EP0862491A1 - A filter member - Google Patents

A filter member

Info

Publication number
EP0862491A1
EP0862491A1 EP97929539A EP97929539A EP0862491A1 EP 0862491 A1 EP0862491 A1 EP 0862491A1 EP 97929539 A EP97929539 A EP 97929539A EP 97929539 A EP97929539 A EP 97929539A EP 0862491 A1 EP0862491 A1 EP 0862491A1
Authority
EP
European Patent Office
Prior art keywords
filter member
membrane
spot
bondings
member according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97929539A
Other languages
German (de)
French (fr)
Inventor
Masakazu Teijin Limited Fujita
Takashi Teijin Limited KUDO
Shoichi Teijin Limited Murakami
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP17908196A external-priority patent/JPH1015362A/en
Priority claimed from JP22836596A external-priority patent/JPH1066847A/en
Application filed by Teijin Ltd filed Critical Teijin Ltd
Publication of EP0862491A1 publication Critical patent/EP0862491A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/10—Supported membranes; Membrane supports
    • B01D69/107—Organic support material
    • B01D69/1071—Woven, non-woven or net mesh

Definitions

  • the present invention relates to a filter member, more particularly to a filter member suited for membrane separation, for example, to treat waste water or to ensure drinking water in the event of a disaster or for use in the field.
  • Background of the Invention A variety of porous filter membranes have been used as filters for waste water treatment. These porous filter membranes are laid out on a frame body for use. Above all, a porous synthetic resin membrane comprising a high molecular weight polyethylene is used over an extensive range because of high porosity, excellent filtering capacity and economic advantages. (For example, see Japanese Patent TOKKAI-HEI No. 2-232242 (1990), TOKKAI-HEI No .5-98065 (1993), TOKKAI-HEI No . 5-239246 (1993) and TOKKAI-HEI No. 5-245923 (1993)).
  • Such a porous synthetic resin membrane comprising the polyethylene featuring high porosity and excellent filtering capacity provides an excellent tensile strength for the thin membrane in the machine direction and traverse direction, despite its high porosity since it comprises a high molecular weight polyethylene and is formed by high degree of stretching; whereas it is less strong in tear strength despite its flexibility, since the fibrous non-woven structure is formed m the direction of thickness. Accordingly, extreme care is required in handling the thin membrane when making an element for membrane separation by using this porous synthetic resin membrane of polyethylene laid out on the frame body, and making a module using this element. For example, there are problems such as easy separation from the surface layer when caught by small protrusions.
  • the supporting body for a filter membrane must allow the permeation of liquid more easily than the filter membrane itself.
  • a polyester non-woven fabric is used for this supporting body, and many improvements have been made.
  • Official Gazette of Japanese Patent No. TOKKO-HEI NO. -21526 (1992) discloses as the supporting body a multi-layered non-woven fabric based on the dual structure comprising a front surface layer having a greater aperture and surface roughness using thick fibers, and a back surface layer having a smaller aperture and compact structure using fine fibers.
  • this multi-layered non-woven fabric consisting of staple fibers serves to decrease variations in the thickness and water permeability of the non-woven fabric as the supporting body of the filter membrane; it is not intended to solve these problems which arise when said porous synthetic resin membrane of polyethylene featuring a high porosity and excellent filtering capacity is used as a filter membrane. At present, such problems as above-mentioned remain to be solved. Summary of the Invention
  • the present invention is intended to solve the problems involved in a conventional porous filter membrane using a porous synthetic resin membrane of polyethylene characterized by a high porosity and excellent filtering capacity, to ensure improvements in handling when preparing the element and module for membrane separation from the porous synthetic resin membrane, and to provide a porous filter member of excellent durability which ensures stable filtration of a large amount of fluid as in waste water treatment for a long time, without the filter member being damaged.
  • the present invention thus provides the following embodiments of a filter member:
  • a filter member comprising a porous filter membrane of a synthetic resin and a water-permeable reinforcing sheet laminated on the membrane wherein the membrane.and sheet are joined by spot-bondings scattered over an interfacial phase of lamination wherein the area of spot-bondmgs at any portion thereof is m the range of 0.05 - 0.35 cm per 1 cm of the interfacial phase.
  • a filter member according to (1) wherein the spot-bondmgs are polygonal bondings.
  • a filter member according to (1) wherein the spot-bondmgs are bondings with a network structure.
  • the membrane comprises a high molecular weight polyethylene having a molecular weight of 5 x 10 to 7 x 10 , and contains a large number of very fine pores providing a porosity of 60 to 90 and a pore diameter of 0.1 to 2.0 microns, the tensile strength and the tear strength in at least one of the machine and traverse directions of the membrane being 3.5 kg/5 cm or more, and 5 to 50 gram, respectively.
  • Fig. 1 is a perspective view of a schematic drawing representing an embodiment of a filter member laminated with a woven fabric as a water permeable reinforcing sheet according to the present invention.
  • Fig. 2 is a perspective view of a schematic drawing representing an embodiment of a filter member laminated with a porous film as a water-permeable reinforcing sheet according to the present invention.
  • Fig. 3 is a schematic drawing representing various forms of spot-bondings scattered over an interfacial phase of lamination of the present invention.
  • Fig. 4 is a perspective view representing an embodiment of an element for filtering treatment using a filter member according to the present invention.
  • Fig. 5 is a cross sectional view at A-A in Fig. 4 m the direction of the arrow.
  • Fig. 6 is a perspective view representing an embodiment of a reinforcing bar used for an element for filtering treatment based on a filter member according to the present invention.
  • Fig. 7 is a perspective view representing an embodiment of a filler used for an element for filtering treatment based on a filter member according to the present invention.
  • Fig. 8 is a perspective view representing an embodiment of an element for filtering treatment based on a filter member according to the present invention.
  • Fig. 9 is a cross sectional view of A-A in Fig. 8 in the direction of the arrow.
  • a porous synthetic resin membrane can be exemplified by various porous membranes comprising polytetra- fluoroethylene, polysulfone or hign molecular weigr.- poivethylene, where the water permeability is preferred to be 1 to 10 cc per min. per square centimeter.
  • water permeability characteristic is one obtained by converting the amount of pure water permeating the synthetic resin membrane (area : 4.7 cm x 4.7 cm) for one minute under a pressure of 0.5 kg/cm" into the units of " cc/ ⁇ un Jc "' .
  • the porous synthetic resin membrane is preferred to have a large number of very fine pores providing a porosity of 60 to 90% and a pore diameter of 0.1 to 2.0 microns.
  • porosity is calculated according to the following equation from the density (po) of the starting material and density (p) of synthetic resin membrane after molding:
  • the porous membrane comprising an ultra- high molecular weight polyethylene having a molecular weight of 5 x 10 L to 7 x 10 c is preferably used. If the molecular weight is too high, molding into a porous membrane will be difficult; whereas if it is too low, the strength of the porous membrane will be reduced, making it difficult to provide a high porous membrane with excellent filtering capacity.
  • the polyethylene may be copolymerized with a small amount (preferably 5 mol - or less) of propylene, butene, pentene, hexane, 4-methylpentene-l , and octene.
  • the polyethylene may contain a small amount (for example, 25 wt o or less) of polypropylene, polybutylene, and ethylene-propylene copolymer.
  • the polyethylene may contain the normally used additives such as a stabilizing agent, a coloring agent, a flame retarding agent and a static eliminating agent.
  • Such porous polyethylene membranes having a large number of very fine pores can be manufactured according to tne procedures disclosed in the Official Gazette of Japanese Patent Laid-Open Nos. TOKKAI-HEI 2-232242 (1990), TOKKAI-HEI 5-98065 (1993) and TOKKAI-HEI 5-239246 (1993) .
  • the solution (concentration: 2 to 30 wt C J obtained by dissolving an ultra-high molecular weight polyethylene having a molecular weight of 5 x lO 1 " into a solvent such as decalm is extruded from a slit-formed die to form a gel film; then it is stretched at a high stretching rate after the solvent has been evaporated in the gel film.
  • a polyethylene porous synthetic resin membrane preferably has a weight of 5 to 15 grams/ ⁇ r and a thickness of 25 to 60 microns.
  • the polyethylene porous synthetic resin membrane which can be used the present invention exhibits a fibrous non-woven structure m the direction of thickness, but the tear strength in at least one of the machine and traverse directions is preferred to be 5 to 50 grams .
  • a filter member according to the present invention comprises the porous membrane and a water-permeable reinforcing sheet laminated on the membrane order to improve tear strength, rigidity and durability.
  • the water-permeable reinforcing sheet of various materials and forms can be used if the high porosity and high filtering capacity of porous filter membrane are not degraded, namely, if it has tne same or greater water permeability than the porous synthetic resin membrane (1 to 10 cc/mm/c ⁇ r ) .
  • a reinforcing sheet having a tear strengt of 0.2 kg or more at least one of the machine and traverse directions is preferred.
  • the fibrous clotn or porous film is preferably used as such a water-permeable reinforcing sheet.
  • the woven, knitted or non-woven fabric can be used as the fibrous cloth, and especially a woven fabric or non-woven fabric consisting of continuous fibers is preferred.
  • a material polyester, polyamide, polyolef or polyvinyl chloride can be selected as required, and the use of polyester or polyolefm is preferred.
  • a weight of about 10 to 150 grams/m is preferred.
  • the cloth When a fibrous cloth is used as the reinforcing sheet, the cloth may be quilted, thread strips of high strength may be inserted at a specified interval in the longitudinal and/or traverse direction of the cloth, or tape-formed synthetic resin membrane may be partially bonded to the cloth.
  • a pore diameter of 0.1 to 2.0 mm, a porosity of 30 to 90 1, and a film thickness of 5 to 500 microns are preferred.
  • polyester or polyolefm as the porous film is preferred.
  • a filter member according to the present invention comprises a porous filter membrane of a synthetic resin and a water-permeable reinforcing sheet laminated on the membrane, each having the above characteristics. What is very important is that the membrane and sheet are joined by spot-bondmgs scattered over an interfacial phase of lamination wherein the area of spot-bondmgs is tne range of 0.05 - 0.35 cm- per 1 cm of the interfacial phase wnen taken at any portion thereof.
  • the interfacial phase of lamination can be present on one side or both sides (that is, water-permeable reinforcing sheet on both sides of the porous synthetic resin membrane) .
  • Fig. 1 is a perspective view of a schematic drawing showing an embodiment of a filter member 1 laminated with woven fabric 3 as a water-permeable reinforcing sheet on a porous synthetic resin membrane 2.
  • T is a partial schematic showing the relation between warp and weft yarn consisting of woven fabric 3.
  • D, D' is a partial schematic showing the spot-bondmgs per 1 cm " scattered over an interfacial phase of lamination.
  • D shows the spot-bondmgs a partial schematic S, wherein the fabric 3 is peeled from the membrane 2 at an interfacial phase of lamination and D' shows the image of the spot bondings at inner interfacial phase of lamination.
  • each area of D and D' is 1 cm : , and at D the membrane 2 and sheet 3 are joined by dot-like spot-bondings (di, d_, d_ , d_ ) and the total area of the spot-bondmgs is in the range of 0.05 - 0.35 cm .
  • FIG. 2 is another perspective view of the schematic drawing showing an embodiment of a filter member 1, laminated with porous film 4 as a water-permeable reinforcing sheet on a porous synthetic resin membrane 2.
  • P is a partial schematic showing small pores formed m the porous film 4.
  • L, L' is a partial schematic showing the spot bondings per 1 cm scattered over an interfacial phase of lamination.
  • L shows the spot-bondmgs in a partial schematic S, wherein the film 4 is peeled from the membrane 2 at an interfacial phase of lamination and L' shows the image of the spot bondings at inner interfacial phase of lamination .
  • each area of L and L' is 1 cm", and at L the membrane 2 and film 4 are joined by linear spot-bondings ( (1 ) and the area of said spot-bondmgs is in the range of 0.05 - 0.35 cm " .
  • the tear strength, rigidity and durability of the porous synthetic resin membrane must be improved by ensuring that the fine pores of the porous synthetic resin membrane will not be blocked by spot-bondmgs scattered over an interfacial phase of lamination with a water-permeable reinforcing sheet.
  • spot-bondmgs preferably have a dot-like, linear, polygonal or network structure.
  • Fig. 3 is a schematic diagram showing the various forms of spot-bondmgs.
  • Symbol (a) denotes dot-like spot-bondmgs with a very small area, and dot-like spot-bondmgs are scattered such that a specified bonded area will be formed per 1 cm of the interfacial phase when taken at any portion thereof .
  • Symbol (b) represents linear spot-bondmgs formed by a straight line ((b)-l) or curve ((b) -2) having the width and length.
  • Symbol (c) denotes polygonal spot-bondmgs ((c)-l) formed by straight line or curve having the width and length connected with each other with a space left inside, or polygonal spot-bondings ((c) -2) as its condensed form.
  • Symbol (d) denotes spot-bondmgs with a network structure formed by the straight line or curve having the width and length. Similar to spot-bondmgs of (a), spot-bondings of (b) , (c) or (d) are scattered to form a specified area per 1 cm of the interfacial phase when taken at any portion thereof.
  • spot-bondmgs having numerous straight or curved spot-bon ⁇ mgs will provide greater reinforcement effect on the same area of spot-bondmgs .
  • polygonal spot-bondmgs are especially preferred to dot-like spot-bondmgs because they ensure that greater reinforcement effect, and filtering capacity are compatible with each other with the reduced area of spot- bondmgs .
  • the spot-bondings of a dot-like, linear, polygonal or network structure can be formed on an interfacial phase of lamination by the method of bonaing by heat and pressure after applying a bonding agent to the gravure roll engraved in a specified shape, or jetting a hc melt oonding agent in the form of filament or powder, and ultrasonic or other thermal sealing methods which do not use any oonding agent .
  • the member is preferably made into the filtering element laid out on both sides of the frame body or the filtering element molded in the bag form.
  • Fig. 4 is a perspective view representing the embodiment of an element for filtering treatment utilizing a filter member according to the present invention.
  • Fig. 5 is a cross sectional view of A-A in the direction of the arrow, representing the element.
  • Numeral 1 denotes a filter member according to the present invention, 11 a frame body, 12 a network body, 13 a felt and 14 an outlet.
  • Fig. 8 is a perspective view showing another form of the element or filtering treatment using a filter member according to the present invention.
  • Fig. 9 is a cross sectional view A-A in the direction of the arrow, representing the element.
  • Numeral 1 denotes a filter member according to the present invention, 21 a bag body formed of the member, 22 a form-retaining member accommodated in the bag body 21, 23 an outlet provided m the bag body 21, 24 a sealed portion of a filter member 1, and 25 a water passageway formed above the form-retaining member.
  • a filter member according to the present invention is used for waste water treatment, a multiple number of elements for the filtering treatment comprising a filter member 1 of the present invention laid out on both sides of the frame body as shown m Fig.
  • the water to be treated such as waste water is supplied from the outside, and is filtered by a filter member 1 ; then the filtered water is sucked by a suction pump (not illustrated) , and discharged from outlet 14.
  • the clearance inside the frame body 11 with the filler member 19, as shown m Fig. 7 can be filled, thereby ensuring water will not remain m the frame body 11.
  • the space 17 of the reinforcing bar 16 can be filled with filler member 19, and thus installed mside the frame body 11.
  • a foame ⁇ plastic product having isolated cell foams is preferred.
  • foamed polystyrene is preferably used.
  • a filter member of the present invention can be used for waste water treatment or the like as the element for filtering treatment formed in a bag body, as shown in Fig. 8.
  • the bag body 21 can be made from a filter member of the present invention by forming the sealed portion 24, using an ultrasonic or other thermal sealing method employed for the production of a bag body for foodstuffs.
  • thermal sealing provides low-cost and sufficient sealing properties.
  • a filter member wherein a polyester woven fabric is laminated onto a polyethylene porous synthetic resin membrane and is joined by spot-bondmgs, sufficient sealing properties can be obtained by providing the sealed portion using ultrasonic thermal sealing method through melting of the polyethylene placing the polyester woven fabric on the inner side and polyethylene membrane on the outer side.
  • outlet 23 molded m a valve form advance can be mounted on the bag body 21 according to the method similar to the above thermal sealing.
  • a form-retaining member 22 is stored in the bag body 21 to prevent the bag body 21 from being crushed when filtered water is sucked from the outlet 23.
  • the element must be removed from the water to be treated on a periodic basis for inspection and replacement.
  • the water mside the element may not be discharged immediately, and this may make it difficult to remove the element because of the weight of the remaining water.
  • the filter member may be damaged.
  • a water passageway 25 is preferably formed on the surface of the form-retaining member 22 m order to ensure smooth passing of water and filtering due to the bag body 21, without being brought into close contact with the form- retammg member 22.
  • a groove may be formed, as illustrated in Fig. 9 or multiple convex and concave shapes may be formed.
  • a meshed or corrugated groove on the entire surface of form-retaining member 22 is also effective.
  • the meshed fibrous member or plastic member may be installed on the surface of the form-retaining member 22 , thereby forming a water passage.
  • the element shown m Fig.8 which was formed from a filter member of tne present invention into the bag body, this element is put into tne water such as waste water, and water is sucked from the outlet 23; then water is filtered by the member 1 forming the Pag body 21 in the direction shown by the arrow mark in Fig. 9, is sucked into bag body 21, and is removed from the outlet 23 as purified water. Furthermore, when purified water such as drinking water is required in the event of a disaster or n field use, this element can be put into the water of a river, pond and other such places to suck water from the outlet 23.
  • the present invention solves the problems involved a conventional filter member using a porous synthetic resin membrane featuring a high porosity and excellent filtering capacity, ensures improvements in handling when preparing the element and module for membrane separation from the porous synthetic resin membrane, and provides a porous filter member of excellent durability which ensures stable filtration of a large amount of fluid as m waste water treatment over a long period of time, without the filter member being damaged.
  • the element for filtering treatment using a filter member of the present invention can be produced by laying out the member on both sides of the frame body or molding it in the form of a bag.
  • the element for filtering treatment molded in bag form is light weight, has excellent handling and has high filtering capacity without any problems in sealing.
  • easy mounting and dismounting of the bag body arises, and it is possible to provide at low-cost an element for filtering treatment and the module for filtering treatment incorporating said element.
  • waste water treatment it is expected to find applications over a variety of fields including its application to ensure a drinking water m the event of disaster or m the field.
  • Water permeability was obtained by converting the amount of pure water permeating the synthetic resm membrane (area: 4.7 cm x 4.7 cm) for one minute under a pressure of 0.5 kg/cm into units of cc/min./c ⁇ r .
  • a urethane based adhesive (Polyflex BD registered trade name of Danchikogyoseiyaku Ltd.) was applied m a dot-like structure using a gravure roll engraved m a dot-like structure on one side of the polyethylene terephthalate taffeta woven fabric (B) having the above-mentioned characteristics, on which the porous filter membrane (A) having the above-mentioned characteristics was laminated. Then they were calendered at a temperature of 160 * 0 and joined by spot-bondmgs to each other. In this case, the number of dot-like engravings was changed to evaluate the area of spot-bondmgs, and the accompanying physical properties and effects. Table 1 shows the results of this evaluation. Examples 5 to 6
  • Porous film - Material Polyethylene (by Tamapo i Ltd.)
  • the element for filtering treatment (75 cm vertical, 30 cm lateral, 1.1 cm thick) shown m Figs .8 and 9 was prepared using a filter member each example. After tap water was sucked at 0.2kg/cm 2 for five minutes by this element, backwashmg was performed at 0.1 kg/cm" for five minutes. After repeating this operation 10, 000 times, the peeling state in a filter member was evaluated.
  • Example 1 0
  • the following element for filtering treatment shown in Figs. 8 and 9 were prepared using a filter member in Example 3: - Dimensions 75 cm (vertical) x 30 cm (lateral) - Thickness 1.1 cm Ten of these elements were arranged in parallel inside a module for filtering treatment. Waste water used to wash clothing was poured inside the module at a flow rate of 1.8m 3 per day. At the same time, purified water was sucked and removed from the outlet of the element at the same speed.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Filtering Materials (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The present invention provides a filter member having excellent handling properties when preparing the element and module for membrane separation from the filter member featuring a high porosity and excellent filtering capacity, and excellent durability as filters for waste water treatment. A filter member comprises a porous filter membrane of a synthetic resin and a water-permeable reinforcing sheet laminated on the membrane wherein the membrane and sheet are joined by spot-bondings scattered over an interfacial phase of lamination with the area of spot-bondings at any portion thereof being in the range of 0.05-0.35 cm2 per 1 cm2 of said interfacial phase.

Description

DESCRIPTION A Filter Member
Field of the Invention The present invention relates to a filter member, more particularly to a filter member suited for membrane separation, for example, to treat waste water or to ensure drinking water in the event of a disaster or for use in the field. Background of the Invention A variety of porous filter membranes have been used as filters for waste water treatment. These porous filter membranes are laid out on a frame body for use. Above all, a porous synthetic resin membrane comprising a high molecular weight polyethylene is used over an extensive range because of high porosity, excellent filtering capacity and economic advantages. (For example, see Japanese Patent TOKKAI-HEI No. 2-232242 (1990), TOKKAI-HEI No .5-98065 (1993), TOKKAI-HEI No . 5-239246 (1993) and TOKKAI-HEI No. 5-245923 (1993)).
Such a porous synthetic resin membrane comprising the polyethylene featuring high porosity and excellent filtering capacity provides an excellent tensile strength for the thin membrane in the machine direction and traverse direction, despite its high porosity since it comprises a high molecular weight polyethylene and is formed by high degree of stretching; whereas it is less strong in tear strength despite its flexibility, since the fibrous non-woven structure is formed m the direction of thickness. Accordingly, extreme care is required in handling the thin membrane when making an element for membrane separation by using this porous synthetic resin membrane of polyethylene laid out on the frame body, and making a module using this element. For example, there are problems such as easy separation from the surface layer when caught by small protrusions. Furthermore, when the module with the built-m element is used for waste water treatment, foreign substances m waste water will be caught by the surface layer and when discharged by a large amount of fluid, fine portions of the thin membrane m the element will be damaged, and the thin membrane itself will be damaged over time -- this fails to meet practical requirements. Problems of a similar nature will occur.
When abnormal pressure has occurred m filtration of a large amount of fluid with the module using this porous synthetic resin membrane of polyethylene featuring a high porosity and excellent filtering capacity, or when pressure is applied to remove the filtered matter deposited on the element after filtration of a specified amount (the so-called "backwashmg" ) , it is necessary that applied pressure be distributed over the entire membrane surface. To meet this need, the thin membrane itself must have a certain rigidity, thereby improving durability in repeated use. Generally, when a filter membrane is used, its combination with a supporting body is more prevalent.
Needless to say, the supporting body for a filter membrane must allow the permeation of liquid more easily than the filter membrane itself. At present, a polyester non-woven fabric is used for this supporting body, and many improvements have been made. For example, Official Gazette of Japanese Patent No. TOKKO-HEI NO. -21526 (1992) discloses as the supporting body a multi-layered non-woven fabric based on the dual structure comprising a front surface layer having a greater aperture and surface roughness using thick fibers, and a back surface layer having a smaller aperture and compact structure using fine fibers. However, this multi-layered non-woven fabric consisting of staple fibers serves to decrease variations in the thickness and water permeability of the non-woven fabric as the supporting body of the filter membrane; it is not intended to solve these problems which arise when said porous synthetic resin membrane of polyethylene featuring a high porosity and excellent filtering capacity is used as a filter membrane. At present, such problems as above-mentioned remain to be solved. Summary of the Invention
The present invention is intended to solve the problems involved in a conventional porous filter membrane using a porous synthetic resin membrane of polyethylene characterized by a high porosity and excellent filtering capacity, to ensure improvements in handling when preparing the element and module for membrane separation from the porous synthetic resin membrane, and to provide a porous filter member of excellent durability which ensures stable filtration of a large amount of fluid as in waste water treatment for a long time, without the filter member being damaged.
In an effort to solve these problems, the inventors of the present invention have found that these problems can be solved by lamination through spot-bondings of a water- permeable reinforcing sheet to a porous synthetic resin membrane under specific conditions. This finding has led to the present invention. The present invention thus provides the following embodiments of a filter member:
( 1 ) A filter member comprising a porous filter membrane of a synthetic resin and a water-permeable reinforcing sheet laminated on the membrane wherein the membrane.and sheet are joined by spot-bondings scattered over an interfacial phase of lamination wherein the area of spot-bondmgs at any portion thereof is m the range of 0.05 - 0.35 cm per 1 cm of the interfacial phase.
(2) A filter member according to (1) wherein the spot-bondmgs are dot-like bondings.
(3) A filter member according to (1) wherein the spot-bondmgs are linear bondings.
(4) A filter member according to (1) wherein the spot-bondmgs are polygonal bondings. (5) A filter member according to (1) wherein the spot-bondmgs are bondings with a network structure.
(6) A filter member according to any one of (1) to (5) wherein the water-permeability of the membrane is 1 to 10 cc/mm . /cm . (7) A filter member according to (6) wherein the membrane comprises a high molecular weight polyethylene having a molecular weight of 5 x 10 to 7 x 10 , and contains a large number of very fine pores providing a porosity of 60 to 90 and a pore diameter of 0.1 to 2.0 microns, the tensile strength and the tear strength in at least one of the machine and traverse directions of the membrane being 3.5 kg/5 cm or more, and 5 to 50 gram, respectively.
(8) A filter member according to any one of (1) to (5) wherein the tear strength of the sheet in at least one of the machine and traverse directions is 0.2 kg or more.
(9) A filter member according to (8) wherein the sheet is a fibrous cloth.
(10) A filter member according to (9) wherein the cloth is a woven fabric.
(11) A filter member according to (9) wherein the cloth is a non-woven fabric consisting of continuous fibers. (12) A filter member according to (8) wherein the sheet is a porous film.
Brief Description of the Drawings
Fig. 1 is a perspective view of a schematic drawing representing an embodiment of a filter member laminated with a woven fabric as a water permeable reinforcing sheet according to the present invention.
Fig. 2 is a perspective view of a schematic drawing representing an embodiment of a filter member laminated with a porous film as a water-permeable reinforcing sheet according to the present invention.
Fig. 3 is a schematic drawing representing various forms of spot-bondings scattered over an interfacial phase of lamination of the present invention.
Fig. 4 is a perspective view representing an embodiment of an element for filtering treatment using a filter member according to the present invention.
Fig. 5 is a cross sectional view at A-A in Fig. 4 m the direction of the arrow.
Fig. 6 is a perspective view representing an embodiment of a reinforcing bar used for an element for filtering treatment based on a filter member according to the present invention.
Fig. 7 is a perspective view representing an embodiment of a filler used for an element for filtering treatment based on a filter member according to the present invention.
Fig. 8 is a perspective view representing an embodiment of an element for filtering treatment based on a filter member according to the present invention.
Fig. 9 is a cross sectional view of A-A in Fig. 8 in the direction of the arrow.
In these figures, the reference numbers have the following meaning: 1. Filter member
2. Porous filter membrane of synthetic resin
3. Water-permeable reinforcing sheet (woven fabric)
4. Water permeable reinforcing sheet (porous filπυ (a) Dot-like spot-bondmgs (b) Linear spot-bondings
(c) Polygonal spot bondings
(d) Network spot bondings
11. Frame body
12. Network body 13. Felt
14. Outlet
15. Penetration hole
16. Reinforcing bar
17. Space for reinforcing bar 18. Outlet connected to the outlet of the element for filtering treatment 19. Filler member
21. Bag body
22. Form-retaining member 23. Outlet
24. Sealed portion
25. Water passageway
Detailed Description of the Invention A porous synthetic resin membrane can be exemplified by various porous membranes comprising polytetra- fluoroethylene, polysulfone or hign molecular weigr.- poivethylene, where the water permeability is preferred to be 1 to 10 cc per min. per square centimeter. Here water permeability characteristic is one obtained by converting the amount of pure water permeating the synthetic resin membrane (area : 4.7 cm x 4.7 cm) for one minute under a pressure of 0.5 kg/cm" into the units of " cc/πun Jc "' . To get such water permeability, the porous synthetic resin membrane is preferred to have a large number of very fine pores providing a porosity of 60 to 90% and a pore diameter of 0.1 to 2.0 microns.
Here porosity is calculated according to the following equation from the density (po) of the starting material and density (p) of synthetic resin membrane after molding:
Porosity ( % ) = (1 - p/po) x 100 If the pore diameter is too small, clogging tends to occur and sufficient durability cannot be ensured, whereas filtering capacity is poor if it is too large. Proper selection of pore diameter and its number allows the porosity of the porous synthetic resin membrane, and water permeability wherever practicable, to be established. This makes it possible to show the maximum filtering capacity of the porous filter member according to the present invention.
Especially, the porous membrane comprising an ultra- high molecular weight polyethylene having a molecular weight of 5 x 10L to 7 x 10c is preferably used. If the molecular weight is too high, molding into a porous membrane will be difficult; whereas if it is too low, the strength of the porous membrane will be reduced, making it difficult to provide a high porous membrane with excellent filtering capacity.
Furthermore, the polyethylene may be copolymerized with a small amount (preferably 5 mol - or less) of propylene, butene, pentene, hexane, 4-methylpentene-l , and octene.
Also, it may contain a small amount (for example, 25 wt o or less) of polypropylene, polybutylene, and ethylene-propylene copolymer. In addition, the polyethylene may contain the normally used additives such as a stabilizing agent, a coloring agent, a flame retarding agent and a static eliminating agent. Such porous polyethylene membranes having a large number of very fine pores can be manufactured according to tne procedures disclosed in the Official Gazette of Japanese Patent Laid-Open Nos. TOKKAI-HEI 2-232242 (1990), TOKKAI-HEI 5-98065 (1993) and TOKKAI-HEI 5-239246 (1993) . For example, the solution (concentration: 2 to 30 wt CJ obtained by dissolving an ultra-high molecular weight polyethylene having a molecular weight of 5 x lO1" into a solvent such as decalm is extruded from a slit-formed die to form a gel film; then it is stretched at a high stretching rate after the solvent has been evaporated in the gel film. Such polyethylene porous synthetic resin membrane preferably has a weight of 5 to 15 grams/πr and a thickness of 25 to 60 microns. Since it is composed of an ultra-high molecular weight polyethylene and formed by stretching at a high degree of stretching m the machine and traverse directions, it is preferred to have a high porosity and a tensile strength of the porous membrane at least one of the machine and traverse directions being 3.5 kg/5 cm or more. Furthermore, the polyethylene porous synthetic resin membrane which can be used the present invention exhibits a fibrous non-woven structure m the direction of thickness, but the tear strength in at least one of the machine and traverse directions is preferred to be 5 to 50 grams . To meet this need, it is preferable to improve the mterlaminar strength of the fibrous non-woven structure by calendering, thereby ensuring upgraded durability.
A filter member according to the present invention comprises the porous membrane and a water-permeable reinforcing sheet laminated on the membrane order to improve tear strength, rigidity and durability. The water-permeable reinforcing sheet of various materials and forms can be used if the high porosity and high filtering capacity of porous filter membrane are not degraded, namely, if it has tne same or greater water permeability than the porous synthetic resin membrane (1 to 10 cc/mm/cπr ) . However, a reinforcing sheet having a tear strengt of 0.2 kg or more at least one of the machine and traverse directions is preferred. The fibrous clotn or porous film is preferably used as such a water-permeable reinforcing sheet. The woven, knitted or non-woven fabric can be used as the fibrous cloth, and especially a woven fabric or non-woven fabric consisting of continuous fibers is preferred. As a material, polyester, polyamide, polyolef or polyvinyl chloride can be selected as required, and the use of polyester or polyolefm is preferred. When a cloth is used, a weight of about 10 to 150 grams/m is preferred.
When a fibrous cloth is used as the reinforcing sheet, the cloth may be quilted, thread strips of high strength may be inserted at a specified interval in the longitudinal and/or traverse direction of the cloth, or tape-formed synthetic resin membrane may be partially bonded to the cloth.
When a porous film is used, a pore diameter of 0.1 to 2.0 mm, a porosity of 30 to 90 1, and a film thickness of 5 to 500 microns are preferred. Especially the use of polyester or polyolefm as the porous film is preferred.
A filter member according to the present invention comprises a porous filter membrane of a synthetic resin and a water-permeable reinforcing sheet laminated on the membrane, each having the above characteristics. What is very important is that the membrane and sheet are joined by spot-bondmgs scattered over an interfacial phase of lamination wherein the area of spot-bondmgs is tne range of 0.05 - 0.35 cm- per 1 cm of the interfacial phase wnen taken at any portion thereof.
It goes without saying that the interfacial phase of lamination can be present on one side or both sides (that is, water-permeable reinforcing sheet on both sides of the porous synthetic resin membrane) .
Fig. 1 is a perspective view of a schematic drawing showing an embodiment of a filter member 1 laminated with woven fabric 3 as a water-permeable reinforcing sheet on a porous synthetic resin membrane 2. Here, T is a partial schematic showing the relation between warp and weft yarn consisting of woven fabric 3. D, D' is a partial schematic showing the spot-bondmgs per 1 cm" scattered over an interfacial phase of lamination.
Moreover, D shows the spot-bondmgs a partial schematic S, wherein the fabric 3 is peeled from the membrane 2 at an interfacial phase of lamination and D' shows the image of the spot bondings at inner interfacial phase of lamination. Furthermore, each area of D and D' is 1 cm:, and at D the membrane 2 and sheet 3 are joined by dot-like spot-bondings (di, d_, d_ , d_ ) and the total area of the spot-bondmgs is in the range of 0.05 - 0.35 cm . Fig. 2 is another perspective view of the schematic drawing showing an embodiment of a filter member 1, laminated with porous film 4 as a water-permeable reinforcing sheet on a porous synthetic resin membrane 2. Here, P is a partial schematic showing small pores formed m the porous film 4. L, L' is a partial schematic showing the spot bondings per 1 cm scattered over an interfacial phase of lamination. Moreover, L shows the spot-bondmgs in a partial schematic S, wherein the film 4 is peeled from the membrane 2 at an interfacial phase of lamination and L' shows the image of the spot bondings at inner interfacial phase of lamination . Furthermore, each area of L and L' is 1 cm", and at L the membrane 2 and film 4 are joined by linear spot-bondings ( (1 ) and the area of said spot-bondmgs is in the range of 0.05 - 0.35 cm".
In a filter member according to the present invention, the tear strength, rigidity and durability of the porous synthetic resin membrane must be improved by ensuring that the fine pores of the porous synthetic resin membrane will not be blocked by spot-bondmgs scattered over an interfacial phase of lamination with a water-permeable reinforcing sheet. This requires that the area of spot-bondmgs is the range of 0.05 - 0.35 cm" per 1 cm" of the interfacial phase when taken at any portion thereof. If the area of spot-bondmgs is below 0.05 cm , the above target cannot be achieved. If the area of spot-bondmgs exceeds 0.35 cm", water-permeability will be reduced, namely, filtering capacity will be reduced this fails to meet practical requirements. As described above, to ensure the specified area of spot-bondmgs with the minimum blocking of the fine pores of the porous synthetic resin membrane, spot-bondmgs preferably have a dot-like, linear, polygonal or network structure. Fig. 3 is a schematic diagram showing the various forms of spot-bondmgs. Symbol (a) denotes dot-like spot-bondmgs with a very small area, and dot-like spot-bondmgs are scattered such that a specified bonded area will be formed per 1 cm of the interfacial phase when taken at any portion thereof . Symbol (b) represents linear spot-bondmgs formed by a straight line ((b)-l) or curve ((b) -2) having the width and length. Symbol (c) denotes polygonal spot-bondmgs ((c)-l) formed by straight line or curve having the width and length connected with each other with a space left inside, or polygonal spot-bondings ((c) -2) as its condensed form. Symbol (d) denotes spot-bondmgs with a network structure formed by the straight line or curve having the width and length. Similar to spot-bondmgs of (a), spot-bondings of (b) , (c) or (d) are scattered to form a specified area per 1 cm of the interfacial phase when taken at any portion thereof.
Of these various forms of spot-bondmgs, the spot- bondmgs having numerous straight or curved spot-bonαmgs will provide greater reinforcement effect on the same area of spot-bondmgs . Accordingly, polygonal spot-bondmgs are especially preferred to dot-like spot-bondmgs because they ensure that greater reinforcement effect, and filtering capacity are compatible with each other with the reduced area of spot- bondmgs . As discussed above, the spot-bondings of a dot-like, linear, polygonal or network structure can be formed on an interfacial phase of lamination by the method of bonaing by heat and pressure after applying a bonding agent to the gravure roll engraved in a specified shape, or jetting a hc melt oonding agent in the form of filament or powder, and ultrasonic or other thermal sealing methods which do not use any oonding agent . To use a filter member of the present invention for waste water treatment, the member is preferably made into the filtering element laid out on both sides of the frame body or the filtering element molded in the bag form. Fig. 4 is a perspective view representing the embodiment of an element for filtering treatment utilizing a filter member according to the present invention.
Fig. 5 is a cross sectional view of A-A in the direction of the arrow, representing the element. Numeral 1 denotes a filter member according to the present invention, 11 a frame body, 12 a network body, 13 a felt and 14 an outlet.
Fig. 8 is a perspective view showing another form of the element or filtering treatment using a filter member according to the present invention. Fig. 9 is a cross sectional view A-A in the direction of the arrow, representing the element. Numeral 1 denotes a filter member according to the present invention, 21 a bag body formed of the member, 22 a form-retaining member accommodated in the bag body 21, 23 an outlet provided m the bag body 21, 24 a sealed portion of a filter member 1, and 25 a water passageway formed above the form-retaining member. When a filter member according to the present invention is used for waste water treatment, a multiple number of elements for the filtering treatment comprising a filter member 1 of the present invention laid out on both sides of the frame body as shown m Fig. 4 for example, are arranged and installed inside the module for membrane separation; the water to be treated such as waste water is supplied from the outside, and is filtered by a filter member 1 ; then the filtered water is sucked by a suction pump (not illustrated) , and discharged from outlet 14.
In this case, it is preferred to install the reinforcing bar 16 having the penetration hole 15 inside the frame body 11, as shown in 6. This reinforcing Par 16 holds and reinforces a filter member 1. Moreover, since the reinforcing bar 16 is provided with penetration hole 15, this ensures that water filtered by a filter member I flows inside the frame body 11 smoothly, thereby ensuring smooth filtration. In Fig. 6, numeral 17 denotes a space for the reinforcing bar 16, and 18 an outlet connected to the outlet 14 of the element.
Furthermore, when the element must be replaced due to clogging and the like, it will become heavy if a large amount of water remains mside the element and a large amount of labor will be required to remove it from the module for membrane separation. To solve this problem, the clearance inside the frame body 11 with the filler member 19, as shown m Fig. 7 can be filled, thereby ensuring water will not remain m the frame body 11. For example, the space 17 of the reinforcing bar 16 can be filled with filler member 19, and thus installed mside the frame body 11. For such a filler member 19, a foameα plastic product having isolated cell foams is preferred. For example, foamed polystyrene is preferably used.
Furthermore, a filter member of the present invention can be used for waste water treatment or the like as the element for filtering treatment formed in a bag body, as shown in Fig. 8. Here the bag body 21 can be made from a filter member of the present invention by forming the sealed portion 24, using an ultrasonic or other thermal sealing method employed for the production of a bag body for foodstuffs. Such thermal sealing provides low-cost and sufficient sealing properties. For example, in the case of a filter member wherein a polyester woven fabric is laminated onto a polyethylene porous synthetic resin membrane and is joined by spot-bondmgs, sufficient sealing properties can be obtained by providing the sealed portion using ultrasonic thermal sealing method through melting of the polyethylene placing the polyester woven fabric on the inner side and polyethylene membrane on the outer side.
Furthermore, m Fig. 8, the outlet 23 molded m a valve form advance can be mounted on the bag body 21 according to the method similar to the above thermal sealing. Outlet
23 need not always be mounted on tne corner as illustrated; it may be mounted at the center or at any other desired place. The number of outlets is not restricted to one and a multiple number of outlets can be installed. A form-retaining member 22 is stored in the bag body 21 to prevent the bag body 21 from being crushed when filtered water is sucked from the outlet 23.
Also the element must be removed from the water to be treated on a periodic basis for inspection and replacement. In this case, the water mside the element may not be discharged immediately, and this may make it difficult to remove the element because of the weight of the remaining water. In addition, the filter member may be damaged. Such problems can be solved by using a light non-absorbmg molded product having the isolated cell foam, for example, the polystyrene molded product with an isolated cell foam for the form-retaining member 22.
Furthermore, when filtered water is sucked from the outlet 23, a water passageway 25 is preferably formed on the surface of the form-retaining member 22 m order to ensure smooth passing of water and filtering due to the bag body 21, without being brought into close contact with the form- retammg member 22. As water passageway 25, a groove may be formed, as illustrated in Fig. 9 or multiple convex and concave shapes may be formed. A meshed or corrugated groove on the entire surface of form-retaining member 22 is also effective. Furthermore, the meshed fibrous member or plastic member may be installed on the surface of the form-retaining member 22 , thereby forming a water passage.
Normally, when filtered water is sucked from the outlet 23, water permeation and filtering tend to ta e place only from the vicinity of the outlet 23. So it is preferred to select the form and layout of this water passageway 25 so that water permeation and filtering will take place from the entire bag body 21.
When used for waste water treatment, the element shown m Fig.8 which was formed from a filter member of tne present invention into the bag body, this element is put into tne water such as waste water, and water is sucked from the outlet 23; then water is filtered by the member 1 forming the Pag body 21 in the direction shown by the arrow mark in Fig. 9, is sucked into bag body 21, and is removed from the outlet 23 as purified water. Furthermore, when purified water such as drinking water is required in the event of a disaster or n field use, this element can be put into the water of a river, pond and other such places to suck water from the outlet 23.
Especially when a porous membrane of high molecular weight polyethylene having a pore diameter of about 0.1 to 0.3 microns is used, bacteria can be removed almost completely. This makes it possible to get a clean water which can be used as drinking water.
The present invention solves the problems involved a conventional filter member using a porous synthetic resin membrane featuring a high porosity and excellent filtering capacity, ensures improvements in handling when preparing the element and module for membrane separation from the porous synthetic resin membrane, and provides a porous filter member of excellent durability which ensures stable filtration of a large amount of fluid as m waste water treatment over a long period of time, without the filter member being damaged.
Furthermore, the element for filtering treatment using a filter member of the present invention can be produced by laying out the member on both sides of the frame body or molding it in the form of a bag. Especially the element for filtering treatment molded in bag form is light weight, has excellent handling and has high filtering capacity without any problems in sealing. In addition, easy mounting and dismounting of the bag body arises, and it is possible to provide at low-cost an element for filtering treatment and the module for filtering treatment incorporating said element. Thus, m addition to waste water treatment, it is expected to find applications over a variety of fields including its application to ensure a drinking water m the event of disaster or m the field.
The following describes the present invention in greater detail with reference to specific. Water permeability, porosity, tensile strength and tear strength m the examples were measured as follows: (1) Water permeability
Water permeability was obtained by converting the amount of pure water permeating the synthetic resm membrane (area: 4.7 cm x 4.7 cm) for one minute under a pressure of 0.5 kg/cm into units of cc/min./cπr .
(2) Porosity
Porosity was calculated according to the following equation from the density (po) of the starting material and density (p) of synthetic resm membrane after molding: Porosity (%) = (1- p/po) x 100
(3) Tensile strength
Tensile strength was measured in conformity to ASTM D-882.
(4) Tear strength Tear strength is measured in conformity to JIS L-1096.
Examples 1 to 4 and Comparative examples 1 and 2
The following were utilized as s porous filter membrane of synthetic resm (A) and a water-permeable reinforcing sheet (B) :
(A) Porous filter membrane of synthetic resm -Polymer: polyethylene (Hizex Million registered trade name of Mitsui Petrochemical Industries Ltd.)
- Molecular weight (weight average): 3.3 x 10*
- Water permeability: 5 cc/mm./cm
- Porosity: 85%
- Pore diameter (average): 1.0 μm - Tensile strength (machine direction) : 3.8 kg/5 cm
(traverse direction): 4.0 kg/5 cm
- Tear strength (machine direction) : 12 gram
(traverse direction) : 11 gram
- Weight: lOg/m - Thickness: 50 μ (B) Water-permeable reinforcing sheet
- Material: Polyethylene terephthalate taffeta woven fabric (Tetron registered trade name of Tei Ltd.)
- Water permeability: 50 cc/mm./cm - Tear strength (machine direction) : 4.0 kg
(traverse direction): 5.0 kg
- Weight: 105 g/m2
A urethane based adhesive (Polyflex BD registered trade name of Danchikogyoseiyaku Ltd.) was applied m a dot-like structure using a gravure roll engraved m a dot-like structure on one side of the polyethylene terephthalate taffeta woven fabric (B) having the above-mentioned characteristics, on which the porous filter membrane (A) having the above-mentioned characteristics was laminated. Then they were calendered at a temperature of 160*0 and joined by spot-bondmgs to each other. In this case, the number of dot-like engravings was changed to evaluate the area of spot-bondmgs, and the accompanying physical properties and effects. Table 1 shows the results of this evaluation. Examples 5 to 6
Coating, laminating, calendering and bonding were carried out under exactly the same conditions as those m Example 3, except that the form engraved on the gravure roll was linear (Example 5 in (b)-l of Fig.3), hexagonal (Example 6 in (c)-l of Fig.3) and network (Example 7 m (d) of Fig.3) . Evaluation was made in exactly the same manner as that in Example 3, and the results are given in Table 1. Examples 8 and 9
Coating, laminating, calendering and bonding were carried out under exactly the same conditions as those Example 3 except that, instead of polyethylene terephthalate taffeta woven fabric, the following materials, non-woven fabric consisting of continuous fibers (Example 8) or porous film (Example 9) were used as a water-permeable reinforcing sheet. Evaluation was made m exactly the same manner as that in Example 3, and the results are given Table 1. (B) Water-permeable reinforcing sheet o Non-woven fabric consisting continuous fibers
- Material: polypropylene (SPRITOP registered trade name of Nippon Fushokufu, Ltd.) - Water permeability: 80 cc/mm./cπr
- Tear strength (machine direction): 0.6 kg
(traverse direction): 1.0 kg
- Weight: 50 g/m2 o Porous film - Material: Polyethylene (by Tamapo i Ltd.)
- Water permeability: 30 cc/mm./cπT
- Tear strength (machine direction): 0.7 kg
(traverse direction): 0.9 kg
- Pore diameter (average): 0.5 mm - Porosity: 30%
- Thickness: 100 μm
Table 1
Area of Water Tear Strength DuraSpot- Permeabibility bondmgs lity
Machine Traverse Direction Direction cm" cc/πun/cm2 kg kg
Comparative 0.04 * 3.0 4.2 5.3 X Example 1
Example 1 0.06 2.6 4.4 5.5 O
Example 2 0.12 2.0 4.6 5.8 o
Example 3 0.24 1.7 4.8 6.0 o
Example 4 0.34 1.2 5.0 6.2 o
Comparative 0.36 * 0.8 5.2 6.4 o Example 2
Example 5 0.24 1.8 5.0 6.3 o
Example 6 0.24 1.7 5.2 6.5 o
Example 7 0.24 1.9 5.4 6.7 o
Example 8 0.24 2.5 0.7 1.2 o
Example 9 0.24 2.5 0.8 1.0 o
Note : O : Deeling did not occur X : peelαnα occurred Items marked by * in Table are outside the scope of the present invention.
Durability Evaluation Procedures
The element for filtering treatment (75 cm vertical, 30 cm lateral, 1.1 cm thick) shown m Figs .8 and 9 was prepared using a filter member each example. After tap water was sucked at 0.2kg/cm2 for five minutes by this element, backwashmg was performed at 0.1 kg/cm" for five minutes. After repeating this operation 10, 000 times, the peeling state in a filter member was evaluated. Example 1 0
The following element for filtering treatment shown in Figs. 8 and 9 were prepared using a filter member in Example 3: - Dimensions 75 cm (vertical) x 30 cm (lateral) - Thickness 1.1 cm Ten of these elements were arranged in parallel inside a module for filtering treatment. Waste water used to wash clothing was poured inside the module at a flow rate of 1.8m3 per day. At the same time, purified water was sucked and removed from the outlet of the element at the same speed.
After seven days of treatment, elements were remove to check the external appearance. No damage occured. Backwashing was carried out by applying a pressure of 0.1 kg/cm2 to each element, and external appearance was again checked. No damage was observed.

Claims

1. A filter member comprising (1) a porous filter membrane of a synthetic resin and (2) a water-permeable reinforcing sheet laminated on said membrane (1) wherein said membrane (1) and sheet (2) are joined by spot-bondings (3) scattered over an interfacial phase of lamination wherein the area of spot-bondings at any portion thereof is in the range of 0.05 - 0.35 cm2 per 1 cm2 of said interfacial phase.
2. A filter member according to Claim 1 wherein said spot-bondings (3) are dot-like bondings.
3. A filter member according to Claim 1 wherein said spot-bondings (3) are linear bondings.
4. A filter member according to Claim 1 wherein said spot-bondings (3) are polygonal bondings.
5. A filter member according to Claim 1 wherein said spot-bondings (3) are bondings with a network structure.
6. A filter member according to any one of Claims 1 to 5 wherein the water permeability of said membrane (1) is 1 to
10 cc/min./cm2.
7. A filter member according to Claim 6 wherein said membrane (1) comprises a high molecular weight polyethylene having a molecular weight of 5 x 105 to 7 x 10l, and contains a large number of very fine pores providing a porosity of 60 to 90% and a pore diameter of 0.1 to 2.0 microns, the tensile strength and the tear strength in at least one of the machine and traverse directions of membrane (1) being 3.5 kg/5 cm or more, and 5 to 50 gram respectively.
8. A filter member according to any one of Claims 1 to 5 wherein the tear strength of said sheet (2) in at least one of the machine and traverse directions is 0.2 kg or more.
9. A filter member according to Claim 8 wherein said sheet (2) is a fibrous cloth.
10. A filter member according to Claim 9 wherein said cloth is a woven fabric.
11. A filter member according to Claim 9 wherein said cloth is a non-woven fabric consiting of continuous fibers.
12. A filter member according to Claim 8 wherein said sheet (2) is a porous film.
EP97929539A 1996-07-09 1997-07-07 A filter member Withdrawn EP0862491A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP179081/96 1996-07-09
JP17908196A JPH1015362A (en) 1996-07-09 1996-07-09 Bag-type film module
JP22836596A JPH1066847A (en) 1996-08-29 1996-08-29 Porous filter membrane and membrane module using the same
JP228365/96 1996-08-29
PCT/JP1997/002340 WO1998001219A1 (en) 1996-07-09 1997-07-07 A filter member

Publications (1)

Publication Number Publication Date
EP0862491A1 true EP0862491A1 (en) 1998-09-09

Family

ID=26499047

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97929539A Withdrawn EP0862491A1 (en) 1996-07-09 1997-07-07 A filter member

Country Status (4)

Country Link
EP (1) EP0862491A1 (en)
CN (1) CN1197409A (en)
ID (1) ID20443A (en)
WO (1) WO1998001219A1 (en)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10053752A1 (en) * 2000-10-30 2002-05-08 Ic Technology Ag Membrane filter pad
US6986428B2 (en) 2003-05-14 2006-01-17 3M Innovative Properties Company Fluid separation membrane module
US7279215B2 (en) 2003-12-03 2007-10-09 3M Innovative Properties Company Membrane modules and integrated membrane cassettes
EP1625885A1 (en) * 2004-08-11 2006-02-15 Vlaamse Instelling Voor Technologisch Onderzoek (Vito) Integrated permeate channel membrane
DE102004057107B8 (en) * 2004-11-26 2016-07-28 A3 Water Solutions Gmbh Frameless, plate-shaped filtration body and filtration module
JP4175410B2 (en) * 2006-08-31 2008-11-05 ダイキン工業株式会社 Air conditioner
JP4766167B2 (en) * 2009-01-28 2011-09-07 ダイキン工業株式会社 Air conditioning indoor unit and method for manufacturing filter cleaning device
ES2390542B1 (en) * 2010-03-11 2013-11-08 Lisardo A. GONZALEZ ABELLEIRA WATER CLEANING FILTER

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4944974A (en) * 1984-10-24 1990-07-31 Zachariades Anagnostis E Composite structures of ultra-high-molecular-weight polymers, such as ultra-high-molecular-weight polyethylene products, and method of producing such structures
JP2602016B2 (en) * 1986-09-01 1997-04-23 日東電工株式会社 Reinforced porous sheet
JPS63273651A (en) * 1987-04-30 1988-11-10 Toa Nenryo Kogyo Kk Production of fine porous membrane of polyolefin having ultra-high molecular weight
JPH06104736B2 (en) * 1989-08-03 1994-12-21 東燃株式会社 Polyolefin microporous membrane
NL9100279A (en) * 1991-02-18 1992-09-16 Stamicarbon MICROPOROUS FOIL FROM POLYETHENE AND METHOD FOR MANUFACTURING IT.
AU655551B2 (en) * 1992-12-16 1994-12-22 Kubota Corporation Filtration membrane cartridge

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9801219A1 *

Also Published As

Publication number Publication date
WO1998001219A1 (en) 1998-01-15
CN1197409A (en) 1998-10-28
ID20443A (en) 1998-12-17

Similar Documents

Publication Publication Date Title
KR101645483B1 (en) Filter compound material, method for the production thereof and flat filter elements made of the filter compound material
US5108474A (en) Smoke filter
US6454942B1 (en) Liquid separation membrane module
JPH06311A (en) Filtering material
EP1057520A1 (en) Microfilter cartridge
KR20070059059A (en) Integrated permeate channel membrane
JP5888439B2 (en) Separation membrane, sheet channel material and separation membrane element
US6186341B1 (en) Integrity testable filtration unit using supported hydrophilic porous membranes
EP0862491A1 (en) A filter member
JP2000354743A (en) Membrane module for separating liquids
JP3956262B2 (en) Liquid separation membrane module
US11478734B2 (en) Filter medium, method for manufacturing same, and filter unit comprising same
US11207644B2 (en) Filter medium with improved backwashing durability, method for manufacturing same, and filter unit comprising same
EP0513392A1 (en) Flat sheet type separating film leaf
JP2018086638A (en) Spiral type separation membrane element
JPH1066847A (en) Porous filter membrane and membrane module using the same
KR20180018934A (en) Filter media and Filter unit comprising the same
KR19990044425A (en) Filtration member
JPH1015362A (en) Bag-type film module
KR101254101B1 (en) Precipitated fiber media
JPH1147514A (en) Filter member
JP2000051668A (en) Liquid separation element and water making method
JP2015027666A (en) Separation membrane and separation membrane element
JPH11267465A (en) Filter element
JP2003181227A (en) Filter cartridge

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19980220

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB IT LI NL SE

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Withdrawal date: 19991126