EP0854763A2 - Process for producing an intermetallic join - Google Patents

Process for producing an intermetallic join

Info

Publication number
EP0854763A2
EP0854763A2 EP96945136A EP96945136A EP0854763A2 EP 0854763 A2 EP0854763 A2 EP 0854763A2 EP 96945136 A EP96945136 A EP 96945136A EP 96945136 A EP96945136 A EP 96945136A EP 0854763 A2 EP0854763 A2 EP 0854763A2
Authority
EP
European Patent Office
Prior art keywords
reinforcement part
intermetallic
reinforcement
graphite
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96945136A
Other languages
German (de)
French (fr)
Other versions
EP0854763B1 (en
Inventor
Birgit Hudelmaier
Dieter MÜLLER-SCHWELLING
Detlef Schlosser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mahle GmbH
Original Assignee
Mahle GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mahle GmbH filed Critical Mahle GmbH
Publication of EP0854763A2 publication Critical patent/EP0854763A2/en
Application granted granted Critical
Publication of EP0854763B1 publication Critical patent/EP0854763B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00—Casting in, on, or around objects which form part of the product
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02F—CYLINDERS, PISTONS OR CASINGS, FOR COMBUSTION ENGINES; ARRANGEMENTS OF SEALINGS IN COMBUSTION ENGINES
    • F02F7/00—Casings, e.g. crankcases or frames
    • F02F7/0085—Materials for constructing engines or their parts
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05—INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05C—INDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2201/00—Metals
    • F05C2201/02—Light metals
    • F05C2201/021—Aluminium

Definitions

  • the invention relates to a method for producing an intermetallic connection between a motor component made of an aluminum-based alloy and a reinforcement part made of austenitic cast iron, which are connected to one another by casting technology.
  • Corresponding methods are used in particular for introducing ring girders, occasionally also for introducing trough edge reinforcements in diesel engines.
  • the reinforcement part is connected to the piston material using the Alfin process, which has been known in the prior art since approx. 1950, by immersing the reinforcement part in an AlSi melt before the piston material is cast around it forms an intermetallic layer on the surface of the reinforcement part.
  • the invention is therefore concerned with the problem of increasing the strength of the intermetallic bond between the casting and the reinforcement part regardless of the use of a GGG or GGL material.
  • An essential area of application for the method according to the invention is in the production of pistons with reinforcement parts made of austenitic cast iron according to claim 2, the reinforcement parts according to claim 3 preferably being ring carriers.
  • the reinforcement parts must be annealed in an oven atmosphere with oxidizing and reducing components in order to largely avoid the formation of concentration differences due to nickel diffusion on the surface and the formation of iron oxides on the surface a surface formed in this way has a disruptive effect in the subsequent process steps.
  • Fig. 1 shows a cross section of an Alfin bond according to the invention with edge-graphitized reinforcement part
  • Fig. 2 shows a cross section of an Alfin bond without edge graphitization for comparison.
  • a reinforcement part made of austenitic cast material 1 with lamellar graphite formation is connected to a piston material AlSil2CuNiMg 2 by an Alfin layer 3.
  • the austenitic cast material is edge-graphitized in the area of the alfin bond to a depth of approx. 100-150 ⁇ m.
  • the de-graphitization is carried out by annealing the casting material in exogas at temperatures of at least o o
  • the content of CO and CO and the dew point must be set so that there is a good decarburizing effect in order to achieve short annealing times. In the present case, the glow time was 25 minutes.
  • exogas which has both reducing and oxidizing components, largely avoids differences in concentration and the formation of oxides on the surface.
  • the further process steps correspond to the Alfin process known in the prior art.
  • the compact graphite lamellae instead of the compact graphite lamellae, only loosened, non-coherent, pearl-cord-shaped oxides can be seen in the alfin layer 3, which do not have an effect on the strength of the alfin layer, or at least have a significantly lower effect than the graphite lamellae of an unannealed austenitic cast iron.
  • FIG. 2 A conventional alfin layer is shown in FIG. 2 only for comparison. There, the Alfin layer 4 is clearly penetrated by graphite lamellae, which weaken the Alfin bond, since they act as defects.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Pistons, Piston Rings, And Cylinders (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)

Abstract

The aim is to improve the strength of an intermetallic bond between engine component made from an aluminium alloy and a reinforcing element made from austenitic cast iron. For that purpose, the reinforcing element is annealed in a decarbonising atmosphere before the known prior art alfin process is carried out, in order to obtain an alfin layer largely free of graphite scales.

Description

Verfahren zur Herstellung einer intermetallischen Verbindung Process for producing an intermetallic compound
Die Erfindung befaßt sich mit einem Verfahren zur Herstel¬ lung einer intermetallischen Verbindung zwischen einem Mo¬ torenbauteil aus einer Aluminium-Basis-Legierung und einem Bewehrungsteil aus austenitischem Gußeisen, die gießtech¬ nisch miteinander verbunden werden. Entsprechende Verfahren werden insbesondere zum Einbringen von Ringträgern, verein¬ zelt auch zum Einbringen von Muldenrandbewehrungen bei Die¬ sel-Motoren angewendet.The invention relates to a method for producing an intermetallic connection between a motor component made of an aluminum-based alloy and a reinforcement part made of austenitic cast iron, which are connected to one another by casting technology. Corresponding methods are used in particular for introducing ring girders, occasionally also for introducing trough edge reinforcements in diesel engines.
Dabei wird die Verbindung des Bewehrungsteils mit dem Kol- benwerkstoff mit dem im Stand der Technik seit ca. 1950 be¬ kannten Alfin-Verfahren hergestellt, indem das Bewehrungs¬ teil vor dem Umgießen mit dem Kolbenwerkstoff in eine AlSi- Schmelze getaucht wird, wobei sich an der Oberfläche des Bewehrungsteils eine intermetallische Schicht ausbildet.The reinforcement part is connected to the piston material using the Alfin process, which has been known in the prior art since approx. 1950, by immersing the reinforcement part in an AlSi melt before the piston material is cast around it forms an intermetallic layer on the surface of the reinforcement part.
Mit den bei Dieselmotoren in der Vergangenheit kontinuier¬ lich gestiegenen Zünddrücken zeigten sich die Festigkeits¬ grenzen der bisher produzierten Alfin-Bindung, so daß nun eine höhere Bindungsfestigkeit gefordert wird.With the ignition pressures which have risen continuously in the past in the case of diesel engines, the strength limits of the Alfin bond produced to date have become apparent, so that a higher bond strength is now required.
Es wurde daher in DE-OS 42 21 448 schon vorgeschlagen, als Bewehrungsmaterial austenitisches Gußeisen mit globularer oder vermicularer Graphitausbildung zu verwenden, wodurch im Vergleich mit dem üblichen GGL-Werkstoff mit lamellarer Graphitausbildung die Bindungsfestigkeit infolge der gerin¬ geren Kerbwirkung der in der Schicht eingebundenen Graphit¬ partikel verbessert wird. Diese Lösung bringt allerdings auch verschiedene Nachteile mit sich. Sie bedeutet zunächst die Abkehr von einem seit langem be¬ währten Ringträgerwerkstoff. Außerdem weist der bisherige GGL-Ringträgerwerkstoff eine bessere Bearbeitbarkeit, höhe¬ re Wärmeleitfähigkeit und eine höhere Verschleißfestigkeit auf und ist etwas billiger als der GGG-Ringträgerwerkstoff.It has therefore already been proposed in DE-OS 42 21 448 to use austenitic cast iron with globular or vermicular graphite formation as the reinforcement material, as a result of which, in comparison with the conventional GGL material with lamellar graphite formation, the bond strength due to the lower notch effect of the bound in the layer Graphite particle is improved. However, this solution also has various disadvantages. First of all, it means turning away from a ring carrier material that has been tried and tested for a long time. In addition, the previous GGL ring carrier material has better machinability, higher thermal conductivity and higher wear resistance and is somewhat cheaper than the GGG ring carrier material.
Die Erfindung beschäftigt sich daher mit dem Problem, die Festigkeit der intermetallischen Bindung zwischen Umguß und Bewehrungsteil unabhängig von der Verwendung eines GGG- oder GGL-Werkstoffs zu erhöhen.The invention is therefore concerned with the problem of increasing the strength of the intermetallic bond between the casting and the reinforcement part regardless of the use of a GGG or GGL material.
Dieses Problem wird durch ein Verfahren mit den Merkmalen des Anspruchs 1 gelöst.This problem is solved by a method with the features of claim 1.
Ein wesentliches Anwendungsgebiet für das erfindungsgemäße Verfahren liegt in der Herstellung von Kolben mit Beweh¬ rungsteilen aus austenitischem Gußeisen gemäß Anspruch 2, wobei die Bewehrungsteile gemäß Anspruch 3 vorzugsweise Ringträger sind.An essential area of application for the method according to the invention is in the production of pistons with reinforcement parts made of austenitic cast iron according to claim 2, the reinforcement parts according to claim 3 preferably being ring carriers.
Durch das Glühen des austenitischen Grundwerkstoffs bis zur weitgehenden Entgraphitisierung des bei der Herstellung der intermetallischen Bindung beteiligten Bereichs wird die Kerbwirkung der Graphitlamellen bzw. anderer Graphitparti¬ kel auf einfache und kostengünstige Art und Weise verhin¬ dert und es kann sich eine nahezu störungsfreie intermetal¬ lische Schicht ausbilden. Erste Abrißversuche zeigen, daß die Zugfestigkeit der erfindungsgemäßen Schicht - vergli¬ chen mit der Zugfestigkeit konventioneller Alfin- Bindungen - um mindestens 30% gesteigert werden konnte.The notching effect of the graphite flakes or other graphite particles is prevented in a simple and cost-effective manner by annealing the austenitic base material until the region of the region involved in the production of the intermetallic bond is largely decagitized, and an almost trouble-free intermetal can be achieved Form layer. Initial tear tests show that the tensile strength of the layer according to the invention - compared to the tensile strength of conventional alfin bonds - could be increased by at least 30%.
Das Glühen der Bewehrungsteile muß in einer Ofenatmosphäre mit oxidierenden und reduzierenden Bestandteilen erfolgen, um die Entstehung von Konzentrationsunterschieden durch Diffusion des Nickels an die Oberfläche und die Bildung von Eisenoxiden an der Oberfläche weitgehend zu vermeiden, da eine so gebildete Oberfläche bei den nachfolgenden Verfah¬ rensschritten störend wirkt.The reinforcement parts must be annealed in an oven atmosphere with oxidizing and reducing components in order to largely avoid the formation of concentration differences due to nickel diffusion on the surface and the formation of iron oxides on the surface a surface formed in this way has a disruptive effect in the subsequent process steps.
Die Erfindung wird im folgenden anhand eines Ausführungs¬ beispiels beschrieben.The invention is described below using an exemplary embodiment.
Es zeigt:It shows:
Fig. 1 einen Querschliff einer erfindungsgemäßen Alfin-Bindung mit randentgraphitisiertem BewehrungsteilFig. 1 shows a cross section of an Alfin bond according to the invention with edge-graphitized reinforcement part
Fig. 2 einen Querschliff einer Alfin-Bindung ohne Randentgraphitisierung zum Vergleich.Fig. 2 shows a cross section of an Alfin bond without edge graphitization for comparison.
Ein Bewehrungsteil aus austenitischem Gußwerkstoff 1 mit lamellarer Graphitausbildung ist mit einem Kolbenwerkstoff AlSil2CuNiMg 2 durch eine Alfin-Schicht 3 verbunden. Der austenitische Gußwerkstoff ist im Bereich der Alfinbindung bis zu einer Tiefe von ca. 100-150 _μm randentgraphiti- siert. Die Entgraphitisierung erfolgt durch Glühen des Gu߬ werkstoffs in Exogas, bei Temperaturen von mindestens o oA reinforcement part made of austenitic cast material 1 with lamellar graphite formation is connected to a piston material AlSil2CuNiMg 2 by an Alfin layer 3. The austenitic cast material is edge-graphitized in the area of the alfin bond to a depth of approx. 100-150 μm. The de-graphitization is carried out by annealing the casting material in exogas at temperatures of at least o o
800 C und vorzugsweise bei Temperaturen > 1000 C. Dabei sind der Gehalt an CO und CO und der Taupunkt so einzu¬ stellen, daß sich eine gut entkohlende Wirkung ergibt, um kurze Glühzeiten zu erreichen. Im vorliegenden Fall lag die Glühzeit bei 25 min.800 C and preferably at temperatures> 1000 C. The content of CO and CO and the dew point must be set so that there is a good decarburizing effect in order to achieve short annealing times. In the present case, the glow time was 25 minutes.
Durch die Verwendung von Exogas, das sowohl reduzierende als auch oxidierende Anteile aufweist, werden Konzentrati¬ onsunterschiede und die Bildung von Oxiden an der Oberflä¬ che weitgehend vermieden.The use of exogas, which has both reducing and oxidizing components, largely avoids differences in concentration and the formation of oxides on the surface.
Die weiteren Verfahrensschritte entsprechen dem im Stand der Technik bekannten Alfin-Verfahren. In der Alfin-Schicht 3 sind an Stelle der kompakten Gra¬ phitlamellen nur noch aufgelockerte, nicht kohärente, perl- schnurförmige Oxide zu erkennen, die sich auf die Festig¬ keit der Alfin-Schicht nicht oder zumindest wesentlich ge¬ ringer auswirken als die Graphitlamellen eines ungeglühten austenitischen Gußeisens.The further process steps correspond to the Alfin process known in the prior art. Instead of the compact graphite lamellae, only loosened, non-coherent, pearl-cord-shaped oxides can be seen in the alfin layer 3, which do not have an effect on the strength of the alfin layer, or at least have a significantly lower effect than the graphite lamellae of an unannealed austenitic cast iron.
Nur zum Vergleich wird in Fig. 2 eine konventionelle Alfin- Schicht dargestellt. Dort wird die Alfin-Schicht 4 deutlich erkennbar von Graphitlamellen durchsetzt, die die Alfin¬ Bindung schwächen, da sie als Störstellen wirken. A conventional alfin layer is shown in FIG. 2 only for comparison. There, the Alfin layer 4 is clearly penetrated by graphite lamellae, which weaken the Alfin bond, since they act as defects.

Claims

PatentanspruchClaim
Verfahren zur Herstellung einer intermetallischen Ver¬ bindung zwischen einem Motoren-Bauteil aus einer ersten Aluminium-Basis-Legierung und einem Bewehrungsteil aus austenitischem Gußeisen, die gießtechnisch miteinander verbunden werden, mit den VerfahrensschrittenProcess for producing an intermetallic connection between a motor component made of a first aluminum-based alloy and a reinforcement part made of austenitic cast iron, which are connected to one another by casting technology, with the process steps
a) Glühen des Bewehrungsteils in einer Ofenatmo¬ sphäre mit oxidierenden und reduzierenden Gas¬ anteilen zwecks zumindest teilweiser Zerset¬ zung der im Bereich der Oberfläche des Beweh¬ rungsteils liegenden Graphitlamellen oder Gra¬ phitpartikela) Annealing of the reinforcement part in an oven atmosphere with oxidizing and reducing gas components for the purpose of at least partial decomposition of the graphite lamellae or graphite particles lying in the area of the surface of the reinforcement part
b) Tauchen des Bewehrungsteils in einer Schmelze aus einer zweiten Aluminium-Basis-Legierung zwecks Ausbildung einer intermetallischen Bin¬ deschicht,b) immersing the reinforcement part in a melt of a second aluminum-based alloy in order to form an intermetallic bonding layer,
c) Entnahme des Bewehrungsteils aus dem Tauchbad, Einlegen des Bewehrungsteils in eine Gießform und direkt daran anschließendes Umgießen des Bewehrungsteils mit der ersten Aluminium-Ba¬ sis-Legierung. c) Removing the reinforcement part from the immersion bath, inserting the reinforcement part into a casting mold and then casting the reinforcement part directly afterwards with the first aluminum-base alloy.
2. Leichtmetallkolben mit einem Bewehrungsteil aus auste¬ nitischem Gußeisen, gekennzeichnet durch eine nach dem in Anspruch 1 angegebenen Verfahren her¬ gestellte intermetallische Bindung zwischen Kolben und Bewehrungsteil.2. Light metal piston with a reinforcement made of auste¬ nitical cast iron, characterized by an intermetallic bond between the piston and the reinforcement made according to the method specified in claim 1.
3. Leichtmetallkolben nach Anspruch 2, dadurch gekennzeichnet, daß das Bewehrungsteil ein Ringträger ist.3. Light metal piston according to claim 2, characterized in that the reinforcement part is a ring carrier.
4. Leichtmetallkolben nach Anspruch 2, dadurch gekennzeichnet, daß in der intermetallischen Bindung - verglichen mit dem Grundwerkstoff des Bewehrungsteils - keine kompak¬ ten Graphitlamellen oder Graphitpartikel vorliegen. 4. Light metal piston according to claim 2, characterized in that in the intermetallic bond - compared to the base material of the reinforcement part - no compact graphite lamellae or graphite particles are present.
EP96945136A 1995-10-11 1996-09-20 Process for producing an intermetallic join Expired - Lifetime EP0854763B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE19537847A DE19537847A1 (en) 1995-10-11 1995-10-11 Reinforcement part, the base material of which is austenitic cast iron
DE19537847 1995-10-11
PCT/DE1996/001808 WO1997013597A2 (en) 1995-10-11 1996-09-20 Process for producing an intermetallic join

Publications (2)

Publication Number Publication Date
EP0854763A2 true EP0854763A2 (en) 1998-07-29
EP0854763B1 EP0854763B1 (en) 1999-09-01

Family

ID=7774578

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96945136A Expired - Lifetime EP0854763B1 (en) 1995-10-11 1996-09-20 Process for producing an intermetallic join

Country Status (6)

Country Link
US (1) US6112802A (en)
EP (1) EP0854763B1 (en)
JP (1) JPH11514931A (en)
BR (1) BR9610925A (en)
DE (2) DE19537847A1 (en)
WO (1) WO1997013597A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU773579B2 (en) * 2000-08-10 2004-05-27 Breville Pty Ltd Improvements in forming metallic laminates
DE10103596A1 (en) * 2001-01-26 2002-08-01 Bruehl Eisenwerk Method for producing a cast workpiece formed from at least two different metal materials
DE10103896A1 (en) * 2001-01-30 2002-08-08 Mahle Gmbh Process for the pretreatment of a ring carrier before the finishing
DE10137436C2 (en) * 2001-07-31 2003-07-31 Ks Kolbenschmidt Gmbh Pre-finishing of cast parts
DE10153306B4 (en) * 2001-10-31 2010-07-15 Daimler Ag Method for pouring an insert
DE10157478A1 (en) * 2001-11-23 2003-06-05 Fne Gmbh Compound metal material is a shaped first metal, e.g. a wire coil, embedded in a ground matrix of the second metal.
DE10205798A1 (en) * 2002-02-13 2003-09-04 Federal Mogul Wiesbaden Gmbh Metallic insert for inserting in an upper part and/or a lower part or a reinforcing rib of a bearing block made of cast aluminum alloy or cast aluminum has on its outer peripheral surface a cover layer made of aluminum alloy or aluminum
EP1485514A1 (en) * 2002-03-18 2004-12-15 Karl Merz Method and device for the alfin processing of components
DE102012011992A1 (en) * 2012-06-16 2013-12-19 Volkswagen Aktiengesellschaft Metallic cast component and method of making a metallic cast component
DE102012220645B3 (en) * 2012-11-13 2014-04-03 Federal-Mogul Nürnberg GmbH Piston for internal combustion engine, has cooling duct that is formed entirely in cast-on upper portion made from aluminum or aluminum alloy, and ring box that is formed in base portion made from steel

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1048677B (en) * 1959-01-15 Mahle-Werk Gesellschaft mit be schrankter Haftung, Fellbach (Wurtt) Process for applying an aluminum or aluminum oxide coating to an iron alloy - for example cast iron - existing and to be cast around with light metal in the die casting process Em position pieces
US2620530A (en) * 1945-02-07 1952-12-09 United Engine & Machine Co Manufacture of pistons
DE901104C (en) * 1949-11-10 1954-01-07 Fairchild Engine And Airplane Composite casting and process for its manufacture
US2550879A (en) * 1949-11-10 1951-05-01 Fairchild Engine & Airplane Bimetallic piston
US2775493A (en) * 1953-11-27 1956-12-25 Gillett & Eaton Inc Piston with head insert and process of making it
JPS5125214B2 (en) * 1973-02-09 1976-07-29
CH645562A5 (en) * 1980-06-19 1984-10-15 Sulzer Ag Process for welding workpieces of nodular cast iron
JPS59185567A (en) * 1983-04-08 1984-10-22 Usui Internatl Ind Co Ltd Pretreatment of cast iron member joined by adhering
IT1183114B (en) * 1985-01-11 1987-10-05 Ass Eng Italia ALUMINUM OR ALUMINUM ALLOY PISTON FOR INTERNAL COMBUSTION ENGINES
SU1507532A1 (en) * 1987-10-13 1989-09-15 Научно-исследовательский институт автотракторных материалов Method of producing castings of piston with cast iron insert from aluminium alloy
DE4010474A1 (en) * 1990-03-31 1991-10-02 Kolbenschmidt Ag LIGHT METAL PISTON
DE4019983A1 (en) * 1990-06-22 1992-01-02 Kolbenschmidt Ag LIGHT METAL PISTON
US5333668A (en) * 1991-12-09 1994-08-02 Reynolds Metals Company Process for creation of metallurgically bonded inserts cast-in-place in a cast aluminum article
DE4221448A1 (en) * 1992-06-30 1994-01-13 Mahle Gmbh Reinforcement material for pistons of internal combustion engines

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9713597A3 *

Also Published As

Publication number Publication date
JPH11514931A (en) 1999-12-21
WO1997013597A2 (en) 1997-04-17
DE19537847A1 (en) 1997-04-17
WO1997013597A3 (en) 1997-06-05
BR9610925A (en) 1999-06-29
EP0854763B1 (en) 1999-09-01
US6112802A (en) 2000-09-05
DE59602965D1 (en) 1999-10-07

Similar Documents

Publication Publication Date Title
WO1997013597A2 (en) Process for producing an intermetallic join
DE2632739A1 (en) METHOD OF APPLYING A SELF-ADHESIVE COATING MADE OF A NICKEL-ALUMINUM ALLOY OR A NICKEL-TITANIUM ALLOY TO A SUBSTRATE BY SPRAYING USING AN ARC SPRAY GUN AND THE FORM WITH IT
DE10310865B3 (en) Use of an iron-chromium-aluminum alloy containing additions of hafnium, silicon, yttrium, zirconium and cerium, lanthanum or neodymium for components in Diesel engines and two-stroke engines
DE2931116C2 (en) Piston ring for a piston of an internal combustion engine
EP1444421A1 (en) Method for the production of a valve seat
DE2903080A1 (en) METHOD OF FORMING AN ALUMINUM COATING LAYER ON AN IRON ALLOY WORKPIECE
DE19729017A1 (en) Cylinder sleeve for IC motors and piston compressors
DE10043108A1 (en) Production of a metallurgical toughened bond between a coated insert and a casting material comprises applying a first thin layer to the insert, applying a second thin layer and casting the casting material against the surface of the insert
DE19855908C2 (en) Process for forming a graphite-free surface of an iron-containing material to produce an improved intermetallic bond
DE3221312A1 (en) Steel pipe
DE3114124A1 (en) ALUMINUM PISTON WITH HARDOXIZED BOTTOM
DE19940022A1 (en) Piston ring, especially the second pressure ring of a direct injection diesel engine, consists of a surface nitrided steel of relatively low chromium content
EP0712340B1 (en) Casting process for producing a workpiece, in particular a piston, made of two different materials
WO1997013396A2 (en) Reinforcing component of which the basic material is austenitic cast iron
DE3300582C2 (en) Process for the powder metallurgical production of ring carriers
AT6041U1 (en) COLD DRAWN WIRE AND METHOD FOR PRODUCING IT
DE3343976A1 (en) METHOD FOR TREATING CAST IRON PARTS BEFORE CONNECTING TO OTHER PARTS
DE3633879C2 (en)
DE2352704A1 (en) WELDABLE, OXIDATION-RESISTANT COBALT ALLOY
DE3435460A1 (en) METHOD FOR PRODUCING WORKPIECES FROM LIGHT METAL
DE3700089C2 (en)
EP0437685B1 (en) Soot filter
DE4321921A1 (en) Overhead wire (contact wire) and a method for its production
DD222930A1 (en) WEAR-RESISTANT LIGHT METAL PISTON AND METHOD FOR THE PRODUCTION THEREOF
DE3114701C2 (en) Process for surfacing a metal layer on an aluminum alloy

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 19980218

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): DE FR GB IT

17Q First examination report despatched

Effective date: 19980714

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAG Despatch of communication of intention to grant

Free format text: ORIGINAL CODE: EPIDOS AGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB IT

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 19990902

REF Corresponds to:

Ref document number: 59602965

Country of ref document: DE

Date of ref document: 19991007

ITF It: translation for a ep patent filed

Owner name: DE DOMINICIS & MAYER S.R.L.

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20080926

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20080924

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20080930

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20080922

Year of fee payment: 13

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20090920

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20100531

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090930

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20100401

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090920

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090920