EP0884377A2 - Liquefied petroleum gas composition - Google Patents
Liquefied petroleum gas composition Download PDFInfo
- Publication number
- EP0884377A2 EP0884377A2 EP98201892A EP98201892A EP0884377A2 EP 0884377 A2 EP0884377 A2 EP 0884377A2 EP 98201892 A EP98201892 A EP 98201892A EP 98201892 A EP98201892 A EP 98201892A EP 0884377 A2 EP0884377 A2 EP 0884377A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- petroleum gas
- liquefied petroleum
- composition
- denaturant
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/12—Liquefied petroleum gas
Definitions
- the present invention relates to liquefied petroleum gas which is a mixture of propane and butanes that can be liquefied under relatively low pressure and at ambient temperature.
- liquefied petroleum gas is for example used as lighter fuel and as aerosol propellant.
- the present invention relates in particular to deterring ingestion of liquefied petroleum gas by denaturating the liquefied petroleum gas.
- the liquefied petroleum gas composition according to the present invention comprises liquefied petroleum gas and a denaturant composition comprising denatonium benzoate dissolved in a low molecular weight alcohol.
- Denatonium benzoate the most bitter substance known to man, is a well known denaturant which is commercially available from McFarlan Smith Limited under the name Bitrex.
- the present invention is based on the finding that the denatonium benzoate is insoluble in liquefied petroleum gas because it is a polar substance. Applicant had found, however, that a composition comprising denatonium benzoate dissolved in a low molecular weight alcohol is soluble in liquefied petroleum gas.
- the term 'low molecular weight alcohol' is used to refer to an alcohol having an alkyl group with between 1 and 5 carbon atoms, and suitably between 1 and 3 carbon atoms.
- Suitable low molecular weight alcohols are methanol and isopropyl alcohol.
- the concentration of denatonium benzoate in the low molecular weight alcohol should not exceed 1 %m, and suitably the concentration is between 0.5 and 1 %m.
- the concentration of the denaturant composition in the liquefied petroleum gas composition suitably is not more than 1 000 ppmm, and more suitably between 500 and 1 000 ppmm.
- the concentration of denatonium benzoate in the low molecular weight alcohol is between 0.5 and 1 %m and the concentration of the denaturant composition is not more than 1 000 ppmm.
- the concentration of denatonium benzoate in the low molecular alcohol is expressed in %m, for example 1 %m corresponds to 1 g denatonium benzoate in 100 g alcohol.
- the concentration of denaturant composition in the liquefied petroleum gas composition is expressed in ppmm (parts per million based on mass), for example 1 000 ppmm of denaturant composition corresponds to 1 g of denaturant composition per kg of liquefied petroleum gas.
- composition A remained stable for 48 hours under more stringent temperature conditions between -20 and +40 °C.
- the denaturant composition of the present invention is soluble in liquefied petroleum gas, and that a stable solution can be prepared if the denaturant composition contains between 0.5 and 1 %m of denatonium benzoate.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Abstract
Description
Summary of the compositions used in the experiments and the results, DB refers to denatonium benzoate, MeOH refers to methanol, DC refers to denaturant composition and LPG refers to liquefied petroleum gas, and [X] means concentration of X. | ||
Composition A | Composition B | |
[DB] in MeOH | 1 %m | 2 %m |
[DC] in LPG | 1 000 ppmm | 500 ppmm |
[DB] in LPG | 10 ppmm | 10 ppmm |
Result | stable solution | unstable solution |
Claims (5)
- A liquefied petroleum gas composition comprising liquefied petroleum gas and a denaturant composition comprising denatonium benzoate dissolved in a low molecular weight alcohol.
- Liquefied petroleum gas composition as claimed in claim 1, wherein the low molecular weight alcohol is methanol or isopropyl alcohol.
- Liquefied petroleum gas composition as claimed in claim 1 or 2, wherein the concentration of denatonium benzoate in the low molecular weight alcohol is between 0.5 and 1 %m.
- Liquefied petroleum gas composition according to any one of the claims 1-3, wherein the concentration of the denaturant composition is not more than 1 000 ppmm.
- Liquefied petroleum gas composition as claimed in claim 1 or 2, wherein the concentration of denatonium benzoate in the low molecular weight alcohol is between 0.5 and 1 %m, and wherein the concentration of the denaturant composition is not more than 1 000 ppmm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP19980201892 EP0884377B1 (en) | 1997-06-09 | 1998-06-08 | Liquefied petroleum gas composition |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97303961 | 1997-06-09 | ||
EP97303961 | 1997-06-09 | ||
EP19980201892 EP0884377B1 (en) | 1997-06-09 | 1998-06-08 | Liquefied petroleum gas composition |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0884377A2 true EP0884377A2 (en) | 1998-12-16 |
EP0884377A3 EP0884377A3 (en) | 1999-06-02 |
EP0884377B1 EP0884377B1 (en) | 2004-03-17 |
Family
ID=8229361
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19980201892 Expired - Lifetime EP0884377B1 (en) | 1997-06-09 | 1998-06-08 | Liquefied petroleum gas composition |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0884377B1 (en) |
DE (1) | DE69822367T2 (en) |
ES (1) | ES2217498T3 (en) |
PL (1) | PL187600B1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999060077A1 (en) * | 1998-05-15 | 1999-11-25 | Macfarlan Smith Limited | Hydrocarbon liquid formulation |
WO2004024849A1 (en) * | 2002-09-13 | 2004-03-25 | Dometic Ag | Fuel composition |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2581732A (en) | 2017-11-27 | 2020-08-26 | Chemours Co Fc Llc | Aerosol compositions |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4844713A (en) * | 1987-07-05 | 1989-07-04 | Fragrant Liquefied Butane Gas Producing Company | Fragrant liquefied petroleum gas composition and the method of preparing the same |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2668420B2 (en) * | 1988-11-07 | 1997-10-27 | 新高化学工業株式会社 | Solid fuel with accidental eating prevention performance |
-
1998
- 1998-06-05 PL PL98326693A patent/PL187600B1/en not_active IP Right Cessation
- 1998-06-08 DE DE1998622367 patent/DE69822367T2/en not_active Expired - Fee Related
- 1998-06-08 ES ES98201892T patent/ES2217498T3/en not_active Expired - Lifetime
- 1998-06-08 EP EP19980201892 patent/EP0884377B1/en not_active Expired - Lifetime
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4844713A (en) * | 1987-07-05 | 1989-07-04 | Fragrant Liquefied Butane Gas Producing Company | Fragrant liquefied petroleum gas composition and the method of preparing the same |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Section Ch, Week 9026 Derwent Publications Ltd., London, GB; Class A95, AN 90-196131 XP002099312 & JP 02 127496 A (SHIN-KO KAGAKU KOGY) , 16 May 1990 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999060077A1 (en) * | 1998-05-15 | 1999-11-25 | Macfarlan Smith Limited | Hydrocarbon liquid formulation |
WO2004024849A1 (en) * | 2002-09-13 | 2004-03-25 | Dometic Ag | Fuel composition |
Also Published As
Publication number | Publication date |
---|---|
DE69822367D1 (en) | 2004-04-22 |
EP0884377B1 (en) | 2004-03-17 |
EP0884377A3 (en) | 1999-06-02 |
ES2217498T3 (en) | 2004-11-01 |
PL326693A1 (en) | 1998-12-21 |
DE69822367T2 (en) | 2005-02-17 |
PL187600B1 (en) | 2004-08-31 |
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