EP0840840A1 - A catalyst carrier arrangement - Google Patents

A catalyst carrier arrangement

Info

Publication number
EP0840840A1
EP0840840A1 EP96911153A EP96911153A EP0840840A1 EP 0840840 A1 EP0840840 A1 EP 0840840A1 EP 96911153 A EP96911153 A EP 96911153A EP 96911153 A EP96911153 A EP 96911153A EP 0840840 A1 EP0840840 A1 EP 0840840A1
Authority
EP
European Patent Office
Prior art keywords
monolith
casing
gap
arrangement
section
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96911153A
Other languages
German (de)
French (fr)
Other versions
EP0840840B1 (en
Inventor
Sven Melker Nilsson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dinex Ecocat Oy
Original Assignee
Kemira Metalkat Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=20398107&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0840840(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Kemira Metalkat Oy filed Critical Kemira Metalkat Oy
Publication of EP0840840A1 publication Critical patent/EP0840840A1/en
Application granted granted Critical
Publication of EP0840840B1 publication Critical patent/EP0840840B1/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
    • F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28—Construction of catalytic reactors
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00—Structure of catalyst support or particle filter
    • F01N2330/02—Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal

Definitions

  • the subject invention concerns a carrier arrangement for catalytic converters.
  • metal substrates As substrates to be used to support the catalytic material in internal combustion engine exhaust systems ceramic materials are predominantly used. In latter years, metal substrates have, however, come into use to an increasingly large extent. The advantage of metal substrates is their ability to reach working temperatures more rapidly than do cermamic ones, as accordingly they begin their exhaust gases purification function at an earlier stage after start, which is a most essential feature. Moreover, metal substrates are more efficient thermal conductors, and thus they may be heated more quickly and the risk of local overheating is reduced. In addition, metal substrates support higher temperatures than ceramic ones.
  • metal monoliths As carrier members supporting the catalytic material so called metal monoliths are used. These consist of metal foils, preferably of stainless steel, wound into rolls wherein metal foils of flat configuration alternate with metal foils of corrugated configuration, whereby throughflow channels extending through the catalyst body are formed.
  • the foil thickness is small, normally only about 0.05 mm.
  • the catalyst body also includes a metal cover forming a jacket surrounding the monolith in contact with the latter. The cover thickness may amount to approximately 1 - 1.6 mm.
  • the thin carrier member foils are heated very rapidly.
  • the temperature quickly reaches between 500 and 800°C.
  • the temperature may rise to the range of up to between 1100 and 1200°C.
  • the temperature of the catalyst body rapidly sinks to the level of the ambient temperature.
  • the repeated temperature changes constitue a problem that affects the catalyst long-term durability.
  • the rapidly heated thin foils of the monolith also expand quickly.
  • the surrounding casing in abutment against the monolith but not in close contact with the exhausts and in addition having a larger material thickness, is heated and expands at a slower pace. During the heating, the casing thus prevents the monolith from expanding, which gives rise to considerable radial compressive forces that cause deformations to form in the monolith.
  • the strength of the metal also is reduced considerably, often down to about 10% of its strength at room temperature, which aggravates the deformations and reduces the monolith life further.
  • Fig. 1 is a broken schematical longitudinal sectional view through a catalyst body
  • Fig. 2 is a similar schematical longitudinal sectional view through a catalyst body showing a modified arrangement of attachment in accordance with the invention
  • Fig. 3 is a larger-scale view of a part of the attachment arrangement in accordance with the invention.
  • Fig. 1 illustrates a basic design of the inventive object.
  • a catalyst body 1 comprises a metal casing 2 enclosing a so called monolith 3.
  • the latter in turn consists of carrier members, designed to support a catalytic material and consisting of helically wound metal foils, arranged so that flat metal foils 4 alternate with corrugated metal foils, so as to form through-flow channels 5 extending through the catalyst body 1.
  • the monolith 3 has a width or diameter that is slightly smaller than the internal width of the casing 2. Accordingly, a gap 6 forms between the casing 2 and the monolith 3, the size of which varies within different temperature ranges.
  • the casing 2 is provided with at least one band-like depression 7, in accordance with the embodiment illustrated in the drawing figure with two such depressions, the gap 6 around the monolith 3 thus being eliminated in the area opposite said depressions.
  • the casing 2 and the monolith 3 are interconnected, preferably only at spaced intervals 8, for instance by means of soldering or welding.
  • the expansion may now take place essentially unimpededly, with the exception of in the area of the depressions 7 where a certain deformation of the outermost foil 4 of the monolith 3 will take place. Consequently, no compressive forces will generate along the major part of the surface of the monolith 3.
  • the monolith 3 may again retract and thus again open up a gap 6.
  • the catalyst body 1 may operate in an intact condition over a longer period than has hitherto been possible, with consequential increase of its serviceable life. Further improvements may be achieved by omitting to join one or some of the outermost foils 4 along the entire foil length to the the foils immediately interiorly thereof but instead joining them to one another at points spaced laterally from the points 8 of attachment. When the monolith 3 cools down, with consequential contraction, the tensile forces at the points 8 of attachment will not be very pronounced because of the resiliency imparted to the outermost foils 4 between their interconnection points. Figs.
  • FIG. 2 and 3 illustrate a modification of the mode of attachment in accordance with the invention.
  • an exhaust pipe 9 serves as the casing.
  • the monolith 3 is provided at each end with a circumferential collar 10 which projects past its associated monolith end and which is attached to the exhaust pipe 9.
  • the collars 10 preferably are attached to the monolith 3 at discrete intervals 12.
  • the collars 10 bridge a gap 11 formed between the exhaust pipe 9 and the monolith 3, the latter thus, upon heating and cooling, being given a compara- tively free space in which to expand and contract while at the same time it is securely anchored inside the exhaust pipe 9.
  • the gap 6 could be eliminated by introduction of one or several inserts between the casing 2 and the monolith 3 instead of by forming depressions 7 in the casing.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Catalysts (AREA)

Abstract

The invention concerns a carrier arrangement for catalytic converters comprising a catalyst body (1) consisting of a monolith (3) formed of carrier members desined to support a catalytic material, and of a metal casing (2, 9) enclosing the monolith (3). The interior width of the casing (2, 9) exceeds that of the monlith (3) whereby a gap (6, 11) forms between the casing (2, 9) and the monolith (3). This gap (6, 11) is bridged at least in the area of a section (7, 10) extending circumferentially around the monolith (3), the monolith (3) being attached to the casing (2, 9) along said section (7, 10).

Description

A CATALYST CARRIER ARRANGEMENT
The subject invention concerns a carrier arrangement for catalytic converters.
As substrates to be used to support the catalytic material in internal combustion engine exhaust systems ceramic materials are predominantly used. In latter years, metal substrates have, however, come into use to an increasingly large extent. The advantage of metal substrates is their ability to reach working temperatures more rapidly than do cermamic ones, as accordingly they begin their exhaust gases purification function at an earlier stage after start, which is a most essential feature. Moreover, metal substrates are more efficient thermal conductors, and thus they may be heated more quickly and the risk of local overheating is reduced. In addition, metal substrates support higher temperatures than ceramic ones.
As carrier members supporting the catalytic material so called metal monoliths are used. These consist of metal foils, preferably of stainless steel, wound into rolls wherein metal foils of flat configuration alternate with metal foils of corrugated configuration, whereby throughflow channels extending through the catalyst body are formed. The foil thickness is small, normally only about 0.05 mm. The catalyst body also includes a metal cover forming a jacket surrounding the monolith in contact with the latter. The cover thickness may amount to approximately 1 - 1.6 mm.
When the hot exhaust gases flow through the monolith during the combustion engine operation the thin carrier member foils are heated very rapidly. Usually, the temperature quickly reaches between 500 and 800°C. In some types of engines, the temperature may rise to the range of up to between 1100 and 1200°C. As soon as the engine stops, the temperature of the catalyst body rapidly sinks to the level of the ambient temperature.
The repeated temperature changes constitue a problem that affects the catalyst long-term durability. The rapidly heated thin foils of the monolith also expand quickly. The surrounding casing, in abutment against the monolith but not in close contact with the exhausts and in addition having a larger material thickness, is heated and expands at a slower pace. During the heating, the casing thus prevents the monolith from expanding, which gives rise to considerable radial compressive forces that cause deformations to form in the monolith. When the abovementioned high temperature levels are reached, the strength of the metal also is reduced considerably, often down to about 10% of its strength at room temperature, which aggravates the deformations and reduces the monolith life further.
When the engine is stopped and the exhausts cool down the opposite phenomenon occurs, i.e. the monolith foils cool at a higher speed than the surrounding thicker casing. As a result, considerable tensile forces generate between the outermost part of the monolith and the cover.
For the reasons outlined in the aforegoing, considerable problems are involved as regards the attachment of metal monoliths in their casings. Several various solutions have been proposed and tested, but often with poor results. Some viable constructions have been developed, e.g. by the German company Emitec GmbH, but they are comparatively complex and expensive. A feature common to all these prior-art solutions is that they apply to monoliths wherein the various metal foil layers are interconnected by means of soldering, with the outermost layer being soldered to the surrounding jacket. The subject invention provides a simple, reliable and economical solution to the securement problem. The solution functions both when applied to metal monoliths soldered together in the manner indicated above and when applied to metal monoliths joined together in some other manner, without soldering. The characteristic features of the attachment arrangement appear from the appended claims. The invention will be described in closer detail in the following with reference to the accompanying drawings, wherein
Fig. 1 is a broken schematical longitudinal sectional view through a catalyst body, Fig. 2 is a similar schematical longitudinal sectional view through a catalyst body showing a modified arrangement of attachment in accordance with the invention, and
Fig. 3 is a larger-scale view of a part of the attachment arrangement in accordance with the invention. Fig. 1 illustrates a basic design of the inventive object. A catalyst body 1 comprises a metal casing 2 enclosing a so called monolith 3. The latter in turn consists of carrier members, designed to support a catalytic material and consisting of helically wound metal foils, arranged so that flat metal foils 4 alternate with corrugated metal foils, so as to form through-flow channels 5 extending through the catalyst body 1. The monolith 3 has a width or diameter that is slightly smaller than the internal width of the casing 2. Accordingly, a gap 6 forms between the casing 2 and the monolith 3, the size of which varies within different temperature ranges.
In accordance with the invention, the casing 2 is provided with at least one band-like depression 7, in accordance with the embodiment illustrated in the drawing figure with two such depressions, the gap 6 around the monolith 3 thus being eliminated in the area opposite said depressions. Along these depressions 7 the casing 2 and the monolith 3 are interconnected, preferably only at spaced intervals 8, for instance by means of soldering or welding. When the monolith 3 is heated by the exhaust gases flowing through it, the monolith 3 expands quicker than the casing 2, which is due partly to the more intimate contact of the monolith 3 with the hot exhaust gases, partly to the larger material thickness of the casing 2. The expansion may now take place essentially unimpededly, with the exception of in the area of the depressions 7 where a certain deformation of the outermost foil 4 of the monolith 3 will take place. Consequently, no compressive forces will generate along the major part of the surface of the monolith 3. When the casing and the monolith 3 again cool down, the monolith 3 may again retract and thus again open up a gap 6.
Because the monolith 3 is exposed only to minor local deformations in the area of the depressions 7 and is allowed to expand and contract freely elsewhere, the catalyst body 1 may operate in an intact condition over a longer period than has hitherto been possible, with consequential increase of its serviceable life. Further improvements may be achieved by omitting to join one or some of the outermost foils 4 along the entire foil length to the the foils immediately interiorly thereof but instead joining them to one another at points spaced laterally from the points 8 of attachment. When the monolith 3 cools down, with consequential contraction, the tensile forces at the points 8 of attachment will not be very pronounced because of the resiliency imparted to the outermost foils 4 between their interconnection points. Figs. 2 and 3 illustrate a modification of the mode of attachment in accordance with the invention. In this case, an exhaust pipe 9 serves as the casing. In accordance with this modification, the monolith 3 is provided at each end with a circumferential collar 10 which projects past its associated monolith end and which is attached to the exhaust pipe 9. In the same manner as in accordance with the embodiment of Fig. 1, the collars 10 preferably are attached to the monolith 3 at discrete intervals 12. The collars 10 bridge a gap 11 formed between the exhaust pipe 9 and the monolith 3, the latter thus, upon heating and cooling, being given a compara- tively free space in which to expand and contract while at the same time it is securely anchored inside the exhaust pipe 9.
The invention is not limited to the embodiments as shown and described but could be modified in a variety of ways within the scope of the appended claims. For instance, the gap 6 could be eliminated by introduction of one or several inserts between the casing 2 and the monolith 3 instead of by forming depressions 7 in the casing.

Claims

1. A carrier arrangement for catalytic converters of the kind comprising a catalyst body (1) which consists of a monolith (3) of carrier members designed to support a catalytic material, said carrier members formed by superposed, alternately flat and corrugated metal foils (4) which are helically wound to form through-flow channels (5) extending through the catalyst body (1), and of a metal casing (2, 9) , the material thickness of which exceeds that of the metal foils (4) and which casing encloses the monolith (3), c h a r a c t e r i z e d in that the interior width of the casing (2, 9) exceeds that of the monolith (3), whereby a gap (6, 11) forms between the casing (2, 9) and the monolith (3), and in that said gap (6, 11) is bridged at least in the area of a section (7, 10) extending circumferentially around the monolith (3) , said monolith (3) being attached to the casing (2, 9) along said section (7, 10) .
2. An arrangement as claimed in claim 1, c h a ¬ r a c t e r i z e d in that the gap (6) is bridged in the area of said section (7) by a radial depression of the casing (2) .
3. An arrangement as claimed in claim 1, c h a ¬ r a c t e r i z e d in that in the area of said section (7) the monolith (3) is attached to the casing (2) only in some points (8) circumferentially around the monolith.
4. An arrangement as claimed in claim 1, c h a ¬ r a c t e r i z e d in that the monolith (3) is formed at each end with a circumferential collar (10) which bridges the gap (11) between the monolith (3) and the casing (9) and which is attached to said casing (9) .
5. An arrangement as claimed in claim 4, c h a ¬ r a c t e r i z e d in that the collar (10) is attached to the monolith (3) only at some points (12) along the monolith circumference.
EP96911153A 1995-04-27 1996-04-18 A catalyst carrier arrangement Revoked EP0840840B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SE9501556A SE506670C2 (en) 1995-04-27 1995-04-27 Catalyst mounting arrangement
SE9501556 1995-04-27
PCT/SE1996/000499 WO1996034188A1 (en) 1995-04-27 1996-04-18 A catalyst carrier arrangement

Publications (2)

Publication Number Publication Date
EP0840840A1 true EP0840840A1 (en) 1998-05-13
EP0840840B1 EP0840840B1 (en) 2003-07-23

Family

ID=20398107

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96911153A Revoked EP0840840B1 (en) 1995-04-27 1996-04-18 A catalyst carrier arrangement

Country Status (9)

Country Link
EP (1) EP0840840B1 (en)
JP (1) JPH11504094A (en)
KR (1) KR19990008026A (en)
CN (1) CN1084429C (en)
AU (1) AU5412096A (en)
DE (1) DE69629196T2 (en)
ES (1) ES2203689T3 (en)
SE (1) SE506670C2 (en)
WO (1) WO1996034188A1 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE257904T1 (en) * 1997-03-21 2004-01-15 Kemira Metalkat Oy CATALYTIC REACTOR
CN1096542C (en) * 1997-03-21 2002-12-18 凯米拉梅塔尔卡特公司 Improvements in catalytic reactors
SE9704265L (en) * 1997-11-21 1998-10-19 Nilcon Eng Ab Catalyst with cam flange for clamping
SE522537C2 (en) 2000-03-21 2004-02-17 Kemira Metalkat Oy Catalyst support with jacket
EP1230978B1 (en) * 2001-02-12 2005-09-28 Ecocat Oy Method for manufacturing a corrugated metal reactor packing
JP5080306B2 (en) * 2008-02-14 2012-11-21 エコキャット オサケユイチア Improved catalytic reactor
DE102018201738A1 (en) * 2018-02-05 2019-08-08 Continental Automotive Gmbh Catalyst and process for its preparation

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3664361D1 (en) * 1985-07-25 1989-08-17 Interatom Mounting device for a metallic flue gas catalyst support body, and method of manufacturing it
JPH0721855Y2 (en) * 1987-07-10 1995-05-17 日産自動車株式会社 Catalytic converter device
DE8812762U1 (en) * 1988-10-11 1989-06-29 Emitec Gesellschaft für Emissionstechnologie mbH, 5204 Lohmar Catalyst with double jacket system
DE3926072C2 (en) * 1989-08-07 1994-01-13 Emitec Emissionstechnologie Exhaust gas purification catalyst with elastic elements to compensate for longitudinal expansion
DE3930680A1 (en) * 1989-09-14 1991-03-28 Behr Gmbh & Co Radial and axial movements of expanding exhaust purifier - matrix in housing are permitted by fixed and mobile supports incorporating spring strips
JPH0634927B2 (en) * 1989-11-16 1994-05-11 トヨタ自動車株式会社 Metal carrier for exhaust gas purification catalyst

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9634188A1 *

Also Published As

Publication number Publication date
SE9501556L (en) 1996-10-28
SE9501556D0 (en) 1995-04-27
DE69629196D1 (en) 2003-08-28
DE69629196T2 (en) 2004-02-19
CN1182468A (en) 1998-05-20
AU5412096A (en) 1996-11-18
SE506670C2 (en) 1998-01-26
EP0840840B1 (en) 2003-07-23
ES2203689T3 (en) 2004-04-16
JPH11504094A (en) 1999-04-06
WO1996034188A1 (en) 1996-10-31
CN1084429C (en) 2002-05-08
KR19990008026A (en) 1999-01-25

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