EP0847455A1 - Production of diamond dressers - Google Patents

Production of diamond dressers

Info

Publication number
EP0847455A1
EP0847455A1 EP96928616A EP96928616A EP0847455A1 EP 0847455 A1 EP0847455 A1 EP 0847455A1 EP 96928616 A EP96928616 A EP 96928616A EP 96928616 A EP96928616 A EP 96928616A EP 0847455 A1 EP0847455 A1 EP 0847455A1
Authority
EP
European Patent Office
Prior art keywords
electrolyte
current
mould
procesε
nickel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96928616A
Other languages
German (de)
French (fr)
Other versions
EP0847455B1 (en
Inventor
Peter David Morris
Stephen Leslie Noakes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Consort Precision Diamond Co Ltd
Original Assignee
Consort Precision Diamond Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consort Precision Diamond Co Ltd filed Critical Consort Precision Diamond Co Ltd
Publication of EP0847455A1 publication Critical patent/EP0847455A1/en
Application granted granted Critical
Publication of EP0847455B1 publication Critical patent/EP0847455B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0018Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for by electrolytic deposition
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires

Definitions

  • Thi ⁇ invention concerns the production of diamond dressers.
  • Diamond dressers sometimes known as diamond profile rolls, are mainly used in the aero engine and motor engine manufacturing industries.
  • a diamond dresser is generally circular in shape with its .periphery coated with diamonds to a predetermined configuration of high tolerance.
  • a diamond dresser is mounted on a grinding machine and rotated by means of an independent drive unit to dress the configuration of the dresser onto a rotating abrasive (grinding) wheel. The grinding wheel is then ready for use in forming and finishing component ⁇ especially of aero- and motor engines.
  • Diamond dressers are generally made by first forming a graphite mould to high accuracy, the internal profile of the mould matching the desired external profile of the finished diamond dresser. Diamonds are then adhered onto the internal surface of the mould and the mould is placed in a bath of electrolyte. The mould forms the cathode and a basket of nickel pellets form the anode, so that nickel is deposited on the diamond layer by an electro-plating process. The electro ⁇ plating process is continued until a layer of nickel of sufficient depth has been deposited on the diamonds. A solid steel shaft is then fitted in the centre of the mould using a low melting alloy. When the mould has cooled, the end faces of the mould are machined in a lathe and the graphite mould broken away to leave the diamond dresser.
  • each electro-plating process reguires a large area of operation as each mould has to be in its own electrolyte bath and each bath reguires a heating jacket to bring the electrolyte up to a suitable operating temperature.
  • An object of this invention is to provide an improved process and apparatus for producing diamond dressers.
  • a process for producing diamond dressers including the steps of forming a mould for the dresser having a desired internal profile, adhering diamonds to said profile, and electro-plating a metal, typically nickel, onto the diamonds, characterised in that the electro-plating process is carried out with agitation of the electrolyte.
  • apparatu ⁇ for producing diamond dressers comprising a electrolyte bath for receiving a mould of graphite having a desired internal profile coated with diamonds as cathode, a metal source, typically nickel, as anode and means for passing current between the anode and cathode, whereby metal is deposited on the diamonds, characteri ⁇ ed by mean ⁇ for agitating the electrolyte.
  • the electrolyte may be agitated in any ⁇ uitable way.
  • electrolyte i ⁇ pumped through the mould.
  • the electrolyte i ⁇ preferably pumped through a plate having angled pa ⁇ age ⁇ for the electrolyte.
  • the ⁇ e pa ⁇ ages preferably have an entrance on one radius and an exit on another radius spaced axially from the one radius in order to impart the desired swirling motion to the electrolyte.
  • agitation of the electrolyte in the mould eliminate ⁇ air entrapment in the metal coating and hence reduces poro ⁇ ity.
  • nodule formation ⁇ on the metal coating may be reduced or even eliminated because of the agitation.
  • the invention can produce required nickel depths on the diamonds within a much ⁇ horter time period than hitherto. Typically a desirable depth of nickel may be achieved in under 7 days and even in about 3 1 / 2 days.
  • the electrolyte bath i ⁇ preferably maintained at a temperature above 35°C. Lower temperatures tend to result in uneven nickel growth on the diamonds.
  • the electrolyte temperature is preferably in the range of 39 to 41°C.
  • the electrolyte for nickel plating is preferably nickel ⁇ ulfamate ideally at a concentration in the range of 550 to 650 g/litre.
  • the electrolyte may contain hardener and other additive ⁇ , typically boric acid, nickel chloride and wetting agent.
  • the electrolyte preferably has an acidic pH of above 3.5.
  • the diamonds may be adhered to the graphite mould in any suitable way.
  • a conductive adhesive is preferably used for this purpose, such as a silver ba ⁇ ed adhe ⁇ ive, especially a silver loaded epoxy adhesive.
  • the nickel used for the electro-plating process is preferably in the form of pellets. These are ideally contained in a ba ⁇ ket in the electrolyte within the graphite mould.
  • the basket is preferably made of a conductive material that is not reactive with nickel.
  • the preferred basket for use in the invention is made of titanium.
  • the electro-plating proces ⁇ i ⁇ preferably commenced at low current, which may be dependent on the area to be plated. The larger the area to be plated, the higher is the current used. Typically the start current u ⁇ ed will be in the region of 2 amps and will be raised incremently up to 12-14 amps. The ⁇ tart current may be maintained for 16-24 hours and the final current may be maintained for up to 48 hours.
  • This gradual raising of the current may be achieved manually ie with regular attendance at the apparatus to adjust manually the current up to the maximum current to be used. It is preferred, however, that such raising of the current be independently controlled, ⁇ o that attendance at the apparatus can be kept to a minimum.
  • the raising of the current is pulsed, in other words, a con ⁇ tant current i ⁇ preferably ⁇ witched from one level to another in a pre ⁇ determined, e ⁇ pecially regular, manner.
  • Rai ⁇ ing of the current i ⁇ preferably controlled by a microproce ⁇ or or computer. It is believed that pulsed electro-plating may have several advantages. These advantages include that the metal (nickel) depo ⁇ ited will be finer, purer and ⁇ oother.
  • the rate of metal (nickel) depo ⁇ ition may be increa ⁇ ed.
  • a better plating di ⁇ tribution may be achieved.
  • the electro ⁇ plating process may be commenced at any time during the working day and left to reach it ⁇ maximum operating current at any de ⁇ ired time day or night.
  • the mould can be removed from the electrolyte bath and fini ⁇ hed in the usual way.
  • metal such as nickel
  • the mould can be removed from the electrolyte bath and fini ⁇ hed in the usual way.
  • Traditionally only a single diamond dresser mould is electro-processed at a time in an electrolyte bath. It has now been found that a multiple diamond dresser mould can be proces ⁇ ed in a ⁇ ingle bath using the present invention. After electro-proce ⁇ ing the mould i ⁇ ⁇ plit and each part fini ⁇ hed conventionally.
  • Figure 1 hows ⁇ chematically a prior art apparatus for producing a diamond dresser
  • Figure 2 show ⁇ schematically an apparatus according to the invention for producing a diamond dresser
  • Figure 3 is a section through apparatus of the invention for producing multiple diamond dressers in a single operation.
  • a diamond dres ⁇ er i ⁇ produced conventionally, in the following manner.
  • a graphite mould 10 is prepared having an internal profile 12 matching the de ⁇ ired outer profile of the diamond dresser to be made.
  • a coating 14 of diamonds is adhered to the profile 12 using a conductive adhesive.
  • the diamond coated mould 10 is placed in a bath of electrolyte 16 comprising an aqueous solution of nickel sulfamate.
  • a porous ceramic tube 18 within which is placed a titanium basket 20 containing nickel pellets 22.
  • the nickel pellets form the anode and the mould 10 the cathode of an electrolytic cell.
  • a constant current is applied acros ⁇ the anode and cathode for a sufficient period of time to deposit by electro-plating a layer of nickel 25 on the diamonds of a desired thickness.
  • the deposition period will be around 30-35 days.
  • the titanium ba ⁇ ket of nickel pellet ⁇ is replaced by a bianode, so that the basket can be flushed with water to remove debris.
  • the pH of the electrolyte i ⁇ checked daily. Attempts to reduce the electro-plating time by increasing current density have proved unsuccessful.
  • the resultant nickel coating was uneven, modular and pitted. In mould recesses nickel plating was found to be thinner than elsewhere.
  • the mould After completion of the nickel plating, the mould is removed from the electrolyte bath, a steel shaft fixed in the centre of the mould using a low melting alloy and the graphite mould broken away. Finishing of end faces of the dresser on a lathe completes the production proces ⁇ .
  • Electrolyte Nickel sulfamate with additions of boric acid, nickel chloride and wetting agent. Electrolyte temperature: 40 + 1°C. Electrolyte pH: acidic above 3.5. Current Den ⁇ ity: dependent on surface area to be plated and to be increased gradually during plating period up to, for example 14 amps.
  • Electro-plating time 3.5 days.
  • FIG. 3 of the accompanying drawing ⁇ shows how the principles of the apparatu ⁇ of Figure 2 can be extended to enable more than one diamond dre ⁇ ser to be made at one time.
  • a bath 50 of nickel sulfamate electrolyte (as in Figure 2) contains a cylindrical plastics chamber 52 having a base 54 and a top 56.
  • the base 54 includes an inlet pipe 58 connected to a filter pump (not ⁇ hown) leading to an entry flange 60 which enclo ⁇ e ⁇ a multi-entry manifold 62.
  • a turbulence plate 64 having angled pa ⁇ sage ⁇ 66 therethrough for delivering electrolyte pumped from the electrolyte bath.
  • the passage ⁇ 66 are angled outward and upward ⁇ a ⁇ well a ⁇ into and out of the paper re ⁇ pectively in order to impart a ⁇ wirling or turbulent motion to the electrolyte as it emerges into the chamber 52.
  • Al ⁇ o from the base of the chamber are return pipes 68 for the electrolyte.
  • a graphite mould 70 Seated on the turbulence plate 64 i ⁇ a graphite mould 70 which ha ⁇ three dre ⁇ er form ⁇ 70A, B and C leaving a gap between each.
  • the internal profile of the mould is coated with diamonds 71 in the area of each dresser form. The diamonds being adhered using a silver loaded epoxy adhesive.
  • a porous ceramic tube 72 enclosing a titanium basket 74 containing nickel pellets 76 is fitted in the chamber 52 through its top 56 centrally of the mould 70.
  • the titanium ba ⁇ ket and the graphite mould are connected to a d.c. current ⁇ upply a ⁇ anode and cathode re ⁇ pectively.
  • the operating condition ⁇ for the apparatu ⁇ of Figure 3 were ⁇ ub ⁇ tantially the ⁇ ame as for the apparatu ⁇ of Figure 2, i.e. with the electrolyte being continuously pumped through the chamber 52. After completion of the electro-plating, the mould 70 is removed and the three dresser forms separated and finished off conventionally.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
  • Disintegrating Or Milling (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Grinding-Machine Dressing And Accessory Apparatuses (AREA)

Abstract

A process for producing diamond dressers by electro-plating nickel (76) onto diamonds (71) adhered to a graphite mould (70) includes the step of agitating the electrolyte and apparatus for producing such diamond dressers includes means for agitating the electrolyte.

Description

TITLE: Production of Diamond Dressers
DESCRIPTION
Thiε invention concerns the production of diamond dressers. Diamond dressers, sometimes known as diamond profile rolls, are mainly used in the aero engine and motor engine manufacturing industries. A diamond dresser is generally circular in shape with its .periphery coated with diamonds to a predetermined configuration of high tolerance. A diamond dresser is mounted on a grinding machine and rotated by means of an independent drive unit to dress the configuration of the dresser onto a rotating abrasive (grinding) wheel. The grinding wheel is then ready for use in forming and finishing componentε especially of aero- and motor engines.
Diamond dressers are generally made by first forming a graphite mould to high accuracy, the internal profile of the mould matching the desired external profile of the finished diamond dresser. Diamonds are then adhered onto the internal surface of the mould and the mould is placed in a bath of electrolyte. The mould forms the cathode and a basket of nickel pellets form the anode, so that nickel is deposited on the diamond layer by an electro-plating process. The electro¬ plating process is continued until a layer of nickel of sufficient depth has been deposited on the diamonds. A solid steel shaft is then fitted in the centre of the mould using a low melting alloy. When the mould has cooled, the end faces of the mould are machined in a lathe and the graphite mould broken away to leave the diamond dresser.
To avoid a build up of stress or porosity in the nickel and to avoid excessive over plating, the electro¬ plating process is carried out slowly at a low current density. Typically the electro-plating process can take as long as 32 days. That length of time increases costs and causeε considerable delays between receipt of and completion of an order for a diamond dresser. Furthermore, each electro-plating process reguires a large area of operation as each mould has to be in its own electrolyte bath and each bath reguires a heating jacket to bring the electrolyte up to a suitable operating temperature.
An object of this invention is to provide an improved process and apparatus for producing diamond dressers.
According to a first aspect of this invention, there is provided a process for producing diamond dressers including the steps of forming a mould for the dresser having a desired internal profile, adhering diamonds to said profile, and electro-plating a metal, typically nickel, onto the diamonds, characterised in that the electro-plating process is carried out with agitation of the electrolyte.
According to a second aspect of this invention there is provided apparatuε for producing diamond dressers comprising a electrolyte bath for receiving a mould of graphite having a desired internal profile coated with diamonds as cathode, a metal source, typically nickel, as anode and means for passing current between the anode and cathode, whereby metal is deposited on the diamonds, characteriεed by meanε for agitating the electrolyte. The electrolyte may be agitated in any εuitable way. In a preferred embodiment electrolyte iε pumped through the mould. Preferably a εwirling motion iε imparted to the electrolyte. To that end the electrolyte iε preferably pumped through a plate having angled paεεageε for the electrolyte. Theεe paεεages preferably have an entrance on one radius and an exit on another radius spaced axially from the one radius in order to impart the desired swirling motion to the electrolyte. It iε believed that agitation of the electrolyte in the mould eliminateε air entrapment in the metal coating and hence reduces poroεity. Furthermore, nodule formationε on the metal coating may be reduced or even eliminated because of the agitation. Further, it has been found that the invention can produce required nickel depths on the diamonds within a much εhorter time period than hitherto. Typically a desirable depth of nickel may be achieved in under 7 days and even in about 31/2 days.
The electrolyte bath iε preferably maintained at a temperature above 35°C. Lower temperatures tend to result in uneven nickel growth on the diamonds. The electrolyte temperature is preferably in the range of 39 to 41°C.
The electrolyte for nickel plating is preferably nickel εulfamate ideally at a concentration in the range of 550 to 650 g/litre. The electrolyte may contain hardener and other additiveε, typically boric acid, nickel chloride and wetting agent. The electrolyte preferably has an acidic pH of above 3.5. The diamonds may be adhered to the graphite mould in any suitable way. A conductive adhesive is preferably used for this purpose, such as a silver baεed adheεive, especially a silver loaded epoxy adhesive.
The nickel used for the electro-plating process is preferably in the form of pellets. These are ideally contained in a baεket in the electrolyte within the graphite mould. The basket is preferably made of a conductive material that is not reactive with nickel. The preferred basket for use in the invention is made of titanium. The electro-plating procesε iε preferably commenced at low current, which may be dependent on the area to be plated. The larger the area to be plated, the higher is the current used. Typically the start current uεed will be in the region of 2 amps and will be raised incremently up to 12-14 amps. The εtart current may be maintained for 16-24 hours and the final current may be maintained for up to 48 hours.
This gradual raising of the current may be achieved manually ie with regular attendance at the apparatus to adjust manually the current up to the maximum current to be used. It is preferred, however, that such raising of the current be independently controlled, εo that attendance at the apparatus can be kept to a minimum. Preferably the raising of the current is pulsed, in other words, a conεtant current iε preferably εwitched from one level to another in a pre¬ determined, eεpecially regular, manner. Raiεing of the current iε preferably controlled by a microproceεεor or computer. It is believed that pulsed electro-plating may have several advantages. These advantages include that the metal (nickel) depoεited will be finer, purer and ε oother. Secondly by raiεing the limiting current denεity, the rate of metal (nickel) depoεition may be increaεed. Thirdly, there may be improved metal adheεion to the εubεtrate. Fourthly, a better plating diεtribution may be achieved. Finally, with a programmable meanε for raising the current, the electro¬ plating process may be commenced at any time during the working day and left to reach itε maximum operating current at any deεired time day or night.
Once a desired depth of metal, such as nickel, haε been depoεited in the mould, the mould can be removed from the electrolyte bath and finiεhed in the usual way. Traditionally only a single diamond dresser mould is electro-processed at a time in an electrolyte bath. It has now been found that a multiple diamond dresser mould can be procesεed in a εingle bath using the present invention. After electro-proceεεing the mould iε εplit and each part finiεhed conventionally.
Thiε invention will now be further deεcribed, by way of example only, with reference to the accompanying drawingε, in which:-
Figure 1 εhows εchematically a prior art apparatus for producing a diamond dresser;
Figure 2 showε schematically an apparatus according to the invention for producing a diamond dresser; and
Figure 3 is a section through apparatus of the invention for producing multiple diamond dressers in a single operation.
Referring to Figure 1 of the accompanying drawings, a diamond dresεer iε produced conventionally, in the following manner. A graphite mould 10 is prepared having an internal profile 12 matching the deεired outer profile of the diamond dresser to be made. A coating 14 of diamonds is adhered to the profile 12 using a conductive adhesive. The diamond coated mould 10 is placed in a bath of electrolyte 16 comprising an aqueous solution of nickel sulfamate. Within the mould 10 iε placed a porous ceramic tube 18 within which is placed a titanium basket 20 containing nickel pellets 22. The nickel pellets form the anode and the mould 10 the cathode of an electrolytic cell. A constant current is applied acrosε the anode and cathode for a sufficient period of time to deposit by electro-plating a layer of nickel 25 on the diamonds of a desired thickness. Usually the deposition period will be around 30-35 days. Periodically, the titanium baεket of nickel pelletε is replaced by a bianode, so that the basket can be flushed with water to remove debris. Also, the pH of the electrolyte iε checked daily. Attempts to reduce the electro-plating time by increasing current density have proved unsuccessful. The resultant nickel coating was uneven, modular and pitted. In mould recesses nickel plating was found to be thinner than elsewhere. After completion of the nickel plating, the mould is removed from the electrolyte bath, a steel shaft fixed in the centre of the mould using a low melting alloy and the graphite mould broken away. Finishing of end faces of the dresser on a lathe completes the production procesε.
Referring now to Figure 2 of the accompanying drawings it has been found that agitation of the electrolyte allows the current density to be increased and hence the electro-plating time to be reduced. A main difference according to the invention over the prior art process, as illustrated in Figure 2 of the drawings, iε that the electrolyte 18 iε pumped through a baffle plate 24 having angled passages 26 therethrough which are arranged to promote a εwirling motion or turbulent flow pattern for the electrolyte through the mould. Thuε, the paεεages 26 have a lower entry on one radiuε and an upper exit on a different radius, the respective radu being axially spaced from each other.
The electro-plating conditions used in the apparatuε of Figure 2 were aε followε:
Electrolyte: Nickel sulfamate with additions of boric acid, nickel chloride and wetting agent. Electrolyte temperature: 40 + 1°C. Electrolyte pH: acidic above 3.5. Current Denεity: dependent on surface area to be plated and to be increased gradually during plating period up to, for example 14 amps.
Electro-plating time: 3.5 days.
It waε found that using a combination of electrolyte turbulence, higher electrolyte temperature than hitherto and higher current density than hitherto, a relatively uniform nickel coating could be achieved which was generally free of pitting.
Figure 3 of the accompanying drawingε shows how the principles of the apparatuε of Figure 2 can be extended to enable more than one diamond dreεser to be made at one time. A bath 50 of nickel sulfamate electrolyte (as in Figure 2) contains a cylindrical plastics chamber 52 having a base 54 and a top 56.
The base 54 includes an inlet pipe 58 connected to a filter pump (not εhown) leading to an entry flange 60 which encloεeε a multi-entry manifold 62. Above the manifold.62 iε a turbulence plate 64 having angled paεsageε 66 therethrough for delivering electrolyte pumped from the electrolyte bath. The passageε 66 are angled outward and upwardε aε well aε into and out of the paper reεpectively in order to impart a εwirling or turbulent motion to the electrolyte as it emerges into the chamber 52. Alεo from the base of the chamber are return pipes 68 for the electrolyte.
Seated on the turbulence plate 64 iε a graphite mould 70 which haε three dreεεer formε 70A, B and C leaving a gap between each. The internal profile of the mould is coated with diamonds 71 in the area of each dresser form. The diamonds being adhered using a silver loaded epoxy adhesive. A porous ceramic tube 72 enclosing a titanium basket 74 containing nickel pellets 76 is fitted in the chamber 52 through its top 56 centrally of the mould 70. The titanium baεket and the graphite mould are connected to a d.c. current εupply aε anode and cathode reεpectively.
The operating conditionε for the apparatuε of Figure 3 were εubεtantially the εame as for the apparatuε of Figure 2, i.e. with the electrolyte being continuously pumped through the chamber 52. After completion of the electro-plating, the mould 70 is removed and the three dresser forms separated and finished off conventionally.

Claims

1. A process for producing diamond dressers including the steps of forming a mould for the dresser having a desired internal profile, adhering diamonds to said profile, placing the mould in electrolyte, and electro-plating a metal onto the diamonds, characterized in that the electro-plating process is carried out with agitation of the electrolyte.
2. A process as claimed in claim 1, characterized in that the electrolyte is pumped through the mould.
3. A procesε aε claimed in claim 1 or 2, characterized in that a εwirling motion is imparted to the electrolyte.
4. A process as claimed in claim 3, characterized in that the electrolyte is pumped through a plate having angled pasεageε for the electrolyte.
5. A proceεε aε claimed in claim 4, characterized in that the passages have an entrance on one radius and an exit on another radius εpaced axially from the one radiuε.
6. A proceεε aε claimed in any one of claimε 1 to 5, characterized in that the electrolyte is maintained at a temperature above 35°C.
7. A procesε aε claimed in claim 6, characterized in that the electrolyte temperature iε maintained in the range of 39 to 41°C.
8. A procesε as claimed in any one of claimε 1 to 7, characterized in that the metal iε nickel.
9. A proceεε as claimed in claim 8, characterized in that the electrolyte is aqueous nickel sulfamate.
10. A proceεε aε claimed in claim 9, characterized in that the electrolyte concentration is in the range of 550 to 650 g/litre.
11. A procesε aε claimed in claim 9 or 10, characterized in that the electrolyte has an acidic pH of above 3.5.
12. A proceεε aε claimed in any one of claimε 1 to 11, characterized in that the diamonds are adhered to the profile by means of a conductive adhesive.
13. A process as claimed in claim 12, characterized in that the adhesive is a silver based adhesive.
14. A procesε as claimed in claim 13, characterized in that the adhesive is a silver loaded epoxy adhesive.
15. A procesε aε claimed in any one of claimε 8 to 14, characterized in that the nickel iε in the form of pelletε.
16. A proceεε aε claimed in any one of claimε 1 to 15, characterized in that the electro-plating is commenced at low current and raised gradually.
17. A procesε aε claimed in claim 16, characterized in that the electro-plating is commenced at a current in the region of 2 amp .
18, A process as claimed in claim 16 or 17, characterized in that the current is raised to 12 to 14 ampε.
19. A process as claimed in claim 16, 17 or 18, characterized in that the start current iε maintained for 16 to 24 hours.
20. A process as claimed in any one of claims 1 to
19, characterized in that the final current is maintained for up to 48 hours.
21. A proceεs as claimed in any one of claims 16 to
20, characterized in that raising of the current iε pulsed.
22. Apparatus for producing diamond dresεerε compriεing an electrolyte bath for receiving a mould of graphite having a deεired internal profile coated with diamondε aε cathode, a metal source aε anode and means for passing electric current between the anode and cathode whereby metal is deposited on the diamonds, characterized by means for agitating the electrolyte.
23. Apparatus as claimed in claim 22, characterized in that the means for agitating compriεes pump meanε.
24. Apparatus as claimed in claim 23, characterized in that said pump means is arranged to impart a swirling motion to the electrolyte.
25. Apparatus as claimed in claim 24, characterized by a plate through which the electrolyte is pumped, the plate having angled pasεageε therethrough.
26. Apparatuε as claimed in claim 25, characterized in that the pasεageε of the plate have an entrance on one radius and an exit on another radius spaced axially from the one radius.
27. Apparatus as claimed in any one of claims 22 to 26, characterized by meanε for heating the electrolyte.
28. Apparatuε aε claimed in any one of claimε 22 to 27, characterized in that the metal is contained in a basket in the electrolyte within the graphite mould.
29. Apparatus aε claimed in claim 28, characterized in that the basket iε made of conductive material that is not reactive with nickel.
30. Apparatuε as claimed in claim 28 or 29, characterized in that the basket is made of titanium.
31. Apparatuε aε claimed in any one of claimε 22 to 30 further characterized by meanε for altering the applied current.
32. Apparatuε aε claimed in claim 31, characterized by meanε for altering the applied current in a pulεed manner.
33. A proceεε aε claimed in claim 1 and εubεtantially as hereinbefore described with reference to Figures 2 and 3 of the accompanying drawings.
34. Apparatus for producing diamond dressers substantially as hereinbefore deεcribed with reference to and aε illuεtrated in Figures 2 and 3 of the accompanying drawings.
EP96928616A 1995-09-01 1996-08-30 Production of diamond dressers Expired - Lifetime EP0847455B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB9517854 1995-09-01
GBGB9517854.7A GB9517854D0 (en) 1995-09-01 1995-09-01 Production of diamond dressers
PCT/GB1996/002132 WO1997009469A1 (en) 1995-09-01 1996-08-30 Production of diamond dressers

Publications (2)

Publication Number Publication Date
EP0847455A1 true EP0847455A1 (en) 1998-06-17
EP0847455B1 EP0847455B1 (en) 1999-05-06

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EP96928616A Expired - Lifetime EP0847455B1 (en) 1995-09-01 1996-08-30 Production of diamond dressers

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EP (1) EP0847455B1 (en)
AT (1) ATE179767T1 (en)
AU (1) AU6833596A (en)
DE (1) DE69602373T2 (en)
GB (1) GB9517854D0 (en)
WO (1) WO1997009469A1 (en)

Families Citing this family (4)

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Publication number Priority date Publication date Assignee Title
WO2004094111A1 (en) * 2003-04-24 2004-11-04 Empa Eidgenössische Materialprüfungs- Und Forschungsanstalt Method for the production of an abrasive tool
DE102009007992A1 (en) * 2009-02-07 2010-08-19 Ab Skf Coating arrangement comprises a coating carrier and a layer arranged on surface of the carrier, where the layer is formed by coating of particles in quasi manner and is fixed with galvanically applied metallic materials on the surface
CN104440605B (en) * 2014-11-11 2017-08-25 富耐克超硬材料股份有限公司 A kind of superhard abrasive compound of polygonal, the method for preparing using the abrasive material grinding tool
CN112757178A (en) * 2021-01-14 2021-05-07 沈阳恒鹏商务服务有限公司 Sand feeding method of diamond roller and diamond roller

Family Cites Families (1)

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Publication number Priority date Publication date Assignee Title
US4737162A (en) * 1986-08-12 1988-04-12 Alfred Grazen Method of producing electro-formed abrasive tools

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9709469A1 *

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Publication number Publication date
AU6833596A (en) 1997-03-27
WO1997009469A1 (en) 1997-03-13
DE69602373T2 (en) 2000-01-13
ATE179767T1 (en) 1999-05-15
EP0847455B1 (en) 1999-05-06
DE69602373D1 (en) 1999-06-10
GB9517854D0 (en) 1995-11-01

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