, said frequency being at least 10 kHz. Method according to claim 1, characterized in what the frequency is at least 100 kHz. Method according to one of claims 1 or 2, characterized in that the frequency is between 250 kHz and 500 kHz approximately. Method according to one of claims 1 to 3, characterized in that at least one step of annealing recrystallization is carried out subsequently at least a step of reducing the diameter of the tube by rolling and / or wire drawing Method according to one of claims 1 to 4, characterized in that it comprises, subsequent to a recrystallization annealing step, at least one step tube cooling. Method according to claim 5, characterized in that the tube cooling includes at least one slow cooling step since about the recrystallization temperature up to a temperature intermediate and possibly at least one step of fast cooling from about temperature intermediate to room temperature. Method according to claim 6, characterized in that the slow cooling step has a duration of at least at least 10 seconds, preferably at least 20 seconds, and / or in that the rapid cooling step is produced by means of a refrigerant and, preferably by spraying water. Method according to claim 6, characterized in what the intermediate temperature is between 300 ° C and 550 ° C, preferably of the order of 400 ° C. Method according to one of claims 1 to 8, characterized in that the recrystallization temperature is greater than or equal to 700 ° C, preferably greater or equal to 750 ° C. Method according to one of claims 1 to 9, characterized in that the filling elements of the tube include at least one powder chosen from powders iron, ferro-silicon, silico-manganese, manganese, ferro-silico-titanium, magnesium, aluminum and their mixtures. Process according to claims 1 to 10, characterized in that the metal tube is a wire thicket. Process according to claims 1 to 11, characterized in that at least part of the step of induction and / or stage heating slow cooling is carried out under an inert atmosphere protection. Cored wire likely to be obtained by the method according to one of claims 1 to 12. Cored wire according to claim 13, characterized in that it comprises a metallic envelope mild steel. Use of a cored wire according to one of the claims 13 or 14 for the implementation of a arc welding process. TIG, MIG, MAG, arc welding process submerged or vertical under slag likely to put using a cored wire according to one of claims 13 or 14.