EP0816476A1 - Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt - Google Patents

Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt Download PDF

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Publication number
EP0816476A1
EP0816476A1 EP97401413A EP97401413A EP0816476A1 EP 0816476 A1 EP0816476 A1 EP 0816476A1 EP 97401413 A EP97401413 A EP 97401413A EP 97401413 A EP97401413 A EP 97401413A EP 0816476 A1 EP0816476 A1 EP 0816476A1
Authority
EP
European Patent Office
Prior art keywords
fuel
oil
weight
heavy
fuel according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP97401413A
Other languages
English (en)
French (fr)
Other versions
EP0816476B1 (de
Inventor
Jean-Bernard Sigaud
Corinne Van Den Neste
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Marketing Services SA
Original Assignee
Total Raffinage Distribution SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Total Raffinage Distribution SA filed Critical Total Raffinage Distribution SA
Publication of EP0816476A1 publication Critical patent/EP0816476A1/de
Application granted granted Critical
Publication of EP0816476B1 publication Critical patent/EP0816476B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only

Definitions

  • the present invention relates to a fuel for oil-based boilers natural vegetable and containing very small quantities of sulfur, this fuel being capable of being burned in combustion plants, either directly or mixing with other fuels, without modifying the burners.
  • the fuel according to the present invention may optionally contain, in preferably less than 20% by weight, a complement of compounds hydrocarbons whose distillation interval is preferably between that of petroleum and vegetable oil cutting, and the sulfur content of which is also less than 0.05% by weight and preferably less than 0.01% by weight.
  • the invention also relates to fuel mixtures including fuel that has just been defined.
  • hydrotreatment reactors for this type of cut, as well as the other types of valuation likely to apply to said cut must also be taken into account.
  • cuts may come, among other things, from a non-hydrogenating conversion of the FCC type (catalytic cracking in the fluid state), catalytic reforming, steam cracking, or pyrolysis.
  • the cuts thus obtained are free of heavy polyaromatic compounds with 3 or more cycles, (amount less than 0.5% by weight and preferably less than 0.1% by weight); they are also free of nitrogen compounds.
  • they can comprise up to 25% and more of monoaromatic and diaromatic compounds; these will be present in a volume ratio of a chosen value, preferably between 8 and 12.
  • this cut of hydrocarbons, after hydrotreatment (hydrodesulfurization), that is to say after passage in the presence of a hydrotreatment catalyst in a reactor containing hydrogen with a pressure greater than 10 ⁇ 10 5 Pa (10 bars), contains less than 0.05% and preferably less than 0.01% by weight of sulfur.
  • the vegetable oil which can be used in the fuel according to the invention is preferably an oil from a plant that can be cultivated with a high yield at per hectare. It can be advantageously chosen from the group comprising sunflower, palm oil, coconut oil, soybean oil, rapeseed oil and their mixtures. Preferably, the vegetable oil is rapeseed oil.
  • the ratio between the volume of heavy petrol rich in aromatic compounds and the volume of vegetable oil in the mixture will be between 0.5 and 10 and preferably between 0.8 and 5.
  • This fuel is therefore particularly suitable for combustion on a boiler located in an environmentally sensitive area.
  • the fuel according to the present invention can be mixed with another cut of hydrocarbons, preferably free of sulfur, such as, for example, heavy diesel from a hydrocracking process, or an ester of a vegetable oil.
  • another cut of hydrocarbons preferably free of sulfur, such as, for example, heavy diesel from a hydrocracking process, or an ester of a vegetable oil.
  • the subject of the invention is also the use of the fuel in accordance with the invention in boilers and / or furnaces of the collective and / or industrial type, without modifications to said boilers or said ovens.
  • This table also shows that the fuels (3) and (4) consisting exclusively of heavy gasoline of catalytic cracking and vegetable oil have remarkably low sulfur contents; no SO 2 emission was detected in the combustion fumes.
  • the green fuels described in (3) to (6) can be burned in a boiler usually using domestic fuel oil, without modifying the installation of initial boiler, and in particular of burner (s). They also have good storage stability.
  • the burning rapeseed oil even on a modified burner, poses a big problem of start-up (given the low intrinsic volatility of the product), adding variable proportion of cut B, mixed with significant quantities of oil of rapeseed, considerably improves the ignition by electrodes, when starting the burner.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Liquid Carbonaceous Fuels (AREA)
EP97401413A 1996-06-19 1997-06-19 Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt Expired - Lifetime EP0816476B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9607641A FR2750141B1 (fr) 1996-06-19 1996-06-19 Combustible pour chaudieres a base d'huile vegetale et a basse teneur en soufre
FR9607641 1996-06-19

Publications (2)

Publication Number Publication Date
EP0816476A1 true EP0816476A1 (de) 1998-01-07
EP0816476B1 EP0816476B1 (de) 2002-08-28

Family

ID=9493226

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97401413A Expired - Lifetime EP0816476B1 (de) 1996-06-19 1997-06-19 Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt

Country Status (6)

Country Link
EP (1) EP0816476B1 (de)
AT (1) ATE222942T1 (de)
DE (1) DE69714919T2 (de)
DK (1) DK0816476T3 (de)
ES (1) ES2184043T3 (de)
FR (1) FR2750141B1 (de)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1486555A1 (de) * 2003-06-04 2004-12-15 Shell Internationale Researchmaatschappij B.V. Verwendung von korrosionsarmen Brenstoffenzusammensetzungen in einem Kessel
EP1965134A1 (de) * 2007-03-01 2008-09-03 Viessmann Werke GmbH & Co KG Heizkesselanlage und Verfahren zum Betrieb einer Heizkesselanlage
FR2916204A1 (fr) * 2007-05-15 2008-11-21 Region Poitou Charentes Combustible a base d'huile vegetale.
WO2013098524A1 (fr) * 2011-12-28 2013-07-04 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse
FR2985267A1 (fr) * 2011-12-28 2013-07-05 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse.
FR2985266A1 (fr) * 2011-12-28 2013-07-05 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse.

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6740134B2 (en) 2001-08-24 2004-05-25 Twin Rivers Technologies, L.P. Use of a natural oil byproduct as a reduced-emissions energy source
DE202004016756U1 (de) * 2004-10-28 2006-03-09 Evg Ein- Und Verkaufs-Genossenschaft E.G. Pflanzenölverbrennungsanlage

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2292033A1 (fr) * 1974-11-22 1976-06-18 Puget Marcel Nouveau carburant et procede pour sa preparation
WO1994019430A1 (en) * 1993-02-26 1994-09-01 Exxon Chemical Patents Inc. Oil additives and compositions
DE4333418C1 (de) * 1993-09-30 1994-10-13 Tessol Kraftstoffe Mineraloele Treibstoffgemisch
WO1995025152A1 (en) * 1994-03-14 1995-09-21 Valtion Teknillinen Tutkimuskeskus New fuel composition
EP0717097A1 (de) * 1994-12-14 1996-06-19 Total Raffinage Distribution S.A. Auf pflanzlichem Öl und aromatenreicher Petroleumfraktion basierter Brennstoff

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2292033A1 (fr) * 1974-11-22 1976-06-18 Puget Marcel Nouveau carburant et procede pour sa preparation
WO1994019430A1 (en) * 1993-02-26 1994-09-01 Exxon Chemical Patents Inc. Oil additives and compositions
DE4333418C1 (de) * 1993-09-30 1994-10-13 Tessol Kraftstoffe Mineraloele Treibstoffgemisch
WO1995025152A1 (en) * 1994-03-14 1995-09-21 Valtion Teknillinen Tutkimuskeskus New fuel composition
EP0717097A1 (de) * 1994-12-14 1996-06-19 Total Raffinage Distribution S.A. Auf pflanzlichem Öl und aromatenreicher Petroleumfraktion basierter Brennstoff

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1486555A1 (de) * 2003-06-04 2004-12-15 Shell Internationale Researchmaatschappij B.V. Verwendung von korrosionsarmen Brenstoffenzusammensetzungen in einem Kessel
EP1965134A1 (de) * 2007-03-01 2008-09-03 Viessmann Werke GmbH & Co KG Heizkesselanlage und Verfahren zum Betrieb einer Heizkesselanlage
FR2916204A1 (fr) * 2007-05-15 2008-11-21 Region Poitou Charentes Combustible a base d'huile vegetale.
WO2009004134A2 (fr) * 2007-05-15 2009-01-08 Region Poitou Charentes Combustible a base d'huile vegetale
WO2009004134A3 (fr) * 2007-05-15 2009-03-05 Region Poitou Charentes Combustible a base d'huile vegetale
WO2013098524A1 (fr) * 2011-12-28 2013-07-04 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse
FR2985267A1 (fr) * 2011-12-28 2013-07-05 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse.
FR2985266A1 (fr) * 2011-12-28 2013-07-05 Total Raffinage Marketing Composition combustible comprenant un fioul lourd et un produit issu de la biomasse.

Also Published As

Publication number Publication date
ES2184043T3 (es) 2003-04-01
ATE222942T1 (de) 2002-09-15
FR2750141A1 (fr) 1997-12-26
DK0816476T3 (da) 2002-12-09
EP0816476B1 (de) 2002-08-28
FR2750141B1 (fr) 2004-04-30
DE69714919T2 (de) 2003-04-24
DE69714919D1 (de) 2002-10-02

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